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i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 2 ( 2 0 1 7 ) 1 9 4 9 6 e1 9 5 0 3

Available online at www.sciencedirect.com

ScienceDirect

journal homepage: www.elsevier.com/locate/he

Battery dynamic energy model for use in electric


vehicle simulation

Kawtar Benabdelaziz*, Mohammed Maaroufi


Department of Electrical Engineering, Mohammed V University, Mohammadia School of Engineers, Rabat, Morocco

article info abstract

Article history: The majority of work carried out around battery models is partly motivated by vehicle
Received 27 February 2017 simulation. Specifically, for electric vehicle simulation, some characteristics of the battery
Received in revised form require more attention while others can be simplified, thus distinguishing dynamic models
20 May 2017 for battery system simulation slightly and requiring different tools. In this paper, we
Accepted 22 May 2017 propose a dynamic battery model that accounts for changes in temperature and can be
Available online 12 June 2017 integrated in electric vehicle simulation for testing purposes by computer simulation.
Possibilities shown open the door for extensions of the model according to the needs, using
Keywords: the bond graph formalism and Matlab/Simulink. Comparison with other literature data
Dynamic model and experiment made on electric vehicle show the accuracy and the efficiency of this
Batteries approach.
Bond graph © 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Matlab Simulink
Electric vehicle
Simulation

the development of hybrid-electric vehicle applications. In-


Introduction vehicle testing of battery packs can be lengthy and expen-
sive: this is where simulation comes into play. It allows us to
Interest in electric vehicles has grown in recent years as a predict the behavior of the system under several operating
solution for reducing CO2 emissions and fossil energy conditions and reduce the number of tests to provide an
dependence. Automakers are therefore seizing this new analysis for a battery pack in real world driving conditions.
market and offering more efficient but considerably more Several battery models exist in the literature, ranging from
expensive models. These costs are directly related to battery electrochemical models to fully electrical models and several
technology, which alone accounts for 1/3 of the cost of the combinations of different methods. Shafiei, Momeni, and
vehicle [1,2]. Batteries in fact have a limited lifetime which Williamson [3] summarize and categorize different battery
makes their use subject to many constraints. Several factors models with focus on vehicular applications: electrochemical
come into play in this issue: temperature, charge/discharge, models, stochastic models, analytical models, electrical cir-
number of charge/discharge cycles, driver behavior, etc. cuit models (Thevenin-based models, impedance-based
Simulating and validating the performance envelope of models and runtime-based models.) We can group the
advanced battery packs for electric vehicles is important for

* Corresponding author.
E-mail addresses: kawtarbenabdelaziz@gmail.com (K. Benabdelaziz), Maaroufi@emi.ac.ma (M. Maaroufi).
http://dx.doi.org/10.1016/j.ijhydene.2017.05.165
0360-3199/© 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 2 ( 2 0 1 7 ) 1 9 4 9 6 e1 9 5 0 3 19497

models into three main categories: electrochemical, mathe-


matical and electrical. Electrochemical models are widely Background
used for optimizing the design of the electrodes and the
electrolyte as they deal with chemical reactions at the Representing the inner interactions within a battery in the
microscopic level of the battery cell. The challenge is the form of an electrical network has been commonly used by
models' slow computation time as it involves differential many researchers. Ceraolo [11] proposes a third-order model
equations, complex nonlinear and specific information on the formulation and a particular implementation that shows a
chemical properties of the battery which requires long and good compromise between complexity and accuracy, a dy-
difficult investigation to obtain. namic battery model lead using modeling equivalent circuits.
Mathematical models use mathematical methods such as This approach allowing for the output variables satisfactory
stochastic approach or empirical equations to predict system system has been widely studied in the literature. However, it
behavior levels in terms of efficiency, capacity or autonomy does not allow to analyze the effects on the different chemical
which are needed by battery designers. The downside of these components of the battery. Another example is the work of
abstract models is that they do not provide currentevoltage Lijun Gao, Shengyi Liu, and Roger A. Dougal [12] who propose a
information for the battery which is important for simulation model coded according to the resistive companion method. It
and optimization. The results are inaccurate with an error approximates all electro-chemical and electro-thermal pro-
margin between 5% and 20%. cesses as uniform throughout the entire battery and ignores
Electric models on the other hand have a lower error all spatial variations of concentrations, phase distributions
margin of 1% up to 5%. They juggle between electrochemical and potentials. It is coded specifically for use in the Virtual
and mathematical models using equivalent electrical models Test Bed computational environment. The model deviates
and by combining the sources of voltage, resistance and ca- from the experimental data at low temperatures and at high
pacity. These models are more intuitive for electricians, discharge rates, using mostly discharge data; and its validity
practical and easy to handle and implement in circuit simu- for representing charging processes is unknown. Additionally,
Chen and Rinco  n-Mora [13] create a simplified extracted
lation. Many models exist that can be divided into three main
groups: The Thevenin models, impedance models and per- electrical battery model ignoring self-discharge, cycle num-
formance models. ber, and temperature to predict runtime and IeV perfor-
The Thevenin model assumes that the open-circuit mance. In other work by Mischie and Stoiciu [14] the dynamic
voltage is constant and the battery is modeled as a series model takes into account the changes in the received or
combination of the voltage source, a series resistance, and a delivered battery current.
parallel combination of a capacitor and a resistor. The same Regarding the electric vehicle application, Tremblay, Des-
is for the impedance based models. The Impedance spec- saint, and Dekkiche [15] developed a battery model that can be
troscopy is used to fit a complicated equivalent network to applied to dynamic simulation software. The simulation
measured impedance spectra in order to validate the time model uses only the battery state-of-charge (SOC) as a state
constants found in the Thevenin models. Increasing the variable in order to avoid the algebraic loop problem on
number of parallel RC networks can increase the accuracy of simulation tools. Kroeze and Krein [5], on the other hand,
the predicted battery response but prediction errors for present a multiple time-constant battery model for use in
estimating run time and SOC tend to be high. These models dynamic electric vehicle simulations for predicting SOC, ter-
are then accurate only for a fixed SOC and temperature minal voltage, and power losses of different type of batteries.
setting [4]. So did Erdinc, Vural and Uzunoglu [6] with their dynamic
In Runtime-based electrical models, the continuous or model of lithium-ion battery developed with MATLAB/Simu-
discrete-time implementations are used to simulate battery link and that allows to observe the changes in battery terminal
runtime and dc voltage response in SPICE-compatible simu- output voltage under different charging/discharging, tem-
lations for constant current discharges. But as the load cur- perature and cycling conditions. In Ref. [5], the battery ter-
rents vary, inaccuracy increases [5]. minal voltage variation was calculated by taking into account
In most cases it is a combination of these three that pro- transient and steady state behavior of internal resistance of
vides a model that brings together the advantages of each the battery with respect to SOC for a dynamic battery model
[5e7]. Most of the work carried out around power system for hybrid vehicles.
simulation use electric models whether for fuel cell, super- In this work, we focus on electrical dynamic models.
capacitor, lead-acid or lithium ion batteries [8e10]. Instead of considering the individual components of the
Based on all the literature presented in the upcoming battery or only its behavior as seen from the terminals, a
section, the work detailed in this paper is the development of different approach is adopted that consists of modeling the
a dynamic model of a traction battery for the simulation of energy flow absorbed and delivered by the battery. This
hybrid-electric vehicles. A dynamic simulation is set up to model will not only analyze the electrical and thermal
verify the performance of the developed battery model and behavior of the battery during charging and discharging, but
the results of simulations carried out to observe changes in can also be integrated later in as an independent block on a
battery output characteristics under different charging/dis- hybrid-electric vehicle dynamic model to be assembled in
charging, temperature and cycling conditions. Finally, a the desired configuration and will assist with appropriate
comparison with data obtained by several studies realized by design of the battery in vehicle operation and system
different authors will validate the model. analysis.
19498 i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 2 ( 2 0 1 7 ) 1 9 4 9 6 e1 9 5 0 3

connected to create an electric generator. These cells consist


Simulation tools essentially of a current collector, a separator, an electrolyte in
which are immersed two electrodes: a negative electrode
The bond graph representation was first devised by Henry M. (anode) and a positive electrode (cathode). The electrical po-
Paytner in the 1960s and further developed by Karnopp, tential is produced by redox reactions between the cathode
Rosenberg and Thoma [16]. It is now widely used in the field of and the anode. Indeed, during these reaction, there is an ex-
mechatronics and by several major companies: PSA, EDF, change of electrons between the two electrodes.
Thomson, CEA, Renault, Ford, Toyota, General Motors, etc. When a load is applied through the electrodes, an electric
The bond graph is a graphical tool of power transfer within a current (im) responsible for the voltage (Ubat) is established
system. The power and energy being factors common to all areas, which creates the chemical modification responsible for the
it can be applied to any field of physics whether linear, nonlinear, potential difference. This is the discharge process. During this
continuous, sampled, digital, electronic, hydraulic, mechanical, discharge the positive electrode undergoes reduction: it con-
thermal etc. and makes possible the interaction between them. sumes the electrons released by the negative electrode. Dur-
The major interest in the use of bond graphs is the repre- ing charge the reverse occurs. The electrolyte acts as the
sentation of energy transfer and thereafter the extraction of internal circuit that allows ions to move. The current collector
mathematical model. It is a complement to conventional serves to conduct current between the electrodes and the
methods that allows the acquisition of qualitative and quan- separator, when the electrolyte is solid, prevents the elec-
titative information about the energy aspect of the system. trodes from touching to avoid creating a short circuit [20].
The use of bond graphs in modeling traction batteries fo- The proposed model is illustrated in Fig. 1. The aim is to
cuses on mechanisms of energy generation, storage, and build a battery block that highlights the energy interaction
dissipation [10e14]. The first significant instance was by Kar- between the battery and the external world according to the
nopp [13] in a study of electrochemical energy storage, internal interactions and its parameters. As shown in Fig. 1,
modeled using the bond graph technique. All these models the battery exchanges thermal and electrical energy with
combine between the electrical and electrochemical models other system by means of temperature, voltage and charging/
as a bond graph is the simplest tool to represent different discharging current. On the other hand, the entropy flow ds/dt
areas of physics. It also allows the integration of the model is directly related with the open-circuit voltage Em0 of the
into other more complex and multidisciplinary ones such as battery. From the combination of bond graph with dynamic
vehicles with all the components, namely, engine, clutch, gear equation, it is possible to extract several pieces of information
box, chassis, and power system. Chemical reactions of the including parasitic voltage and current, temperature of the
battery can be converted into forms of resistances and ca- electrolyte (T), state of charge (SOC) and depth of charge
pacity, the electric model remains the most appropriate and (DOC).
simplest to analyze electrical properties of the battery. The model of Thevenin improved and the equivalent bond
Simulink, an extension of Matlab software, is used exten- graph presented in Fig. 2 include a parasitic branch with a
sively in academia and industry to represent mathematical resistance Rp, an internal resistance R2 and a capacitor Ce in
functions in the form of diagram blocks. Although other soft- series with the voltage source.
ware is available to directly use bond graphs, Simulink is more
appealing when it comes to in depth analysis of the physical Model parameters formulation
and dynamic concepts that are involved in the system.
The method to go from Bond graph to MATLAB/Simulink The use of the bond graph method allows to ignore the
for mechanical and electrical systems is detailed in Refs. mathematical equations and to focus only on elements that
[17,18]. It is also possible to use the bond graph library in govern the links between the components. To find the
Simulink as stated in Ref. [19] but we opted for the detailed analytical functions able to reproduce the typical behavior of
method in order to retrieve and view the parameters of in- the elements of Fig. 2, a large amount of lead-acid battery data
terest as needed for the simulation. have been processed to be computed based on experimental
battery tests in Ref. [11]. Based on the electric equivalent

Modeling and representation of the battery

To model the battery, it is essential to understand its energy


behavior. Dissipative phenomena and the particular behavior
related to internal chemical energy storage must be taken into
account.
This will lead to the bond graph based electrical model
using nonlinear equation to translate the electrochemical
reactions.

Building the bond graph model

A battery is an electrochemical cell assembly that converts


stored chemical energy into electrical energy. The cells are Fig. 1 e Block diagram of the battery model.
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The temperature of the electrolyte changes from one point


to another. However, an average can be regarded according to
the following equation:

T ¼ Ps Rt þ Ta =1 þ Rt Ct (6)

where Ct is the battery thermal capacitance Rt is thermal


resistance between the battery and its environment, Ta is the
ambient temperature, Ps is source thermal power, i.e., the heat
that is generated internally in the battery.
Fig. 2 e Electrical representation and its corresponding
As for the SOC, it is an indicator of the maximum capacity
bond graph.
that the battery is able to deliver at a given temperature while
the DOC (depth of charge) indicate the actual value of the
chosen in this paper, these analytical functions are reported in constant discharge current I, both expressed in percentage:
this paragraph. .
The main reversible cell reaction is represented by the SOC ¼ 1  Q e C0 ð1  T=TF ÞE
h   * d i. (7)
main branch which contains the electromotive force Em. The DOC ¼ 1  Q e 1 þ ðKc  1Þ im i C0 ð1  T=TF ÞE
OCV (open-circuit voltage) Em0 between the two electrodes of a
battery is also called electromotive force. The voltage of the We define causality as the causal relationship that con-
battery does not have a linear behavior but depends on the nects the two components A and B (see Fig. 4) [22]. Once
temperature T of the electrolyte and the battery state of defined causality (Fig. 5), we can extract the mathematical
charge SOC as shown on Eq. (1): relations systems as shown in Figs. 3 and 6.

Em ¼ Em0  KE ð273 þ TÞð1  SOCÞ (1) From bond graph to simulink


During the charging process, the stored load Qe is the in-
tegral of the charging current entering the battery: Now that the bond graph and mathematical model have been
built, expanding the block diagram model will be following the
Z
Q e ðtÞ ¼ im ðtÞ dt (2) logic established in Ref. [16].
The first step is to set the output/input systems according
Side reactions inside the battery are represented by the to affected causalities. For example, a causality derived
parasitic current ip depending on both internal and external
temperatures of the battery and where TF is the electrolyte
freezing temperature, VPN, GP0,VP0 and AP are constant for a
particular battery referring to the parasitic reaction branch
of the electric equivalent. The exponential term in this
equation gives an idea of the nonlinear character of the
behavior of the battery that matches the Tafel gas-
singecurrent relationship:
 
ip ¼ VPN Gp0 exp VPN =VP0 þ Ap ð1  T=TF Þ (3)

The impedance of the battery, the results of chemical re-


actions that induce the electrochemical double layer phe-
nomenon and diffusion phenomena and ohmic losses [21] are
represented by the terms C1 and R1 parallel and R0. They
simulate the dynamic behavior of the battery and which de-
pends on the state of charge of the battery, the temperature of
the electrolyte and constants parameters referring to the main
branch of the electric equivalent:

R0 ¼ R00 ½1 þ A0 ð1  SOCÞ
R1 ¼ R10 lnðDOCÞ (4)
C1 ¼ t1 =R1
Fig. 3 e Detailed bond graph representation.
The storage of energy within the battery is represented by
the total battery capacity Ce and R2 which are a function of
discharge current and temperature of the electrolyte T, the
electrolyte freezing temperature TF and the parameters of the
battery Kc, Ke and C0.
   
R2 ¼ R20 exp½A21 ð1  SOCÞ
. 1 þ exp A22 Im I*
(5)
Ce ¼ C0 Kc ð1  T=TF ÞE Ke T Fig. 4 e How the bond graph causality translated into
simulink block.
19500 i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 2 ( 2 0 1 7 ) 1 9 4 9 6 e1 9 5 0 3

Table 1 e Parameters referring to the battery thermal


model.
Parameters Value
CT 12 kJ/ C
RT 1.1  C/W

Table 2 e Parameters referring to the main electric branch


of the battery.
Parameters Value
Em0 2.165 V
KE 0.782 mV/ C
R00 1.810 mU
Fig. 5 e Effort and flux direction according to the causality. R10 0.386 mU
A0 0.056
R20 15 mU
A21 8

Table 3 e Parameters referring to the parasitic reaction


branch.
Parameters Value
Ep 1.95 V
Vp0 0.1
Ap 2

Table 4 e Parameters referring to the battery capacity.


Parameters Value
C0 404.7 Ah
Kc 1.098
Fig. 6 e Simulink block corresponding to the bond graph TF 35  C
E 0.468
battery representation.
d 1.8

resistance will be entered as the flux and output effort ac-


cording to the relationship e ¼ f*B. electrical systems with batteries by the implementation of the
Secondly, we expand all the links in flux signal and bilat- third-order model. The behavior of the proposed models is
eral effort linked by junctions 0 and 1 (Fig. 5). Junction 0 will be compared with results obtained with extensive lab tests on
modeled by a summation element for the flow and a node to different types of batteries. Some of the parameters can be
distribute the effort. Junction 1 is represented by a signal-node taken as constant for all the batteries built with the same
for the flows and a summation for the efforts. The sign in technology. Also, Ceraolo results have been concluded under a
equations depend on the direction of the arrow. At this point, constant electrolyte temperature while in this paper, the
we obtain a readily transposable complete block diagram in evolution of the electrolyte temperature under different
Simulink bypassing the creation of a specific library. The charging current will be shown.
causal model of the battery and the corresponding Simulink Simulation results are obtained by the implementation of
model is shown in Figs. 5 and 6. the model in Fig. 6 on MATLAB/Simulink. The Matlab/Simu-
link model obtained by the bond graph method is shown on
Fig. 7. The digital experience offered in this section is intended
Simulation and results to analyze the battery performance during the charging or
discharging under conditions of different temperatures.
To validate the dynamic model of the battery, we compare the
results with those in Ref. [11] using the same parameters of Discharge and charge of the battery
the battery (see Tables 1e4) and with applying the same
voltage and current for both charge and discharge. We apply a discharge voltage 1.75 V and 58 A of load current
The work Carried out by Massimo Ceraolo in Ref. [11] is for a period of 8.6 h followed by a period when the current is
about modeling the electrochemical batteries for the use of zero on a battery whose characteristics are listed in Tables 1e4
the electrical engineer, in particular for the analysis of The result of simulating the discharge of a fully charged
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Fig. 7 e Matlab/Simulink model obtained by bond graph method.

battery under a temperature of 18  C in Fig. 8 is close to that


obtained in Ref. [11] under an unknown temperature.
When charging, the simulation results obtained in Fig. 9
are similar the results obtained in Ref. [11] during a charging

Fig. 8 e Battery voltage response curve during discharging


condition: simulation results of the proposed model
(points), simulation results and measured data given in
Ref. [11] (line).

Fig. 9 e Battery voltage response curve during charging


condition: simulation results of the proposed model (dash), Fig. 10 e The change in battery during discharging process
simulation results and measured data given in Ref. [11] at different temperatures. (a) Battery voltage change (b)
(line). State of charge change.
19502 i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 2 ( 2 0 1 7 ) 1 9 4 9 6 e1 9 5 0 3

Fig. 11 e Temperature of the electrolyte versus SOC for an Fig. 13 e Variation of the temperature of the electrolyte
ambient temperature of 18  C. under different charging current.

process of the fully discharged battery with a current of Table 5 e Specifications of the electric vehicle battery.
53 Amps.
Parameters Value

Effect of temperature and charging current Battery voltage 400 V


Number of cells 192
Number of modules 12
We tested the response of the battery at different tempera-
Capacity 26 kWh
tures. The results of this simulation are shown in Fig. 10. For Material Lithium ion
the same battery subjected to different temperatures (0, 18
and 60  C), the same power and the same discharge current
followed by a period where the current is zero, we obtained
different results of output voltage and charging status.
The influence of the ambient temperature on the battery is
clearly in evidence. In Fig. 10 we notice that the battery sub-
jected to very low temperatures (0  C) discharges faster than a
battery subjected to a temperature of 60  C the more deeply a
battery discharges, the faster it ages [20]. Fig. 11 shows the
electrolyte temperature rise while the battery is charging.
Fig. 12 illustrates the rise of the electrolyte temperature while
the battery is charged at a current of 53 A. We observe that for
a cold temperature (0  C), the temperature rise rapidly. On the
other hand, a high charging current, even if it helps to rapidly
Fig. 14 e Comparison of simulated and measured
charge the battery, compromises the battery's health or
temperature of the electrolyte during charge under a
soundness regarding the quick rise of temperature as seen in
constant ambient temperature.
Fig. 13.
We also conducted a first draft experiment on an electric
vehicle batteries. The electric vehicle is powered by a 26 kWh the model simulation to the new parameters shown in Table 5
battery and we used an On Board Diagnostics tool that we and compared the simulation results to the data acquisition.
connected to the vehicle to extract the values of the temper- The ambient temperature has been kept constant by charging
ature of the electrolyte during the charge process. We adapted the vehicle indoor. The model is checked during the charge
process. The comparison of measured and simulated voltage
for a 32 A charge (at a 22 kW charging station for the vehicle)
and its effect on the electrolyte temperature is shown in
Fig. 14.

Conclusion

By combining electrical modeling and the bond graph method,


the complex and nonlinear behavior of a battery has been
developed. The objective of this paper was to propose a simple
yet effective model that can be easily integrated to vehicle
simulation and highlights the most important variation in
Fig. 12 e Variation of the temperature of the electrolyte battery parameters, specially the electrolyte temperature. Our
under different ambient temperatures. contribution has allowed us to exploit advantages of both
i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 2 ( 2 0 1 7 ) 1 9 4 9 6 e1 9 5 0 3 19503

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