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reduce microstructural length scales and enhance fatigue moulding system employed commercially for the pro-
performance.11 To address these contrasting require- duction of cylinder heads and engine blocks. The wedge
ments, the chill is often preheated to reduce early heat mould is designed to allow solidification horizontally
extraction. The problem with this approach is that the from the narrow end of the wedge, where the chill is
preheated chill also has less ability to refine the soli- located, toward the thicker end, which is attached to a
dification microstructure away from the casting/chill large riser (also shown in Fig. 1). Dimensioned drawings
interface within thick sections of the casting by virtue of of the solid and water cooled chills placed within the
the fact that the preheat has reduced the capacity of the mould package are shown in Fig. 2. Figure 3 shows a
chill to absorb heat before saturation (saturation is photograph of one-half of the mould with the solidified
defined as the point where the chill reaches approxi- casting, riser and metal feeding system in place after the
mately the same temperature as the casting at the casting is cooled and the opposite one-half of the mould
interface between the two). One possible solution is to has been removed. This image shows the case in which a
use a water cooled chill. It is envisioned that during water cooled chill was employed. Note that the original
mould filling, the chill would be in a preheated state, cavity for the chill in the wedge mould package was
void of water, to facilitate a slow initial cooling rate larger than the chills used in this study, and hence, a
beside the chill. Then, at the desired time, the water shim was used to force the chill into contact with the
would be switched on to drastically increase the capacity casting.
of the chill to extract heat deep into the casting, thereby A319 was used in the study as it represents the
improving alloy fatigue performance. In essence, the dominant alloy used for the commercial production of
point of introduction of water cooling would both engine blocks and cylinder heads in North America. The
increase the driving force for heat transport (tempera- alloy composition is presented in Table 1. Commercially
ture difference between the chill and the casting surface) pure copper (99?9%) used for the chills.
and increase the effective thermal mass of the chill (the To collect data suitable for assessing the thermal
capacity to adsorb heat). behaviour of the castings with the various chill
In addition to driving force and chill thermal mass, combinations used in the study, a series of holes were
the behaviour of the interface between the chill and the made in the bonded mould to allow thermocouples to be
casting will also have an influence on the ability of a chill placed into the mould cavity at 5, 10, 30 and 50 mm
to extract heat. Generally, during metal casting pro- from the interface with the chill. This series of
cesses, the contact between the metal and mould, which thermocouples was located at approximately midheight
would also include a chill, varies with time leading to a in the cavity (refer to Fig. 1 for exact height). Four
change in the thermal resistance of the interface.12–14 additional thermocouples were placed in the mould
Therefore, the resistance to heat flow that develops at cavity 50 mm from the chill at different heights (refer to
the interface, normally expressed mathematically as 1/h, Fig. 1). Two were located in the top half of the casting
where h (W m22 K21) is the heat transfer coefficient, and two in the bottom half. These were used to assess
needs to be considered in castings that utilise chills.15–17 the extent to which a vertical temperature gradient
The time dependence arises because the thermal/ developed in the casting, thereby guiding the develop-
mechanical distortion of the cast component and/or ment of heat transfer model. To examine the thermal
the chill can result in changes in interface contact, e.g. behaviour of the chills, holes were also drilled into the
the interface behaviour is not generally exclusively chills to facilitate placement of a series of thermocouples
dependent on the thermal behaviour of the casting.16,18
2 mm from the interface. These were also placed at
This paper presents the results of a quantitative
various heights (refer to Fig. 2 for exact locations). All
assessment of the performance of a standard solid chill
of the thermocouples used in the study were of type K
in comparison to a water cooled chill (with and without
and were 3 mm in diameter and sheathed in a nickel–
a delay in cooling). The performance metrics measured
chrome based alloy (Super OMEGACLAD XL sheath-
experimentally include the cooling rate variation in the
ing). The thermocouple data were logged at a frequency
wedge casting as a function of time and distance from
of 2 Hz using Labview software (Labview is a trademark
the chill and the associated microstructure length scale
of National Instruments Corporation).
variation with distance from the chill. In addition, a
To fill each mould, 18 kg of A319 alloy was heated in
quantitative assessment of the variation in the thermal
a silicon carbide crucible until molten by placing the
resistance at the interface between the chill and casting
crucible in a top loading electric furnace model Q3C.
with time has been conducted using a mathematical
Before pouring and while still in the electric furnace,
model. Specifically, this research programme is focused
on determining quantitatively the efficacy of a water argon was injected into the bottom of the melt for
cooled chill in transitioning from a low initial heat 15 min through a stainless steel lance with a porous
transfer rate (chill preheated, no water cooling) to a high graphite head in order to degas the melt. The melt was
heat transfer rate (water cooling) using a standard wedge poured into the mould in ,15 s. The casting conditions
chill mould fabricated in precision sand. employed for each experiment are shown in Table 2.
With one exception, casting 1, the pouring temperature
was 740¡5uC for all of the castings. Casting 1 was cast
Experimental set-up and procedure at 780¡5uC in order to assess the impact of melt
To simulate the broad range of solidification rates superheat. In the cases where the chills were preheated
experienced in engine blocks, a standard, wedge shaped (castings 1–3 and 6), they were heated in an electrical
casting, dimensioned drawing shown in Fig. 1, was furnace to the designated temperature and placed in the
utilised in this study. The mould used to produce the mould cavity immediately before pouring. The water
casting was made from bonded sand and was provided flow rate for castings 5 and 6 was set to 50 L min21 and
by Nemak Canada Ltd, using the same precision sand measured with an inline water flow meter. The
1 Dimensioned drawing of cast wedge and riser (all dimensions are in mm)
2 Dimensioned drawing of a solid chill and b water cooled chill configurations used in study (all dimensions are in mm)
Alloying element/Wt.% Si Fe Cu Mn Mg Zn Ti Sr Al
8.10–8.75 0.27–0.59 2.60–2.95 (0.7?Fe)-0.44 0.31–0.4 0.4–0.8 0.12–0.16 0.004 max. Balance
Cooling conditions Solid chill Solid chill Solid chill Solid chill Water cooled, no delay Delayed water cooled
transition from the pour temperature to the solidus at uniform change in temperature DTcast (K) within the
the location plotted. Note, therefore, that the time scales solidification temperature range. rA319 is the density
in the two figures are different. (kg m23) of cast material, CP,A319 (J kg21 K21) is the
From these data, it can be observed that, in general, specific heat capacity, LA319 (J m23) is the volumetric
the cooling curves for the cast-in thermocouples show an latent of solidification, Dfs is the increment in fraction
initial rapid drop in temperature at the beginning of solid associated with the uniform change in temperature
solidification that gradually moderates with increasing and Vcast (m3) is the volume of cast component. The
fraction solid. The chill thermocouples in comparison equivalent expression for the chill can be generated by
initially rapidly increase in temperature levelling off in removing the latent heat term, using the appropriate
the range of 300–400uC at ,1000 s. The levelling off in volume for the chill and substituting the properties for
temperature in the chill may be referred to as a copper. Assuming that r and CP are temperature
saturation point and represents the time at which the independent in both materials and that the fraction
chill ceases to accelerate the removal of heat from the solid varies linearly with temperature for A319, equa-
casting as heat transport is shifted to be dominated by tion (1) can be used to roughly estimate the equivalent
the mould. response of the chill to a one-degree uniform change in
From the two figures, the time intervals between the temperature in the casting during solidification assuming
liquidus and solidus are 80?5 s at the 5 mm location for no heat transport to the mould. The result is that a 1uC
casting 2, 53 s for casting 3 and 53 s for casting 4. At the uniform change in casting temperature corresponds to a
50 mm location, the corresponding times are 1054, 703 19uC change in chill temperature.
and 673 s respectively. Assuming a linear cooling rate Another observation that can be made from Fig. 4 is
for the solidification interval, this translates into average that the reduction in cooling rate observed at the 5 mm
cooling rates of 1?3uC s21 at 5 mm location for casting location at between ,15 and 20 s in all three castings does
2, 2?0uC s21 for casting 3 and 2?0uC s21 for casting 4. At not correspond to saturation in chill temperature and a
50 mm, the corresponding rates are 0?1, 0?15 and loss in driving force for heat transfer (temperature
0?16uC s21 respectively. The 5 mm data do not show difference across the chill) as the chill data indicate that
the expected trend of consistently increasing cooling rate the chill temperatures are continuing to increase in
with decreasing initial chill temperature, whereas the temperature. Moreover, the similar cooling behaviour in
50 mm data generally do. A couple of comments may be all three castings at 5 mm occurs despite significantly
made based on these data. different chill temperatures. Both of these observations
First, the lack of strong sensitivity to chill preheat is would imply a different mechanism limiting heat transfer,
not surprising as the solid chill employed in castings 2–4 which is examined in the section on ‘Estimation of chill/
is relatively small (10?5 kg) compared with the mass of casting interfacial heat transfer coefficient’.
the casting (16 kg), taken to be the wedge and riser and Finally, it would also appear that chill preheating is
ignoring the feeding system. This difference in mass relatively ineffective in moderating cooling rates beside
directly impacts on the capacity of the chill to extract the chill until chill preheat temperatures approach 160uC
heat from the casting. Taking a lumped approach as a for the experimental conditions examined in this study.
first approximation, the change in enthalpy associated In contrast, chill preheat appears to be more effective in
with a uniform change in temperature within the manipulating solidification conditions 50 mm from the
solidification temperature range may be estimated using interface.
equation (1)
Effect of superheat
DHthermal,cast ~ rA319 CP,A319 DTcast zLA319 Dfs Vcast (1)
To assess the effect of pour superheat, another process
where DHthermal,cast (J) represents the change in heat variable that may be controlled industrially, the results
content or enthalpy in the casting resulting from a for castings 1 and 2 have been compared, which have
approximately the same chill temperature, but different Effect of water cooling
pouring temperatures (780 and 740uC respectively). Figures 8 and 9 present a comparison between the
Figures 6 and 7 contain the cooling curves for the thermocouple results for casting 4 and 5 at the 5 and
thermocouples located at 5 and 50 mm from the chill 50 mm locations respectively. Casting 4 employed a
respectively. The behaviour of the chill has been added solid chill, and casting 5 employed the water cooled chill
to the two figures and is plotted on the secondary y-axis. (no delay). Both castings had approximately the same
Again, in each figure, the liquidus and solidus tempera- casting conditions, i.e. same pouring temperature and
tures for A319 have been added for reference, and the same initial chill temperature. The two figures also
range of time plotted has been limited to the time to include the thermocouple responses observed in the
complete solidification, resulting in different time scales chills for the two castings plotted on the secondary y-
in the two figures. axis. Again, in each figure, the liquidus and solidus
As can be seen, the amount of superheat has a temperatures for A319 have been added for reference,
moderate effect on cooling response. The sample cast at and the range of time plotted has been limited to the
780uC (170uC superheat) has a time interval for time to complete solidification, resulting in different time
solidification of 294 s at 5 mm and the sample cast at scales in the two figures.
740uC (130uC superheat) 80?5 s. At 50 mm, the times are These graphs clearly show the increased heat extrac-
1489?5 and 1054 s respectively. The corresponding tion capacity achieved by means of water cooling the
average cooling rates are 0?36 and 1?32uC s21 at 5 mm chill. In comparison to the results for the solid chill, the
and 0?07 and 0?1uC s21 at 50 mm respectively. Figure 7 solidification time at 5 mm with water cooling applied at
also shows that the chill saturates in temperature sooner the beginning of mould filling is reduced from 56 to 15 s
and at a higher temperature for the cast poured with the and at 50 mm from 588 to 93?5 s. Furthermore, the
higher amount of superheat. The comparatively large average cooling rate is increased from 1?9 to 7?06uC s21
sensitivity to pour superheat is again related to the mass at 5 mm and from 0?18 to 1?13uC s21 at 50 mm. The
difference between the casting and the chill discussed in response observed in the chill thermocouples plotted in
the previous section, and thus, changes in the superheat Fig. 8 shows only a small initial increase in temperature
have a larger impact than changes in chill temperature. in the water cooled chill peaking at ,60uC followed by a
8 Cooling curve comparison with and without water cooling 5 mm from chill
drop to ,25uC. There is no saturation in chill corresponds to as solid fraction of y0?9 being achieved.
temperature, and a large temperature differential is In fact, the solid chill appears to cool the material at the
maintained across the casting/chill interface helping to 5 mm location quicker over the 30 s interval, which is
sustain the high cooling rate deep into the casting. The most likely caused by the reduced mass of the water
increase in cooling achieved with the water is greater cooled chill (y33%) associated with the removal of
deeper into the casting (63?5 at 5 mm vs. 64 at material to create the water cooling channel. Then, at
50 mm). This is because the water cooling maintains a ,30 s, there is a marked divergence in behaviour
larger driving force for heat transfer as the material associated with a large increase in the cooling rate in
deeper into the casting solidifies, whereas in the solid the water cooled casting. Solidification is complete at
chill, the chill has saturated by the time this material y32 s in the water cooled casting compared with y45 s
solidifies. in the solid chill casting. Again, note that at the 5 mm
Effectiveness of delay in water cooling
location, the material is y90% solidified at the low
cooling rate easily avoiding the formation of a columnar
To investigate the effectiveness of delaying the water structure beside the chill. The results presented in
cooling as a means of reducing the cooling rate in Fig. 11 show that switching the water on after a 10 s
proximity to the chill, the results from castings 3 and 6 delay was effective in significantly increasing the cooling
have been compared. Both castings were poured at rate and decreasing the solidification time 50 mm into
740uC and a chill preheat of 115uC. The results for the the casting. In comparison to the solid chill, the
thermocouples located at 5 mm from the chill are solidification time at 50 mm decreased from 657 to
presented in Fig. 10 and for the 50 mm thermocouples 168 s. Overall, these results show that this method has
in Fig. 11. Both figures also include the thermocouple the potential to both avoid missruns and a columnar
responses observed in the chills plotted on the secondary structure at locations in proximity to the chill while at
y-axis. Again, in each figure, the liquidus and solidus the same time improving the cast microstructure from a
temperatures for A319 have been added for reference, fatigue standpoint farther into castings remote from the
and the range of time plotted has been limited to the chill such as for example in main bearing bulkheads.
time to complete solidification, resulting in different time
scales in the two figures. Microstructure
As can be seen in Fig. 10, the thermocouples located In order to investigate and quantify the effect of cooling
5 mm from the chill show approximately the same rate on SDAS, five metallographic specimens at 5, 10,
cooling rate for the two castings up to ,30 s, which 30, 50 and 150 mm from the chill were taken from the
9 Cooling curve comparison with and without water cooling 50 mm from chill
10 Cooling curve comparison between delayed water cooling and solid chill at distance of 5 mm from chill
11 Cooling curve comparison between delayed water cooling and solid chill at distance of 50 mm from chill
central vertical plane of castings 1 and 5. Castings 1 and with increasing distance from the chill in both castings
5 were chosen for assessment as they represent the two reflecting the decreasing cooling rate as would be
extremes in cooling rate examined in this study. expected. In addition, the results clearly show that the
Figure 12 shows a plot of the variation in SDAS size SDAS sizes at all of the positions examined for the water
with distance from the chill for the two castings. As can cooled chill (no delay) condition are significantly smaller
be seen, the microstructure of the solidified casting (as than for the solid chill case. At 50 mm, for example, the
defined by the SDAS) becomes progressively coarser reduction in SDAS is from 40 to 25 mm or ,40%. The
12 Variation of SDAS with distance from chill: error bars show range of data given by 40 measurements taken from each
sample; marker shows average value
optical microscope images of the two casting taken at addition, the analysis of the thermocouples located
50 mm are presented in Fig. 13 and further support this 50 mm from the chill at various heights revealed that
fact qualitatively. only a small vertical gradient in temperature develops in
the casting. Thus, it has been assumed to a first
Estimation of chill/casting interfacial heat approximation that the calculation domain can be
transfer coefficient further limited to a two-dimensional (2D) slice of the
Model development and fit to measured data casting at midheight and fluid flow and mould filling can
As previously described, in addition to maintaining a be ignored and only diffusive heat transport need be
large temperature difference across the chill/casting considered. As a final step in reducing the computational
interface to drive heat transfer, good thermal contact size of the problem, the thermal field was assumed to be
must also be maintained at the interface for the chill to symmetric about a vertical plane bisecting the casting
be most effective. Normally expressed in terms of the and hence only one-half of the geometry was modelled.
interfacial heat transfer coefficient, it is therefore According to the experimental results, the melt tem-
important to quantify and compare the behaviour of perature drops ,60uC during the pouring process. Since
the interface heat transfer coefficient for the solid chill the modelling does not include pouring process, the
and water cooled chill under some of the conditions initial temperature of the melt was set to 60uC less than
examined in the study. This information will help to the pouring temperature. The initial conditions applied
identify any potential issues related to interfacial heat to each casting are presented in Table 3.
transport associated with the application of water The mathematical model has been developed in the
cooled chills industrially. commercial finite volume program ANSYS CFX
There are a variety of methods appearing in the version 12.1. The details of the application including
literature for estimating the interface heat transfer coeffi- governing equations, development of the various
cient in casting processes.6,13,14,17,18,21,22 In the current boundary conditions and materials properties (including
work, the method employed is to develop a mathematical method of incorporation of the latent heat of solidifica-
based heat transfer model of the casting and chill including tion) are presented in Ref. 23. The model domain,
the interface, which is then used to estimate the heat including identification of the various boundary condi-
transfer coefficient by aligning the model predictions to the tions, is shown in Fig. 14a for the solid chill casting and
thermocouple measurements. A trial and error methodol- in Fig. 14b for the water cooled chill. As ANSYS CFX
ogy is used whereby changes are made to the temperature does not allow the analysis of 2D domains, a ‘2D slice’
and or time dependence of the interfacial heat transfer was taken to be a planar horizontal section through the
coefficient until good alignment is achieved between the casting 2 mm in thickness. All of the surfaces normal to
model predictions and measurements. the plane of the analysis domain are assumed to be
In the early stages of casting solidification, at adiabatic as is the symmetry plane. A series of specified
locations in proximity to the chill, transport of heat heat transfer coefficients are used to describe the casting/
takes place mainly through the chill/casting interface. sand mould boundary, casting/chill interface and chill/
This is due to the fact that the sand mould has a low sand mould boundary (see Ref. 23).
thermal conductivity and acts as an insulating material, Comparisons between the model predictions and
whereas in comparison, the copper is a strong heat measurements for the solid chill model (casting 4) and
conductor. Thus, as an approximation, the sand mould for a water cooled casting (casting 6) are shown Figs. 15
geometry is not included in the analysis domain and is and 16 respectively. As can be seen, the model is able to
instead approximated using a heat transfer coefficient in reproduce the thermal behaviour obtained from the
combination with a time dependent sink temperature. thermocouples within the casting and chill to a reason-
The details of this approach are presented in Ref. 23. In ably accuracy to within ,2% or 10uC for most of the
Cooling conditions Solid chill Solid chill Solid chill Solid chill Water cooled, no delay Delayed water cooled
14 Model domains and boundaries conditions applied to a solid chill and b water cooled chill conditions
15 Comparison between the experimental data and model predictions for casting 4 (solid chill, chill initial temperature,
20uC; pour temperature, 740uC)
16 Comparison between experimental data and model predictions for casting 6 (10 s delayed water cooled chill, chill
initial temperature, 115uC; pour temperature, 740uC)
17 Temperature dependent melt/chill interfacial heat transfer coefficient for solid chill conditions
locations examined. Thus, the estimates obtained for interface develops and localised microscale shrinkage
behaviour of the interface heat transfer coefficients may occurs. In stage 3, solidification proceeds into the casting
also be expected to be reasonably accurate. resulting macroscale shrinkage and formation of a gap.
Solid chill interfacial heat transfer coefficient Water cooled chill/casting interfacial heat transfer
Figure 17 compares the temperature dependent inter- coefficient
facial heat transfer coefficients needed to fit the model to The thermal behaviour of the chills in the water cooled
the thermocouple data for the four solid chill experi- castings consistently showed an initial increase in
ments. The temperature on the x-axis of the plot temperature followed by a drop within the first y60 s
represents the surface temperature of the casting at the of the casting process. This required the application of a
interface, which is predicted by the model. Vertical lines time dependent interfacial heat transfer coefficient to fit
have been added representing the liquidus temperature the model predictions to the thermocouple data, unlike
and solidus temperature. Qualitatively, all the curves in the case of the solid chill based castings, which could
show the same behaviour. The heat transfer coefficient be adequately described with a temperature based
starts at a high value in the range of 1700 to coefficient. Figure 18 shows the time dependent inter-
2300 W m22 K21 and remains constant until the facial heat transfer coefficient applied to the two water
liquidus temperature is reached (stage 1). A small drop cooled chill models. The data for both castings show the
is observed between liquidus and solidus in the range of same initial high value for the interfacial heat transfer
10–15% (stage 2), and finally, they all drop between 65 coefficient in the range of 1800–2000 W m22 K21. They
and 75% to a value of 500 W m22 K21, at an interface then show a drop in heat transfer to between 1400 and
temperature in the range of 475–480uC (stage 3), which 1500 W m22 K21 in a relatively short period of time
represents the end of the computational analysis. In (y25 s), which is followed by a plateau ranging in time
addition, there is a strong dependence of the IHTC on from ,10 to 30 s in which the interfacial heat transfer
the amount of melt superheat showing a trend to higher coefficient does not drop, followed by a continues drop
initial values with elevated pouring temperatures. to ,900 W m22 K21 at 300 s, which represents the end
These results are consistent with other studies in of the period of the computational analysis.
which the behaviour of the casting/mould interface has To examine this behaviour more closely, the data
been examined.14,17,21,22 In stage 1, good physical from casting 5 has been replotted at two different time
contact between the casting and the chill is achieved as scales 0–50 and 0–350 s. In addition, the temperature
the molten metal fills at least a portion of the asperities behaviour of the casting, at the interface, and chill, at
present on the chill surface due to its high fluidity. the interface, has been added using the secondary y-axis.
Complete contact with the chill cannot be obtained due The liquidus and solidus lines have also been added. As
to the melt surface tension effects. Higher superheats can be seen, the behaviour in stages 1 and 2, as labelled
and higher chill initial temperatures result in better on the plots, is identical to the interface behaviour
conformability with asperities and higher heat transfer, observed for the solid chill. Stage 3 in contrast behaves
which is consistent with the data shown in Fig. 17. In differently showing two regimes of behaviour, defined as
stage 2, the liquid to solid transformation starts at the stages 39 and 30, in Fig. 19. In stage 39, the interfacial
interface and contact between the casting, and the chill heat transfer coefficient is observed to be invariant in
begins to degrade as the solidification structure at the time, and in stage 30, it is observed to decrease with time
18 Time dependent melt/chill interfacial heat transfer coefficient for water cooled conditions
19 Temperature variation of interface at casting domain and time dependent IHTC, casting 5 (water cooled chill, chill
initial temperature, 20uC; pour temperature, 740uC)
in a similar fashion to that observed in stage 3 for the 2. Cast superheat was found to have a moderate effect
solid chills. The period of invariant behaviour appears on cooling rate for the conditions examined in the study
to coincide with a slowing in the increase in the chill at both the 5 and 50 mm locations.
interface temperature as it approaches its peak value. 3. Water cooling was found to significantly reduce the
Stage 30 begins with the drop in chill temperature. cooling rate at both the 5 and 50 mm locations.
In the standard water cooled casting, casting 5, stage 4. Switching the water on with a 10 s delay was shown
39 is longer than in the delayed water cooled casting. The to be effective in transitioning from an initial low
mechanism for this difference is unclear. The delay in cooling rate similar to that achieved with a preheated
water cooling results in the chill, reaching a much higher solid chill 5 mm from the interface to a high cooling rate
temperature before beginning to cool. It also results in a 50 mm from the interface.
reduction in the cooling rate of the casting in the early 5. A comparison between the variation in SDAS in
stages of the casting. Both factors should contribute to a the castings produced with the solid chill and water
longer delay in gap formation, e.g. expansion of the chill cooled chill (no delay) showed a substantial reduction in
and reduced contraction in the casting, respectively, SDAS at distances ranging from 5 to 150 mm, which
which is contrary to what is observed. Further work is was the maximum depth examined.
planned to directly measure the behaviour of the gap 6. Characterisation of the variation in interfacial heat
and to move to a coupled thermal stress model for transfer under the casting conditions examined in the
analysis of the results. study with a 2D transient heat conduction model
revealed differences in behaviour between the castings
Conclusions produced with the solid chills and those produced with
the water cooled chills. The evolution of temperature
The work shows that application of water cooled chill with time in all of the solid chill castings could be
technology in combination with the appropriate delay accurately described using a temperature dependent
interval for switching the water cooling on has the function for the interfacial heat transfer coefficient. In
potential to improved mechanical fatigue performance contrast, the water cooled castings required a time
in large section thicknesses in A319 via a substantial dependent function. Further work is required to under-
reduction in SDAS. The delay was found to be effective stand the variation in the interfacial heat transfer
in moderating the cooling rate beside the chill, which has coefficient particularly as it is effected by the develop-
the potential to avoid some of the problems associated ment of a macroscale gap at the interface.
with the application of large cold chills in industry
including cold shuts and the tendency to form a References
columnar grain structure directly beside the chill.
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