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AS CHEMISTRY CHEMICAL BONDING.

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Name:-___________________________________________________

1 Sodium azide, NaN3 is an explosive used to inflate airbags in cars when they crash. It consists of
positive sodium ions and negative azide ions.

What are the numbers of electrons in the sodium ion and the azide ion?

sodium ion azide ion

A 10 20
B 10 22
C 12 20
D 12 22

2 The 68Ge isotope is medically useful because it undergoes a natural radioactive process to give
an isotope of a different element, 68X, which can be used to detect tumours. This transformation
of 68Ge occurs when an electron enters the nucleus and changes a proton into a neutron.

Which statement about the composition of an atom of 68X is correct?

A It has 4 electrons in its outer p orbitals.


B It has 13 electrons in its outer shell.
C It has 37 neutrons.
D Its proton number is 32.

3 When solid aluminium chloride is heated, Al 2Cl 6 is formed.

Which bonding is present in Al 2Cl 6?

A covalent and co-ordinate (dative covalent)


B covalent only
C ionic and co-ordinate (dative covalent)
D ionic only

4 Some car paints contain small flakes of silica, SiO2.

In the structure of solid SiO2

● each silicon atom is bonded to x oxygen atoms,


● each oxygen atom is bonded to y silicon atoms,
● each bond is a z type bond.

What is the correct combination of x, y and z in these statements?

x y z

A 2 1 covalent
B 2 1 ionic
C 4 2 covalent
D 4 2 ionic
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5 Copper and iodine are both shiny crystalline solids.

Which forces exist between particles in solid copper and between neighbouring iodine molecules
in solid iodine?

copper iodine

A ionic bonds covalent bonds


B ionic bonds van der Waals’ forces
C metallic bonds covalent bonds
D metallic bonds van der Waals’ forces

6 Use of the Data Booklet is relevant to this question.

In which set do all species contain the same number of electrons?

A Co2+, Co3+, Co4+


B F–, Br –, Cl –
C Na+, Mg2+, Al 3+
D K2SO4, K2SeO4, K2TeO4

77 Which diagram represents the overlap of two orbitals which will form a π bond?

D
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1. DRAW THE DOT AND CROSS DIAGRAMS OF THE FOLLOWING.

1. NO

2. CS2

3. N2H4

4. NaN3
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2. DRAW THE ORBITALS OVERLAPPING OF THE FOLLOWING.

(i) HF

(ii) F2

(iii) O2
DATA SHEET
The Periodic Table of the Elements
Group
I II III IV V VI VII 0
1 4
H He
Hydrogen Helium
1 2

7 9 11 12 14 16 19 20
Li Be B C N O F Ne
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
3 4 5 6 7 8 9 10

23 24 27 28 31 32 35.5 40
Na Mg Al Si P S Cl Ar
Sodium Magnesium Aluminium Silicon Phosphorus Sulphur Chlorine Argon
11 12 13 14 15 16 17 18

39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36

85 88 89 91 93 96 101 103 106 108 112 115 119 122 128 127 131

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

133 137 139 178 181 184 186 190 192 195 197 201 204 207 209
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Caesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
55 56 57 * 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

226 227
Fr Ra Ac
Francium Radium Actinium
87 88 89 †

(LGS,BSS,LACAS,ROOTS IVY,KIMS,LLC,GHA,LEADS)
140 141 144 150 152 157 159 162 165 167 169 173 175
*58-71 Lanthanoid series
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
†90-103 Actinoid series Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium
58 59 60 61 62 63 64 65 66 67 68 69 70 71
a a = relative atomic mass 232 238
Key X X = atomic symbol Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium
b b = proton (atomic) number 90 91 92 93 94 95 96 97 98 99 100 101 102 103

O/AS/A2/SATII/SSE/ ULTIMATE CHEMISTRY PREPARATION WITH ZAFAR IQBAL CH (0333


The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
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(0333-4227604)
O/AS/A2/SAT2/SSE/ ULTIMATE CHEMISTRY PREPARATION WITH ZAFAR IQBAL CH. 0333-4227604 (LGS,BSS,LACAS, ROOTS IVY, KIMS,LLC,GHA,LEADS)

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