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A. General:
B. Marking scheme:
3. Single Choice Correct Type +4, –1
PART – I : PHYSICS
(Single Correct Answer Type)
1 The distance between plates of a parallel plate capacitor is 5d. Let the positively
charged plate is at x=0 and negatively charged plate is at x=5d. Two slabs
one of conductor and other of a dielectric of equal thickness d are inserted
between the plates as shown in figure.
Potential versus distance graph will look like :
2 A parallel plate capacitor has two layers of dielectric as shown in figure. This
capacitor is connected across a battery. The graph which shows
the variation of electric field (E) and distance (x) from left plate.
3 The distance between the plates of a charged parallel plate capacitor is 5 cm and electric field inside the plates
is 200 Vcm–1. An uncharged metal bar of width 2 cm is fully immersed into the capacitor. The length of the metal
bar is same as that of plate of capacitor. The voltage across capacitor after the immersion of the bar is
(A) zero (B) 400 V (C) 600 V (D) 100 V
4 Three large plates are arranged as shown. How much charge will flow through
the key k if it is closed?
5Q 4Q 3Q
(A) (B) (C) (D) none
6 3 2
FIITJEE 1
5 A nonconducting ring of radius R has uniformly distributed positive charge A small part of the ring, of length d,
is removed (d << R). The electric field at the centre of the ring will now be
(A) directed towards the gap, inversely proportional to R3.
(B) directed towards the gap, inversely proportional to R2.
(C) directed away from the gap, inversely proportional to R3.
(D) directed away from the gap, inversely proportional to R2.
6 If charge on left plane of the 5F capacitor in the circuit segment shown in the
figure is –20C, the charge on the right plate of 3F capacitor is
(A) +8.57 C (B) –8.57 C (C) +11.42 C (D) –11.42 C
7 Electric field given by the vector E x î yˆj is present in the XY plane. A
small ring carrying charge +Q, which can freely slide on a smooth non
conducting rod, is projetced along the rod from the point (0, L) such that it can
reach the other end of the rod. What minimum velocity should be given to the
ring?(Assume zero gravity)
(A) (QL2/m)1/2 (B) 2(QL2/m)1/2
8 A capacitor of capacitance C is charged to a potential difference V from a cell and then disconnected from it. A
charge +Q is now given to its positive plate. The potential difference across the capacitor is now
Q Q Q
(A) V (B) V + (C) V + (D) V – , if V < CV
C 2C C
9 A unit positive point charge of mass m is projected with a velocity V inside the tunnel
as shown. The tunnel has been made inside a uniformly charged non conducting
sphere. The minimum velocity with which the point charge should be projected such it
can it reach the opposite end of the tunnel, is equal to
(A) [R2/4m0]1/2
(B) [R2/24m0]1/2
(C) [R2/6m0]1/2
(D) zero because the initial and the final points are at same potential.
10 A conducting body 1 has some initial charge Q, and its capacitance is C. There are two other conducting
bodies, 2 and 3, having capacitances : C2 = 2C and C3 . Bodies 2 and 3 are initially uncharged. "Body 2 is
touched with body 1. Then, body 2 is removed from body 1 and touched with body 3, and then removed." This
process is repeated N times. Then, the charge on body 1 at the end must be
(A) Q/3N (B) Q/3N–1 (C) Q/N3 (D) None
11 Condenser A has a capacity of 15 F when it is filled with a medium of dielectric constant 15. Another condenser
B has a capacity 1 F with air between the plates. Both are charged separately by a battery of 100V . After
charging, both are connected in parallel without the battery and the dielectric material being removed. The
common potential now is
(A) 400V (B) 800V (C) 1200V (D) 1600V
12 In the adjoining figure, capacitor (1) and (2) have a capacitance ‘C’ each. When the dielectric of dielectric consatnt
K is inserted between the plates of one of the capacitor, the total charge flowing through battery is
KCE KCE
(A) from B to C (B) from C to B
K 1 K 1
(K 1)CE (K 1)CE
(C) from B to C (D) from C to B
2(K 1) 2(K 1)
FIITJEE 2
13 Two identical capacitors 1 and 2 are connected in series to a battery as shown in figure.
Capacitor 2 contains a dielectric slab of dielectric constant k as shown. Q1 and Q2 are
the charges stored in the capacitors. Now the dielectric
slab is removed and the corresponding charges are Q’1 and Q’2. Then
Q1 k 1 Q2 k 1 Q2 k 1 Q1 k
(A) (B) (C) (D)
Q1 k Q2 2 Q2 2k Q1 2
14 The area of the plates of a parallel plate capacitor is A and the gap between them is d. The gap is filled with a
non-homogeneous dielectric whose dielectric constant varies with the distance ‘y’ from one plate as : K =
sec(y/2d), where is a dimensionless constant. The capacitance of this capacitor is
(A) 0A / 2d (B) 0A /d (C) 20A /d (D) none
15 A capacitor stores 60C charge when connected across a battery. When the gap between the plates is filled
with a dielectric , a charge of 120C flows through the battery. The dielectric constant of the material inserted is
:
(A) 1 (B) 2 (C) 3 (D) none
16 In the above question, if the initial capacitance of the capacitor was 2F, the amount of heat produced when
the dielectric is inserted.
(A) 3600J (B) 2700J (C) 1800J (D) none
18 Three plates A, B and C each of area 0.1 m2 are separated by 0.885 mm from
each other as shown in the figure. A 10 V battery is used to
charge the system. The energy stored in the system is
(A) 1 J (B) 10–1 J (C) 10–2 J (D) 10–3 J
19 A parallel plate capacitor of capacitance C is connected to a battery and is charged to a potential difference V.
Another capacitor of capacitance 2C is similarly charged to a potential difference 2V. The charging battery is
now disconnected and the capacitors are connect in parallel to each other in such a way that the positive
terminal of one is connected to the negative terminal of the other. The final energy of the configuration is
3 2 25 2 9 2
(A) zero (B) CV (C) CV (D) CV
2 6 2
21 A parallel plate capacitor A is filled with a dielectric whose dielectric constant varies with applied voltage as K =
V. An identical capacitor B of capacitance C0 with air as dielectric is connected to voltage source V0 = 30V and
then connected to the first capacitor after disconnecting the voltage source. The charge and voltage on capacitor.
(A) A are 25C0 and 25V (B) A are 25C0 and 5 V
(C) B are 5c0 and 5V (D) B are 5C0 and 25 V
FIITJEE 3
22 Two capacitors of 2 F and 3 F are charged to 150 volt and 120 volt
respectively. The plates of capacitor are connected as shown in the
figure. A discharged capacitor of capacity 1.5 F falls to the free ends
of the wire. Then
(A) charge on the 1.5 F capacitors is 180 C
(B) charge on the 2F capacitor is 120 C
(C) charge flows through A from right to left.
(D) charge flows through A from left to right.
23 In the circuit shown, each capacitor has a capacitance C. The emf of the cell is E. If the switch S is closed
(A) positive charge will flow out of the positive terminal of the cell
(B) positive charge will enter the positive terminal of the cell
(C) the amount of charge flowing through the cell will be CE.
(D) the amount of charge flowing through the cell will be 4/3 CE.
24 In the circuit shown initially C1, C2 are uncharged. After closing the switch
(A) The charge on C2 is greater that on C1
(B) The charge on C1 and C2 are the same
(C) The potential drops across C1 and C2 are the same
(D) The potential drops across C2 is greater than that across C1
25 A parallel plate air-core capacitor is connected across a source of constant potential difference. When a dielectric
plate is introduced between the two plates then :
(A) some charge from the capacitor will flow back into the source.
(B) some extra charge from the source will flow back into the capacitor.
(C) the electric field intensity between the two plate does not change.
(D) the electric field intensity between the two plates will decrease.
FIITJEE 4
PART – II : CHEMISTRY
(Single Correct Answer Type)
28 If the starting material is 1–methyl–1,2–epoxy cyclopentane, of absolute configuration, decide which one
compound correctly represent the product of its reaction with sodium methoxide in methanol.
(A) (B)
(C) (D)
14 14
(C) C H 2 CHCH 2 OC 2 H 5 (D) CH 2 CH C H 2 OC 2 H 5
\ / \ /
O O
30 Ethanol on reaction with acetic anhydride gives
(A) Acetic ester (B) Formic ester
(C) Ethanoic acid (D) Acetic ester and Ethanoic acid both
31 Ethanol cannot be dried by anhydrous CaCl2 due to formation of the following solvated product
(A) CaCl2·2C2H5OH (B) 2CaCl2·3C2H5OH (C) CaCl2·3C2H5OH (D) CaCl2·C2H5OH
32 Rate of hydration of
, ,
will be in order:
(A) I < II < III (B) I < III < II (C) II < I < III (D) III < II < I
FIITJEE 5
35 A compound ‘X’ with molecular formula C3H8O can be oxidised to a compound ‘Y’ with the molecular formula
C3H6O2, ‘X’ is most likely to be
(A) Primary alcohol (B) Secondary alcohol (C) Aldehyde (D) Ketone
••
36 I R O R ' RI + R'OH true about this mechanism
|
H
(A) SN1 in gas phase (B) SN2 in aqueous phase
(C) both of the above (D) none
38
A. ‘A’ is
H 3O
cold
39 A CrO
3 B
alkaline KMnO
4 AcOH
A and B are:
(A) , (B) ,
NaBH H / Pt
40 4
B CH = CH – CHO 2
A
A and B are:
FIITJEE 6
3 CH OH H O18
41 B 2 A
CH 3ONa H
A and B are
CH 3 CH 3 CH 3 CH 3
| | | |
(A) CH 3 C CH 2 , CH 3 C CH 2 (B) CH 3
C — CH 2 , CH 3 C CH 2
| | | | | | | |
18 OH OH OH OCH 3 OH18OH OH OCH 3
CH 3 CH 3 CH 3 CH 3
| | | |
(C) CH 3 C CH 2 , CH C — CH (D) CH C — CH , CH C — CH
3 2 3 2 3 2
| | | | | | | |
18 OH OH OH 18OH 18
18 18 OH OH
OCH 3 OH
42
will be in order
(A) IV > III > II > I (B) I > II > III > IV (C) IV > II > III > I (D) II > IV > I > III
H O HBr HCHO
B Mg
/
ether
44 CH3MgBr + 3
A C D
HI E
H O 3
E is
FIITJEE 7
45 H
? Product is:
Alc
. KOH
46 Major product is
(A) (B)
(C) (D)
47 RMgX
? Product Obtained is:
H2O
R R' R R
| | | |
(A) R 'C CH 2 OH (B) RCH 2 C OH (C) R ' CH 2 C OH (D) R ' ' CH 2 C OH
| | | |
R'' R'' R' ' R'
2 I / NaOH
48 H
A, A is
49 AlCl
3 ? Major Product is:
(C) (D)
FIITJEE 8
NaNO
50 2 A
HCl
A is
O
||
(C) CH 2 CHCCH 2 CHO (D) CH CHCCH COH
2 2
|| ||
O O
O O OH O
|| || | ||
(A) CH CH CCH CCH (B) CH 3CHCCH 2 CH 3
3 2 2 3
O O
|| ||
(C) (D) CH 3CCH 2 CHCH 2 CCH 3
|
OH
FIITJEE 9
57 Which one of the following will most readily be dehydrated in acidic condition:
60 Reaction of entainomerically pure acid with 1 chiral carbon and racemic alcohol with 1 chiral carbon gives an
ester which is:
(A) Meso (B) Optically active mixture
(C) Racemic mixture (D) Enantionmerically pure
H O dil. H SO
2 H
67 In the reaction sequence, CaC2
2 2
A 4 B C, true about the product C is
2 Ni
Hg
(A) give yellow ppt. with NaOI
(B) its final oxidation product is carbonyl compound
(C) its final oxidation product is CO2 and H2O
(D) its final oxidation product is CH3COOH
FIITJEE 10
68 HBO, oxymercuration-demercuration and acid catalysed hydration will not give same product in
(A) + HNO3 H SO 4
2
(B) + HNO3 H SO 4
2
(C) CH2 = CH–CHO + LiAlH4 CH3 CH2CH2OH
(D) + CH3ONa
O
Select the correct statement(s) ||
(A) It is more acidic than CH3OH (B) It is more acidic than CH COH
3
(C) It reacts very fast with Lucas reagent (D) It is a diacid base
FIITJEE 11
P
PAAR
RTT –– IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
(Single Correct Answer Type)
1 x 1
76 The range of f(x) (sin–1 x tan–1 x) 2 is :
x 2x 5
3 1 –5 3 –3 5 –3
(A) – , (B) , (C) , (D) , 1
4 5 4 4 4 4 4
2
77 Let f(x) x 2 – x where x [0, n], n N Find number of elements in the range of f(x) is (where [.]
denotes G.I.F)
(A) 2n + 1 (B) 4n – 3 (C) 2n (D) 2n – 1
(A) {0} (B) 0, (C) 0, (D) None of these
2
x 1
79 The real values of ‘a’ does range of f(x) contains the interval [0, 1] is :
x2 a
(A) (–, –1) (–1, 10) (B) (–, 0) (C) (–1, 1) (D) None of these
x2
81 If the normal of y = f(x) at (0, 0) is given by y – x = 0, then lim is equal to :
x 0 f(x 2 ) – 20f(9x 2 ) 2f(99x 2 )
1 –1 1
(A) (B) (C) (D) Non-existent
19 19 2
x
82 Let f(x) tan2 2 cot(n m)x (n, N, m Q) is a periodic function with fundamental period 2
n – 5n 8
then m cannot belong to :
(A) (–, –2) (–1, ) (B) (–, –3) (–2, ) (C) (–2, –1) (–3, –2) (D) (–3, –5/2) (–5/2, –2)
83 Let f : A B & g : B C be functions & gof : A C then which of the following is incorrect.
(A) If gof is one-one then f & g both are one-one (B) If gof is one-one then f is one-one
(C) If gof is a bijection then f one-one & g is onto (D) If f & g are both one-one then gof is one-one
1
84 If f(x) = 2x + |x|, g(x) (2x– | x |) and h(x) f(g(x)). then domain of sin–1(h(h(h........... h(x)))) is :
3 n times
1 1 1 1
(A) [–1, 1] (B) –1, – , 1 (C) –1, – (D) , 1
2 2 2 2
n
k 1
85 lim
n
(2k 1)2 (2k 3)2 equals
k 1
1 1 1 1
(A) (B) (C) (D)
72 36 18 9
x2 x2
12
FIITJEE
[x] [x – 2] 8{x} 12
87 Number of solution of equation – where [.] G.I.F & {.} denotes fractional
[x – 2] [x] [x – 2][x]
part of x.
(A) 3 (B) 4 (C) 5 (D) None of these
x
e(x 1)
– xx
88 The value of lim 2
is equal to
x 0
(x 2 x
) –1
1 3 1
(A) 1 (B) (C) (D)
8 2 4
89 Number of solution of equation [x] + [2x] + [4x] + [8x] + [16x] + [32x] = 12345 where [.] denotes greatest
integer function.
(A) 0 (B) 1 (C) 2 (D) None of these
2 2
90 Number of ordered pair (x, y) which satisfy |x – 2x| + y = 1 and x + |y| = 1 is :
(A) 2 (B) 3 (C) 4 (D) 5
2 1– cos2x
91 The no. of solution of equation 1 ecot x
2 | sin x | –1 is (where x [–2, 2])
1 sin4 x
(A) 3 (B) 4 (C) 5 (D)
3 2
92 The range of value of ‘a’ so that all roots of 2x – 3x – 12x + a = 0 are real and distinct is :
(A) (7, 20) (B) (–7, 20) (C) (–20, 7) (D) (–7, 7)
x r
93 Let x2 – 4px + q2 > 0 x R & r2 + p2 < qr, then range of function f(x) is :
x qx p2
2
P q
(A) , (B) (0, ) (C) (–, 0) (D) (–, )
2r 2r
x
1
94 Let f(x) is a continuous function which positive values for x 0 and satisfy f(t)lt = x f(x) with f(1) ,
0
2
then value of f( 2 1) is :
1 1
(A) 1 (B) 2 –1 (C) (D)
4 2 –1
95 Let f(x) and g(x) are non periodic function then h(x) f(g(x)) is :
(A) non periodic (B) periodic
(C) may be periodic (D)always periodic of domain of h(x) is proper subset of real number
x(x 4 1)(x 1) x 4 2
96 f : R R defined as f(x) then f(x) is :
x2 x 1
(A) one-one into (B) may one onto (C) one-one onto (D) May one into
x
1– tan 1– sin x
2
97 lim is :
x 3
2 1 tan – 2x
x
2
1 1
(A) (B) (C) 0 (D)
8 32
13
FIITJEE
Paragraph Type
2
Let f(x) = ax + bx + c, where a, b, c R if |f(x)| 1 x [–1, 1] then answer the following questions.
8 2
98 The possible value of |a + c|, if a 2b2 is maximum :
3
(A) 1 (B) 0 (C) 2 (D) 3
8 2
99 The possible value of |a + b|, if a 2b2 is maximum :
3
(A) 1 (B) 0 (C) 2 (D) 3
8 2
100 The possible maximum value of a 2b2is
3
16
(A) 32 (B) (C) 10 (D) None of these
3
14
FIITJEE