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ELECTRON STRUCTURES
&
PERIODIC TABLE
ELECTRONS IN ATOMS
Atomic Models
Systems of atomic and subatomic entities can be
explained by following the establishment of principles and
laws set which known as quantum mechanic.
Therefore, to understand the behaviour of electron in
atoms and crystalline solids, discussion of quantum-
mechanical concepts are necessarily involved.
Quantum mechanics of atoms was simplified and called
as Bohr atomic model
Bohr Atomic Model
Bohr Rules:
1. Electrons can orbit only at certain
allowed distances from the
nucleus.
2. Atoms radiate energy when an
electron jumps from a higher-
energy orbit to a lower-energy
orbit. An atom absorbs energy
when an electron gets boosted
from a low-energy orbit to a high-
energy orbit.
Bohr model was eventually found to
have some significant limitations:
The electron does not orbit the
nucleus in circles as Bohr
suggested (as popular drawing),
but in ‘fuzzy’ orbit.
Wave-Mechanical Model
Sublevels
If n=1 one sublevel: s
If n=2 two sublevels: s and p
Orbitals
Space for electrons
If n=2, electron occupy in 1s, 2s and 2px, 2py, 2pz
s orbital
x x x
y y y
z
z z
x
x x
y
y y
px py pz
Electron configuration
1s1
Guidelines to Write Electron Configuration
7 7s2 7p6
1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f
He He He
1s 1s 1s
2. Hund’s rule:
the most stable arrangement of electrons in
sublevel is the one with the greatest number of
parallel spins.
Consider, how to write valence orbital diagram for
atom carbon:
1s2 2s2 2p2 electron configuration
Orbital diagram:
1s 2s
Orbital diagram:
1s 2s 2p
Mg: no. of electron = proton number = _____
Electron configuration:_____________________
Orbital diagram:
1s 2s 2p 3s
Orbital diagram:
Core electron and valence electron
Mg 1s2 2s2 2p6 3s2 1s2 2s2 2p6 or 3s2 [Ne] 3s2
Ne
Cl 1s2 2s2 2p6 3s2 3p5 1s2 2s2 2p6 or 3s2 3p5 [Ne] 3s2 3p5
Ne
Al 1s2 2s2 2p6 3s2 3p1 1s2 2s2 2p6 or 3s2 3p1 [Ne] 3s2 3p1
Ne
Quantum Numbers
x x x
z z z
s orbital
1s orbital 2s orbital 3s orbital
z z z
x x x
y y y
p orbital
px py pz
3. Magnetic quantum number (mℓ)
describes the orientation in space of an orbital of a given
energy (n) and shape (ℓ).
It called the magnetic quantum number because the
effect of different orientations of orbitals was first
observed in the presence of a magnetic field.
m is entitled to be any integer from -ℓ up to ℓ.
Given a particular ℓ, there are 2ℓ+1 magnetic quantum
numbers, m ranging from -ℓ to ℓ
Thus, s subshell has only one orbital, the p subshell has
three orbitals, and so on.
Relationship between Quantum Numbers
3 orientations is space
ml = -2, -1, 0, 1, or 2 5 orientations is space
4. Spin quantum number (ms)
Specifies the orientation of the spin axis of
an electron
An electron can spin in only one of two
directions (sometimes called up and down)
+½ (↑) or -½ (↓)
ms = +½ or -½
The Pauli exclusion principle (Wolfgang Pauli,
Nobel Prize 1945) states that no two electrons in
the same atom can have identical values for all four
of their quantum numbers.
n=3; l = 2
n=3; l = 1
n=3; l = 0
n=2; l = 1
n=2; l = 0
n=1; l = 0
Example
Write all sets of quantum numbers that describe the 6 electrons of
carbon atom.
1s 2s 2p
Noble
Group Period
gases
1 18
1
2 13 14 15 16 17
2
3 4 5 6 7 8 9 10 11 12 3
Transition metals
Representative Lanthanides
(Main Group)
Actinides
Electronic Configuration & Periodic Table
Elements in the same group have the same numbers of outer
electron (valence electron)
Isoelectronic
EXERCISE
1. Write the electron configuration and orbital diagram for the
following elements.
2. Determine the group and period (WITHOUT LOOKING AT THE
PERIODIC TABLE).
Silicon 14
Potassium 19
Bromin 35
Aluminium ion 13
Effective Nuclear Charge, Zeff
the larger the Zeff, the stronger the hold of the nucleus on
these electrons, and the smaller the atomic radius
Atomic radius decreases as we move from left to right across
a period because of an increase in effective nuclear charge,
Zeff , for the valence shell electron
Anion are always larger than the atom from which they were
formed.
Because the Zeff remains the same but the repulsion resulting
from the additional electron(s) enlarges the domain of the
electron cloud.
Na Na+ O O2-
186 pm 95 pm 73 pm 140 pm
• When comparing cations or anions within a column (group),
they get larger going down the column. Example:
Ca2+ > Mg2+ and I- > Br-
I2
Na+ (g) Na2+ (g) + e- E = 4560 kJ/mol
Alkali metals
Very reactive (why?)
Have low first ionization energy great tendency to lose the
its valence electron to form ions with a +1 charge.
React with water producing hydrogen gas and solutions of
alkali metal hydroxides
2Na (s) + 2H2O (l) 2NaOH (aq) + H2 (g)
Reaction between alkali metals and oxygen:
Lithium form metal oxides (which contain O2- ion)
4Li (s) + O2 (g) 2Li2O (s)
other metals form metal oxides and peroxides (contain O22-
ion)
2Na (s) + O2 (g) Na2O2 (s)
K, Rb and Cs also form superoxides (contains O2- ion)
K (s) + O2 (g) KO2 (s)
Group 2 (ns2, n ≥ 2 )