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1 3.18 5 x1 2 x 2
1. (c) No. of moles of O atoms = 3 mole of H = 3 = x = 3
1.06 mol kw 10 14
h 1
2. (a) Kh KaKb = (3 10 7 )2
8. (a) 1 h = = = 3 ,h =
0.25 or 25%
1
A2( g )
B( g ) C( g )
9. (a) 2
3. (a)
t 0 100 0 0
4. (a) N has half filled p-subshell therefore its
electron affinity in minimum, in group 16 2nd member t 5 100-p p p /2
has high electron affinity than 1st member therefore O < p
100
S. Hence answer is N < O < S < Cl At t 5min 2 = 100 , p = 20
Na2 CO3 CaCO3 20
5. (d) 106g 100g
Hardness in rate of disappearance of A2 = 5 = 4
106 g H2O 100g CaCO3 10. (d) When all particles along one body diagonal are
Hardness in 10L (10 ml 10 g)H2O 1g CaCO3
4 4
removed, these 2X particles from corner are removed
one Y particle removed and 2Z particle removed
100g CaCO3 required = 106g Na2 CO3
1 1 15
6 6
1g CaCO3 required = 1.06 g Na2 CO3
Hence new arrangement, X particle = 8 2 = 4
1000M , Y particle = 3, Z particle = 6
6. (c) Use relation, m’ (molarity) = (1000d Mm) X YZ X YZ
Hence formula = 15/4 3 6 = 5/4 2 = X5Y4Z8
7. (c) G1 5x1F G02 2x2 F G03 = G10 G20
0
11. (d)
3xF = 5x1F (2x2F )
12. (d)
13. (a) PbO2 does not have peroxide linkage
= 5x1F x2F
14. (a) Na2 Ba4O7·10H2O in actually exist as 29. (b)
Na2 [B4O5 (OH2 )]·8H2O
15. (b)
16. (a) because NH4NO3 on heating gives N2 O and
NH4NO2 on heating gives N 2 30. (b) Treatment with bromine water gives aldonic acid
in which only —CHO of aldose in oxidised.
17. (b) because ionic radii decrease with increase in the
31. (d) f () sin 3sin cos 5cos
2 2
atomic number
18. (a) 3 3
1 4cos2 sin 2 3 2 cos 2 sin 2
Chloride K2Cr2O7(solid) Conc.H2 SO4
2 2
19. (d)
f
reddish brown vapour of chromyl chloride (CrO2 Cl 2 ) Minimum of f () and 2 will be same because
Pass the vapour of CrO2 Cl 2 into NaOH solution, yellow 5 1
3
Na2 CrO4 solution in formed. of the type of function a sin b cos and is 2 2
20. (b) 1
21. (a) It has two chiral carbon as well as symmetrical g() = 2
therefore, there will be a pair of enantiomers and a 1
meso form ) = 2
g (
22. (d) the most acidic group (—COOH) will be
neutralized
23. (a)
32. (c)
Clearly triangle formed by the given points
i j 2 k , i 2 j k and 2i j k is equilateral as
AB BC AC 2
Distance of orthocenter ‘ O ’ from the sides is equal
24. (a) Tolleng’s reagent forms precipitate of Silver
to inradius of the triangle
acetylide with terminal alkyne
3
EtO PhOH EtOH PhO ( 2 )2
Stronger Excess 4
25. (c) base
, The 3 1
( 2)
l1 l2 l3 = inradius = r = s = 2 = 6
nucleophile will be PhO
26. (b) 3 6
(l1 l2 l3 ) = 6 = 2
x y 1 z1
33. (b) Projection of line 2 2 1 on a plane P
x y 1 z1
is 1 1 1
Plane through these lines is perpendicular to the
plane P .
Normal to the plane determined by the given lines is
27. (c)
i j k
28. (b)
2 2 1
1 1 1
= 3i 3 j
Direction ratios normal to the required plane is
i j k 3sin x sin 3x
3 3 0 lim cos 2 x cos 3x2 cos x cos 2x
= x0 4x tan x
1 1 1 = 3i 3 j 6k
3 3 4sin 2 x
Equation of the plane is x y 2 z 3 = 0 as it passes
lim cos 2 x cos 3x 2 cos x cos 2x
through (0,1,1). x 0 4x
= cos x
3
Its distance from origin is 2. 1 3cos x (3 4sin 2 x )cos 3x
lim
= x0 cos2x cos3x 4x 2
34. (b) Any point on the given line is ( k 1,2k 1, k 1) .
3(cos x cos 3x ) 4sin2 x
but x = 0 A (0, 1,0) lim
x 0 4x 2
=
and y = 0 B (1 /2,0,1 /2) 6sin x sin 2x 4sin2 x
lim
35. (a) The possible arrangements of teachers and = x0 4x 2
students can be as follows:
3 sin x 2 sin 2x sin 2 x
(i) T S S T S S T S S lim
x 0 2
x 2x x2
(ii) S T S S T S S T S =
(iii) S S T S S T S S T =3+1=4
=
Hence, total number of ways = 3·(3!)6! = (18)6! x(sin 2 (sin x) cos2 (cos x))dx
40. (b) I 0 ...(1)
36. (c) Let the first term be a and the common
I = 0
difference d . ( x)(sin 2 (sin x) cos2 (cos x))dx
...(2)
Then it is given that a 8d = 55 and Adding (1) and (2)
25
1900 (2 a 24d ) 2000 2 2 (sin 2 (sin x) cos2 (cos x))dx
2 2I = 0
f (x) dy
1
ye = 2(t 1)
2t
Since dx = dx
3
4 f ( x )t = 1 t
When t = 1, y (1) = e
2
1t
2x 3 f (x) = t 3 = x
dx
43. (b) I = ( x 3x)( x 3x 2) 1
2 2
= x
2
dt dt 1
,
I = t(t 2) 1 (t 1) =
2 C
t1 =
II. f ( x) = x and g( x ) = x
3
Length of arc(s) = r
or = . r 49. (c) Case I : when Q is a quadratic equation
Therefore perimeter of the sector DP = (m 3) and DQ = (m 2)
2 2
p = r s r = 2r s ...(ii)
roots of 1st equation are 2, (m 1)
s 1 2 s 1
r rs 1
Substituting = r in (i), A = 2 r = 2 1,
roots of 2nd equation are 1m ,
2A
s = r . Now substituting the value of s in (ii), we For exactly there elements in P Q two of the roots
must be same
get
So we have following possibilities
2A
2r
p =
r or 2A = pr 2r
2
2 = (m 1) m = –3
1
Differentiating with respect to r , we get
2= 1 m m = 1/2
dA
2 m 1 = –1 m = 0
dr = p 4r = 0
For maximum value of order
1 for x 4x 4 = 1, x = 1 or 3
2
(m 1) = 1 m 1 m2 = –1 m = 2
Put x = 3 and 5 in the given relation to get
1 f (3) f (1) = 6 f ( 3) = 5
1 m = –1 m = 2
and f (1) f (9) = 10 f (9) 9
Case II : Now if m = 1, then Q becomes linear
f (3) f (9) 5 f (1) = 9
roots of Q as x = –1 n r 1/3
54. (b) Tr 1 = C , a , b where a = 2 and b = 3
n r 1/3
50. (b)
3 3i (i) 3 3i n 12 = – 3 n = 9
3 1 3i (1 i )
3 3 i (i )(1 i )
=
1 3i (1 i)
3 1 3i (1 i ) 55. (a)
=
Let BP = PQ = QC = x
(1 i )2
2 i
In ABP , using cosine rule
= 2 3 = 2 3 , which lies on imaginary axis
9 = c x 2cx cos B
2 2
arithmetic sequence. 2
x =5
5 5
xr x xr 2 xr
4 = 4 BC = 3x = 3 5
1
2r 5r 2 = 0, r = 2 and r = 2
2
x = 6 or 24
56. (d)
53. (c) x 6x 6 = x 4x 4 x = 1
2 2
P(3,0)Q(0,3t), R( 1,2t)
Put x in the given relation to get
Let the mid point of RN be ( h , k ) .
f (1) = 1
k =t
for x 6x 6 = 1, x = 1 or 5
2
2t 3t x y 4x 10y 19 = 0 (i)
2 2
RN PQ 2 h 2 3 = –1
Equation of circle passing through points of intersection
2t 2 = 2h 2
of circles x y 2x 6y 6 = 0 and
2 2
t2 = h 1
x2 y 2 2x 6y 6 = 0 is given by
k2 = h 1
(x2 y 2 2x 6y 6) (x2 y 2 2x 6y 6) = 0
2
Locus of ( h , k ) is y = x 1 (2 2)
x2 y 2 x 6y 6
57. (a) Let h be the length of the altitude from A 1 = 0 ...(ii)
h 122 122 As circle (ii) is orthogonal to circle (i), we have
Distance from centroid to BC = 3 = 11 60
2 2
= 61 2 2
2 5( 6)
=2 1 = 19 + 6
h = 6 is height of ABC 4 4 = 5 5
2
h = –9
Area = 3 = 12 3
5
x 2 y 2 x 6y 6
2h 2
3 Hence equation of circle is =0
Perimeter, P = 3 = 12 3
25 73
96
58. (b) Let y mx c be a tangent to the ellipse Radius of circle = 16 = 4
x2 y2
1 X i 2 4 6 8 ... 100
9 4 . 60. (b) Here, X = n = 50 =
Substituting the value of y mx c in equation of 50 51
50 = 51
ellipse, we get
x 2 (mx c)2 [ 2n = n(n 1) , here n = 50]
1
1
9 4
2
X12 X
Variance, = n
2
4 x 2 9(m2 x 2 2mxc c2 ) 36
1 2
x 2 (4 9m2 ) 18mxc 9c2 36 0 (2 42 ... 1002 ) (51)2
= 50 = 833
Since, y mx c is a tangent. 61. (c)
D 0
(18mc)2 4(9c2 36)(4 9m2 ) 0
324m2c2 4(36c2 144 81m2c2 324m2 ) 0
324m2c2 144c2 576 324m2c2 1296m2 0
1296m2 576 144c2 0
144c2 1296m2 576
144(9m2 4) The blocks will remain in contact till the blocks do not
c2
44 go above the natural length of the spring, because after
c 9m2 4 this condition the deceleration of the lower block
becomes more than the upper block due to spring force.
So they will get separated.
2mg
So, maximum possible amplitude = x0 = k
59. (a) 62. (a) W mg(2r ) 0 2mgr
Equation of circle circumscribing PAB is :
63. (b) n1 = Frequency of the police car horn observer
(x 1)(x 3) ( y 8)( y 2) = 0
heard by motorcyclist
n2 = Frequency of the siren heard by motorcyclist hc W01 E11 and hc W02 E22
d d
1 0.5 Using conservation of linear momentum
R R max
4v 4v
65. (b) For total internal reflection from surface BC 206v ' 4 v 0 v ' v'
(206) 206
e 2
( a )
M
IA
2
e
72. (b) L ma ma
2 2
2m
n 1/3
N 1 1
C sin sin C
73. (b) Here N 0 2 2
1
1
sin
l g where n = Number of half-lives = 3
N 1 NU 1
Liquid N0 1.26 N Pb NU 1.26
sin
Prism N Pb
N Pb 0.26NU 0.26
1.32 11 NU
sin sin
1.56 13 74. (b) Due to volume expansion of both liquid and
2I I 1 IRH vessel, the change in volume of liquid relative to
area · ·2 R· H
66. (d) Radiation force = c c2 c container is given by
I V V0 [ L g ]
67. (a) As both the halves are identical therefore 2 and V0 1000cc , g 0.1 104 /º C
Given
I
g 3 g 3 0.1 104 /º C 0.3 104 /º C
2 current will be distributed and magnetic field at the
centre due to both these halves will be equal and V 1000[1.82 104 0.3 104 ] 100 15.2cc
opposite therefore its value is 0. 75. (c) Resistance of network is
hc hc 1 1 1 1 1 1 1 1
E W0 Kmax W0 E1 and W0 E2
68. (c) 1 2 RP R1 R2 R3 12 12 12 4
RP 4 In path 4 range is maximum so football possesses
Total resistance, R 2 4 6 maximum horizontal velocity in this path.
e Blv 80. (d) As the relative acceleration is zero, the particles
( K 2 is open). Hence, charge Q will appear on the left the current coming from A1 will pass through A2
side of plate B and –Q on the right side of plate A , because in A3 branch resistance is connected
10
which will flow through K 1 to plate D . The current on 1A
I = 10
plate D is not induced current, hence there is no role of
dielectric constant K . Hence, reading of A1 A2 1A and that of A3 is 0 A.
9
R 1
87. (a) Equivalent resistance 9