ATP | PT #1 Chemistry Questions

ATP | PT # 1
CHEMISTRY
Q.1) Which of the following compound can show geometrical as well as optical isomerism?
a) CH3CH(Me) CH2CH=CHCl
b*) Et CH(Me) CH2CH=CHCl
c) Et CH(Et) CH2CH=CH2
d) Et CH(Me) CH2CH=CH2
Q.2) Identify IUPAC name of the following compound?
a) 3-Chloro-4-Bromo Benzene carbonyl chloride

b*) 4-Bromo-3-Chloro Benzene carbonyl chloride
c) 4-Bromo-3-Chloro Benzoyl chloride
d) 3-chloro-4-Bromo Benzoyl chloride
Q.3) Identify the set of Acids having lower pKa value than C6H5COOH :
a) HCOOH, CH3CH2COOH, NO2CH2COOH
b*) CF3COOH, HCOOH, NC–CH2COOH
c) ,
d) (CH3)2CHCOOH, HCOOH
Q.4) Which of the following set of Bases are stronger than (CH3)3N in aqueous solution?
a) (CH3)2NH, C6H5NH2, CH3NH2
b*) (CH3)2NH, CH3NH2
c) C6H5NH2 only
d) N, N–Dimethyl aniline only
Q.5) Which of the following is optically active with configuration at asymmetric carbon? (if applicable)
a*) b) c) d)
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ATP | PT # 1
Q.6) Identify the most unstable compound at room temperature?
a)
b*)
c)
d)
Q.7) Which one of the following does not have sp hybridized carbon?
a) Allene (C3H4)
b*) 3-Butadiene
c) Acetylene
d) Benzonitrate
Q.8) Which of the following diene is thermodynamically most stable?
a)
b*)
c)
d)
Q.9) Which of the following compound is not resonance stabilized?

a) CO2
b*)
c) CO32–
d) Vinyl Alcohol
Q.10) Identify the compound have maximum enol forms (consider isomers separately).
a) b) c) d*)

ATP | PT # 1
Q.11) Which of the following element have highest Ionization energy?

2 1
a) [Ne]3s 3p
b*) [Ne]3s23p3
c) [Ne]3s23p2
10 2 3
d) [Ne]3d 4s 4p
Q.12) Which one of the following is not an amphoteric oxide?

a) ZnO
b) Al2O3
c) SnO2
d*) SO2
Q.13) Identify the correct set of Isoelectronic species?

a) N3–, F–, O
b) N, F–, O–2
c*) k+, Cl–, S–2
d) k, Cl–, S–2
Q.14) The correct order of Radii is :
a*) F  O2  N3 
b) k  Li  Na
c) B > Be > N
d) Fe3  Fe2  Fe4 
Q.15) In which of the following arrangement the order is not according to the property indicated against
it?
a) SO2 > P2O3 > SiO2 > Al2O3 (Acidic nature)
b) N > O > C > B (Ionisation potential)
c) k   Mg2   Al3  (Size)
d*) NH3  PH3  AOH3  SbH3 (Basic character)
Q.16) Which of the following is most acidic oxide?

a) ZnO
b) Na2O2
c*) P2O5
d) MgO

ATP | PT # 1
Q.17) Element “X” has most stable +2 oxidation state. Identify X :

a*) Pb
b) Fe
c) Sn
d) Ag
Q.18) The oxidation number of phosphorous in Ba(H2PO2)2 is :

a*) +1
b) +2
c) +3
d) –1
Q.19) Which of the following element has maximum number of atoms?

a) 108 gm of Ag-108
b) 56 gm of Fe-56
c*) 24 gm of C-12
d) 27 gm of Al-27
Q.20) Identify the correct order of energy of electrons with the following quantum numbers
Electron Q.Number
1 n = 5,  =1
2 n = 4,  =2
3 n = 5,  =0
4 n = 4,  =1
a) 172 > 4 > 3

b*) 173 > 2 > 4
c) 31 > 4 > 2
d) 472 > 3 > 1
Q.21) Which of the following statement is correct?

a) The magnetic quantum number may have a positive value
b) The oxidation state of nitrogen in NH3 is +3
c) Electrons in same orbital may have same spen.
d*) The electronic configuration of Cr is [Ar]3d54s1
Q.22) The radius of which of the following orbit is same as Ist Bohr’s orbit of Hydrogen atom?
a) He+ (n = 2)
b) Li2+ (n = 3)
2+
c) Li (n = 2)
d*) Be3+ (n = 2)

ATP | PT # 1
Q.23) The number of radial nodes of 4s and 3p orbitals are respectively :

a*) 3, 1 b) 1, 3 c) 3, 2 d) 2, 3
Q.24) If Vn = Potential energy of nth orbit

kn = Kinetic energy of nth orbit
En = Total energy of nth orbit
Vn
 x & Radius of nth orbit  Eny
kn
value of x & y respectively is :

a*) –2, –1 b) +2, –1 c) –1, +1 d) –2, +1
Q.25) Which of the reaction can define Hf ?
a) C(diamond) + O2(g)  CO2(g)

1 1
b*) H2(g) + F2(g)  HF(g)
2 2
c) N2(g) + 3H2(g)  2NH3(g)

1
d) CO(g) + O2(g)  CO2(g)
2
Q.26) In which of the chemical change

H  E
a) HCl + NaOH  NaCl

1
b) H2(g) + (g)  2 HI(g)
2
c) C(5) + O2(g)  CO2(g)
d*) N2(g) + 3H2(g)  2NH3(g)
Q.27) Consider the following reaction :
CO2(g) + H2(g)  CO(g) + H2O(g)
Find the standard enthalpy change of the reaction (in kJ) of Hf for CO2(g) CO(g) and H2O(g)
are –393.5, –110.5, –241.8 kJ mol–1 respectively.
a*) 41.2
b) –41.2
c) 524.1
d) –262.5

ATP | PT # 1
Q.28) The enthalpy of vaporization of liquid is 30 kJ mol–1 and entropy of vaporization is 75 J mol–1 k.
What is the boiling point of the liquid at 1 atm?
a) 250 k
b*) 400 k
c) 450 k
d) 600 k
Q.29) Consider the reaction


x 
y
Ho = –5407 kJ mol–1

–1 –1
So = 10 Jk mol
What is the value of log10k is T = 298 k
a*) 10
b) 95
c) 5
d) 100
Q.30) Identify the Intensive quantity among the following :

a) Enthalpy
b) Heat capacity
c) volume
d*) Temperature


ATP | PT #1 Chemistry Questions

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ATP | PT # 1

Q.2) Identify IUPAC name of the following compound?

a) 3-Chloro-4-Bromo Benzene carbonyl chloride

Corporate Office : Shakun Elegance, Jhalawar Road, Kota (Raj.)-324005

Q.6) Identify the most unstable compound at room temperature?

Q.8) Which of the following diene is thermodynamically most stable?

Q.9) Which of the following compound is not resonance stabilized?

Corporate Office : Shakun Elegance, Jhalawar Road, Kota (Raj.)-324005

Q.11) Which of the following element have highest Ionization energy?

Q.12) Which one of the following is not an amphoteric oxide?

Q.13) Identify the correct set of Isoelectronic species?

Q.14) The correct order of Radii is :

d) Fe3  Fe2  Fe4 

c) k   Mg2   Al3  (Size)

d*) NH3  PH3  AOH3  SbH3 (Basic character)

Q.16) Which of the following is most acidic oxide?

Corporate Office : Shakun Elegance, Jhalawar Road, Kota (Raj.)-324005

Q.17) Element “X” has most stable +2 oxidation state. Identify X :

Q.18) The oxidation number of phosphorous in Ba(H2PO2)2 is :

Q.19) Which of the following element has maximum number of atoms?

a) 172 > 4 > 3

Q.21) Which of the following statement is correct?

Corporate Office : Shakun Elegance, Jhalawar Road, Kota (Raj.)-324005

Q.23) The number of radial nodes of 4s and 3p orbitals are respectively :

Q.24) If Vn = Potential energy of nth orbit

value of x & y respectively is :

Q.25) Which of the reaction can define Hf ?

a) C(diamond) + O2(g)  CO2(g)

c) N2(g) + 3H2(g)  2NH3(g)

Q.26) In which of the chemical change

a) HCl + NaOH  NaCl

c) C(5) + O2(g)  CO2(g)

d*) N2(g) + 3H2(g)  2NH3(g)

Q.27) Consider the following reaction :

CO2(g) + H2(g)  CO(g) + H2O(g)

Corporate Office : Shakun Elegance, Jhalawar Road, Kota (Raj.)-324005

Q.29) Consider the reaction

Ho = –5407 kJ mol–1

Q.30) Identify the Intensive quantity among the following :

Corporate Office : Shakun Elegance, Jhalawar Road, Kota (Raj.)-324005

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