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The first definition of calc-alkaline igneous rocks was that of Peacock’s alkali-
lime index. The variation diagram opposite shows the Ca and alkali contents of
a series of related volcanic rocks relative to their silica content. All these rocks
are related by crystal fractionation and the curves show fractionation trends.
As we saw in Skaergaard with increasing crystal fractionation silica contents in
a magma generally increase (because we are removing silica-poor minerals).
Calcium content of a magma may increase at first during fractionation prior to
the crystallisation of Ca-rich plagioclase. Once plagioclase begins to crystallise,
however, the Ca-content of the magma becomes less and the alkali-content
increases (because alkalis are not being removed by the Ca-rich plagioclase).
Where these two curves cross gives peacock’s alkali-lime index. Peacock
defined igneous rocks with an index of between 56-61 as calc-alkali. Tholeiites
have indexes of 51-56 and alkaline rocks of <51.
2.1. The Calc-Alkaline Fractionation Trend.
The modern definition of calc-alkaline, however, uses the form of fractionation trend on an AFM (alkali-Fe-Mg) diagram.
Unlike the Tholeiite-fractionation trend, which shows initial Fe-enrichment
due to the early crystallisation of Mg-rich silicates (e.g. olivine and
pyroxene), the calc-alkaline fractionation trend shows increases in alkalis
and little Fe-enrichment. Calc-alkaline rocks are also high in Al. Note that
calc-alkaline basalts have similar compositions to tholeiites but aluminous.
Andesites are mainly calc-alkaline, those with the highest Mg are known
as boninites.
The origins of the calc-alkaline trend are still controversial but are
known to relate to the effects of H2O on the phase relations controlling
crystal fractionation. The presence of water depresses the liquidus of
most dry-silicate minerals. Plagioclase will, therefore, be more Ca-rich at
lower temperatures. Dissolving water in magma also increases the
oxygen fugacity (see melt structure notes) and makes it more likely that
an iron-oxide will crystallise. Finally water in the magma also stabilises
hydrous minerals, such as hornblende, and allows them to crystallise from
Back-arc basins (such as the South Fiji Basin) tend to erupt tholeiites that are
similar to MORB. The reasons for extension in back-arc basins are
controversial, however, there is evidence for lithospheric thinning in these
regions and a shallow asthenosphere.
LILE are highly soluble in water whereas HFSE are not. The enrichment in LILE compared with HFSE in the magmas thus
suggests the source regions where enriched by aqueous solutions. The flat-profile and MORB-like abundances of the HREE
are also significant since although these elements are incompatible under most circumstances they are compatible in
garnet and will be retained by this mineral during melting. Magmas derived by melting of garnet peridotites, deep within the
mantle (e.g. kimberlites), thus have significant depletions in HREE relative to MORB. The lack of a depletion in the HREE thus
indicates garnet was absent from the source regions of convergent plate margins. This is important since basalts and
gabbros within subducted oceanic crust transform to
eclogite at pressure which contains abundant garnet.
Magmas generated at convergent plate margins,
therefore, cannot be generated by melting of
subducted oceanic crust but from the mantle wedge
overlying the subducting slab. The observation that K
(and the other incompatible elements) become
increasingly abundant with distance from the margin
(i.e. as the benioff zone increases in depth) would be
consistent with decreases in the amount of partial
melting.
3.1.a. Key Features
Magmas with affinities to island arc/cordilleria are
often identified on the basis of their depleted Nb and
Ta contents (these are HFSE), and their high Ba/Ti
contents (Ba is a LILE, Ti is a HFSE).
3.2. Isotopic Evidence.
The Nd-Sr isotopes of convergent plate margin
magmatic rocks support the evidence from trace
elements that these magmas originate from a depleted MORB-like source (i.e. depleted lithospheric mantle) that has been
enriched. They suggest the enriching fluids originate from oceanic sediments and/or seawater. The fact that many CPM
rocks plot to the right (i.e. are enriched in 87Sr) relative to the mantle array (MORB and OIB) in particular suggests seawater
contributes to their enrichment (shown as square in diagram).
(5) The calc-alkaline basaltic magmas produced by melting of the hydrated mantle wedge rise towards the surface. They
may be arrested and form magma chambers in which they evolve by crystal fractionation into the calc-alkaline series of
magmas or erupt at the surface as aluminous basalts. Later in the evolution of the magmatic arc rising basaltic
magmas will frequently encounter chambers and mix with the calc-alkaline magma. With increasing age of the arc
more silicic magmas are to be expected due to continued crystal fractionation and mixing of magmas. In cordilleria the
calc-alkaline magmas assimilate silica-rich continental crust explaining the predominance of silicic magmas.
(6) There are many complications that can affect the nature of melting by influencing the thermal regime and the
isotherms: (a) the rate of subduction, (b) the age of the subducting slab (young crust is hotter), (c) the age of the
subduction, (d) the extent to which the subducting slab causes downwards flow of the lithospheric mantle wedge.
with that in the surrounding metamorphic rocks. Migmatites (small pods of what appears to have been melted rock
surrounded by and grading into metamorphic rocks) are common. Some catazonal plutons appear to have formed by
either melting in place or by ultrametamorphism that grades into actually melting. Others appear to have intruded into
ductile crustal rocks.
Mesozonal. The mezozone occurs at intermediate crustal depths, likely between 8 and 12 km. The plutonic rocks are more
easily distinguished from the surrounding metamorphic rocks. Contacts are both sharp and discordant (cutting across
structures in the country rock), and gradational and concordant like in the catazone. The plutons generally lack foliation and
are often chemically and mineralogically zoned.
Epizonal. The epizone is the shallowest zone of emplacement, probably within a few kilometres of the surface. In such an
environment there is a large difference in temperatures between the magma and the country rock. The country rock is
commonly metamorphosed, but the metamorphism is contact metamorphism produced by the heat of the intrusion.
Contacts between the plutons and surrounding country rock are sharp and discordant, indicating intrusion into brittle and
cooler crust. Porphyrys are typical of the epizone.
1.1.d. Phase Relations
Another way of looking at the classification of granitic rocks is based on the feldspars, and whether or not they crystallized
under relatively dry low pressure conditions or "wet",
higher pressure conditions. At low pressure under dry
conditions, the alkali feldspars form a complete solid
solution at high temperature, but, upon slow cooling, they
eventually reach the solvus and exsolve into two
feldspars, one rich in albite and the other rich in
orthoclase. But, because of the low temperature at which
this occurs, only single feldspars will occur and these will
show a perthitic texture. Granites that crystallize under
low pressure and exhibit a single perthitic alkali feldspar
are considered hypersolvus granites.
The large volume of most batholiths was used as an argument for the formation of
granites by solid state metasomatism and recrystallisation of crustal rocks (known
as granitisation) since they represent a significant space problem. Many Granite
batholiths appear to have been emplaced without significant deformation of the surrounding country rocks. This is,
however, explained by emplacement by stopping in which the country rocks are fragmented and included in the granitic
magma as xenoliths. Many of these xenoliths then becoming assimilated into the magma to change its composition.
Stopping still represents a problem in the emplacement of granites since
large scale assimilation of country rocks will cool the magma rapidly. Rise
by diapirism, in which the granite rises buoyantly through existing country
rocks may also occur at depth where rocks are ductile. Plutons will also
make space for themselves at shallower levels by brittle failure and
extensional faulting of country rocks.
related to continental rifting events wherein continental lithosphere is thinned as a result of upwelling asthenosphere. They
are generally silica-rich and may evolve from alkaline magmas (with crustal assimilation).
M-type Granites have low silica (46-70 mole%) and are metaluminous. They have low 87Sr/86Sr ratios and high Ca contents.
They are found in small intrusions in ocean island arcs and probably originate by crystal fractionation of calc-alkaline
magmas and crustal assimilation.
1.5. Tectonic Setting of Orogenic Granites
Crustal thickening and its affect on the ambient geotherm plays an
important role in the genesis of orogenic granites. Underthrusting
during orogenesis can led to rapid increases in crustal thickness
and disequilibrated raised geotherms high enough to cause crustal
anatexis at depth and the generation of granitic magmas.
Dehydration of subducted oceanic crust or sediments buried during
mantle building may also generate granitic magmas by further
depression of the solidus.
Post orogenic extension occurs due to the relaxation of the
geotherm. The relaxation of the geotherm can locally raise
temperatures within the thickened continental crust and cause
further crustal anatexis. Sometimes the cooling lithosphere below
an orogenic belt can delaminate and sink causing rise of the
asthenosphere and enhanced heat flow. Decompression melting in
the rising asthenosphere may even generate basaltic magmas
which can intrude the crust to produce more anatexis.
In cordillera thickening due to compression also plays a
role in raising the geotherm which together with heat from basaltic
magmas, generated in the mantle wedge, underplating the
continental crust causes anatexis.
2. Lamprophyres
Lamprophyres are porphyritic rocks dominated by phenocrysts of
hydrous minerals (mainly phlogopite, biotite and/or hornblende) with
lesser amounts of cpx and/or melilite. Their groundmass often
includes silica-undersaturated minerals such as olivine and
feldspathoid. Textural evidence suggests they crystallised out of
equilibrium under high partial pressures of H2O.
Lamprophyres are frequently found associated with
tonalite-granodiorite-granodiorite plutons as late-stage, rapidly
emplaced dykes and plugs. They are often related to larger bodies of
hornblende-rich rocks known as appinites. Their origin is not yet fully
understood, however, their high incompatible and compatible
element concentrations suggests derivation by low degree partial
melting of metasomatised mantle within the mantle wedge. They are possibly related to the mantle-derived melts that may
produce large scale crustal anatexis and the formation of granitoid magmas. Mica-rich lamprophyres are known as
minettes.