UP ENGINEERING RADIO GUILD

Chem 16- Second Long Exam

Review Questions A

A. THERMOCHEMISTRY

1. Path-dependent. Which of the following is a path 9. Determine the change of the system’s internal
dependent parameter energy if it absorbs 125 J of heat and does 687 J of
 Enthalpy work
 Heat  812 J
 Entropy  -812 J
 Gibb’s Free Energy  562 J
2. Chemical Change. Which of the following
 -562 J
processes will ALWAYS DECREASE the internal
energy (ΔE < 0) for gaseous systems? 10. Which of the following is a consequence of the
 Endothermic & increase in volume adiabatic condition of the Styrofoam ball
 Endothermic & decrease in volume calorimeter
 Exothermic & increase in volume  Exothermic reactions will give decrease in
 Endothermic & decrease in volume temperature
3. Equations. In which of the following is ΔH an  Endothermic reactions gives a (+)ΔT
enthalpy of formation?  qcalorimeter = ΔHrxn / nLR
 CaO(s) + H2O(l) -> Ca(OH)2(s)  qcalorimeter + qreaction =0
 Cu(s) + ½ I2(s) -> CuI(s) 11. Given the different reactions below, determine the
 CH4(g) + 2O2(g) -> CO2(g) + 2H20(l) effect of the entropy, whether it will increase,
 CO(g) + ½ O2(g) -> CO2(g) decrease or uncertain.
4. I just cannot. Which of the following CANNOT be a. CCl4(l) -> CCl4(g) increase, change to gas
determined from the ΔG of a reaction? b. CuSO4•3H2O(s) + 2H2O(g) ->
 The change in the disorder of the reaction CuSO4•5H2O(s) decrease, gas combines
 The amount of heat at constant pressure to crystalline
c. SO3(g) + H2(g) -> SO2(g) + H2O(g)
 The spontaneity of the reaction
uncertain, all are gases and have the
 The fraction of energy available to do work
same no of moles
5. Which of the following has a ΔHf°= 0 kJ/mol at 25
d. H2S(g) + O2(g) -> H2O(g) + SO2(g)
degrees C and 1 atm?
decrease, balancing the equation, we see
 C(diamond)
that there are more moles of reactants
 NaCl(aq)
12. Determine the ΔG of the system it is non-
 Hg(l) spontaneous at all temperature, spontaneous at all
 O3(g) temperature, etc.
6. Which of the following processes will not result to ΔH ΔS ΔG
an increase in entropy?
 Melting of candle NH4CO2NH2(s) ->
 Combustion of carbon 2NH3(g) + CO2(g)
 Evaporation of ethanol
 Formation of N2O4(g) from NO2(g) ΔH° = + 159.2 kJ
7. Which of the following substances would be H2O(g) + ½ O2(g) ->
H2O2(g)
expected to have the lowest specific heat capacity
per gram of substance ΔH° = + 105.5 kJ
 Ni(s) C6H6(l) + 15/2 O2(g) ->
 S(s) 6CO2(g) + 3H2O(g)
 H2O(l)
 N2(g) ΔH° = -3135 kJ
8. The reaction NH4Cl -> NH3(g) + HCl(g) ΔH°= +177 NO(g) + 1/2Cl2(g) ->
kJ/mol is NOCl(g)
 Spontaneous at all temperatures
ΔH° = -38.54 kJ
 Non-spontaneous at all temperature
 Spontaneous at low temperature
 Spontaneous only at high temperature
13. Set up. 3.
a. the enthalpy of reaction for
2H2(g) + O2(g) -> 2H2O(l) at 25 °C
b. the enthalpy of vaporization
H2O(l) -> H2O(g)
B. COMPOSITION STOICHIOMETRY
1. Mole Concept. How many moles, molecules, and
oxygen atoms are contained in 60.0g of ozone?
2. Mass Percent. Determine the percent composition
4.
of C in C3H8.
3. Empirical Formula. Elemental analysis of a
sample of an ionic compound showed 2.82 g of Na,
4.35 g of Cl, and 7.83 g of O. What is the empirical
5.
formula and name of the compound?
6.
Experiment 6 : Corrosion
a. What is the compound responsible for the
turnbull’s blue color?
b. What is the indicator that was used to visualize
where the oxidation occurred?
c. What is the output of the acidic medium?
 Colorless solution due to the formation
of Mn 2+
 Brown precipitate caused by MnO2
 A greenish solution due to MnO4 2-
Experiment 2 : LODC
a. Solution A is 0.2 mL, 0.2 mmol
Solution B is 0.3 mL, 0.6 mmol.
Find Molarity and the ratio of A and B.
Experiment 8: Calorimetry
Experiment 3: Titrimetric Analysis

C. LABORATORY
1. Experiment 11: Identification of Unknown Ions Sources: Chem 16 notes, Previous DGs,
a. Ions that are precipitated by addition of
Reviewers of Chem 16 profs, (First Sem 2013)
Ba(NO3)2
b. Ion that causes effervescence after ©2014
dissolution (in acidic media) of precipitate
with barium cation
c. Forms a white precipitate with excess
NaoH
d. Ions in an unknown solution that produce
a reddish brown precipitate and dark blue
solution after adding excess ammonia
e. Ion that forms a precipitate upon addition
of MgCl2
f. The chemical formula of the complex
formed after adding excess NaoH to a
solution of Zn2+ (aq)
g. The chemical formula of the brown ring in
the confirmatory test for NO3-
2. Experiment 5: Oxidation-Reduction
a. Given metals A , X, Y, Z and their
corresponding reduction-oxidation reactions,
which metal has the largest reducing property?
A2+ + Z -> A + Z2+
Z2+ + X -> Z + X2+
X2+ + Y -> X + Y2+
 A
 X
 Y
 Z
b. Which of the following is arranged in
decreasing reactivity series for metals
(reducing property)
 Zn > Fe > H2 > Cu
 Fe > H2 > Cu >Zn
 H2 > Zn > Fe > Cu
 Cu > Fe > Zn > H2
c. Which of the following is arranged in
increasing oxidizing property
 I2 < Cl2 < Br2
 Cl2 < Br2 < I2
 I2 < Br2 < Cl2
 Br2 < I2 < Cl2
UP ENGINEERING RADIO GUILD
Chem 16- Second Long Exam
Review Questions A: Answer Key

THERMOCHEMISTRY
14. Path-dependent. Which of the following is a path 22. Determine the change of the system’s internal
dependent parameter energy if it absorbs 125 J of heat and does 687 J of
 Enthalpy work
 Heat  812 J
 Entropy  -812 J
 Gibb’s Free Energy  562 J
15. Chemical Change. Which of the following
 -562 J
processes will ALWAYS DECREASE the internal
23. Which of the following is a consequence of the
energy (ΔE < 0) for gaseous systems?
 Endothermic & increase in volume adiabatic condition of the Styrofoam ball
 Endothermic & decrease in volume calorimeter
 Exothermic & increase in volume  Exothermic reactions will give decrease in
 Endothermic & decrease in volume temperature
16. Equations. In which of the following is ΔH an  Endothermic reactions gives a (+)ΔT
enthalpy of formation?  qcalorimeter = ΔHrxn / nLR
 CaO(s) + H2O(l) -> Ca(OH)2(s)  qcalorimeter + qreaction =0
 Cu(s) + ½ I2(s) -> CuI(s) 24. Given the different reactions below, determine the
 CH4(g) + 2O2(g) -> CO2(g) + 2H20(l) effect of the entropy, whether it will increase,
 CO(g) + ½ O2(g) -> CO2(g) decrease or uncertain.
17. I just cannot. Which of the following CANNOT be a. CCl4(l) -> CCl4(g) increase, change to gas
determined from the ΔG of a reaction? b. CuSO4•3H2O(s) + 2H2O(g) ->
 The change in the disorder of the reaction CuSO4•5H2O(s) decrease, gas combines
 The amount of heat at constant pressure to crystalline
c. SO3(g) + H2(g) -> SO2(g) + H2O(g)
 The spontaneity of the reaction
uncertain, all are gases and have the
 The fraction of energy available to do work
same no of moles
18. Which of the following has a ΔHf°= 0 kJ/mol at 25
d. H2S(g) + O2(g) -> H2O(g) + SO2(g)
degrees C and 1 atm?
decrease, balancing the equation, we see
 C(diamond)
that there are more moles of reactants
 NaCl(aq)
25. Determine the ΔG of the system it is non-
 Hg(l) spontaneous at all temperature, spontaneous at all
 O3(g) temperature, etc.
19. Which of the following processes will not result to ΔH ΔS ΔG
an increase in entropy?
 Melting of candle NH4CO2NH2(s) -> + - + non-
 Combustion of carbon 2NH3(g) + CO2(g) spontan.
 Evaporation of ethanol at all
 Formation of N2O4(g) from NO2(g) ΔH° = + 159.2 kJ temp
20. Which of the following substances would be
H2O(g) + ½ O2(g) -> - + - spont.
expected to have the lowest specific heat capacity
H2O2(g) at all
per gram of substance
temp
 Ni(s) ΔH° = + 105.5 kJ
 S(s) C6H6(l) + 15/2 O2(g) -> - - Spont at
 H2O(l) 6CO2(g) + 3H2O(g) low
 N2(g) temp
21. The reaction NH4Cl -> NH3(g) + HCl(g) ΔH°= +177 ΔH° = -3135 kJ
kJ/mol is NO(g) + 1/2Cl2(g) -> + + Spont at
 Spontaneous at all temperatures NOCl(g) high
 Non-spontaneous at all temperature temp
ΔH° = -38.54 kJ
 Spontaneous at low temperature
 Spontaneous only at high temperature
26. Set up.
 a. the enthalpy of reaction for
2H2(g) + O2(g) -> 2H2O(l) at 25 °C
ΔHrxn°=(2 ΔHf,H2O(l)°)-[( 2 ΔHf,H2(g)°)+
(ΔHf,O2(g)°)]
ΔHrxn° = (2 ΔHf,H2O(l)°)
b. the enthalpy of vaporization
H2O(l) -> H2O(g)
ΔHvap° = (ΔHf,H2O(g)°) - (ΔHf,H2O(l)°)
COMPOSITION STOICHIOMETRY
4. Mole Concept. How many moles, molecules, and
oxygen atoms are contained in 60.0g of ozone?
1 𝑚𝑜𝑙𝑒
h. 60 g O3 ( ) = 1.25 moles O3
48.0𝑔 𝑂3
6.022 𝑥 10−23 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑒𝑠 𝑂3
i. 1.25 moles O3 (
1 𝑚𝑜𝑙𝑒 𝑂3
23
x 10 molecules O3
3 𝑂 𝑎𝑡𝑜𝑚𝑠
j. 7. 5 x 1023 molecules O3 ( 1 𝑂3 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑒) =
2.26 x 1024 atoms O
5. Mass Percent. Determine the percent composition
of C in C3H8.
𝑚𝑎𝑠𝑠 𝐶
%C = (𝑚𝑎𝑠𝑠 𝐶3𝐻8 )x 100% = 81.68%
6. Empirical Formula. Elemental analysis of a
sample of an ionic compound showed 2.82 g of Na,
4.35 g of Cl, and 7.83 g of O. What is the empirical
formula and name of the compound?
𝑁𝑎𝐶𝑙𝑂4 (Sodium Perchlorate)
LABORATORY
7. Experiment 11: Identification of Unknown Ions
k. Ions that are precipitated by addition of
Ba(NO3)2 SO4 2- , CO3 2-, PO4 3-
l. Ion that causes effervescence after
dissolution (in acidic media) of precipitate
with barium cation CO3 2-
m. Forms a white precipitate with excess
NaoH Ca2+
n. Ions in an unknown solution that produce
a reddish brown precipitate and dark blue
solution after adding excess ammonia
Fe3+ , Cu2+
o. Ion that forms a precipitate upon addition
of MgCl2 PO4 3-
p. The chemical formula of the complex
formed after adding excess NaoH to a
solution of Zn2+ (aq) Zn(OH)4 2+
Source: Chem 16 notes, Previous DGs , Reviewers of Chem 16 profs, (First Sem 2013) ©2014
q. The chemical formula of the brown ring in
the confirmatory test for NO3-
[Fe(H2O)3(NO)]2+ or [Fe(NO)]2+
8. Experiment 5: Oxidation-Reduction
d. Given metals A , X, Y, Z and their
corresponding reduction-oxidation reactions,
which metal has the largest reducing property?
A2+ + Z -> A + Z2+ z>A
Z2+ + X -> Z + X2+ X>Z
X2+ + Y -> X + Y2+ Y>X
 A
 X
 Y
 Z
) = 7. 5 e. Which of the following is arranged in
decreasing reactivity series for metals
(reducing property)
 Zn > Fe > H2 > Cu
 Fe > H2 > Cu >Zn
 H2 > Zn > Fe > Cu
 Cu > Fe > Zn > H2
f. Which of the following is arranged in
increasing oxidizing property
 I2 < Cl2 < Br2
 Cl2 < Br2 < I2
 I2 < Br2 < Cl2
 Br2 < I2 < Cl2
9. Experiment 6 : Corrosion
d. What is the compound responsible for the
turnbull’s blue color? Fe3[Fe(CN)]2
e. What is the indicator that was used to visualize
where the oxidation occurred? K3Fe(CN)6
f. What is the output of the acidic medium?
 Colorless solution due to the formation
of Mn 2+
 Brown precipitate caused by MnO2
 A greenish solution due to MnO4 2-
10. Experiment 2 : LODC
b. Solution A is 0.2 mL, 0.2 mmol
Solution B is 0.3 mL, 0.6 mmol.
Find Molarity and the ratio of A and B.
Molarity = mmol solute/ mL of solution
AB3
11. Experiment 8: Calorimetry
12. Experiment 3: Titrimetric Analysis