1.

A capacitor is charged by using a battery, which is then C

disconnected. A dielectric slab is then slided between the
plates which results in:
Reduction of charge on the plates and increase of potential
difference across the plates
Increase in the potential difference across the plates,
Reduction in stored energy, but no change in the charge on
the plates
Decrease in the potential difference across the plates,
reduction in stored energy, but no change in the charge on the
plates
None of the above
2. A capacitor is connected across another charged capacitor. B
The energy in the two capacitors will:
Be equal to the energy in the initial capacitor
Be less than that in the initial capacitor
Be more than that in the initial capacitor
Be more or less depending on the relative capacities of the
two capacitors
3. A dielectric K1 and K2 are filled between the plates of a A
capacitor as shown in figure. The capacity of the system is:

20 A(K1K 2 )
(K1  K 2 )d
0 A  (K 1  K 2 ) 
d  2 
0 AK1 K 2
(K1  K 2 )d
0 A
(K1  K 2 )
d
4. In the arrangement of capacitors shown in figure. The C
capacitors are initially uncharged and now are connected with
switch S open. Find the potential of point b and the amount
of charge flowing through the switch, when it is closed.
 66.7 V, 300 C
66.7 V, 400 C
100 V, 300 C
133.3 V, 400 C
5. Two identical capacitors A and B shown in the given circuit B
are joined in series with a battery. If a dielectric slab of
dielectric constant K is slipped between the plates of
capacitor B and battery remains connected, then the energy to
capacitor A will:

Decrease
Increase
Remain the same
Be zero since circuit will not work
6. You have a parallel plate capacitor, a spherical capacitor and C
a cylindrical capacitor. Each capacitor is charged by and then
removed from the same battery. Consider the following
situations.
(i) Separation between the plates of parallel plate capacitor is
reduced
(ii) Radius of the outer spherical shell of the spherical
capacitor is increased
(iii) Radius of the outer cylinder of cylindrical capacitor is
increased
Which of the following is correct?
In each of these situations (i), (ii) and (iii), charge on the
given capacitor remains the same and potential difference
across it also remains the same
In each of these situations (i), (ii) and (iii), charge on the
given capacitor remains the same but potential difference, in
situations (i) and (iii), decreases and in situation (ii),
 increases
In each of these situations (i), (ii) and (iii), charge on the
given capacitor remains the same but potential difference, in
situation (i) decreases and in situations (ii) and (iii), increases
Charge on the capacitor in each situation changes. It
increases in all these situations but potential difference
remains the same
7. Capacity of a parallel plate air capacitor is 5 F. If dielectric C
materials are filled between the plates as shown in figure.
The new capacitance will be:

16.4 F
18.6 F
14.2 F
10.8 F
8. Figure shows four identical metal plates, each of area A. The A
plates are placed at equal distance ‘d’ successively. If
0 A
 4F and a source of emf 10 V is connected between x
d
and y:

Charge on plate x will be + 60 C and that on plate

A  20C
Charge on plate A will be 20 C and that on plate
B  20C
Charge on plate y will be 40C and that on plate B  20C
 Charge on plate y will be 60 C and that on plate A  40C
9. In figure the capacitor is initially uncharged. Area of each C
plate is A and initial separation between plates ‘a’. Plate 2 of
the capacitor is fixed while plate 1 is connected to the spring
as shown. The capacitor is now connected across a source of
potential difference V. As a result, separation between the
plates becomes ‘b’. Spring constant of the spring can be
expressed as:

0 AV
2b(a  b)
0 AV 2
2b(a  b)
0 AV 2
2b2 (a  b)
0 AV
2
b (a  b)
10. Six capacitors each of capacitance of 2 F are connected as A
shown in the figure. The effective capacitance between A and
B is:

12 F
8/3 F
3 F
6 F
11. Equivalent capacitance between X and Y points in the given B
(shown in figure):
 2 F
4 F
3 F
1F
12. Given a number of capacitors labeled as C, V. Find the D
minimum number of capacitors needed to get an arrangement
equivalent to Cnet ,Vnet:
2
C net Vnet
n  2
C V
C V2
n  2
C net Vnet
C V
n 
C net Vnet
C net Vnet
n 
C V
13. n conducting plates are placed face to face. Distance between A
two consecutive plates is d. Area of plates is
A A A  1 
A, , , ,..... n 1  A. A dielectric slab of dielectric
2 4 8 2 
constant k is inserted between the first and second plates and
the assembly is charged by a battery of emf  . Find the
charge stored in the assembly.
 0 A
1 
2d   2 n 1  2 
k 
0 A
1 
2d   2n 1  1
k 
0 A
1 
d   2 n 1  2 
k 
0 A
1 
3d   2n 1  2 
k 
14. A 2F capacitor is charged as shown in the figure. The D
percentage of its stored energy dissipated after the switch S is
turned to position 2 is:

0%
20%
75%
80%
15. Resistances of 6 each are connected in the manner shown C
in figure. The PD between points P and Q is:
 3.6 V
6.0 V
3.0 V
7.2 V
16. The resistances 500 and 1000 are connected in series C
with a battery of 1.5 volt. The voltage across the 1000
resistance is measured by a voltmeter having a resistance of
1000 . The reading in the voltmeter would be:

1.5 volt
1.0 volt
0.75 volt
0.5 volt
17. In the circuit shown in figure. Find the maximum energy D
stored on the capacitor. Initially, the capacitor was
uncharged.

150 C
100 C
50 C
Zero
18. In the circuit shown in figure, A is an ideal ammeter C
current is 1.5 A. If the component PQ is a resistance,
potential difference between P and Q is:
 18.5 V
15.5 V
13.5 V
9.5 V
19. In the circuit in figure, the ammeter reads a current: B

1A
2A
0.3 A
0.2 A
20. In figure. B

There is no current in the section acb

Current in the section acb passes along a  c  b
Current in the section acb passes along b  c  a
Sense of current in the section acb cannot be determined
21. A pendulum consists of a wooden bob of mass m and length B
l. A bullet of mass m1 is fired towards the pendulum with a
v
speec v1 and it emerges from the bob with speed 1 . The bob
3
just completes motion along a vertical circle. The v1 is:
 m
5gl
m1
3m
5gl
2m1
2 m 
  5gl
3  m1 
 m1 
  gl
m
22. Two blocks A and B of mass m and 2m are connected B
together by a light spring of stiffness k. The system is lying
on a smooth horizontal surface with the block A in contact
with a fixed vertical wall as shown in the figure. The block B
is pressed towards the wall by a distance x0 and then released.
There is no friction anywhere. If spring takes time t to
acquire its natural length then average force on the block A
by the wall is

Zero
2mk
x0
t
mk
x0
t
3mk
x0
t
23. A ball of mass 1 kg is suspended by an inextensible string 1m B
long attached to a point O of a smooth horizontal bar resting
on fixed smooth supports A and B. The ball is released from
 rest from the position when the string makes an angle 30 o
with the vertical. The mass of the bar is 4 kg. The
displacement of bar when ball reaches the other extreme
position (in m) is

0.4
0.2
0.25
0.5
24. Two identical balls of equal masses A and B, are lying on a B
smooth surface as shown in the figure. Ball A hits the ball B
(which is at rest) with a velocity v = 16 ms -1. What should be
the minimum value of coefficient of restitution e between A
and B so that B just reaches the highest point of inclined
plane? (g = 10 ms-2)

2
3
1
4
1
2
1
3
25. Particle A makes a head on elastic collision with another A
stationary particle B. They fly apart in opposite directions
with equal speeds. The mass ratio will be
1
3
1
2
1
4
 2
3
26. A particle of mass 4m which is at rest explodes into four A
equal fragments. All four fragments scattered in the same
horizontal plane. Three fragments are found to move with
velocity v as shown in the figure. The total energy released in
the process is

mv 2 (3  2)
1 2
mv (3  2)
2
2mv 2
1 2
mv (1  2)
2
27. A body of mass m is dropped from a height of h. D
Simultaneously another body of mass 2m is thrown up
h
vertically with such a velocity v that they collide at height .
2
If the collision is perfectly inelastic, the velocity of combined
mass at the time of collision with the ground will be
5gh
4
gh
gh
4
None of these
28. A man is standing on a cart of mass double the mass of man. D
Initially cart is at rest. Now, man jumps horizontally with
velocity u relative to cart. Then work done by man during the
process of jumping will be
 mu 2
2
3mu 2
4
mu 2
None of these
29. A particle of mass m and momentum p moves on a smooth C
horizontal table and collides directly and elastically with a
similar particle (of mass m) having momentum 2 p. The
loss () or gain (+) in the kinetic energy of the first particle
in the collision is
p2

2m
p2

4m
p2

4m
Zero
30. A particle of mass m0, travelling at speed v0, strikes a B
stationary particle of mass 2m0. As a result the particle of
mass m0 is deflected through 45o and has a final speed of
v0
. Then the speed of the particle of mass 2m0 after this
2
collision is
v0
2
v0
2 2
2v 0
v0
2
31. Which of the following is not a valid resonating structure? C
32. Which of the following resonating structure is most stable? D

33. Correct order of stability of carbocation is: C

I > II > III > IV

I > II > IV > III
II > I > III > IV
II > I > IV > III
34. Correct order of heat of hydrogenation for following compound : D

1<2<3<4
2<3<1<4
4<2<3<1
4<3<2<1
35. Order of stability of following carbocation: A
 C>B>A
A>B>C
B>C>A
C>A>B
36. Arrange the following in increasing order of acid strength : D

c<f<d<a<b<e
f<d<c<b<e<a
f<c<d<b<e<a
c<d<f<a<b<e
37. Which of the following compound is aromatic? A

All of these
38. A

chain isomers
positional isomers
both (A) and (B)
None of these
39. Minimum C atoms required for a compound to show geometrical D
isomerims:
2
3
4
None of these
40. B

Configuration of both the double bond in this compound respectively are:

2E 4E
2E 4Z
2Z 4E
2Z 4Z
41. B

functional isomers
Metamers
positional isomers
chain isomers
42. Which of the following is a meso compound? B

All of these
43. In which of the following, electron withdrawing hyperconjugation B
decreases electron density of the phenyl ring?
44. Which is the most stabilised carbocation? B

45. How may hyperconjugation structures are possible for the following C
carbocation?

5
6
7
8
46. A

Among these compound which of the following is the correct order of

their heats of hydrogenation?
I > II > III
III > II > I
II > I > III
II > III > I
47. For the reaction 3A  Products the value of k = 1 × 10–3 L/(mol–min) C
 d [A]
the value of  in mol/L-sec when [A] = 2 M is:
dt
6.67 × 10–3
1.2 × 10–2
2 × 10–4
4 × 10–3
48. The rate constant for the reaction, D
2N 2O5   4NO 2  O 2
is 3 × 10–5 s–1. If the rate is 2.4 × 10–5 mol L–1 s–1, then the concentration
of N2O5 (in mol L–1) is :
1.4
1.2
0.04
0.8
49. Propanone reacts will iodine in acid solution as shown in this equation. D

H
CH3C(O)CH3  I 2   CH3C(O)CH 2 I  HI
These data were obtained when the reaction was studied.

What is the rate equation for the reaction?

Rate = k [CH3C(O)CH3] [I2]
Rate = k [CH3C(O)CH3]2
Rate = k [CH3C(O)CH3] [I2] [H+]
Rate = k [CH3C(O)CH3] [H+]
50. A and B react as per the reaction : B
A(g)  2B(g)   C(g)
From the data given below identify the Rate Law.

R = K[A]2[B]1
R = K [A] [B]
R = K [A]1 [B]0
R = K [A] [B]–1
51. The rate law for a certain reaction is found to be : D
2
Rate = k [A] [B]
How will the rate of this reaction compare if the concentration of A is
doubled and the concentration of A is doubled and the concentration of B
is halved? The rate will :
remain the same
be double the original rate
be triple the original rate
be one–half the original rate.
52. These data were obtained for the reaction: B
X  Y  Z

Rate law is given as :

Rate = k [X] [Y]
Rate = k[X]2[Y]
Rate = k[X] [Y]2
Rate = k [X]2[Y]2
53. A gaseous substance dissociates in a rigid vessel at constant temperature B
as shown
P(g)  Q(g)  R(g)
The pressure at different instant is observed as shown. Calculate rate
constant of the dissociation.
t = 0 min t = 20 min t = 40 min
1.5 atm 2 atm 7/3 atm
ln 2
min 1
20
1 3
ln min 1
20 2
0.5
atm min 1
2
5
atm min 1
120
54. Consider a first order gas phase decomposition reaction given below : B
A(g)  B(g)  C(g)
The initial pressure of the system before decomposition of A was
pi. After lapse of time ‘t’, total pressure of the system increased by x
units and became ‘pt’ The rate constant k for the reaction is given as :
 2.303 pi
k log
t pi  x
2.303 pi
k log
t 2 pi  pt
2.303 pi
k log
t 2 pi  pt
2.303 pi
k log
t pi  x
55. The solubility product of a salt having general formula MX2, in water is B
4 × 10–12. The concentration of M2+ ions in the saturated aqueous solution
of the salt is :
2.0 × 10–6 M
1.0 × 10–4 M
1.6 × 10–4 M
4.0 × 10–10 M
56. Determine K for the reaction D
 2
H 2C2O 4 (aq) + 2OH (aq)   C2O 4 (aq)  2H 2O(l )
H 2C2O4 (aq) K a1  6.5  102 , K a 2  6.1 105 , H 2OK w  1.0  1014
4.0 × 10–34
4.0 × 10–6
4.0 × 106
4.0 × 1022
57. For ortho phosphoric acid, C
 H 3O  (aq)  H 2 PO 4 (aq); K a1
H 3PO 4 (aq)  H 2O(aq) 
H 2 PO 4 (aq)  H 2O(aq) 
 H 3O  (aq)  HPO 42 (aq); K a 2
HPO 24 (aq)  H 2O(aq)  H 3O  (aq)  PO 34 (aq); K a 3
The correct order of Ka values is :
K a1  K a2  K a3
K a1  K a2  K a3
K a1  K a2  K a3
K a1  K a2  K a3
58. In terms of K1, K2 and K3 of a weak triprotic acid H3B, the value of Kb B
for BH2– will be :
Kw
K1
Kw
K2
 K2
Kw
Kw
K3
59. Number of H+ ions present in 10 mL of solution of pH = 3 are : B
13
10
6.02 × 1018
6.02 × 1013
6.02 × 1010
60. 10–2 mole of NaOH was added to 10 litre of water. The pH will change A
by :
4
3
11
7
61. If | z  3  2i | 4, (where i  1) then the difference of greatest and C
least values of | z | is
2 11
3 11
2 13
3 13
62. If   1 is a cube root of unity and x + y + z  0, then B
x y z
1     2  2  1
y z x
2 2
 0 if
  1 1 
z x y
2  1 1     2
x 2  y2  z 2  0
x  y  z2  0 or x  y  z
xyz0
x  2y  3z
63. If z1, z2, z3 are three distinct complex numbers and a, b, c are three A
a b c
positive real numbers such that   , then
| z 2  z 3 | | z 3  z1 | | z1  z 2 |
a2 b2 c2
  is equal to
 z 2  z3   z3  z1   z1  z 2 
0
 abc
3abc
a+b+c
64. If 8i z 3  12z 2  18z  27i  0, (where i  1) then A
| z | 3 / 2
| z | 2 / 3
| z | 1
| z | 3 / 4
200 50
65. k p B
If i  i
k 0 p 1
 x  iy, (where i  1) then (x, y) is

(0, 1)
(1, -1)
(2, 3)
(4, 8)
66. If the tangent at the point P on the circle x2 + y2 + 6x + 6y = 2 meets C
the straight line 5x – 2y + 6 = 0 at appoint Q on the y-axis, then the
length of PQ is
4
2 5
5
3 5
67. The locus of a point such that the tangents drawn from it to the circle A
x2 + y2 – 6x – 8y = 0 are perpendicular to each other is
x2 + y2 – 6x – 8y – 25 = 0
x2 + y2 + 6x – 8y – 5 = 0
x2 + y2 – 6x + 8y – 5 = 0
x2 + y2 – 6x – 8y + 25 = 0
68. (–6, 0), (0, 6) and (–7, 7) are the vertices of ABC. The incircle of B
the triangle has the equation
x2 + y2 – 9x – 9y + 36 = 0
x2 + y2 + 9x – 9y + 36 = 0
x2 + y2 + 9x + 9y – 36 = 0
x2 + y2 + 18x – 18y + 36 = 0
69. The equations of the circles which touch both the axes and the line C
x=a
2 2 a2
x  y  ax  ay   0
4
a2
x 2  y2  ax  ay   0
4
2 2 a2
x  y  ax  ay   0
4
 None of the above
70. The equation of the image of the circle (x – 3)2 + (y – 2)2 = 1 by the D
mirror x + y = 19 is
(x – 14)2 + (y – 13)2 = 1
(x – 15)2 + (y – 14)2 = 1
(x – 16)2 + (y – 15)2 = 1
(x – 17)2 + (y – 16)2 = 1
71. Equation of the circle cutting orthogonally the three circles A
2 2 2 2
x  y  2x  3y  7  0, x  y  5x  5y  9  0 and
x 2  y2  7x  9y  29  0 is
x 2  y2  16x  18y  4  0
x 2  y2  7x  11y  6  0
x 2  y2  2x  8y  9  0
None of the above
72. The locus of centre of a circle which touches externally the circle D
x 2  y2  6x  6y  14  0 and also touch the y-axis is given by the
equation
x 2  6x  10y  14  0
x 2  10x  6y  14  0
y 2  6x  10y  14  0
y 2  10x  6y  14  0
73. One of the diameter of the circle circumscribing the rectangle ABCD C
is 4y = x + 7. If A and B are the points (–3, 4) and (5, 4)
respectively, then the area of the rectangle is
16 sq unit
24 sq unit
32 sq unit
None of these
74. The equation of the line touching both the parabolas y2 = 4x and D
x2 = –32y is
x + 2y + 4 = 0
2x + y – 4 = 0
x – 2y – 4 = 0
x – 2y + 4 = 0
75. The locus of the points of trisection of the double ordinates of the B
parabola y2 = 4ax is
y2  ax
9y 2  4ax
9y2  ax
 y 2  9ax
76. A double ordinate of the parabola y2 = 8px is of length 16p. The B
angle subtended by it at the vertex of the parabola is
/4
/2

/3
77. The equation of the parabola whose vertex and focus lie on the axis B
of x, at distances a and a1 from the origin respectively is
y 2  4(a1  a) x
y 2  4(a1  a)(x  a)
y 2  4(a1  a)(x  a1 )
None of these
78. A ray of light moving parallel to the x-axis gets reflected from a B
parabolic mirror whose equation is y2 + 10y - 4x + 17 = 0. After
reflection, the ray must pass through the point
(2,  5)
(1,  5)
(3,  5)
(4,  5)
79. If a circle and a parabola intersect in 4 points, then the algebraic sum B
of the ordinates is
Proportional to arithmetic mean of the radius and latus-rectum
Zero
Equal to the ratio of arithmetic mean and latus-rectum
None of the above
80. x2 y2 D
Three points A, B, C are taken on the ellipse 2  2  1 with
a b
accentric angles ,    and   2, then
The area of ABC is independent of 
The area of ABC is independent of 
3
The maximum value of area is ab
4
3 3
The maximum value of area is ab
4
81. The area of a triangle inscribed in an ellipse bears a constant ratio to A
the area of the triangle formed by joining points on the auxillary
circle corresponding to the vertices of the first triangle. This ratio is
b/a
2a/b
 a2/b2
b2/a2
82. x2 y2 B
If the normal at the point P() to the ellipse   1 intersects it
14 5
again at the point Q(2), then cos  is equal to
2
3
2

3
3
2
3

2
83. The radius of the circle passing through the foci of the ellipse A
x 2 y2
  1, and having its centre (0, 3) is
16 9
4
3
12
7/2
84. Equation to the ellipse whose centre is (2, 3) and whose semi-axis C
are 3 and 2 and major axis is parallel to the x-axis, is given by
4x 2  9y 2  16x  54y  61  0
4x 2  9y 2  16x  54y  61  0
4x 2  9y 2  16x  54y  61  0
None of these
85.  A
If   arg(z)   , then arg z  arg ( z) is
2



2


2
86. If  is real and z1, z2 are connected by z12  z 22  2z1z 2 cos   0, then C
triangle with vertices 0, z1 and z2 is
Equilateral
Right angled
Isosceles
None of these
87. If a, b, c are distinct integers and   1 is a cube root of unity then A
minimum value of | a  b  c2 |  | a  b2  c | is
2 3
3
4 2
2
88. Shortest distance of the point (0, c) from the parabola y = x2 where C
0  c  5 is
c if 0  c 1 / 2
c if 3  c  5
c  1 / 4 if 1 / 2  c  5, c if 0  c  1 / 2
c
89. If P,Q,R are three points on a parabola y2 = 4ax whose ordinates are B
in geometrical progression, then the tangents at P and R meet on
The line through Q parallel to x-axis
The line through Q parallel to y-axis
The line joining Q to the vertex
The line joining Q to the focus
90. The locus of the mid-point of the line segment joining the focus to a C
moving point on the parabola y2 = 4ax is another parabola with
directrix
x  a
x  a / 2
x0
x a/2