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805
Ber. Bunsenges. Phys. Chem. 89, 805-809 (1985) - 0VCH Verlagsgesellschaft mbH, D-6940 Weinheim, 1985.
OOO5-9021/85/0707-0805 $02.50/0
806 E. Obermeier, S. Fischer, and D. Bohne: Thermal Conductivity, Density, Viscosity, and Prandtl-Numbers etc.
0,80 Density
Density measurements were performed with a digital den-
sity meter. The measuring principle is based on the variation
w
- of natural frequency of a hollow oscillator filled with liquid
mK
or gas [14]. The temperatures ranged between -10°C and
140°C and were checked by a calibrated platinum resistance
0,60 1.1 5
I0,50
g
-
h cm3
0,40
11.05
0,30
P
0,20
1.00
0,lO 0.95
-25 0 50 100 150 "C 200
t-
Fig. l a
Thermal conductivity of diethylene glycol-water mixtures 0.90
0 40 80 120 "C 160
t -
0,80 r
- Fig. 2a
A 100% trig Iy col Density of diethylene glycol-water mixtures
0 75% t r i g l y c o l
0 50% t r i g l y c o l
w
- 0 25 % t r i g l y c o l
mK VlOO % w a t e r
0,60
1
h
oso
0,40
0,30
0.20
0,l 0
-25 0 50 100 150 "C 200
t--- t -
Fig. l b Fig. 2b
Thermal conductivity of triethylene glycol-water mixtures Density of triethylene glycol-water mixtures
E. Obermeier, S . Fischer, and D. Bohne: Thermal Conductivity, Density, Viscosity, and Prandtl-Numbers etc. 807
thermometer with an accuracy of 0.2 K. Using a thermostat correlates measured data with an accuracy of f5%. The
the temperature was kept constant within k0.01 K. The constants ai have to be calculated with Eq. (10) using the
accuracy of measured density is about k 1.0. lop4 g/cm3. empirical constants given in Table 4. Eq. (9) fits (DWM)
The experimental data for (DWM) and for (TWM) are well data within +4%. Fig. 3 graphically shows the viscosity
represented by the quadratic equation data for (DWM) and (TWM).
Prandtl-Number
The Prandtl-Number is frequently used to describe char-
where Q is the density in kg/m3 and acteristic physical properties. The Prandtl-Number
j - 1 j = 2 j=3
Dynamic Viscosity
Viscosity was determined by means of a Hoeppler Falling
Body viscosimeter [lS] and an Ubbelohde capillary viscosi-
meter [16]. Both viscosimeters were calibrated with two
standard solutions. The accuracy of this methods is better
than f 2 % .
Experimental results are obtained in the range from
-10°C to 80°C for (DWM) and (TWM). Temperature
measurements were made as described above. The following
equation correlates the viscosity data with temperature and
concentration for (DWM):
In 4 = (a1)1,3514 + a 2 .t + (u3)06803.
t2 (9)
30 1000
mPas 500
300
25
100
20
1 ;:
t
rl
15
Pr
10
10 5
3
5
1
-25 0 50 100 "C 150
t-
0 Fig. 4b
-10 0 I0 20 30 40 50 60 "C 80 Prandtl-Number of triethylenc glycol-water mixturcs
t-
Fig. 3b
Viscosity of tricthylene glycol-water mixtures The accuracy of calculated Prandtl-Numbers (Eqs. (13), (14))
is better than +3%. Fig. 4 shows the Prandtl-Numbers as
1000 a function of temperature.
Table 3
500 Coefficients A,J of Eq. (9) - (DWM)
3 00 j = l j = 2 j = 3
1: Table 4
CoefficientsA,,, of Eq. (11) - (TWM)
Pr j = l j = 2 j = 3
j = l j = 2 j = 3
1
-25 0 50 100 "C 150
t- i = 1 1.4539 9.5616.10-' -2.1388.10-'
i =2 1.0111~10-~ 2.8728. lo-' -3.6635.
Fig. 4a i =3 1.6878.10-'0 1.4891. - 6.7294.10- "
Prandtl-Number of diethylene glycol-water mixtures
A. Lainez, J.-P. E. Grolier, and E. Wilhelm: Excess Molar Heat Capacity of (1,2-Dichloroethane + Benzene) Revisited 809
J.-P. E. Grolier
Laboratoire de Thermodynamique et Cinbtique Chimique, Universiti: de Clermont-Ferrand 2, F-63170 Aubiire, France
Emmerich Wilhelm
Institut fur Physikalische Chemie, Universitat Wien, WahringerstraDe 42, A-1090 Wien, Austria
Excess molar heat capacities C," at constant pressure were measured, as a function of mole fraction x1 at 298.15 K, for {xl 1,2-C2H&
+ x2CsHs}. Determinations in the regions x1 < 0.1 and x1 > 0.9 were emphasized. The instrument used was a Picker flow calorimeter.
The new data corroborate our results of 1977 [2]: CpE shows only one minimum at about xlSmin= 0.4595, and C,"(xl,min)= -1.162
J K-' mol-'. The "inverted" W-shaped composition dependence of CF, as inferred by Baiios et al. [9] from their measurements of excess
enthalpies between 288.15 and 318.15 K, is thus shown to be untenable.
1. Introduction for instance Refs. [2-41). Perhaps one of the most inter-
esting results obtained recently is the highly unusual com-
1,2-Dihaloethanes are classical examples of molecules position dependence of the excess molar heat capacity C,",
showing rotational isomerism (trans-gauche conformational at 298.15 K, in the series (1,2-DCE + an n-alkane) [S]. In
equilibrium) [I]. In particular, 1,2-dichloroethane (1,2- mixtures with the lower n-alkanes, say n-hexane, the curve
DCE) - either in the pure liquid state or in mixtures with CpE vs. mole fraction x1 of 1,2-DCE is almost W-shaped.
various hydrocarbons - has been well investigated, the fo- This behavior is remarkably similar to that found in the
cus being on thermodynamic and acoustic properties (see series (1P-dioxane + an n-alkane) [6]. At present, only a
Ber. Bunsenges. Phys. Chem. 89, 809-811 (1985) - 0VCH Verlagsgesellschaft mbH, D-6940 Weinheim, 1985.
OOO5 -9021/85/0707-0809 $02.50/0