JP XII Organic Chemistry (11) - 1

ORGANIC CHEMISTRY
TARGET : JEE (Main + Advanced) 2016

Course : VIJETA ( JP & JP Star) Date : 08-06-2015 NO. 15
TEST IN FORMATI ON
DATE : 28.06.2015 PART TEST (PT) - 2 (ADVANCED)
Syllabus : Organic Reaction Mechanisms-I & Organic Reaction Mechanisms-II and Reduction,
Oxidation & Hydrolysis, Cheminfo (Till date)
This DPP is to be discussed in the week (08-06-2015 to 13-06-2015)

DPP No. # 15 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]
1. What is incorrect about ?
(A) it has six carbon atoms (B*) it's molecular formula is C6H12
(C) it's empirical formula is CH (D) it has six sp 2 hybridised carbon atoms
ds fy, vlR; D;k gS \
(A) ;g N% dkcZu ijek.kq j[krk gSA (B*) bldk v.kqlw=k C6H12 gSA
(C) bldk ewykuqikrh lw=k CH gSA (D) ;g N% sp 2 ladfjr dkcZu ijek.kq j[krk gSA
2. Which type of isomerism is not possible in C4H8 ?

(A) Chain (B*) Metamerism (C) Position (D) Geometrical
v.kqlw=k C4H8 dkSulh leko;ork iznf'kZr ugha djsxk \
(A) Jà[kyk (B*) e/;ko;ork (C) fLFkrh (D) T;kferh
3. When Acetaldehyde is heated with Fehling solution, a red precipitate is formed Red Precipitate is due to ?
tc ,lhVsfYMgkbM dks Qsgfyax foy;u ds lkFk xeZ djrs gS rc yky vo{ksi curk gSA yky vo{ksi fuEu ds dkj.k curk
gS \
(A*) Cu2O (B) Cu (C) CuO (D) CuSO4
4. Which order of I effect is incorrect. (fuEu esa ls I izHkko dk vlR; Øe gS %)

 
(I) – N(CH3 )3 > – S(CH3 )2 [–I] (II) –OCH3 > –OH [–I]

(III) –F > –Cl [–I] (IV) –CH3 > – O [+I]
(A) II, III & IV (B) III & IV (C*) IV only (D) all
(A) II, III rFkk IV (B) III rFkk IV (C*) dsoy IV (D) lHkh
Sol. Self explanatory. (Lor% le>us ;ksX;)
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5. The correct decreasing order of electron density in aromatic ring of following compounds is :
fuEufyf[kr ;kSfxdkas esa ,sjkseSfVd oy; ij bysDVªkWu ?kuRo dk lgh ?kVrk gqvk Øe gksxk %
(I) (II) (III) (IV)
(A) (II) > (III) > (IV) > (I) (B*) (III) > (II) > (IV) > (I)
(C) (IV) > (I) > (III) > (II) (D) (III) > (II) > (I) > (IV)
Sol. + m group increases electron density and – m group decreases electron density in aromatic ring.
,sjkseSfVd oy; esa + m lewg bysDVªkWu ?kuRo c<+k nsrk gS rFkk – m lewg bysDVªkWu ?kuRo esa deh dj nsrk gSA
6. Hyperconjugation is not present in :

fuEu esa ls fdlesa vfrla;qXeu lEHko ugha gS %
(A) (B) (C*) (D)
Sol. C has no sp3 carbon and H for hyperconjugation.

fodYi C esa] ;kSfxd esa vfrla;qXeu ds fy, H rFkk sp3 dkcZu mifLFkr ugha gSA
7. Which of the following carbocation is most unstable :

fuEu esa ls dkSulk dkcZ/kuk;u lokZf/kd vLFkk;h gS \
(A) (B*) (C) (D)
8. Which fo the following has highest pKa ?

fuEu esa ls fdl ;kSfxd dk pKa eku vf/kdre gS \
(A) (B) (C*) (D)
9. Which is Aspirin ?
fuEu esa ,Lizhu gS \
(A) (B*) (C) (D)
10. An unknown compound A has a molecular formula C 4H6. When A is treated with an excess of Br 2 a new
substance B with formula C4H6Br4 is formed. A forms a white precipitate with ammoniacal silver nitrate
solution. A may be
(A*) But-1-yne (B) But-2-yne (C) But-1-ene (D) But-2-ene
,d vKkr ;kSfxd dk v.kqlw=k C4H6 gSA tc A dks Br2 ds vkf/kD; ds lkFk mipkfjr djrs gS] rks v.kqlw=k C4H6Br4 dk ,d
u;k inkFkZ B curk gSA A veksfu;ke; flYoj ukbVªsV foy;u lkFk 'osr vo{ksi cukrk gSA A gks ldrk gS &
(A) C;wV-1-vkbu (B) C;wV-2-vkbu (C) C;wV-1-bu (D) C;wV-2-bu
PAGE NO.- 2
11. Choose the correct reaction to obtain the given product ¼fn;s x;s izkIr mRikn ds ckjs esa lgh vfHkfØ;k dks pqfu;sA½
Reactant (vfHkdkjd) 
(A*) D / Pd (B) D / Pt
2  2 
(C) D / Ni (D) D / Ni
2  2 
Sol. D / Pd
2 
12. The product of following reaction is
Product
fuEu vfHkfØ;k esa mRikn D;k gksxk %
mRikn
(A) (B*) (C) (D)
Sol.
PAGE NO.- 3
x y
13. Ph—CC—Ph  
The reagents x and y are respectively :

(A) Br2 / CCl4 , H2 / Ni (B) HBr , HBr
(C*) Na / NH3 () , Br2 / CCl4 (D) Br2 / CCl4 , Lindlar's hydrogenation
x y
Ph—CC—Ph  
vfHkdeZd x vkSj y Øe'k% gksaxs %

(A) Br2 / CCl4 , H2 / Ni (B) HBr , HBr
(C*) Na / NH3 () , Br2 / CCl4 (D) Br2 / CCl4 , fy.Mykj gkbMªkstuhdj.k
X Br
Sol. Ph – C  C – Ph  2

Na(NH3 (  )) CCl4
14. product is :
mRikn gS &
(A) (B*) CH3–CH2–OH, Ph–CH2–OH

(C) CH3–CH2–CH2–Ph (D)
 LiAlH4
15. H2N–(CH2)4–COOH    ?
(A*) (B) (C) (D)

Sol. H2N CH2)4 – COOH  LiAlH
  4

PAGE NO.- 4
16. The products A and B in the reactions given below are :
(A) A & B are (B) A & B are
(C*) A is & B is (D) A is & B is
fuEu vfHkfØ;k esa mRikn A rFkk B gS %
(A) A rFkk B gS (B) A rFkk B gS
(C*) A ,oa B gS (D) A ,oa B gS
PAGE NO.- 5
17. Product of given reaction is :
H / Pd(CaCO ) Quinoline
2   3  

mijksDr vfHkfØ;k dk mRikn gSA

H / Pd ( CaCO , )
2   3  

(A) CH3–CH2 –CH2–OH (B*)
(C) (D) CH3CH2COOH
H / Ni PHI
18. A 2
   B ,
A and B can be :
(A) Both are n-Butane (B) Both are Butane-1,2,3,4 -tetraol
(C) A is n-Butane & B is Butane-1,2,3,4 -tetraol (D*) A is Butane-1,2,3,4 -tetraol & B is n-Butane
H / Ni PHI
A 2
   B ,
A rFkk B gks ldrs gSa %

(A) nksuksa n- C;wVsu gSA (B) nksuksa C;wVsu-1,2,3,4 -VsVªkvkWy gSA
(C) A n-C;wVsu rFkk B C;wVsu-1,2,3,4-VsVªkvkWy gSA (D*) A C;wVsu-1,2,3,4-VsVªkvkWy rFkk B n-C;wVsu gSA
19. Which reducing agent, would you use to carry out the following transformation.
fuEu :ikUrj.k ds fy, vki dkSulk vipk;d dke esa ysxsa \

(A) LiAlH4 (B*) NaBH4 (C) Na/NH3 (D) B2H6/THF
LiAlH4
20.   product is mRikn gS &
(A) (B) (C*) (D)
PAGE NO.- 6

JP XII Organic Chemistry (11) - 1

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ORGANIC CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

DATE : 28.06.2015 PART TEST (PT) - 2 (ADVANCED)

This DPP is to be discussed in the week (08-06-2015 to 13-06-2015)

1. What is incorrect about ?

ds fy, vlR; D;k gS \

2. Which type of isomerism is not possible in C4H8 ?

4. Which order of I effect is incorrect. (fuEu esa ls I izHkko dk vlR; Øe gS %)

(I) (II) (III) (IV)

6. Hyperconjugation is not present in :

(A) (B) (C*) (D)

Sol. C has no sp3 carbon and H for hyperconjugation.

7. Which of the following carbocation is most unstable :

(A) (B*) (C) (D)

8. Which fo the following has highest pKa ?

(A) (B) (C*) (D)

(A) (B*) (C) (D)

Reactant (vfHkdkjd) 

12. The product of following reaction is

fuEu vfHkfØ;k esa mRikn D;k gksxk %

(A) (B*) (C) (D)

The reagents x and y are respectively :

vfHkdeZd x vkSj y Øe'k% gksaxs %

(A) (B*) CH3–CH2–OH, Ph–CH2–OH

(A*) (B) (C) (D)

(A) A & B are (B) A & B are

(C*) A is & B is (D) A is & B is

fuEu vfHkfØ;k esa mRikn A rFkk B gS %

(A) A rFkk B gS (B) A rFkk B gS

(C*) A ,oa B gS (D) A ,oa B gS

mijksDr vfHkfØ;k dk mRikn gSA

(A) CH3–CH2 –CH2–OH (B*)

(C) (D) CH3CH2COOH

A rFkk B gks ldrs gSa %

(A) LiAlH4 (B*) NaBH4 (C) Na/NH3 (D) B2H6/THF

(A) (B) (C*) (D)

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