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Practice Problems
As a supplement to our discussion, below are some practice problems on
the topic. We will work them out together in class if we don’t run out of
time.
1. Show that the reciprocal lattice of a BCC crystal is FCC and vice versa.
a. Why can first order X-Ray diffraction be observed from the (110)
planes of a BCC crystal but not from the (110) planes of an FCC
crystal? Derive the selection rules for which planes are observed
in BCC and FCC.
b. Show that these selection rules do not depend on the composing
atoms of the crystal. In other words, show that as long as the
structure is BCC or FCC, the selection rules derived in part (a)
will hold true.
c. A powdered sample of cubic metal palladium is characterized using
collimated monochromatic X-Ray beams with wavelength 0.162
nm. In the obtained scattering pattern, peaks are observed at
the following angles (from the direction of the incident beam):
42.3◦ 49.2◦ 72.2◦ 87.4◦ 92.3◦ . Identify the lattice type and calculate
the values of the lattice constant and nearest-neighbor distance.
d. Assuming there is only one atom inside the basis, do the values
calculated in part (c) agree with the known data for palladium
(density is 12023 kg · m−3 and atomic mass is 106.4)? Account for
any discrepancy and propose a way to minimize the error.
1
Use this information to calculate Avogadro’s number. How far off are
you from the accepted value? How can you account for this discrepancy?