JEE ADV. (2017) CHEMISTRY [XI- TOPICS QUESTIONS] SINGLE CORRECT TYPE Which of the following combination will produce H, gas ? (A) Zn metal and NaOH(aq) (B) Au metal and NaCN(aq) in the presence of air (C) Cumetal and conc. HNO, (D) Fe metal and cone. HNO, ‘The order of the oxidation state of the phosphorous atom in H,PO,, HjPO,, HPO, and H,P,0, is (A) H,PO, > H,P,0, > H.PO, > H,PO, (8) H,PO, > HPO, > H,PO, > H,P,0, (C)H,PO, > H,PO, > H,P,0, > H,PO, (D)H,PO, > H,PO, > H,PO, > H,P,0,, The standatd state Gibbs free energies of formation of C{graphite) and Cldiamond) at T = 298 K are A,G? [Claraphite)] = 0 kJ mot AG? [C{diamond)] = 2.9 kJ mol" ‘The standard state means that the pressure should be 1 bar, and substance should be pure ata given temperature. The conversion of graphite (Claraphite)] to diamond [Cidiamond)] reduces its volume by 2 x 10 m® mol. I (graphite) is converted to C{diamond) isothermally at T = 298 K, the pressure at which C(graphite) i in equilibrium with C(diamond), is {Useful information : 1J = 1 kgm®s; 1 Pa = 1kg ms; 1 bar = 10° Pal (A) 14501 bar (B) 29001 bar (C) 58001 bar (0) 1450 bar ‘The order of basicity among the following compounds is NH NH JL. DD a NH am iN 7) c ‘NH, NS/ un HN ‘NH (A) >> >I B)IV>I>l>t (C)l>WV>m>0 (D)V>t>0> i ONE OR MORE THAN ONE CORRECT An ideal gas is expanded from (p,, V;. T;) to (Pz. Vz, Tz) under different conditions. The comect statement(s) among the following is(are) (A) The work done on the gas is maximum when it is compressed ireversibly from (pp, V2) to (Py, V;) against constant pressure P, {B) The work done by the gas is less when it is expanded reversibly from V, to Vp under adiabatic conditions as compared to that when expanded reversibly from V, to V under isothermal conditions. (C) The change in internal energy ofthe gsi) 270 its expanded reversibly with T, itis expanded reversibly under adiabatic conditions with T, # Tp. {D) Ifthe expansion is carried out freely, itis simultaneously both isothermal as well as adiabatic. and (i) positive, if For a reaction taking place in a container in equilibrium with its surroundings, the effect of temperature on its equilibrium constant K in terms of change in entropy is described by (A) With inerease in temperature, the value of K for exothermic reaction decreases because the entropy change of the system is positive (B) With increase in temperature, the value of K for endothermic reaction increases because the unfavourable change in entropy of the surroundings decreases (C) With increase in temperature, the value of K for exothermic reaction decreases because the favourable change in entropy of the surroundings decreases (D) With increase in temperature, the value of K for endothermic reaction increases because the entropy change of the system is negative7. Theoption(s) with only amphoteric oxides is (are) (A) Cr,0,, CxO, SnO, PbO (B) NO, B,O,, PbO, SnO, {C) Cr,0,, BeO, SnO, Sn, (D) Zn0, AL,O,, PbO, PbO, 8. Amongthe following, the correct statement{s)is(are) (A) Al(CH,). has the three-centre two-electron bonds in its dimeric structure (B) AICI, has the three-cenire two-electron bonds in its dimeric structure (C) BH, has the three-centre two-electron bonds in its dimeric structure {D) The Lewis acidity of BCI, is greater than that of AICI, COMPREHENSION TYPE PARAGRAPH FOR Q.9 TO Q.10 The reaction of compound P with CH.MgBr (excess) in (C,H,),0 followed by addition of H,O gives Q. The compound Q on treatment with H,SO, at 0°C gives R. The reaction of R with CH,COCI in the presence of anhydrous AICI, in CH,CI, followed by treatment with H,O produces compund S. [Etin compound P is ethylgroup] (HO), COE 9. The reaction, Q to R and R to §, are ~ (A) Dehydration and Friedel-Crafts acylation (B) Friedel-Crafts alkylation, dehydration and Friedel-Crafts acylation, (C) Aromatic sulfonation and Friedel-Crafts acylation {D) Fridedel-Crafts alkylation and Friedel-Crafts acylation 10. The product $ is — HOS (HO). OUCH, a) (BHO) (OCH, OCH, (HO) CH, © 0) MATRIX MATCH TYPE Answer Q.11, Q.12 and Q.13 by appropriately matching the information given in the three columns of the following table. ‘The wave function, y, ;,, ia mathematical function whose value depends upon spherical polar coordinates (r 6, 6) of the electron and characterized by the quantum numbers n, [and m,. Here ris distance from nucleus, 0 is colatitude and (is azimuth. In the mathematical functions given in the Table, Z is atomic number and a, is Bohr radius,‘Column T Column 2 Column 3 @ _ Isorbital @ Fam ?P) ef a s e 2 0 tla > TH Beorbial TH One radi node TO) Probabiliy densiyat nucleus oe 4. a Ti 2p, orbital WW Yam Ri Probability density B wa {2) maximum at nucleus -(2) 1) e080 TW) Siz ombta | We) xy-plane isa nodal plane | (6) Energy needed to excite election from n = 2state to 4state is 22 times the energy needed to excite election from n = 2 state to n= 6state 11. _Forthe given oribtal in Coumn 1, the only CORRECT combination for any hydrogenlike species is (A) IV) iv) (R) (B) ll (i) P) (C) at Gi) (P) ()() (a(S) 12. ForHe* ion, the only INCORRECT combination is (a) a) (Q) Boas) OnaR (©) Gi) (RY 13. Forhydrogen atom, the only CORRECT combination is (a) (1) (iv) (R) BP) (Ca) GQ ©) 1S) Answer Q.14, Q.15 and Q.16 by appropriately matching the information given in the three columns of the following table. Columns 1, 2 and 3 contain starting materials, reaction conditions, and type of reactions, respectively. ‘Column 1 Column 2 (Column 3 (Toluene ()_NeOH/Br, (P) Condensation (i) Acetophenone _| (i) Br, /hu (Q) Carboxylation (lll) Benzaldehyde | (ili) _(CH,CO),0 | CH,COOK_| (R) Substitution (IV) Phenol (iv) NaOH / CO; (S) Haloform. 14. _Forthe synthesis of benzoic acid, the only CORRECT combination is (A) (Ill) (iv) (R) (B) (IV) (i) (P) {C) (1) (iv) (Q) (D) (Ml) (i) (S) 15. The only CORRECT combination in which the reaction proceeds through radical mechanism is (a) () Gi) R) (B) (i) (i) R) (C) At (i) (P) (DAV) 6) (Q 16. The only CORRECT combination that gives two different carboxylic acids is (A) QV) (il) (Q) (B) (ll) (ii) (P) (©) Ge) R) OM aS)