Sunteți pe pagina 1din 7

IEEE Transactions on Dielectrics and Electrical Insulation Vol. 24, No.

4; August 2017 2299

The Influence of Cu, Al and Fe Free Metal Particles


on the Insulating Performance of SF6
in C-GIS
Song Xiao1, Xiaoxing Zhang1, Ran Zhuo2, Dibo Wang2, Ju Tang1,
Shuangshuang Tian1 and Yi Li1
1
School of Electrical Engineering, Wuhan University, Wuhan 430072, China
2
Electric Power Research Institute, China Southern Power Grid, Guangzhou 510623, China

ABSTRACT
Studying the influence of free metal particles on breakdown voltage is important to
investigate the insulation performance of SF6 in electric equipment. Under 0.1 MPa
pressure and free metal particles defect, this study shows the influence of particle
number, gap distance and particle variety on SF6 breakdown voltage on AC power.
Experimental results indicate that the breakdown voltage of SF6 decreases as the
number of particles increases and eventually stabilizes; A shorter gap distance means a
greater effect of free metal particles on the SF6 insulation performance during
breakdown; Under the same conditions with copper or aluminum particles, the
breakdown voltage of SF6 is approximate and is simultaneously lower than that with
iron particles. The electric field force of copper and aluminum particles are close, and
larger than that of iron particles, leading to their take-off voltage close and below the
iron particles. Metal particles can reduce the reaction barrier of SF6, copper and
aluminum particles have similar effects on the reaction barrier of SF6, which are
obviously larger than that with iron particles. This study compares the breakdown
performance under different numbers of particles, gap distances and varieties of
particles. Result shows that copper or aluminum particles in C-GIS affect the insulation
performance of SF6 more obviously than that with iron particles.

Index Terms — C-GIS, free metal particles, breakdown, energy band theory,
density functional theory.

1 INTRODUCTION inevitably produce distinct materials and shapes of metal


particles. Metal particles will rise and drift if the electric field
CUBICLE type gas insulated switchgear (C-GIS) is a reaches a certain intensity. As the electric field continues to
new switchgear used in 10-110 kV power systems. C-GIS strengthen, the electric field distortion caused by free metal
contains devices such as circuit breakers, disconnectors, particles stimulates partial discharge and even a breakdown.
potential transformers and current transformers. The main Hence, free metal particles adversely affect the insulation of
functions of C-GIS are controlling, protecting, reckoning electrical equipment.
and monitoring power systems [1]. The pressure of SF6 in Many simulation and experimental studies on SF6 insulation
C-GIS is about 0.1 MPa. SF6 is colorless, tasteless, non- performance under metal particles are currently performed
toxic and has a stable physicochemical property. Meanwhile, worldwide. For instance, a computer software based on the
SF6 performs well in electric insulation and arc resistance[2]. Runge-Kutta method is used to calculate the trajectory of a
Thus SF6 has been widely used in distinct types of electric spherical metal particle between inclined plate electrodes filled
equipment including C-GIS. with SF6 [3]. Furthermore, partial discharge and breakdown
However, when manufacturers fail to clean C-GIS voltage of SF6 with metal particles in GIS triple junction are
thoroughly before the equipment leaves factories, metal obviously reduced compared with those without particles [4]. It
particles that were produced during manufacturing and is discovered that under the same pressure and particle number, a
assembling remain inside the equipment; In addition, during large particle size has increased effects on SF6 breakdown
the actual operation, the aging of internal insulation, the performance [5]. Todd Hattori has studied the relation between
vibration of circuit breakers and other factors will the length of aluminum wire in GIS and SF6 AC flashover
characteristics. Hattori has found that the length of aluminum
Manuscript received on 16 September 2016, in final form 25 March wire is negatively correlated to the flashover voltage, but is
2017, accepted 19 April 2017. Corresponding author: X. Zhang. positively correlated to the discharge capacity [6].

DOI: 10.1109/TDEI.2017.006343
2300 S. Xiao et al.: The Influence of Cu, Al and Fe Free Metal Particles on the Insulating Performance of SF6 in C-GIS

However, almost all these studies focus on SF6 insulation This study mainly investigates the SF6 breakdown
performance only under the defect of fixed particles from performance of power frequency under metal particles. The
the particle trajectory, particle size, SF6 gas pressure, and laboratory adopts ball-bowl electrodes to simulate a uniform
discharge capacity. Investigating the effect of the other electric field in C-GIS. Concurrently, the electrodes can
three factors, namely, particle number, gap distance and effectively prevent the particles from escaping [7]. The ball-
particle variety on SF6 breakdown voltage of power bowl electrodes used in this study are shown in Figure 3. The
frequency is necessary. The need for such a study is mainly bowl electrode is a stainless steel hemisphere with an external
due to three reasons: First, the distribution of particles in radius of 35 mm and an internal radius of 30 mm. The ball
the SF6 chamber of C-GIS is nonuniform; second, the gap electrode consists of a 30 mm pole and a solid ball with a
distances in the SF6 chamber vary; and third, metal particle radius of 25 or 20 mm for the gap distance to reach 5 or 10 mm,
materials may contain copper, aluminum and iron. respectively. The ball electrode is also made of stainless steel.
To simulate the particle defect in C-GIS, this study The spherical centers of the ball-bowl electrodes coincide to
places square foils between ball-bowl electrodes with a gap always maintain the distance between the electrodes and for the
distance of 5 or 10 mm. We used 2×2 mm2 square flakes electric field to be uniform in an ideal condition. Unfortunately,
with smooth surfaces to simulate real particles. We did not given the limitation of present mechanical technology,
choose smaller metal particles because they may jump out guaranteeing that the electrode surface is completely smooth
of the area between the sphere and bowl electrodes under and the electrode curvature is completely the same is difficult.
the influence of an electric field. We did not choose larger Hence, the actual electric field is approximately uniform.
metal particles because they may connect the electrodes in Because the working gas pressure of pure SF6 in C-GIS is
series. The flake thicknesses of these three types of metals around 0.1 MPa, the object of this experiment is SF6 gas in 0.1
were different to ensure that their weights were nearly the MPa, whose purity is perpetually more than 99. 9%.
same (≈9 mg). The influence of particle number, gap
distance and particle variety on the SF6 breakdown voltage
of power frequency is discussed in this study.
2.2 EXPERIMENTAL METHOD AND DATA
2 EXPERIMENTAL SECTION COLLECTION
2.1 EXPERIMENTAL CIRCUIT 1) The internal surfaces of the gas tank and electrodes are
cleaned by using a clean silk cloth with anhydrous alcohol. The
influence of solid particles, water, and other impurities, except
metal particles, on the power frequency breakdown should be
diminished. When the breakdown test is ensured in a clean and
dry environment, metal particles are placed into the electrode
gap. Finally, the tightness of the experimental device is
checked.
2) Tentative gas is piped into the tank to eliminate air. The
Figure 1. Experimental circuit. procedure is repeated twice to reduce the gas impurities and
moisture in the device. Subsequently, 0.1 MPa tentative gas is
The experimental circuit used in the study is shown in piped into the tank.
Figure 1. The gas breakdown of power frequency is tested 3) Extremely low power frequency voltage is applied to the
in the device shown in Figure 2. This device can be used for sample initially. The voltage rises gradually with 0.3 kV/s until
gas insulation experiments. The experimental device is a breakdown. The breakdown voltage value is recorded and
sealed container composed of stainless steel flanges and a calculated repetitively every 5 minutes. The final value is then
cylindrical organic glass tank. The defect model is placed in averaged by 5 records.
the tank full of tentative gas. The breakdown experiment on
power frequency is performed in the tank.
3 ANALYSIS OF EXPERIMENTAL RESULTS
The number of metal particles in the same material is set as 0,
1, 3, 5, 7, and 9 to investigate the influence of the particle
number on breakdown voltage. Copper, aluminum and iron
particles exist in C-GIS and these particles are rectangular,
hemispherical, and irregularly shaped [8]. Therefore, to reflect
the influence of particle materials on breakdown performance,
this study employs copper, aluminum and iron square foils to
simulate the defect of metal particles in C-GIS. The side length
of the foils is 2 mm because the maximum length of the
particles in GIS is 3 mm [9]. The gap distance is set as 5 mm or
10 mm to investigate the effect of gap distance on breakdown
Figure 2. Gas insulation experiment device. performance.
IEEE Transactions on Dielectrics and Electrical Insulation Vol. 24, No. 4; August 2017 2301

Ø15 Research by Masanori Hara has shown that metal particles can
significantly reduce the initial voltage of partial discharge
between a gap and promote the development of positive and
negative streamers [10]. The existence of free metal particles

30
generates a distorted electric field between ball-bowl electrodes.
Breakdown voltage decreases when the inhomogeneous degree
R 20 of electric field increases. In addition, more metal particles
means greater inhomogeneity of the electric field. Research by
Sarathi has also shown that random jitter of particles between
R 30 electrodes obviously decreases gas insulating property
R 35 accompanied with discharge [11]. During the experiment, we
also found that copper or aluminum particles in the ball-bowl
electrodes would jump when the applied voltage reaches certain
values called take-off voltages, which are all lower than that of
iron particles. Breakdown would appear immediately after the
random jitter of particles. In addition, the breakdown voltages of
copper or aluminum particles are also lower than that of iron
particles. The take-off voltage is positively correlated with
breakdown voltage.
Meanwhile, as the number of particles increases, the drop of
breakdown voltage flattens. As the number of particles exceeds
7, the breakdown voltage tends to stabilize gradually. This
occurrence is mainly caused by the free metal particles jittering
constantly and colliding with electrodes frequently when the
voltage reaches a certain value. Jitter and collision shortens the
effective insulation distance of gas. Once the particle number
Figure 3. Ball- bowl electrodes. reaches a certain value, a short circuit can easily form.
3.1 SF6 BREAKDOWN PERFORMANCE OF
POWER FREQUENCY UNDER DIFFERENT
PARTICLE NUMBERS 3.2 SF6 BREAKDOWN PERFORMANCE OF POWER
Figure 4 shows the breakdown voltage of SF6 with FREQUENCY UNDER DIFFERENT GAP DISTANCES
copper, aluminum or iron particles along with the rise of the To describe the decrease in gas insulation performance when
particle number when the gap distance is 10 mm and the metal particles exist in C-GIS, this study defines particle defect
pressure is 0.1 MPa. Based on Figure 4, all three kinds of
factor (PCF) as the ratio of breakdown voltage in the particle
free metal particles cause the breakdown voltage to decline
obviously. When the particle number rises from 0 to 9, the defect to the breakdown voltage in the clean gap [12].
breakdown voltage of SF6 under copper, aluminum and iron
particles decreases from 41 kV to 21, 22 and 26 kV,
5mm SF6 Cu
respectively.
45 5mm SF6 Al
45 5mm and10mm SF6
5mm SF6 Fe
10mm SF6 10mm SF6 Cu 40
10mm SF6 Cu
10mm SF6 Al 35
40 10mm SF6 Al
10mm SF6 Fe 10mm SF6 Fe
30
Voltage(kV)

Voltage (kV)

35 25
20
30 15
10
25
5
0
20 0 1 2 3 4 5 6 7 8 9 10
0 1 2 3 4 5 6 7 8 9 10 Number
Number
Figure 4. SF6 breakdown voltage under 10 mm distance. Figure 5. SF6 breakdown voltage under the distances of 10 and 5 mm.
2302 S. Xiao et al.: The Influence of Cu, Al and Fe Free Metal Particles on the Insulating Performance of SF6 in C-GIS
Table 2. SF6 PCF under the distance of 5 mm
5mm SF6 Cu
5mm SF6 Al Number 0 1 3 5 7 9
1.0 5mm and 10mm SF6 5mm SF6 Fe
10mm SF6 Cu Cu 1 0.42 0.27 0.17 0.15 0.15
10mm SF6 Al Al 1 0.42 0.25 0.15 0.14 0.13
0.8 10mm SF6 Fe
Fe 1 0.5 0.38 0.33 0.29 0.29

0.6
The steady PCF values of SF6 under copper, aluminum, and
PCF

iron particles when the gap distance is 10 mm are 0.51, 0.54 and
0.4 0.63, respectively. Meanwhile, the steady PCF values under 5
mm are 0.15, 0.13, and 0.25, respectively. Thus, copper and
0.2 aluminum particles have greater adverse effects on the
performance of SF6 insulation than iron particles in the same
conditions. The findings of Masanori Hara and other studies
0.0 reveal that metal particles can significantly reduce the onset
0 1 2 3 4 5 6 7 8 9 10
Number
corona and breakdown voltage of a gap. Unfortunately, the
influence of different particle materials on breakdown voltage
remains unknown. Hence, this study attempts to analyze this
Figure 6. PCF of SF6 breakdown under the distances of 10 and 5 mm.
phenomenon through metallic catalysis and electronegativity.
Subsequently, the breakdown performance of SF6 is
investigated when the gap distance is 5 mm and the pressure is 4 THEORETICAL ANALYSIS AND
0.1 MPa. A distinction in different gap distances can be easily SIMULATION
achieved after comparing the gap distance of 10 mm with 5
mm, shown in Figures 5 and 6. 4.1 THEORETICAL ANALYSIS OF THE INFLUENCES
Figures 5 and 6 show that the declining law of breakdown OF METAL PARTICLE TYPES ON THE TAKE-OFF
voltage under 5 mm is similar to that under 10 mm. VOLTAGE OF SF6
Concurrently, the steady PCF values of SF6 under copper, The beating of metal particles in the electrodes can seriously
aluminum, and iron particles are 0.15, 0.13, and 0.25, affect the uniform distribution of the original electric field, which
respectively, when the gap distance is 5 mm. By contrast, the makes the electric field distortion. Therefore, different types of
steady PCF values under 10 mm are 0.51, 0.54, and 0.63, particles take-off voltage difference appeared in the analysis
respectively, which are obviously higher than those under 5 experiment is of great significance for the study of SF6
mm. This phenomenon indicates that a shorter gap distance breakdown voltage differences.
generates a greater electric field distortion because of the free Under the condition of equal mass of each particle, copper and
metal particles. When the length of particles is close to the gap aluminum particles have similar take-off voltage and lower than
distance, particle size evidently influences the electric field that of iron particles. This indicates that under the same field
distribution. Moreover, under the same voltage, as the gap strength, the electric field force of iron particles is obviously
distance decreases, electric field strength increases. Hence, the smaller than that of copper and aluminum. According to F=Eq, it
take-off voltage of the particles under 5 mm is lower than that can be known that when the electric field is the same, the
under 10 mm. Existing studies have proven that the take-off difference of the electric field force is due to the different charge
voltage and gap distance of metal particles are positively q in the electric field, i.e., the induced charge q of the iron
correlated[9]. particles is less than that of the copper and aluminum particles.
Therefore, we studied the difference of induced charge from
3.3 SF6 BREAKDOWN PERFORMANCE OF
different types of metal particles through energy band theory and
POWER FREQUENCY UNDER VARIOUS METAL
the characteristics of electron distribution in different metal
PARTICLES
atoms.
This study adopts PCF to compare the breakdown
performance of SF6 with copper, aluminum and iron 1) In the absence of electric field, according to the fermi-dirac
particles when the gap distance is 5 and 10 mm, and the distribution in thermodynamic equilibrium state, as shown in the
pressure is 0.1 MPa, as shown in Tables 1 and 2. formula (1):
1
Table 1. SF6 PCF under the distance of 10 mm gE  (1)
 E  E f  / k BT
e 1
Number 0 1 3 5 7 9
where T is the temperature, kB is the Boltzmann constant, Ef is the
Cu 1 0.77 0.69 0.62 0.52 0.52 chemical potential. This function describes the probability g(E)
that the energy state of energy E is occupied by electrons under
Al 1 0.82 0.62 0.52 0.52 0.52
the condition of the thermal equilibrium. It is concluded that the
Fe 1 0.93 0.76 0.71 0.69 0.69 full band electrons will completely fill the states of the first
IEEE Transactions on Dielectrics and Electrical Insulation Vol. 24, No. 4; August 2017 2303

Brillouin zone (A', A) in the k space, as shown in Figure 7. nuclear electron is bounded greater by nucleus. The valence band
When there is an external electric field, all electrons will of iron atom is full band (4s2), although the 3d and 4s band also
move synchronously along the electric field in the opposite have some overlap, but 3d6 is unfilled band, inhibit the transition
direction, some electronic states removed from point A, of the outer electrons, making the electrical conductivity of the
equivalent to move into the first Brillouin zone from A', weakest. Therefore, three kinds of metal producing free electrons
thus the electronic distribution does not change, the total under the same electric field from easily to difficultly
crystal current is zero. respectively are: copper, aluminum, iron. Under the same electric
field, the more free electrons, the greater induced charge q.
Experiments show that the resistivity of copper, aluminum, iron
at 25 oC are respectively 1.7×10-8, 2.8×10-8, 10×10-8·m, this
also shows that the conductivity of copper is the best, the second
is the aluminum but the difference is not large and the
conductivity of iron is poor.
In summary, under the same electric field the induced charge q
of iron particles is less than that of copper and aluminum, and the
induced charge q of copper and aluminum is closer. Therefore,
Figure.7 The distribution of full band electrons in the k space. the electric field force F of copper and aluminum particles are
close, and larger than that of iron particles, leading to their take-
Figure 8a shows the situation when the un-filled band off voltage close and below the iron particles eventually. Electric
electrons are filled with no external electric field. The field distortion occurs in the case of particles beating frequently,
electrons begin to fill from the lowest energy level in the reducing the insulation level of SF6.
positive and negative k space, leading to the total current
zero. In the effect of external electric field, the electrons in 4.2 SIMULATION ANALYSIS OF THE INFLUENCES OF
the k space will move in opposite direction of electric field, METAL PARTICLE TYPES ON THE INSULATING
as shown in Figure 8b and the electron distribution will not PROPERTY OF SF6
be central symmetry. The carrying current from the Through computational method of quantum chemistry theory
electrons in positive or negative k space will not be all was adopted to investigate the influences of metal particle types
counteracted, the total current of energy band turns to be on the insulating property of SF6. The results of quantum
not zero. The energy band theory can be used to determine chemistry computation can provide much valuable information
the conductivity of the crystal by investigating the status of including molecular structure of reactant and product, structure
the electron filling energy bands situation. of intermediate and critical complex, the minimum energy path.
This study adopts the Dmol3 module, which is a part of the
Material Studios (MS) software, to calculate the reaction barrier
of SF6 under copper, aluminum and iron metal particles. The MS
software is developed by Accelrys Corporation. Dmol3 is a
quantum chemical module used to calculate density functional
theory (DFT). Dmol3 exploits the density function method on
atomic orbits to calculate molecular band structure. Calculus of
variations is then used to calculate wave function and energy.
(a) (b) Dmol3 can be used to predict structures and energy of molecules
Figure 8. The distribution of partially occupied band electrons in the k and atoms, search and optimize transition states of reactions, and
space.
reflect reaction paths by using graphs [13]. The S-F bond energy
when SF6 decomposes into SF5 and F is calculated by Dmol3, as
2) Electron filling consistent with Pauli Exclusion shown in Table 3
Principle and lowest energy principle. Extranuclear electron
configuration for copper is 1s22s22p63s23p63d104s1; for Table 3. Calculation of S-F bond energy.
aluminum, it is 1s22s22p63s23p1; for iron, it is
1s22s22p63s23p63d64s2. The electronic configuration may No. Equation S-F Bond Energy(kJ/mol)
reflect the metal valence electron number and status.
The principle of 1) and 2) used in the analysis of copper, (2) SF6 SF5 +F 315.7
aluminum, iron three metal shows: Since the outermost (3) 2SF6 +Cu 2SF5 +CuF2 247.4
layer of copper atoms only have one valence electron,
which valence band (4s band) is only half filled, so the (4) 3SF6 +Al 3SF5 +AlF3 235.3
outermost electron is very lively, similar to the alkali metal (5) 3SF6 +Fe 3SF5 +FeF3 289.1
has a strong electrical conductivity. The 3s2 of the
aluminum atom is full band, 3p1 is the un-filled band, and
If any impurity does not exist in pure SF6, the insulation of SF6
the two band can overlap with larger degree, resulting in a
former band electrons can be easily transferred to a latter has an excellent self-recovery ability, as shown in equation (1)
one. Therefore, aluminum showed a certain metallicity, but [14]. The S-F bond energy of SF6 is 315.7 kJ/mol based on
its conductivity was less than that of copper for its extra calculation, which is similar to 318.4 kJ/mol in literature [15].
2304 S. Xiao et al.: The Influence of Cu, Al and Fe Free Metal Particles on the Insulating Performance of SF6 in C-GIS

Belmadani has certified that metallic fluorides emerge where x and Q represent the electronegativity and total charges
during arc discharge of SF6 [16]. Dervos has observed the in the system, respectively. The Pauling electronegativity of SF6
generation of CuF2 and AlF3 on the surface of copper and molecules is 6.63 based on the equations, whereas the Pauling
electronegativity of SF5 is only 2.91. True used gas phase X-ray
aluminum particles in GIS by using an electron microscope
spectrometry to calculate the electronegativity of SF5 as 2.88
[17]. Belmadani has also presented the corresponding [19]. Kimura used the Langmuir probe technology to calculate
reaction equations. Therefore, in accordance with the that the electronegativity of SF6 is between 5 and 10 [20]. The
reaction equations in the literature [16, 17], the present results of the present study are similar to the results obtained by
study calculates the S-F bond energy under copper, these previous studies. Consequently, SF6 decomposition is a
aluminum and iron particles when SF6 decomposes into SF5 decline of electronegativity, which reduces the ability to adsorb
and F. The reaction process is shown in Figure 9, and the electrons. The decline of electronegativity increases electron
density in SF6 and development rate of streamers, but throughout
results are shown in equations (3)-(5).
time decreases. Finally, the breakdown voltage declines [21].
Simulation has verified that metal particles also reduce the
decomposition reaction barrier of SF6. Furthermore, copper and
aluminum particles have similar effects on reaction barrier,
which are obviously larger than that with iron particles. Finally,
SF6 molecules near metal particles decompose under a lower
voltage, which benefits the formation of streamers. Cooke has
demonstrated that breakdown voltages under copper and
aluminum particles in 0.1 MPa SF6 are similar [22].
(a) Before the reaction (b) After the reaction
Figure 9. SF6 reacts with a copper atom.
5 CONCLUSIONS
The result shows that the S-F bond energy for SF6 under
metal particles is obviously lower than the bond energy Free metal particles can influence the insulating ability of SF6
without particles. In addition, the effects of copper and in C-GIS seriously. With the number of particles increases, the
aluminum particles on S-F bond energy are similar and breakdown voltage of SF6 decreases from rapidly to slowly.
greater than those with iron particles. Consequently, SF6 Free metal particles have obvious effects on the insulating
molecules with excellent electronegativity decompose into ability of SF6 in short gap. When the length of particles is close
SF5 and F under the effect of lower electric field intensity. F to the gap distance, particle size can evidently influence the
atoms then combine with metal atoms to produce metallic electric field distribution.
fluorides, which makes the reaction balance move towards With the same number of particles, the weakening effects to
SF6 decomposition. Hence, the number of SF6 molecules the breakdown voltage of SF6 from copper particles and
with excellent insulation performance adjacent to metal aluminum particles are similar and more obvious than the effect
particles is reduced. from iron particles.
Based on the analysis of reaction barrier, this study Under the same electric field, the induced charge of iron
compares the electronegativity change of SF6 before and particles is less than those of copper and aluminum particles, and
after decomposition under the defect of free metal particles. the induced charges of copper and aluminum are closer.
The Pauling electronegativity of SF6 and the SF6 Therefore, the electric field force F of copper and aluminum
decomposition SF5 are calculated according to DFT and particles are close, and larger than that of iron particles, leading
electronegativity equalization principle. to their take-off voltages close and lower than that of iron
According to the precise expression of molecular particles.
electronegativity via DFT [18], the following is obtained: Free metal particles promotes the decomposition of SF6, which
xa =Aa +2Ba qa +k ∑b≠a qb /Rab (6) weakens the electronegativity of SF6. Copper and aluminum
where subscripts a and b represent the atoms; particles have more influences than iron particles on the reaction
represents the effective electronegativity of atom a in a barrier of SF6.
molecule; is the charge of atom a; is the distance In summary, according to the study of theory and experiment,
between atoms a and b; and represent the influence of copper and aluminum particles on the insulating
electronegativity and hardness scale of atom a in a capacity of SF6 is greater than that of iron particles.
molecule, respectively; and k is a coordination factor.
The electronegativity equilibrium equation is then
expressed as
xa =xb =…=x (7)
6 ACKNOWLEDGMENT
According to conversation of charge, the atomic charges The current work is supported by the Key Project of National
in molecules or free radicals are the total charge of this Natural Science Foundation of China (Grant No. 51537009) and
system, and the constraint of charges is Project supported by Key Technology R&D Innovation Program
∑a qa =Q (8) of Hubei Province (Grant No. 2014AAA015).
IEEE Transactions on Dielectrics and Electrical Insulation Vol. 24, No. 4; August 2017 2305

REFERENCES [15] E. Duffour, “Molecular Dynamic Simulations of the Collision Between


Copper Ions, SF6 Molecules and a Polyethylene Surface: A Study of
[1] T. Shioiri, M. Honma, M. Miyagawa, E. Kaneko, I. Ohshima Decomposition Products and an Evaluation of the Self-Diffusion
“Insulation Characteristics of Vacuum Interrupter for a New 72/84 kV Coefficients”, Macromol. Theory Simul, Vol. 19, pp. 88-99, 2009.
C-GIS”, IEEE Trans. Dielectr. Electr. Insul, Vol. 6, No. 4, pp. 486- [16] B. Belmadani, J. Casanovas and A.M Casanovas, “SF6 Decomposition under
490, 1999. Power Arcs Physical Aspects”, IEEE Trans. Electr. Insul, Vol. 26, No. 6, pp.
[2] M. Yul, L. Zhenyu and T. Takuya, “Detection of SF6 decomposition 1163-1176, 1991.
products generated by DC corona discharge using a carbon nanotube [17] C. T Dervos, P. Vassiliou and J. A Mergos, “Thermal Stability of SF6
gas sensor”, IEEE Trans. Dielectr. Electr. Insul, Vol. 19, No. 2, pp. Associated with Metallic Conductors Incorporated in Gas Insulated
671-676, 2012. Switchgear Power Substations”, J. Appl. Phys, Vol. 40, No. 22, pp. 6942-
[3] I.A Metwally and A.A A-Rahim, “Dynamic Analysis of Motion of 6952, 2007.
Spherical Metallic Particles in Non-Uniform Electric Field”, IEEE [18] Z. Yang and C. Wang, “Atom-Bond Electronegativity Equalization Method
Trans. Dielectr. Electr. Insul, Vol. 9, No.2, pp. 282-293, 2002. and Its Applications Based on Density Functional Theory”, J. Chem. Theory,
[4] L. Caliap, O. Lesaint and A. Denat, “Influence of a Metallic Particle Vol. 2, No. 2, pp. 273-299, 2003.
at a Metal/Insulator/Gas Triple Junction in Air and SF6”, IEEE Conf. [19] J. E True, T. D Thomas and R. W Winter, “Electronegativities from Core-
Electr. Insul. Dielectr. Phenomena, Virginia, USA, pp. 364-367, 2009. Ionization Energies: Electronegativities of SF5 and CF3”, Inorg. Chem, Vol.
[5] M.S Indira and T.S Ramu, “Theoretical and Experimental Model for 42, No. 14, pp. 4437−4441, 2003.
Particle Initiated Breakdowns in GIS”, IEEE Int’l. Conf. Electr. Insul., [20] T. Kimura and K. Ohe, “Investigation of Electronegativity in a Radio-
Virginia, USA, Vol. 2, pp. 697-700, 1998. Frequency Xe/SF6 Inductively Coupled Plasma Using a Langmuir Probe”,
[6] T. Hattori, M. Honda and H. Aoyagi, “A Study on Effects of Appl. Phys. Lett, Vol. 79, No. 18, pp. 2874-2876, 2001.
Conducting Particles in SF6 Gas and Test Methods for GIS”, IEEE [21] A. Luque and U. Ebert, “Electron Density Fluctuations Accelerate the
Trans. Power Deliv, Vol. 3, No. 1, pp. 197-204, 1988. Branching of Positive Streamer Discharges in Air”, Phys. Rev. E, Vol. 84,
[7] X. Ren, “Research on the Correlation Characteristics between Partial No. 4, pp. 2149-2157, 2011.
Discharge Quantity and SF6 Decomposition Components Under [22] C. M. Cooke, R. E Wootton and A. H Cookson, “Influence of Particles on
Different Insulation Defects”, M.Sc. Chongqing University, AC and DC Electrical Performance of Gas Insulated Systems at Extra-High-
Chongqing, China, 2012 (in Chinese). Voltage”, IEEE Trans. Power App. Syst., Vol. 96, No. 3, pp. 768-777, 1977.
[8] N. Kanako, O. Takashi and K. Hiroki, “Particle Size Identification in
GIS by Ultra High Speed Measurement of Partial Discharge”, IEEE Song Xiao was born in Zhangjiakou City, Hebei
Int’l. Conf. Condition Monitoring and Diagnosis, Beijing, China, pp. Province, China, in 1988. He received the B.S. degree in
443-447, 2008 electrical engineering from Chongqing University,
[9] A. P Purnomoadi, M. Al-Suhaily and S. Meijer, “The Influence of Chongqing, China. He received the Ph.D. degree in
Free Moving Particles on the Breakdown Voltage of GIS under electrical engineering at Chongqing University,
Different Electrical Stresses”, IEEE Int’l. Conf. Condition Monitoring Chongqing, China and the Ph.D. degree in plasma
and Diagnosis, Bali, Indonesia, pp. 383-386, 2012. engineering at Universit´e de Toulouse, Toulouse,
[10] M. Hara, Y. Negara and M. Setoguchi, “Particle-Triggered Pre- France. Dr. Xiao is a postdoctoral researcher in School
Breakdown Phenomena in Atmospheric Air Gap Under AC Voltage”, of Electric Engineering, Wuhan University. His research
IEEE Trans. Dielectr. Electr. Insul, Vol. 12, No. 5, pp. 1071-1081, interests include partial discharge online monitoring and
2005. gas substituting SF6.
[11] R. Sarathi and R. Umamaheswari, “Understanding the Partial
Discharge Activity Generated Due to Particle Movement in a
Composite Insulation Under AC Voltages”, Int’l. J. Electr. Power, Xiaoxing Zhang was born in Qianjiang City, Hubei
Vol. 48, pp. 1-9, 2013. Province, China, in 1972. He received the Bachelor and
[12] S. A. Ward, “Optimum SF6-N2, SF6-Air, SF6-CO2 Mixtures Based on Master degrees from Hubei Institute of Technology, and
Particle Contamination”, The Int’l. Sympos. Electr. Insul., Anaheim, Doctor degree from Chongqing University. Dr. Zhang is
USA, pp. 292-295, 2000. a professor of School of Electric Engineering, Wuhan
[13] B. Delley, “From molecules to solids with the DMol3 approach”, J. University. He is involved in the online monitoring and
Chem. Phys, Vol.113, No.18, pp. 7756-7764, 2000. fault diagnosis of high voltage electrical insulation
[14] J Tang, F. P Zeng and X Liang, “A Comparative Experimental Study equipment, the decomposition mechanism of insulating
on the Interaction of SF6 Feature Decomposition”, Proc. Chinese Soc. gas SF6 and the new nano-sensor.
Electr. Eng. (CSEE), Vol. 33, No. 31, pp. 211-219, 2013.

S-ar putea să vă placă și