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SR #1 SR #1/LCO SR #2 SR #2/LCGO
˚API 33.27 27.73 34.44 33.63
Sulfur, wt.% 0.68 0.93 1.12 1.34
Nitrogen, wppm 120 293 127 249
Total Aromatics, vol.% 31.5 40.0 27.3 30.1
PNA’s (2-ring+), vol.% 10.7 21.9 9.5 10.8
ASTM Color L3.5 L6.5 L2.0 L5.5
Distillation (D2887), ˚F
IBP 275 265 222 238
10% 454 439 477 437
50% 580 565 613 579
90% 600 703 681 667
FBP 837 841 740 754
product color.
2.0
As might be expected, adding LCO
1.5 to the ULSD unit feed makes the
product color situation worse.
1.0 Figure 5 compares the product
color for the SR feed and the 30%
0.5
LCO feed at 2100 scfb H2/Oil ratio
and two pressures. The SR feed
0.0
results in acceptable color over the
680 690 700 710 720 730 740 750 760 770 wide range of temperatures for both
pressures shown. This compares
Temperature, ˚F
36 www.e-catalysts.com
with the 30% LCO feed which goes Figure 5
off color at about 730-740°F at 800 Comparison of Product Color for SR and 30% LCO
psig; and at 1200 psig the tempera-
ture can exceed 760°F before 4.0
reaching 2.5 ASTM color. This data 800 psig
3.5
demonstrates the significant impact SR
that pressure has on diesel product 3.0 LCO
color when processing feeds that
ASTM Color
contain LCO. 2.5 1200 psig
800 psig
1.5
As mentioned previously, it is gen-
erally accepted that product color
ASTM Color
ASTM Color
One approach which has been put
to commercial practice is to 2.0
increase quench to the bottom bed
of the hydrotreater. This accom- 1.5
plishes two things which are impor-
tant to maintaining a good environ- 1.0
ment for hydrogenation of PNA’s. It
reduces the outlet temperature and 0.5
helps to increase the outlet hydro-
0.0
gen partial pressure relative to no or 0.0 1.0 2.0 3.0 4.0 5.0
lower amounts of quench.
Product PNAs (3 rings+), vol.%
38 www.e-catalysts.com