CAREER POINT JEE Main Online Paper

JEE Main Online Exam 2019

[Memory Based Paper]
Questions & Answer
12th January 2019 | Shift - II

CHEMISTRY
Q.1 Which of the following is used in the preparation of Nylon 6, 6
(1) HOOC–(CH2)4–COOH, NH2–(CH2)4–NH2 (2) HOOC–(CH2)6–COOH, NH2–(CH2)6–NH2
(3) HOOC–(CH2)2–COOH, NH2–(CH2)6–NH2 (4) HOOC–(CH2)4–COOH, NH2–(CH2)6–NH2
Ans. [4]

Q.2 Which of the following forms p–p bonds -

(1) Pb (2) C (3) Si (4) Sn
Ans. [2]

Q.3 Which of the following shows catenation -

(1) Pb (2) Sn (3) Si (4) Ge
Ans. [3]

Q.4 What is the correct order of atomic radii

Eu Ce Ho N
(1) N > Eu > Ce > Ho (2) Eu > Ce > N > Ho (3) Ce > Eu > Ho > N (4) Eu > Ce > Ho > N
Ans. [4]

Q.5 What is volume strength of 1 M H2O2 -

(1) 22.4 ‘V’ (2) 22.22 ‘V’ (3) 11.2 ‘V’ (4) 11.11 ‘V’
Ans. [3]

Q.6 If the value of spin only magnetic moment for Mn+2 ion complex is 5.9 B.M. then which of the following can
form compound most suitably -
(1) CN– (2) en (3) CO (4) SCN–
Ans. [4]

2 th
Q.7 An open vessel is heated at 27ºC at constant atmospheric pressure to escape amount of gas. How much
5
temperature is required for it ?
(1) 750 K (2) 750 ºC (3) 500 K (4) 500 ºC
Ans. [3]
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Q.8 Cl2 Hot

 & Conc .
 product are -
NaOH

(1) Cl & ClO 2 (2) Cl & ClO 3 (3) Cl ClO  (4) Cl ClO 4
Ans. [2]

Q.9 8 gm NaOH is dissolved in 18 gm H2O calculate mole fraction of NaOH and it molality =
(1) 0.16, 11.11 (2) 0.18, 11.2 (3) 0.2, 9.2 (4) 0.3, 8.8
Ans. [1]

Q.10 Following reaction are given

C(graphite) + O2(g)  CO 2 (g ) ; H   x ....(1)
1
C(graphite) + O 2 (g )  CO (g ) ; H   y ....(2)
2
1
CO(g) + O 2 (g )  CO 2 (g ) ; H  z ....(3)
2
Which one is correct -
(1) x = y + z (2) y = x + z (3) x = y – z (4) z = y + x
Ans. [1]

Q.11 Mn(II) form homoleptic octahedral complex for that which is suitable ligand

(1) CN  (2) CO (3) CNS (4) CH2 – NH2
|
CH2 – NH2
Ans. [2]

Q.12 In upper stratosphere O3 layer prevent us from sunlight. What is wavelength of sunlight absorb by O3
(1) 200 nm – 330 nm (2) 0.8 nm – 1.5 nm
(3) 600 nm – 700 nm (4) 450 nm – 550 nm
Ans. [1]

Q.13 Which of the following component is not present in photo chemical smog
(1) O3 (2) PAN
(3) CF2Cl2 (4) CH2 = CH – C – H
||
O
Ans. [3]

Q.14 Which of the following are obtain by calcination process

(1) FeCO3 (2) ZnO, MgO (3) Cu2S, FeS2 (4) FeSO4  xH2O
Ans. [2]

Q.15 Radius of nth orbit of a hydrogen atom is 1.5 a0. What is the n/z ratio when a0 is first Bohr radius
(1) 2.17 (2) 2.5 (3) 3.2 (4) 1.98
Ans. [1]

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Q.16 If we have 1 equivalent of grignard reagent, which compound do not give grignard product
CHO CHO CHO CHO

OCH3 CH2OH COOH

(A) (B) (C) (D)
(1) A, C (2) C, D (3) B, C, D (4) A, B, C, D
Ans. [2]

Q.17 Structure of Histidine at pH = 2

 
NH3 NH3

CH2 – CH – COOH CH2 – CH – COOH

(1) NH (2) NH

N N
H H H

NH3
|
COOH CH2 – CH – COOH

NH2 H 
(3) NH3 (4)
|
CH2 – CH – COOH
OH
Ans. [1]

Q.18 Which of the following is false

(1) Tyndall effect is used to distinguish colloidal solution and true solution
(2) Lyophilic colloids can be coagulated by electrolyte and solvent change
(3) Artificial rain can be done by coagulation of oppositely charge cloud.
(4) Latex is made of colloidal solution of positive charge
Ans. [4]

Q.19 Ksp of Ag2CO3 in water is 8 × 10–12 find out the solubility of Ag2CO3 in 0.1 M AgNO3
(1) 8 × 10–12 (2) 8 × 10–13 (3) 8 × 10–10 (4) 8 × 10–14
Ans. [3]

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Q.20 Which of the following curves are not related to isothermal process :

P PV U P

V P V V
(a) (b) (c) (d)

(1) a, c (2) a, b (3) b, d (4) b, c

Ans. [1]

Q.21 The value of rate constant at 400K is 10–5 sec–1 if temperature raises for 400 K to 500 K. Calculate rate
constant at 500 K.

Slope = – 4606 JK–1

ln k

1
T
(1) 10–4 sec–1 (2) 2 × 10–4 sec–1 (3) 4 × 10–4 sec–1 (4) 3 × 10–4 sec–1
Ans. [1]

CH2–CH3

NaOEt
Q.22 Cl C OC2H5

CH3
OC2 H5 O–C2H5

(1) CH3 C CH–CH3 (2) CH2 C CH2–CH3

CH2–CH3 CH2–CH3

(3) OC2H5 C OC2H5 (4) HO C OC2H5

CH3 CH3

Ans. [1]

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O
|| (A) HNO2
Q.23 CH3 – C – O NH2
(B) CrO3
(C) H+/
(1) CH2 – C – O
||
O
O
(2) CH2 – C – O
||
O

O
O O
(3) CH2 – C
||
O
OH
O
|| O
(4) CH3 – C O

Ans. [1]

Cl NaOH
Q.24

CH3
OH
(1) CH3 (2)

OH

OH
(3) OH (4)

Ans. [3]

NaBH4
Q.25 Product Product is

O O O O–H
OH
(1) (2) (3) (4)
OH
Ans. [4]
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Q.26 (i) Alc.KOH

CH3–CH–CH2
(ii) NaNH2 in Liq NH3
Br Br
CH3 –CH–CH2
(1) CH3–CC–H (2) CH3–C=CH2 (3) CH3–CH2–CH3 (4)
NH2 NH2
Ans. [1]


Q.27 If  ln HCl = 424.9 –1 cm2 mol–1

 NaA = 100.5 –1 cm2 mol–1

 NaCl = 126.4 –1 cm2 mol–1
calculate degree of dissociation of HA if 10–3 M HA has molar conductivity 40–1 cm2 mol–1
(1) 10 % (2) 20 % (3) 15 % (4) 22 %
Ans. [1]

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