Nama = Sigit permadi

NPM = 1615041053
Matkul = Operasi Teknik Kimia III

PROBLEMS

10.2-1 Equilibrium and Henry’s Law Constant. The partial pressure of CO2 IN
AIR IS 1.333 X 104 Pa and the total pressure is 1.133 x 105 Pa. The gas phase is in
equlibrium with a wter solution at 303 K. What is the value of XA of CO2 in equilibrium in
the solution ? See Appendix A.3 for the Henry’s law constant.

10.2-3 Phase Rule for a Gas-Liquid System. For the system SO2 -air-water, the
total pressure is set at 1 atm abs and the partial pressure of SO2 in the vapor is set at 0.20
atm. Calculate the number of degrees of freedom, F. What variables are unspecified that
can be arbitrari;y set ?

10.3-1 Equilibrium Stage Contact for Gas-Liquid System. A gas mixture at 2.026
x 105 Pa total pressure containing air and SO2 is contacted in a single-stages equilibrium
mixer with pure water at 293 K. The partial pressure of SO2 in the original gas is 1.52 x 104
Pa. The inle gas contains 5.70 total kg mol an dthe inlet water 2.20 total kg mol. The exit
gas and liquid leaving are in equilibrium. Calculate the amounts and compositions of the
outlet phases. Use equilbrium data from Fig. 10.2-1

10.3-2 Absorption in a Countercurrent Stage Tower. Repeat example 10.3-2 using

the same conditions but with the following change. Use a pure water flow to the tower of
108 kg mol H2O/h, that is, 20% above the 90 used in Example 10.3-2. Determine the number
of stages required graphically. Repeat using the analytical Kremser equation.

10.3-3 Stripping Taint from Cream by Steam. Countercurrent stgae stripping is to

be used to remove a taint from cream. The taint is present in the original cream to the
stripper at a concentration of 20 parts per million (ppm). For every 100 kg of cream entering
per unit timer], 50 kg of steam will be used fo stripping. It is desired to reduce the
concentartion of the taint in the cream to 1 ppm. The equilibrium relation between the taint
is present in steam vapor and the liquid cream is yA = 10xA, where yA is ppm of taint in the
steam and xA ppm in the cream (E1). Determine the number of theoritical stages needed.
[Hint : In this case, for stripping from the liquid (L) stream to the vapor (V) stream the
operating line will be below the equilibrium line on the yA - xA diagram. It assumed that
none of the steam condenses in the stripping. Use ppm in the material balances.]
PENYELESAIAN

10.2-1 Equilibrium and Henry’s law constant

Pa = 1,333 x 104 Pa = 1,315569 x 10-1 atm
P = 1,133 x 103 P
T = 303 K
H = 0,186 x 104 atm/mole
Pa = H x Xa
1,315569 x 10-1 = 0,186 x 104 Xa
Xa = 7,07 x 10-5 mole

10.2-3 Phase Rule for a Gas-Liquid System

F = C – P +2
F =3–2+2
F =3
Jadi temperaturnya dapat ditentukan karena temperature total diketahui

10.3-1 Equilibrium Stage Contact for Gas-Liquid System.

V1 V2 = 5,70 kg mol
Lo = 2,20 kg mol 2 293 K KA2 = 1,52 X 104 Pa
XAO = 0 P = 2,026 X 105 Pa
L1 XA1
Equation 10.2-1 Pa (atm) = HXA = 29,6 XA
2,026 𝑥 105 1,52 𝑥 104
P= = 2,00 atm YA2 = = 0,0750
1,0132 𝑥 105 2,026 𝑥 105
RA1 H 29,6
YA1 = = XA1 = XA1 = 14,8XA1
P P 2,0

Equation 10.3-4 L’ = Lo = 2,2 V’ = V2 (1-YA2)

= 5,7 (1-0,075)
= 5,272
L′ XAO Y L′ XA1 V′ YA1
+ V’ 1−YA2 = +
1−XAO A2 1−XA1 1− YA1
 2,2 (0) (0,0750) 2,20 XA1 5,272YA1
+ 5,272 1−0,075 = +
1−0 1−XA1 1− YA1
(0,0750) 2,20 XA1 5,272 (14,8 XA1 )
0 + 5,272 1−0,075 = +
1−XA1 1− 14,8XA1

Diperoleh XA1 = 0,00495

YA1 = 14,8 (0,00495) = 0,0733 = YA1

L′ 5,272
L’ = 1−Y = 1−0,0495
= 2,21 kg mol
A1

V′ 5,272
V1 = 1−Y = = 5,69 kg mol
A1 1−0,0733

10.3-2 Absorption in a Countercurrent stage towes (a)

YAN+1 = 0,01
Xa0 =0
VN+1 = 30 Kgmole/ h
L0 = 108 kgmole/h

Aseton masuk
YAN+1 x VN+1 =0,01 x 30
= 0,3 Kgmole/h aseton
Air masuk
VN+1 – (YAN+1 x YAN+1)
(1 - YAN+1) VN+1
(1 – 0,01) 30
0,99 . 30 = 29,7 Kgmole/h air

Aseton keluar V1 = 0,1 x 0,3 = 0,03 Kgmole/h

Air keluar LN = 0,9 x 0,3 = 0,27 Kgmole/h
V1 = 29,7 + 0,03
= 29,73 Kgmole air + aseton/h
YA1 = 0,03/29,73
= 0,00101 Kgmole water + aseton /h

LN = 108 + 0,27
= 108,27 Kgmole/h

XAN = 0,27/108
= 2,5 x 10-3 mole

L0 = 108 Kgmole/h
LN = 108,27 Kgmole/h
V0 = 30 Kgmole/h
VN = 29,73 Kgmole/h
Yn+1 = LN . Xn/Vn+1 + {(V1Y1 – L0X0)}/vn+1
= 108,27 . 2,3 . 10-3/27,73 + {(29,73 . 0,001 – 108 . 0)}29,73
=9,1 x 10-3 + 1. 10-3
= 10,1 x 10-3
= 0,0101 mole
10.3-2 Absorption in a Countercurrent stage towes (b)
YA = m V1 m = 2,53 xA0 = 0 YA1 = 0,00101
xAN = 0,002404 YAN+1 = 0,010
L0 = 108 LN = 108,27
V1 = 29,73 VN+1 = 30

A1 = L0/ m V1 = 108/2,53 . 29,73 = 1,436

AN+1 = LN/m VN+1 = 108,27/2,53 . 30 = 1,426

Aair = √1,436 . 1,426

= 1,431
N = {log[ (YN+1 – mx0/Y1 – mx0) . (1 – 1/A) + 1/A]} /log a
= {log [ (0,01 – 0/0,00101– 0) . (1 – 1/1,431) + 1/1,431]} /log 1,431
= 3,64 theoritical stage

10.3.3 Stripoing Taint from cream by system

Diketahui ;

L0 = 100kg

X0 = 20ppm

Xw = 1ppm

Vn+1 = 50 kg

Ditanya ; N?
Maka

Jumlah taint yang masuk = 2 x 10-5 x 100 = 2 x 10-3 kg

Jumlah cream yang masuk = (1-2 x10-50)x100 = 99,998 kg

Jumlah taint yang ada pada LN = 1/20x2x10-3 = 10-4 kg

Jumlah taint yang ada pada v1 = 19/20

Maka v1 = 50 + (1,9x10-3) kg

LN =99,998 + 10-4 kg
1,9.106−3
𝑦𝐴1 = = 3,7998.10−5
50+(1,9.10−3 )

0 𝐿 100
𝐴1 = 𝑚×𝑣 = 50+(1,9x10−3 ) = 0,1999
1

𝐿𝑁 99,998 + 10−4
𝐴𝑁 = = = 0,999
𝑚+𝑣𝑁+1 10+50
1,9×10−3
𝑦𝐴1 = = 3,7988
50+(1,9×10−3 )

𝐿0 100
𝐴1 = = = 0,1999
𝑚 × 𝑣1 10 × (1,9 × 10−3 )
𝐿𝑁 99,998 + 10−4
𝐴𝑁 = = = 0,1999
𝑚 × 𝑣𝑁+1 10 × 50

𝐴 = √(𝐴1 × 𝐴𝑁 ) = √0,1999 + 0,1999 = 0,1999

(𝑌𝑁+1 −(𝑚×𝑥0 ) 1 1
log[{ )×(1− )}+( )⦌
(𝑌1 −(𝑚×𝑥0 ) 𝐴 4
𝑁= 𝑙𝑜𝑔𝐴

0−(10×2×10−6 1 1
log[{ ×(1−( )}+ ]
3,7998×10−5 −(10×2×10−5 ) 0,1999 0,1999
𝑁= log(0,1998)
= 1,7358

Maka nilai N = 1,7358