Sunteți pe pagina 1din 5

ARGON

CASTING
FOR IMPROVING STEEL QUALITY
Tests have shown that complete argon atmosphere protection of molten
steel during ingot casting results in a 30 to 65 pct reduction in non-metallic
inclusions, a decrease of 3 to 24 pct in conditioning losses, and a preservation
of the effects of vacuum treatment.

by M. F. Hoffman, P. G. Bailey, and R. L. W. Holmes

C leanliness of metals and their dissolved gas


contents have become increasingly important
cause of this increased viscosity and because of the
short time between teem and actual solidification,
to metal producers and users. As the physical prop- the inclusions are unable to float to the surface and
erty requirements of high-quality metals and alloys are trapped in the body of the ingot. Argon protec-
become more and more stringent, increased atten- tion of the teem stream prevents these oxides from
tion must be devoted to non-metallic inclusions and forming.
dissolved gases which adversely affect these physical In addition, the argon atmosphere in the mold
properties. Measurable progress has been made in protects molten metal splash from oxidation thus
attaining higher quality product by close control of allowing the metal droplets adhering to the mold
melting practice and by special treatments. However, wall to remelt into the rising metal. The occurrence
in most processing practices the molten metal is of scabs and laps is thus reduced. The oxide surface
exposed to air in the final step of casting ingots. This formed on droplets during air casting slows heat
exposure to air can be eliminated by argon casting, transfer across the droplet surface and impedes re-
now developed as an economical and practical tech- melting of the droplet. Reduction in droplet oxida-
nique for providing inert gas protection to molten tion also reduces the occurrence of hot working
metal during casting. This process has proven bene- cracks at non-metallic discontinuities in the ingot
ficial in protecting aircraft quality, forging grade, surface. Increased metal yield and reduced condi-
stainless, and specialty steels and nickel-base alloys. tioning costs can thus be realized.
With ladle vacuum-treated steels the effcts of the Vacuum treatment is used to reduce dissolved hy-
degassing treatment are preserved. drogen, oxygen, and nitrogen in steels. When vac-
Recent literature' -5 points out that a large portion uum-treated metal is teemed in air some of the bene-
of the non-metallic inclusions existing in the ingot fits of the treatment are lost by exposure to the at-
have their origin in the teeming operation. This is mospheric gases. Unless adequate protection is pro-
shown by radioactive tracer studies which conclude vided, the high metal temperature, large exposed
that only 4 to 18 pct of ingot inclusions come from molten-metal surfaces, and the low gas content of
ladle and pouring refractory erosion. It is believed the treated metal provide' a strong drivi-ng force
that the teem stream contributes a much greater towards resolution of atmospheric gases. The pro-
portion of non-metallic inclusions because of the tection provided by argon casting thus becomes de-
large surface area exposed to oxidation. A ton of sirable in the handling of vacuum-treated metal.
steel passing through a 1lj2 in. diam nozzle as a
liquid cylinder has 144 sq ft of surface area exposed Process
in the ladle to mold stream. Actually the falling Argon casting provides complete inert-atmosphere
stream does not remain a cylinder but tends to break protection of the metal throughout the casting oper-
up thereby exposing an even greater surface area. ation. Two distinct steps-mold purging and teem
As the metal fills the mold, the oxides formed by stream shrouding-are involved. Purging the mold
exposure to air are dispersed by the metal agitation. insures inert or protected starting conditions.
Metal temperature in the mold decreases rapidly Shrouding the teem stream with argon maintains
thereby increasing the viscosity of the metal. Be- an inert atmosphere during the filling of the mold
and protects the high surface area teem stream from
M. F. HOFFMAN, P. G. BAILEY, and R. L. W. HOLMES are with ladle to mold. Previous attempts at argon-protected
the Newark Development Laboratory of Linde Co., a div. of Union casting usually used either mold purging or stream
Carbide Corp. This paper was presented at the Eighteenth Annual shrouding but not both. A sacrifice in atmosphere
Electric Furnace Conference.
quality or an excessive consumption of argon re-

MAY 1961, JOURNAL OF METALS-345


sulted. Included among these early procedures were /
./
lance pipe purging of uncovered and unsealed molds 440
/'
/
and directing jets of argon through air toward the 40 0
f---- 500cr.~.+- IOOOC.F.~y- C.F.H~2000 C.F.H.
1500
~
metal stream. Development of the process described •• 0
......::2.00C~
in this paper started out in much the same manner, 0

but the use of an oxygen analyzer for mold atmos- ,,280


/ ./
../ ../
.Y

~ L ./ V /""
phere monitoring indicated the inadequacy of these

--
824 0
ill ../ V ~
approaches. ~20 0
/"" L
3000C.F.H.-
./ ../
Two requirements must be fulfilled in establish- i= 16 0 ,,/ ....--:

-
ing a truly inert atmosphere effectively and effi- .20 .-/- 7:'--::' ;; /"" 4000C.F.H.~
2
ciently: 1) special attention must be directed toward 0 CHART FOR SELECTING§
mold preparation so that the mold cavity is made ./ ;'---.-0""'"
PUR~ ~~~~I~~OW •
semi-gas-tight to minimize the possibility of argon o I//t" ~
o
leakage and dilution of the inert atmosphere by air .0 '4 '8
GROSS I NeaT WE IGHT - TONS
22 2. '0 .4
currents passing over the mouth of the mold and
2) introduction of the purge argon should be in Fig. I-Purging times at various flow rates as a function of ingot
such a manner that a displacement rather than a weight.
dilution purge is achieved. The first requirement is
satisfied by covering the mold and sealing the hot- Brick hot tops must be sealed after they have been
top joint. The second requirement is met by using set on the mold because they are much closer fitting
an appropriately designed purge gas distributor. and more fragile than other types· of hot tops. In
Argon is particularly effective as a purge gas be- this case, the asbestos rope is tamped into the space
cause· it is 38 pct heavier than air. Displacement between the mold and the hot top. Experience with
purging, to be described later, cannot be practiced brick hot tops has not been extensive enough to de-
effectively with helium or nitrogen. Helium is ex- termine if the ingot can be poured all the way with-
tremely difficult to contain in the mold cavity be- out a pause.
cause of its extreme lightness and because of its To complete sealing of the mold chamber, the
high diffusivity. Nitrogen with a density very nearly hot top opening must be covered. The most satis-
that of air will not displace air and can only be used factory sealing has been obtained with 0.003 in. thick
to purge by diluting the air in the mold. aluminum foil. Domestic or kitchen foil, which is
only 0.0015 in. thick, is too thin and delicate. A piece
Mold preparation of foil 3 to 6 in. larger than the outer dimensions of
Because of argon's density some attention is the hot top should be used as a cover for the opening.
needed to insure a seal at the mold bottom. With The foil can be held in place by a split ring or by
big-end-up molds it has been found that the plug in folding down and wiring to the hot top. The split
the bottom usually fits tight enough to eliminate the ring allows lifting the foil cover to admit the purge
necessity for added sealing. With big-end-down gas distributor before purging. When the foil cover
molds, some auxiliary sealing in the form of refrac- is wired, access for the gas distributor is provided
tory mud or asbestos rope is usually required at the by piercing a hole in the cover. This hole is taped
mold-stool joint. shut again after purging is completed. Previously
Mold-hot top joints must be sealed to prevent air prepared patches, taped or glued to the covering,
currents flowing through these joints and contam- facilitate the resealing.
inating the inert gas atmosphere. Tiger hot tops and
cast hot tops resting on the top of the mold, where Purging
the joint is sealed with refractory mud, require no A completely inert atmosphere surrounding the
special treatment. With C&D hot tops, asbestos rope teeming operation cannot be attained without first
is wrapped around the hot top below the wiper. establishing an inert atmosphere in the mold cavity.
As the hot top is set in place, the rope forces the Experience has shown that reasonable teem protec-
wiper tightly into the gap thereby forming a satis- tion without prior mold purging only partially elim-
factory seal. It has been found with asbestos rope inates air from the mold.
sealing of C&D hot tops that molds may be teemed Purging in the argon casting process takes ad-
all the way without a pause to allow the metal to vantage of argon's greater-than-air density to estab-
solidify at the mold-hot top joint. lish an inert atmosphere most economically in the
mold cavity. Purging can be accomplished by d.ilu-
Table I. Nominal Composition of Argon Cast Steels tion or displacement. Dilution purging is the most
wasteful and uneconomical way of eliminating air
Alloy Elements, Pet
from the mold. The purge gas, introduced through
a straight pipe at high velocity, thoroughly mixes
Steel C Cr NI Mn Si Mo P S Others
with the chamber atmosphere, and a portion of the
purge gas is exhausted along with the ambient
Suprimpacto 0.12 1.50 3.75 0.50 0.20 0.030 0.030
Max Max chamber atmosphere. With a dilution purge, 7 to 10
SAE-8745 0.45 0.50 0.55 0.80 0.30 0.25 0.040 0.040
mold cavity volumes of purge gas are required to
Max Max reduce the oxygen content in the chamber to less
SAE-4130 0.30 0.95 0.50 0.30 0.20 0.040 0.040 than 0.25 pct.
Max Max Displacement purging was developed specifically
AHT28 0.30 1.30 4.00 0.50 0.25 0.20 0.030 0.030 Al 0.02 for the argon casting process described in this
Modified 4340 0.40 0.75 1.75 0.75 0.30 0.40 0.040 0.040 V 0.20 paper. Displacement purging with heavier-than-
Max Max
air argon, introduced at the bottom of the mold,
Nitralloy N 0.25 1.20 3.50 0.55 0.30 0.25 0.040 0.040 Al 1.25
Max Max
forms an upward moving front much like a piston,
pushing the mold atmosphere out of the top of
SAD 155 0.30 0.60 2.50 0.60 0.20 0.60 - V 0.20
the mold. The ideal displacement purge, therefore,

346-JOURNAL OF METALS, MAY 1961


would require only 1 mold volume to establish a tom of the ladle concentric with the nozzle. The top of
completely inert atmosphere. However, due to gase- the protector must surface on the ladle bottom or
ous diffusion at the mold atmosphere interface, the nozzle retaining plate. The diameter of the pro-
slightly more than 1 chamber volume of the purge tector should be slightly less than the minimum
gas is required to establish an inert atmosphere. In inside hot top dimension. Sometimes it is necessary
the recommended argon casting process, 1.5 to 1.75 to make a stepped cylinder so that its upper
mold volumes of argon are used to obtain less than diameter can clear the nozzle retaining plate.
0.25 pct O 2 in the atmosphere at the mold-hot top The length of the protecting cylinder should be
joint. This is the most economical method for ob- approximately equal to its diameter. This allows a
taining an inert atmosphere in the mold. fanning teem stream to clear the bottom and, al-
Experience in laboratory tests and in mold purg- though small amounts of splash may reach the
ing has shown that purging efficiency is practically cylinder, these will not be harmful. This protector
independent of gas flow rate with a properly-de- length also achieves the greatest visibility without
signed purge gas distributor. Therefore, to minimize interfering with a fanning stream.
the holding time between purging and teeming, the An alternate, but less desirable, position for the
purging operation can be synchronized with teeming teem protector is resting on the mold hot top. The
so that one mold can be purged while the previous latter position should be used only if some physical
mold is being teemed. Fig. 1 shows purging times at condition makes suspension from the ladle impos-
various flow rates as a function of ingot weight. This sible. Placing the teem protector on the hot top
diagram has been prepared on the basis of a 1-2/3 requires a supporting collar which limits visibility.
mold volume purge. When moving from mold to mold, the protector
In most cases, only one set of purging equipment must then be moved by hand. Also, it is impractical
is necessary to synchronize purging with teeming. to lower the ladle to touch the protector. This leaves
In selecting a purge flow, the average time of teem- a space for air infiltration and increases the required
ing an ingot must be established. This average time teem protection argon flow to maintain an inert
is the time to teem a complete heat divided by the atmosphere.
number of ingots poured. The actual purge time Before teeming begins, the ladle with the sus-
would be the average teem time less the time for pended teem protector should be centered over the
moving the purging equipment from one ingot mold hot top opening with the bottom of the cylinder less
to the next. To illustrate, let us assume that teeming than % in. from the aluminum foil. The protector
a lOO-ton heat into ten 10-ton ingots requires 22% aids in locating the nozzle over the center of the
min. Actual filling of a mold requires less than 2 % mold. About 5 sec before the nozzle is opened, the
min, but hot-top pouring and moving the ladle ac- teem protection argon should be turned on. A flow
counts for the additional time. Allowing 15 sec for rate of 1100 cu ft per hr with a 12-in. diam protector
removing and replacing the purge gas distributor, prevents mold atmosphere contamination without
the purge time would then be about 2 min. Thus, disturbing the teem stream.
for a 10-ton ingot the purge argon flow rate from As the molten steel falls from the nozzle a hole
Fig. 3 should be 2000 cu ft per hr. is melted through the aluminum foil to approxi-
When casting small ingots, the average teeming mately the outside diameter of the protector. Ex-
time per ingot may approach the time necessary to pansion of the argon mold atmosphere, argon from
remove the purge gas distributor, reseal the alum- the teem protection flow, and gases from the de-
inum hot-top cover, and place the distributor in the composition of the mold coating raise the aluminum
next mold. Obviously, the purge flow compatible foil around the protector forming an effective seal
with this condition would approach infinity. In this against the back diffusion of air. The temporary seal
circumstance, the use of two sets of purge equip- is maintained until the mold is nearly filled. Finally,
ment would be necessary. This must be determined the aluminum melts away when the metal reaches
in the individual shop. the hot top, allowing observation of the metal level.
Teem protection Results
Protecting the teem stream is necessary to elimin- Argon casting is effective in three general areas
ate exposing the molten steel to oxidizing conditions of application. First, with steels which are accepted
from the ladle to the ingot and to maintain low oxy- on the basis of cleanliness, argon casting minimizes
gen content in the mold. In normal practice, the non-metallic inclusions which. form on expos..i.ng the
falling metal stream not only aspirates air into the molten metal to air. Second, inert-atmosphere pro-
mold, but heats mold gases causing them to rise and
draw in air. In an early test with an argon purged
mold without teem protection, 13 pct O 2 (or 62 pct ITEEM PROTECTOR ATTACH MENT I
air) was found in the mold atmosphere when the
mold was half filled during teeming.
A physical barrier between the teem protection
argon and the surrounding air is necessary to achieve
a completely inert atmosphere around the teem
stream. Argon jets directed at the stream can not
provide adequate protection. A jet of gas is diluted
by the ambient gases as the square of the distance
from the jet source.
A teem stream protector for distributing argon
around the teem stream and providing the mechani-
cal barrier between the argon and air is shown in
Fig. 2. The protector is constructed of light-gage Fig. 2-Teem stream protector for distributing argon around the
steel welded into a cylinder. It is attached to the bot- teem stream and for protection from the atmosphere.

MAY 1961, JOURNAL OF METALS--347


tection reduces conditioning losses by decreasing The data from all the heats were studied statisti-
surface oxidation during teeming. Thirdly, the cally. It was found with 99 pct confidence that there
effects of special vacuum treatments are preserved was an improvement in inclusion ratings with argon
where steel is vacuum degassed then teemed from casting. Also, with 90 pct confidence the average
the ladle through air. The inert atmosphere elimi- improvement on inclusion rating with argon casting
nates the reaction between molten steel and oxygen, will fall within the range of 30 to 65 pct. This has
nitrogen, or water vapor which would otherwise been substantiated during a year's production ex-
partially nullify the effects of vacuum treatment. perience at Atlas Steels. In Atlas' quality control
procedures strategically-located samples from
blooms of six ingots from each scheduled aircraft
Effects on cleanliness quality heat are given a preliminary examination to
Aircraft quality steels in particular are evalu- establish an average inclusion rating. This deter-
ated on the basis of their relative lack of non- mines whether the heat will be accepted for further
metallic inclusions. Inclusions originating prior to inspection to meet the specifications of aircraft-
teeming have a chance to float liP into the slag quality steel orders. At the beginning of 1959, the
cover-the degree of removal being dependent upon inclusion rating level for heat acceptance was re-
size, relative density, metal temperature, and hold- duced by 40 pct, without an increase in the rejection
ing time. However, as previously discussed, oxides rate, indicating a step forward in overall quality
formed on exposure to air during the teem have of product. Other improvements have been incor-
little chance to float out due to rapidly changing porated in Atlas' melting practices; however, argon
conditions which retard their movement. casting has substantially improved quality.
In the studies of the effects of argon casting, it was
soon recognized that evaluation could not be made Effects on ingot surface
on a heat-to-heat comparison. Variations con-
tributed randomly by other operations in the melting Application of argon casting to improve ingot
process affect the number of inclusions remaining surface and reduce conditioning requirements has
in the ingot metal. It was also known that clean- been evaluated to date on stainless and specialty
liness varied within the ingots cast from one heat alloys because it could most easily be justified in
of steel. The first and last ingots poured from a these materials. In the Atlas investigation, approx 90
heat are generally less clean than those in the middle comparison ingots from 15 heats were cast and
of a heat. Therefore, in tests of argon casting, pairs followed to determine differences in metal removal
of compari50n ingots were cast in the first, middle, required during primary conditioning. Twelve of
and last portions of a heat. In a test pair, one ingot the heats were 430 stainless, one was 405, and two
was argon cast and the next adjacent ingot was air were 316. Ingots were cast in test pairs alternately
cast according to normal practices. In a cooperative down the line of ingots. Blooms were weighed before
test with Atlas Steels Ltd., Welland, Ontario, and after primary conditioning following ingot
Canada, approx 150 ingots were cast and examined break-down and cropping.
for comparison purposes. During this test, the argon The percentage of metal removed in primary con-
casting process was still under development. On ditioning ranged between 3.5 and 9 pct. From these
each argon cast ingot, the mold atmosphere oxygen tests, it appears that argon casting is more effective on
content was followed to determine the extent of austenitic stainless steels. However, the results are
purging and atmosphere quality during the teem. not completely conclusive since only two heats of
The aim for oxygen content at the end of purging 316 were included in the investigation. Statistically,
was 0.25 pct or less. Some tests were discarded be- there was a reduction in grinding losses using argon
cause gas analysis showed incomplete elimination casting with 90 pct confidence. Assuming a 90 pct
of air. Faults in equipment and technique were cor- confidence limit, the average reduction divided by
rected as the experimental program progressed. the normal conditioning losses will lie between 3.5
The inclusion ratings were established according and 15.5 pct. Considering the processes involved
to techniques used at Atlas Steels, which have been in removing metal during conditioning, argon cast-
previously reported in the Proceedings of the AIME ing will effectively increase production rate and
Electric Furnace Conference by Atlas personnel." reduce metal removal required by about 10 pct.
An the steels used in the tests were melted according Argon casting has been adopted by Wrought Alloy
to normal procedures established for aircraft quality Dept., Haynes Stellite Co., div. of Union Carbide
steel. The steels and their nominal compositions are Corp., Kokomo, Indiana, for its· reduction of condi-
'listed in Table r. Fig. 3 shows the results of the tioning losses. To evaluate the effectiveness of argon
side-by-side inclusion rating comparison within casting on conditioning a nickel-based super alloy,
individual heats. The, calculated percentage im- 38 ingots were cast from 19 heats. Two 2.5-ton
provement is the difference between the average of ingots were cast per heat from a 5-ton electric
the air cast and the average of the argon cast in- furnace. To minimize effects of early or late teem-
clusion ratings divided by the average air cast ing, argon casting was applied alternately to the
rating. It will be noted that in one heat the average first and second ingots of each heat.
air cast inclusion rating is better than the average Finish grinding loss was the criterion for com-
argon cast inclusion rating. This illustrates the paring the effects of argon casting and air casting
variability in ratings from ingot to ingot. In this on the ingot surface. After casting, the ingots are
heat the inclusion ratings for the six test ingots were normally spot conditioned to remove gross surface
fairly uniform with one very low rating on an air defects. Average losses from this operation were
cast ingot and one quite high rating on its argon essentially equal on both air and argon cast ingots.
cast mate. If these two ratings had been discarded After hot top cropping, the ingots were forged to
in developing the average rating there would have break down cast structure and subsequently ground.
been a 5 pct improvement favoring argon casting Each ingot was weighed before and after grinding
on this heat. to determine weight loss. The finish grinding losses

348-JOURNAL OF METALS, MAY 1961


ranged between 3.5 and 8.7 pct. In this test, the Sources of hydrogen include the water v:apor con-
argon ingots had less grinding losses than the air tents of the atmosphere and decomposition products
cast ingots. Comparison of grinding losses ar,e shown of mold coatings. Hydrogen pickup from volatile
in Fig. 4. Argon cast ingots averaged 17.5 pct less portions of mold coating would be essentially equal
metal removed in final conditioning. Statistically, in both the argon and air cast ingots. Therefore,
the average reduction in grinding losses will fall differences in final hydrogQn content can be attrib-
between 11.2 and 24.4 pct with 90 pct confidence. uted to reaction with water vapor in the surround-
ing atmosphere. Oxygen and nitrogen differences
Effect on vacuum-treated steels are essentially equal and are not in proportion to
their partial pressures in air. The greater reac-
Currently, more and more steel is being vacuum tivity of oxygen relative to nitrogen is reflected in
treated to reduce dissolved gas contents and in- the increased oxygen pickup.
crease cleanliness. The vacuum-treating processes
include vacuum casting, vacuum stream degassing
from ladle to ladle, vacuum ladle degassing (A. Finkl Economics
& Sons process), the reciprocating vacuum vessel The actual cost of utilizing the argon casting pro-
(Dortmund-Hoerder), and the vacuum siphon pro- cess is affected by several factors; these include
cess. In vacuum casting, the molten steel is protected method of teeming, either direct or using an inter-
from atmospheric contamination. However, in the mediate tundish; the size of the ingots; and the
vacuum ladle methods unless an inert atmosphere teeming rate. Mold purging requires 7 cu ft of argon
is provided at teeming, exposure to air may cause per ingot ton of steel. At a pouring rate of 5 tons
oxygen, nitrogen, and hydrogen to be redissolved per min, argon consumption for teem protection is
in the steel. approx 3.5 cu ft per ingot ton. Total argon con-
A test of argon casting applied to vacuum ladle sumption (mold purging plus teem protection) has
degassed 4340 steel was conducted at A. Finkl & ranged between 9 and 15 cu ft per ingot ton with
Sons, Chicago, Ill. The results of these tests have direct pouring. Argon prices are volume dependent
been previously reported by Finkl personnel'. The and normally range between $0.05 and $0.10 per
test consisted of two heats, each with an argon cast cu ft. Using 15 cu ft of argon per ton plus an allow-
and an air cast ingot. Six samples from each test ance of $0.05 per ton for mold sealing, the cost of
ingot were analyzed by vacuum fusion for dissolved consumables for argon casting will vary between
hydrogen, oxygen and nitrogen. Results are pre- $0.80 and $1.55 per ton. With proper argon flow
sented in Argon Teeming of Degassed Steel which control apparatus it has been found that no increase
also appears in this issue. in the pit crew is required.
It is apparent from these results that the argon There are appreciable dollar values attached to
cast ingots were protected against pickup of gas reduction of inclusion count and conditioning losses
components in air. The relative difference in indi- resulting from argon casting; however, these can
vidual gas contents reflect the reactivity of each gas only be determined on an individual mill basis.
and its partial pressure in ambient air. The amount
of hydrogen pickup is dependent on several factors. Summary

. , r--
100 It has been shown that proper argon protected

I
IINCWSION RATING IMPROVEMENT I teeming can have selected application in steelmak-

~ t-
WITH ARGON CASTING
-~~--

ing processes:
o ~--~~--- -~--- ~
I - - 1) While the process requires some care in ob-
taining a completely inert or protected atmos-

1I!0_0= ,=-~;
phere, it is simple and has been developed to

:I-.~~.~ ~~
the point that it does not require extra man-
power;
~ ~- 2) The utilization of an argon protective atmos-
phere can be economically justified in selected
0- ---~ ---~- 0 -
applications;
0-
:1~"~ z>-~ !!
3) It is SUbstantially effective in reducing non-
metallic inclusions in the final product. It
SUPR IMPACTO
4 HEATS
SAE 4100
5HEATS
SAE 8700
a HEATS I AHT28
2HEATS
~ ~
IHEAT IHEAT IH£AT
~ eliminates those which .. have their sou.r.ce in
Fig. 3-Above, Effect of organ costing on inclusion rating. Fig. 4-
the last exposure of the liquid metal to air;
Below, Effect of organ costing on grinding losses for Haynes Super- 4) It is effective in reducing conditioning losses
olloy. in high-alloy steels, specialty steels, and in
certain other alloys; and
0
5) It maintains the gas contents which have been
HGRINOING~I~I minimized by vacuum treatment.
o HAYNES SUPER /lJ..lJ1f

40
References

JIII~iHlbl0 -t
'7
1 E. I. Malinovskii, A. N. Morozov: Izvestia Akad. Nauk. Otd.

~ Tekh. Nauk, August, 1957, no. 8, pp. 102-108.


2 O. M. Margulis, A. G. Karaulov: Ogneupory, VD!. 21, 1956, no. 6,
pp. 253 258.
3 V. A. Grigoryan, A. M. Samarin: Izvestia Akad. Nauk SSSR,

10 OTN, March, 1954, no. 3, pp. 91-101-


• M. P. Fedock: AIME Electric Furnace Proceedings, VD!. 11,
1953, p. 269.
5 D. J. Carney, E. C. Rudolphy: AIME Electric Furnace Proceed-
ings, VD!. 11, 1953, p. 274.
6 L. F. Barnhardt, P. Adams: AIME Electric Furnace Proceedings,
-10 vo!. 15, 1957, p. 142.
7 W. Wilson: Proceedings Vacuum Metallurgy Conference, New
HAYNES SUPER ALLDY
I'HI:~
York University, June, 1960 [See also this issue JOURNAL OF
METALS.]

MAY 1961, JOURNAL OF METALS-349

S-ar putea să vă placă și