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Volume 1
Liquid Metal Processing: Applications to Aluminium Alloy Production
I.G. Brodova, P.S. Popel and G.I. Eskin
Volume 2
Iron in Aluminum Alloys: Impurity and Alloying Element
N.A. Belov, A.A. Aksenov and D.G. Eskin
Volume 3
Magnesium Alloys Containing Rare Earth Metals: Structure and Properties
L.L. Rokhlin
Magnesium Alloys Containing Rare
Earth Metals
Structure and Properties
L.L. Rokhlin
Baikov Institute of Metallurgy and Materials Science, Moscow, Russia
L O N D O N A N D NEW YORK
First published 2003 by Taylor & Francis
11 New Fetter Lane, London EC4P 4 E E
This book has been produced from camera-ready copy supplied by the authors
Printed and bound in Great Britain by TJ International Ltd, Padstow, Cornwall
Every effort has been made to ensure that the advice and information in this book is true
and accurate at the time of going to press. However, neither the publisher nor the authors
can accept any legal responsibility or liability for any errors or omissions that may be made.
In the case of drug administration, any medical procedure or the use of technical
equipment mentioned within this book, you are strongly advised to consult the
manufacturer's guidelines.
ISBN 0-415-28414-7
Contents
Preface ix
Introduction 1
Chapter 1
Physico-chemical Interaction between Magnesium and Rare Earth Metals 3
General characteristics o f rare earth metals 3
Binary phase diagrams of magnesium with individual rare earth metals 18
M g - L a phase diagram 20
M g - C e phase diagram 24
M g - P r phase diagram 29
M g - N d phase diagram 32
M g - P m phase diagram 36
M g - S m phase diagram 37
M g - E u phase diagram 41
M g - G d phase diagram 43
M g - T b phase diagram 45
M g - D y phase diagram 48
M g - H o phase diagram 51
M g - E r phase diagram 53
M g - T m phase diagram 54
M g - Y b phase diagram 57
M g - L u phase diagram 60
M g - Y phase diagram 62
M g - S c phase diagram 63
Metallography 65
Regularities o f M g - R E phase diagram constitution 67
Similarity and difference o f the M g - R E systems i n compound formation 68
Lattice parameters o f the M g - R E compounds 70
Regularities o f rare earth metal solubility i n solid magnesium 72
Regular change o f the invariant equilibrium characteristics at M g - r i c h side 78
Ternary and quaternary phase diagrams of magnesium systems where at least
one of the rare earth metals is a component 80
Ternary M g systems with two rare earth metals as components 80
Ternary M g systems with one rare earth metal as a component 86
Quaternary M g systems with at least one rare earth metal as a component 92
Structure of M g - R E alloys after rapid solidification 94
vi MAGNESIUM ALLOYS CONTAINING RARE EARTH METALS
Chapter 2
Decomposition of Supersaturated Solid Solutions in M g - R E Alloys 97
Kinetics of solid solution decomposition in M g - R E alloys 97
Comparison of the decomposition kinetics in the binary M g systems
with various rare earth metals 99
Effect o f temperature on kinetics of the solid solution decomposition 103
Influence of the grain size and supersaturation 108
Phase transformations during decomposition of M g - R E solid solutions 109
Systems with rare earth metals of the cerium subgroup 111
Systems with rare earth metals of the yttrium subgroup, except ytterbium 117
The magnesium-ytterbium system 123
S o l i d solution decomposition i n ternary M g alloys containing rare earth metals 124
Resistance of M g - R E solid solutions against decomposition during
continuous cooling and isothermal ageing 128
Reversion after ageing in M g - R E alloys 131
Chapter 3
Peculiarities of Plastic Deformation and Recrystallisation in M g - R E Alloys 135
Behaviour o f alloys during cold deformation 136
Plasticity of M g - R E alloys at near room temperatures 136
Effect o f cold deformation on mechanical properties of the M g - R E alloys 137
Effect o f cold deformation on kinetics of solid solution decomposition
and accompanying transformation in structure 140
Behaviour of the alloys during annealing after cold deformation 143
Recrystallisation after heavy cold deformation 143
Recovery and recrystallisation after cold deformation of
solution treated alloys 144
Behaviour o f the alloys during hot deformation and following annealing 147
Effect o f rare earth addition on the hot deformation mechanism
of M g at small deformations 147
Effect of rare earth addition on the transition from brittle to
ductile behaviour of M g with rising temperature 148
Structural peculiarities of recovery and recrystallisation during
hot deformation 151
Effect o f deformation temperature on mechanical properties of the alloys 154
Recrystallisation of hot deformed alloys during annealing 155
Chapter 4
Effect of Rare Earth Metals on Mechanical and Some Other Properties of
Magnesium 159
M e c h a n i c a l properties of the binary M g - R E alloys 159
Binary magnesium alloys with lanthanum, cerium, praseodymium
and neodymium 159
Binary alloys M g - S m 166
Binary alloys M g - Y 169
Binary magnesium alloys with G d , T b , D y , H o and E r 172
Binary magnesium alloys with europium and ytterbium 177
CONTENTS vii
Chapter 5
Commercial Magnesium Alloys with Rare Earth Metals,
their Compositions and Properties 209
M a g n e s i u m alloys of the West 209
Cast alloys 210
Wrought alloys 212
M a g n e s i u m alloys of Russia 213
Cast alloys 213
Wrought alloys 217
Conclusion 225
References 227
w h i c h is offered to readers, includes the main contents of the first issue, although with a
certain shortening, but also covers descriptions of the new investigations o f M g - R E alloys
conducted after the first issue was published. In addition, it contains descriptions of the
investigations of the acoustic properties of magnesium alloys. These investigations were
aimed to develop materials with l o w ultrasound attenuation, and some of the rare earth
metals turned out to be very effective additives in this case. A s i n the first issue, the new
book contains a great deal of information about the investigations of these alloys i n Russia.
Nevertheless, many investigations of magnesium alloys with rare earth metals conducted
in other countries are also presented.
Introduction
The first commercial applications of magnesium alloys with rare earth metals were
connected with development of light structural materials having high strength properties at
elevated temperatures. The need for such materials arose i n aircraft from significant
increase of the engine power and the flight speeds of planes after W o r l d W a r II. A t the
beginning, rare earth metals were used for alloying magnesium alloys i n the form o f
"mishmetar. This was the alloy of different rare earth metals in proportions corresponding
approximately to their ratio in the ores where the rare earth metals were presented
commonly together. The main constituent part of mishmetal was cerium and this was the
reason why mishmetal was often named incorrectly as cerium. In that time there was the
widespread opinion that properties of different rare earth metals were quite close.
A s s u m i n g this opinion it was supposed that effects of mishmetal and cerium on magnesium
were practically the same. Nevertheless, the investigations [ 1 , 2 ] where effects of mish-
metal and cerium on magnesium were compared showed this view point to be incorrect.
The effects of mishmetal and cerium on mechanical properties of magnesium established
in [ 1, 2] turned out to be close, but different.
The important step in production and application of magnesium alloys with rare earth
metals began after works of T . E . Leontis from D o w Chemical C o [3,4]. W o r k i n g with both
cast and extruded magnesium alloys i n various conditions T . E . Leontis established signifi-
cant differences between four initial rare earth metals of the lanthanum series, lanthanum,
cerium, praseodymium and neodymium in their effects on mechanical properties of
magnesium. M a g n e s i u m alloys containing neodymium showed significantly higher
strength at elevated temperatures as compared with magnesium alloys containing other rare
earth metals used, including cerium and mishmetal. Magnesium alloys with neodymium
surpassed also magnesium alloys with cerium i n strength at room temperature. A s a result,
magnesium alloys containing neodymium attracted attention for development of
commercial structural materials. Soon such commercial magnesium alloys were developed
and began to be used in industry despite the higher cost of neodymium as compared with
cerium and mishmetal. Commercial production and application o f magnesium alloys
containing neodymium required, of course, a corresponding increase of commercial
neodymium production.
A t about that time, new magnesium alloys containing thorium were studied and
developed for applications at elevated temperatures [ 5 - 7 ] . The main advantage of magne-
sium alloys with thorium was the high creep resistance at elevated temperatures. A t room
temperature and a range above, these alloys had moderate strength properties. M a g n e s i u m
alloys with thorium were produced and used in industry in spite o f the natural radioactivity
of thorium.
Some later increase o f commercial production of individual rare earth metals stimu-
lated investigation of magnesium alloys with yttrium and scandium. The investigations
revealed the possibility of reaching in these alloys higher strength at elevated temperatures
2 MAGNESIUM ALLOYS CONTAINING RARE EARTH METALS
than magnesium alloys with neodymium [8, 9]. The alloys with yttrium showed also the
highest strength properties at room temperature amidst known magnesium alloys. These
discoveries stimulated continuation of the investigations on magnesium alloys with
individual rare earth metals. So, the investigations of magnesium alloys with the rest of the
rare earth metals were conducted. This group of rare earth metals included samarium,
gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium.
Some of these elements showed quite high strengthening effect on magnesium and could
be considered as useful additives for its alloys. The investigation revealed also strict regu-
larities i n constitution and properties of magnesium alloys with different rare earth metals.
C o m m e r c i a l production and application of magnesium alloys with separate rare earth
metals depends, to a great extent, on volumes of rare earth commercial production and the
price, w h i c h is significantly different for each of the rare earth metals. Because of l o w
production and high cost of some rare earth metals, commercial usage of magnesium alloys
with them remains possible now only in very limited quantities, although these alloys may
have very attractive properties. Meanwhile, commercial production of individual rare earth
metals tends to grow and the price of them tends to fall. These factors must promote the
possibility to enlarge usage of magnesium alloys with separate rare earth metals, even with
the most expensive of them i n the shortest supply.
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