11 05 2016perlwitz PDF

Air Liquide Global E&C Solutions
Air Liquide’s Engineering & Construction Activity
Mai 2016 | Air Liquide Global E&C Solutions

Customers across the entire energy value chain
2 Air Liquide E&C - CONFIDENTIAL Air Liquide, world leader in gases, technologies and services for Industry and Health
Product Lines
Driving Air Liquide Global E&C Solutions’ technology portfolio

through Product Lines strategies across all Regions
Downstream &
Standard Plants Petrochemicals
Cryogenics Hydrocarbons
Hydrogen Oleochemicals
Downstream & Petrochemicals Product Line
Downstream & Petrochemicals
Providing best in class and

fully referenced technologies
for gas and coal monetization
comprising syngas generation
and conditioning, production of
methanol and its derivatives
up to selected petrochemicals.
Petrochemicals
 Low Pressure (LP) Methanol
 Lurgi Megamethanol™
 Lurgi MTP™ - Methanol-to-

Propylene
 Butadiene Extraction
 Acrylic Acid
 Acrylates
 Distapex™
A wealth of experience and know-how in  G2G™ - Gas-to-Gasoline
petrochemical processes spanning more than
60 years.
Air Liquide MegaMethanol® Market Position
Source: PML
Methanol – Market
Methanol Production Technologies
LP Synthesis MegaMethanol GigaMethanol
1-Stage Synthesis 2-Stage Synthesis
SMR Combined Reforming ATR
0 2,500 5,000 7,500 10,000

Capacity (mtpd)
Combined Reforming for 5000 MTPD Methanol (MegaMethanol™)
Lurgi Reformer™ (SMR) Combined Reforming
Autothermal Reformer (ATR)
Methanol Synthesis in reality
Gas Cooled
Reactor
Water Cooled
Reactor
Air Liquid Methanol - Our Track Record
■ Methanol Licenses Track Record

 55+ Plants licensed since 1969 (40 mtpy)
■ Multiple new MegaMethanol™ units in the last 18 months
■ 17 Oxygen reforming plants (20 mtpy)
■ 14 MegaMethanol plants (24 mtpy)
■ 21 Plants licensed since 2001 (29 mtpy)
6%
Natural Gas
(33 plants)
31% Coal
(11 plants)
63% Others
(11 plants)
Based on installed capacity
Overall licensor market share
■ Number of operating plants
■ Total Methanol capacity
Air Liquide‘s Lurgi Technology is

the leader in methanol
Source: Nexant, 2012
Air Liquide MegaMethanol® – Proven in Operation
Air Separation Unit Plant Core Process Units
Natural Gas Methanol
Electricity Flue Gases

Backup only
Waste Water
Sea Water
Sea Water
Natural Gas Requirements Plot Requirements Production

HHV 32 MMBTU/t MeOH = 300 m x 400 m 5 000 MTPD Methanol Grade AA
160 MMSCFD
40 acres
Selected Reference - MegaMethanol® Plant, Malaysia
 Client: Petronas Methanol (Labuan) SDN BHD
 Process: MegaMethanol®
 Licensor: Air Liquide
 Plant Capacity: 5,000 t/d
 Feedstock: Natural Gas
 Scope of Work: EPC
 Start-Up Year: Dec. 2008
 Project Highlights: Second Methanol Plant for PML and Largest in Asia.
Further Methanol Processing: MTX
MeOH to Propylene ® Acrylic Acid
DME Fuels
Natural Gas Ethylene,

Air Liquide MeOH to Olefins Propylene
Coal Syngas MegaMethanol® (Poly-Olefines)
Process
Residue Benzene,
MeOH to Aromatics Xylenes
ASU MeOH to Gasoline Fuels
MeOH to Glycol Ethylene Glycol
Methanol-to-Propylene / Gas-to-Propylene
Poly-
Propylene MTP® Mega
Methanol
ASU
DME Coal
Gasification
Sulfur
Recovery Rectisol
MTP® Overview - Flowsheet
MegaMethanol® Fuel Gas

5,000 t/d Internal use (Optional)
Ethylene
60 t/d
DME Propylene
Pre- 1,410 t/d 1)
Reactor
Product
Conditioning MTP-LPG
109 t/d
MTP-Gasoline
MTP Reactors 540 t/d
(2 Operating + 1 Regenerating)
Product
Olefin Recycle Fractionation
Water Recycle
Process Water 2,800 t/d
Internal Use (+)
1) Propylene Purity 99.6 wt. %
Integrated Plant Configuration (GTP)
Reforming Methanol Methanol Vapour DME and

Distillation MTP
Reaction
Methanol Liquid
Methanol Grade AA Purification
Synthesis
Lurgi MegaMethanol® Plant MTP® Plant
Steam and Condensate System

Utilities
MTP/GTP® References
4 Licenses awarded
3 MTP Plants under commercial operation (470, 000 tpy)

- Datang Power Corporation (DTP: Duolon) – start-up 2011
- Shenhua Ningxia Coal Industry Group (SNCG: Ningdong) – start-up 2010
- Shenhua Ningxia Coal Industry Group (SNCG: Ningdong) – start-up 2014
1 GTP Plant in the U.S. (BASF) under engineering (470, 000 tpy)
Gas to Propylene: BASF presentations
BASF
press
release:
BASF
Investor Day
presentation:
Hydrogen Product Line
Hydrogen
Offering hydrogen to the
refining and chemicals
markets with our
competitive range of
small and large Steam
Methane Reformers.
Hydrogen
 Steam Methane Reformer (including

small scale) - Hydrogen Production
 SMR-X™ - Zero Steam Hydrogen

Production
 Pressure Swing Adsorption (PSA) -

Hydrogen Purification
 ATR
Offering hydrogen to the refining and

chemicals markets with a competitive range of
small and large Steam Methane Reformers.
Hydrocarbons Product Line
Hydrocarbons
Offering a full portfolio of

natural gas treatment
technologies from well to
clean product including
Liquefied Natural Gas
(small-, mid- to large scale)
as well as re-gasification
technologies.
Liquefied Natural Gas (LNG)
 Small-scale LNG (Nitrogen

Refrigeration Cycle)
 Mid- to Large- scale LNG

(Mixed Refrigerant Cycle)
 Boil-Off Gas Reliquefaction
100 years of cryogenic experience available for

LNG with small- to large- scale plants, and
equipment to serve applications ranging from
peak shaving, LNG as a fuel, to base load LNG
for export markets.
Natural Gas Treatment
 Nitrogen Rejection Unit

 Natural Gas Liquids Recovery
 Acid Gas Removal
 Combined Membranes
 Amine washes
 Omnisulf™ - Acid Gas enrichment
and removal
 Cryocap™
Offering a full portfolio of natural gas treatment

technologies from well to clean product as well
as re-gasification technologies.
Sulfur
 OxyClaus™ Sulfur Recovery Unit
 Sulfur Recovery Unit
 Lurgi Tail Gas Treatment (LTGT™)

 Sub-dewpoint tail gas technologies
(Sulfreen™)
 Sulfur degassing (Aquisulf™)
 Claus - Emission-free Sulfur Recovery

Unit
Sulfur Management technologies that are

helping customers to meet increasingly
stringent environmental targets.
Standard Plants Product Line
Standard Plants
Fully packaged cost efficient

plants mastering cryogenic
and adsorption technologies
for oxygen and nitrogen
production from 40 to 800
tons per day.
Standard Plants
 Yango™ - Standard Air Separation Unit
 Sigma - Standard Air Separation Unit
 Vacuum Swing Adsorption On-Demand

Oxygen Generator
 Nitrogen Generation System
 HYOS™ R - Hydrogen Generation
System
Fully packaged cost efficient plants mastering

cryogenic and adsorption technologies for
oxygen and nitrogen production from 40 to 800
tons per day.
Cryogenics Product Line
Cryogenics
Providing state-of-the-
art Air Separation Units
and Cryogenics
technologies that yield
the lowest possible Total
Cost of Ownership.
Cryogenics
 Large Air Separation Unit
 CO Cold Box - Syngas Separation and

Purification
 Liquid Nitrogen Wash
 Hydrogen, Nitrogen and Argon Recovery
 Cryocap™ H2 - Cryogenic CO2 Separation
 Cryocap™ Oxy - Cryogenic CO2 Separation

for Oxycombustion
State-of-the-art Air Separation Units and  Helium Extraction and Liquefaction

Cryogenics technologies that yield the lowest
possible Total Cost of Ownership.
Oleochemicals Product Line
Oleochemicals
Providing oil seed extraction
and refining, fatty acids, fatty
alcohols, glycerin, sorbitol
and methyl esters alongside
biodiesel technologies.
Biodiesel & Oleochemicals
 Sliding Cell Extractor - Seed Crushing and
Extraction
 Natural Oil Refining
 Lurgi Biodiesel
 Methyl Ester Distillation/Fractionation
 Fatty Acid
 Production (Oil Splitting)

 Distillation/Fractionation
 Hydrogenation
 Glycerin Distillation and Bleaching
Proven Lurgi technologies to ensure  Fatty Alcohol
smooth, reliable operations, superior
 Wax Ester and Methyl Ester Route
product quality and maximum efficiency.
 LP3 - Low Pressure Fatty Alcohol Production
 Bio Propylene Glycol
 Sorbitol Production
End of presentation
Thank you for your attention

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Air Liquide Global E&C Solutions

Air Liquide’s Engineering & Construction Activity

Mai 2016 | Air Liquide Global E&C Solutions

Driving Air Liquide Global E&C Solutions’ technology portfolio

Downstream & Petrochemicals

Providing best in class and

 Low Pressure (LP) Methanol

 Lurgi MTP™ - Methanol-to-

LP Synthesis MegaMethanol GigaMethanol

1-Stage Synthesis 2-Stage Synthesis

SMR Combined Reforming ATR

0 2,500 5,000 7,500 10,000

Autothermal Reformer (ATR)

■ Methanol Licenses Track Record

Based on installed capacity

■ Number of operating plants

■ Total Methanol capacity

Air Liquide‘s Lurgi Technology is

Natural Gas Methanol

Electricity Flue Gases

Natural Gas Requirements Plot Requirements Production

MeOH to Propylene ® Acrylic Acid

Natural Gas Ethylene,

ASU MeOH to Gasoline Fuels

MeOH to Glycol Ethylene Glycol

MegaMethanol® Fuel Gas

1) Propylene Purity 99.6 wt. %

Reforming Methanol Methanol Vapour DME and

Lurgi MegaMethanol® Plant MTP® Plant

Steam and Condensate System

3 MTP Plants under commercial operation (470, 000 tpy)

 Steam Methane Reformer (including

 SMR-X™ - Zero Steam Hydrogen

 Pressure Swing Adsorption (PSA) -

Offering hydrogen to the refining and

Offering a full portfolio of

 Small-scale LNG (Nitrogen

 Mid- to Large- scale LNG

 Boil-Off Gas Reliquefaction

100 years of cryogenic experience available for

 Nitrogen Rejection Unit

Offering a full portfolio of natural gas treatment

 OxyClaus™ Sulfur Recovery Unit

 Sulfur Recovery Unit

 Lurgi Tail Gas Treatment (LTGT™)

 Claus - Emission-free Sulfur Recovery

Sulfur Management technologies that are

Fully packaged cost efficient

 Yango™ - Standard Air Separation Unit

 Sigma - Standard Air Separation Unit

 Vacuum Swing Adsorption On-Demand

Fully packaged cost efficient plants mastering

 Large Air Separation Unit

 CO Cold Box - Syngas Separation and

 Liquid Nitrogen Wash

 Hydrogen, Nitrogen and Argon Recovery

 Cryocap™ H2 - Cryogenic CO2 Separation

 Cryocap™ Oxy - Cryogenic CO2 Separation

State-of-the-art Air Separation Units and  Helium Extraction and Liquefaction

 Natural Oil Refining

 Methyl Ester Distillation/Fractionation

 Production (Oil Splitting)

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