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Q1.
What is the final volume of the gas mixture, in cm3, when all volumes are measured at room
temperature and pressure?
A 100
B 200
C 300
D 400
Q2.
A compound has the composition by mass of 54.5% C, 9.1% H and 36.4% O. What is its empirical
formula?
A C2 H2 O
B C2H4O
C C4H9O
D C6HO4
Q3.
Sodium hydrogencarbonate decomposes on heating.
What is the maximum volume of carbon dioxide, in dm3, which could be obtained by heating
0.25 mol sodium hydrogencarbonate?
The gas volume is measured at room temperature and pressure when the molar volume of a gas
= 24 dm3 mol–1.
A 3
B 6
C 12
D 24
Q4.
50 cm3 of hydrogen is mixed with 25 cm3 of chlorine. The gases react as shown in the equation
below.
What is the total volume of gas present at the end of the reaction?
[All gas volumes are measured at the same temperature and pressure.]
A 75 cm3
B 100 cm3
C 125 cm3
D 150 cm3
Which of the following gas samples has the same volume as 7.0 g of carbon monoxide?
A 1.0 g of hydrogen
B 3.5 g of nitrogen
C 10.0 g of argon
D 35.5 g of chlorine
Q6.
How many moles of ions are present in 30 cm3 of 0.025 mol dm–3 barium hydroxide solution,
Ba(OH)2(aq)?
A 0.00075
B 0.00150
C 0.00225
D 0.00450
Q7.
Which of the following aqueous solutions contains the greatest number of negative ions?
Q8.
In the synthesis of ammonia, 56.0 g nitrogen was reacted with excess hydrogen.
A 5.66
B 8.82
C 9.10
D 10.7
Q9.
Calculate the empirical formula of the compound with the percentage composition by mass:
Li = 17.9%; P = 26.8%; O = 55.3%
(1)
A Li2P3O6
B Li3PO3
C LiPO3
D Li3PO4
(Total for question = 1 mark)
Q10.
In an experiment carried out at 200°C and 1 atm pressure, 20 cm3 of ammonia gas reacted with
an excess of heated copper(II) oxide.
If all measurements were made at 200°C and 1 atm pressure, what would be the total volume, in
cm3, of gaseous products?
A 10
B 20
C 30
D 40
Q11.
What is the concentration, in mol dm–3, of a solution of 10.6 g of sodium carbonate, Na2CO3, in
250 cm3 of solution?
A 0.40
B 0.25
C 0.10
D 0.025
In which of the following pairs does each gas occupy the same volume?
Q13.
What is the maximum volume, in dm3, of nitrogen dioxide that could be obtained in the reaction
occurring when 1 dm3 of nitrogen monoxide is mixed with 2 dm3 of oxygen, under suitable
conditions?
A 1
B 2
C 3
D 4
When 1.270 g of copper (Ar = 63.5) is added to excess silver nitrate solution, 4.316 g of silver (Ar
= 107.9) forms.
Q15.
D Al3+ and F−
Q16.
A E-3-methylpent-2-ene
B E-3-methylpent-3-ene
C Z-3-methylpent-2-ene
D Z-3-methylpent-3-ene
Q17.
A Cl−
B Ca2+
C K+
D S2−
Q18.
Q19.
A CaO
B CaBr2
C Na2O
D LiF
(1)
A 2.7 × 10–6
B 2.7 × 10–3
C 2.7
D 2.7 × 103
Q21.
(1)
A NaF
B NaI
C AlF3
D AlI3
Q22.
Which row in the table shows the number of protons, neutrons and electrons in a fluoride ion, F–?
Use the Periodic Table as a source of data.
Q23.
(1)
A but-1-ene
B but-2-ene
C 1,1-dichloroethene
D 2-methylbut-2-ene
Q24.
In the electrolysis of copper(II) chromate(VI) solution, the colour that develops around the
positive electrode (anode) is
A orange.
B yellow.
C green.
D blue.
(Total for question = 1 mark)
Q25.
Q26.
Which compound has an empirical formula different from its molecular formula?
(1)
(Total for question = 1 mark)
Q27.
What is the empirical formula of the oxide formed when 2.6 g of chromium produces 3.8 g of
chromium oxide?
(1)
A CrO
B CrO2
C Cr2O3
D Cr3O4
Q28.
A CH
B CH2
C C2H4
D CnH2n
Q29.
When ethane reacts with chlorine, a mixture of products forms. Which product is the best
evidence for a free radical mechanism?
A HCl
B C4H10
C C2H5Cl
D C2H4Cl2
Q30.
Which of these statements is the best evidence for the existence of ions in sodium chloride?
B When an electric current is passed through a solution of sodium chloride, the movement
of the coloured ions is observed.
D There is good agreement between theoretical and experimental lattice energies for
sodium chloride.
Which of the following graphs, not drawn to scale, best represents the trend in the melting
temperatures of the elements across Period 3, from sodium to argon?
A 2
B 3
C 4
D 5
Q33.
(1)
A propane.
B propene.
C 2-methylbutane.
D 2-methylbut-1-ene.
A OH
B OH−
C OH2
D OH
Q35.
Q36.
Which of the following is a step in the propagation stage of the chlorination of methane?
Q37.
In the mechanism of the reaction of methane with chlorine to form chloromethane, which of the
following is a propagation step?
Q38.
Q39.
A 2,2-dipropylbutane
B 4-methyl-4-propylhexane
C 2-ethyl-2-propylpentane
D 4-ethyl-4-methylheptane
Q40.
Which of the following fuels, when burned, would make no significant contribution to climate
change?
A Hydrogen
B Methane
C Petrol
D Coal
A ionic only.
Q42.
Q43.
0.2 mol of an alkene reacted completely with 19.2 dm3 of hydrogen gas at room temperature
and pressure.
[The molar volume of a gas is 24.0 dm3 mol−1 at room temperature and pressure]
A 4
B 3
C 2
D 1
Q44.
A O2–
B F–
C Na+
D Mg2+
Q45.
Solutions of barium chloride and silver nitrate are mixed together. The reaction that takes place
is an example of
A displacement.
B neutralization.
C oxidation.
D precipitation.
10 g of magnesium is added to 1 dm3 of 1 mol dm−3 copper(II) sulfate solution and the mixture is
stirred until no further reaction occurs.
B 10 g of copper is displaced.
Q47.
Calcium chloride can be prepared by reacting calcium carbonate with dilute hydrochloric acid.
(1)
(b) An excess of calcium carbonate is used in the preparation. The sequence of processes
needed to obtain crystals of calcium chloride from the reaction mixture is
(1)
(c) The excess calcium carbonate was added to 100 cm3 of 2.00 mol dm–3 hydrochloric acid. The
mass of calcium chloride crystals obtained was 10.4 g.
(1)
A 71.2
B 70.7
C 35.4
D 17.7
Q48.
(1)
A Ca2+
B Cl–
C K+
D S2–
Q49.
What is the sequence of the orbitals from which electrons are removed in the first four
ionisations of boron?
(1)
Q50.
(1)
A 1.2 × 1024
B 2.4 × 1024
C 3.6 × 1024
D 8.4 × 1024
Q51.
Q52.
Identify the atom with two unpaired electrons in its lowest energy state (ground state).
(1)
A Be
B C
C Cl
D Ca
Q53.
What is the maximum volume, in dm3, of sulfur trioxide that could be obtained when 0.5 dm3 of
sulfur dioxide is mixed with 1 dm3 of oxygen, under suitable conditions?
(1)
A 0.5
B 1.5
C 2.0
D 2.5
Q54.
In the United Kingdom, the limit for gaseous hydrocarbons in vehicle exhaust gases is 200 ppm.
What is the maximum volume of gaseous hydrocarbons allowed in 10 mol of exhaust gases, at
room temperature and pressure?
A 24 cm3
B 48 cm3
C 96 cm3
D 480 cm3
Q55.
Which of the following series shows the elements in order of increasing melting temperature?
(1)
A Li, Na, K
B Al, Si, P
C Na, Mg, Al
D S, Cl, Ar
(Total for question = 1 mark)
Q56.
Phenol, C6H5OH, is converted into trichlorophenol (known as TCP), C6H2Cl3OH, according to the
equation below.
If 50.0 g of phenol produces 97.6 g of TCP, what is the percentage yield of the TCP?
A 47.6%
B 49.4%
C 51.2%
D 92.9%
Q57.
If 60 tonnes of hydrogen produces 80 tonnes of ammonia, what is the percentage yield in the
reaction?
A
× 100%
B
× 100%
C
× 100%
D
× 100%
Q58.
A 1s 2s 2p 3s 3p 4s 4p 3d
B 1s 2s 2p 3s 3d 3p 4s 4p
C 1s 2s 2p 3s 3p 3d 4s 4p
D 1s 2s 2p 3s 3p 4s 3d 4p
Q59.
A a vacuum pump.
B a magnetic field.
C an ionization chamber.
D electron bombardment.
16 17 18
A sample of oxygen contains the isotopes O, O, O.
How many peaks would there be for the O ions in the mass spectrum of this sample of oxygen?
A 3
B 5
C 6
D 9
Q61.
(1)
B 1,2-dibromopropane
C 2-bromopropan-1-ol
D 1-bromopropan-2-ol
Q62.
(1)
A hydrogen peroxide solution
Q63.
A s
B p
C d
D f
Q64.
A electron affinity
B lattice energy
(1)
=q
K(s) + ½Cl2(g) → KCl(s) ΔH
(1)
½Cl2(g) → Cl(g) ΔH = r
(1)
Q65.
A F−
B Mg2+
C Na+
D O2−
Q66.
Each diagram shows the trend in the ionic radius for four sequences of ions.
The diagrams are not to scale.
(a) Which diagram shows the trend in the ionic radius for the sequence Li+, Na+, K+, Rb+?
(1)
(b) Which diagram shows the trend in the ionic radius for the sequence Na+, Mg2+, Al3+, Si4+?
(1)
Q67.
The atomic radius of potassium is larger than that of sodium because potassium has
B a larger nucleus.
Q68.
Q70.
Which of the following equations represents a step that is not involved in the Born-Haber cycle
for lithium iodide, LiI?
B ½I2(s) → I(g)
C Li(s) → Li(g)
D I(g) → I+(g) + e−
Q71.
How many straight chain isomers have the molecular formula C3H5Cl?
A 3
B 4
C 5
D 6
Q72.
(1)
A 2,2-dimethyl-4-ethylpentane
B 2-ethyl-4,4-dimethylpentane
C 3,5,5-trimethylhexane
D 2,2,4-trimethylhexane
Q73.
Q74.
The following statements give information about the thermodynamic stability of magnesium
chlorides.
Which signs of the standard enthalpy changes of formation of MgCl and MgCl3 are correct?
Q76.
Q77.
The Avogadro constant is numerically equal to the number of
Q78.
Q79.
Q80.
The diagram, which is not drawn to scale, shows the Born-Haber cycle for potassium chloride.
The energy changes given are in kJ mol−1.
A −956
B −82
C +82
D +956
Q81.
Carbon (diamond) and oxygen both form covalent bonds between their atoms in the element.
What is the best reason for the fact that diamond has a much higher melting temperature than
oxygen?
B Diamond has a giant atomic structure but oxygen has a simple molecular structure.
C The covalent bonds between carbon atoms in diamond are stronger than those between
oxygen atoms.
D There is a single covalent bond between carbon atoms in diamond but a double covalent
bond between oxygen atoms.
Q82.
Q83.
A H3O+
B H2O
C OH−
D O2
Q84.
A N2
B NH3
Q85.
Q86.
A PbO
B Pb3O2
C Pb3O4
D Pb4O3
Q87.
A propene
B but-1-ene
C but-2-ene
D 2,3-dimethylbut-2-ene
Q88.
A Caesium fluoride
B Caesium iodide
C Potassium fluoride
D Potassium iodide
Q89.
(1)
(b) The amount of hydrochloric acid used was 0.10 mol. Which of the following solutions of
hydrochloric acid contains this amount of HCl?
(1)
(c) An excess of magnesium oxide was reacted with the 0.10 mol of hydrochloric acid.
Which of the following is the smallest mass which would provide an excess of magnesium
oxide?
(1)
A 1.50 g
B 2.50 g
C 3.00 g
D 5.00 g
(d) What is the first step in obtaining pure hydrated crystals of magnesium chloride from the
resulting reaction mixture?
(1)
(e) Use the data below to calculate the number of moles of water of crystallization in each mole
of hydrated magnesium chloride.
(1)
A 2
B 4
C 6
D 8
Q90.
A CH3
B C2H6
C C2H5
D C4H10
Q91.
A 1 g of H
B 1 g of C
C 2 g of Mg
D 2 g of Ne
The experimental value for the lattice energy of beryllium iodide is −2800 kJ mol−1 and the
theoretical value is −2653 kJ mol−1.
Q93.
In the solution, the concentration of the solute in parts per million (ppm) is
A 3.0
B 7.5
C 30
D 75
Q94.
Which row in the table shows the lattice energies, in kJ mol−1, of calcium fluoride, potassium
fluoride and potassium iodide?
(Total for question = 1 mark)
Q95.
Q96.
Which of the following does not represent the structure of the compound 2-methylpent-2-ene?
(Total for question = 1 mark)
Q97.
Q98.
A solution contains 33 ppm of solute. The mass of solute dissolved in 1 kg of this solution is
A 33 g
B 0.33 g
C 0.033 g
D 0.000033 g
Cold water fish require a minimum of 8 parts per million by mass (ppm) of oxygen dissolved in
water.
A 8 × 10–6 g
B 8 × 10–3 g
C 8 × 10–2 g
D 8 × 10–1 g
Q100.
0.05 mol of calcium carbonate was added to a solution containing 0.08 mol of nitric acid.
Q101.
If the price of one tonne (1000 kg) of sulfur, S, is £160, what is the cost (to the nearest pound) of
the sulfur needed to make one tonne of sulfuric acid, H2SO4?
A £52
B £98
C £160
D £490