MONTHLY TEST 2016-17 (JUNE)

CLASS : XII
SUBJECT: CHEMISTRY
SET-1
TIME: 1:00hrs
MM:30
1. How many coulomb of electricity is needed for the following reactions?
(1)
2 moles of MnO4- to Mn2+
2. What do you mean by pseudo first order reaction. Give one example
(1)
3.Describe the construction of a H2-O2 fuel cell and the reactions taking place in it.
(2)
4.Predict the product of electrolysis of the following:-
(2)
a)An aqueous solution of cupric chloride with platinum electrode.
b)An aqueous solution of silver nitrate with silver electrode.
5. Give differences between order and molecularity of a reaction.
(2)
6 Can nickel spatula be used to stir copper sulphate solution? Support your answer with
(2)
a reason:
( E0Ni2 + / Ni = -0.25 V, E0Cu2 + / Cu = +0.34 V ).
7. A first order reaction is 20% complete in 10 minutes.
(2)
Determine the time taken for 80% completion of the reaction
.
8. The rate constant for the first order decomposition of H2O2 is given as logK = 14.34 –
1.25x 104 K/T. Calculate Ea for this reaction. At what temperature will its half life be 256
minutes? (3)

9. Find the emf of the cell Pb/Pb2+(0.001M)|| Pt, Cl2 (1.5 atm) / 2Cl-(1M) E0Pb2+/ Pb = -
0.13V,
E0 Cl2/ 2 Cl- = 1.36V
(3)

10. For a certain chemical reaction variation in the concentration in [R ] versus time(s) plot
is given below
i) what is the order of the reactions?
ii) what are the units of rate constant k?
iii) give the relationship between k and t1/2 iv) what does the slope of the above line
indicate?
v) draw the plot [R ] 0 / [R] versus time(s)
(5)
11. a) Define molar conductivity of a solution and explain how molar conductivity changes
with change in
concentration of solution for a weak and a strong electrolyte.
(2)
b).Conductivity of 0.00241 M acetic acid is 7.896 x10 –5 Scm-1 Calculate its molar
conductivity and if 0m for
acetic acid is 390.5Scm2mol-1, what is its dissociation constant? (3

MONTHLY TEST 2016-17 (JUNE)

CLASS : XII
SUBJECT: CHEMISTRY
SET-2
TIME: 1:00hrs MM:30

1.In a reaction , the value of rate constant was found to be . (1)

What is the order of reaction?
2. How many coulomb of electricity is needed to deposit 50g of Al from Al 2O3? (1)
3. Name two sacrificial metals. What is the roll of ZnCl2 in dry cell? (2)

4.Define1. Activation Energy 2. Threshold Energy (2)

5. Give four differences between molecularity and order of reaction (2)

6..Prove that the time required for completion of ¾th of a first order reaction is twice the time
required for the completion of half of the reaction. (2)
7. How does molar conductivity varies on dilution .Explain graphically for strong and weak electrolyte. (2)
8. Predict the product of electrolysis of the following:-
a) An aqueous solution of cupric sulphate with copper electrode electrode.
b) An aqueous solution of silver nitrate with platinum electrode. (2)
9. A first order reaction has a rate constant value of 0.00510 min-1 .If we begin
with 0.10M concentration of reactant ,how much reactant will remain after 5 hrs? (3)

10. The conductivity of 0.001028 mol L–1 acetic acid is 4.95 × 10–5 Scm–1. Calculate its dissociation
constant if Λm° for acetic acid is 390.5 S cm2 mol–1 (3)

11. (a) Write down the reactions involved in the working of a lead storage batteries. (5=2+3)
(b) A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of
5.0 amperes for 20.0 minutes. What mass of Ni is deposited at the cathode.
[ At. Wt. Ni = 58.7 ]
12. For the reaction (5)
H+
C12H22O11 + H2O C6H12O6 + C6H12O6
Write:Rate law expression of reaction
(II)Molecularity ,order of reaction
(iii) The decomposition of A into product has value of k as 4.5 x 10 3 s-1 at 10°C and activation energy
is 60 KJ mol-1.Calculate the temperature at which the value kW(J) be 1.5 x104 s-1

SET-1
State both Faraday’s law of electricity.