HOLIDAY

ASSIGNMENT
for

for

XII-IIT BATCHES

CHEMISTRY

Education is the ability to listen to almost anything

without losing your temper or self-confidence.
- Robert Frost
 HOLIDAY ASSIGNMENT - CHEMISTRY
Q.1 If a neutral atom changes to cation its :
[1] atomic size decreases [2] atomic number decreases
[3] atomic size increase [4] atomic number increases
Q.2 The K.E. of an electron in first Bohr’s orbit of H-atom is 13.6 eV. Total energy of first orbit is :

1 1
[1] – × 13.6 eV [2] – 13.6 eV [3] 2 × 13.6 eV [4] × 13.6 eV
2 2

Q.3 C11 and 5B11 are called :

6

[1] Nuclear isomers [2] Isobars [3] Isotopes [4] Fission products
Q.4 Correct set of four quantum numbers for the valence (outermost) electron of rubidium (Z = 37) is :
[1] 5, 0, 0 + 1/2 [2] 5, 1, 0, + 1/2 [3] 5, 1, 1, + 1/2 [4] 6, 0, 0, + 1/2

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Q.5 Which of the following formula represents the K.E. of an electron in nth Bohr’s orbit of H-atom ?

Rhc Rhc 2Rhc 2Rhc

[1] 2 [2] – 2 [3] – 2 [4]
n n n n2

Q.6 The frequency of a radiobulletin is 600 kilocycles. What is the wavelength of the signal ?

Q.7
[1] 100 m
ys
[2] 250 m [3] 500 m [4] 600 m
The energy of electron in excited H-atom is – 3.4 eV. What is the angular momentum of electron ?

h h 2h 3h
[1] [2] [3] [4]
 2  
al
Q.8 How many spectral lines will be obtained by the various transitions when an electron comes from excited state
n = 5 to its original state ?
[1] 20 [2] 5 [3] 4 [4] 10
Q.9 Principal, azimuthal and magnetic quantum numbers are respectively related to :
at

[1] size, shape and orientation [2] shape, size and orientation
[3] size, orientation and shape [4] None of these
Q.10 The angular momentum of electron in Bohr’s orbit is J. What will be the K.E. of that Bohr’s orbit ?
C

1 Jv Jv J2 J2
[1] [2] [3] [4]
2 r r 2m 2

Q.11 The wavelength of first line of Balmer series of H-atom is – (R = Rydberg’s constant)

36 36R 5R 5
[1] [2] [3] [4]
5R 5 36 36R

Q.12 The excitation energy of an electron from second orbit to third orbit of an atom with + Ze nuclear charge is 47.2
eV. If the energy of H-atom in lowest energy state is – 13.6 eV. What will be the value of Z ?
[1] 4 [2] 5 [3] 6 [4] 7

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Q.13 The statement ‘It is not possible to estimate accurately the position and momentum of an electron simulta-
neously is associated with :
[1] Heisenberg’s uncertainty principle [2] De-Broglie’s principle
[3] Pauli’s uncertainty principle [4] Aufbau principle
Q.14 The increasing order (lowest first) for the value of e/m (charge/mass) for :
[1] e, p, n,  [2] n, p, e,  [3] n, p, , e [4] n, , p, e
Q.15 The electron of H-atom transits from n = 1 to n = 4 by absorbing energy. If the energy of n = 1 state
is – 21.8 × 10–19 Joule then its energy in n = 4 state will be :
[1] – 21.8 × 10–19 Joule [2] – 5.45 × 10–19 Joule
[3] – 2.725 × 10–19 Joule [4] – 1.362 × 10–19 Joule
Q.16 Energy of orbit :
[1] Increases as we move away from nucleus

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[2] Decreases as we move away from nucleus
[3] Remains same as we move away from nucleus
[4] None of these
Q.17 Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon ?
[1] 3s [2] 2p [3] 2s [4] 1s
Q.18
ys
de’ Broglie equation tells about :
[1] the relation between electron and nucleus
[3] the relation between electron and neutron
[2] the relation between electron and proton
[4] electrons’ dual nature of wave and particle
Q.19 Helium atom is two times heavier than a hydrogen molecule. At 298 K, the average kinetic energy of helium
al
atom is :
[1] two times that of hydrogen molecule [2] same as that of hydrogen molecule
[3] four times that of hydrogen molecule [4] half that of hydrogen molecule
Q.20 The potential energies of first, second and third Bohr’s orbits of He+ cation are E1, E2 and E3. The correct
at

sequence of these energies is :

[1] E1 > E2 > E3 [2] E1 = E2 > E3 [3] E1 = E2 = E3 [4] E3 > E2 > E1
Q.21 The circumference of first Bohr’s orbit of hydrogen atom is how many times the circumference of second Bohr’s
orbit of He+ ?
C

[1] two times [2] half [3] equal [4] none of these
Q.22 According to Sommerfeld, the numbers of circular and elliptical suborbits in n th Bohr’s orbit are
respectively :
[1] 1 and (n – 1) [2] (n – 1) and 1 [3] 2 and (n – 1) [4] (n – 2) and 1
Q.23 According to Pauli’s exclusion principle :
[1] No two electrons can have the same energy in an orbital
[2] No two electrons can have the parallel spin in an orbital
[3] As far as possible the electrons fill in different orbitals
[4] Electron try to occupy the orbital of lower energy
Q.24 The mass of a cricket ball is 0.21 kg. If the order of uncertainty in position is 100 pm then uncertainty in its
velocity will be :
[1] 3.5 × 10–24 m/sec [2] 6.02 × 1023 m/sec [3] 6.602 × 10–27 m/sec [4] 2.5 × 10–24 m/sec

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Q.25 The molecular weight of an oxide of nitrogen is 30. The number of electrons present in one molecule of this
compound is :
[1] 15 [2] 30 [3] 6.02 × 1023 × 15 [4] 6.02 × 1023 × 30
Q.26 Which of the following statements is false ?
[1] (n + ) rule arranges the orbitals in increasing order of energy
[2] Wavelength of a particle is inversely proportional to its momentum
[3] Aufbau’s principle was given a scientist named Aufbau
[4] Velocity of all types of electromagnetic radiation is same
Q.27 The electron with highest energy is :
[1] in nucleus [2] in ground state
[3] in first excited state [4] At infinite distance from the nucleus
Q.28 If the Rydberg constant is R then the energy of electron in ground state of H-atom will be :
ch Rc
[1] – [2] – Rch [3] – [4] – R/ch
R h
Q.29 In which of the following planes of s-orbitals, the probability of finding the electrons is not zero ?

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(a) xy plane (b) yz plane (c) along the x axis (d) xyz plane
Correct answer is :
[1] (a) and (d) only [2] (b) and (c) only [3] (d) only [4] (a) and (c) only
Q.30 It is known that atoms contain protons, neutrons and electrons. If the mass of neutron is assumed to be half of
its original value whereas that of electron is assumed to be twice to this original value. The atomic mass of 6C12
will be : ys
[1] Twice [2] 75% less [3] 25% less [4] One half of its original value
Q.31 Calculate the de-Broglie wave length of the electron in the ground state of hydrogen atom, given that its kinetic
energy is 13.6 eV : (1eV = 1.602 × 10–19 J)
[1] 3.328 × 10–10 m [2] 2.338 × 10–10 m [3] 3.328 × 1010 m [4] 2.338 × 10 m
al
Q.32 Which of the following pair having same number of orbitals :
(a) N, O (b) O, F (c) Na, K (d) S, Cl
The correct answer is :
at

[1] a, b, c [2] b, c, d [3] c, d, a [4] a, b, d

Q.33 The speed of a proton is one hundredth of the speed of light in vacuum. What is its de-Broglie wavelength ?
Assume that one mole of protons has a mass equal to one gram [h = 6.626 × 10–27 erg sec] :
[1] 13.31 × 10–3 Å [2] 1.33 × 10–3 Å [3] 13.13 × 10–2 Å [4] 1.31 × 10–2 Å
C

Q.34 The value of charge on the oil droplets experimentally observed were – 1.6 × 10–19 and –4 × 10–19 coulomb. The
value of the electronic charge, indicated by these results is :
[1] 1.6 × 10–19 [2] –2.4 × 10–19 [3] –4 × 10–19 [4] –0.8 × 10–19
Q.35 Which set of quantum numbers is possible for the last electron of Mg+ ion :

1 1
[1] n = 3, l = 2, m = 0, s = + [2] n = 2, l = 3, m = 0, s = +
2 2

1 1
[3] n = 1, l = 0, m = 0, s = + [4] n = 3, l = 0, m = 0, s = +
2 2

Q.36 The discovery of neutron became very late because :

[1] Neutrons are present in nucleus [2] Neutrons are fundamental particles

[3] Neutrons are charge less [4] All

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Q.37 If E1, E2 and E3 represent respectively the kinetic energies of an electron, an alpha particle and a proton each
having same de Broglie wavelength then :

[1] E1 > E3 > E2 [2] E2 > E3 > E1 [3] E1 > E2 > E3 [4] E1 = E2 = E3

Q.38 The value of : [2p(energy) – 1s(energy)] for H-atom would be :

[1] 10.2 eV [2] 13.6 eV [3] 3.4 eV [4] None of these

Q.39 In hydrogen atom, If an electron jumps from n = 6 to n = 2, how many possible spectral lines are obtained :

[1] 15 [2] 10 [3] 6 [4] 12

Q.40 If n and l are respectively the principal and azimuthal quantum numbers, then the expression for calculating the
total number of electrons in any energy level is :

l n l n–1 l n 1 l n–1

[1]  2(2l  1)
l 0
[2]  l 1
2(2l  1) [3] l 0
2(2l  1) [4] l 0
2(2l  1)

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Q.41 The potential energy of the electron present in the ground state of Li2+ ion is represent by :

3e2 3e 3e2
[1] + [2] – 4 r [3] – [4] None of these
40r 0 40r

Q.42 Energy levels A, B, C of a certain atom corresponds to increasing values of energy, i.e., EA < EB < EC. If 1, 2 and
ys
3 are the wavelengths of radiations corresponding to the transitions C to B, B to A and C to A respectively, which
of the following statement is correct :

C
1
B
al
2  3
A

1 2
at

[1] 3 = 1 + 2 [2] 3 =    [3] 1 + 2 + 3 = 0 [4]  23 =  12 +  22

1 2

Q.43 Which of the following curves may represent the speed of the electron in a hydrogen atom as a function of the
principal quantum number n :
C

a
d
b
v c

[1] a [2] b [3] c [4] d

Q.44 The graphical representation of energy of e– and atomic number is :

2
E Z
E E E
[1] 2
[2] 2
[3] 2
[4]
Z Z Z

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Q.45 In the chemical reaction : N2 + 3H2 2NH3

at equilibrium point, state whether

[1] Equal volumes of N2 and H2 are reacting

[2] Equal masses of N2 and H2 are reacting

[3] The reaction has stopped

[4] The same amount of ammonia is formed as is decomposed into N2 and H2

Q.46 A reversible chemical reaction having two reactants, is in equilibrium. If the concentrations of the reactants are
doubled then the equilibrium constant will :

[1] Be doubled [2] Be halved [3] Become one fourth [4] Remain the same

1 1
Q.47 (I) N2 + O2 2NO (II) 2 N2 + 2 O2 NO

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If K1 and K2 are equilibrium constants for reactions (I) and (II) respectively, then the relation between K1 and K2 is

1
[1] K1 = K2 [2] K2 = K1 [3] K1 = 2K [4] K1 = 2 K2

Q.48 For the gas phase reaction : C2H4 + H2 C2H6 (H = – 32.7 k cal)

carried out in a vessel, the equilibrium concentration of C2H4 can be increased by :

ys
(a) Increasing the temperature (b) Decreasing the pressure

(c) Removing some H2 (d) Adding some C2H6

Correct answer is :
al
[1] a, c, d [2] a, b, c [3] a, b [4] a, b, c, d

Q.49 CO and Cl2 are allowed to interact in a 500 ml flask to form COCl2

At equilibrium, concentrations of CO, Cl2 and COCl2 are found 0.1, 0.1 and 0.3 gm moles
at

respectively. The equilibrium constant will be :

[1] 30 [2] 3 [3] 15 [4] 0.3

Q.50 Which of the following oxides of nitrogen will be most stable one :
C

[1] 2NO2 (g) 2O2 (g) + N2 (g) ; K = 6.7 × 1016 mol litre–1

[2] 2NO (g) N2 (g) + O2 (g) ; K = 2.2 × 1030

[3] 2N2O5 (g) 2N2 (g) + 5O2 (g) ; K = 1.2 × 1034 mol5 litre–5

[4] 2NO2 (g) 2N2 (g) + O2 (g) ; K = 3.5 × 1033 Mol litre–1

Q.51 HI was heated in a sealed tube at 440ºC till the equilibrium was reached. HI was found to be 22% decomposed.
The equilibrium constant for dissociation is :

[1] 0.282 [2] 0.0796 [3] 0.0199 [4] 1.99

Q.52 2 moles of PCl5 were heated in a closed vessel of 2 litre capacity. At equilibrium, 40% of PCl5 dissociated into
PCl3 and Cl2. The value of equilibrium constant is :

[1] 0.267 [2] 0.53 [3] 2.63 [4] 5.3

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 1
Q.53 The equilibrium constant for equilibria : SO2(g) + 2 O2(g) SO3(g)

and 2SO3 2SO2(g) + O2 (g)

are K1 and K2 respectively. The relationship between K1 and K2 is :

[1] K2 = K1 [2] K2 = K12 [3] K2 = 1/K1 [4] K2 = 1/K12

Q.54 The rate at which a substance reacts depends on its :

[1] Atomic weight [2] Molecular weight [3] Equivalent weight [4] Active mass

Q.55 Le Chatelier’s principle is applicable only to :

[1] Reaction under equilibrium [2] Reaction without equilibrium

[3] Ionization of electrolytes [4] None of these

Q.56 At 298 K, the equilibrium between N 2O 4 and NO 2 may be represented by the following equation

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N2O4(g) 2NO2(g). If the total pressure of the equilibrium mixture is P and the degree of dissociation of
N2O4(g) at 298 K is x, which one of the following is the pressure of N2O4(g) under this condition :

(1  x)  P 2x  P 2x  P 2P
[1] [2] [3] [4]
(1  x) (1  x ) (1 – x ) 3

Q.57 For the reaction : PCl5(g)

ys PCl3(g) + Cl2(g)

the forward reaction at a constant temperature is favoured by :

[1] Introducing an inert gas at constant volume [2] Introducing chlorine gas at constant volume

[3] Introducing an inert gas at constant pressure [4] None of these

al
Q.58 One mole of SO3 was placed in one litre vessel at a certain temperature. The following equilibrium was estab-
lished 2SO3 2SO2 + O2 . At equilibrium 0.6 moles of SO2 were formed. The equilibrium constant of the
at

reaction will be :

[1] 0.36 [2] 0.45 [3] 0.54 [4] 0.675

Q.59 Raising the temperature of a reversible chemical reaction :

[1] Favours the forward rate only [2] Favours the backward rate only
C

[3] Favours both the forward and backward rate [4] Favours neither the forward nor the backward rates

Q.60 Which of the following reactions will be favoured at low pressure :

[1] H2 + I2 2HI [2] N2 + 3H2 2NH3

[3] PCl5 PCl3 + Cl2 [4] N2 + O2 2NO

Q.61 CH3COOH + C2H5OH CH3COOC2H5 + H2O (KC = 4)

In the above reaction one mole each of acetic acid and alcohol are heated in the presence of a little conc. H2SO4.
On equilibrium being attained :

[1] One mole of ethyl acetate is formed [2] 2 moles of ethyl acetate are formed

[3] 1/3 moles of ethyl acetate is formed [4] 2/3 moles of ethyl acetate is formed

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Q.62 Suppose the reaction : PCl5(s) PCl3(g) + Cl2(g) is at equilibrium in a closed vessel. At a constant
temperature on addition of PCl5, what will be effect on equilibrium concentration of Cl2 (g) :

[1] Will be decreased

[2] Will be increased

[3] Will remain unaffected

[4] Can not be predicated without the value of Kp

Q.63 An equilibrium mixture for the reaction : 2H2S (g) 2H2 (g) + S2(g) has 0.5 mole H2S, 0.1 mole of H2 and
0.4 mole S2 in a one litre vessel. The equilibrium constant of this reaction is given by :

[1] 0.004 mole litre–1 [2] 0.08 mole litre–1 [3] 0.016 mole litre–1 [4] 0.160 mole litre–1

Q.64 What will be the rate of decomposition of a gas at a particular temperature, if concentration of the gas is
0.05 mole/litre ? Rate constant of decomposition of gas at this temperature is 10–4 min–1.

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[1] 5 × 10–6 [2] 1 × 10–4 [3] 5 × 10–4 [4] 2 × 10–6

Q.65 0.96 gram hydrogen iodide is heated at 400ºC till equilibrium is established. 14.0 ml of N/10 Na2S2O3 solution is
needed to neutralize iodine obtained from this reaction, then calculate the percent amount of dissociation of
HI :

[1] 28% [2] 18.6% [3] 20% [4] 62.3%

Q.66 When 20 g of CaCO3 were put into 10 litre flask and heated to 800 °C, 35% of CaCO3 remained unreacted at
ys
equilibrium. Kp for decomposition of CaCO3 is
[1] 1.145atm [2] 0.145 atm [3] 2.145 atm [4] 3.145 atm

Q.67 

A quantity of PCl5 was heated in a 10 litre vessel at 250°C, PCl5(g) + Cl2(g) 
 PCl3(g) + Cl2 (g). At equilibrium
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the vessel contains 0.1 mole of PCl5, 0.20 mole of PCl3 and 0.2 mole of Cl2. The equilibrium constant of the
reaction is
[1] 0.02 [2] 0.05 [3] 0.04 [4] 0.025
Q.68 Which of the following is wrong
at

Reaction Degree of dissociation Reaction Degree of dissociation


 Dd 
 M t  Mo
[1] PCl5 
 PCl3 + Cl2 [2] N2O4 
 2NO2
d 2d
C

K K


[3] H2 + I2 
 2HI 

[4] A + B 
 C+D
K 2 2 K

Q.69 Which of the following graphs represents an exothermic reaction

ln Kp

ln Kp

ln Kp

ln Kp

[1] [2] [3] [4]

1/T 1/T 1/T 1/T

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 H  1 1 
Q.70 Effect of temperature on equilibrium constant is given by log K2 –log K1 = 2.303R  T  T  . Then for a endot-
 2 1

hermic reaction the false statement is

 1 1
[1]  T  T  = positive [2] log K2 > log K1 [3] H = positive [4] K2 > K1
 2 1

Q.71 
For the reaction : 2HI(g) 
 H2(g) + I2(g), the degree of dissociation () of HI(g) is related to equilibrium
constant Kp by the expression

1  2 KP 1  2K P 2K P 2 KP
[1] [2] [3] 1  2KP [4]
2 2 1  2 KP

Q.72 List X List Y



(A) A 
 B heat (i) Equilibrium constant
(B) rb/rf (ii) Adaptation of low temp.

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(C) rf/rb (iii) (Equilibrium constant)–1


(D) 2A(g) + B(g) 
 C(g) 

(iv) A(g) + B(g) 
 C(g) + D(g)
(E) No effect of pressure (v) n < 0
Correct match list X and Y
[1] A–(ii), B–(iii), C–(i), D–(v), E –(iv)
ys [2] A–(iii), B–(ii), C–(i), D–(v) , E –(iv)
[3] A–(iv), B–(iii), C –(i), D–(v), E–(ii) [4] None of these
Q.73 When heating PCl5 then it decompose PCl3 and Cl2 in form of gas, The density of gas mixture is 70.2 and 57.9
at 200°C and 250°C. The degree of dissociation of PCl5 at 200°C and 250°C if
[1] 48.50% & 80% [2] 60% & 70% [3] 70% & 80% [4] 80% & 90%
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Q.74 

X2 + Y2 
 2XY reaction was studied at a certain temperature. In the beginning 1 mole of X2 was taken in a
one litre flask and 2 moles of Y2 was taken in another 2 litre flask. What is the equilibrium concentration of X2 and
Y2 (Given equilibrium concentration of [XY] = 0.6 moles/lit.
at

1  2  1  2 
[1]   0.3  .   0.3  [2]   0.6  .   0.6  [3] (1–0.3), (2–0.3) [4] (1–0.6), (2–0.6)
 3   3   3   3 

Q.75 

XY2 dissociates as XY2(g) 
 XY(g) + Y(g)
C

Initial pressure of XY2 is 600 mm Hg. At equilibrium the total pressure is 800 mm Hg. Calculate the value of Kp.
It is assumed that the volume of the system remains unchanged
[1] 100 [2] 400 [3] 200 [4] 50

Q.76 

The equilibrium constant for the reaction N2 + O2 
 2NO is 0.0842 at 3500K. The fraction of equilibrium
mixture of N2 and O2 converted into NO is
[1] 12.66% [2] 17.2% [3] 15.9% [4] 16.0%
Q.77 The equilibrium constant for the reaction


Zn (s) + Cu2+ (aq)  

 Zn2+ (aq) + Cu (s) + and Cu (s) 2 Ag+ (aq) 
 Cu2+ (aq) + 2Ag (s) are K1 and K2
respectively. Then the equilibrium constant for the reaction


Zn (s) + 2 Ag+ (aq) 
 Zn2+ (aq) + 2 Ag (s) will be

[1] K1 + K2 [2] K1 × K2 [3] K1 / K2 [4] K1 – K2

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Q.78 Ammonia forms complexes with Ag+ according to the following reactions


(i) Ag[H2O]2 + NH3(aq) 
 [Ag[NH3] [H2O (aq)]+ + H2O()



(ii) [Ag(NH3)(H2O) (aq)]+ + NH3(aq) 
 Ag (NH3)2+ (aq) + H2O()

The equilibrium constants of equilibrium (i) and (ii) are 2.0 × 103 and 8.3 × 103 respectively. Equilibrium constant


of the following reaction [Ag(H2O)2(aq)+ + 2NH3(aq) 
 Ag(NH3)2+ + 2H2O () will be -

[1] 4.15 [2] 2.0 × 103 [3] 8.3 × 103 [4] 16.6 × 106
Q.79 In which of the following equilibrium, change in the volume of the system does not alter the number of moles

[1] N (g) + O (g)  
 2NO(g) 
[2] PCl (g)  PCl (g) + Cl (g)
2 2 5 3 2


[3] N2(g) + 3H2(g) 
 2NH3(g) 

[4] SO2Cl2 
 SO2(g) + Cl2(g)
1  
Q.80 For the reaction CO(g) + O (g)   CO2(g), Kp/Kc is
2 2
[1] RT [2] (RT)–1 [3] (RT)–1/2 [4] (RT)1/2

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Q.81 For the reaction

2NO2(g)   2NO(g) + O2(g) (Kc = 1.8 × 10–6 at 184ºC) (R = 0.0831 kJ/(mol.K))
When Kp and Kc are compared at 184ºC it is found that
[1] Whether Kp is greater than, less than or equal to Kc depends upon the total gas pressure
[2] Kp = Kc ys
[3] Kp is less than Kc
[4] Kp is greater than Kc
Q.82 The exothermic formation of ClF3 is represented by the equation

Cl (g) + 3F (g)  
 2ClF (g); H = – 329 kJ
2 2 3
al
Which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2, F2 and ClF3 ?
[1] Adding F2 [2] Increasing the volume of the container
[3] Removing Cl2 [4] Increasing the temperature

  1
Q.83 The equilibrium constant for the reaction SO3 (g)   SO2(g) + O2(g) is Kc = 4.9 × 10–2. The value of Kc for
at

2

the reaction 2SO2(g) + O2(g)  
 2SO3(g) will be -
[1] 2.40 × 10–3 [2] 9.8 × 10 –2 [3] 4.9 × 10–2 [4] 416
Q.84 
Phosphorus pentachloride dissociates as follows, in a closed reaction vessel, PCl5(g)   PCl3(g) + Cl2(g),
If total pressure at equilibrium of the reaction mixture is P and degree of dissocition of PCl5 is x, the partial
C

pressure of PCl3 will be -

 2x   x   x   x 
[1]   P [2]  P [3],  P [4]  P
 1 x   x  1  1 x   x  1
Q.85 Maximum number of molecules are present in
(1) 54 g of N2O5 (2) 28 g of CO (3) 36 g of H2O (4) 46 g of C2H5OH.
Q.86 Number of atoms in 12 gram of 6C12 is
(1) 6 (2) 6 x 10–23 (3) 12 (4) 12 x 6 X 1023
Q.87 Order of the rate of diffusion of SO2, CO2, PCl3 and SO3 will be
(1) SO2> SO3 > PCl3 > CO2 (2) CO2 > SO2 > SO3 > PCI3
(3) PCl3 > SO3 > SO2 > CO2 (4) CO2 > SO2 > PCl3> SO3
Q.88 21 % by volume of oxygen is present in one litre of air. What should be the number of moles in oxygen ?
(1) 0.186 (2) 0.21 (3) 2.10 (4) 0.93

CatalyseR Eduventures (India) Pvt. Ltd. 9

Q.89 At constant temperature, in a given mass of an ideal gas
(1) The ratio of pressure and volume always remains constant
(2) Volume always remains constant
(3) Pressure always remains constant.
(4) The product of pressure and volume always remains constant.
Q.90 Dalton’s law of partial pressure is not applicable to
(1) H2 and N2 mixture (2) H2 and CI2 mixture
(3) H2 and CO2 mixture (4) None
Q.91 A cylinder is filled with a gaseous mixture containing equal masses of CO and N2. The ratio of their partial
pressure is-

1
(1) PN = PCO (2) PCO = 0.875 PN (3) PCO = 2 PN (4) PCO = P
2 2 2 2 N2
Q.92 Number of molecules in one litre of water is close to

18

eR
(1) 18 x 6.023 x 1023 (2)
22.4 1023
(3) 55.5 x 6.023 x 1023 (4) None of these
Q.93 The increasing order of effusion among the gases, H2, O2, NH3 and CO2 is
(1) H2, CO2, NH3, O2 (2) H2, NH3, O2, CO2
(3) H2, O2, NH3, CO2 (4) CO2, O2, NH3, H2
Q.94 The rate of diffusion of methane at a given temperature is twice that of a gas X. The molecular weight of X is
ys
(1) 64 (2) 32 (3) 4 (4) 8
Q.95 Gases deviate from ideal gas behaviour at high pressure. Which of the following is correct for non ideality
(1) At high pressure, the collision between the gas molecules becomes enormous
(2) At high pressure, the gas molecules move only in one direction
al
(3) At high pressure, the volume of gas becomes insignificant
(4) At high pressure the intermolecular interaction become significant
Q.96 Four rubber tubes are respectively filled with H2, O2, N2 and He. The tube which will be reinflated first is
(1) H2 filled tube (2) O2 filled tube (3) N2 filled tube (4) He filled tube
at

Q.97 A balloon filled with methane (CH4) is pricked with a sharp point and quickly plunged into a tank of hydrogen at
the same pressure. After sometime, the balloon will have -
(1) Enlarged (2) Collapsed
(3) Remain unchanged in size (4) Ethylene (C2H4) inside it
Q.98 The partial pressure of hydrogen in a flask containing 2gm of H2 & 32gm of SO2 is
C

1 1
(1) of total pressure (2) of total pressure
16 2

2 1
(3) of total pressure (4) of total pressure.
3 8
Q.99 One litre of an unknown gas weighs 1.25 gm at N.T.P. which of the foliowing gas pertains to the above data -
(1) CO2 (2) NO2 (3) N2 (4) O2
Q.100 The kinetic energy of 1 mole of gas is equal to

3 3 RT 2R
(1) RT (2) KT (3) (4)
2 2 2 3

CatalyseR Eduventures (India) Pvt. Ltd. 10

Q.101 The root mean square velocity of an ideal gas in a closed container of fixed volume is increased from
5 x 104 cm. s–1 to 10 x 104 cm. s–1. Which of the following statements might correctly explain how the change
accomplished
(1) By heating the gas, the temperature is doubled
(2) By heating the gas, the pressure is made four times
(3) By heating the gas, the volume is tripled’
(4) By heating the gas, the pressure is doubled.
Q.102 With increase in pressure, the mean free path
(1) Increases. (2) Becomes zero (3) Decreases (4) Remains constant
Q.103 Which of the following substances can be used for drying of gases
(1) P2O5 (2) H2SO4 (3) CaO (4) all
Q.104 The term that accounts for intermolecular force in vander Waal’s equation” for non ideal gas is
[1] RT [2] V - b [3] (P + a / V2) [4] [RT]–1
Q.105 The critical temperature of a substance is
[1] The temperature above which the substance undergoes decomposition

eR
[2] The temperature above which a substance can exist only as a ga,s
[3] Boiling point of the substance [4] All are wrong
Q.106 Critical temperature of the gas is the temperature
[1] Below which it cannot be liquified [2] Above which it cannot be liquified
[3] At which it occupies 22.4 L of volume [4] At which one mole of it occupies volume of 22.4 L
Q.107 A box of 1 L capacity is divided into two equal compartments by a thin partition which are filled with 2g H2 and

[1] P [2] 2P
ys
16gm CH4 respectively. The pressure in each compartment is recorded as P atm. The total pressure when
partition is removed will be
[3] P/2 [4] P/4
Q.108 26 c.c. of CO2 are passed over red. hot coke. The volume of CO evolved is
al
[1] 15 c.c [2] 10 c.c. [3] 32 c.c. [4] None
Q.109 The oxygen and hydrogen formed during electrolysis of Water are in the weight ratio of
[1] 2 : 1 [2] 8 : 1 [3] 16 : 1 [4] 1 : 8
Q.110 An open vessel containing air is heated from 27°C to 127°C. The fraction of air originally present which goes out
at

of it is

3 1 2 1
[1] [2] [3] [4]
4 4 3 8
Q.111 Which of the following is valid at absolute zero - .
C

[1] KE of the gas becomes zero, but molecular motion does not become zero.
[2] KE of the gas becomes zero and the molecular motion also becomes zero.
[3] KE of the gas decreases but does not become zero.
[4] None of these.
Q.112 Reducing the pressure from 1.0 atm to 0.5 atm would change the number of molecules in one mole of ammonia
to -
[1] 75% of initial volume [2] 50% of initial volume
[3] 25% of initial volume [4] None ofthese
Q.113 Which of the following represents the avogadro number
[1] Number of molecules present-in 1 L of gas at N.T.P.
[2] Number of molecules present in 22.4 ml of gas at N. T. P.
[3] Number of molecules present in 22.4 L of gas at 298K and 1 atm. pressure
[4] Number of molecules present in one mole of gas at any temp. and pressure.

CatalyseR Eduventures (India) Pvt. Ltd. 11

Q.114 The mean values of densities of liquid and saturated vapour for any stable substance are a linear function of
[1] Temperature [2] Pressure [3] Volume [4] None ofthese.
Q.115 Which of the following is true
[1] urms > v > .. [2] urms < v < .. [3] urms > v < .. [4] urms < v > 

Q.116 Some moles of O2 diffuse through a small opening in 18 seconds. Same number of moles of an unknown gas
diffuse through the same opening in 45 seconds. Molecular mass of the unknown gas is :

(18)2 (45)2 18 45
(1) 32 x (2) 32 x (3) (32)2 x (4) (32)2 x
(45)2 (18)2 45 18

Q.117 The number ofmoles of H2 in 0.224 litre of hydrogen gas at STP is:
(1) 0.1 (2) 0.01 (3) 0.001 (4) 1
Q.118 If a gas is allowed to expand at constasnt temperature then:
(1) Number, of molecules of the gas decreases

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(2) Tbe kinetic energy of gas molecules remains the same
(3) The,kinetic energy of gas molecules increases
(4) The kinetic energy of gas molecules decreases
Q.119 If the pressure and absolute temperature of 2 litres of CO2 are doubled, the volume of CO2 would become:
(1) 2 litres (2) 4 litres (3) 5 litres (4) 7 litres
Q.120 0.24 g of a volatile gas upon vapourisation gives 45 ml vapour at N.T.P. What will be vapour: density of the
ys
substance? (Density of H2 =0.089)
(1) 95.39 (2) 5.993 (3) 95.93 (4) 59.93
Q.121 The gas molecules have rms velocity of its molecules as 1000 m/s. What is its average velocity?
(1) 1012 m/s (2) 921.58 m/s (3) 546 m/s (4) 960 m/s
Q.122 If the volume of 2 moles of an ideal gas at 540 K is 44.8 litre then its pressure will be :
al
(1) 1 atmosphere (2) 2 atmosphere (3) 3 atomsphere (4) 4 atmosphere
Q.123 The compressibility factor of an ideal gas is
(1) 0 (2) 1 (3) 2 (4) 4
Q.124 One mole of N2O4(g) at 300 K is kept in a closed container under one atmospheric pressure. It is heated to 600
at

K when 20% by mass of N2O4(g) decomposes to NO2(g). The resultant pressure is :

(1) 1.2 atm (2) 2.4 atm (3) 2.0 atm (4) 1.0 atm
Q.125 A 0.5 litres flask contains gas ‘A’ and a one litre flask contains gas ‘B’ at the temperature. The density of gas ‘A’
is 3.0 grams/litre and that of gas ‘B’ is 1.5 grams/litre. The molar mass of gas ‘A’ is one half that of gas ‘B’. The
C

ratio of pressure PA/ PB exerted by the two gases is :

(1) 4 (2) 3 (3) 2 (4) 1
Q.126 At a temperature TK, the pressure of 4.0g argon in a bulb is P. The bulb is put in a bath having temperature higher
by 50 K than the first one. 0.8g of argon gas had to be reomved to maintain original pressure the temperature T
is equal to :
(1) 510 K (2) 200 K (3) 100 K (4) 73 K
Q.127 One mole of a monoatomic gas was expanded adiabatically agains constant external pressure (1 atm) from
volume 1 litre to 2 litre at an initial temperature of TK. The final temperature of the gas will be

T 2 2
(1) ( 5 / 3 1) (2) T (3) T  (4) T 
2 3  0.0821 3  0.0821
Q.128 At 298 K, if the ionic product of water is Kw and ionisation constant is K then :
[1] K = Kw [2] 55.55 K = Kw [3] K = 55.5 Kw [4] K = 1.8 Kw

CatalyseR Eduventures (India) Pvt. Ltd. 12

Q.129 The aqueous solution of H2S has the equilibrium : H2S H+ + HS–
If HCl is added to this solution without changing temperature then :
[1] Concentration of HS– increases [2] Concentration of HS– decreases
[3] Concentration of H2S decreases [4] Equilibrium constant changes

N
Q.130 The pH of KOH solution is :
1000
[1] 10–11 [2] 3.0 [3] 11 [4] 2.0
Q.131 The hydrolysis constants of two salts M1X and M2X formed from strong acid and weak base are 10–6 and 10–3
respectively. If Kb = 10–3 for M3OH then base strength :
[1] M1OH < M2OH < M3OH [2] M1OH > M2OH > M3OH
[3] M3OH > M1OH > M2OH [4] None of these
Q.132 The first and second ionisation constants of H2S are K1 and K2 respectively. If ionisation constant of H2S is K
then :
[1] pK = pK1 + pK2 [2] pK = pK1 – pK2 [3] pK + pK2 = pK1 [4] pK + pK1 – pK2 = 0

eR
Q.133 The Hunderson equation for the pOH of a basic buffer is :
[Salt] [ Acid]
[1] pOH = 14 – log [2] pOH = 14 – log
[ Acid] [Salt]

[Base ] [Salt]
[3] pOH = pKb + log [4] pOH = pKb + log
[Salt] ys [Base ]
Q.134 In the reaction : HNO3 + H2O H3O+ + NO3–
the conjugate base of HNO3 is :
[1] H2O [2] H3O+ [3] NO3– [4] H3O+ and NO3–
Q.135 The correct sequence of the colours obtained by the dissociation of methyl orange is :
al
[1] MeOH (Red) Me+ (Colourless) + OH– (Yellow)
[2] MeOH (Red) Me+ (Yellow) + OH– (Colourless)
[3] MeOH (Yellow) Me+(Colourless) + OH– (Red)
[4] MeOH (Yellow) Me+ (Red) + OH– (Colourless)
at

Q.136 0.05 M ammonium hydroxide solution is dissolved in 0.001 M ammonium chloride solution. What will be the OH–
ion concentration of this solution ?
Kb(NH4OH) =1.8 × 10–5
–3
[1] 3.0 × 10 [2] 9.0 × 10–4 [3] 9.0 × 10–3 [4] 3.0 × 10–4
C

Q.137 Ksp value of Al(OH)3 and Zn(OH)2 are 8.5 x 10–23 and 1.8 x 10–14 respectively. If NH4OH is added in a solution of
Al3+ and Zn2+, which will precipitate earlier
[1] Al (OH)3 [2] Zn(OH)2 [3] Both together [4] None
Q.138 H2O can act either as an acid or a base. Which of the following reaction bast illustrates the behaviour of water
as a base
[1] HCl + H2O  H3O+ + Cl– [2] HCl + NaOH  NaCl + H2O
[3] H2O + NH2–  NH3 + OH– [4] H2O + NH3  NH4+ + OH–

Q.139 Any precipitate is formed when

[1] Solution becomes saturated
[2] The value of ionic product is less that than the value of solubility product
[3] The value of ionic product is equal than the value of solubility product
[4] The value of ionic product is greater than the value of solubility product

CatalyseR Eduventures (India) Pvt. Ltd. 13

Q.140 Correct statement is
[1] NH4Cl gives alkaline solution in water [2] CH3COONa gives acidic solution in water
[3] CH3COOH is a weak acid [4] NH4OH is a strong base
Q.141 The solubility product of a sparingly soluble salt AB at room temperature is 1.21 x 10–6. Its molar solubility is
[1] 1.21 x 10–6 [2] 1.21 x 10–3 [3] 1.1 x 10–4 [4] 1.1 x 10–3

Q.142 In the equilibrium HClO4 + H2O  H O+ + ClO – :
 3 4
[1] HClO4 is the conjugate acid of H2O [2] H2O is the conjugate acid of H3O+|
[3] H3O+ is the conjugate base of H2O [4] ClO4– is the conjugate base of HClO4

[Salt]
Q.143 The pH of a simple sodium acetate buffer is given by pH = pKa + log
[Acid]

Ka of acetaic acid = 1.8 × 10–5

If [Salt] = [Acid] = 0.1M, the pH of the solution would be about :
[1] 7 [2] 4.7 [3] 5.3 [4] 1.4

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Q.144 With reference to protonic acids, which of the following statements is correct :
[1] PH3 is more basic than NH3 [2] PH3 is less basic than NH3
[3] PH3 is equally basic as NH3 [4] PH3 is amphoteric while NH3 is basic
Q.145 If the solubility product of AgBrO3 and Ag2SO4 are 5.5 x 10–5 and 2 x 10–5 respectively, the relationship between
the solubilities of these can be correctly represented as
ys
[1] SAgBrO > SAg SO [2] SAgBrO < SAg SO [3] SAgBrO = SAg SO [4] SAgBrO  SAg SO
3 2 4 3 2 4 3 2 4 3 2 4
Q.146 The sulphide ion concentration [S2–]
in saturated H2S solution is 1 x 10–22. Which of the following sulphides
should be quantitativel precipitated by H2S in the presence of dil. HCl
Sulphide Solubility product
al
(I) 1.4 x 10–16
(II) 1.2 x 10–22
(III) 8.2 x 10–46
(IV) 5.0 x 10–34
at

[1] I, II [2] III, IV [3] II, III, IV [4] Only I

Q.147 A physician wishes to prepare a buffer solution at pH = 3.85 that efficiently resists changes in pH yet contains
only small concentration of the buffering agents. Which of the following weak acids together with its sodium salt
would be best to use
C

[1] m-chlorobenzoic acid (pKa = 3.98) [2] p-chlorocinnamic acid (pKa = 4.41)
[3] 2,5-dihydroxy benzoic acid (pKa = 2.97) [4] Acetoacetic acid (pKa = 3.58)
Q.148 pKa of a weak acid is defined as
1 1 1
[1] log10 Ka [2] log K [3] log10 K [4] –log10 K
10 a a a
Q.149 One weak acid (like CH3COOH) and its strong base together with salt ( like CH3COONa) is a buffer solution. In
which pair this type of characteristic is found -
[1] HCl and NaCl [2] NaOH and NaNO3 [3] KOH and KCl [4] NH4OH and NH4Cl
Q.150 Which one of the following is most soluble -
[1] CuS (KSP = 8 x 10–37) [2] MnS (KSP = 7 x 10–16) [3] Bi2S3 (KSP = 1 x 10–70) [4] Ag2S (KSP = 6 x 10–51)
Q.151 Which of the following is a buffer -
[1] NaOH + CH3COONa [2] NaOH + Na2SO4
[3] K2SO4 + H2SO4 [4] NH4OH + CH3COONH4

CatalyseR Eduventures (India) Pvt. Ltd. 14

Q.152 Which one has pH 12
[1] 0.01 M KOH [2] 1 N KOH [3] 1N NaOH [4] 1N Ca(OH)2
Q.153 A precipitate of CaF2 (KSP = 1.7 x 10–10) will be obtained when equal volume of the following are mixed -
[1] 10–4 M Ca2+ and 10–4 M F– [2] 10–2M Ca2+ and 10–3 M F–
[3] 10–5 M Ca2+ and 10–3 M F– [4] 10–3 M Ca2+ and 10–5 M F–
Q.154 If the solubility product of BaSO4 is 1.5 x 10–9 in water, its solubility in moles per litre is -
[1] 1.5 x 10–9 [2] 3.9 x 10–5 [3] 7.5 x 10–5 [4] 1.5 x 10–5
Q.155 Which of the following cannot be hydrolysed
[1] A salt of weak acid and strong base [2] A salt of strong acid and weak base
[3] A salt of weak acid and weak base [4] A salt of strong acid and strong base
Q.156 The ionic product of water at 25ºC is 10–14. The ionic product at 90ºC will be -
[1] 1 x 10–20 [2] 1 x 10–12 [3] 1 x 10–14 [4] 1 x 10–16
Q.157 By adding a strong acid to the buffer solution, the pH of the buffer solution -
[1] Remains constant [2] Increases [3] Decreases [4] Becomes zero

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Q.158 100 ml of 0.2 M H2SO4 is added to 100 ml of 0.2 M NaOH. The resulting solution will be
[1] Acidic [2] Basic [3] Neutral [4] Slightly basic
Q.159 Which hydroxide will have lowest value of solubility product at normal temperature (25ºC)
[1] Mg(OH)2 [2] Ca(OH)2 [3] Ba(OH)2 [4] Be(OH)2
Q.160 Solubility of AgCl at 20ºC is 1.435 x ys 10–3 gm per litre. The solubility product of AgCl is -
[1] 1 x 10–5 [2] 1 x 10–10 [3] 1.435 x 10–5 [4] 108 x 10–3
Q.161 Solubility of a salt M2X3 is y mol dm –3. The solubility product of the salt will be -
[1] 6y4 [2] 64y4 [3] 36y5 [4] 108y5
Q.162 The solubility of CaCO 3 in water is 3.05 x 10–4 moles/litre. Its solubility product will be -
[1] 3.05 x 10–4 [2] 9.3 [3] 6.1 x 10–4 [4] 9.3 x 10–8
al
Q.163 The solubility product of Ag2CrO 4 is 32 x 10–12. What is the concentration of CrO 4– ions in that solution
[1] 2 x 10–4 m/s [2] 16 x 10–4 m/s [3] 8 x 10–4 m/s [4] 8 x 10–8 m/s
Q.164 The solubility product of CuS, Ag 2S HgS are 10–31, 10–44, 10–54 respectively. The solubilities of these
sulphides are in the order -
at

[1] Ag2S > CuS > HgS [2] Ag2S > HgS > CuS
[3] HgS > Ag2S > CuS [4] CuS > Ag2S > HgS
Q.165  I3– , the Lewis base is
In the reaction I2 + I– 
C

[1] I2 [2] I– [3] I3– [4] None

Q.166 The hydride ion H–
is stronger base than its hydroxide ion OH–. Which of the following reaction will occur if
sodium hydride (NaH) is dissolved in water
[1] H– (aq) + H2O  H2O [2] H– (aq) + H2O ()  OH– + H2
[3] H– + H2O  No reaction [4] None



Q.167 If the Kb value in the hydrolysis reaction B + + H2O 
 BOH + H+ is 1.0 x 10–6, then the hydrolysis
constant of the salt would be -
[1] 1.0 x 10–6 [2] 1.0 x 10–7 [3] 1.0 x 10–8 [4] 1.0 x 10–9

Q.168 The solubility of BaSO 4 in water is 2.33 x 10–3 gm/litre. Its solubility product will be (molecular weight of
BaSO 4 = 233) –
[1] 1 x 10–5 [2] 1 x 10–10 [3] 1 x 10–15 [4] 1 x 10–20

CatalyseR Eduventures (India) Pvt. Ltd. 15

Q.169 Amongst the following, the one having characteristics of Lewis acid is -
[1] ClF3 [2] BF3 [3] NCl3 [4] BrF3

Q.170 pH of a solution can be expressed as -

[1] – loge [H+] [2] – log10 [H+] [3] loge [H+] [4] log10 [H+]

Q.171 The solubility of CaF 2 is 2 x 10–4 moles/litre. Its solubility product (K SP) is -
[1] 2.0 x 10–4 [2] 4.0 x 10–3 [3] 8.0 x 10–12 [4] 3.2 x 10–11
Q.172 The concentration of [H+]
and concentration of [OH¯] of a 0.1 aqueous solution of 2% ionised weak acid is
[Ionic product of water = 1 x 10–14] –
[1] 0.02 x 10–3 M and 5 x 10–11 M [2] 1 x 10–3 M and 3 x 10–11 M
[3] 2 x 10–3 M and 5 x 10–12 M [4] 3 x 10–2 M and 4 x 10–13 M
Q.173 Concentration CN– in 0.1 M HCN is - [Ka = 4 x 10–10]
[1] 2.5 x 10–6M [2] 4.5 x 10–6 M [3] 6.3 x 10–6 M [4] 9.2 x 10–6 M

eR
Q.174 In the process : BCl3 + PH3  Cl3B : PH3. The Lewis acid is
[1] PH3 [2] BCl3 [3] Both 1 & 2 [4] None
Q.175 Weakest acid is -
[1] HI [2] HBr [3] HCl [4] HF
Q.176 Review the equilibrium and choose the correct statement -



HClO4 + H2O 
 H3O+ + ClO4–
ys
[1] HClO4 is the conjugate base of H2O [2] H3O+ is the conjugate base of H2O
[3] H2O is the conjugate acid of H3O+ [4] ClO4– is the conjugate base of HClO4
Q.177 Which of the following is most soluble in water -
[1] MnS = (K SP = 8 x 10–37) [2] ZnS (KSP = 7 x 10–16)
al
[3] Bi 2S3 (KSP = 1 x 10–70)[4] Ag2S (KSP = 6 x 10–51)
Q.178 Which of the following statement about AgCl is wrong -
[1] AgCl is sparingly soluble in water
[2] AgI is less soluble in water as compared to AgCl
at

[3] AgCl precipitation takes place on mixing AgNO 3 and NaCl

[4] AgCl is more soluble in aqueous KI than water
Q.179 Solubility of a M2S salt is 3.5 x 10–6 then find out solubility product -
[1] 1.7 x 10–6 [2] 1.7 x 10–16 [3] 1.7 x 10–18 [4] 1.7 x 10–12
C

Q.180 Identify the correct order or solubility of Na2S, CuS and ZnS in aqueous medium -
[1] CuS > ZnS > Na2S [2] ZnS > Na2S > CuS
[3] Na2S > CuS > ZnS [4] Na2S > ZnS > CuS
Q.181 1M NaCl and 1 M HCl are present in an aqueous solution. The solution is
[1] Not a buffer solution with pH < 7 [2] Not a buffer solution with pH > 7
[3] A buffer solution with pH < 7 [4] A buffer solution with pH > 7
Q.182 The relationship between ionisation and change in concentration of any weak electrolyte is represented as

Ka Ka Ka
[1]  = [2]  = [3]  = K.C [4]  =
C C C2
Q.183 Which is nucleophile
[1] BF 3 [2] NH3 [3] BeCl 2 [4] H2O

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Q.184 The solubility in water of a sparingly soluble salt B 2 is 1.0 x 10–5 mol l –1. Its solubility product number will
be
[1] 4 x 10–15 [2] 4 x 10–10 [3] 1 x 10–15 [4] 1 x 10–10
Q.185 Which one of the following statements is not true
[1] The conjugate base of H2PO 4– is HPO 42–
[2] pH + pOH = 14 for all aqueous solutions
[3] The pH of 1 x 10–8 M HCl is 8
[4] 96,500 coulombs of electricity when passed through a CuSO 4 solution deposits 1 gram equivalent of
copper at the cathode
Q.186 A solution which is 10–3 M each in Mn2+, Fe2+, Zn2+ and Hg2+ is treated with 10–16M sulphide ion. If Ksp of
MnS, FeS, ZnS and HgS are 10–15, 10–23, 10–20 and 10–54 respectively, which one will precipitate first

[1] FeS [2] MgS [3] HgS [4] ZnS

Q.187 pH of a solution of 10 ml. 1N sodium acetate and 50 ml 2N acetic acid (K a = 1.8 x 10–5), is approximately

[1] 4 [2] 5 [3] 6 [4] 7

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Q.188 The concentration of K I and KCl in a certain solution containing both is 0.001 M each. If 20 mL of this
solution is added to 20 mL of a saturated solution of AgI in water. What will happen ?
Ksp AgCl = 10–10 ; Ksp AgI = 10–16
[1] AgI will be precipitated [2] AgCl will be precipitated
[3] There will be no precipitate ys [4] Both AgCl and AgI will be precipitated
Q.189 The rapid change of pH near the stiochiometric point of an acid base titration is the basis of indicator
detection. pH of the solution is related to the ratio of the concentrations of the conjugate acid HIn and base
In– forms of the indicator by the expression -

[1] log
In   pK

 pH
 HIn
[2] log  In   pK In  pH
al
In
HIn  

 HIn  In 
[3] log  In   pH  pK In [4] log  pH  pK In
   HIn
at

Q.190 A weak acid HX has the dissociation constant 1 × 10–5 M. It forms a salt NaX on reaction with alkali. The
degree of hydrolysis of 0.1 M solution of NaX is -
[1] 0.0001 % [2] 0.01 % [3] 0.1 % [4] 0.15 %
Q.191 The Ksp of Mg(OH)2 is 1 × 10–12. 0.01 M Mg(OH)2 will precipitate at the limiting pH -
C

[1] 3 [2] 9 [3] 5 [4] 8

Q.192 The correct expression for the solubility product of Ca3(PO 4)2 is -
[1] 108s5 [2] 27s5 [3] 16s4 [4] 81s4
Q.193 The solubility product of a salt, having the general formula MX2. In water is 4 × 10–12. The concentration of
M2+ ions in the aqueous solution of the salt is -
[1] 2 × 10–6 M [2] 1 × 10–4 M [3] 1.6 × 10–4 M [4] 4 × 10–10 M
Q.194 Equal volumes of the following Ca2+ and F– solutions are mixed, In which solution will the precipitation occur
Ksp of CaF 2 = 1.7 × 10–10
1. 10–2 m Ca2+ + 10–5 M F – 2. 10–3 M Ca2+ + 10–3 M F –
3. 10–4M Ca2+ + 10–2 M F – 4. 10–2M Ca2+ + 10–3 M F –
Select the correct answer using the codes given below -
[1] In 4 only [2] In 1 and 2 [3] In 3 and 4 [4] In 2,3 and 4

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Q.195 Given pH of a solution A is 3 and it is mixed with another solution B having pH 2. If both are mixed, then the
resultant pH of the solution will be -
[1] 3.2 [2] 1.9 [3] 3.4 [4] 3.5
Q.196 When 10 mL of 0.1 M acetic acid (pKa = 5) is titrated against 10 mL of 0.1 M ammonia solution (pkb = 5), the
equivalent point will occur at pH -
[1] 5 [2] 6 [3] 7 [4] 9
Q.197 In a saturated solution of the sparingly soluble strong electrolyte AgIO3 (Molecular mass = 283) the equilibrium
which sets in is

AgIO3(s)  Ag+(aq) + IO3- (aq)


If the solubility product constant Ksp of AgIO3 at a given temperature is 1.0 ´ 10-8, what is the mass of AgIO3
contained in 100 ml of its saturated solution ?
[1] 1.0 ´ 10-7 g [2] 1.0 ´ 10-4 g [3] 28.3 ´ 10-2 g [4] 2.83 ´ 10-3 g
Q.198 The first and second dissociation constants of an acid H2A are 1.0 × 10–5 and 5.0 × 10–10 respectively. The overall
dissociation constant of the acid will be

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[1] 5.0 × 10–15 [2] 0.2 × 105 [3] 5.0 × 10–5 [4] 5.0 × 1015
Q.199 Which one of the following statements is false ?
[1] An element of a substance contains only one kind of atoms
[2] A compound can be decomposed into its constituents
[3] Milk is a homogeneous mixture
ys
[4] All homogeneous mixtures are called solutions
Q.200 Which of the following best explains the law of conservation of mass ?
[1] No change in mass is observed when 2.0 g of Mg is heated in vacuum
[2] 1.2 g of carbon when burnt in excess of oxygen consumes only 3.2 g of it to form 4.4 g of carbon dioxide
al
[3] 12 g of carbon when heated in a limited supply of air produces only 20 g of carbon monoxide
[4] A sample of air on heating does not shown any change in mass but volume increases.
Q.201 Two gaseous samples were analyzed. One contained 1.2 g of carbon and 3.2 g of oxygen. The other contained
27.3% carbon and 72.7% oxygen. The experimental data are in accordance with -
at

[1] Law of conservation of mass [2] Law of definite proportions

[3] Law of reciprocal proportion [4] Law of multiple proportion
Q.202 The law of multiple proportions is illustrated by -
[1] Carbon monoxide and carbon dioxide [2] Potassium bromide and potassium chloride
C

[3] Water and heavy water [4] Calcium hydroxide and barium hydroxide
Q.203 Percentage of copper and oxygen in sample of CuO obtained by different methods were found to be same. This
proves the law of-
[1] Constant proportion [2] Multiple proportion [3] Reciprocal proportion [4] None of these
Q.204 The number of moles of KI required to produce 0.4 moles of K2 HgI4 by reaction with HgCl2 is -
[1] 0.4 [2] 0.8 [3] 3.2 [4] 1.6
Q.205 Which of the following statements is incorrect ?
[1] One gram atom of nitrogen contains Avogadro’s number of atoms
[2] One mole of ozone gas contains Avogadro’s number of molecules
[3] One mole of ozone contains Avogadro’s number of atoms
[4] One mole of electrons stands for 6.02 × 1023 electrons

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Q.206 One mole of nitrogen gas is the volume of -
[1] 1 litre of nitrogen at S.T.P. [2] 32 litres of nitrogen at S.T.P
[3] 22.4 litres of nitrogen atom S.T.P.
[4] 6.02 × 1023 molecules of oxygen at any temperature and pressure
Q.207 Three flasks of equal volumes contain CH4, CO2 and Cl2 gases respectively. They will contain equal number of
molecules if -
[1] the mass of all the gases is same
[2] the moles of all the gas is same but temperature is different
[3] temperature and pressure of all the flasks are same
[4] temperature, pressure, and masses are same in the flasks
Q.208 What is not correct regarding 22 g of CO2 ?
[1] It occupies always 11.2 L of volume at STP [2] It corresponds to 1 g molecule of carbon dioxide
[3] It contains one g-atom of oxygen [4] It contains 0.5 g-atom of carbon

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Q.209 Two flasks of equal capacity contain argon and chlorine gases respectively at room temperature. What is true
about them ?
[1] Both contain same number of atoms [2] Cl atoms are half of the Ar atoms
[3] Cl atoms are double the number of Ar atoms
[4] Chlorine molecules are double the number of argon molecules
Q.210 How many moles of potassium chlorate is to be heated to produce 11.2 litre oxygen.
ys
1 1 1 2
[1] mol [2] mol [3] mol [4] mol
2 3 4 3

Q.211 Which one is a false statement -

al
[1] 11.2 litre of a gas at NTP weight equal to vapour density
[2] 22.4 litre of water vapour at NTP when condensed gives 18ml of liquid water
[3] 1 mole of H2 at NTP occupies 11.2 litres of volume
[4] 5.6 litre of oxygen at NTP is equivalent to 0.25 moles
at

Q.212 Equal weight of NaCl and KCl are dissolved separately in equal volumes of solutions. Molarity of the two
solutions will be -
[1] Equal [2] That of NaCl will be less than that of KCl
[3] That of NaCl will be more than that of KCl solution [4] That of NaCl will be half of than that of KCl solution
C

Q.213 In m1 grams of a metal A displaces m2 gram of another metal B from its salt solution and if the equivalent weights
are E1 and E2 respectively then the equivalent weight of A can be expressed by -

m1 m2 m1 m1
[1] E1 = m × E2 [2] E1 = m × E2 [3] E1 = E × m2 [4] E1 =  E2
2 1 2 m2

Q.214 If law of conservation of mass was to hold true, then 20.8g of BaCl2 on reaction with 9.8g of H2SO4 will produce
7.3g of HCl and BaSO4 equal to -
[2] 11.65g [2] 23.3g [3] 25.5g [4] 30.6g
Q.215 The molecular weight of the compounds (a) Na2SO4 (b) Na3PO4. 12H2O and (c) Ca3(PO4)2 respectively are X, Y,
and Z. The correct set of their equivalent weights will be -

X Y Z Y Z X Z
[1] (a) (b) (c) [2] (a) X (b) (c) [3] (a) (b) Y (c) [4] (a) X (b) Y (c) Z
2 3 6 3 3 2 3

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 N
Q.216 0.59g of a dibasic acid is completely neutralized by 100 c.c of NaOH solution. What is the molecular weight
10
of the acid -
[1] 59 [2] 118 [3] 29.5 [4] 11.8
Q.217 A metal oxide is reduced by passing H2 gas. 3.15g of oxide on complete reduction gives 1.05g metal. We
concluded that -
[1] atomic weight of metal is 4 [2] equivalent weight of metal is 8
[3] equivalent weight of metal is 4 [4] atomic weight of metal is 8

N
Q.218 3.92g ferrous ammonium sulphate (FAS) consumes 50 ml of KMnO4 . What is the percentage purity of the
10
sample of FAS-
[1] 50% [2] 78.4% [3] 80% [4] 39.2%
Q.219 A bottle of commercial sulphuric acid (density 1.787g/ml.) is labelled as 86% by weight. What is the molarity of

eR
the acid -
[1] 1.717  86  1000/100 [2] 1.787  86  1000/100  49
[3] 1.787  86  1000/100  98 [4] None
Q.220 Review the following reactions -
(i) CaC2 + H2O  CaO + C2H2 ; (ii) C2H2 + H2  C2H4 ; (iii) nC2H4  (C2H4)n
What is the weight of polyethene obtained from 10kg CaC2 -
ys
[1] 4.375kg [2] 10kg [3] 15kg [4] 20kg
Q.221 An isotope of the element polonium, of atomic mass 210, is strongly radioactive and each day one two hun-
dredth part of it changes into an inactive isotope of lead. Approximately, how many atoms of lead are formed in
one day from one milligram of 210Po -
al
[1] 1.5  1016 [2] 3  1018 [3] 1.23  1019 [4] 1.2  1022
Q.222 If human blood contains 195 mg/ml of K+ ion; the molarity of the solution is -

195  1000 195  10 3  10 3 195  10 3  10 3 195  1000

[1] [2] [3] [4]
at

39 39 38 38

Q.223 W 1g of an element combines with oxygen forming W 2g of its oxide. The equivalent weight of the element is

 W1   W1   W2  W1   W1 
[1]  W  x 8 [2]  W  W  x8 [3]  W  x8 [4]  W  W  x8
C

 2  2 1  1   1 2

Q.224 KMnO4 reacts with oxalic acid according to the reaction

2KMnO4– + 5C2O42– + 16H+  2Mn2+ + 10CO2  + 8H2O

Then, 20 ml of 0.1 M KMnO4 is equivalent to
[1] 30 ml of 0.5 M C2H2O4 (Oxalic acid) [2] 50 ml of 0.1 M C2H2O4 (Oxalic acid)
[3] 20 ml of 0.5 M C2H2O4 (Oxalic acid) [4] 10 ml of 0.1 M C2H2O4 (Oxalic acid)
Q.225 In the following reaction 4NH3 (g) + 5O2 (g)  4NO(g) + 6H2O (l)
when 1 mole of ammonia and 1 mole of O2 are mixed. Then
[1] 0.2 mole of H2O is produced [2] 0.1 mole of NO is produced
[3] all the oxygen will be consumed
[4] all the ammonia will be consumed in order to form 1 mole NO

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 N
Q.226 When 3.92 gL–1 of a sample of Mohr's salt reacts completely with 50 ml. KMnO4 solution. The % purity of
10
the sample of Mohr's salt is
[1] 50 [2] 70 [3] 37 [4] 40
Q.227 For preparing 1 M solution of a compound from its impure sample, the weight of the substance required will
be
[1] more than the theoretical weight [2] less than the theroretical weight
[3] equal to the theoretical weight [4] less or equal to the theoretical weight
Q.228 When potassium permanganate is titrated against ferrous ammonium sulphate in acidic medium, the
equivalent weight of potassium permanganate is

molecular weight molecular weight molecular weight molecular weight

[1] [2] [3] [4]
3 5 2 10

Q.229 Avogadro numbers is -

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[1] Number of atoms in one gram of the element
[2] Number of milliliters which one mole of a gaseous substance occupies at N.T.P.
[3] Number of molecules present in one gram molecular mass of a substance
[4] All are correct
Q.230 What is the volume strength of 1.5 N H2O2 -
ys
[1] 4.8 [2] 8.4 [3] 3.0 [4] 8.0
Q.231 An aqueous solution of 6.3g oxalic acid dihydrate is made up to 250mL. The volume of 0.1N NaOH required to
solution is-
[1] 40mL [2] 20mL [3] 10mL [4] 4mL
al
Q.232 How many moles of electrons weigh one kilogram :

1 6.023 1 10 8
[1] 6.02 × 1023 [2] × 1031 [3] × 1054 [4] ×
9.108 9.108 9.108 6.02
at

Q.233 25 mL of a solution of Ba(OH)2 on titration with a 0.1 M solution of HCl gave a titre value of 35 mL. The molarity
of barium hydroxide solution was :
[1] 0.07 [2] 0.14 [3] 0.28 [4] 0.35
Q.234 To neutralize completely 20 mL of 0.1 M aqueous solution of phosphorus acid (H3PO3), the volume of 0.1 M
aqueous KOH solution required is :
C

[1] 60 mL [2] 20 mL [3] 40 mL [4] 10 mL

Q.235 Two solutions of a substance (non electrolyte) are mixed in the following manner.480 ml of 1.5M first solution
+ 520 ml of 1.2 M second solution. What is the molarity of the final mixture?
[1] 1.20M [2] 1.50M [3] 1.344M [4] 2.70M
Q.236 If we consider that 1/6, in place of 1/2, mass of carbon atom is taken to be the relative atomic mass unit, the
mass of one mole of a substance will–
[1] decrease twice [2] increase two fold
[3] remain unchanged [4] be a function of the molecular mass of the substance
Q.237 How many moles of magnesium phosphate, Mg3(PO4)2 will contain 0.25 mole of oxygen atoms–
[1] 1.25 x 10–2 [2] 2.5 x 10–2 [3] 0.02 [4] 3.125 x 10–2
Q.238 Density of a 2.05M solution of acetic acid in water is 1.02g/mL. The molality of the solution is–
[1] 2.28 mol kg–1 [2] 0.44 mol kg–1 [3] 1.14 mol kg–1 [4] 3.28 mol kg–1

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Q.239 Lithium chloride is highly soluble in -
[1] C6H6 [2] H2O [3] D2O [4] All
Q.240. Alkali metals salts are -
[1] Diamagnetic and coloured [2] Diamagnetic and colourless
[3] Paramagnetic and coloured [4] Paramagnetic and colourless
Q.241 The ionic radii of alkali metal ions in water (hydrated radii) are in the order -
[1] Li+ > Na+ > K+ > Rb+ > Cs+ [2] Li+(aq) > Na+(aq) > K+(aq) > Rb+(aq) > Cs+(aq)
[3] Li+ < Na+ > K+ > Rb+ > Cs+ [4] Li+(aq) > Na+(aq) < K+(aq) < Rb+(aq) < Cs+(aq)
Q.242 Sodium form Na+ and not Na2+ because -
[1] Sodium contains only one electron in outer most shell
[2] First ionisation potential is small and the difference in first and second ionization potentials is very large
[3] Radius of Na2+ is much smaller than of Na+

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[4] None of these
Q.243 Which of the following alkali metals has the biggest tendency of the half reaction -
M(g)  M+(aq) + e
[1] Sodium [2] Lithium [3] Potassium [4] Cesium
Q.244 Both Be and Al become passive on reaction with conc. nitric acid due to -
ys
[1] The non reactive nature of the metal [2] The non reactive nature of the acid
[3] The formation of an inert oxide layer on the surface of the metals
[4] None of these
al
Q.245 Sodium loses its lustre on exposare to air due to the formation of -
[1] Na2O, NaOH and Na2CO3 [2] Na2O and NaOH [3] Na2O and Na2CO3
[4] NaOH and Na2CO3
Q.246 Sodium has ----------- as compared to potassium -
at

[1] Less electronegativity [2] More ionization potential [3] Large atomic radius [4] Lower melting point
Q.247 In the case of the alkali metals -
[1] The cation is less stable that the atom [2] The cation is smaller than the atom
C

[3] The cation and the atom have about the same size [4] The cation is larger than the atom
Q.248 Element of group I and group VII in the periodic table have one thing common. That is with the increasing atomic
number the -
[1] Maximum valency increases [2] Reactivity increases
[3] Atomic radius increases [4] Oxidising power increases
Q.249 The chloride ion is isoelectronic with patassium. The size of chloride ion is -
[1] Large than K+ion [2] Smaller than K+ ion [3] Same as that of K+ ion [4] None of these
Q.250 Increasing order of stability of -
I. K2CO3 II. MgCO3 III. Na2CO3
[1] I < II < III [2] II < III < I [3] II < I < III [4] I < III < II

END OF HOLIDAY ASSIGNMENT

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 HOLIDAY ASSIGNMENT - CHEMISTRY
ANSWER KEY

Qus. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 1 2 2 1 1 3 1 4 1 1 1 2 1 4 4 1 4 4 2 4
Qus. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. 2 1 2 4 1 3 4 2 3 3 1 4 2 1 4 3 4 1 2 4
Qus. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 3 2 3 4 4 4 2 4 3 1 3 1 4 4 1 1 3 4 3 3
Qus. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
Ans. 4 3 3 1 2 1 3 4 4 1 4 1 1 1 1 1 2 4 1 3

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Qus. 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
Ans. 4 1 4 4 3 2 4 2 4 2 1 3 4 1 4 1 1 3 3 1
Qus. 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
Ans. 2 3 4 3 2 42 2 1 2 2 4 4 2 1 2 2 2 1 4
Qus. 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140
Ans. 2 2 3 2 4 2 3 2 2 3 3 1 4 3 4 2 1 1 4 3

4 2 2 2 1 3 3 4
ys
Qus. 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160
Ans. 4 2 4 1 2 2 4 1 1 1 4 2
Qus. 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
Ans. 4 4 1 1 2 2 3 2 2 2 4 3 3 2 4 4 2 4 2 4
Qus. 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200
al
Ans. 1 2 2 1 3 3 1 1 3 2 2 1 2 4 2 3 4 1 3 2
Qus. 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220
Ans. 2 1 1 4 3 3 3 2 3 2 3 3 1 2 1 2 3 1 3 1
Qus. 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240
at

Ans. 1 2 3 2 3 1 1 2 3 2 1 2 1 3 3 1 1 2 1 2
Qus. 241 242 243 244 245 246 247 248 249 250
Ans. 2 2 2 3 1 2 2 3 1 2
C

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