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Questions

Q1.

100 cm3 of methane, CH4, is completely burned in 400 cm3 of oxygen.

What is the final volume of the gas mixture, in cm3, when all volumes are measured at room
temperature and pressure?

A 100

B 200

C 300

D 400

(Total for question = 1 mark)

Q2.

A compound has the composition by mass of 54.5% C, 9.1% H and 36.4% O. What is its empirical
formula?

A C2 H2 O

B C2H4O

C C4H9O

D C6HO4

(Total for question = 1 mark)

Q3.
Sodium hydrogencarbonate decomposes on heating.

2NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(l)

What is the maximum volume of carbon dioxide, in dm3, which could be obtained by heating
0.25 mol sodium hydrogencarbonate?

The gas volume is measured at room temperature and pressure when the molar volume of a gas
= 24 dm3 mol–1.

A 3

B 6

C 12

D 24

(Total for question = 1 mark)

Q4.

50 cm3 of hydrogen is mixed with 25 cm3 of chlorine. The gases react as shown in the equation
below.

H2(g) + Cl2(g) → 2HCl(g)

What is the total volume of gas present at the end of the reaction?

[All gas volumes are measured at the same temperature and pressure.]

A 75 cm3

B 100 cm3

C 125 cm3

D 150 cm3

(Total for question = 1 mark)


Q5.

Which of the following gas samples has the same volume as 7.0 g of carbon monoxide?

All volumes are measured at the same temperature and pressure.

A 1.0 g of hydrogen

B 3.5 g of nitrogen

C 10.0 g of argon

D 35.5 g of chlorine

(Total for question = 1 mark)

Q6.

How many moles of ions are present in 30 cm3 of 0.025 mol dm–3 barium hydroxide solution,
Ba(OH)2(aq)?

A 0.00075

B 0.00150

C 0.00225

D 0.00450

(Total for question = 1 mark)

Q7.

Which of the following aqueous solutions contains the greatest number of negative ions?

A 500 cm3 of 0.10 mol dm−3 Na2SO4(aq)

B 250 cm3 of 0.12 mol dm−3 BaCl2(aq)

C 250 cm3 of 0.15 mol dm−3 KI(aq)


D 500 cm3 of 0.10 mol dm−3 Zn(NO3)2(aq)

(Total for question = 1 mark)

Q8.

In the synthesis of ammonia, 56.0 g nitrogen was reacted with excess hydrogen.

N2(g) + 3H2(g) → 2NH3(g)

The mass of ammonia produced was 6.00 g.

What is the percentage yield of ammonia?

A 5.66

B 8.82

C 9.10

D 10.7

(Total for question = 1 mark)

Q9.

Calculate the empirical formula of the compound with the percentage composition by mass:
Li = 17.9%; P = 26.8%; O = 55.3%

Molar masses / g mol–1 Li = 6.9, P = 31.0, O = 16.0

(1)

A Li2P3O6

B Li3PO3

C LiPO3

D Li3PO4
(Total for question = 1 mark)

Q10.

In an experiment carried out at 200°C and 1 atm pressure, 20 cm3 of ammonia gas reacted with
an excess of heated copper(II) oxide.

If all measurements were made at 200°C and 1 atm pressure, what would be the total volume, in
cm3, of gaseous products?

A 10

B 20

C 30

D 40

(Total for question = 1 mark)

Q11.

What is the concentration, in mol dm–3, of a solution of 10.6 g of sodium carbonate, Na2CO3, in
250 cm3 of solution?

A 0.40

B 0.25

C 0.10

D 0.025

(Total for question = 1 marks)


Q12.

In which of the following pairs does each gas occupy the same volume?

All volumes are measured at the same temperature and pressure.

A 2 g of hydrogen and 14 g of nitrogen.

B 32 g of methane and 88 g of carbon dioxide.

C Calcium carbonate is in excess by 0.01 mol.

D Nitric acid is in excess by 0.03 mol.

(Total for question = 1 mark)

Q13.

Consider the reaction below.

2NO(g) + O2(g) → 2NO2(g)

What is the maximum volume, in dm3, of nitrogen dioxide that could be obtained in the reaction
occurring when 1 dm3 of nitrogen monoxide is mixed with 2 dm3 of oxygen, under suitable
conditions?

All measurements are made at the same temperature and pressure.

A 1

B 2

C 3

D 4

(Total for question = 1 mark)


Q14.

When 1.270 g of copper (Ar = 63.5) is added to excess silver nitrate solution, 4.316 g of silver (Ar
= 107.9) forms.

The ionic equation for the reaction is:

A Cu(s) + 2Ag+(aq) → Cu2+(aq) + 2Ag(s)

B 2Cu(s) + Ag2+(aq) → 2Cu+(aq) + Ag(s)

C Cu(s) + Ag2+(aq) → Cu2+(aq) + Ag(s)

D Cu(s) + Ag+(aq) → Cu+(aq) + Ag(s)

(Total for question = 1 mark)

Q15.

In which pair are the ions isoelectronic?

A Li+ and O2−

B Na+ and Cl−

C Mg2+ and S2−

D Al3+ and F−

(Total for question = 1 mark)

Q16.

What is the systematic name for the compound shown below?

A E-3-methylpent-2-ene
B E-3-methylpent-3-ene

C Z-3-methylpent-2-ene

D Z-3-methylpent-3-ene

(Total for question = 1 mark)

Q17.

Which ion has the smallest ionic radius?

A Cl−

B Ca2+

C K+

D S2−

(Total for question = 1 mark)

Q18.

The skeletal formula of 3-methylcyclobut-1-ene is shown below.

What is the skeletal formula of 1-ethyl-3-methylcyclopent-1-ene?


(Total for question = 1 mark)

Q19.

Ions with the same electronic configuration are said to be isoelectronic.

Which of the following compounds is made up of isoelectronic ions?

A CaO

B CaBr2

C Na2O

D LiF

(Total for question = 1 mark)


Q20.

Sea water contains 2.7 mg of sulfate ions per kilogram.

What is the concentration of sulfate ions in parts per million by mass?

(1)

A 2.7 × 10–6

B 2.7 × 10–3

C 2.7

D 2.7 × 103

(Total for question = 1 mark)

Q21.

The compound with the greatest covalent character is

(1)

A NaF

B NaI

C AlF3

D AlI3

(Total for question = 1 mark)

Q22.

Which row in the table shows the number of protons, neutrons and electrons in a fluoride ion, F–?
Use the Periodic Table as a source of data.

(Total for question = 1 marks)

Q23.

Which compound has E-Z isomers?

(1)

A but-1-ene

B but-2-ene

C 1,1-dichloroethene

D 2-methylbut-2-ene

(Total for question = 1 mark)

Q24.

In the electrolysis of copper(II) chromate(VI) solution, the colour that develops around the
positive electrode (anode) is

A orange.

B yellow.

C green.

D blue.
(Total for question = 1 mark)

Q25.

Which diagram best represents the electron densities in lithium iodide?

(Total for question = 1 mark)

Q26.

Which compound has an empirical formula different from its molecular formula?

(1)
(Total for question = 1 mark)

Q27.

What is the empirical formula of the oxide formed when 2.6 g of chromium produces 3.8 g of
chromium oxide?

Molar masses / g mol–1 Cr = 52.0, O = 16.0

(1)

A CrO

B CrO2

C Cr2O3

D Cr3O4

(Total for question = 1 mark)

Q28.

The empirical formula of poly(ethene) is

A CH
B CH2

C C2H4

D CnH2n

(Total for question = 1 mark)

Q29.

When ethane reacts with chlorine, a mixture of products forms. Which product is the best
evidence for a free radical mechanism?

A HCl

B C4H10

C C2H5Cl

D C2H4Cl2

(Total for question = 1 mark)

Q30.

Which of these statements is the best evidence for the existence of ions in sodium chloride?

A Solid sodium chloride conducts electricity.

B When an electric current is passed through a solution of sodium chloride, the movement
of the coloured ions is observed.

C Sodium chloride crystals have a regular shape.

D There is good agreement between theoretical and experimental lattice energies for
sodium chloride.

(Total for question = 1 mark)


Q31.

Which of the following graphs, not drawn to scale, best represents the trend in the melting
temperatures of the elements across Period 3, from sodium to argon?

(Total for question = 1 mark)


Q32.

The first six ionization energies, in kJ mol–1, of an element are

1086, 2353, 4621, 6223, 37832, 47278

In which group of the Periodic Table is this element?

A 2

B 3

C 4

D 5

(Total for question = 1 marks)

Q33.

Copolymers are formed from two different monomers.

The repeat unit of a copolymer is

This copolymer is formed from ethene and

(1)

A propane.

B propene.

C 2-methylbutane.

D 2-methylbut-1-ene.

(Total for question = 1 mark)


Q34.

Which is a free radical?

A OH

B OH−

C OH2

D OH

(Total for question = 1 mark)

Q35.

Which of the following is a reforming reaction?

(Total for question = 1 mark)

Q36.
Which of the following is a step in the propagation stage of the chlorination of methane?

(Total for question = 1 mark)

Q37.

In the mechanism of the reaction of methane with chlorine to form chloromethane, which of the
following is a propagation step?

A •CH3 + •Cl →CH3Cl

B •CH3 + Cl2→ CH3Cl + •Cl

C CH4 + •Cl → CH3Cl + •H

D •CH3+ Cl2 → •CH2Cl + HCl

(Total for question = 1 mark)

Q38.

What is the equation for the lattice energy of magnesium chloride?

A Mg(s) + Cl2(g) → MgCl2(s)

B Mg2+(s) + 2Cl–(g) → MgCl2(s)

C Mg2+(g) + 2Cl–(g) → MgCl2(s)

D Mg2+(g) + 2Cl–(g) → MgCl2(g)


(Total for question = 1 mark)

Q39.

What is the IUPAC name of the following hydrocarbon?

A 2,2-dipropylbutane

B 4-methyl-4-propylhexane

C 2-ethyl-2-propylpentane

D 4-ethyl-4-methylheptane

(Total for question = 1 mark)

Q40.

Which of the following fuels, when burned, would make no significant contribution to climate
change?

A Hydrogen

B Methane

C Petrol

D Coal

(Total for question = 1 mark)


Q41.

The bonding in solid ammonium chloride is

A ionic only.

B ionic and covalent only.

C ionic and dative covalent only.

D ionic, covalent and dative covalent only.

(Total for question = 1 mark)

Q42.

An electrophile is a species that

A can accept a pair of electrons to form a covalent bond.

B can donate a pair of electrons to form a covalent bond.

C always has a negative charge.

D always has a positive charge.

(Total for question = 1 mark)

Q43.

Alkenes react with hydrogen gas in the presence of a nickel catalyst.

0.2 mol of an alkene reacted completely with 19.2 dm3 of hydrogen gas at room temperature
and pressure.

How many bonds are there in a molecule of this alkene?

[The molar volume of a gas is 24.0 dm3 mol−1 at room temperature and pressure]
A 4

B 3

C 2

D 1

(Total for question = 1 mark)

Q44.

Which of the following has the smallest ionic radius?

A O2–

B F–

C Na+

D Mg2+

(Total for question = 1 mark)

Q45.

Solutions of barium chloride and silver nitrate are mixed together. The reaction that takes place
is an example of

A displacement.

B neutralization.

C oxidation.

D precipitation.

(Total for question = 1 mark)


Q46.

10 g of magnesium is added to 1 dm3 of 1 mol dm−3 copper(II) sulfate solution and the mixture is
stirred until no further reaction occurs.

Which of the following is a result of this reaction?

A The resulting solution is colourless.

B 10 g of copper is displaced.

C 63.5 g of copper is displaced.

D All the magnesium reacts.

(Total for question = 1 mark)

Q47.

Calcium chloride can be prepared by reacting calcium carbonate with dilute hydrochloric acid.

CaCO3(s) + 2HCl(aq) → CaCl2(aq) + H2O(l) + CO2(g)

(a) The ionic equation for the reaction is

(1)

(b) An excess of calcium carbonate is used in the preparation. The sequence of processes
needed to obtain crystals of calcium chloride from the reaction mixture is

(1)

A filtering, concentrating the solution, slowly evaporating.

B filtering, slowly evaporating, distilling.


C concentrating the solution, filtering, distilling.

D concentrating the solution, slowly evaporating, filtering.

(c) The excess calcium carbonate was added to 100 cm3 of 2.00 mol dm–3 hydrochloric acid. The
mass of calcium chloride crystals obtained was 10.4 g.

Molar mass of calcium chloride crystals, CaCl2.2H2O = 147 g mol–1.

The percentage yield, by mass, of calcium chloride crystals is

(1)

A 71.2

B 70.7

C 35.4

D 17.7

(Total for question = 3 marks)

Q48.

Which ion has the largest ionic radius?

(1)

A Ca2+

B Cl–

C K+

D S2–

(Total for question = 1 mark)

Q49.
What is the sequence of the orbitals from which electrons are removed in the first four
ionisations of boron?

(1)

(Total for question = 1 mark)

Q50.

How many ions are in 284 g of sodium sulfate, Na2SO4?

Avogadro constant = 6.0 × 1023 mol–1

Molar mass of sodium sulfate = 142 g mol–1

(1)

A 1.2 × 1024

B 2.4 × 1024

C 3.6 × 1024

D 8.4 × 1024

(Total for question = 1 mark)

Q51.

Which equation represents the lattice energy of magnesium nitride, Mg3N2?


A 3Mg(s) + N2(g) → Mg3N2(s)

B 3Mg(g) + 2N(g) → Mg3N2(s)

C 3Mg2+(g) + 2N3−(g) → Mg3N2(g)

D 3Mg2+(g) + 2N3−(g) → Mg3N2(s)

(Total for question = 1 mark)

Q52.

Identify the atom with two unpaired electrons in its lowest energy state (ground state).

(1)

A Be

B C

C Cl

D Ca

(Total for question = 1 mark)

Q53.

Consider the reaction

2SO2(g) + O2(g) → 2SO3(g)

What is the maximum volume, in dm3, of sulfur trioxide that could be obtained when 0.5 dm3 of
sulfur dioxide is mixed with 1 dm3 of oxygen, under suitable conditions?

All measurements are made at the same temperature and pressure.

(1)

A 0.5
B 1.5

C 2.0

D 2.5

(Total for question = 1 mark)

Q54.

In the United Kingdom, the limit for gaseous hydrocarbons in vehicle exhaust gases is 200 ppm.

What is the maximum volume of gaseous hydrocarbons allowed in 10 mol of exhaust gases, at
room temperature and pressure?

[Molar volume = 24 dm3 mol–1]

A 24 cm3

B 48 cm3

C 96 cm3

D 480 cm3

(Total for question = 1 mark)

Q55.

Which of the following series shows the elements in order of increasing melting temperature?

(1)

A Li, Na, K

B Al, Si, P

C Na, Mg, Al

D S, Cl, Ar
(Total for question = 1 mark)

Q56.

Phenol, C6H5OH, is converted into trichlorophenol (known as TCP), C6H2Cl3OH, according to the
equation below.

C6H5OH + 3Cl2 → C6H2Cl3OH + 3HCl

If 50.0 g of phenol produces 97.6 g of TCP, what is the percentage yield of the TCP?

[Molar masses: phenol = 94 g mol−1; TCP = 197.5 g mol−1]

A 47.6%

B 49.4%

C 51.2%

D 92.9%

(Total for question = 1 mark)

Q57.

Ammonia is manufactured from hydrogen and nitrogen in the Haber process.

If 60 tonnes of hydrogen produces 80 tonnes of ammonia, what is the percentage yield in the
reaction?

A
× 100%

B
× 100%

C
× 100%
D
× 100%

(Total for question = 1 mark)

Q58.

In which order do the electrons fill the orbitals of an atom?

A 1s 2s 2p 3s 3p 4s 4p 3d

B 1s 2s 2p 3s 3d 3p 4s 4p

C 1s 2s 2p 3s 3p 3d 4s 4p

D 1s 2s 2p 3s 3p 4s 3d 4p

(Total for question = 1 mark)

Q59.

Ions are separated in the mass spectrometer by

A a vacuum pump.

B a magnetic field.

C an ionization chamber.

D electron bombardment.

(Total for question = 1 mark)


Q60.

16 17 18
A sample of oxygen contains the isotopes O, O, O.

How many peaks would there be for the O ions in the mass spectrum of this sample of oxygen?

A 3

B 5

C 6

D 9

(Total for question = 1 marks)

Q61.

Propene reacts with hydrogen bromide to form

(1)

A a mixture of 1-bromopropane and 2-bromopropane

B 1,2-dibromopropane

C 2-bromopropan-1-ol

D 1-bromopropan-2-ol

(Total for question = 1 mark)

Q62.

Which reagent reacts with propene to form this compound?

(1)
A hydrogen peroxide solution

B oxygen and water

C aqueous sodium hydroxide

D acidified potassium manganate(VII)

(Total for question = 1 mark)

Q63.

An ion, X−, contains 36 electrons.

In which block of the Periodic Table would element X be found?

A s

B p

C d

D f

(Total for question = 1 mark)

Q64.

Some energy changes involved in a Born-Haber cycle are

A electron affinity

B lattice energy

C standard enthalpy change of atomization

D standard enthalpy change of formation

(a) Which enthalpy or energy change is represented by p?


K(s) → K(g) ΔH =p

(1)

(b) Which enthalpy or energy change is represented by q?

=q
K(s) + ½Cl2(g) → KCl(s) ΔH

(1)

(c) Which enthalpy or energy change is represented by r?

½Cl2(g) → Cl(g) ΔH = r

(1)

(Total for question = 3 marks)

Q65.

Which one of the following ions has the smallest radius?

A F−

B Mg2+
C Na+

D O2−

(Total for question = 1 mark)

Q66.

Each diagram shows the trend in the ionic radius for four sequences of ions.
The diagrams are not to scale.

(a) Which diagram shows the trend in the ionic radius for the sequence Li+, Na+, K+, Rb+?

(1)

(b) Which diagram shows the trend in the ionic radius for the sequence Na+, Mg2+, Al3+, Si4+?
(1)

(Total for question = 2 marks)

Q67.

The atomic radius of potassium is larger than that of sodium because potassium has

A a larger nuclear charge.

B a larger nucleus.

C more occupied electron shells.

D a smaller first ionization energy.

(Total for question = 1 mark)

Q68.

Which quantity is exothermic?

A Enthalpy change of atomisation of sulfur.

B First ionisation energy of sulfur.

C First electron affinity of sulfur.

D Second electron affinity of sulfur.

(Total for question = 1 mark)


Q69.

Which hazard symbol must be displayed on a bottle containing hexane?

(Total for question = 1 mark)

Q70.

Which of the following equations represents a step that is not involved in the Born-Haber cycle
for lithium iodide, LiI?

A Li(s) + ½I2(s) → LiI(s)

B ½I2(s) → I(g)

C Li(s) → Li(g)
D I(g) → I+(g) + e−

(Total for question = 1 mark)

Q71.

How many straight chain isomers have the molecular formula C3H5Cl?

A 3

B 4

C 5

D 6

(Total for question = 1 mark)

Q72.

What is the systematic name for the hydrocarbon shown?

(1)

A 2,2-dimethyl-4-ethylpentane

B 2-ethyl-4,4-dimethylpentane

C 3,5,5-trimethylhexane
D 2,2,4-trimethylhexane

(Total for question = 1 mark)

Q73.

The Avogadro constant is equal to the number of

A atoms in one mole of any element.

B atoms in one mole of any monatomic element.

C atoms in one mole of any compound.

D ions in one mole of an ionic compound.

(Total for question = 1 mark)

Q74.

The process with the highest atom economy is the production of

A propene by cracking eicosane, C20H42.

B 1-chloropropane from propane and chlorine.

C cyclohexene by reforming hexane.

D poly(propene) by polymerising propene.

(Total for question = 1 mark)


Q75.

The following statements give information about the thermodynamic stability of magnesium
chlorides.

MgCl is stable with respect to chlorine and magnesium.


MgCl is unstable with respect to MgCl2 and Mg.
MgCl3 is unstable with respect to chlorine and magnesium.

Which signs of the standard enthalpy changes of formation of MgCl and MgCl3 are correct?

(Total for question = 1 mark)

Q76.

In the reaction of methane with chlorine, ultraviolet light causes

A homolytic fission of the Cl—Cl bond in chlorine molecules.

B heterolytic fission of the Cl—Cl bond in chlorine molecules.

C homolytic fission of the C—H bond in methane molecules.

D heterolytic fission of the C—H bond in methane molecules.

(Total for question = 1 mark)

Q77.
The Avogadro constant is numerically equal to the number of

A ions in 1 mol of sodium chloride, NaCl

B atoms in 1 mol of hydrogen gas, H2

C electrons in 1 mol of helium gas, He

D molecules in 1 mol of oxygen gas, O2

(Total for question = 1 mark)

Q78.

The Avogadro constant is equal to the number of

A grams of an element which contains 6.02 × 1023 atoms of that element.

B atoms contained in one mole of any element.

C atoms contained in one mole of any monatomic element.

D particles (atoms, ions or molecules) required to make one gram of a substance.

(Total for question = 1 mark)

Q79.

A molecule of Z has the following structure:

What are the total numbers of σ-bonds and π-bonds in a molecule of Z?


(Total for question = 1 mark)

Q80.

The diagram, which is not drawn to scale, shows the Born-Haber cycle for potassium chloride.
The energy changes given are in kJ mol−1.

What is the value for W, in kJ mol−1?

A −956

B −82

C +82
D +956

(Total for question = 1 mark)

Q81.

Carbon (diamond) and oxygen both form covalent bonds between their atoms in the element.

What is the best reason for the fact that diamond has a much higher melting temperature than
oxygen?

A Diamond is a solid but oxygen is a gas at room temperature.

B Diamond has a giant atomic structure but oxygen has a simple molecular structure.

C The covalent bonds between carbon atoms in diamond are stronger than those between
oxygen atoms.

D There is a single covalent bond between carbon atoms in diamond but a double covalent
bond between oxygen atoms.

(Total for question = 1 mark)

Q82.

Potassium combines with iodine to form potassium iodide.

Which of the following describes the bonding in the three substances?


(Total for question = 1 mark)

Q83.

Which species has a dative covalent bond?

A H3O+

B H2O

C OH−

D O2

(Total for question = 1 mark)

Q84.

Which of the following contains a dative covalent bond?

A N2

B NH3

(Total for question = 1 mark)

Q85.

One of the isomers with the formula C4H8 is


Possible names for this isomer are

A cis-but-2-ene and E-but-2-ene.

B cis-but-2-ene and Z-but-2-ene.

C trans-but-2-ene and E-but-2-ene.

D trans-but-2-ene and Z-but-2-ene.

(Total for question = 1 mark)

Q86.

In an experiment, 3.425 g of lead oxide was reduced to form 3.105 g of lead.

The empirical formula of the lead oxide is

A PbO

B Pb3O2

C Pb3O4

D Pb4O3

(Total for question = 1 mark)

Q87.

Which of the following shows geometric isomerism?

A propene

B but-1-ene
C but-2-ene

D 2,3-dimethylbut-2-ene

(Total for question = 1 mark)

Q88.

Which of the following compounds has the greatest ionic character?

A Caesium fluoride

B Caesium iodide

C Potassium fluoride

D Potassium iodide

(Total for question = 1 mark)

Q89.

Magnesium chloride crystals were prepared using the following reaction.

2HCl(aq) + MgO(s) → MgCl2(aq) + H2O(l)

(a) The ionic equation for this reaction is

(1)

A 2Cl–(aq) + Mg2+(s) → MgCl2(aq)

B 2Cl–(aq) + MgO(s) → MgCl2(aq) + O2–(l)

C 2H+(aq) + 2Cl–(aq) + MgO(s)→ Mg2+(Cl–)2(aq) + H2O(l)

D 2H+(aq) + MgO(s) → Mg2+(aq) + H2O(l)

(b) The amount of hydrochloric acid used was 0.10 mol. Which of the following solutions of
hydrochloric acid contains this amount of HCl?
(1)

A 100 cm3 of 0.10 mol dm–3

B 40 cm3 of 0.25 mol dm–3

C 25 cm3 of 0.40 mol dm–3

D 20 cm3 of 5.00 mol dm–3

(c) An excess of magnesium oxide was reacted with the 0.10 mol of hydrochloric acid.

Which of the following is the smallest mass which would provide an excess of magnesium
oxide?

Molar mass of MgO = 40.3 g mol–1

(1)

A 1.50 g

B 2.50 g

C 3.00 g

D 5.00 g

(d) What is the first step in obtaining pure hydrated crystals of magnesium chloride from the
resulting reaction mixture?

(1)

A Heating the mixture to concentrate it.

B Allowing the mixture to evaporate slowly.

C Filtering the mixture.

D Distilling the mixture.

(e) Use the data below to calculate the number of moles of water of crystallization in each mole
of hydrated magnesium chloride.

(1)

A 2

B 4
C 6

D 8

(Total for question = 5 marks)

Q90.

A hydrocarbon contains, by mass, 82.7% carbon and 17.3% hydrogen.

The molecular formula of the hydrocarbon is

A CH3

B C2H6

C C2H5

D C4H10

(Total for question = 1 mark)

Q91.

Which of the following contains one mole of neutrons?

A 1 g of H

B 1 g of C

C 2 g of Mg

D 2 g of Ne

(Total for question = 1 mark)


Q92.

The experimental value for the lattice energy of beryllium iodide is −2800 kJ mol−1 and the
theoretical value is −2653 kJ mol−1.

The best explanation for the difference is that the

A beryllium ion is large and polarizes the iodide ion.

B beryllium ion is small and polarizes the iodide ion.

C iodide ion is large and polarizes the beryllium ion.

D iodide ion is small and polarizes the beryllium ion.

(Total for question = 1 mark)

Q93.

2000 g of a solution contains 0.015 g of solute.

In the solution, the concentration of the solute in parts per million (ppm) is

A 3.0

B 7.5

C 30

D 75

(Total for question = 1 marks)

Q94.

Which row in the table shows the lattice energies, in kJ mol−1, of calcium fluoride, potassium
fluoride and potassium iodide?
(Total for question = 1 mark)

Q95.

Which of the following results in the most polarizing cation?

(Total for question = 1 mark)

Q96.

Which of the following does not represent the structure of the compound 2-methylpent-2-ene?
(Total for question = 1 mark)

Q97.

Which is the structure of Z-1,2-dibromoprop-1-ene?


(Total for question = 1 mark)

Q98.

A solution contains 33 ppm of solute. The mass of solute dissolved in 1 kg of this solution is

A 33 g

B 0.33 g

C 0.033 g

D 0.000033 g

(Total for question = 1 mark)


Q99.

Cold water fish require a minimum of 8 parts per million by mass (ppm) of oxygen dissolved in
water.

The minimum mass of oxygen required in 1 kg of water is

A 8 × 10–6 g

B 8 × 10–3 g

C 8 × 10–2 g

D 8 × 10–1 g

(Total for question = 1 mark)

Q100.

Calcium carbonate reacts with dilute nitric acid as follows:

CaCO3(s) + 2HNO3(aq) → Ca(NO3)2(aq) + H2O(l) + CO2(g)

0.05 mol of calcium carbonate was added to a solution containing 0.08 mol of nitric acid.

Which of the following statements is true?

A 0.05 mol of carbon dioxide is produced.

B 0.08 mol of calcium nitrate is produced.

C Calcium carbonate is in excess by 0.01 mol.

D Nitric acid is in excess by 0.03 mol.

(Total for question = 1 mark)

Q101.

If the price of one tonne (1000 kg) of sulfur, S, is £160, what is the cost (to the nearest pound) of
the sulfur needed to make one tonne of sulfuric acid, H2SO4?

A £52

B £98

C £160

D £490

(Total for question = 1 mark)

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