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SCIENCE
AND THE SKY
Solving
the
mystery
of
disappearing
ozone
Dr.
B.H.
Lower
(Ohio
State
University)
The Scientific Method
Prediction
Fail to
reject Peer review
Test hypothesis of Paper
Results
Scientific
paper
Monday, April 2, 12
2 SCIENCE AND THE SKY
Learning
Outcomes
Earth’s Atmosphere
Layers of Earth’s
Atmosphere
Gases in extremely thin air absorb X-
rays and short-wave radiation raise
temperature to 1000oC or higher
is below 30 km
Sun
O O O
uv + molecular O
light O oxygen (O2) O O
oxygen
O atom (O) ozone (O3)
O
Earth’s stratosphere
The Ozone (O3) Layer Shields Earth’s Surface from ultraviolet radiation
The Sun (like all stars) emits different types radiation and one type of radiation,
called ultraviolet (uv) radiation, is particularly dangerous to living organisms. UV
radiation can damage DNA and cause cancer. UV radiation travels from the Sun,
through space to our planet. Earth’s ozone (O3) layer is found in the stratosphere,
approximately 30 km (20 miles) up from Earth’s surface. Ozone (O3) absorbs
nearly all of the Sun’s uv radiation and protects all organisms from its damages.
https://svs.gsfc.nasa.gov/vis/a000000/
a000800/a000834/index.html
Sun
O O
O O O O O
O
O O
O
O O O
uv O
light O O
O O
O
ozone (O3)
O
Earth’s
O
layer
O
O
O
stratosphere
2 SCIENCE AND THE SKY
TERMS
TO
KNOW:
Solomon
and
her
team
flew
to
the
ObservaMons
AntarcMc
to
collect
data
about
the
Inferences
thinning
of
the
ozone
in
response
to
a
Atmosphere
publicaMon
by
Joe
Farman
of
the
BriMsh
Troposphere
AntarcMc
Survey.
Stratosphere
Ozone
2 Science gives us tools to observe the natural world
1957–
Beginning
of
data
collecMon
with
on-‐the-‐ground
instruments
designed
to
extend
the
researchers’
senses
and
measure
atmospheric
composiMon
First
indicaMons
of
lower
than
normal
ozone
levels
used
to
make
inferences
about
possible
causes
2 Science gives us tools to observe the natural world
1970s
–
Discovered
that
the
ozone
layer
had
thinned
about
33%
during
the
AntarcMc
spring
Dangers associated
with UV-‐B:
TERMS
TO
KNOW:
CFCs
were
first
developed
in
the
1930s
as
a
Ultraviolet
radiaMon
(UV)
commercial
coolant
in
refrigerators
and
air
condiMoners.
By
the
1970s,
they
were
in
Science
everything
from
hairspray
to
fast-‐food
Empirical
evidence
containers.
CorrelaMon
uv
light Cl + O O molecular oxygen
(O2)
Sun chlorine O
(Cl) ozone O O
F Cl (O3)
C Cl O chlorine
CFC
Cl F Earth’s monoxide (ClO)
stratosphere
The Hole is the Ozone (O3) is Bad for Life
ozone (O3)
O layer
O O O
F
C
O O
uv
ozone C l
light
hole Cl
F CFC
Earth’s
O
O
stratosphere O
1. The formation of ozone is a slow chemical process
compared to the process by which CFCs break apart (i.e.,
destroy) ozone molecules.
2. The hole in Earth’s ozone layer occurs because CFCs
break apart ozone molecules faster than new ozone
molecules can be created.
3. The destruction of ozone by CFCs is an anthropogenic
process (i.e., caused by human activity), while the creation
of ozone is a natural process.
4. Ozone is important for life on Earth because ozone acts
like a shield to block ultraviolet (uv) radiation from
organisms that live on Earth.
5. Ultraviolet radiation (uv radiation) is harmful to all
organisms on Earth because it damages DNA and causes
cancer.
Cl catalyzed ozone
(O3) destruc?on over Antarctica
In
the
winter
sun
does
NOT
reach
AntarcMca,
which
becomes
very
cold.
Strong
winds
develop
in
the
middle
to
lower
stratosphere
that
circulate
around
the
conMnent
creaMng
a
polar
vortex
which
isolates
the
air
within
it.
Polar
stratospheric
clouds
form
in
the
extreme
cold
(-‐80o
C).
These
clouds
are
composed
of
water,
nitric
acid,
and
ice
and
these
provide
surfaces
for
O3
destrucMon
by
atomic
Cl.
Susan Solomon’s hypothesis
-‐
In
the
spring
the
sun
returns
and
ozone
is
destroyed
via:
CFCl3
+ sunlight
→
CFCl2
+ Cl
Cl
+
O3
→
ClO
+
O2
ClO
+
O3
→
Cl
+
2
O2
The
ozone
hole
grows
through
the
spring
unMl
air
warms
and
polar
vortex
weakens.
NASA Ozone Watch
Ozone maps from 1979 to present for Northern and Southern Hemispheres
https://ozonewatch.gsfc.nasa.gov/monthly/SH.html
2 The scientific method systematically rules out explanations
TERMS
TO
KNOW:
Was
there
evidence
for
the
possibility
that
ScienMfic
method
CFCs
were
destroying
ozone?
Hypothesis
A
NASA
report
in
1985
confirmed
that
ozone
Testable
was
being
destroyed
even
faster
than
earlier
PredicMon
projecMons.
Hypothesis
–
Cloud
parMcles
in
the
polar
stratospheric
clouds
were
providing
surfaces
for
the
reacMons
that
would
free
chlorine
molecules
from
CFCs.
In
sunlight,
the
chlorine
molecules
would
then
break
up
into
isolated
chlorine
atoms
that
destroyed
ozone.
Is
this
hypothesis
testable
and
falsifiable?
2 Different types of studies amass a body of evidence
Normal
ozone
breakdown
and
formaMon
Studying
effects
of
UV-‐B
on
plants
2 Different types of studies amass a body of evidence
CFC-‐driven
ozone
breakdown
Studying
effects
of
UV-‐B
on
plants
2 Different types of studies amass a body of evidence
CFC-‐driven
ozone
breakdown
2 Different types of studies amass a body of evidence
TERMS
TO
KNOW:
Actual
and
projected
change
over
Mme
for
global
emissions
of
ozone-‐depleMng
substances
StaMsMcs
Montreal
Protocol
Policy
PrecauMonary
principle
AdapMve
management
1985
– Experts
meet
in
Vienna
to
discuss
ways
to
research
and
solve
the
problem.
1987
– The
internaMonal
community
comes
together
in
Montreal
to
produce
a plan
for
dealing
with
ozone
depleMon
—phase
out
dangerous
chemicals
like
CFCs.
2009
– The
Montreal
Protocol
is
raMfied
by
all
196
countries
in
the
world.
Helping
the
Ozone
Layer
Recover
In
1978
the
USA
(the
largest
user
of
• In
1987
Montreal
Protocol
was
CFCs)
banned
the
use
of
CFC
signed
by
many
countries
and
it
propellants
in
anMperspirants
and
hair
sMpulated
a
50%
reducMon
in
CFC
sprays.
This
was
a
good
start,
but
producMon
by 1998.
propellants
represented
only
a
small
• Industries
have
manufactured
new
porMon
of
the
CFC
use.
CFCs
that
do
NOT
aOack
the
ozone
layer,
but
ARE
potent
greenhouse
gases
others
aOack
ozone,
but
not
as
much
as
older
CFCs
• CFCs
are
extremely
stable
in
atmosphere
with
lifeMmes
of
decades
• Full
recovery
of
ozone
layer
is
es?mated
to
take
place
some?me
a2er 2050.
2 The international community got together to meet the
problem head on
AntarcMca
1979
– First
year
of
available
images
showing
area
of
thinning
2006
– Lowest
ozone
level
ever
reached
CorrelaMon
between
levels
of
CFC12
and
ozone
over
AntarcMca
and
the
beginning
of
recovery
2 PERSONAL CHOICES THAT HELP