Documente Academic
Documente Profesional
Documente Cultură
Department of Justice RT
ME
NT OF J
US
PA
TI
CE
DE
Office of Justice Programs
BJ A C E
G OVC
MS
OF F
RA
IJ
National Institute of Justice
N
I
S
J
O F OJJ D P B RO
J US T I C E P
The Law Enforcement and Corrections Standards and Testing Program is sponsored by the Office of Science and
Technology of the National Institute of Justice (NIJ), U.S. Department of Justice. The program responds to the mandate
of the Justice System Improvement Act of 1979, which created NIJ and directed it to encourage research and
development to improve the criminal justice system and to disseminate the results to Federal, State, and local agencies.
The Law Enforcement and Corrections Standards and Testing Program is an applied research effort that
determines the technological needs of justice system agencies, sets minimum performance standards for specific devices,
tests commercially available equipment against those standards, and disseminates the standards and the test results to
criminal justice agencies nationally and internationally.
The program operates through:
The Law Enforcement and Corrections Technology Advisory Council (LECTAC) consisting of nationally
recognized criminal justice practitioners from Federal, State, and local agencies, which assesses technological needs
and sets priorities for research programs and items to be evaluated and tested.
The Office of Law Enforcement Standards (OLES) at the National Institute of Standards and Technology, which
develops voluntary national performance standards for compliance testing to ensure that individual items of equipment
are suitable for use by criminal justice agencies. The standards are based upon laboratory testing and evaluation of
representative samples of each item of equipment to determine the key attributes, develop test methods, and establish
minimum performance requirements for each essential attribute. In addition to the highly technical standards, OLES
also produces technical reports and user guidelines that explain in nontechnical terms the capabilities of available
equipment.
The National Law Enforcement and Corrections Technology Center (NLECTC), operated by a grantee, which
supervises a national compliance testing program conducted by independent laboratories. The standards developed by
OLES serve as performance benchmarks against which commercial equipment is measured. The facilities, personnel,
and testing capabilities of the independent laboratories are evaluated by OLES prior to testing each item of equipment,
and OLES helps the NLECTC staff review and analyze data. Test results are published in Equipment Performance
Reports designed to help justice system procurement officials make informed purchasing decisions.
Publications are available at no charge from the National Law Enforcement and Corrections Technology Center.
Some documents are also available online through the Internet/World Wide Web. To request a document or additional
information, call 800-248-2742 or 301-519-5060, or write:
Jeremy Travis
Director
FOREWORD
The Office of Law Enforcement Standards (OLES) of the National Institute of Standards
and Technology furnishes technical support to the National Institute of Justice program to
strengthen law enforcement and criminal justice in the United States. OLES’s function is to
conduct research that will assist law enforcement and criminal justice agencies in the selection
and procurement of quality equipment.
OLES is: (1) subjecting existing equipment to laboratory testing and evaluation, and (2)
conducting research leading to the development of several series of documents, including
national standards, user guides, and technical reports.
This document covers research conducted by OLES under the sponsorship of the National
Institute of Justice. Additional reports as well as other documents are being issued under the
OLES program in the areas of protective clothing and equipment, communications systems,
emergency equipment, investigative aids, security systems, vehicles, weapons, and analytical
techniques and standard reference materials used by the forensic community.
Technical comments and suggestions concerning this report are invited from all interested
parties. They may be addressed to the Director, Office of Law Enforcement Standards, National
Institute of Standards and Technology, Gaithersburg, MD 20899.
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BACKGROUND
The Office of Law Enforcement Standards conventional format, that details the
(OLES) was established by the National performance that the equipment is required to
Institute of Justice (NIJ) to provide focus on two give, and describes test methods by which its
major objectives: (1) to find existing equipment actual performance can be measured. These
which can be purchased today, and (2) to requirements are technical, and are stated in
develop new law-enforcement equipment which terms directly related to the equipment’s use.
can be made available as soon as possible. A The basic purposes of a standard are (1) to be a
part of OLES’s mission is to become thoroughly reference in procurement documents created by
familiar with existing equipment, to evaluate its purchasing officers who wish to specify
performance by means of objective laboratory equipment of the “standard” quality, and (2) to
tests, to develop and identify objectively
improve these equipment of
methods of test, to acceptable
develop performance A standard is not intended to inform performance.
standards for
selected equipment
and guide the reader; that is the Note that a standard
items, and to prepare function of a guideline is not intended to
guidelines for the inform and guide the
selection and use of reader; that is the
this equipment. All of these activities are function of a “guideline.” Guidelines are written
directed toward providing law enforcement in non-technical language and are addressed to
agencies with assistance in making good the potential user of the equipment. They
equipment selections and acquisitions in include a general discussion of the equipment,
accordance with their own requirements. its important performance attributes, the various
models currently on the market, objective test
As the OLES program has matured, there has data where available, and any other information
been a gradual shift in the objectives of the that might help the reader make a rational
OLES projects. The initial emphasis on the selection among the various options or
development of standards has decreased, and the alternatives available to him or her.
emphasis on the development of guidelines has
increased. For the significance of this shift in This battery guide is provided to inform the
emphasis to be appreciated, the precise reader of the latest technology related to battery
definitions of the words “standard” and composition, battery usage, and battery charging
“guideline” as used in this context must be techniques.
clearly understood.
Kathleen Higgins
A “standard” for a particular item of equipment National Institute of Standards and Technology
is understood to be a formal document, in a March 27, 1997
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CONTENTS
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List of Figures
6. Battery Chargers and Adapters . . . . . . . . . . . . . . 35 page
6.1 Battery Chargers . . . . . . . . . . . . . . . . . . . . . 35 Figure 1. Conceptual diagram of a galvanic cell. . . . 1
6.2 Charge Rates . . . . . . . . . . . . . . . . . . . . . . . . 36 Figure 2. Energy densities, W#h/kg, of various battery
6.3 Charging Techniques . . . . . . . . . . . . . . . . . . 36 types (adapted from NAVSO P-3676). . . . . . . . 15
6.4 Charging Lead-Acid Batteries . . . . . . . . . . . 36 Figure 3. Energy densities, W#h/L, of various battery
6.5 Charging Ni-Cd Batteries . . . . . . . . . . . . . . 37 types (adapted from NAVSO P-3676). . . . . . . . 16
6.6 Timed-Charge Charging . . . . . . . . . . . . . . . 37 Figure 4. Flat discharge curve vs. sloping discharge
6.7 Pulsed Charge-Discharge Chargers . . . . . . . 38 curve. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
6.8 Charging Button Batteries . . . . . . . . . . . . . . 38 Figure 5. Performance comparison of primary and
6.9 Internal Chargers . . . . . . . . . . . . . . . . . . . . . 38 secondary alkaline and Ni-Cd batteries (adapted
6.10 Battery Testers . . . . . . . . . . . . . . . . . . . . . . 38 from Design Note: Renewable Reusable Alkaline
6.11 “Smart” Batteries . . . . . . . . . . . . . . . . . . . . 39 Batteries). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
6.12 End of Life . . . . . . . . . . . . . . . . . . . . . . . . 39
6.13 Battery Adapters . . . . . . . . . . . . . . . . . . . . 40 List of Tables
page
7. Products and Suppliers . . . . . . . . . . . . . . . . . . . . 41 Table 1. The Electromotive Series for Some Battery
7.1 Battery Manufacturers . . . . . . . . . . . . . . . . . 41 Components . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
7.1.1 Battery Engineering . . . . . . . . . . . . . . 42 Table 2. Various Popular Household-Battery Sizes . 8
7.1.2 Duracell . . . . . . . . . . . . . . . . . . . . . . . 42 Table 3. Battery Technology Comparison (adapted from
7.1.3 Eveready . . . . . . . . . . . . . . . . . . . . . . 42 Design Note: Renewable Reusable Alkaline
7.1.4 Rayovac . . . . . . . . . . . . . . . . . . . . . . . 42 Batteries) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Table 4. A Comparison of Several Popular Battery
8. A Glossary of Battery Terms . . . . . . . . . . . . . . . 43 Types . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
Table 5. Recommended Battery Types for Various
9. Bibliography . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 Usage Conditions . . . . . . . . . . . . . . . . . . . . . . . . 25
Table 6. Typical Usage of Portable
Telecommunications Equipment. . . . . . . . . . . . . 27
Table 7. Charge Rate Descriptions . . . . . . . . . . . . . 35
Table 8. Some On-Line Information Available via the
World Wide Web . . . . . . . . . . . . . . . . . . . . . . . . 41
List of Equations
page
Equation 1. The chemical reaction in a lead-acid
battery. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Equation 2. The chemical reaction in a Leclanché cell.
....................................... 8
Equation 3. The chemical reaction in a nickel-
cadmium battery. . . . . . . . . . . . . . . . . . . . . . . . . . 9
Equation 4. The chemical reaction in a lithium-
manganese dioxide cell. . . . . . . . . . . . . . . . . . . . 11
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area=unit2 (e.g., ft2, in2, etc.); volume=unit3 (e.g., ft2, m3, etc.)
PREFIXES
ft/s×0.3048000=m/s lb×0.4535924=kg
ft×0.3048=m lbf×4.448222=N
ft#lbf×1.355818=J lbf/ft×14.59390=N/m
gr×0.06479891=g lbf#in×0.1129848=N #m #
in×2.54=cm lbf/in2×6894.757=Pa
kWh×3600000=J mph1.609344=km/h
qt×0.9463529=L
Temperature: (T F32)×5/9=T C
( (
Temperature: (T C×C9/5)+32=T F
( (
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x
1. Fundamentals of Battery Technology
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When the anode is fully oxidized or the Table 1. The Electromotive Series for Some
cathode is fully reduced, the chemical reaction Battery Components
will stop and the battery is considered to be
discharged. Anode Materials Cathode Materials
(Listed from worst (Listed from best
[most positive] to best [most positive] to
Recharging a battery is usually a matter of
[most negative]) worst [most negative])
externally applying a voltage across the plates
to reverse the chemical process. Some
chemical reactions, however, are difficult or Gold Ferrate
impossible to reverse. Cells with irreversible Platinum Iron Oxide
reactions are commonly known as primary
cells, while cells with reversible reactions are Mercury Cuprous Oxide
known as secondary cells. It is dangerous to Palladium Iodate
attempt to recharge primary cells.
Silver Cupric Oxide
The amount of voltage and current that a Copper Mercuric Oxide
galvanic cell produces is directly related to the
Hydrogen Cobaltic Oxide
types of materials used in the electrodes and
electrolyte. The length of time the cell can Lead Manganese Dioxide
produce that voltage and current is related to
Tin Lead Dioxide
the amount of active material in the cell and
the cell’s design. Nickel Silver Oxide
Iron Oxygen
Every metal or metal compound has an
electromotive force, which is the propensity of Chromium Nickel Oxyhydroxide
the metal to gain or lose electrons in relation Zinc Nickel Dioxide
to another material. Compounds with a
positive electromotive force will make good Aluminum Silver Peroxide
anodes and those with a negative force will Magnesium Permanganate
make good cathodes. The larger the difference
between the electromotive forces of the anode Lithium Bromate
and cathode, the greater the amount of energy
that can be produced by the cell. Table 1
shows the electromotive force of some
common battery components. Over the years, battery specialists have
experimented with many different
combinations of material and have generally
tried to balance the potential energy output of
a battery with the costs of manufacturing the
battery. Other factors, such as battery weight,
shelf life, and environmental impact, also
enter into a battery’s design.
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1.3 GALVANIC CELLS VS. BATTERIES diminished capacity), it is more likely that the
battery will simply fail to hold any charge, will
From earlier discussion, we know that a
leak electrolyte onto the battery charger, or
battery is one or more galvanic cells connected
will overheat and cause a fire. It is unwise and
in series or in parallel.
dangerous to recharge a primary battery.
A battery composed of two 1.5 V galvanic
1.5 SECONDARY BATTERY
cells connected in series, for example, will
produce 3 V. A typical 9 V battery is simply A secondary battery is commonly known as a
six 1.5 V cells connected in series. Such a rechargeable battery. It is usually designed to
series battery, however, will produce a current have a lifetime of between 100 and 1000
that is the equivalent to just one of the recharge cycles, depending on the composite
galvanic cells. materials.
A battery composed of two 1.5 V galvanic Secondary batteries are, generally, more cost
cells connected in parallel, on the other hand, effective over time than primary batteries,
will still produce a since the battery
voltage of 1.5 V, can be recharged
but the current A battery is one or more galvanic and reused. A
provided can be cells connected in series or in single discharge
double the current cycle of a primary
that just one cell parallel battery, however,
would create. Such will provide more
a battery can current for a longer
provide current twice as long as a single cell. period of time than a single discharge cycle of
an equivalent secondary battery.
Many galvanic cells can be thus connected to
create a battery with almost any current at any 1.6 BATTERY LABELS
voltage level.
The American National Standards Institute
(ANSI) Standard, ANSI C18.1M-1992, lists
1.4 PRIMARY BATTERY
several battery features that must be listed on a
A primary battery is a battery that is designed battery’s label. They are:
to be cycled (fully discharged) only once and
then discarded. Although primary batteries are _ Manufacturer -- The name of the battery
often made from the same base materials as manufacturer.
secondary (rechargeable) batteries, the design _ ANSI Number -- The ANSI/NEDA
and manufacturing processes are not the same. number of the battery.
_ Date -- The month and year that the battery
Battery manufacturers recommend that was manufactured or the month and year that
primary batteries not be recharged. Although the battery “expires” (i.e., is no longer
attempts at recharging a primary battery will guaranteed by the manufacturer).
occasionally succeed (usually with a _ Voltage -- The nominal battery voltage.
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4
2. Available Battery Types
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they are most likely to be found in commercial Equation 1 shows the chemical reaction in a
usage. lead-acid cell.
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5 6
The Story of Packaged Power, Duracell Why Use Energizer AA Lithium Batteries?,
International, Inc., July, 1995. Eveready Battery Company, Inc., 1993.
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Unfortunately, the same feature that makes Lithium primary batteries (in small sizes, for
lithium attractive for use in batteries—its high safety reasons) are currently being marketed
electrochemical potential—also can cause for use in flash cameras and computer
serious difficulties in the manufacture and use memory. Lithium batteries can last three times
of such batteries. Many of the inorganic longer than alkaline batteries of the same
components of the battery and its casing are size.8 But, since the cost of lithium batteries
destroyed by the lithium ions and, on contact can be three times that of alkaline batteries,
with water, lithium will react to create the cost benefits of using lithium batteries are
hydrogen which can ignite or can create marginal.
excess pressure in the cell. Many fire
extinguishers are water based and will cause Button-size lithium batteries are becoming
disastrous results if used on lithium products. popular for use in computer memory back-up,
Special D-class fire extinguishers must be in calculators, and in watches. In applications
used when lithium is known to be within the such as these, where changing the battery is
boundaries of a fire.7 difficult, the longer lifetime of the lithium
battery makes it a desirable choice.
Lithium also has a relatively low melting
temperature for a metal, 180 (C (356 (F). If One company now produces secondary
the lithium melts, it may come into direct lithium-ion batteries with a voltage of 3.7 V,
contact with the cathode, causing violent “four times the energy density of Ni-Cd
chemical reactions. batteries,” “one-fifth the weight of Ni-Cd
batteries,” and can be recharged 500 times.9
Because of the potentially violent nature of
lithium, the Department of Transportation In general, secondary (rechargeable) lithium-
(DOT) has special guidelines for the transport ion batteries have a good high-power
and handling of lithium batteries. Contact performance, an excellent shelf life, and a
them to ask for DOT Regulations 49 CFR. better life span than Ni-Cd batteries.
Unfortunately, they have a very high initial
Some manufacturers are having success with
lithium-iron sulfide, lithium-manganese
dioxide, lithium-carbon monoflouride,
8
lithium-cobalt oxide, and lithium-thionyl cells. Navy Primary and Secondary Batteries.
Design and Manufacturing Guidelines, NAVSO P-
3676, September 1991.
7 9
Battery Engineering Web Site, Battery Engineering Web Site,
http://www.batteryeng.com/, August 1997. http://www.batteryeng.com/, August 1997.
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cost and the total energy available per usage more room is available for the anode and
cycle is somewhat less than Ni-Cd batteries. electrolyte, so the cell size can be very small
while providing good energy output. Small
2.4 SPECIALTY BATTERIES (“BUTTON” AND metal-air cells are available for applications
MINIATURE BATTERIES) such as hearing aids, watches, and clandestine
listening devices.
“Button” batteries are the nickname given to
the category of batteries that are small and
Metal-air cells have some technical
shaped like a coin or a button. They are
drawbacks, however. It is difficult to build and
typically used for small devices such as
maintain a cell where the oxygen acting as the
cameras, calculators, and electronic watches.
cathode is completely isolated from the anode.
Also, since the electrolyte is in direct contact
Miniature batteries are very small batteries
with air, approximately one to three months
that can be custom built for devices, such as
after it is activated, the electrolyte will become
hearing aids and electronic “bugs,” where
too dry to allow the chemical reaction to
even button batteries can be too large. Industry
continue. To prevent premature drying of the
standardization has resulted in five to ten
cells, a seal is installed on each cell at the time
standard types of miniature batteries that are
of manufacture. This seal must be removed by
used throughout the hearing-aid industry.
the customer prior to first use of the cell.
Alternately, the manufacturer can provide the
Together, button batteries and miniature
battery in an air-tight package.
batteries are referred to as specialty batteries.
2.4.2 Silver Oxide
Most button and miniature batteries need a
Silver oxide cells use silver oxide as the
very high energy density to compensate for
cathode, zinc as the anode, and potassium
their small size. The high energy density is
hydroxide as the electrolyte. Silver oxide cells
achieved by the use of highly electro-
have a moderately high energy density and a
positive—and expensive—metals such as
relatively flat voltage profile. As a result, they
silver or mercury. These metals are not cost
can be readily used to create specialty
effective enough to be used in larger batteries.
batteries. Silver oxide cells can provide
higher currents for longer periods than most
Several compositions of specialty batteries are
other specialty batteries, such as those
described in the following sections.
designed from metal-air technology. Due to
the high cost of silver, silver oxide technology
2.4.1 Metal-Air Cells
is currently limited to use in specialty
A very practical way to obtain high energy
batteries.
density in a galvanic cell is to utilize the
oxygen in air as a “liquid” cathode. A metal,
2.4.3 Mercury Oxide
such as zinc or aluminum, is used as the
Mercury oxide cells are constructed with a
anode. The oxygen cathode is reduced in a
zinc anode, a mercury oxide cathode, and
portion of the cell that is physically isolated
potassium hydroxide or sodium hydroxide as
from the anode. By using a gaseous cathode,
the electrolyte. Mercury oxide cells have a
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New Technology Batteries Guide
high energy density and flat voltage profile physical abuse (such as vibrations or shocks)
resembling the energy density and voltage between uses.
profile of silver oxide cells. These mercury
oxide cells are also ideal for producing Thermal batteries can generate voltages of
specialty batteries. The component, mercury, 1.5 V to 3.3 V, depending on the battery’s
unfortunately, is relatively expensive and its composition. Due to their rugged construction
disposal creates environmental problems. and absence of maintenance requirements,
they are most often used for military
2.5 OTHER BATTERIES applications such as missiles, torpedoes, and
space missions and for emergency-power
This section describes battery technology that
situations such as those in aircraft or
is not mature enough to be available off-the-
submarines.
shelf, has special usage limitations, or is
otherwise impractical for general use.
The high operating temperatures and short
active lives of thermal batteries limit their use
2.5.1 Nickel-Hydrogen (Ni-H)
to military and other large-institution
Nickel-hydrogen cells were developed for the
applications.
U.S. space program. Under certain pressures
and temperatures, hydrogen (which is,
2.5.3 Super Capacitor
surprisingly, classified as an alkali metal) can
This kind of battery uses no chemical reaction
be used as an active electrode opposite nickel.
at all. Instead, a special kind of carbon (carbon
Although these cells use an environmentally
aerogel), with a large molecular surface area,
attractive technology, the relatively narrow
is used to create a capacitor that can hold a
range of conditions under which they can be
large amount of electrostatic energy.10 This
used, combined with the unfortunate volatility
energy can be released very quickly, providing
of hydrogen, limits the long-range prospects of
a specific energy of up to 4000 Watt-hours per
these cells for terrestrial uses.
kilogram (Wh/kg), or it can be regulated to
provide smaller currents typical of many
2.5.2 Thermal Batteries
commercial devices such as flashlights, radios,
A thermal battery is a high-temperature,
and toys. Because there are no chemical
molten-salt primary battery. At ambient
reactions, the battery can be recharged
temperatures, the electrolyte is a solid, non-
hundreds of thousands of times without
conducting inorganic salt. When power is
degradation. Other potential advantages of this
required from the battery, an internal
kind of cell are its low cost and wide
pyrotechnic heat source is ignited to melt the
temperature range. One disadvantage,
solid electrolyte, thus allowing electricity to be
however, is its high self-discharge rate. The
generated electrochemically for periods from a
voltage of some prototypes is approximately
few seconds to an hour. Thermal batteries are
2.5 V.
completely inert until the electrolyte is melted
and, therefore, have an excellent shelf life,
require no maintenance, and can tolerate
10
PolyStor Web Page,
http://www.polystor.com/, August, 1997.
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14
3. Performance, Economics and Tradeoffs
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reactions and the increased internal resistance predetermined level of discharge. This kind of
of the electrolyte. At high temperatures, the test simulates the battery usage of a portable
loss of energy capacity is due to the increase radio.
of unwanted, parasitic chemical reactions in
the electrolyte. A comparison of these two kinds of tests was
performed on five commonly available types
Ni-Cd batteries have a recommended of batteries.11 The data shows that the five
temperature range of +17 (C (62 (F) to 37 (C tested batteries all had a constant-load
(98 (F). Ni-MH have a recommended duration of 60 to 80 minutes, which indicates
temperature range of 0 (C (32 (F) to 32 (C that the five batteries had similar capacities.
(89 (F).
But, intermittent-load testing of those same
3.8 CYCLE LIFE five batteries showed that the duration of the
batteries ranged from 8.5 hours to 12 hours.
The cycle life of a battery is the number of
There was no correlation of the results of the
discharge/recharge cycles the battery can
two tests, meaning that batteries that
sustain, with normal care and usage patterns,
performed best under constant-load testing did
before it can no longer hold a useful amount
not necessarily perform well under
of charge.
intermittent-load testing. The study concluded
that the ability of a battery to recover itself
Ni-Cd batteries should have a normal cycle
between heavy current drains cannot be made
life of 600 to 900 recharge cycles. Ni-MH
apparent through a constant-load test.
batteries will have a cycle life of only 300 to
400 recharge cycles. As with all rechargeable
3.10 BATTERY TECHNOLOGY COMPARISON
batteries, overcharging a Ni-Cd or Ni-MH
battery will significantly reduce the number of Table 3 shows a comparison of some of the
cycles it can sustain. performance factors of several common
battery types.
3.9 CAPACITY TESTING
The initial capacity of a battery refers to the
Many battery manufacturers recommend the
electrical output, expressed in ampere-hours,
constant-load test to determine the capacity of
which the fresh, fully charged battery can
a battery. This test is conducted by connecting
deliver to a specified load. The rated capacity
a predetermined load to the battery and then
is a designation of the total electrical output of
recording the amount of time needed to
the battery at typical discharge rates; e.g., for
discharge the battery to a predetermined level.
each minute of radio transceiver operation, 6
seconds shall be under a transmit current
Another recommended test is the intermittent-
or switching-load test. In this type of test, a
predetermined load is applied to the battery for 11
a specified period and then removed for Batteries Used with Law Enforcement
Communications Equipment: Chargers and Charging
another period. This load application and Techniques, W. W. Scott, Jr., U.S. Department of
removal is repeated until the battery reaches a Justice, LESP-RPT-0202.00, June 1973.
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19
20
Cell Type* Basic Anode Cathode Main Volts Advantages & Disadvantages
Type** material Material Electrolyte per Applications
Material Cell
Carbon-Zinc P Zinc Manganese Ammonium 1.5 Low cost, good shelf Output capacity
(“Leclanché”) dioxide chloride, zinc life. Useful for decreases as it
chloride flashlights, toys, and drains; poor
small appliances. performance at
low temperatures.
Zinc Chloride P Zinc Manganese Zinc Chloride 1.5 Good service at high Relatively
dioxide drain, leak resistant, expensive for
good low-temperature novelty usage.
performance. Useful for
flashlights, toys, and
small appliances.
“Alkaline” P or S Zinc Manganese Potassium 1.5 High efficiency under Primary cells are
(Zinc- dioxide hydroxide moderate, continuous expensive for
Manganese drains, long shelf life, novelty usage.
Dioxide) good low-temperature Secondary cells
performance. Useful for have a limited
camera flash units, number of
motor-driven devices, recharge cycles.
portable radios.
Car Battery S Lead Lead dioxide Sulfuric acid 2 Low cost, spill resistant Limited low-
(Lead-Acid) (sealed batteries). Useful temperature
for automobiles and performance.
cordless electric lawn Vented cells
mowers. require
maintenance.
Cells are relatively
heavy.
* -- Common name, ** -- P=Primary, S=Secondary (Rechargeable)
Table 4 (continued)
Cell Type* Basic Anode Cathode Main Volts Advantages & Disadvantages
Type** material Material Electrolyte per Applications
Material Cell
“Ni-Cd” (Nickel- S Cadmium Nickel Potassium 1.25 Excellent cycle life; flat High initial cost;
Cadmium) hydroxide hydroxide discharge curve; good only fair charge
high- and low- retention;
temperature memory effect.
performance; high
resistance to shock and
vibration. Useful for
small appliances that
have intermittent usage,
such as walkie-talkies,
portable hand tools, tape
players, and toys. When
batteries are exhausted,
they can be recharged
before the next needed
use.
Mercuric Oxide P Zinc Mercuric Potassium 1.35 Relatively flat discharge Poor low-
oxide hydroxide curve; relatively high temperature
energy density; good performance in
high-temperature some situations.
performance; good
service maintenance.
Useful for critical
Cell Type* Basic Anode Cathode Main Volts Advantages & Disadvantages
Type** material Material Electrolyte per Applications
Material Cell
“Ni-MH” S Hydrogen Nickel oxide Potassium 1.5 No memory effects (such High initial cost,
(Nickel-Metal storage metal hydroxide as Ni-Cd has), good relatively high
Hydride) high-power rate of self-
performance, good low- discharge.
temperature
performance. Useful for
portable devices where
the duty cycle varies
from use to use.
Silver Oxide P or S Zinc Silver oxide Potassium 1.5 High energy density; flat Silver is very
hydroxide discharge curve. Useful expensive; poor
for very small appliances storage and
such as calculators, maintenance
watches, and hearing characteristics.
aids. Rechargeable
cells have a very
limited number of
cycles.
Zinc-Air P Zinc Oxygen Potassium 1.25 High energy density in Dries out quickly.
hydroxide small cells. Flat
discharge rate.
Lithium P Lithium Iron sulfide Lithium salts 1.0 - Good energy density. Limited high-rate
in ether 3.6 capacities; safety
concerns.
* -- Common name, ** -- P=Primary, S=Secondary (Rechargeable)
4. Selecting the Right Battery for the
Application
Batteries come in many different shapes, sizes, However, the small differences that do exist
and compositions. There is no one “ideal” between batteries made by different
battery that can satisfy all possible manufacturers, can be significant when using a
requirements equally. Different battery multi-cell array of matched cells. In these
technologies have been developed that will cases, potential replacement cells must be
optimize certain parameters for specific graded to see if the cells properly match the
battery uses. capacity of the existing cells.
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New Technology Batteries Guide
Figure 5 shows some discharge curves for expected temperature range for the
several popular AA size battery types. Two of application?
the curves (secondary alkaline [1st use] and Good Cycle Life -- How many
[25th use]) show that secondary alkaline times can the rechargeable battery be
batteries rapidly lose their capacity as they are discharged and recharged before it becomes
used and recharged. Only one Ni-Cd curve is unusable?
shown, since its curve remains essentially the Costs -- How expensive is the
same throughout most its life span. battery to purchase? Does the battery require
special handling?
4.1 BATTERY PROPERTIES
Shelf Life -- How long can the
Battery applications vary, as do considerations battery be stored without loss of a significant
for selecting the correct battery for each amount of its power?
application. Some of the important factors that Voltage -- What is the voltage of
customers might consider when selecting the the battery? [Most galvanic cells produce
right battery for a particular application are voltages of between 1.0 and 2.0 V.]
listed below:
Safety -- Battery components
range from inert, to mildly corrosive, to highly
Chemistry -- Which kind of toxic or flammable. The more hazardous
battery chemistry is best for the application? components will require additional safety
Different chemistries will generate different procedures.
voltages and currents.
Hidden Costs -- Simpler
Primary or Secondary -- Primary manufacturing processes result in lower cost
batteries are most appropriate for applications batteries. However, if a battery contains toxic
where infrequent, high-energy output is or hazardous components, extra costs will be
required. Secondary batteries are most incurred to dispose of the battery safely after
appropriate for use in devices that see steady its use.
periods of use and non-use (pagers, cellular
phones, etc.). Table 5 shows a short list of different battery
Standardization and types and the kinds of application that are
Availability -- Is there an existing battery appropriate for each.
design that meets the application needs? Will
replacement batteries be available in the 4.2 ENVIRONMENTAL CONCERNS
future? Using existing battery types is almost
always preferable to specifying a custom-made All battery components, when discarded,
battery design. contribute to the pollution of the environment.
Some of the components, such as paperboard
Flexibility -- Can the battery and carbon powder, are relatively organic and
provide high or low currents over a wide range can quickly merge into the ecosystem without
of conditions? noticeable impact. Other components, such as
Temperature Range -- Can the steel, nickel, and plastics, while not actively
battery provide adequate power over the
24
New Technology Batteries Guide
toxic to the ecosystem, will add to the volume 1980, to 0.00%, in 1996.12 Other
of a landfill, since they decompose slowly. manufacturers report that their current battery
formulas contain no mercury. The U.S.
Table 5. Recommended Battery Types for Department of Mines, in 1994, estimated that,
Various Usage Conditions for the U.S. production of household batteries,
mercury usage had fallen from 778 tons in
Battery Device Device Use 1984 to (a projected) 10 tons in 1995.13
Type Drain Rate Frequency
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New Technology Batteries Guide
The most popular secondary batteries, Standard duty cycles for battery service life
however, contain cadmium. Many and capacity determinations are defined in
manufacturers, responding to customer EIA/TIA Standard 60315 for land mobile radio
requests and legislative demands, are communications and NIJ Standard-0211.0116
designing nickel-metal hydride, lithium-ion, for hand-held portable radio applications.
and rechargeable-alkaline secondary batteries Specifically, in an average 1 minute period of
that contain only trace amounts of cadmium, mobile-radio usage, 6 seconds (10%) is spent
lead, or mercury. receiving, 6 seconds (10%) is spent
transmitting and 48 seconds (80%) is spent in
4.3 STANDARDIZATION the idle mode. Table 8 provides an example
of a transceiver drawing an average current of
Existing off-the-shelf batteries are often
8.0 + 6.2 + 32.5 = 46.7 mA. For a typical duty
preferred to batteries that require special
cycle composed of 8 hours of operation
design and manufacturing. Some benefits of
(followed by 16 hours of rest) a minimum
using off-the-shelf batteries are listed below:
battery capacity of 374 mAh is required. One
manufacturer of portable communications
The use of a proven design can equipment recommends that batteries be
reduce the risk of the battery not working replaced if they fail to deliver 80% or more of
properly. their original rated capacity. Below 80%
batteries are usually found to deterioriate
The use of tested technology quickly. Because a minimum requirement of
eliminates costly and time-consuming 374 mAh is 75% of the rated capacity of a 500
development efforts. mAh battery, the latter should adequately
provide power for the entire duty described.17
The use of a proven design reduces
unit production costs because of competitive,
multi-source availability.
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New Technology Batteries Guide
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New Technology Batteries Guide
from dozens of different manufacturers.18 The and at the self-discharge rate when the
user is advised to check battery inter- computer is shut off. Quite often, the user will
operability charts before purchasing a use the computer until the “low battery” alarm
replacement battery. sounds. At this point, the battery will be
drained of 90% of its charge before the user
One battery manufacturer offers a battery recharges it. The computer will also register
replacement system that allows a phone owner regular periods of non-use, during which the
to use household primary batteries, inserted battery can be recharged. Secondary Ni-Cd
into a special housing (called a refillable batteries are most appropriate for this usage
battery pack), to replace the phone’s regular pattern.
rechargeable battery pack. This refillable pack,
says the manufacturer, is designed for light- When a laptop-computer battery reaches the
use customers, who require that their phone’s end of its life cycle, it should be replaced with
batteries have the long shelf life of primary a battery designed specifically for that laptop
batteries. This refillable pack can also be used computer. Using other types of batteries may
in emergencies, for example, where the damage the computer. The user’s manual for
phone’s rechargeable battery pack is the laptop computer will list one or more
exhausted and no recharged packs are battery types and brands that may be used. If
available. Primary household batteries can be in doubt, the user is advised to contact the
readily purchased (or borrowed from other manufacturer of the laptop computer and ask
devices), inserted into the refillable pack, and for a battery-replacement recommendation.
used to power the phone.19
4.8 CAMCORDERS
4.7 LAPTOP COMPUTERS
Almost all commercial, off-the-shelf
Most commercial, off-the-shelf laptop camcorders come with a battery and a
computers have a built-in battery system. In recharging unit when purchased.
addition to the battery provided, most laptops
will have a battery adapter that also serves as a The camcorder is typically operated
battery charger. continuously for several minutes or hours (to
produce a video recording of some event).
The expected usage of a laptop computer is This use will require that the battery provide
that the operator will use it several times a approximately 2 hours of non-stop recording
week, for periods of several hours at a time. time. The electric motor driving the recording
The computer will drain the battery at a tape through the camcorder requires a
moderate rate when the computer is running, moderately high amount of power throughout
the entire recording period.
18
Easy to Choose, Easy to Use, Eveready
Rechargeable Ni-Cd or Ni-MH batteries or
Battery Corporation, 1997. primary lithium batteries are usually the only
choice for camcorder use. Several battery
19
Cellular Duracell Rechargeable Batteries, manufacturers produce Ni-Cd or Ni-MH
Duracell, 1996.
28
New Technology Batteries Guide
batteries that are specially designed for use in _ Alkaline -- The most commonly used
camcorders. Due to the lack of sufficient primary cell (household) is the zinc-alkaline
standardization for these kind of batteries, the manganese dioxide battery. They provide
battery manufacturers must design and sell more power-per-use than secondary batteries
approximately 20 different camcorder and have an excellent shelf life.
batteries to fit at least 100 models of _ Rechargeable Alkaline -- Secondary
camcorders from over a dozen alkaline batteries have a long shelf life and are
manufacturers.20 useful for moderate-power applications. Their
cycle life is less than most other secondary
Camcorder batteries are usually designed to batteries.
provide 2 hours of service, but larger batteries _ Lithium Cells -- Lithium batteries offer
are available that can provide up to 4 hours of performance advantages well beyond the
service. capabilities of conventional aqueous
electrolyte battery systems. However, lithium
Lithium camcorder batteries can provide three batteries are not widely used because of safety
to five times the energy of a single cycle of concerns.
secondary Ni-Cd batteries. These lithium _ Thermal Batteries -- These are special
batteries, however, are primary batteries and batteries that are capable of providing very
must be properly disposed of at the end of high rates of discharge for short periods of
their life cycle. Secondary lithium-ion time. They have an extremely long shelf life,
camcorder batteries are being developed. but, because of the molten electrolyte and high
operating temperature, are impractical for
4.9 SUMMARY most household uses.
There are six varieties of batteries in use, each
with its own advantages and disadvantages.
Below is a short summary of each variety:
20
Camcorder Battery Pocket Guide, Eveready
Battery Company, 1996.
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New Technology Batteries Guide
30
5. Battery Handling and Maintenance
The following guidelines offer specific advice which may result in an explosion or
on battery handling and maintenance. This asphyxiation.
advice is necessarily not all inclusive. Users
are cautioned to observe specific warnings on Do not attempt to solder directly onto a
individual battery labels and to use common terminal of the battery. Attempting to
sense when handling batteries. do so can damage the seal or the safety
vent.
5.1 BATTERY DANGERS
When disconnecting a battery from the
8 To get help, should someone swallow a
device it is powering, disconnect one
battery, immediately call The National
terminal at a time. If possible, first
Battery Ingestion Hot Line collect at
remove the ground strap at its
(202) 625-3333. Or, call 911 or a
connection with the device’s
state/local Poison Control Center.
framework. Observing this sequence
can prevent an accidental short circuit
8 Batteries made from lead (or other heavy
and also avoid risking a spark at the
metals) can be very large and heavy
battery. In most late-model, domestic
and can cause damage to equipment or
automobiles, the battery terminal
injuries to personnel if improperly
labeled “negative” is usually connected
handled.
to the automobile’s framework.
8 When using lithium batteries, a “Lith-X”
Do not attempt to recharge primary
or D-Class fire extinguisher should
batteries. This kind of battery is not
always be available. Water-based
designed to be recharged and may
extinguishers must not be used on overheat or leak if recharging is
lithium of any kind, since water will attempted.
react with lithium and release large
amounts of explosive hydrogen. 8 When recharging secondary batteries, use a
charging device that is approved for
Before abusively testing a battery, contact that type of battery. Using an approved
the manufacturer of the battery to charging device can prevent
identify any potential dangers. overcharging or overheating the
battery. Many chargers have special
8 Vented batteries must be properly circuits built into them for correctly
ventilated. Inadequate ventilation may charging specific types of batteries and
result in the build up of volatile gases,
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New Technology Batteries Guide
will not work properly with other Do not carry batteries in your pocket.
types. Coins, keys, or other metal objects can
short circuit a battery, which can cause
Do not use secondary (rechargeable) extreme heat, acid leakage, or an
batteries in smoke detectors. explosion.
Secondary batteries have a high self-
discharge rate. Primary batteries have a Do not wear rings, metal jewelry, or metal
much longer shelf life and are much watchbands while handling charged
more dependable in emergencies. cells. Severe burns can result from
Consult the smoke detector’s user accidentally short circuiting a charged
manual for the recommended battery cell. Wearing gloves can reduce this
types. danger.
Do not attempt to refill or repair a worn-out Do not use uninsulated tools near charged
or damaged battery. cells. Do not place charged cells on
metal workbenches. Severe arcing and
Do not allow direct bodily contact with overheating can result if the battery’s
battery components. Acidic or alkaline terminals are shorted by contact with
electrolyte can cause skin irritation or such metal objects.
burns. Electrode materials such as
mercury or cadmium are toxic.
Lithium can cause an explosion if it
comes into contact with water. Other
components can cause a variety of
short-term (irritation and burns) or
long-term (nerve damage) maladies.
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8 Use a marking pen to indicate, on the higher than those recommended by the
battery casing, the day and year that the manufacturer.
battery was purchased. Also, keep
track of the number of times the
battery has been recharged. Avoid
writing on or near the battery
terminals.
34
6. Battery Chargers and Adapters
“C” is the theoretical current needed to completely It is not recommended that battery
charge the fully discharged battery in one hour. users design and build their own
charging units. Many low-cost
chargers are available off-the-shelf
that do a good job of recharging batteries.
Specific, off-the-shelf chargers are identified
Batteries should only be recharged with
and recommended, by each of the major
chargers that are recommended, by the
battery manufacturers, for each type of
manufacturer, for that particular type of
secondary battery they produce.
battery. In general, however, battery-industry
standards ensure that any off-the-shelf battery
charger, specified for one brand, size, and type
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New Technology Batteries Guide
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New Technology Batteries Guide
charge. Current limiting may be accomplished have a temperature sensor or a voltage sensor
through the use of a current-limiting resistor. that can detect when the battery is nearing
One manufacturer uses a miniature light bulb thermal-runaway conditions. When near-
as a current-limiting resistor. The brightness runaway conditions are indicated, the charger
of the bulb will provide a visual indication of will reduce or shut off the current entering the
the state of charge of the battery. In modern battery.
practice, however, current limiting is
accomplished with integrated circuits. 6.6 TIMED-CHARGE CHARGING
Most charging methods, described so far in
6.5 CHARGING NI-CD BATTERIES
this guide, allow the user to begin charging a
During their recharge cycle, nickel-cadmium cell regardless of its current state of charge.
batteries react in a manner different from other One additional method can be used to charge
batteries. Nickel-cadmium batteries will Ni-Cd cells, but only if the cell is completely
actually absorb heat during the first 25% of discharged. It is called the timed-charged
the charge cycle (as opposed to most method.
secondary batteries, which generate heat all
through their recharge cycle). Beyond that first One characteristic of Ni-Cd cells is that they
quarter of the charge cycle, a Ni-Cd battery can accept very large charge rates (as high as
will generate heat. If constant current is 20 C), provided that the cell is not forced into
applied past the point when the battery reaches an overcharge condition.
approximately 85% of its fully charged state,
the excess heat will cause “thermal runaway” The timed-charge charger will provide high-
to occur. Under thermal runaway conditions, rate current to the cell for a very specific
the excess heat in the battery will cause its period. A timer will then cut off the charging
voltage to drop. The drop in voltage will cause current at the end of that period. Some cells
the charge rate to increase (according to can be charged completely in as little as 10
Ohm’s Law), generating more heat and minutes (as opposed to 8 hours on a slow
accelerating the cycle. The temperature and charger).
internal pressure of the battery will continue to
rise until permanent damage results. Great care should be exercised when using a
timed-charge charger, because there is no
When using trickle or slow chargers to charge room for error. If the cell has any charge in it
Ni-Cd batteries, the heat build-up is minimal at all at the beginning of the charge cycle, or if
and is normally dissipated by atmospheric the cell’s capacity is less than anticipated, the
convection before thermal runaway can occur. cell can quickly reach the fully charged state,
Most chargers supplied with, or as a part of, proceed into thermal-runaway conditions, and
rechargeable devices (sealed flashlights, mini- cause the explosion or destruction of the cell.
vacuums, etc.) are slow chargers.
Some timed-charge chargers have a special
Quick or fast battery chargers, designed circuit designed to discharge the cell
especially for Ni-Cd batteries, will usually completely before charging it. These are
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New Technology Batteries Guide
called dumped timed-charge chargers, since cannot escape. The pressure will build up and
they dump any remaining charge before will damage the battery or cause an explosion.
applying the timed charge. Care should be taken not to overcharge a
secondary button battery.
6.7 PULSED CHARGE-DISCHARGE
CHARGERS 6.9 INTERNAL CHARGERS
This method of charging Ni-Cd cells applies a For some applications, the charger may be
relatively high charge rate (approximately 5 C) provided, by the battery manufacturer, as an
until the cell reaches a voltage of 1.5 V. The integral part of the battery itself. This design
charging current is then removed and the cell has the obvious advantage of ensuring that the
is rapidly discharged for a brief period of time correct charger is used to charge the battery,
(usually a few seconds). This action but this battery-charger combination may
depolarizes the cell components and dissipates result in size, weight and cost penalties for the
any gaseous buildup within the cell. The cell is battery.
then rapidly charged back to 1.5 V. The
process is repeated several more times until 6.10 BATTERY TESTERS
the cell’s maximum charge state is reached.
A battery tester is a device that contains a
small load and attaches across the terminals of
Unfortunately, this method has some
a battery to allow the user to see if the battery
difficulties. The greatest difficulty is that the
is sufficiently charged. A simple battery tester
maximum voltage of a Ni-Cd cell will vary
can be made from a flashlight bulb and two
with several outside factors such as the cell’s
pieces of wire. Flashlight bulbs are ideal for
recharge history and the ambient temperature
testing household batteries, since the voltage
at the charger’s location. Since the cell’s
and current required to light the bulb is the
maximum potential voltage is variable, the
same as that of the battery. This kind of
level to which it must be charged is also
flashlight-bulb tester can also be used to drain
variable. Integrated circuits are being
a secondary battery safely before fully
designed, however, that may compensate for
charging it.
such variations.
Some off-the-shelf household batteries are
6.8 CHARGING BUTTON BATTERIES
sold with their own testers. These testers are
Secondary cylindrical (household) cells will attached to the packaging material or to the
usually have a safety seal or vent built into battery itself. The active conductor in the
them to allow excess gases, created during the tester is covered by a layer of heat-sensitive
charging process, to escape. Secondary, ink. As the ends of the tester are pressed
button-type batteries do not have such seals against the battery terminals, a small amount
and are often hermetically sealed. of current will flow through the material under
the ink, heating it. The heating will cause the
When cylindrical cells are overcharged, excess ink to change color, indicating that the battery
gases are vented. If a button battery is still has energy.
inadvertently overcharged, the excess gases
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New Technology Batteries Guide
Using a simple battery tester to test a Ni-Cd since the battery will not hold as much charge
battery can be somewhat misleading, since a as it would have had it been charged at the
Ni-Cd battery has a flat voltage profile. The recommended temperature.
tester will indicate near-maximum voltage
whether the battery is 100% charged or 85% Most battery users are not sufficiently diligent
discharged. in matters of battery maintenance. “Smart”
batteries allow the battery itself to record all
6.11 “SMART” BATTERIES pertinent information and make it available to
the user at a glance.
Many battery-powered devices require the use
of multi-cell battery packs (i.e., several
6.12 END OF LIFE
ordinary battery cells strapped together to be
used as a single unit). The individual cells All secondary batteries will eventually fail due
cannot be charged or measured separately, to age, expended components, or physical
without destroying the battery pack. damage. A battery, when properly maintained,
will fail through gradual loss of capacity. To
A new development in rechargeable battery the user, this gradual failure will appear as a
technology is the use of microelectronics in frequent need to change and charge the
battery-pack cases to create “intelligent” batteries. Sudden failure, usually due to
battery packs. These “smart” battery packs physical abuse, will prevent the battery from
contain a microprocessor, memory, and holding any charge at all.
sensors that monitor the battery’s temperature,
voltage, and current. This information can be The physical manifestations of a gradual
relayed to the device (if the device is designed failure of the battery can be seen as a
to accept the information) and used to degradation of the separator material, dendritic
calculate the battery’s state of charge at any growth or other misshapening of the
time or to predict how much longer the device electrodes, and permanent material loss of the
can operate. The microprocessor on a battery active components.
pack may also record the history of the battery
and display the dates and number of times that The physical manifestations of a sudden
it has been charged. failure, can be seen as the destruction of the
battery components. Open-circuit failure can
To get the maximum potential from a be induced by an applied shock to or excess
secondary battery, the user must adopt a strict vibration of the battery. As a result, the
regimen of noting certain information about internal components of the battery may
the battery and acting upon that information. become loose or detached, causing a gap in the
For example, if a battery is already partially electrical circuit.
discharged, using it in a device will obviously
not allow the device to be used for its entire Short-circuit failure can be caused by an
duty cycle. Attempting to charge a battery applied shock. It can also be caused by
when the ambient temperature is too high is overheating or overcharging the battery. In a
another example of suboptimal battery usage, short-circuit failure, some part of one of the
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New Technology Batteries Guide
electrodes pierces (caused by shock) or grows An adapter will usually have a dc-output plug
through (caused by overcharging) the that is inserted into the battery-powered device
separator material in the electrolyte. This to provide dc current to the device.
piercing effect will cause the electrical path to
be shorted. Usually, manufacturers of the more expensive
battery-powered devices (e.g., cellular phones,
If a battery and its replacements seem to be laptop computers) will provide the customer
suffering repeated premature failures, in with a battery adapter designed especially for
reoccurring and similar circumstances, the that device. The adapter will plug into a
failed batteries should be sent to a laboratory special connector in the device to provide it
for dissection and analysis. The problem may power. If designed to do so, the battery adapter
lie in faulty equipment, inappropriate battery will charge the device’s batteries as well.
usage, or in physical abuse to the device and
its batteries. Resolution of the problem will Other manufacturers make generic battery
save time and money in future battery designs adapters. These adapters will have a battery-
and applications. shaped appendage that plugs into a battery-
powered device in place of a real battery and
6.13 BATTERY ADAPTERS will provide energy equivalent to a real
battery. While this kind of adapter has some
A battery adapter is a device that can be used
advantages (it can be used for any battery
instead of a battery to provide current to a
powered device, it can be used when no
battery-powered device.
charged batteries are available, etc.), those
advantages are usually outweighed by the
disadvantages (the power cord is inconvenient
and negates the portability of the device, the
battery cover cannot be replaced while the
cord is attached, a multiple-battery device
would require multiple adapters, etc.).
40
7. Products and Suppliers
Table 8. Some On-Line Information Available via the World Wide Web
Batteries and
battery Battery Manufacturers Web Address
manufacturers and Battery Engineering http://www.batteryeng.com/
suppliers listed or
mentioned in this Duracell Batteries http://www.duracell.com/
section, and Eveready Batteries http://www.eveready.com/
elsewhere in this
guideline, are listed Kodak Corporation http://www.kodak.com/
for the convenience NEXcell http://www.battery.com.tw/
of the reader. The
name of a specific Panasonic Batteries http://www.panasonic-batteries.be/home.html
product or PolyStor Corporation http://www.polystor.com/
company does not
Radio Shack http://www.radioshack.com/
imply that the
product or Rayovac Batteries http://www.rayovac.com/
company is,
Sony Corporation http://www.sel.sony.com/SEL/rmeg/batteries/
necessarily, the best
for any particular Battery Distributors Web Address
application or
Battery-Biz, Inc. http://www.battery-biz.com/battery-biz/
device. The lists
are, necessarily, not Battery Depot http://www.battery-depot.com/
all-inclusive. The
Battery Network http://batnetwest.com/
list of Web pages
was compiled Batteries Plus http://www.spromo.com/battplus/
following a Web E-Battery http://e-battery.com/
search performed in
August, 1997. New Powerline http://www.powerline-battery.com/
Web pages may All Web information was verified in August, 1997.
have appeared
since then and
some which appear in this list may no longer 7.1 BATTERY MANUFACTURERS
be available. Other Web pages, that were not
The battery manufacturers listed below are
listed in the Web-search database at that time,
some of the manufacturers of household
will also not appear in this list.
batteries. They are presented in alphabetical
41
New Technology Batteries Guide
7.1.2 Duracell
Postal Address:
Duracell, Inc.
Berkshire Corp Park
Bethel, CT 06801
Phone Number:
1 (800) 551-2355
Web Page:
http://www.duracell.com/
7.1.3 Eveready
Postal Address:
Eveready Battery Company, Inc.
Checkerboard Square
St. Louis, MO 63164-0001
Phone Number:
1 (800) 383-7323
Web Page:
http://www.eveready.com/
42
8. A Glossary of Battery Terms
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New Technology Batteries Guide
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2 Polarity -- Refers to the charges residing 2 Seal -- The structural part of a galvanic
at the terminals of a battery. cell that restricts the escape of solvent
or electrolyte from the cell and limits
2 Positive Terminal -- The terminal of a the ingress of air into the cell (the air
battery toward which electrons flow may dry out the electrolyte or interfere
through the external circuit when the with the chemical reactions).
cell discharges. See Negative
Terminal. 2 Secondary Battery -- A battery made up
of secondary cells. See Storage
2 Primary Battery -- A battery made up of Battery; Storage Cell.
primary cells. See Primary Cell.
2 Self Discharge -- Discharge that takes
2 Primary Cell -- A cell designed to place while the battery is in an open-
produce electric current through an circuit condition.
electrochemical reaction that is not
efficiently reversible. Hence the cell, 2 Separator -- The permeable membrane
when discharged, cannot be efficiently that allows the passage of ions, but
recharged by an electric current. prevents electrical contact between the
Note: When the available energy drops anode and the cathode.
to zero, the cell is usually discarded.
Primary cells may be further classified 2 Series Connection -- The arrangement of
by the types of electrolyte used. cells in a battery configured by
connecting the positive terminal of
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New Technology Batteries Guide
each successive cell to the negative 2 Storage Cell -- An electrolytic cell for the
terminal of the next adjacent cell so generation of electric energy in which
that their voltages are cumulative. See the cell after being discharged may be
Parallel Connection. restored to a charged condition by an
electric current flowing in a direction
2 Shelf Life -- For a dry cell, the period of opposite the flow of current when the
time (measured from date of cell discharges. Synonym: Secondary
manufacture), at a storage temperature Cell. See Storage Battery.
of 21(C (69(F), after which the cell
retains a specified percentage (usually 2 Taper Charge -- A charge regime
90%) of its original energy content. delivering moderately high-rate
charging current when the battery is at
2 Short-Circuit Current -- That current a low state of charge and tapering the
delivered when a cell is short-circuited current to lower rates as the battery
(i.e., the positive and negative becomes more fully charged.
terminals are directly connected with a
low-resistance conductor). 2 Terminals -- The parts of a battery to
which the external electric circuit is
2 Starting-Lighting-Ignition (SLI) connected.
Battery -- A battery designed to start
internal combustion engines and to 2 Thermal Runaway -- A condition
power the electrical systems in whereby a cell on charge or discharge
automobiles when the engine is not will destroy itself through internal heat
running. SLI batteries can be used in generation caused by high overcharge
emergency lighting situations. or high rate of discharge or other
abusive conditions.
2 Stationary Battery -- A secondary battery
designed for use in a fixed location. 2 Trickle Charging -- A method of
recharging in which a secondary cell is
2 Storage Battery -- An assembly of either continuously or intermittently
identical cells in which the connected to a constant-current supply
electrochemical action is reversible so that maintains the cell in fully charged
that the battery may be recharged by condition.
passing a current through the cells in
the opposite direction to that of 2 Vent -- A normally sealed mechanism that
discharge. While many non-storage allows for the controlled escape of
batteries have a reversible process, gases from within a cell.
only those that are economically
rechargeable are classified as storage 2 Voltage, cutoff -- Voltage at the end of
batteries. Synonym: Accumulator; useful discharge. (See Voltage, end-
Secondary Battery. See Secondary point.)
Cell.
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9. Bibliography
American National Standard Specification for Design Note: Renewal Reusable Alkaline
Dry Cells and Batteries, American Batteries Applications and System
National Standards Institutes, Inc. Design Issues For Portable Electronic
ANSI C18.1M-1992. Equipment, Rayovac Corporation,
presented at: Portable by Design
Application Notes & Product Data Sheet: Conference, 1995.
Primary Batteries—Alkaline, Heavy
Duty & General Purpose, Rayovac Duracell Batteries Web Site,
Corporation, January 1996. http://www.duracell.com, August
1997.
Batteries Used with Law Enforcement
Communications Equipment: Chargers Easy to Choose, Easy to Use, Eveready
and Charging Techniques, W.W. Battery Corporation, 1997.
Scott, Jr., U.S. Department of Justice,
LESP-RPT-0202.00, June 1973. Encyclopedia of Physical Science and
Technology, Brooke Schumm, Jr.,
Batteries Used with Law Enforcement 1992.
Communications Equipment:
Comparison and Performance Eveready and the Environment, Eveready
Characteristics, R.L. Jesch and I.S. Battery Company, Inc., 1995.
Berry, U.S. Department of Justice,
LESP-RPT-0201.00, May 1972. Eveready Batteries Web Site,
http://www.eveready.com, August
Battery Engineering Web Site, 1997.
http://www.batteryeng.com, August
1997. Household Batteries and the Environment,
Rayovac Corporation, 1995.
Battery Selection & Care, Eveready Battery
Corporation, 1995. How to Choose, Use, Care For, and Dispose
of Batteries, Electronics Industries
Camcorder Battery Pocket Guide, Eveready Association Consumer Electronics
Battery Corporation, Inc., 1996. Group, 1992.
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