MAJOR TEST (MT)

JEE MAIN PATTERN

TARGET : JEE (MAIN+ADVANCED) 2014
DATE : 27-01-2014 COURSE : VISHWAAS (JF), ANOOP (EP) & AKHIL (EF)
HINTS & SOLUTIONS
PART- A    
=    = 
MATHEMATICS  4 12  3
1. AB = A + B 6.  ++ =0
 B = AB – A = A(B – l)  +  +  = p
 det(B) = det (A) det(B – l) = 0  = q
 det(B) = 0
 1 1 1 
 
2. (x + a)(x + 1991) = –1 So ( + ) ( + ) ( + )   2  2   2 
 x + a = 1 and x + 1991 = – 1 or x + a = –1 and x + 1991  
=1
 a = 1993 or a = 1989  ( ) {(    )2 – 2(    )} p2
= =–
3. Let g(x) be inverse of f(x), then ( )2 q
g(x) = f –1(x)   
f(g(x)) = x 7. 2x  y  p
f (g(x)) g(x) = 1         
f (g()) g () = 1 x  2y  q i.e. 2x  4 y  2q  3 y  2q – p
 
   2q – p 2 î – 2 ĵ – î – ĵ î – 3 ĵ
By hit and trial f   =  and so f–1 () =
2 i.e. y  = =
  2 3 3 3
   
      4q – 2p 2p – q
i.e. g() =  f    g() = 1  x  q – 2 y = q – =
2 2 3 3
Now, f (x) = 3(2x – )2 (2) + 2 + sin x
2 î  2 ĵ – î  ĵ î  3 ĵ
= =
 1 3 3
 f  = 3  g() =
2 3
  î – 3 ĵ î  3 ĵ 1 – 9 8
Now x. y = . = =–
xdx  ydy xdy – ydy 3 3 9 9
4. + =0
x2  y2 x2
8
 xycos= –
2 2
9
1 d(x  y ) d  y  1 x2  y2 y
+   = 0   =c
2 2
x y 2 x
  2 1 x 1 9 1 9 8 8 4
 cos = –  cos = – = –
2 3 3 9 10 5
8. I = sin(78 x + x) . sin77x dx
( 3  1)
5. |z – 5 + 5i |  5 is a circle with centre at (5 – 5i) and = (sin(78 x) cos x + cos(78 x) sin x) sin77x dx
2 = sin(78 x) cos x . sin77x dx + cos(78x)sin78x dx

5( 3  1) sin 78 x  . sin78 x

radius = = – cos(78x) sin78x dx + cos(78x) sin78x
2 78
dx + C
Distance of centre from the origin = 5 2
sin 78 x  sin78 x
 least principal argument of z = +C
78
 3  1  9. AB = OA = OB = 1  AOB  60
is equal to   sin 1
4 2 2  in BDO, if BOD  

BDO BOD  

12  12  ( 3 )2  1
cos   
2.1.1 2
 = 120°

RESONANCE SOLEPFMT270114 - 1
 D Hence number of ways = 5 C1 .5C1  5C1 . 5C1  5C2
= 25 + 25 + 10 = 60

15. Let D’ratio of the line are < a, b, c >

A  2a – 3b + 4c = 0
O C
a b c
& 2a – 3b + 4c = 0  = =
1 3 14 9
Let given line passes through (, , 0)  2 – 3 + 1 = 0
and 4 + 3 – 7 = 0
B   = 1,  = 1
AOD  BOD  AOB 16. x4 + 36  13x2
= 120 – 60 (x2 – 9)(x2 – 4)  0
= 60 (x + 2)(x + 3)(x – 2)(x – 3)  0
x  [–3, –2]  [2, 3]
 AOD is equilateral triangle.
2
n n
1 2
1 
10.    x12   x1 
n i1
n
 i 1


2
1 2  1 
 (1  3 2  ......  19 2 )   (1  3  .....  19 ) 
10  10  By graph maximum value = cos2
4
1 2  100 
2
n ( x – 9 ) 2
 (1  2 2  3 2  ......  20 2 )  ( 2 2  4 2  .....  20 ) 2  
  17. Let I = dx .......(i)
10  10 
 
2 n ( x – 9)2  n ( x  3) 2
1  20.21.41 4.10.11.21 b b

10  6

6   100 = 33
 [ by property
 f ( x ) dx   f (a  b – x ) dx ]
a a
11.
x6–x
p q p q ~p ~q ~ p  ~ q (p  q)    p   q )
4
T T T F F T T n ( x  3 ) 2
T F F F T T F
I=  dx .......(ii)
F T T T F F F 2  n ( x  3 ) 2   n (9 – x ) 2
Adding (i) & (ii)
F F T T T T T
4
12. The equation of the tangent at (–3, 2) T = 0
2y + 2 (x – 3) + 2 (y + 2) = 0  x + 2y – 1 = 0
2I =
 1dx = 2
2
 I = 1

18. We have R = {(x, y) : x2 – 4xy + 3y2 = 0, x, y  N}

The tangent at one end of the focal chord is parallel to the normal
Let x  N, x2 – 4.x.x + 3x2 = 0
at the other end.  (x, x)  R  R is reflexive
we have (3)2 – 4(3)(1) + 3(1)2 = 9 – 12 + 3 = 0
1 or (3, 1)  R
 slope of normal at Q = slope of tangent at P =  Also 12 – 4(1)(3) +3(3)2 = 1 – 12 + 27  0
2  (1, 3)  R,  R is not symmetric
1 Again (9, 3)  R because
13. 4 x 2  (3  2x ) 2  5  x  1, 92 – 4(9)(3) + 3(3)2 = 108 – 108 = 0
2 and (3, 1)  R because
1  (3)2 – 4(3)(1) + 3(1)2 = 12 – 12 = 0
P(1, 1) . Q , 2  and (9, 1)  R if 92 – 4(9)(1) + 3(1)2 = 0
2  if 84 – 36 = 0 which is not possible
 (9, 3), (3, 1)  R and (9, 1)  R
4 x1  R is not transitive.
Slope of tangent, m1    1  Relation R is reflexive but neither symmetric nor transitive.
y1
4x 2 19. f(x) = |x + 1| – 2 |x – 1|
m2    4
y2
angle between normal equal to angle between tangent
m1  m 2 3
tan   
1  m1m 2 5
14. A1 = 5n+1 = {1, 6,.....}
A2 = 5n+2 = {2, 7,.....}
(i) x<–1
A3 = 5n+3 = {3, 8,.....} f(x) = – x – 1 + 2x – 2 = x – 3
(ii) – 1  x  1
A4 = 5n+4 = {4, 9,.....}
f(x) = x + 1 + 2x – 2 = 3x – 1
A5 = 5n = {5, 10,.....} (iii) x > 1
f(x) = x + 1 – 2x + 2 = – x + 3
sum is div by 5 if two number belongs to {A1, A4} OR {A2, A3} or
20. f() = (sin + cos)(1 – sin2)
both from A5. now f() = 0  tan = –1 or sin2 = 1

RESONANCE SOLEPFMT270114 - 2
    
3  (28) d  (c  (a  c )
 = ,
4 4       
d  ((c . c ) a  (c . a). c )
f () 
Also = sin + cos ( – 2 , 2 ) d  (9 ( î  2 ĵ  2k̂ )  4 (2 î  ĵ  2k̂ ))
1 – sin 2

2x x d  (17 î  14 ĵ  10k̂ )
21. y = = = m (Slope)
8 4  
x = – 4m b . d  3   (17  14 )  3    1
1 (For 29 to 30)
y= .16m2 – 3 Sol. 29. There are two cases (i) 1, 1, 1, 1, 3 (ii) 1, 1, 1, 2, 2
8 case - 1 : 5C1 7C3 × 4!
y = – 2m2 – 3  y + 2m2 + 3 = m(x + 4m) case - 2 : 5C2 × 7C2 × 5C2 × 3!
 Total cases = 5C1 7C3 × 4! + 5C2 × 7C2 × 5C2 × 3! = 16800
1
Slope of tangent = m = 30.Required number of ways=7+5–1C5–1= 11C4
x
1 PART- B
 x= equation of tangent
m PHYSICS
1  1 1 1 1
y – n = m x   31. for lens :    v = 60 cm
m  m  v  30 20
y + n m = mx – 1
 –1 – nm = 2m2 – 3
2m2 + nm = 2
m=1
equation of tangent  y = x – 1
point of contact B  (–4, –5)
C  (1, 0) height of image formed by mirror is 
Area of ABC
 4
1 0 1    = 1.2 cm
90 30
1  4  5 1 |  7   1 8  5  |
= = = 10
2 1 2 1 2 32.

D : (–6 ,–3)
12
22. P(A  B) = = P(A). P(B)
25
1
/2 2
23. O . R2 = kx
2 0

24. Clearly statement-2 is true 33. mg sin  = ma cos 

0 , x  I 1
= 1 , x  I  a = g tan   tan  =
 2
 N = mg cos  + ma sin  = 5 5 N
f(0) = cos–1 (0) =
2
f(1) = cos–1 (–1) =  3  A
34. a =   1 × A =
 statement-1 is false  2  2
25. Statement-2 is obviously true
Statement-1 : f is many one function  3/2  A
statement-1 is false W =   1 A =
 4/3  8
26. Obviously statement-1 is true and statement-2 is false  air 4
(For 27 to 28)
 water = 1 .

i j k
 
Sol. (27) a  ( a  c )  1  2 2  22 î  ĵ  10k̂ 35.
2 6 5
mv 2
       
a  (a  c )  (a . c ) a  (a . a ) c
T – Mg Cos 60 = (1)

 22 î  ĵ  10k̂  4( î  2 ĵ  2k̂ )  9 c 
V2 = u2 - 2gh (2)

 9c  – 4 î  8 ĵ – 8k̂  22 î  ĵ – 10k̂ V2 = 5 g  - 2g   Cos60  0

 1 2
V = 4 g
 c  (18 î  9 ĵ – 18k̂ )  2 î  ĵ – 2k̂
9
V= 4 g

RESONANCE SOLEPFMT270114 - 3
 mg m g g
Putting in (1) T =  4 g 39. K 1 = m 1
x
; k2 = m2
x
2 
9mg m
T=  225 N Thus, Using T = 2 
k
2
 1  2
m1 m2
36.  = (Bx)A =   × r2 = r T1 = 2  T2 = 2 
 x  x (m1 g / x ) (m2 g / x)
 T1 = T2
d r 2 dx r2 Energy of oscillation :
Induced emf = = 2 = 2 v
dt x dt x 1
E= m 2 A2
emf r 2v 2
Current in the ring = = 2 Since  and A are same for both and m 1 > m 2  E 1 > E 2.
R x R
 r 2v  P02 P P02
  2 40.  =  = ; where P,, P 0 , V are power,
Opposing magnetic force = iBr =  x 2R  × 2r ×
x
2 V 4r 2 2 V
 
pressure amplitude and velocity respectively.
4r 3 v
fm = . P V 50   1 330
Rx 3 P0 = = = 5 Ans.
2 r 2

37. C = 40a (when sphere is isolated) 2  330
Q dN
C' = 41. = t2 – N
V dt
dN d 2N
for to be minimum; =0
dt dt 2
d2N dN
 = 2t –  = 2t –  (t 2 – N) = 0
dt 2 dt
t 02  2t 0
Q or N=
C' =
2
 KQ KQ 
   1 T 1 YL
 a b 
42. f = = = 35 Hz
– (Potential of inner sphere) 2L s 2L L
4  ab
C' = 43.
(b  a)
C' = nC
4  ab
= n40a
(b  a)
1
Work done = – Area of semi–ellipse
n =  1  a 

 ab
 b W=
2
a 1
1 =   9  103  2  103 
b n =    (5 × 10–3 – 3 × 10–3)
2  2 
a 1 b  n 
= 1  =   = – 11 J.
b n a  n  1
44. At t = 0 position of cm is :
38.  = 
M(0 )  ML / 2 L
R0 = =
MM 4
 L
R 0  0 î  ĵ
4
There is no external forces on the system, the velocity of the
centre of mass of the system is constant,
2
mR
4 × 10 × r2 =   MV0 î  M(0) V0
2 Vcm  = î
MM 2
40  2 At time t,
=
2    L V0
 = 40 rad/s2. R cm  R 0  Vcm t = ĵ  t î .
4 2

RESONANCE SOLEPFMT270114 - 4
 4 52. P1 = P2 = P
45. Mg – fB = Fv  r3(m – l)g = Fv m1v1 = m2v2
3
 P2   P2  64
46. Volume flow rate = AV    
Mass flow rate = AV  2m   2m  =
 1  2  27
1
Per second K.E. flow = Power = (AV)V2 m2 64 v1
2 = =
m1 27 v2
1 1
= V3 =
AV (1000) (50 × 5) (2)3 1 h / P1
2 2
= 1 MW.  2 = h / P2 = 1 : 1.
47. ( – 0) = 0G.
yd
SS´ 53. Net path difference = (  - 1) t -
(2 – 0) = 0G D
S  S´
3  d / 2d
SS´ =  1 6  m -
( – 0) S = (2 – 0) 2  D
S  S´
= 1m
 S – S0 + S´ – S´0 = 2S´  – S´0 For destructive interference
  
S´ = S 1  0  x = 1 m = ( 2n + 1)

   2
b 2
48. T = =
m (2n  1)  m
Rate of energy emitted by the sun is
4 2000 2000
dE  b   = 2000 n m, nm nm.
= AT4 = A   3 5
dt  m  54. Statement-1 is True, Statement-2 is False
and energy is produced in the sun due to nuclear fusion 55. Statement-1 is False, Statement-2 is True
dE dm loss 56. The potential difference across the resistance is always |E1 –
E = mlossc2 , = c2 E2| in magnitude. Hence statement 1 and 2 are true and
dt dt
statement 2 is correct explanation of statement 1 .
4
 dm   b  57. P = V i s
  c2 = A  
 dt   m  where V = accelerating voltage
i s = saturation photocurrent
dm loss A b 4 Power of source of light  Quantum efficiency  (in Å)
= 2 is =
4 12400
dt c m
100  .01 124
= = 0.01 A
12400
49.  Power = 100 watt
P = V is
hc
58. Maximum energy of incoming electron = –  + eV

 12400 
– 2(2.5 + ) + 10 = 2 =   10  10,000  eV = 10,090 eV
5 = 4.  124 
50. Mass defect m = 4mH – mHe 12400
= 4(1.007825) – 4.002603 = 0.028697 u  min = = 1.23 Å
10090
MeV
= 0.028697 u × 932 = 26.7 MeV Sol. (59-60)
u
d(KE )
51. P = 0
dt
  
For block a  2 r , direction of a is continuously changing
with time.
V
V – iR + =0
2
3V
i=
2R

Normal force is parallel to axis and for uniform circular motion of

block friction force 'f' passes through axis of rotation, so torque of
these forces are zero about vertical axis.

RESONANCE SOLEPFMT270114 - 5
 CV BrO– + 4OH–  BrO3– + 2H2O + 4e– E30 = ?
(Q  ) Q
V– 2 – =0
C C 0
 G0 E
3 = – 4 × F ( 3)
Q V Q
C– + – =0 Target reaction,  G03 =  G10 –  G02
C 2 C
 4  F E 03 = [ 6  F0.61 ] – [–2 × F(–0.76)]
 
2Q 3 V
=
C 2  3.66  1.52 
E03 = –  4  = –0.535 V
3CV  
Q=
4 0
G0 = –4 × F( E3 ) = 206.5 kJ.
PART- C
68. p = CRT order of conc is urea > glucose > sucrose
CHEMISTRY
69. Wolframite is ferromagnetic in nature and, therefore, it is sepa-
x 1 rated from cassiterite ore (non-magnetic) by magnetic separa-
61. log = log k + log P tion method.
M n
1 70. 3Mg + N2  Mg3N2
= tan 45° log k = 0.3010 (X) (Y)
n
n=1 k=2 Mg3N2 + 6H2O  3Mg(OH)2 + 2NH3
x H2[PtCl6] + 2NH3  (NH4)2[PtCl6] (yellow)
= 2 x (0.3)1
m
x = 0.6 71. Cl2 is dried over H2SO4, concentrated HCl + concentrated HNO3
is aqua regia. Available chlorine is obtained from bleaching pow-
62. Rate is governed by slowest step der by treating with dilute acids. All interhalogens do not have
any unpaired electron.
A + B2 AB + B
72. 2Hg + O3  Hg2O + O2
r = k1 [A] [B2]
......... (i) 73. – 1º Alkyl halide and anionic strong nucleophile  SN2
– 2º Alkyl halide and anionic strong base  E2
From A2 A+A – 3º Alcohol and acidic medium  E1
– 3º Alkyl halide and weak neutral nucleophile  SN1
[ A ]2 74. In reaction Ist value of x is 4
kC =
[A 2 ] In reaction IInd value of y is 3
In reaction IIIrd value of z is 3
......... (ii)
x + y + z = 4 + 3 + 3 = 10
[A] = k c [A2]1/2

r = k1 k c [A2]1/2 [B2]
75.
1 3
order = +1=
2 2
Cl
63. No. of octahedral voids in hcp = 6
so formula A6B4 = A3B2 CH2–CH3
Cl2 CH–CH3
2.4 V1  4.6 V2
64. R = = 2.95 atm (assume temperature con-
V1  V2
stant) Monochloro
V1 product
V2 = 3.

C0  Ct
65. = KC0t slope - tan45° = 1 = KC0
Ct
& t1/2 = 1/KC0 = 1 min = 60 sec.

66. SFL d6 = t2g2, 2, 2 eg 0, 0 – diamagnetic

WFL d6 = t2g2, 1, 1 eg 1, 1 – Paramagnetic

67. (1) 6OH– + Br–  BrO3– + 3H2O + 6e– E10 = –0.61,

0
 G1 = – 6 × F (– 0.61)

(2) 2OH– + Br–  BrO– + H2O + 2e– E20 = –0.76,

 G0
2 = – 2 × F (– 0.76)
For reaction

RESONANCE SOLEPFMT270114 - 6
 O

(D)
77. O

83.

Hydrolysis + 3 CH3COOH
   84. 3Br2 + 3Na2CO3  5 NaBr + NaBrO3 + 3CO2
NaBr + H2SO4  Na2SO4 + SO2 + Br2 + H2O

85. Zn2+ occupy 50% tetrahedral voids in zinc blende or wurtizite, so

Br empty tetrahedral voids = empty octahedral voids.

78. (A) HBr 86. (1) For aldol condensation  Hydrogen should be present.

87. Al2O3 + 3C  3CO + 2Al GºR = ?

(B) CH3 – CH  CH2  CH3 4 2

| Al + O2  Al O Gº = –910
( ) 3 3 2 3
Br 2C + O2  2 CO Gº = –430
3 3
GºR = (–430) – (–
CH3 2 2
910) = 720 kJ
88. The temperature at where Gº is more –ve, there will more
C2H5 Br affinity for oxygen.
(C) C2H5 Br (meso)
89 & 90.

CH3

CN CN (1) Mg / Ether
  

(D) H OH HO H
+
D H D H

CH3 CH3
Diasteromers
79. Method of separating Ba2+.

80. Metal ion Example Configuration CFSE

Configuration in Ligand field
d3 Cr3+, V2+ t2g1,1,1, eg0–1.2 0
d8 Ni2+ t2g2,2,2 eg1,1
–2.4 0
+ 1.2 0 
= –1.2 0 (1) O H / 
Therefore, for the above configurations, there is no effect of the
nature of ligand. They may be strong or weak, the formula for ( 2)H
CFSE will remain the same.
For configuration from d4 to d7 :

Metal ion Example Configuration CFSE 

Configuration in Ligand field (1) O H / 
d4 Cr2+ S.L. t2g2,1,1, eg0,0 –1.6 ( 2 +P
0 ) H
W.L. t2g1,1,1, eg1,0 –0.6 0
d7 Co2+ S.L. t2g2,2,2, eg1,0 –1.8 0 + P
W.L. t2g2,2,1, eg1,1 – 0.8 0

Note : S.L. = Strong field ligands

W.L. = Weak field ligands

81. The S.R.P. of Ag+ is higher than that of Ni+2 hence it is a better
oxidsing agent. Like wise the S.O.P. of Ni is higher than that of
Ag hence it is a better reducing agent.

82. (A) Picric acid & Benzoic acid both give CO2 gas with NaHCO3
(C) Acid base reaction is fast

RESONANCE SOLEPFMT270114 - 7
 MAJOR TEST (MT)
(JEE MAIN PATTERN)
TARGET : JEE (MAIN+ADVANCED) 2014

DATE : 27-01-2014 COURSE : VISHWAAS (JF), ANOOP (EP) & AKHIL (EF)

ANSWER KEY

CODE 0

1. (1) 2. (4) 3. (4) 4. (3) 5. (1) 6. (1) 7. (3)

8. (3) 9. (2) 10. (4) 11. (1) 12. (1) 13. (3) 14. (2)

15. (3) 16. (1) 17. (2) 18. (1) 19. (1,2,3) 20. (1,3) 21. (1,4)

22. (1,4) 23. (1,4) 24. (4) 25. (4) 26. (3) 27. (4) 28. (3)

29. (2) 30. (3) 31. (2) 32. (3) 33. (1) 34. (4) 35. (4)

36. (3) 37. (3) 38. (1) 39. (4) 40. (1) 41. (1) 42. (1)

43. (3) 44. (1) 45. (3) 46. (2) 47. (2) 48. (2) 49. (3)

50. (1,2,3,4) 51. (1,2,3,4) 52. (2, 3) 53. (1, 3) 54. (3) 55. (4)

56. (1) 57. (1) 58. (3) 59. (2) 60. (4) 61. (2) 62. (3)

63. (2) 64. (5) 65. (3) 66. (3) 67. (1) 68. (3) 69. (3)

70. (2) 71. (4) 72. (3) 73. (2) 74. (3) 75. (2) 76. (5)

77. (2) 78. (4) 79. (1,3,4) 80. (2,3) 81. (1,2,4) 82. (1,3,4) 83. (1,3)

84. (3) 85. (3) 86. (1) 87. (1) 88. (3) 89. (4) 90. (2)

RESONANCE SOLEPFMT270114 - 8