1. How will you separate a solution (miscible) of benzene and CHCl3?

a. Sublimation
b. Filtration
c. Distillation
d. Crystallization
2. The Lassaigne’s extract is boiled with conc. HNO3 while testing for halogens. By doing so
it
a. Increase the conc. Of NO3- ions
b. Decomposes Na2S & NaCN, if formed
c. Helps in the precipitation of AgCl
d. Increase the solubility product of AgCl
3. In Dumas’ method of estimation of nitrogen 0.35g of an organic compound gave 55Ml of
nitrogen collected at 300K temperature and 715mm pressure. The %age composition of
nitrogen in the compound would be(Aqueous tension at 300K=15mm)
a. 1.25
b. 15.45
c. 16.45
d. 17.45
4. 1.2g of organic compound of Kjeldalization liberates ammonia which consumes 30 cm-3
of 1N HCl. The %age of nitrogen in the organic compound is
a. 30
b. 35
c. 46.67
d. 20.8
5. In carius method of halogens, 0.099g organic compound gave 0.287g AgCl. The %age of
chlorine in the organic compound will be
a. 19.2
b. 18.11
c. 20.17
d. 71.71
6. In Kjeldahl’s method, ammonia from 5g of food neutralizes 30cm3 of 0.1N acid. The
%age of nitrogen in the food is
a. 1.68
b. 8.4
c. 16.8
d. 0.84
7. Monobromination of 2-methylbutane gives how many distinct isomers?
a. 3
b. 1
c. 4
 d. 2
8. The no. of metamers possible for C4H10O is
a. 4
b. 2
c. 3
d. 1
9. Methylacetate and propionic acid are
a. Geometrical isomers
b. Structural isomers
c. Stereoisomers
d. Functional isomers
10. Which of the following is the correct IUPAC name?
a. 3-ethyl-4, 4-dimethylheptane
b. 4, 4-dimethy-3-ethyllheptane
c. 5-ethyl-4, 4-dimethylheptane
d. 4, 4-bis (methyl)-3-ethyllheptane
11. The principle involved in paper chromatography is
a. Adsorption
b. Partition
c. Solubility
d. Volatility
12. The fragrance of flowers is due to the presence of some steam volatile organic compounds
called essential oils. These are generally insoluble in water at room temperature but are
miscible with water vapor in vapour phase. A suitable method for the extraction of these
oils from the flowers is:
a. Distillation
b. Crystallization
c. Distillation under reduced pressure
d. Steam distillation
13. Benzene reacts with CH3Cl in the presence of anhydrous AlCl3 to form
a. Chlorobenzene
b. Benzyl chloride
c. Xylene
d. Toluene
14. Which of the following reagents will be able to distinguish between 1-butyne & 2-butyne?
a. NaNH2
b. HCl
c. O2
d. Br2
15. The reaction of toluence with Cl2 in presence of FeCl3 gives X & reaction in presence of
light gives Y. Thus, X & Y are
a. X=benzal chloride, Y= o-chlorotoluene
b. X=o-chlorotoluene, Y=p-chlorotoluene
c. X=o-& p- chlorotoluene, Y=tri chloromethyl benzene
d. X=benzyl chloride, Y= m-chlorotoluene
16. Which of the following compounds will not undergo Friedel-Crafts reaction easily
a. Nitrobenzene
b. Toluene
c. Cumene
d. Xylene
17. Which of the following organic compounds has same hybridization as its combustion
product (CO2)?
a. Ethane
b. Ethyne
c. Ethene
d. Ethanol
18. The pair of electrons in the given carbanion, CH3C C-, is present in which of the
following orbitals?
a. SP2
b. SP
c. 2P
d. SP3
19. Consider the nitration of benzene using mixed conc. H2SO4 & HNO3. If a large amount of
KHSO4 is added to the mixture, the rate of nitration will be
a. Unchanged
b. Doubled
c. Faster
d. Slower
20. Which of the following can be used as the halide component for friedel-crafts reaction?
a. Chlorobenzene
b. Bromobenzene
c. Chloroethane
d. Isopropyl-chloride
21. With respect to the conformers of ethane, which of the following statements is true?
a. Bond angle changes but bond length remains same
b. Both bond angle & bond length remains change
c. Both bond angle & bond length remain same
d. Bond angle remain same but bond length change
22. Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by
Wurtz reaction is converted to gaseous hydrocarbon containing less than 4 carbon
atoms.(A) is
a. CH CH
b. CH2=CH2
c. CH3-CH3
d. CH4
23. Ozonolysis of an organic compound gives formaldehyde as one of the products. This
confirms the presence of :
a. Two ethylenic double bounds
b. A vinyl group
c. An isopropyl group
d. An acetylenic triple bond
24. The major organic compound formed by the reaction of 1,1,1-trichloroethane with silver
powder is
a. Acetylene
b. Ethene
c. 2-butyne
d. 2-butene
25. The trans-alkene are formed by the reduction of alkynes with
a. NaBH4
b. Na/liq.NH3
c. Sn-HCl
d. H2-Pd/C,BaSO4
26. 3- methyl-pent-2-ene on reaction with HBr in presence of peroxide forms an addition
product. The no. of possible stereoisomers for the product is
a. 4
b. 6
c. 0
d. 2
27. Among the following compounds the one that is most reactive toward electrophiles
nitroation is
a. Benzoic acid
b. Nitrobenzene
c. Toluene
d. Benzene
28. Which of the following acids does not exhibit optical isomerism?
a. Maleic acid
b. α- amino acids
c. Lactic acids
 d. Tartaric acid
29. Which of the following species contain equal no. of σ- & π-bonds?
a. (CN) 2
b. CH2 (CN) 2
c. HCO3-
d. XeO4
30. Which of the following statements is not correct for a nucleofile?
a. Ammonia is nucleofile
b. Nucleofile attack at low e-density sites
c. Nucleofiles are not electron seeking
d. Nucleofile ia a Lewis acid
31. The most suitable method of separation of 1:1mixture of ortho & para-nitrophenols is
a. Chromatography
b. Crystallization
c. Steam distillation
d. Sublimation
32. Which of the following is correct with respect to –I effect to the substituents?(R=alkyl)
a. -NH2 < -OR<F
b. -NR2 < -OR<F
c. -NH2 > -OR>F
d. -NR2 > -OR>F
33. The correct statement regarding electrofile is
a. Electrofile is a negatively charged species & can form a bond by accepting a pair
of electrons from another electrofile.
b. Electrofile are generally a neutral species & can form a bond by accepting a pair
of electrons from a nucleofile.
c. Electrofile can be either neutral or positively charged species & can form a
bond by accepting a pair of electrons from a nucleofile.
d. Electrofile is a negatively charged species & can form a bond by accepting a pair
of electrons from a nucleofile.
34. Which of the following compounds gives blood red colouration when its Lassaigne’s
extract is treated with alkali and ferric chloride?
a. Thiourea
b. Diphenyl sulphide
c. Phenyl hydrazine
d. Benzamide
35. Lassaigne’s test for the detection of nitrogen fails in
a. C6H5NHNH2.HCl
b. NH2.NH2.HCl
c. NH2CONH2
 d. NH2CONHNH2
36. Which is purified by steam distillation?
a. Aniline
b. Benzoic acid
c. Petroleum
d. Naphthalene
37. For the purification, isolation & separation of organic compounds, the latest tech.
followed is
a. Chromatography
b. Steam distillation
c. Fractional distillation
d. Vaccum distillation
38. Fractional distillation is a process by which the separation of different fractions from
mixture of solution is carried by making use of the following property of the fractions
a. Solubility
b. Boiling point
c. Melting point
d. Freezing point
39. The correct IUPAC name of CH3CH2CH(CH3)CH(C2H5)2 is
a. 4-ethyl-3-methylhexane
b. 3-ethyl-4-methylhexane
c. 4-methyl-3- ethyl hexane
d. 2,4-diethylpentane
40. 0.833 mole of a carbohydrate, with empirical formula CH2O, has 10g of hydrogen.
Molecular formula of carbohydrate is
a. C3H5O3
b. C6H12O6
c. C3H10O5
d. C3H4O3
41. Geometry of reaction intermediate in SN1 reaction is
a. Planner
b. Tringular bipyramidal
c. Tetrahedral
d. None of the above
42. Dehydrohalogenation of alkyl halide is a/an
a. Rearragement
b. Both nucleophilic substitution and elimination reaction
c. Nucleophilic substitution reaction
d. Elimination reaction
43. Which of the following an electrophile?
a. AlCl3
 b. CN-
c. NH3
d. CH3OH
44. Which of the following compound does not show anti-Markownikoff’s addiction?
a. Propene
b. 1-Butene
c. 2-Butene
d. 2-Pentene
45. Allyl cyanide contains _____Sigma bond and _______pi bond
a. 5, 7
b. 9, 9
c. 3, 4
d. 9, 3