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Reduced surface leakage current and trapping


effects in AlGaN/GaN high electron mobility
transistors on silicon with SiN/Al2O3...

Article in Applied Physics Letters · April 2011


DOI: 10.1063/1.3567927 · Source: IEEE Xplore

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APPLIED PHYSICS LETTERS 98, 113506 共2011兲

Reduced surface leakage current and trapping effects in AlGaN/GaN high


electron mobility transistors on silicon with SiN/ Al2O3 passivation
Z. H. Liu,1,2,a兲 G. I. Ng,1,2 H. Zhou,1 S. Arulkumaran,2 and Y. K. T. Maung2
1
School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore 639798
2
Temasek Laboratories, Nanyang Technological University, Singapore 637553
共Received 23 February 2011; accepted 28 February 2011; published online 17 March 2011兲
The surface leakage currents and the surface trapping effects of the AlGaN/GaN high electron
mobility transistors 共HEMTs兲 on silicon with different passivation schemes, namely, a 120 nm
plasma enhanced chemical vapor deposited SiN, a 10 nm atomic layer deposited 共ALD兲 Al2O3 and
a bilayer of SiN/ Al2O3 共120/10 nm兲 have been investigated. After SiN passivation, the surface
leakage current of the GaN HEMT was found to increase by about six orders; while it only increased
by three orders after the insertion of Al2O3 between SiN and AlGaN/GaN. The surface conduction
mechanism is believed to be the two-dimensional variable range hopping for all the samples. The
leakage current in the etched GaN buffer layer with SiN/ Al2O3 bilayer passivation was also much
smaller than that with only SiN passivation. The pulse measurement shows that the bilayer of
SiN/ Al2O3 passivation scheme can effectively reduce the surface states and suppress the trapping
effects. © 2011 American Institute of Physics. 关doi:10.1063/1.3567927兴

The GaN high electron mobility transistor 共HEMT兲 has samples with different passivation schemes were studied:
been demonstrated to be a promising candidate for high Sample A, without passivation; Sample B, passivated with
power amplifiers in the microwave communication system 120 nm PECVD SiN; Sample C, passivated with 10 nm ALD
and high-voltage power switches.1,2 Surface passivation is Al2O3; Sample D, passivated with a bilayer of 10 nm ALD
generally necessary to suppress the serious trapping effects Al2O3 and 120 nm PECVD SiN. Before passivation, the sur-
such as current collapse and dc-to-rf dispersion due to the face of the samples were carefully treated using ultrasonic
large surface states in GaN HEMTs.3 SiN grown by plasma acetone and isopropyl alcohol followed by buffered oxide
enhanced chemical vapor deposition 共PECVD兲 system is etchant 共HF: NH4F = 1 : 6.4兲. The PECVD SiN was deposited
widely used as the surface passivation dielectric and has with SiH4 : NH3 = 2 : 3 at rf power of 20 W and at 300 ° C; and
been demonstrated to be an effective material to reduce the the ALD Al2O3 was deposited with trimethylaluminum and
surface states on GaN or AlGaN.3 However, The surface H2O as precursors at 300 ° C. The dc and pulsed current-
leakage current of the GaN HEMT after PECVD SiN passi- voltage 共I-V兲 measurement were carried out using an HP
vation depends on the deposition conditions, and it has been 4156 semiconductor parameter analyzer and a Diva pulse
observed to obviously increase after passivation.4,5 measurement system, respectively.
Recently the Al2O3 grown by atomic layer deposition The surface leakage currents of the GaN HEMTs with
共ALD兲 system has attracted great interests in the application various passivation schemes were measured using the
of GaN metal-insultor-semiconductor HEMTs due to its high double-gate devices. The circuit configuration for the mea-
dielectric constant, high breakdown field, excellent unifor- surement is shown in Fig. 1共a兲, similar to the technique re-
mity and good quality.6–8 It has also been demonstrated to be ported in Ref. 12. The distances from gate 1 to gate 2 and
used as a surface passivation layer in the GaN HEMT.9,10 We from gate 2 to drain are 3 ␮m and 2 ␮m, respectively. The
have observed that a thin ALD Al2O3 layer used for the gate gate length and width are 1 ␮m and 50 ␮m, respectively.
dielectric and passivation can increase the 2-dimensional-
electron-gas sheet carrier density and drift mobility through
the suppression of the trapping effect.11 In this letter, we
report that the high surface leakage current in the GaN
HEMT caused by the PECVD SiN passivation can be re-
duced by inserting a thin ALD Al2O3 layer.
The GaN HEMT structure is shown in Fig. 1. It
was grown on a high-resistivity silicon substrate
共⬎6000 ⍀ cm兲 by metal-organic chemical vapor deposition.
Its epilayer includes a 2 nm unintentionally doped GaN cap
layer, a 17.5 nm Si-doped AlGaN barrier layer, a 1.2 nm AlN
spacer layer and a 1.5 ␮m undoped GaN buffer. The fabri-
cation details of the GaN HEMT can be found elsewhere.7
The device surface was passivated and the electrodes were
opened by etching away the dielectric for measurement. Four FIG. 1. 共Color online兲 共a兲 Schematic of the passivated AlGaN/GaN HEMT
with double gate and the circuit configuration for surface leakage current
measurement; 共b兲 schematic of the circuit configuration for etched GaN
a兲
Electronic mail: liuzhihong@ntu.edu.sg. buffer leakage current measurement.

0003-6951/2011/98共11兲/113506/3/$30.00 98, 113506-1 © 2011 American Institute of Physics


113506-2 Liu et al. Appl. Phys. Lett. 98, 113506 共2011兲

FIG. 3. 共Color online兲 共a兲 Arrhenius plot of surface leakage conductivity


from 25 to 175 ° C at VG1 = −20 V; 共b兲 leakage current of the etched GaN
FIG. 2. 共Color online兲 共a兲 The surface leakage current 共IG2兲 and 共b兲 vertical buffer with various passivation schemes.
leakage current 共ID兲 of the double-gate GaN HEMTs with various passiva-
tion schemes under the measurement configuration in Fig. 1.
leakage current, the Al2O3 passivated device shows the low-
est vertical leakage current among the three passivated de-
During the measurement, the gate 2 and drain were biased at
vices, whereas the SiN passivated device shows the highest
0 V, and the gate 1 was swept from 0 to ⫺20 V. The mea-
value.
surement of the etched GaN buffer leakage current was from
To further investigate the physical origin of the surface
two Ohmic contact electrodes fabricated on the AlGaN/GaN
leakage current, we carried out the temperature dependent
mesa with a gap of 5 ␮m and width of 50 ␮m, as shown in
I-V measurement for the double-gate devices from 25 to
Fig. 1共b兲. Between the two electrodes, the AlGaN/GaN was
175 ° C. The Arrhenius plot of the surface leakage conduc-
etched down to a depth around 200 nm.
tivity ␴sur is shown in Fig. 3共a兲. It can be seen that the
Figure 2 shows the measured vertical leakage current
devices without passivation and with Al2O3 passivation
共ID兲 and surface leakage current 共IG2兲. For comparison, the
have similar activation energies 共Ea = 0.065 eV and Ea
values of the currents at Vg1 = −20 V for four samples have
= 0.045 eV, respectively, see Table I兲. It means that the
also been listed in Table I. Compared to the device without
Al2O3 dielectric has not introduced any new surface leakage
passivation, the SiN passivation has increased the surface
mechanism. The device with SiN passivation has a much
leakage current up to six orders. However, the device passi-
different activation energy Ea = 0.26 eV. In CVD prepared
vated with 10 nm Al2O3 has a similar value of surface leak-
amorphous SiN alloy, typically two activation energies Ea1,
age current compared to the unpassivated device. The sur-
Ea2 exist in the leakage conductivity, as shown in the follow-
face leakage current of the device passivated with the
ing expression:13
SiN/ Al2O3 bilayer is three orders larger than those of the

冉 冊 冉 冊
devices unpassivated and passivated with Al2O3, but three
orders smaller than that of the device passivated with only Ea1 Ea2
SiN. This means that the surface leakage current of the de- ␴SiN = ␴1 exp − + ␴2 exp − ,
k BT k BT
vice with bilayer passivation neither flows along the
Al2O3 / nitride semiconductors interface, nor along the Al2O3 where Ea1 ⬎ Ea2 and Ea1 is typically around 0.7–0.8 eV from
bulk, but along the SiN bulk. The 10 nm Al2O3 has blocked the extended state conduction. Ea2 is typically around 0.1–
part of current injected from the SiN layer to the gate. It can 0.2 eV from the hopping conduction through the gap-states
be expected that a thicker Al2O3 can further suppress the near the Fermi level.13 The Ea value of 0.26 eV obtained
surface leakage current in the bilayer passivated device. from our measurement shows that, the surface leakage cur-
The vertical leakage current was also observed to in- rent after PECVD SiN passivation is due to the hopping
crease after passivation, as shown in Fig. 2共b兲. For all the conduction through the gap-states near the Fermi leveling in
samples, the magnitude of ID is at least one order larger than SiN. The device with bilayer passivation has an Ea of 0.14
that of IG2, indicating that the gate leakage current of the eV, which is believed to be resulting from the combination of
GaN HEMTs is mainly from the vertical path, namely, the the hopping conduction in SiN and the tunneling conduction
Schottky leakage current, instead of the surface path. The across the Al2O3.
increase in the vertical leakage current after passivation is We have also found that a straight line can be fit well for
believed to be due to the enhanced electrical line crowding at the plot of ln共␴sur兲 versus T1/3 for all the four samples 共the
the drain side of the gate. Similar to the case of the surface figures are not shown here兲. This verifies that the conductiv-

TABLE I. Various characteristics for the GaN HEMTs with different passivation schemes. 关ID, IG2 are the values at Vg1 = −20 V; Ibuf is the value at
V = −20 V兴.

ID IG2 Ea Ibuf Rsh Idmax drop at pulsed dc Ron increase at pulsed dc


Sample No. Passivation scheme 共mA/mm兲 共mA/mm兲 共eV兲 共mA/mm兲 共⍀ / sq兲 共%兲 共%兲

A Without passivation 6.1⫻ 10−5 1.0⫻ 10−8 0.065 2.1⫻ 10−7 367 59 72
B 120 nm PECVD SiN 1.4 1.2⫻ 10−2 0.26 6.3⫻ 10−2 324 0 0
C 10 nm ALD Al2O3 5.9⫻ 10−4 2.4⫻ 10−8 0.045 6.1⫻ 10−7 325 0 14
D SiN/ Al2O3 共120/10 nm兲 4.3⫻ 10−2 3.9⫻ 10−5 0.14 1.4⫻ 10−5 328 0 0
113506-3 Liu et al. Appl. Phys. Lett. 98, 113506 共2011兲

ity of the surface leakage follows the two-dimensional vari- proposed to be an appropriate passivation scheme to effec-
able range hopping model, as the following expression tively reduce the surface states without the introduction of
shows:12 large surface leakage current.
␴共T兲 ⬀ exp关− 共T0/T兲1/3兴, In conclusion, the PEDCVD SiN passivation has been
found to largely increase the surface leakage current for the
where T0 is the characteristic temperature. GaN HEMT, due to the hopping conduction through the gap-
The leakage current of the etched GaN buffer is also states near the Fermi level with Ea = 0.26 eV. The insertion
important for the actual GaN circuits. Figure 3共b兲 shows the of a thin ALD Al2O3 layer between the PECVD SiN and the
measured buffer leakage current of the four samples with nitride semiconductors can effectively reduce the surface
different passivation schemes. The unpassivated GaN buffer leakage current, and meantime maintain the effective passi-
and Al2O3 passivated GaN buffer show similar leakage cur- vation effect to reduce the surface states.
rents at voltage ⬎10 V. The SiN passivation increases the
leakage current by more than five orders, and the insertion of The authors would like to thank the Defense Science and
a 10 nm Al2O3 has lowered down the value by two orders. Technology Agency of Singapore for the support of this
To investigate the passivation effect of the various work.
schemes, the sheet carrier resistance 共Rsh兲 of the four
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