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Chapter 3
Problems
Problem 3.1:
Given Data:
1 𝜕𝑉
𝑉𝑜𝑙𝑢𝑚𝑒 𝑒𝑥𝑝𝑎𝑛𝑠𝑖𝑣𝑖𝑡𝑦 = 𝛽 = ( )
𝑉 𝜕𝑇 𝑃
Or
1 𝑑𝑉
𝛽= ( ) → (1)
𝑉 𝑑𝑇 𝑃
1 𝜕𝑉
𝐼𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝐶𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑏𝑖𝑙𝑡𝑦 = 𝜅 = − ( )
𝑉 𝜕𝑃 𝑇
Or
1 𝑑𝑉
𝜅 = − ( ) → (2)
𝑉 𝑑𝑃 𝑇
𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇 = 50 0C
𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃1 = 1 𝑏𝑎𝑟
𝜅 = 44.18 ∗ 10−6 𝑏𝑎𝑟 −1
𝑘𝑔
𝐷𝑒𝑛𝑠𝑖𝑡𝑦 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 = 𝜌1 = 1 3
𝑚
𝑘𝑔
𝜌2 = (1 + 1%) 3
𝑚
𝑘𝑔
𝜌2 = 1.01 3
𝑚
𝑃2 =?
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Solution:
(a)
We know that
1
𝜌=
𝑉
1
𝑉=
𝜌
Put in (1) & (2)
𝑑 1
𝛽 = 𝜌( )
𝑑𝑇 𝜌 𝑃
𝜌 𝑑𝜌
𝛽 = − 2( )
𝜌 𝑑𝑇 𝑃
𝟏 𝒅𝝆
𝜷=− ( ) Proved
𝝆 𝒅𝑻 𝑷
Now,
𝑑 1
𝜅 = −𝜌 ( )
𝑑𝑃 𝜌 𝑇
𝜌 𝑑𝜌
𝜅= ( )
𝜌2 𝑑𝑃 𝑇
𝟏 𝒅𝝆
𝜿 = 𝝆 (𝒅𝑷) Proved
𝑻
(b)
As
1 𝑑𝜌
𝜅= ( )
𝜌 𝑑𝑃 𝑇
𝑑𝜌
𝜅𝑑𝑃 =
𝜌
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Problem 3.2:
𝝏𝜷 𝝏𝜿
( ) = −( )
𝝏𝑷 𝑻 𝝏𝑻 𝑷
Solution:
We know that
1 𝜕𝑉
𝑉𝑜𝑙𝑢𝑚𝑒 𝑒𝑥𝑝𝑎𝑛𝑠𝑖𝑣𝑖𝑡𝑦 = 𝛽 = ( )
𝑉 𝜕𝑇 𝑃
Since 𝛽 is very small
1 𝜕𝑉
𝑉= ( ) → (1)
𝜕𝛽 𝜕𝑇 𝑃
1 𝜕𝑉
𝐼𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝐶𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑏𝑖𝑙𝑡𝑦 = 𝜅 = − ( )
𝑉 𝜕𝑃 𝑇
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Problem 3.3:
Solution:
We Know That,
1 𝜕𝑉
𝐼𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝐶𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑏𝑖𝑙𝑡𝑦 = 𝜅 = − ( ) → (1)
𝑉 𝜕𝑃 𝑇
Given that
𝐴𝑃
𝑉 = 𝑉0 (1 − )
𝐵+𝑃
Where
V0 = Hypothetical molar/specific volume at zero pressure, so it is constant
V = Molar/specific volume
Now,
𝐴𝑃
𝑉 = 𝑉𝑜 − V
𝐵+𝑃 o
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𝐴𝑃
𝑉 − 𝑉𝑜 = − 𝑉
𝐵+𝑃 𝑜
𝑉 − 𝑉𝑜 𝐴𝑃
=−
𝑉𝑜 𝐵+𝑃
Differentiate w.r.t Pressure
1 𝜕 𝜕 𝐴𝑃
(𝑉 − 𝑉𝑜 ) = − ( )
𝑉𝑜 𝜕𝑃 𝜕𝑃 𝐵 + 𝑃
1 𝜕𝑉 𝐴(𝐵 + 𝑃) − 𝐴𝑃(1)
( − 0) = − [ ]
𝑉𝑜 𝜕𝑃 (𝐵 + 𝑃)2
1 𝜕𝑉 𝐴𝐵 + 𝐴𝑃 − 𝐴𝑃
− ( )=
𝑉𝑜 𝜕𝑃 (𝐵 + 𝑃)2
1 𝜕𝑉 𝐴𝐵
− ( )=
𝑉𝑜 𝜕𝑃 (𝐵 + 𝑃)2
Since, Temperature is constant
Therefore,
1 𝜕𝑉 𝐴𝐵
− ( ) =
𝑉𝑜 𝜕𝑃 𝑇 (𝐵 + 𝑃)2
Or, From (1)
𝑨𝑩
𝜿=( Proved
𝑩+𝑷)𝟐
Problem 3.4:
Given Data:
𝑐
𝐼𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝑐𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑏𝑖𝑙𝑖𝑡𝑦 = 𝜅 =
𝑉 (𝑃 + 𝑏)
𝑀𝑎𝑠𝑠 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 = 𝑚 = 1 𝑘𝑔
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𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃1 = 1 𝑏𝑎𝑟
𝑃2 = 500 𝑏𝑎𝑟𝑠
𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇 = 60 0C
𝑏 = 2700 𝑏𝑎𝑟𝑠
𝑐 = 0.125 𝑐𝑚3 ⁄𝑔
𝑊𝑜𝑟𝑘 = 𝑊 =?
Solution:
We know that
𝑊 = − ∫ 𝑃𝑑𝑉 → (1)
𝑐
𝜅= → (2)
𝑉(𝑃 + 𝑏)
Also
1 𝑑𝑉
𝜅 = − ( ) → (3)
𝑉 𝑑𝑃 𝑇
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𝑃2 𝑃2
1
𝑊 = 𝑐 ∫ 𝑑𝑃 − 𝑏𝑐 ∫ 𝑑𝑃
𝑃1 𝑃1 𝑃+𝑏
𝑃 𝑃
𝑊= 𝑐|𝑃|𝑃21 − 𝑏𝑐|𝑙𝑛(𝑃 + 𝑏)|𝑃21
𝑊 = 𝑐(𝑃2 − 𝑃1 ) − 𝑏𝑐[𝑙𝑛(𝑃2 + 𝑏) − 𝑙𝑛(𝑃1 + 𝑏)]
𝑃2 + 𝑏
𝑊 = 𝑐(𝑃2 − 𝑃1 ) − 𝑏𝑐 [𝑙𝑛 ]
𝑃1 + 𝑏
Putting values
Problem 3.5:
Given Data:
𝑊𝑜𝑟𝑘 𝑑𝑜𝑛𝑒 = 𝑊 =?
𝑉𝑜𝑙𝑢𝑚𝑒 = 𝑉 = 1 𝑓𝑡 3
𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇 = 32 𝐹
𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃1 = 1 𝑎𝑡𝑚
𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃2 = 3000 𝑎𝑡𝑚
𝜅⁄𝑎𝑡𝑚−1 = 3.9 ∗ 10−6 − 0.1 ∗ 10−9 𝑃(𝑎𝑡𝑚)
Where
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Term, 3.9*10-6 has unit of atm-1 & 0.1*10-9 has units of atm-2
Solution:
We know that, work done for a reversible process is
𝑊 = − ∫ 𝑃𝑑𝑉 → (1)
Also
1 𝑑𝑉
𝜅=− ( )
𝑉 𝑑𝑃 𝑇
𝑑𝑉 = −κVdP
Put in (1),
𝑊 = − ∫ 𝑃 (−𝜅𝑉𝑑𝑝)
𝑃2
𝑊 = 𝑉 ∫ 𝜅 𝑃 𝑑𝑃
𝑃1
𝑃2
𝑊 = 𝑉 ∫ (3.9 ∗ 10−6 − 0.1 ∗ 10−9 𝑃)𝑃 𝑑𝑃
𝑃1
𝑃2 𝑃2
𝑊 = 𝑉 ∫ 3.9 ∗ 10 𝑃 𝑑𝑃 − 𝑉 ∫ 0.1 ∗ 10−9 𝑃2 𝑑𝑃
−6
𝑃1 𝑃1
3000 3000
−6 −9
𝑊 = 3.9 ∗ 10 𝑉 ∫ 𝑃 𝑑𝑃 − 0.1 ∗ 10 𝑉 ∫ 𝑃2 𝑑𝑃
1 1
3000 3000
𝑃2
−6 −9
𝑃3
𝑊 = 3.9 ∗ 10 𝑉 | | − 0.1 ∗ 10 𝑉 | |
2 1 3 1
1.95 ∗ 10−6 ∗ 1 𝑓𝑡 3 2 2 2
3.333 ∗ 10−11 ∗ 1 𝑓𝑡 3
𝑊= (3000 − 1 )𝑎𝑡𝑚 −
𝑎𝑡𝑚 𝑎𝑡𝑚2
∗ (30003 − 13 ) 𝑎𝑡𝑚3
𝑊 = (17.55 − 0.8991)𝑎𝑡𝑚 ∗ 𝑓𝑡 3
𝑾 = 𝟏𝟔. 𝟔𝟓 𝒂𝒕𝒎 ∗ 𝒇𝒕𝟑 Answer
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Problem 3.6:
Given Data:
𝑀𝑎𝑠𝑠 = 𝑚 = 5 𝑘𝑔
𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃 = 1 𝑏𝑎𝑟
𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇1 = 0 0C
𝑇1 = 273.15 𝐾
𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇2 = 20 0C
𝑇2 = (20 + 273.15)𝐾
𝑇2 = 293.15 𝐾
𝛽 = 1.2 ∗ 10−3 𝐾 −1
𝑘𝐽
𝐶𝑃 = 0.84
𝑘𝑔 ∗ 𝐾
𝑘𝑔
𝜌 = 1590 3
𝑚
𝑡
∆𝑉 =?
𝑊 =?
𝑄 =?
∆𝑈𝑡 =?
Solution:
As
1
𝑉=
𝜌
1
𝑉1 =
𝜌1
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1 𝑚3
𝑉1 =
1590 𝑘𝑔
Also,
we know that
1 𝑑𝑉
𝑉𝑜𝑙𝑢𝑚𝑒 𝑒𝑥𝑝𝑎𝑛𝑠𝑖𝑣𝑖𝑡𝑦 = 𝛽 = ( )
𝑉 𝑑𝑇 𝑃
1
𝛽𝑑𝑇 = 𝑑𝑉
𝑉
Integrating on both sides,
𝑇2 𝑉2
𝑑𝑉
𝛽 ∫ 𝑑𝑇 = ∫
𝑇1 𝑉1 𝑉
𝑇 𝑉
𝛽|𝑇| 𝑇21 = |ln 𝑉|𝑉21
𝛽(𝑇2 − 𝑇1 ) = (ln 𝑉2 − ln 𝑉1 )
𝑉2
𝛽(𝑇2 − 𝑇1 ) = 𝑙𝑛
𝑉1
Putting values
1.2 ∗ 10−3 𝑉2 ∗ 1590𝑘𝑔
∗ (293.15 − 273.15)𝐾 = 𝑙𝑛
𝐾 𝑚3
𝑉2 ∗ 1590𝑘𝑔
𝑒 0.024 =
𝑚3
1.024 𝑚3
𝑉2 = ∗
1590 𝑘𝑔
𝒎𝟑
𝑽𝟐 = 𝟎. 𝟎𝟎𝟎𝟔𝟒𝟒
𝒌𝒈
Now,
∆𝑉 = 𝑉2 − 𝑉1
1 𝑚3
∆𝑉 = (0.000644 − )
1590 𝑘𝑔
−6
𝑚3
∆𝑉 = 15.28 ∗ 10
𝑘𝑔
Now, for total volume,
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∆𝑉 𝑡 = ∆𝑉 ∗ 𝑚
𝑡
𝑚3
−6
∆𝑉 = (15.28 ∗ 10 ∗ 5) ∗ 𝑘𝑔
𝑘𝑔
∆𝑽𝒕 = 𝟕. 𝟔𝟑𝟖 ∗ 𝟏𝟎−𝟓 𝒎𝟑 Answer
Now,
We know that for a reversible process,
𝑄 = ∆𝐻
𝑄 = 𝑚𝐶𝑃 ∆𝑇
𝑘𝐽
𝑄 = 5 𝑘𝑔 ∗ 0.84 ∗ (293.15 − 273.15) 𝐾
𝑘𝑔 ∗ 𝐾
𝑸 = 𝟖𝟒 𝒌𝑱 Answer
Now,
According to first law of thermodynamics,
∆𝑈 𝑡 = 𝑄 + 𝑊
∆𝑈 𝑡 = (84 − 7.368 ∗ 10−3 )𝑘𝐽
∆𝑼𝒕 = 𝟖𝟑. 𝟗𝟗 𝒌𝑱 Answer
Problem 3.7:
Solution:
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(a)
We know that
1 𝑑𝑉
𝐼𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝑐𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑏𝑖𝑙𝑡𝑦 = 𝜅 = − ( )
𝑉 𝑑𝑃 𝑇
𝑑𝑉
= −𝜅𝑑𝑃
𝑉
Integrating on both sides,
𝑑𝑉
∫ = −𝜅 ∫ 𝑑𝑃
𝑉
𝑙𝑛𝑉 = −𝜅𝑃 + 𝑙𝑛𝐴(𝑇)
(b)
Work done=W=?
For a mechanically reversible process, we have,
𝑑𝑊 = −𝑃𝑑𝑉 → (1)
Using,
𝑑(𝑃𝑉) = 𝑃𝑑𝑉 + 𝑉𝑑𝑃
−𝑃𝑑𝑉 = 𝑉𝑑𝑃 − 𝑑(𝑃𝑉)
Put in (1)
1 𝑑𝑉
𝐼𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝑐𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑏𝑖𝑙𝑡𝑦 = 𝜅 = − ( )
𝑉 𝑑𝑃 𝑇
𝑑𝑉
− = 𝑉𝑑𝑃
𝜅
Put in (2)
𝑑𝑉
𝑑𝑊 = − − 𝑑(𝑃𝑉)
𝜅
Integrating on both sides,
1
∫ 𝑑𝑊 = − ∫ 𝑑𝑉 − ∫ 𝑑(𝑃𝑉)
𝜅
1
𝑊 = − Δ𝑉 − Δ(𝑃𝑉)
𝜅
Since volume changes from V1 to V2 & pressure changes from P1 to P2 ,
Therefore,
1
𝑊 = − (𝑉2 − 𝑉1 ) − (𝑃2 𝑉2 − 𝑃1 𝑉1 )
𝜅
(𝑽𝟏 − 𝑽𝟐 )
𝑾= + 𝑷𝟏 𝑽𝟏 − 𝑷𝟐 𝑽𝟐 Proved
𝜿
Problem 3.8:
One mole of an ideal gas with CV = 5/2 R, CP = 7/2 R expands from P1 = 8 bars & T1=
600 K to P2 = 1 bar by each of the following path:
a) Constant volume
b) Constant temperature
c) Adiabatically
Assuming mechanical reversibility, calculate W, Q, ∆U, and ∆H for each of the three
processes. Sketch each path in a single PV diagram.
Given Data:
5
𝐶𝑉 = 𝑅
2
7
𝐶𝑃 = 𝑅
2
𝑃1 = 8 𝑏𝑎𝑟
𝑇1 = 600 𝐾
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𝑃2 = 1 𝑏𝑎𝑟
𝑊 =?
𝑄 =?
∆𝑈 =?
∆𝐻 =?
Solution:
(a)
∆𝑈 = 𝑄 + 𝑊 → (1)
For a constant volume process,
𝑊=0
∆𝑈 = 𝐶𝑉 ∆𝑇
Put in (1)
𝑄 = ∆𝑈 = 𝐶𝑉 ∆𝑇
𝑄 = ∆𝑈 = 𝐶𝑉 (𝑇2 − 𝑇1 ) → (2)
For T2 , We know that for an ideal gas
𝑇1 𝑇2
=
𝑃1 𝑃2
𝑇1
𝑇2 = ∗ 𝑃2
𝑃1
600 𝐾
𝑇2 = ∗ 1𝑏𝑎𝑟
8 𝑏𝑎𝑟
𝑇2 = 75 𝐾
Put in (2),
5
𝑄 = ∆𝑈 = 𝑅 (75 − 600) 𝐾
2
5 𝐽
𝑄 = ∆𝑈 = − ∗ 8.314 ∗ 525 𝐾
2 𝑚𝑜𝑙 ∗ 𝐾
𝐽
𝑄 = ∆𝑈 = −10912
𝑚𝑜𝑙
𝒌𝑱
𝑸 = ∆𝑼 = −𝟏𝟎. 𝟗𝟏𝟐 Answer
𝒎𝒐𝒍
Also
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∆𝑈 = 𝑄 + 𝑊
0=𝑄+𝑊
𝑄 = −𝑊
Or
𝒌𝑱
𝑸 = 𝟏𝟎. 𝟑𝟕𝟑 Answer
𝒎𝒐𝒍
(c)
∆𝑈 = 𝑄 + 𝑊
∆𝑈 = 𝑊 → (1)
∆𝑈 = 𝐶𝑉 ∆𝑇
Put in (1)
𝑊 = ∆𝑈 = 𝐶𝑉 ∆𝑇
𝑊 = ∆𝑈 = 𝐶𝑉 (𝑇2 − 𝑇1 ) → (2)
For T2 , We know that for an adiabatic process
(1−𝛾) (1−𝛾)
𝛾 𝛾
𝑇1 𝑃1 = 𝑇2 𝑃2
(1−𝛾)
𝑃1 𝛾
𝑇2 = 𝑇1 ( )
𝑃2
(1−1.4)
8 1.4
𝑇2 = 600 𝐾 ( )
1
𝑇2 = 331.23 𝐾
Put in (2)
5
𝑊 = ∆𝑈 = 𝑅 ∗ (331.23 − 600) 𝐾
2
5 𝐽
𝑊 = ∆𝑈 = − ∗ 8.314 ∗ 268.77 𝐾
2 𝑚𝑜𝑙 ∗ 𝐾
𝐽
𝑊 = ∆𝑈 = −5586.4
𝑚𝑜𝑙
𝑱
𝑾 = ∆𝑼 = 𝟓. 𝟓𝟖𝟔𝟒 Answer
𝒎𝒐𝒍
For a mechanically reversible adiabatic process we have
∆𝐻 = 𝐶𝑃 ∆𝑇
7
∆𝐻 = 𝑅 (𝑇2 − 𝑇1 )
2
7 𝐽
∆𝐻 = ∗ 8.314 ∗ (331.23 − 600)𝐾
2 𝑚𝑜𝑙 ∗ 𝐾
𝑱
∆𝑯 = −𝟕. 𝟖𝟐𝟏 Answer
𝒎𝒐𝒍
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2013
Problem 3.9:
An ideal gas initially at 600k and 10 bar undergoes a four-step mechanically reversible
cycle in a closed system. In step 12, pressure decreases isothermally to 3 bars; in step 23,
pressure decreases at constant volume to 2 bars; in step 34, volume decreases at constant
pressure; and in step 41, the gas returns adiabatically to its initial state. Take CP = (7/2)
R and CV = (5/2) R.
a) Sketch the cycle on a PV diagram.
b) Determine (where unknown) both T and P for states 1, 2, 3, and 4.
c) Calculate Q, W, ∆U, and ∆H for each step of the cycle.
Given Data:
Solution:
(b)
𝑻𝟐 = 𝑻𝟏 = 𝟔𝟎𝟎 𝑲
𝑷𝟐 = 𝟑 𝒃𝒂𝒓
We know that, for an ideal gas
𝑃2 𝑉2 = 𝑅𝑇2
𝑅𝑇2
𝑉2 =
𝑃2
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2013
𝒎𝟑
𝑽𝟑 = 𝑽𝟐 = 𝟎. 𝟎𝟏𝟔𝟔
𝒎𝒐𝒍
𝑷𝟑 = 𝟐 𝒃𝒂𝒓
We know that, for an ideal gas
𝑃3 𝑉3 = 𝑅𝑇3
𝑃3 𝑉3
𝑇3 =
𝑅
3
2 𝑏𝑎𝑟 ∗ 0.0166 𝑚 ∗ 𝑚𝑜𝑙 ∗ 𝑲 𝐽 101325 𝑁
𝑇3 = ∗ ∗
𝑚𝑜𝑙 ∗ 8.314 𝐽 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2
𝑻𝟑 = 𝟒𝟎𝟎 𝑲
𝑷𝟒 = 𝑷𝟑 = 𝟐 𝒃𝒂𝒓
For T4 , we will use an adiabatic relation of temperature and pressure
As
𝑅
𝑇4 𝑃4 𝐶𝑃
=( )
𝑇1 𝑃1
𝑅
𝑃4 𝐶𝑃
𝑇4 = 𝑇1 ( )
𝑃1
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PROBLEMS ZAID YAHYA 11-CH-74
2013
2∗𝑅
2 7𝑅
𝑇4 = 600 𝐾 ∗ ( )
10
𝑻𝟒 = 𝟑𝟕𝟖. 𝟖𝟑 𝑲
We know that, for an ideal gas
𝑃4 𝑉4 = 𝑅𝑇4
𝑅𝑇4
𝑉4 =
𝑃4
8.314 𝐽 ∗ 378.83 𝐾 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 𝑁𝑚
𝑉4 = ∗ ∗
𝑚𝑜𝑙 ∗ 𝐾 ∗ 2 𝑏𝑎𝑟 101325 𝑁 𝐽
𝒎𝟑
𝑽𝟒 = 𝟎. 𝟎𝟏𝟓𝟕
𝒎𝒐𝒍
Step 41, an adiabatic process,
Since
Gas returns to its initial state adiabatically
Therefore,
𝑻𝟏 = 𝟔𝟎𝟎 𝑲
𝑷𝟏 = 𝟏𝟎 𝒃𝒂𝒓
We know that, for an ideal gas
𝑃1 𝑉1 = 𝑅𝑇1
𝑅𝑇1
𝑉1 =
𝑃1
8.314 𝐽 ∗ 600 𝐾 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 𝑁𝑚
𝑉1 = ∗ ∗
𝑚𝑜𝑙 ∗ 𝐾 ∗ 10 𝑏𝑎𝑟 101325 𝑁 𝐽
−𝟑
𝒎𝟑
𝑽𝟏 = 𝟒. 𝟗𝟖𝟖 ∗ 𝟏𝟎
𝒎𝒐𝒍
(c)
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2013
∆𝑼𝟏𝟐 = 𝟎
∆𝑯𝟏𝟐 = 𝟎
For an isothermal process, we have
𝑃2
𝑄 = −𝑅𝑇1 ln
𝑃1
𝐽 3
𝑄 = −8.314 ∗ 600 𝐾 ∗ ln
𝑚𝑜𝑙 ∗ 𝐾 10
𝐽
𝑄 = 6006
𝑚𝑜𝑙
𝑱
𝑸 = 𝟔. 𝟎𝟎𝟔 ∗ 𝟏𝟎𝟑 Answer
𝒎𝒐𝒍
𝑾𝟐𝟑 = 𝟎
At constant volume we have
𝑄23 = ∆𝑈23 = 𝐶𝑉 ∆𝑇
𝑄23 = ∆𝑈23 = 𝐶𝑉 (𝑇3 − 𝑇2 )
5
𝑄23 = ∆𝑈23 = 𝑅(400 − 600)𝐾
2
5 8.314 𝐽
𝑄23 = ∆𝑈23 = ∗ ∗ (−200)𝐾
2 𝑚𝑜𝑙 ∗ 𝐾
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PROBLEMS ZAID YAHYA 11-CH-74
2013
𝐽
𝑄23 = ∆𝑈23 = −4157
𝑚𝑜𝑙
𝑱
𝑸𝟐𝟑 = ∆𝑼𝟐𝟑 = −𝟒. 𝟏𝟓𝟕 ∗ 𝟏𝟎𝟑 Answer
𝒎𝒐𝒍
We know that
∆𝐻23 = 𝐶𝑃 ∆𝑇
∆𝐻23 = 𝐶𝑃 (𝑇3 − 𝑇2 )
7
∆𝐻23 = 𝑅 (400 − 600)𝐾
2
7 𝐽
∆𝐻23 = ∗ 8.314 ∗ (−200)𝐾
2 𝑚𝑜𝑙 ∗ 𝐾
𝐽
∆𝐻23 = −5820
𝑚𝑜𝑙
𝑱
∆𝑯𝟐𝟑 = −𝟓. 𝟖𝟐 ∗ 𝟏𝟎𝟑 Answer
𝒎𝒐𝒍
Step 34, an Isobaric process,
Since
For an isobaric process, pressure is constant
Therefore, at constant pressure we have,
𝑄34 = ∆𝐻34 = 𝐶𝑃 ∆𝑇
7
𝑄34 = ∆𝐻34 = 𝑅(𝑇4 − 𝑇3 )
2
7 𝐽
𝑄34 = ∆𝐻34 = ∗ 8.314 ∗ (378.83 − 400) 𝐾
2 𝑚𝑜𝑙 ∗ 𝐾
𝑱
𝑸𝟑𝟒 = ∆𝑯𝟑𝟒 = −𝟔𝟏𝟔 Answer
𝒎𝒐𝒍
𝑊34 = −𝑅∆𝑇
𝑊34 = −𝑅(𝑇4 − 𝑇3 )
𝐽
𝑊34 = −8.314 ∗ (378.83 − 400)𝐾
𝑚𝑜𝑙 ∗ 𝐾
𝑱
𝑾𝟑𝟒 = 𝟏𝟕𝟔 Answer
𝒎𝒐𝒍
We know that,
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2013
∆𝑈34 = 𝐶𝑉 ∆𝑇
5
∆𝑈34 = 𝑅(𝑇4 − 𝑇3 )
2
5 𝐽
∆𝑈34 = ∗ 8.314 ∗ (378.83 − 400)𝐾
2 𝑚𝑜𝑙 ∗ 𝐾
𝑱
∆𝑼𝟑𝟒 = −𝟒𝟒𝟎 Answer
𝒎𝒐𝒍
∆𝑈41 = 𝐶𝑉 ∆𝑇
5
∆𝑈41 = 𝑅(𝑇1 − 𝑇4 )
2
5 𝐽
∆𝑈41 = ∗ 8.314 ∗ (600 − 378.83) 𝐾
2 𝑚𝑜𝑙 ∗ 𝐾
𝐽
∆𝑈41 = 4597
𝑚𝑜𝑙
𝑱
∆𝑼𝟒𝟏 = 𝟒. 𝟓𝟗𝟕 ∗ 𝟏𝟎𝟑 Answer
𝒎𝒐𝒍
We know that
∆𝐻41 = 𝐶𝑃 ∆𝑇
7
∆𝐻41 = 𝑅(𝑇1 − 𝑇4 )
2
7 𝐽
∆𝐻41 = ∗ 8.314 ∗ (600 − 378.83) 𝐾
2 𝑚𝑜𝑙 ∗ 𝐾
𝐽
∆𝐻41 = 6435.8
𝑚𝑜𝑙
𝟑 𝑱
∆𝑯𝟒𝟏 = 𝟔. 𝟒𝟑𝟓𝟖 ∗ 𝟏𝟎 Answer
𝒎𝒐𝒍
𝑱
𝑾𝟒𝟏 = 𝟒. 𝟓𝟗𝟕 ∗ 𝟏𝟎𝟑 Answer
𝒎𝒐𝒍
Problem 3.10:
An ideal gas, CP= (5/2) R and CV= (3/2) R is changed from P1 = 1bar and 𝑽𝒕𝟏 = 12m3 to
P2 = 12 bar and 𝑽𝒕𝟐 = 1 m3 by the following mechanically reversible processes:
a) Isothermal compression
b) Adiabatic compression followed by cooling at constant pressure.
c) Adiabatic compression followed by cooling at constant volume.
d) Heating at constant volume followed by cooling at constant pressure.
e) Cooling at constant pressure followed by heating at constant volume.
Calculate Q, W, change in U, and change in H for each of these processes, and sketch
the paths of all processes on a single PV diagram.
Given Data:
5
𝐶𝑃 = 𝑅
2
3
𝐶𝑉 = 𝑅
2
𝐼𝑛𝑖𝑡𝑖𝑎𝑙 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃1 = 1 𝑏𝑎𝑟
𝑉1𝑡 = 12 𝑚3
𝐹𝑖𝑛𝑎𝑙 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃2 = 12 𝑏𝑎𝑟
𝑉2𝑡 = 1 𝑚3
𝑄 =?
𝑊 =?
∆𝐻 =?
∆𝑈 =?
Solution:
Since
𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
Therefore, for all parts of the problem,
∆𝑯 = 𝟎
∆𝑼 = 𝟎
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(a)
Isothermal compression,
For an isothermal process, we have
𝑃2
𝑄 = −𝑅𝑇1 ln
𝑃1
Since
For an ideal gas, we have
𝑃1 V1 = 𝑅𝑇1
Therefore,
𝑃2
𝑄 = −𝑃1 V1 ln
𝑃1
12 101325 N J 1𝐤𝐉
𝑄 = −1 𝑏𝑎𝑟 ∗ 12 𝑚3 ∗ ln ∗ ∗ ∗
1 1.01325 bar ∗ m2 Nm 1000 J
𝑸 = −𝟐𝟗𝟖𝟏. 𝟖𝟖 𝒌𝑱 Answer
According to first law of thermodynamics
∆𝑈 = 𝑄 + 𝑊
0=𝑄+𝑊
𝑊 = −𝑄
𝑾𝟏𝟐 = 𝟐𝟗𝟖𝟏. 𝟖𝟖 𝒌𝑱 Answer
(b)
𝑸=𝟎 Answer
𝑃2 (𝑉 ′ )𝛾 = 𝑃1 𝑉1
1
𝑃1 𝛾
𝑉 ′ = 𝑉1 ( )
𝑃2
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2013
𝛾 = 1.67
1
1 1.67
𝑉 ′ = 12𝑚3 ∗ ( )
12
′ 𝟑
𝑽 = 𝟐. 𝟕𝟏 𝒎
We know that,
𝑃2 𝑉 ′ − 𝑃1 𝑉1
𝑊1 =
𝛾−1
(12∗2.71−1∗12)𝑏𝑎𝑟∗𝑚3 101325 N J 1𝐤𝐉
𝑊1 = ∗ ∗ ∗
1.67−1 1.01325 bar∗m2 Nm 1000 J
𝑾𝟏 = 𝟑𝟎𝟔𝟑 𝒌𝑱 → (𝟏)
Second step, cooling at constant pressure P2
We know that, for a mechanically reversible process
𝑊2 = −𝑃2 (𝑉2 − 𝑉 ′ )
101325 𝑁 𝐽 1𝒌𝑱
𝑊2 = −12 𝑏𝑎𝑟 (1 − 2.71)𝑚3 ∗ ∗ ∗
1.01325 𝑏𝑎𝑟 ∗ 𝑚2 𝑁𝑚 1000 𝐽
𝑾𝟐 = 𝟐𝟎𝟓𝟐 𝒌𝑱 → (𝟐)
Now
𝑊 = 𝑊1 + 𝑊2
𝑊 = (3063 + 2052)𝑘𝐽
𝑾 = 𝟓𝟏𝟏𝟓 𝒌𝑱 Answer
(c)
𝑸=𝟎 Answer
′
𝑉1 𝛾
𝑃 = 𝑃1 ( )
𝑉2
For mono atomic gas, we have
𝛾 = 1.67
′
12 1.67
𝑃 = 1 𝑏𝑎𝑟 ( )
1
′
𝑷 = 𝟔𝟑. 𝟒𝟐 𝒃𝒂𝒓
We know that,
𝑃′ 𝑉2 −𝑃1 𝑉1
𝑊1 =
𝛾−1
(63.42 ∗ 1 − 1 ∗ 12)𝑏𝑎𝑟 ∗ 𝑚3 101325 𝑁 𝐽 1𝒌𝑱
𝑊1 = ∗ ∗ ∗
1.67 − 1 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 𝑁𝑚 1000 𝐽
𝑾𝟏 = 𝟕𝟔𝟕𝟒. 𝟕𝟔 𝒌𝑱
Second step, cooling at constant Volume,
Therefore, No work will be done
𝑾𝟐 = 𝟎
Now
𝑊 = 𝑊1 + 𝑊2
𝑊 = (7674.76 + 0)𝑘𝐽
𝑾 = 𝟕𝟔𝟕𝟒. 𝟕𝟔 𝒌𝑱 Answer
(d)
𝑊2 = −𝑃2 ∆𝑉
𝑊2 = −𝑃2 (𝑉2 − 𝑉1 )
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101325 𝑁 𝐽 1𝒌𝑱
𝑊2 = −12 𝑏𝑎𝑟(1 − 12)𝑚3 ∗ ∗ ∗
1.01325 𝑏𝑎𝑟 ∗ 𝑚2 𝑁𝑚 1000 𝐽
𝑾𝟐 = 𝟏𝟑𝟐𝟎𝟎 𝒌𝑱
Now
𝑊 = 𝑊1 + 𝑊2
𝑊 = (0 + 13200)𝑘𝐽
𝑾 = 𝟏𝟑𝟐𝟎𝟎 𝒌𝑱 Answer
According to first law of thermodynamics
∆𝑈 = 𝑄 + 𝑊
0=𝑄+𝑊
𝑄 = −𝑊
𝑸 = −𝟏𝟑𝟐𝟎𝟎 𝒌𝑱 Answer
(e)
𝑊1 = −𝑃1 ∆𝑉
𝑊1 = −𝑃1 (𝑉2 − 𝑉1 )
101325 𝑁 𝐽 1𝒌𝑱
𝑊1 = −1 𝑏𝑎𝑟(1 − 12)𝑚3 ∗ ∗ ∗
1.01325 𝑏𝑎𝑟 ∗ 𝑚2 𝑁𝑚 1000 𝐽
𝑾𝟏 = 𝟏𝟏𝟎𝟎 𝒌𝑱
Step 1, Heating at constant Volume V2 to pressure P2
Therefore no work will be done
𝑾𝟐 = 𝟎
Now
𝑊 = 𝑊1 + 𝑊2
𝑊 = (1100 + 0)𝑘𝐽
𝑾 = 𝟏𝟏𝟎𝟎 𝒌𝑱 Answer
According to first law of thermodynamics
∆𝑈 = 𝑄 + 𝑊
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2013
0=𝑄+𝑊
𝑄 = −𝑊
𝑸 = −𝟏𝟏𝟎𝟎 𝒌𝑱 Answer
Problem 3.11:
𝒅𝑻
The environmental lapse rate characterizes the local variation of temperature with
𝒅𝒛
elevation in the earth's atmosphere. Atmospheric pressure varies with elevation
according to the hydrostatic formula,
𝒅𝑷
= −𝓜𝝆𝒈
𝒅𝒛
Where M is a molar mass, ρ is molar density and g is the local acceleration of gravity.
Assume that the atmosphere is an ideal gas, with T related to P by the polytropic formula
equation (3.35 c). Develop an expression for the environmental lapse rate in relation to
M, g, R, and δ.
Solution:
Given that
𝑑𝑃
= −ℳ𝜌𝑔 → (1)
𝑑𝑧
The polytropic relation is
1−𝛿
𝑇𝑃 𝛿 = 𝐶𝑜𝑛𝑠𝑡𝑎𝑛𝑡
Or
1−𝛿 1−𝛿
𝑇𝑃 𝛿 = 𝑇𝑜 𝑃𝑜 𝛿
Where
To =Temperature at sea level, so it is constant
Po = Pressure at sea level, so it is constant
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2013
𝑇 𝑇𝑜
𝛿−1
= δ−1
𝑃 𝛿
Po δ
𝛿−1
𝑇 𝑃 𝛿
=( )
𝑇𝑜 𝑃𝑜
𝛿
𝑇 𝛿−1 𝑃
( ) =
𝑇𝑜 𝑃𝑜
𝛿
𝑇 𝛿−1
𝑃 = 𝑃𝑜 ( ) → (𝑎)
𝑇𝑜
𝑃𝑜 𝛿
𝑃= 𝛿
∗ 𝑇 𝛿−1
𝑇𝑜 𝛿−1
𝑑𝑃 𝑃𝑜 𝛿 1
= 𝛿
∗ ∗𝑇 𝛿−1
𝑑𝑇 𝛿−1
𝑇𝑜 𝛿−1
𝑃𝑜 𝛿 1
𝑑𝑃 = 𝛿
∗ ∗ 𝑇 𝛿−1 𝑑𝑇 → (2)
𝛿−1
𝑇𝑜 𝛿−1
We know that, for an ideal gas
𝑃
𝜌=
𝑅𝑇
Where
R = Specific gas constant = R′ /ℳ
Put (a) in above equation
𝛿
1 𝑇 𝛿−1
𝜌= ∗ 𝑃𝑜 ( )
𝑅𝑇 𝑇𝑜
Put in (1)
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2013
𝛿
𝑑𝑃 1 𝑇 𝛿−1
= −ℳ𝑔 ∗ 𝑃𝑜 ( )
𝑑𝑧 𝑅𝑇 𝑇𝑜
𝛿
1 𝑇 𝛿−1
𝑑𝑃 = −ℳ𝑔 ∗ 𝑃𝑜 ( ) ∗ 𝑑𝑧
𝑅𝑇 𝑇𝑜
Put (2) in above
𝛿
1
𝑃𝑜 𝛿 1 𝑇 𝛿−1
𝛿 ∗ ∗𝑇 𝛿−1 𝑑𝑇 = −ℳ𝑔 ∗ 𝑃𝑜 ( ) ∗ 𝑑𝑧
𝛿−1 𝑅𝑇 𝑇𝑜
𝑇𝑜 𝛿−1
𝛿 𝛿
𝑑𝑇 𝛿 − 1 ℳ𝑔 𝑃𝑜 𝑇𝑜 𝛿−1 𝑇 𝛿−1
=− ∗ ∗ ∗ 𝛿
∗ 1
𝑑𝑧 𝛿 𝑅 𝑃𝑜
𝑇𝑜 𝛿−1 𝑇 ∗ 𝑇 𝛿−1
𝛿 𝛿
𝑑𝑇 𝛿 − 1 ℳ𝑔 𝑃𝑜 𝑇𝑜 𝛿−1 𝑇 𝛿−1
=− ∗ ∗ ∗ 𝛿
∗ 𝛿
𝑑𝑧 𝛿 𝑅 𝑃𝑜
𝑇𝑜 𝛿−1 𝑇 𝛿−1
𝒅𝑻 𝜹 𝓜𝒈
=− ∗ Proved
𝒅𝒛 𝜹−𝟏 𝑹
Problem 3.12:
An evacuated tank is filled with gas from a constant pressure line. Develop an expression
relating the temperature of the gas in the tank to temperature T’ of the gas in line.
Assume that gas is ideal with constant heat capacities, and ignore heat transfer between
the gas and the tank. Mass and energy balances for this problem are treated in Ex. 2.13.
Solution:
Choose the tank as the control volume. There is no work, no heat transfer & kinetic & potential
energy changes are assumed negligible.
Therefore, applying energy balance
𝑑(𝑚𝑈)𝑡𝑎𝑛𝑘
+ ∆(𝐻𝑚) = 0
𝑑𝑡
𝑑(𝑚𝑈)𝑡𝑎𝑛𝑘
+ 𝐻′′ 𝑚′′ − 𝐻′ 𝑚′ = 0
𝑑𝑡
Since
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Tank is filled with gas from an entrance line, but no gas is being escaped out,
Therefore,
𝑑(𝑚𝑈)𝑡𝑎𝑛𝑘
+ 0 − 𝐻 ′ 𝑚′ = 0
𝑑𝑡
𝑑(𝑚𝑈)𝑡𝑎𝑛𝑘
− 𝐻′ 𝑚′ = 0 → (1)
𝑑𝑡
Where prime (‘) denotes the entrance stream
Applying mass balance
𝑑𝑚𝑡𝑎𝑛𝑘
𝑚′ = → (2)
𝑑𝑡
Combining equation (1) & (2)
𝑑(𝑚𝑈)𝑡𝑎𝑛𝑘 𝑑𝑚𝑡𝑎𝑛𝑘
− 𝐻′ =0
𝑑𝑡 𝑑𝑡
1
{𝑑(𝑚𝑈)𝑡𝑎𝑛𝑘 − 𝐻′ 𝑑𝑚𝑡𝑎𝑛𝑘 } = 0
𝑑𝑡
𝑑(𝑚𝑈)𝑡𝑎𝑛𝑘 = 𝐻′ 𝑑𝑚𝑡𝑎𝑛𝑘
Integrating on both sides
𝑚2 𝑚2
′
∫ 𝑑(𝑚𝑈)𝑡𝑎𝑛𝑘 = 𝐻 ∫ 𝑑𝑚𝑡𝑎𝑛𝑘
𝑚1 𝑚1
∆(𝑚𝑈)𝑡𝑎𝑛𝑘 = 𝐻′ (𝑚2 − 𝑚1 )
𝑚2 𝑈2 − 𝑚1 𝑈1 = 𝐻′ (𝑚2 − 𝑚1 )
Because mass in the tank initially is zero, therefore
𝑚1 = 0
𝑚2 𝑈2 = 𝐻′ 𝑚2
𝑈2 = 𝐻′ → (3)
We know that
𝑈 = 𝐶𝑉 𝑇
𝑈2 = 𝐶𝑉 𝑇2 → (𝑎)
Also
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𝐻′ = 𝐶𝑃 𝑇 ′ → (𝑏)
Put (a) & (b) in (3)
𝐶𝑉 𝑇 = 𝐶𝑃 𝑇 ′
𝐶𝑃 ′
𝑇= 𝑇
𝐶𝑉
Since heat capacities are constant, therefore
𝐶𝑃
𝛾=
𝐶𝑉
𝑻 = 𝜸𝑻′ Proved
Problem 3.14:
A tank of 0.1-m3 volume contains air at 25 oC and 101.33 kPa. The tank is connected to
a compressed-air line which supplies air at the constant conditions of 45oC and 1,500
kPa. A valve in the line is cracked so that air flows slowly into the tank until the pressure
equals the line pressure. If the process occurs slowly enough that the temperature in the
tank remains at 25 oC, how much heat is lost from the tank? Assume air to be an ideal
gas for which CP = (7/2) R and CV = (5/2) R
Given Data:
𝑉𝑜𝑙𝑢𝑚𝑒 = 𝑉 = 0.1 𝑚3
𝑇1 = 25 𝑜.𝐶 = 298 K
𝑃1 = 101.33 𝑘𝑃𝑎
𝑇2 = 45 𝑜.𝐶 = 318 𝐾
𝑃2 = 1500 𝑘𝑃𝑎
𝐻𝑒𝑎𝑡 𝑙𝑜𝑠𝑡 = 𝑄 =?
7
𝐶𝑃 = 𝑅
2
5
𝐶𝑉 = 𝑅
2
Solution:
According to first law of thermodynamics
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∆𝑈 = 𝑄 + 𝑊 → (1)
Since
∆𝐻 = ∆𝑈 + ∆(𝑃𝑉)
∆𝑈 = ∆𝐻 − ∆(𝑃𝑉)
∆𝑈 = ∆𝐻 − 𝑃∆𝑉 − 𝑉∆𝑃 → (𝑎)
Also, we know that
𝑊 = −𝑃∆𝑉 → (𝑏)
Put (a) & (b) in (1)
∆𝐻 = 𝑛𝐶𝑃 ∆𝑇
∆𝐻 = 𝑛𝐶𝑃 (𝑇2 − 𝑇1 )
Put in (2)
𝑃𝑉 = 𝑛𝑅𝑇
Initial number of moles of gas can be obtained as,
𝑃1 𝑉 = 𝑛1 𝑅𝑇1
𝑃1 𝑉
𝑛1 =
𝑅𝑇1
The final number of moles of gas at temperature T1 are
𝑃2 𝑉 = 𝑛2 𝑅𝑇1
𝑃2 𝑉
𝑛2 =
𝑅𝑇1
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(𝑃1 − 𝑃2 )𝑉
𝐶𝑃 (𝑇2 − 𝑇1 ) − 𝑉∆𝑃 = 𝑄
𝑅𝑇1
(𝑃1 − 𝑃2 )𝑉 7
∗ 𝑅 ∗ (𝑇2 − 𝑇1 ) − 𝑉∆𝑃 = 𝑄
𝑅𝑇1 2
(𝑃1 − 𝑃2 )𝑉 7
∗ ∗ (𝑇2 − 𝑇1 ) − 𝑉(𝑃2 − 𝑃1 ) = 𝑄
𝑇1 2
Problem 3.17:
A rigid, no conducting tank with a volume of 4 m3 is divided into two unequal parts by a
thin membrane. One side of the membrane, representing 1/3 of the tank, contains
nitrogen gas at 6 bars and 100 oC, and the other side, representing 2/3 of the tank, is
evacuated. The membrane ruptures and the gas fills the tank.
a) What is the final, temperature of the gas? How much work is done? Is the
process reversible?
b) Describe a reversible process by which the gas can be returned to its initial state,
How much work is done
Given Data:
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𝐹𝑖𝑛𝑎𝑙 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇2 =?
According to first law of thermodynamics
∆𝑈 = 𝑄 + 𝑊
Since
No work is done & no heat is transferred
Therefore
𝑄=𝑊=0
∆𝑈 = 0
𝑚𝐶𝑉 ∆𝑇 = 0
∆𝑇 = 0
𝑇2 − 𝑇1 = 0
𝑇2 = 𝑇1
𝑻𝟐 = 𝟏𝟎𝟎 ℃ Answer
No, process is not reversible
(b)
Since
𝑉2
𝑊 = −𝑅𝑇2 ln
𝑉1
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𝑃2 𝑉2 = 𝑅𝑇2
𝑉2
𝑊 = −𝑃2 𝑉2 ln
𝑉1
4 4
𝑊 = −6 𝑏𝑎𝑟 ∗ 𝑚3 ln
3 3∗4
101325𝑁 𝑘𝐽
𝑊 = 8.788 𝑏𝑎𝑟 ∗ 𝑚3 ∗ ∗ 1
1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1000𝑁𝑚
𝑾 = 𝟖𝟕𝟖. 𝟖 𝒌𝑱 Answer
Problem 3.18:
An ideal gas initially at 30 0C and 100 kPa undergoes the following cyclic processes in a
closed system:
a) In mechanically reversible processes, it is first compressed adiabatically to 500
kPa then cooled at a constant pressure of 500 kPa to 30 0C and finally expanded
isothermally to its original state
b) The cycle traverses exactly the same changes of state but each step is irreversible
with an efficiency of 80% compared with the corresponding mechanically
reversible process NOTE: the initial step can no longer be adiabatic
Find Q W ∆U and ∆H for each step of the process and for the cycle Take Cp = (7/2) R
and CV = (5/2) R
Given Data:
𝑇1 = 30 0.𝐶
𝑇1 = 303.15 K
𝑃1 = 100 𝑘𝑃𝑎
𝑄 =?
𝑊 =?
∆𝑈 =?
∆𝐻 =?
7
𝐶𝑃 = R
2
5
CV = R
2
Solution:
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(a)
𝑃2 = 500 𝑘𝑃𝑎
1) Adiabatic Compression from point 1 to point 2
𝑄12 = 0
Now, from first law of thermodynamics,
𝛾−1
𝑇2 𝑃2 𝛾
=( )
𝑇1 𝑃1
𝛾−1
𝑃2 𝛾
𝑇2 = 𝑇1 ( )
𝑃1
1.4−1
500 1.4
𝑇2 = 303.15 𝐾 ( )
100
𝑻𝟐 = 𝟒𝟖𝟎. 𝟏𝟑 𝑲
Put in (1)
5 𝐽 𝑘𝐽
𝑊12 = ∆𝑈12 = ∗ 8.314 (480.13 − 303.15)𝐾 ∗ 1
2 𝑚𝑜𝑙∗𝐾 1000𝐽
𝒌𝑱
𝑾𝟏𝟐 = ∆𝑼𝟏𝟐 = 𝟑. 𝟔𝟕𝟗
𝒎𝒐𝒍
Also, we have
∆𝐻12 = 𝐶𝑃 (𝑇2 − 𝑇1 )
7 𝐽 𝑘𝐽
∆𝐻12 = ∗ 8.314 (480.13 − 303.15)𝐾 ∗ 1
2 𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽
𝒌𝑱
∆𝑯𝟏𝟐 = 𝟓. 𝟏𝟓
𝒎𝒐𝒍
2) Cooling at constant pressure from point 2 to point 3
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𝑇3 = 303.15 K
7 𝐽 𝑘𝐽
𝑄23 = ∆𝐻23 = ∗ 8.314 (303.15 − 480.13)𝐾 ∗ 1
2 𝑚𝑜𝑙∗𝐾 1000 𝐽
𝒌𝑱
𝑸𝟐𝟑 = ∆𝑯𝟐𝟑 = −𝟓. 𝟏𝟓
𝒎𝒐𝒍
Also, we have
∆𝑈23 = 𝐶𝑉 (𝑇3 − 𝑇2 )
5 𝐽 𝑘𝐽
∆𝑈23 = ∗ 8.314 (303.15 − 480.13)𝐾 ∗ 1
2 𝑚𝑜𝑙∗𝐾 1000 𝐽
𝒌𝑱
∆𝑼𝟐𝟑 = −𝟑. 𝟔𝟕𝟗
𝒎𝒐𝒍
Now, from first law of thermodynamics,
∆𝑈31 = ∆𝐻31 = 0
Here
𝑃3 = 𝑃2 = 500 𝑘𝑃𝑎
For an Isothermal process we have
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𝑃3
𝑊31 = −𝑅𝑇3 𝑙𝑛
𝑃1
𝐽 500 1 𝑘𝐽
𝑊31 = −8.314 ∗ 303.15 𝐾 ∗ ln ∗
𝑚𝑜𝑙∗𝐾 100 1000 𝐽
𝒌𝑱
𝑾𝟑𝟏 = −𝟒. 𝟎𝟓𝟔
𝒎𝒐𝒍
According to first law of thermodynamics
0 = 𝑄31 + 𝑊31
𝑄31 = −𝑊31
𝒌𝑱
𝑸𝟑𝟏 = 𝟒. 𝟎𝟓𝟔
𝒎𝒐𝒍
(b)
If each step that is 80% accomplishes the same change of state then values of ∆𝑈 & ∆𝐻 will remain
same as in part (a) but values of Q & W will change.
1. Adiabatic Compression from point 1 to point 2
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𝑊12
𝑊12 =
0.8
3.679
𝑊12 =
0.8
𝒌𝑱
𝑾𝟏𝟐 = 𝟒. 𝟓𝟗𝟖
𝒎𝒐𝒍
𝑊23
𝑊23 =
0.8
1.471
𝑊23 =
0.8
𝒌𝑱
𝑾𝟐𝟑 = 𝟏. 𝟖𝟑𝟗
𝒎𝒐𝒍
According to first law of thermodynamics
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𝑘𝐽
𝑊31 = −4.056 ∗ 0.8
𝑚𝑜𝑙
𝒌𝑱
𝑾𝟑𝟏 = 𝟑. 𝟐𝟒𝟓
𝒎𝒐𝒍
According to first law of thermodynamics
Problem 3.19:
One cubic meter of an ideal gas at 600 K and 1,000 kPa expands to five times its initial
volume as follows:
a) By a mechanically reversible, isothermal process
b) By a mechanically reversible adiabatic process
c) By adiabatic irreversible process in which expansion is against a restraining
pressure of 100 kPa
For each case calculate the final temperature, pressure and the work done by the gas,
Cp=21 J mol-1K-1.
Given Data:
𝑉1 = 1 𝑚3
𝑇1 = 600 𝐾
𝑃1 = 1000 𝑘𝑃𝑎
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𝑉2 = 5𝑉1
𝑉2 = 5 𝑚3
𝐽
𝐶𝑃 = 21
𝑚𝑜𝑙 𝐾
𝐶𝑉 =?
𝑇2 =?
𝑃2 =?
𝑊 =?
Solution:
We know that,
𝐶𝑃 − 𝐶𝑉 = 𝑅
𝐶𝑉 = 𝐶𝑃 − 𝑅
𝐽
𝐶𝑉 = (21 − 8.314)
𝑚𝑜𝑙 ∗ 𝐾
𝐽
𝐶𝑉 = 12.686
𝑚𝑜𝑙 ∗ 𝐾
As
𝐶𝑃
𝛾=
𝐶𝑉
𝜸 = 𝟏. 𝟔𝟓𝟓𝟒
(a)
𝑻𝟐 = 𝑻𝟏 = 𝟔𝟎𝟎 𝑲 Answer
𝑃1 𝑉1 𝑃2 𝑉2
=
𝑇1 𝑇2
𝑃1 𝑉1 𝑇2
𝑃2 = ∗
𝑇1 𝑉2
1000 𝑘𝑃𝑎 ∗ 1 𝑚3 600 𝐾
𝑃2 = ∗
600 𝐾 5 𝑚3
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𝑉2
𝑊 = −𝑅𝑇1 ln
𝑉1
Since
𝑃1 𝑉1 = 𝑅𝑇1
Therefore,
𝑉2
𝑊 = −𝑃1 𝑉1 ln
𝑉1
5 𝑁 𝐽
𝑊 = −1000 𝑘𝑃𝑎 ∗ 1 𝑚3 ln ∗ ∗
1 𝑃𝑎 ∗ 𝑚2 𝑁𝑚
𝑾 = −𝟏𝟔𝟎𝟗. 𝟒𝟑 𝒌𝑱 Answer
(b)
𝑃1 𝑉1 𝛾 = 𝑃2 𝑉2 𝛾
𝑉1 𝛾
𝑃2 = 𝑃1 ( )
𝑉2
1 1.6554
𝑃2 = 1000 𝑘𝑃𝑎 ∗ ( )
5
𝑷𝟐 = 𝟔𝟗. 𝟔𝟓 𝒌𝑷𝒂 Answer
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𝑃2 𝑉2 −𝑃1 𝑉1
𝑊=
𝛾−1
(69.65 ∗ 5 − 1000 ∗ 1 ) 𝑘𝑃𝑎 ∗ 𝑚3 𝑁 𝐽
𝑊= ∗
1.6554 − 1 𝑃𝑎 ∗ 𝑚2 𝑁𝑚
𝑾 = −𝟗𝟗𝟒. 𝟒𝟑 𝒌𝑱 Answer
(c)
𝑃𝑟 = 100 𝑘𝑃𝑎
Since, for an adiabatic process
𝑄=0
According to first law of thermodynamics
∆𝑈 = 𝑄 + 𝑊
∆𝑈 = 𝑊
∆𝑈 = 𝑊 = −𝑃𝑟 𝑑𝑉
∆𝑈 = 𝑊 = −𝑃𝑟 (𝑉2 − 𝑉1 )
𝑁 𝐽
∆𝑈 = 𝑊 = −100(5 − 1)𝑘𝑃𝑎 ∗ 𝑚3 ∗ ∗
𝑃𝑎 ∗ 𝑚2 𝑁𝑚
∆𝑼 = −𝟒𝟎𝟎 𝒌𝑱
𝑛𝐶𝑉 ∆𝑇 = −400 𝑘𝐽
𝑛𝐶𝑉 (𝑇2 − 𝑇1 ) = −400 𝑘𝐽
−400 𝑘𝐽
𝑇2 = + 𝑇1 → (1)
𝑛𝐶𝑉
For an ideal gas we have,
𝑃1 𝑉1 = 𝑛𝑅𝑇1
𝑃1 𝑉1
𝑛=
𝑅𝑇1
1000 𝑘𝑃𝑎 ∗ 1𝑚3 ∗ 𝑚𝑜𝑙 ∗ 𝐾 𝑘𝑁 𝑘𝐽
𝑛= ∗ ∗
8.314 𝐽 ∗ 600 𝐾 𝑘𝑃𝑎 ∗ 𝑚2 𝑘𝑁𝑚
𝒏 = 𝟎. 𝟐𝟎𝟎𝟓 𝒎𝒐𝒍
Put in (1)
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𝑃1 𝑉1 𝑃2 𝑉2
=
𝑇1 𝑇2
𝑃1 𝑉1 𝑇2
𝑃2 = ∗
𝑇1 𝑉2
1000 𝑘𝑃𝑎 ∗ 1 𝑚3 442.74 𝐾
𝑃2 = ∗
600 𝐾 5 𝑚3
𝑷𝟐 = 𝟏𝟒𝟕. 𝟓𝟖 𝒌𝑷𝒂 Answe𝑟
Problem 3.20:
One mole of air, initially at 150 0C and 8 bars undergoes the following mechanically
reversible changes. It expands isothermally to a pressure such that when it is cooled at
constant volume to 50 0C its final pressure is 3 bars. Assuming air is an ideal gas for
which CP = (7/2) R and CV = (5/2) R, calculate W, Q,∆𝑼, and ∆𝑯
Given Data:
Solution:
Since process is reversible
Two different steps are used in this case to reach final state of the air.
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Step 12:
For step 12 temperatures is constant,
𝑇1 = 𝑇2
Therefore
∆𝑼𝟏𝟐 = ∆𝑯𝟏𝟐 = 𝟎
For an isothermal process we have
𝑉1
𝑊12 = 𝑅𝑇1 ln
𝑉2
As
𝑉2 = 𝑉3
𝑉1
𝑊12 = 𝑅𝑇1 ln → (1)
𝑉3
We know that
𝑃1 𝑉1 𝑃3 𝑉3
=
𝑇1 𝑇3
𝑉1 𝑃3 ∗ 𝑇1
=
𝑉3 𝑇3 ∗ 𝑃1
𝑃1 ∗ 𝑇3
𝑊12 = 𝑅𝑇1 ln
𝑇1 ∗ 𝑃3
8.314 𝐽 ∗ 423.15 𝐾 1 𝑘𝐽 3 ∗ 423.15
𝑊12 = ∗ ∗ 𝑙𝑛
𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽 8 ∗ 323.15
𝒌𝑱
𝑾𝟏𝟐 = −𝟐. 𝟓𝟎𝟐
𝒎𝒐𝒍
Step 23:
For step 23 volume is constant,
Therefore,
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𝑊23 = 0
According to first law of thermodynamics
W e know that
∆𝐻23 = 𝐶𝑃 ∆𝑇
∆𝐻23 = 𝐶𝑃 (𝑇3 − 𝑇2 )
7 𝐽 1 𝑘𝐽
∆𝐻23 = ∗ 8.314 ∗ (423.15 − 323.15) 𝐾
2 𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽
𝒌𝑱
∆𝑯𝟐𝟑 = 𝟐. 𝟗𝟏
𝒎𝒐𝒍
For the complete cycle,
𝑄 = 𝑄12 + 𝑄23
𝑘𝐽
𝑄 = (2.502 − 2.0785)
𝑚𝑜𝑙
𝒌𝑱
𝑸 = 𝟎. 𝟒𝟐𝟒 Answe𝑟
𝒎𝒐𝒍
∆𝑈 = ∆𝑈12 + ∆𝑈23
𝑘𝐽
∆𝑈 = (0 − 2.0785)
𝑚𝑜𝑙
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𝒌𝑱
∆𝑼 = −𝟐. 𝟎𝟕𝟖𝟓 Answe𝑟
𝒎𝒐𝒍
∆𝐻 = ∆𝐻12 + ∆𝐻23
𝑘𝐽
∆𝐻 = (0 − 2.91)
𝑚𝑜𝑙
𝒌𝑱
∆𝑯 = −𝟐. 𝟗𝟏 Answe𝑟
𝒎𝒐𝒍
Problem 3.21:
An ideal gas flows through a horizontal tube at steady state. No heat is added and no
shaft work is done. The cross-sectional area of the tube changes with length, and this
causes the velocity to change. Derive an equation relating the temperature to the velocity
of the gas. If nitrogen at 150 0C flows past one section of the tube with a velocity of 2.5
m/s, what is the temperature at another section where its velocity is 50 m/s? Let CP =
(7/2) R
Given Data:
Solution:
Applying energy balance for steady state flow process
∆𝑢2
∆𝐻 + + 𝑔∆𝑧 = 𝑄 + 𝑊𝑆
2
Since
∆𝑧 = 𝑊𝑆 = 𝑄 = 0
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Therefore,
∆𝑢2
∆𝐻 + =0
2
∆𝑢2
𝐶𝑃 ∆𝑇 = −
2
𝑢2 2 − 𝑢1 2
𝐶𝑃 (𝑇2 − 𝑇1 ) = −
2
2 2
𝑢2 − 𝑢1
𝑇2 = − + 𝑇1
2𝐶𝑃
(502 − 2.52 ) ∗ 2 ∗ 𝑚2 ∗ 𝑚𝑜𝑙 ∗ 𝐾 28 𝑔 𝑁𝑖𝑡𝑟𝑜𝑔𝑒𝑛 𝐽 𝑁 ∗ 𝑠𝑒𝑐 2
𝑇2 = − ∗ ∗ ∗
2 ∗ 7 ∗ 8.314 𝐽 ∗ 𝑠𝑒𝑐 2 1 𝑚𝑜𝑙 𝑁𝑖𝑡𝑟𝑜𝑔𝑒𝑛 𝑁 ∗ 𝑚 𝑘𝑔 ∗ 𝑚
1 𝑘𝑔
∗ + 423.15 𝐾
1000 𝑔
𝑇2 = −1.199 𝐾 + 423.15 𝐾
𝑇2 = 421.95 𝐾
𝑇2 = (421.95 − 273.15) 0.𝐶
𝑻𝟐 = 𝟏𝟒𝟖. 𝟖 𝟎.𝑪 Answe𝑟
Problem 3.22:
One mole of an ideal gas, initially at 30 0C and 1 bar, is changed to 130 0C and 10 bars
by three different mechanically reversible processes:
a) The gas is first heated at constant volume until its temperature is 130 0C; then it
is compressed isothermally until its pressure is 10 bar
b) The gas is first heated at constant pressure until its temperature is 130 0C; then
it is compressed isothermally to 10 bar
c) The gas is first compressed isothermally to 10 bar; then it is heated at constant
pressure to 130 0C
Calculate Q, W, ∆𝑼 𝒂𝒏𝒅 ∆𝑯 in each case. Take CP = (7/2) R and CV = (5/2) R.
alternatively, take CP = (5/2) R and CV = (3/2) R
Given Data:
𝑇1 = 30 0.𝐶
𝑇1 = (30 + 273.15) 𝐾
𝑇1 = 303.15 𝐾
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𝑃1 = 1 𝑏𝑎𝑟
𝑇2 = 130 0.𝐶
𝑇3 = (130 + 273.15) 𝐾
𝑇3 = 403.15 𝐾
𝑃3 = 10 bar
𝑄 =?
𝑊 =?
∆𝑈 =?
∆𝐻 =?
Solution:
7
𝐶𝑃 = 𝑅
2
5
𝐶𝑉 = 𝑅
2
∆𝑈 = ∆𝑈12 = ∆𝑈23 = 𝐶𝑉 ∆𝑇
5
∆𝑈 = ∆𝑈12 = ∆𝑈23 = 𝑅 (𝑇3 − 𝑇1 )
2
5 𝐽 1 𝑘𝐽
∆𝑈 = ∆𝑈12 = ∆𝑈23 = ∗ 8.314 (403.15 − 303.15)𝐾 ∗
2 𝑚𝑜𝑙∗𝐾 1000 𝐽
𝒌𝑱
∆𝑼 = ∆𝑼𝟏𝟐 = ∆𝑼𝟐𝟑 = 𝟐. 𝟎𝟕𝟗 → (𝒂) Answe𝑟
𝒎𝒐𝒍
Now
∆𝐻 = ∆𝐻12 = ∆𝐻23 = 𝐶𝑃 ∆𝑇
7
∆𝐻 = ∆𝐻12 = ∆𝐻23 = 𝑅(𝑇2 − 𝑇1 )
2
7 𝐽 𝑘𝐽
∆𝐻 = ∆𝐻12 = ∆𝐻23 = ∗ 8.314 (403.15 − 303.15)𝐾 ∗ 1
2 𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽
𝒌𝑱
∆𝑯 = ∆𝑯𝟏𝟐 = ∆𝑯𝟐𝟑 = 𝟐. 𝟗𝟏 → (𝒃)Answe𝑟
𝒎𝒐𝒍
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(a)
Step 12:
For step “12” volume is constant
Therefore
𝑾𝟏𝟐 = 𝟎
Here
𝑇2 = 𝑇3
According to first law of thermodynamics
Also we have
𝒌𝑱
∆𝑯𝟏𝟐 = 𝟐. 𝟗𝟏 [𝑭𝒓𝒐𝒎 (𝒃)]
𝒎𝒐𝒍
Step 23:
Since for step “23” process is isothermal
Therefore
∆𝑼𝟐𝟑 = ∆𝑯𝟐𝟑 = 𝟎
Here
𝑇2 = 𝑇3
Now, intermediate pressure can be calculated as
𝑃1 𝑃2
=
𝑇1 𝑇2
𝑃1
𝑃2 = ∗𝑇
𝑇1 2
1 𝑏𝑎𝑟
𝑃2 = ∗ 403.15 𝐾
303.15 𝐾
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𝑃2 = 1.329 𝑏ar
𝑄 = 𝑄12 + 𝑄23
𝑘𝐽
𝑄 = (2.079 − 6.764)
𝑚𝑜𝑙
𝒌𝑱
𝑸 = −𝟒. 𝟔𝟖𝟓 Answe𝑟
𝒎𝒐𝒍
∆𝑈 = ∆𝑈12 + ∆𝑈23
𝑘𝐽
∆𝑈 = (2.079 + 0)
𝑚𝑜𝑙
𝒌𝑱
∆𝑼 = 𝟐. 𝟎𝟕𝟗 Answe𝑟
𝒎𝒐𝒍
∆𝐻 = ∆𝐻12 + ∆𝐻23
𝑘𝐽
∆𝐻 = (2.91 + 0)
𝑚𝑜𝑙
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𝒌𝑱
∆𝑯 = 𝟐. 𝟗𝟏 Answe𝑟
𝒎𝒐𝒍
(b)
Step 12:
For step “12” volume is constant
Therefore, at constant pressure we have
𝑘𝐽
𝑄12 = ∆𝐻12 = 2.91 [𝑭𝒓𝒐𝒎 (𝒃)]
𝑚𝑜𝑙
Also,
𝒌𝑱
∆𝑼𝟏𝟐 = 𝟐. 𝟎𝟕𝟗 [𝑭𝒓𝒐𝒎 (𝒂)]
𝒎𝒐𝒍
Step 23:
Since for step “23” process is isothermal ( T = Constant)
Therefore
∆𝑼𝟐𝟑 = ∆𝑯𝟐𝟑 = 𝟎
Here
𝑇2 = 𝑇3 & 𝑃1 = 𝑃2
For an isothermal process we have
𝑃3
𝑊23 = 𝑅𝑇2 ln
𝑃2
𝐽 1 𝑘𝐽 10
𝑊23 = 8.314 ∗ 403.15 𝐾 ∗ ∗ ln
𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽 1
𝒌𝑱
𝑾𝟐𝟑 = 𝟕. 𝟕𝟏𝟖
𝒎𝒐𝒍
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𝑄 = 𝑄12 + 𝑄23
𝑘𝐽
𝑄 = (2.91 − 7.718)
𝑚𝑜𝑙
𝒌𝑱
𝑸 = −𝟒. 𝟖𝟎𝟖 Answe𝑟
𝒎𝒐𝒍
∆𝑈 = ∆𝑈12 + ∆𝑈23
𝑘𝐽
∆𝑈 = (2.079 + 0)
𝑚𝑜𝑙
𝒌𝑱
∆𝑼 = 𝟐. 𝟎𝟕𝟗 Answe𝑟
𝒎𝒐𝒍
∆𝐻 = ∆𝐻12 + ∆𝐻23
𝑘𝐽
∆𝐻 = (2.91 + 0)
𝑚𝑜𝑙
𝒌𝑱
∆𝑯 = 𝟐. 𝟗𝟏 Answe𝑟
𝒎𝒐𝒍
(c)
𝑃2 = 𝑃3
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Step 23:
For step “23” volume is constant
Therefore, at constant pressure we have
𝒌𝑱
𝑸𝟐𝟑 = ∆𝑯𝟐𝟑 = 𝟐. 𝟗𝟏 [𝑭𝒓𝒐𝒎 (𝒃)]
𝒎𝒐𝒍
Here
𝑇2 = 𝑇3
Now
𝒌𝑱
∆𝑼𝟐𝟑 = 𝟐. 𝟎𝟕𝟗 [𝑭𝒓𝒐𝒎 (𝒂)]
𝒎𝒐𝒍
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𝑄 = 𝑄12 + 𝑄23
𝑘𝐽
𝑄 = (−5.8034 + 2.91)
𝑚𝑜𝑙
𝒌𝑱
𝑸 = −𝟐. 𝟖𝟗𝟒 Answe𝑟
𝒎𝒐𝒍
∆𝑈 = ∆𝑈12 + ∆𝑈23
𝑘𝐽
∆𝑈 = (0 + 2.079)
𝑚𝑜𝑙
𝒌𝑱
∆𝑼 = 𝟐. 𝟎𝟕𝟗 Answe𝑟
𝒎𝒐𝒍
∆𝐻 = ∆𝐻12 + ∆𝐻23
𝑘𝐽
∆𝐻 = (0 + 2.91)
𝑚𝑜𝑙
𝒌𝑱
∆𝑯 = 𝟐. 𝟗𝟏 Answe𝑟
𝒎𝒐𝒍
Solution:
5
𝐶𝑃 = 𝑅
2
3
𝐶𝑉 = 𝑅
2
∆𝑈 = ∆𝑈12 = ∆𝑈23 = 𝐶𝑉 ∆𝑇
3
∆𝑈 = ∆𝑈12 = ∆𝑈23 = 𝑅 (𝑇3 − 𝑇1 )
2
3 𝐽 1 𝑘𝐽
∆𝑈 = ∆𝑈12 = ∆𝑈23 = ∗ 8.314 (403.15 − 303.15)𝐾 ∗
2 𝑚𝑜𝑙∗𝐾 1000 𝐽
𝒌𝑱
∆𝑼 = ∆𝑼𝟏𝟐 = ∆𝑼𝟐𝟑 = 𝟏. 𝟐𝟒𝟕 → (𝒂) Answe𝑟
𝒎𝒐𝒍
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Now
∆𝐻 = ∆𝐻12 = ∆𝐻23 = 𝐶𝑃 ∆𝑇
5
∆𝐻 = ∆𝐻12 = ∆𝐻23 = 𝑅(𝑇2 − 𝑇1 )
2
5 𝐽 𝑘𝐽
∆𝐻 = ∆𝐻12 = ∆𝐻23 = ∗ 8.314 (403.15 − 303.15)𝐾 ∗ 1
2 𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽
𝒌𝑱
∆𝑯 = ∆𝑯𝟏𝟐 = ∆𝑯𝟐𝟑 = 𝟐. 𝟎𝟕𝟗 → (𝒃)Answe𝑟
𝒎𝒐𝒍
(a)
Step 12:
For step “12” volume is constant
Therefore
𝑾𝟏𝟐 = 𝟎
Here
𝑇2 = 𝑇3
According to first law of thermodynamics
Also we have
𝒌𝑱
∆𝑯𝟏𝟐 = 𝟐. 𝟎𝟕𝟗 [𝑭𝒓𝒐𝒎 (𝒃)]
𝒎𝒐𝒍
Step 23:
Since for step “23” process is isothermal
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Therefore
∆𝑼𝟐𝟑 = ∆𝑯𝟐𝟑 = 𝟎
Here
𝑇2 = 𝑇3
Now, intermediate pressure can be calculated as
𝑃1 𝑃2
=
𝑇1 𝑇2
𝑃1
𝑃2 = ∗𝑇
𝑇1 2
1 𝑏𝑎𝑟
𝑃2 = ∗ 403.15 𝐾
303.15 𝐾
𝑃2 = 1.329 𝑏ar
𝑄 = 𝑄12 + 𝑄23
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𝑘𝐽
𝑄 = (1.247 − 6.764)
𝑚𝑜𝑙
𝒌𝑱
𝑸 = −𝟓. 𝟓𝟏𝟔 Answe𝑟
𝒎𝒐𝒍
∆𝑈 = ∆𝑈12 + ∆𝑈23
𝑘𝐽
∆𝑈 = (1.247 + 0)
𝑚𝑜𝑙
𝒌𝑱
∆𝑼 = 𝟏. 𝟐𝟒𝟕 Answe𝑟
𝒎𝒐𝒍
∆𝐻 = ∆𝐻12 + ∆𝐻23
𝑘𝐽
∆𝐻 = (2.079 + 0)
𝑚𝑜𝑙
𝒌𝑱
∆𝑯 = 𝟐. 𝟎𝟕𝟗 Answe𝑟
𝒎𝒐𝒍
(b)
Step 12:
For step “12” volume is constant
Therefore, at constant pressure we have
𝑘𝐽
𝑄12 = ∆𝐻12 = 2.079 [𝑭𝒓𝒐𝒎 (𝒃)]
𝑚𝑜𝑙
Also,
𝒌𝑱
∆𝑼𝟏𝟐 = 𝟏. 𝟐𝟒𝟕 [𝑭𝒓𝒐𝒎 (𝒂)]
𝒎𝒐𝒍
Step 23:
Since for step “23” process is isothermal ( T = Constant)
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Therefore
∆𝑼𝟐𝟑 = ∆𝑯𝟐𝟑 = 𝟎
Here
𝑇2 = 𝑇3 & 𝑃1 = 𝑃2
For an isothermal process we have
𝑃3
𝑊23 = 𝑅𝑇2 ln
𝑃2
𝐽 1 𝑘𝐽 10
𝑊23 = 8.314 ∗ 403.15 𝐾 ∗ ∗ ln
𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽 1
𝒌𝑱
𝑾𝟐𝟑 = 𝟕. 𝟕𝟏𝟖
𝒎𝒐𝒍
𝑄 = 𝑄12 + 𝑄23
𝑘𝐽
𝑄 = (2.079 − 7.718)
𝑚𝑜𝑙
𝒌𝑱
𝑸 = −𝟓. 𝟔𝟑𝟗 Answe𝑟
𝒎𝒐𝒍
∆𝑈 = ∆𝑈12 + ∆𝑈23
𝑘𝐽
∆𝑈 = (1.247 + 0)
𝑚𝑜𝑙
𝒌𝑱
∆𝑼 = 𝟏. 𝟐𝟒𝟕 Answe𝑟
𝒎𝒐𝒍
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∆𝐻 = ∆𝐻12 + ∆𝐻23
𝑘𝐽
∆𝐻 = (2.079 + 0)
𝑚𝑜𝑙
𝒌𝑱
∆𝑯 = 𝟐. 𝟎𝟕𝟗 Answe𝑟
𝒎𝒐𝒍
(c)
Step 12:
Since for step “12” process is isothermal ( T = Constant)
Therefore
∆𝑼𝟏𝟐 = ∆𝑯𝟏𝟐 = 𝟎
Here
𝑃2 = 𝑃3
For an isothermal process we have
𝑃2
𝑊12 = 𝑅𝑇1 ln
𝑃1
𝐽 1 𝑘𝐽 10
𝑊12 = 8.314 ∗ 303.15 𝐾 ∗ ∗ ln
𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽 1
𝒌𝑱
𝑾𝟏𝟐 = 𝟓. 𝟖𝟎𝟑𝟒
𝒎𝒐𝒍
Step 23:
For step “23” volume is constant
Therefore, at constant pressure we have
𝒌𝑱
𝑸𝟐𝟑 = ∆𝑯𝟐𝟑 = 𝟐. 𝟎𝟕𝟗 [𝑭𝒓𝒐𝒎 (𝒃)]
𝒎𝒐𝒍
Here
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𝑇2 = 𝑇3
Now
𝒌𝑱
∆𝑼𝟐𝟑 = 𝟏. 𝟐𝟒𝟕 [𝑭𝒓𝒐𝒎 (𝒂)]
𝒎𝒐𝒍
𝑄 = 𝑄12 + 𝑄23
𝑘𝐽
𝑄 = (−5.8034 + 2.079)
𝑚𝑜𝑙
𝒌𝑱
𝑸 = −𝟑. 𝟕𝟐𝟒 Answe𝑟
𝒎𝒐𝒍
∆𝑈 = ∆𝑈12 + ∆𝑈23
𝑘𝐽
∆𝑈 = (0 + 1.247)
𝑚𝑜𝑙
𝒌𝑱
∆𝑼 = 𝟏. 𝟐𝟒𝟕 Answe𝑟
𝒎𝒐𝒍
∆𝐻 = ∆𝐻12 + ∆𝐻23
𝑘𝐽
∆𝐻 = (0 + 2.079)
𝑚𝑜𝑙
𝒌𝑱
∆𝑯 = 𝟐. 𝟎𝟕𝟗 Answe𝑟
𝒎𝒐𝒍
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Problem 3.23:
One mole of an ideal gas, initially at 30 ℃ and 1 bars, undergoes the following
mechanically reversible changes. It is compressed isothermally to point such that when
it is heated at constant volume to 120 ℃ its final pressure is 12 bars. Calculate Q, W,
∆𝑼 𝒂𝒏𝒅 ∆𝑯 for the process. Take CP = (7/2) R and CV = (5/2) R.
Given Data:
𝑇1 = 30 ℃
𝑇1 = (30 + 273.15) 𝐾
𝑇1 = 303.15 𝐾
𝑃1 = 1 𝑏𝑎𝑟
𝑇3 = 120 ℃
𝑇3 = (120 + 273.15) 𝐾
𝑇3 = 393.15 𝐾
𝑃3 = 12 𝑏𝑎𝑟
𝑄 =?
𝑊 =?
∆𝑈 =?
∆𝐻 =?
7
𝐶𝑃 = 𝑅
2
5
𝐶𝑉 = 𝑅
2
Solution:
The process consist of two steps, 12 & 23
Step 12:
Since for step “12” process is isothermal ( T = Constant)
Therefore
∆𝑼𝟏𝟐 = ∆𝑯𝟏𝟐 = 𝟎
Now, intermediate pressure can be calculated as
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𝑃2 𝑃3
=
𝑇2 𝑇3
𝑃3
𝑃2 = ∗𝑇
𝑇3 2
12 𝑏𝑎𝑟
𝑃2 = ∗ 303.15 𝐾
393.15 𝐾
𝑃2 = 9.25 𝑏ar
Step 23:
Since for step “23” volume is constant
Therefore
𝑾𝟐𝟑 = 𝟎
According to first law of thermodynamics
𝑄23 = ∆𝑈23 = 𝐶𝑉 ∆𝑇
5
𝑄23 = ∆𝑈23 = 𝑅 (𝑇3 − 𝑇1 )
2
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5 𝐽 1 𝑘𝐽
𝑄23 = ∆𝑈23 = ∗ 8.314 (393.15 − 303.15)𝐾 ∗
2 𝑚𝑜𝑙∗𝐾 1000 𝐽
𝒌𝑱
𝑸𝟐𝟑 = ∆𝑼𝟐𝟑 = 𝟏. 𝟖𝟕𝟏
𝒎𝒐𝒍
Now
∆𝐻23 = 𝐶𝑃 ∆𝑇
7
∆𝐻23 = 𝑅(𝑇2 − 𝑇1 )
2
7 𝐽 𝑘𝐽
∆𝐻23 = ∗ 8.314 (393.15 − 303.15)𝐾 ∗ 1
2 𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽
𝒌𝑱
∆𝐻23 = 𝟐. 𝟔𝟏𝟗
𝒎𝒐𝒍
𝑄 = 𝑄12 + 𝑄23
𝑘𝐽
𝑄 = (−5.607 + 1.871)
𝑚𝑜𝑙
𝒌𝑱
𝑸 = −𝟑. 𝟕𝟑𝟔 Answe𝑟
𝒎𝒐𝒍
∆𝑈 = ∆𝑈12 + ∆𝑈23
𝑘𝐽
∆𝑈 = (0 + 1.871)
𝑚𝑜𝑙
𝒌𝑱
∆𝑼 = 𝟏. 𝟖𝟕𝟏 Answe𝑟
𝒎𝒐𝒍
∆𝐻 = ∆𝐻12 + ∆𝐻23
𝑘𝐽
∆𝐻 = (0 + 2.691)
𝑚𝑜𝑙
𝒌𝑱
∆𝑯 = 𝟐. 𝟔𝟗𝟏 Answe𝑟
𝒎𝒐𝒍
Problem 3.24:
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A process consists of two steps: (1) One mole of air at T = 800 K and P = 4 bars are
cooled at constant volume to T = 350 K. (2) The air is then heated air constant pressure
until its temperature reaches 800 K. If this two step process is replaced by a single
isothermal expansion of the air from 800 K and 4 bar to some final pressure P, what is
the value of P that makes the work of two step processes the same? Assume mechanical
reversibility and treat air as an ideal gas with CP = (7/2) R and CV = (5/2) T.
Given Data:
𝑇1 = 800 𝐾
𝑃1 = 4 𝑏𝑎𝑟
𝑇2 = 350 𝐾
𝑃 =?
Solution:
For the first step volume is constant
Therefore,
𝑊12 = 0
For the work done is
𝑃∆𝑉 = 𝑅∆𝑇
𝑃2 ∆𝑉 = 𝑅∆𝑇
Put in (1)
𝑊 = −𝑅∆𝑇
𝑊 = −𝑅(𝑇3 − 𝑇2 )
Since
𝑇3 = 𝑇1
Therefore
𝑊 = −𝑅(𝑇1 − 𝑇2 ) → (2)
For an isothermal process we have
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𝑃
𝑊 = 𝑅𝑇1 ln → (3)
𝑃1
Compare (2) and (3)
𝑃
−𝑅(𝑇1 − 𝑇2 ) = 𝑅𝑇1 ln
𝑃1
𝑃
𝑇2 − 𝑇1 = 𝑇1 ln
𝑃1
𝑇2 − 𝑇1 𝑃
= ln
𝑇1 𝑃1
(350 − 800) 𝐾 𝑃
= ln
800 𝐾 4 𝑏𝑎𝑟
𝑃
𝑒 −0.5625 =
4 𝑏𝑎𝑟
4 𝑏𝑎𝑟 ∗ 0.5698 = 𝑃
𝑷 = 𝟐. 𝟐𝟕𝟗 𝒃𝒂𝒓 Answe𝑟
Problem 3.25:
A scheme for finding the internal volume 𝑽𝒕𝑩 of the gas cylinder consists of the following
steps. The cylinder is filled with a gas to low pressure P1, and connected through a small
line and valve to an evacuated reference tank of known volume𝑽𝒕𝑨 . The valve is opened,
and the gas flows through the line into the reference tank. After the system returns to its
initial temperature, a sensitive pressure transducer provides a valve for the pressure
change ∆𝑷 in the cylinder. Determine the cylinder volume 𝑽𝒕𝑩 from the following data:
a) 𝑽𝒕𝑨 = 𝟐𝟓𝟔 𝒄𝒎𝟑
b) ∆𝑷⁄𝑷𝟏 = −𝟎. 𝟎𝟔𝟑𝟗
Given Data:
𝑉𝐵𝑡 =?
𝑉𝐴𝑡 = 256 𝑐𝑚3
∆𝑃
= −0.0639
𝑃1
Solution:
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∆𝑃
= −0.0639
𝑃1
𝑃2 − 𝑃1
= −0.0639
𝑃1
𝑃2
− 1 = −0.0639
𝑃1
𝑃2
= −0.0639 + 1
𝑃1
𝑃2
= 0.9361 → (1)
𝑃1
Assume that gas is ideal & P2 is the pressure of the tank
When gas flows through the line into the tank then tank’s total volume becomes 𝑉𝐴𝑡 + 𝑉𝐵𝑡
Now, by applying condition for an ideal gas
Put in (1)
𝑉𝐵𝑡
= 0.9361
𝑉𝐴𝑡 + 𝑉𝐵𝑡
𝑉𝐵𝑡 = 0.9361(𝑉𝐴𝑡 + 𝑉𝐵𝑡 )
𝑉𝐵𝑡 = 0.9361𝑉𝐴𝑡 + 0.9361𝑉𝐵𝑡
𝑉𝐵𝑡 − 0.9361𝑉𝐵𝑡 = 0.9361𝑉𝐴𝑡
𝑉𝐵𝑡 (1 − 0.9361) = 0.9361𝑉𝐴𝑡
0.0639𝑉𝐵𝑡 = 256 𝑐𝑚3 ∗ 0.9361
239.6461 3
𝑉𝐵𝑡 = 𝑐𝑚
0.0639
𝑽𝒕𝑩 = 𝟑𝟕𝟓𝟎. 𝟐𝟔 𝒄𝒎𝟑 Answe𝑟
Problem 3.26:
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Given Data:
𝑇1 = 300 𝐾
𝑃1 = 1 𝑎𝑡𝑚
7
𝐶𝑃 = 𝑅
2
Solution:
According to ideal gas equation,
𝑃𝑉 = 𝑛𝑅𝑇
Applying ideal gas equation for initial conditions
On section “A”
𝑃1 𝑉𝐴 = 𝑛𝐴 𝑅𝑇1
𝑛𝐴 𝑅𝑇1
𝑉𝐴 =
𝑃1
On section “B”
𝑃1 𝑉𝐵 = 𝑛𝐵 𝑅𝑇1
Since
𝑛𝐴 = 𝑛𝐵
Therefore,
𝑃1 𝑉𝐵 = 𝑛𝐴 𝑅𝑇1
𝑛𝐴 𝑅𝑇1
𝑉𝐵 =
𝑃1
Total initial volume can be given as
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𝑉𝑖 = 𝑉𝐴 + 𝑉𝐵
𝑛𝐴 𝑅𝑇1 𝑛𝐴 𝑅𝑇1
𝑉𝑖 = +
𝑃1 𝑃1
𝑛𝐴 𝑅𝑇1
𝑉𝑖 = 2.
𝑃1
Let P2 be the final pressure & TA & TB are the final temperatures of section A & section B
respectively
Applying ideal gas equation for final conditions
On section “A”
𝑃2 𝑉𝐴 = 𝑛𝐴 𝑅𝑇𝐴
𝑛𝐴 𝑅𝑇𝐴
𝑉𝐴 =
𝑃2
On section “B”
𝑃2 𝑉𝐵 = 𝑛𝐴 𝑅𝑇𝐵
𝑛𝐴 𝑅𝑇𝐵
𝑉𝐵 =
𝑃2
Total Final volume can be given as
𝑉𝑓 = 𝑉𝐴 + 𝑉𝐵
𝑛𝐴 𝑅𝑇𝐴 𝑛𝐴 𝑅𝑇𝐵
𝑉𝑓 = +
𝑃2 𝑃2
𝑛𝐴 𝑅(𝑇𝐴 + 𝑇𝐵 )
𝑉𝑓 =
𝑃2
Since the total volume is constant, therefore
𝑉𝑖 = 𝑉𝑓
(a)
𝑃2 = 1.25 𝑎𝑡𝑚
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1−𝛾 1−𝛾
𝑇1 (𝑃1 ) 𝛾 = 𝑇𝐵 (𝑃2 ) 𝛾
1−𝛾
𝑇1 (𝑃1 ) 𝛾
𝑇𝐵 = 1−𝛾
(𝑃2 ) 𝛾
𝛾−1
𝑃2 𝛾
𝑇𝐵 = 𝑇1 ( ) → (2)
𝑃 1
We know that,
𝐶𝑃 − 𝐶𝑉 = 𝑅
𝐶𝑉 = 𝐶𝑃 − 𝑅
7
𝐶𝑉 = 𝑅 − 𝑅
2
7𝑅 − 2𝑅
𝐶𝑉 =
2
5
𝐶𝑉 = 𝑅
2
As
𝐶𝑃
𝛾=
𝐶𝑉
7∗𝑅∗2
𝛾=
2∗5∗𝑅
𝛾 = 1.4
Put in (2)
1.4−1
1.25 1.4
𝑇𝐵 = 300 𝐾 ( )
1
𝑇𝐵 = 300 𝐾 ∗ 1.0658
Put in (1)
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∆𝑈 = 𝑄 + 𝑊
Since volume is constant, therefore
∆𝑈 = 𝑄 → (𝑎)
For section A & B
∆𝑈 = ∆𝑈𝐴 + ∆𝑈𝐵
Put in (a)
𝑄 = ∆𝑈𝐴 + ∆𝑈𝐵
𝑄 = 𝑛𝐴 𝐶𝑉 ∆𝑇 + 𝑛𝐴 𝐶𝑉 ∆𝑇
𝑄 = 𝑛𝐴 𝐶𝑉 (𝑇𝐴 − 𝑇1 ) + 𝑛𝐴 𝐶𝑉 (𝑇𝐵 − 𝑇1 )
𝑄 = 𝑛𝐴 𝐶𝑉 [𝑇𝐴 − 𝑇1 + 𝑇𝐵 − 𝑇1 ]
𝑄 = 𝑛𝐴 𝐶𝑉 [𝑇𝐴 + 𝑇𝐵 − 2𝑇1 ]
𝑄
= 𝐶𝑉 [𝑇𝐴 + 𝑇𝐵 − 2𝑇1 ] → (3)
𝑛𝐴
𝑄 5
= 𝑅(430.26 + 319.74 − 2 ∗ 300) 𝐾
𝑛𝐴 2
𝑄 5 𝐽 1𝑘𝐽
= ∗ 8.314 ∗ 150.02 𝐾 ∗
𝑛𝐴 2 𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽
𝑸 𝒌𝑱
= 𝟑. 𝟏𝟏𝟖 Answe𝑟
𝒏𝑨 𝒎𝒐𝒍
(b)
𝑇𝐴 = 425 𝐾
From equation (1)
2. 𝑇1 (𝑇𝐴 + 𝑇𝐵 )
=
𝑃1 𝑃2
𝑃2 (𝑇𝐴 +𝑇𝐵 )
=
𝑃1 2.𝑇1
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Put in (2)
𝛾−1
𝑇𝐴 + 𝑇𝐵 𝛾
𝑇𝐵 = 𝑇1 ( )
2. 𝑇1
Assume 𝑇𝐵 = 319 𝐾
1.4−1
425 + 319 1.4
𝑇𝐵 = 300 𝐾 ( )
2 ∗ 300
𝑇𝐵 = 300𝐾 ∗ (1.0634)
𝑇𝐵 = 319.02 𝐾
Since 319 ≈ 319.02, therefore
𝑻𝑩 = 𝟑𝟏𝟗. 𝟎𝟐 𝑲 Answe𝑟
Put in (1)
2∗300 𝐾 (425+319.02) 𝐾
=
1 𝑎𝑡𝑚 𝑃2
744.02
𝑃2 = 𝑎𝑡𝑚
600
𝑷𝟐 = 𝟏. 𝟐𝟒 𝒂𝒕𝒎 Answe𝑟
From equation (3)
𝑄
= 𝐶𝑉 [𝑇𝐴 + 𝑇𝐵 − 2𝑇1 ]
𝑛𝐴
𝑄 5
= 𝑅(425 + 319.02 − 2 ∗ 300) 𝐾
𝑛𝐴 2
𝑄 5 𝐽 1𝑘𝐽
= ∗ 8.314 ∗ 144.02 𝐾 ∗
𝑛𝐴 2 𝑚𝑜𝑙∗𝐾 1000 𝐽
𝑄 𝑘𝐽
= 2.993 Answe𝑟
𝑛𝐴 𝑚𝑜𝑙
(c)
𝑇𝐵 = 325 𝐾
Put in (2)
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𝛾−1
𝑃2 𝛾
𝑇𝐵 = 𝑇1 ( )
𝑃 1
𝛾−1
𝑃2 𝛾
325 𝐾 = 300 𝐾 ( )
1 𝑎𝑡𝑚
𝛾−1
325 𝑃2 𝛾
=( )
300 1 𝑎𝑡𝑚
𝛾
325 𝛾−1 𝑃2
( ) =
300 1 𝑎𝑡𝑚
1.4
325 1.4−1
𝑃2 = ( ) 𝑎𝑡𝑚
300
𝑷𝟐 = 𝟏. 𝟑𝟐𝟑 𝒂𝒕𝒎 Answe𝑟
Put in (1)
𝑄
= 𝐶𝑉 [𝑇𝐴 + 𝑇𝐵 − 2𝑇1 ]
𝑛𝐴
𝑄 5
= 𝑅(468.9 + 325 − 2 ∗ 300) 𝐾
𝑛𝐴 2
𝑄 5 𝐽 1𝑘𝐽
= ∗ 8.314 ∗ 193.9 𝐾 ∗
𝑛𝐴 2 𝑚𝑜𝑙∗𝐾 1000 𝐽
𝑄 𝑘𝐽
= 𝟒. 𝟎𝟑𝟎𝟐 Answe𝑟
𝑛𝐴 𝑚𝑜𝑙
(d)
𝑄 𝑘𝐽
=3
𝑛𝐴 𝑚𝑜𝑙
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2. 𝑇1 (𝑇𝐴 + 𝑇𝐵 )
=
𝑃1 𝑃2
2. 𝑇1 ∗ 𝑃2
𝑇𝐴 + 𝑇𝐵 = → (𝑏)
𝑃1
From equation (3)
𝑄
= 𝐶𝑉 [𝑇𝐴 + 𝑇𝐵 − 2𝑇1 ]
𝑛𝐴
𝑄
𝑇𝐴 + 𝑇𝐵 − 2𝑇1 =
𝑛𝐴 ∗ 𝐶𝑉
𝑄
𝑇𝐴 + 𝑇𝐵 = + 2𝑇1 → (𝑐)
𝑛𝐴 ∗𝐶𝑉
2. 𝑇1 ∗ 𝑃2 𝑄
= + 2𝑇1
𝑃1 𝑛𝐴 ∗ 𝐶𝑉
𝑃1 𝑄
𝑃2 = [ + 2𝑇1 ]
2.𝑇1 𝑛𝐴 ∗𝐶𝑉
1 𝑎𝑡𝑚 2 ∗ 3 𝑘𝐽
𝑃2 = [ + 2 ∗ 300 𝐾]
2 ∗ 300 𝐾 5𝑅 ∗ 𝑚𝑜𝑙
1 𝑎𝑡𝑚 6 𝑘𝐽 ∗ 𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽
𝑃2 = [ ∗ + 600𝐾]
600 𝐾 5 ∗ 𝑚𝑜𝑙 ∗ 8.314 𝐽 1 𝑘𝐽
1 𝑎𝑡𝑚
𝑃2 = [144.335 + 600] 𝐾
600 𝐾
𝑃2 = 1.2406 𝑎𝑡𝑚 Answe𝑟
Put in (2)
𝛾−1
𝑃2 𝛾
𝑇𝐵 = 𝑇1 ( )
𝑃1
1.4−1
1.2406 1.4
𝑇𝐵 = 300 𝐾 ( )
1
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𝑇𝐵 = 300 𝐾 ∗ 1.0635
𝑻𝑩 = 𝟑𝟏𝟗. 𝟎𝟔 𝑲 Answe𝑟
Put in (1)
2. 𝑇1 (𝑇𝐴 + 𝑇𝐵 )
=
𝑃1 𝑃2
2∗300 𝐾 (𝑇𝐴 +319.06 𝐾)
=
1 𝑎𝑡𝑚 1.2406 𝑎𝑡𝑚
Problem 3.27:
One mole of an ideal gas with constant heat capacities undergoes an arbitrary
mechanically reversible process. Show that:
𝟏
∆𝑼 = 𝜸−𝟏 ∆(𝑷𝑽)
Given Data:
𝑁𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠 = 𝑛 = 1
Solution:
We know that
∆𝑈 = 𝑛𝐶𝑉 ∆𝑇
∆𝑈 = 1. 𝐶𝑉 ∆𝑇
∆𝑈 = 𝐶𝑉 (𝑇2 − 𝑇1 ) → (1)
For an ideal gas we have,
𝐶𝑃 − 𝐶𝑉 = 𝑅
𝐶𝑃 𝐶𝑉 𝑅
− =
𝐶𝑉 𝐶𝑉 𝐶𝑉
𝐶𝑃 𝑅
−1=
𝐶𝑉 𝐶𝑉
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Since
𝐶𝑃
𝛾=
𝐶𝑉
Therefore,
𝑅
𝛾−1=
𝐶𝑉
𝑅
𝐶𝑉 =
𝛾−1
Put in (1)
𝑅
∆𝑈 = (𝑇 − 𝑇1 )
𝛾−1 2
1
∆𝑈 = (𝑅𝑇2 − 𝑅𝑇1 ) → (2)
𝛾−1
𝑃1 𝑉1 = 𝑅𝑇1 → (𝑎)
𝑃2 𝑉2 = 𝑅𝑇2 → (𝑏)
Put (a) & (b) in (2)
1
∆𝑈 = (𝑃 𝑉 − 𝑃1 𝑉1 )
𝛾−1 2 2
1
∆𝑈 = ∆(𝑃𝑉) Proved
𝛾−1
Problem 3.28:
Solution:
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𝑉
𝑊 = − ∫𝑉 2 𝑃𝑑𝑉 → (1)
1
Given that
𝑍 = 1 + 𝐵′𝑃
Also
𝑃𝑉
𝑍=
𝑅𝑇
Therefore,
𝑃𝑉
= 1 + 𝐵′ 𝑃
𝑅𝑇
𝑅𝑇
𝑉= (1 + 𝐵′ 𝑃)
𝑃
1
𝑉 = 𝑅𝑇 ( + 𝐵′)
𝑃
𝑑𝑉 −1
= 𝑅𝑇 ( 2 + 0)
𝑑𝑃 𝑃
𝑅𝑇
𝑑𝑉 = − 2 𝑑𝑃
𝑃
Put in (1)
𝑉2
𝑊 = − ∫ 𝑃𝑑𝑉
𝑉1
𝑃2
𝑅𝑇
𝑊 = − ∫ −𝑃 𝑑𝑃
𝑃1 𝑃2
𝑃2
1
𝑊 = 𝑅𝑇 ∫ 𝑑𝑃
𝑃1 𝑃
𝑃
𝑊 = 𝑅𝑇|ln 𝑃|𝑃21
𝑊 = 𝑅𝑇(ln 𝑃2 − ln 𝑃1 )
𝑷𝟐
𝑾 = 𝑹𝑻 𝐥𝐧 Proved
𝑷𝟏
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Problem 3.30:
For methyl chloride at 100℃ the second and third virial coefficients are:
𝑩 = −𝟐𝟒𝟐. 𝟓𝒄𝒎𝟑 𝒎𝒐𝒍−𝟏 ; 𝑪 = 𝟐𝟓 𝟐𝟎𝟎 𝒄𝒎𝟔 𝒎𝒐𝒍−𝟐 .
Calculate the work of mechanically reversible, isothermal compression of 1 mol of
methyl chloride 1 bar to 55 bars at 100℃. Base calculations on the following forms of
virial equations
𝑩 𝑪
a) 𝒁 = 𝟏 + 𝑽 + 𝑽𝟐
b) 𝒁 = 𝟏 + 𝑩′ 𝑷 + 𝑪′𝑷𝟐
𝑩 𝑪−𝑩𝟐
Where 𝑩′ = 𝑹𝑻 & 𝑪′ = (𝑹𝑻)𝟐
Why don’t both equations give exactly the same result?
Given Data:
𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇 = 100 ℃
𝑇 = (100 + 273.15)𝐾
𝑇 = 373.15 𝐾
𝐵 = −242.5 𝑐𝑚3 𝑚𝑜𝑙 −1
𝐶 = 25200 𝑐𝑚6 𝑚𝑜𝑙−2
𝑃1 = 1 𝑏𝑎𝑟
𝑃2 = 55 𝑏𝑎𝑟
𝐵
𝐵′ =
𝑅𝑇
′
𝐶 − 𝐵2
𝐶 =
(𝑅𝑇)2
𝑊 =?
Solution:
As
𝐵
𝐵′ =
𝑅𝑇
3
′
−242.5 𝑐𝑚 ∗ 𝑚𝑜𝑙 ∗ 𝐾 𝐽 101325 𝑁 1 𝑚3
𝐵 = ∗ ∗ ∗
𝑚𝑜𝑙 ∗ 8.314 𝐽 ∗ 373.15 𝐾 𝑁 ∗ 𝑚 𝑚2 ∗ 1.01325 𝑏𝑎𝑟 1003 𝑐𝑚3
𝟏
𝑩′ = −𝟕. 𝟖𝟏𝟕 ∗ 𝟏𝟎−𝟑
𝒃𝒂𝒓
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Now,
𝐶−𝐵2
𝐶 ′ = (𝑅𝑇)2
[25200 − (−242.5)2 ]𝑐𝑚6 ∗ 𝐾 2 ∗ 𝑚𝑜𝑙 2
′
𝐽2 1013252 𝑁 2
𝐶 = ∗ 2 ∗
𝑚𝑜𝑙 2 ∗ 8.3142 𝐽2 ∗ 373.152 𝐾 2 𝑁 ∗ 𝑚2 𝑚4 ∗ 1.013252 𝑏𝑎𝑟 2
1 𝑚6
∗
1006 𝑐𝑚6
𝟏
𝑪′ = −𝟑. 𝟒𝟗𝟐 ∗ 𝟏𝟎−𝟓 𝟐
𝒃𝒂𝒓
(a)
𝐵 𝐶
𝑍 =1+
+
𝑉 𝑉2
𝑃𝑉 𝐵 𝐶
=1+ + 2
𝑅𝑇 𝑉 𝑉
𝑅𝑇 𝐵 𝐶
𝑃 = (1 + + 2) → (1)
𝑉 𝑉 𝑉
𝑉
𝑊 = − ∫𝑉 2 𝑃𝑑𝑉 → (2)
1
𝑉2
𝑅𝑇 𝐵 𝐶
𝑊 = −∫ (1 + + 2 ) 𝑑𝑉
𝑉1 𝑉 𝑉 𝑉
𝑉2
𝐵 𝐶 1
𝑊 = −𝑅𝑇 ∫ (1 + + ) 𝑑𝑉 → (3)
𝑉1 𝑉 𝑉2 𝑉
Again using
𝑅𝑇 𝐵 𝐶
𝑉1 =
𝑃1
(1 + 𝑉 + 𝑉 2 ) → (4)
1 1
Assume that
𝑐𝑚3
𝑉1 = 30780 → (𝑎)
𝑚𝑜𝑙
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𝐿. 𝐻. 𝑆 = 𝑅. 𝐻. 𝑆
Therefore
𝒄𝒎𝟑
𝑰𝒏𝒊𝒕𝒊𝒂𝒍 𝒗𝒐𝒍𝒖𝒎𝒆 = 𝑽𝟏 = 𝟑𝟎𝟕𝟖𝟎
𝒎𝒐𝒍
Again using
𝑅𝑇 𝐵 𝐶
𝑉2 =
𝑃2
(1 + 𝑉 + 𝑉 2 ) → (5)
2 2
Assume that
𝑐𝑚3
𝑉2 = 241.33 → (𝑐)
𝑚𝑜𝑙
𝑅𝑇 8.314 𝐽∗373.15 𝐾 𝑁∗𝑚 1.01325 𝑏𝑎𝑟∗𝑚2 1003 ∗𝑐𝑚3
𝑃2
= 𝑚𝑜𝑙∗𝐾∗55 𝑏𝑎𝑟
∗ 𝐽
∗ 101325 𝑁
∗ 1 𝑚3
𝑅𝑇 𝑐𝑚3
= 564.067 → (𝑑)
𝑃2 𝑚𝑜𝑙
𝑐𝑚3 𝑐𝑚3
241.33 = 564.067 (1 − 1.0048 + 0.4327)
𝑚𝑜𝑙 𝑚𝑜𝑙
𝑐𝑚3 𝑐𝑚3
241.33 = 564.067 ∗ 0.4278
𝑚𝑜𝑙 𝑚𝑜𝑙
3 3
𝑐𝑚 𝑐𝑚
241.33 = 241.33
𝑚𝑜𝑙 𝑚𝑜𝑙
Since
𝐿. 𝐻. 𝑆 = 𝑅. 𝐻. 𝑆
Therefore
𝒄𝒎𝟑
𝑭𝒊𝒏𝒂𝒍𝒗𝒐𝒍𝒖𝒎𝒆 = 𝑽𝟐 = 𝟐𝟒𝟏. 𝟑𝟑
𝒎𝒐𝒍
𝑉2
𝐵 𝐶 1
𝑊 = −𝑅𝑇 ∫ (1 + + ) 𝑑𝑉
𝑉1 𝑉 𝑉2 𝑉
𝑉2 𝑉2 𝑉2
1 1 1
𝑊 = −𝑅𝑇 [∫ 𝑑𝑉 + 𝐵 ∫ 2
𝑑𝑉 + 𝐶 ∫ 3
𝑑𝑉 ]
𝑉1 𝑉 𝑉1 𝑉 𝑉1 𝑉
𝑉 1 𝑉2 1 1 𝑉2
𝑊 = −𝑅𝑇 [|ln 𝑉|𝑉21− 𝐵 | | − 𝐶 | 2| ]
𝑉 𝑉1 2 𝑉 𝑉1
1 1 1 1 1
𝑊 = −𝑅𝑇 [(ln 𝑉2 − ln 𝑉1 ) − 𝐵 ( − ) − 𝐶 ( 2 − 2 )]
𝑉2 𝑉1 2 𝑉2 𝑉1
𝑉2 1 1 1 1 1
𝑊 = −𝑅𝑇 [ln − 𝐵 ( − ) − 𝐶 ( 2 − 2 )]
𝑉1 𝑉2 𝑉1 2 𝑉2 𝑉1
8.314 ∗ 𝐽 ∗ 373.15𝐾
𝑊 =−
𝑚𝑜𝑙 ∗ 𝐾
1 𝑘𝐽 241.33 1 1
∗ [ln + 242.5 ( − )
1000 𝐽 30780 241.33 30780
25200 1 1
− ( − )]
2 241.332 307802
𝑘𝐽
𝑊 = −3.102 [−4.848 + 0.996 − 0.2163]
𝑚𝑜𝑙
𝒌𝑱
𝑾 = 𝟏𝟐. 𝟔𝟐 Answer
𝒎𝒐𝒍
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(b)
𝑍 = 1 + 𝐵 ′ 𝑃 + 𝐶 ′ 𝑃2
𝑃𝑉
= 1 + 𝐵 ′ 𝑃 + 𝐶 ′ 𝑃2
𝑅𝑇
𝑅𝑇
𝑉= (1 + 𝐵′ 𝑃 + 𝐶 ′ 𝑃2 )
𝑃
1
𝑉 = 𝑅𝑇 ( + 𝐵′ + 𝐶′𝑃)
𝑃
𝑑𝑉 1
= 𝑅𝑇 (− 2 + 0 + 𝐶 ′ )
𝑑𝑃 𝑃
1
𝑑𝑉 = −𝑅𝑇 ( 2 + 𝐶′) 𝑑𝑃
𝑃
Put in (2)
𝑃2
1
𝑊 = − ∫ −𝑃𝑅𝑇 ( 2
+ 𝐶 ′ ) 𝑑𝑃
𝑃1 𝑃
𝑃 1 𝑃
𝑊 = 𝑅𝑇 [∫𝑃 2 𝑑𝑃 + 𝐶′ ∫𝑃 2 𝑃𝑑𝑃 ]
1 𝑃 1
𝑃 𝐶′
𝑊 = 𝑅𝑇 [|𝑙𝑛𝑃|𝑃21 + |𝑃2 |𝑃𝑃21 ]
2
𝑃2
𝑊 = 𝑅𝑇 [ln + 𝐶 ′ (𝑃2 2 − 𝑃1 2 )]
𝑃1
8.314 ∗ 𝐽 ∗ 373.15𝐾 1 𝑘𝐽 55 3.492 ∗ 10−5 1
𝑊= ∗ [ln − 2
(552 − 1)𝑏𝑎𝑟 2 ]
𝑚𝑜𝑙 ∗ 𝐾 1000 𝐽 1 2 𝑏𝑎𝑟
3.102𝑘𝐽
𝑊= (3.9545)
𝑚𝑜𝑙
𝒌𝑱
𝑾 = 𝟏𝟐. 𝟐𝟔𝟖 Answer
𝒎𝒐𝒍
The answers for part (a) and (b) differ because the relations between the two sets of
parameters are exact only for infinite series
Problem 3.32:
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𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇 = 25 ℃
𝑇 = (25 + 273.15)𝐾
𝑇 = 298.15 𝐾
𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃 = 12 𝑏𝑎𝑟
Solution:
(a)
𝐵 𝐶
𝑍 =1+ +
𝑉 𝑉2
𝑃𝑉 𝐵 𝐶
=1+ +
𝑅𝑇 𝑉 𝑉2
𝑅𝑇 𝐵 𝐶
𝑉=(1 + + 2 ) → (1)
𝑃 𝑉 𝑉
𝑅𝑇 8.314 ∗ 𝐽 ∗ 298.15 𝐾 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 ∗ 𝑐𝑚3
= ∗ ∗ ∗
𝑃 𝑚𝑜𝑙 ∗ 𝐾 ∗ 12 ∗ 𝑏𝑎𝑟 𝐽 101325 𝑁 1 𝑚3
𝑅𝑇 𝑐𝑚3
= 2065.68
𝑉 𝑚𝑜𝑙
Put in (1)
𝑐𝑚3 𝐵 𝐶
𝑉 = 2065.68 (1 + 𝑉 + 𝑉 2)
𝑚𝑜𝑙
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Assume
𝑐𝑚3
𝑉 = 1919
𝑚𝑜𝑙
Therefore
Since
𝐿. 𝐻. 𝑆 = 𝑅. 𝐻. 𝑆
Therefore
𝒄𝒎𝟑
𝑽 = 𝟏𝟗𝟏𝟗 Answer
𝒎𝒐𝒍
We know that
𝑃𝑉
𝑍=
𝑅𝑇
3
12 ∗ 𝑏𝑎𝑟 ∗ 1919 ∗ 𝑐𝑚 ∗ 𝑚𝑜𝑙 ∗ 𝐾 𝐽 101325 𝑁 1 𝑚3
𝑍= ∗ ∗ ∗
8.314 ∗ 𝐽 ∗ 298.15 ∗ 𝐾 ∗ 𝑚𝑜𝑙 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 𝑐𝑚3
𝒁 = 𝟎. 𝟗𝟐𝟗 Answer
(b)
𝐵𝑃
𝑍 =1+ → (2)
𝑅𝑇
We know that
𝑇
𝑅𝑒𝑑𝑢𝑐𝑒𝑑 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇𝑟 =
𝑇𝑐
𝑇 = 𝑇𝑟 𝑇𝑐 → (𝑎)
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𝑃
𝑅𝑒𝑑𝑢𝑐𝑒𝑑 𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃𝑟 =
𝑃𝑐
𝑃 = 𝑃𝑟 𝑃𝑐 → (𝑏)
Put (a) and (b) in (2)
𝐵𝑃𝑟 𝑃𝑐
𝑍 =1+
𝑅𝑇𝑟 𝑇𝑐
Since
𝐵𝑃
𝑅𝑒𝑑𝑢𝑐𝑒𝑑 𝑠𝑒𝑐𝑜𝑛𝑑 𝑣𝑖𝑟𝑖𝑎𝑙 𝑐𝑜𝑒𝑓𝑓𝑖𝑐𝑖𝑒𝑛𝑡 = 𝐵̂ = 𝑐
𝑅𝑇𝑐
Therefore
𝐵̂𝑃𝑟
𝑍 =1+ → (3)
𝑇𝑟
Also
𝐵̂ = 𝐵𝑂 + 𝜔𝐵1
Put in (3)
𝑃𝑟
𝑍 = 1 + (𝐵𝑂 + 𝜔𝐵1 ) → (4)
𝑇𝑟
𝝎 = 𝟎. 𝟎𝟖𝟕 → (𝒊)
𝐶𝑟𝑖𝑡𝑖𝑐𝑎𝑙 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇𝑐 = 282.3 𝐾
𝑻 𝟐𝟗𝟖. 𝟏𝟓 𝑲
𝑻𝒓 = = = 𝟏. 𝟎𝟓𝟔 → (𝒊𝒊)
𝑻𝒄 𝟐𝟖𝟐. 𝟑 𝑲
𝐶𝑟𝑖𝑡𝑖𝑐𝑎𝑙 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃𝑐 = 50.40 𝑏𝑎𝑟
𝑷 𝟏𝟐 𝐛𝐚𝐫
𝑷𝒓 = = = 𝟎. 𝟐𝟑𝟖 → (𝒊𝒊𝒊)
𝑷𝒄 𝟓𝟎.𝟒𝟎 𝐛𝐚𝐫
Also we have
0.422
𝐵𝑜 = 0.083 −
𝑇𝑟 1.6
0.422
𝐵𝑜 = 0.083 −
1.0561.6
𝑩𝒐 = −𝟎. 𝟑𝟎𝟒 → (𝒊𝒗)
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0.172
𝐵1 = 0.139 −
1.0564.2
𝑩 = 𝟐. 𝟏𝟖𝟑 ∗ 𝟏𝟎−𝟑 → (𝒗)
𝟏
0.238
𝑍 = 1 + (−0.304 + 0.087 ∗ 2.183 ∗ 10−3 )
1.056
𝒁 = 𝟎. 𝟗𝟑𝟏 Answer
We know that
𝑃𝑉
𝑍=
𝑅𝑇
𝑍𝑅𝑇
𝑉=
𝑃
0.931 ∗ 8.314 𝐽 ∗ 298.15 𝐾 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 𝑐𝑚3
𝑉= ∗ ∗ ∗
𝑚𝑜𝑙 ∗ 𝐾 ∗ 12 𝑏𝑎𝑟 𝐽 101325 𝑁 1 𝑚3
𝒄𝒎𝟑
𝑽 = 𝟏𝟗𝟐𝟑. Answer
𝒎𝒐𝒍
(c)
𝑍−𝛽
𝑍 = 1 + 𝛽 − 𝑞𝛽 (𝑍+𝜖𝛽)(𝑍+𝜎𝛽) → (5)
Where
𝑃𝑟
𝛽=𝛺
𝑇𝑟
From table 3.1
𝟏
𝝈 = 𝟏, 𝛀 = 𝟎. 𝟎𝟖𝟔𝟔𝟒, 𝜺 = 𝟎, 𝝍 = 𝟎. 𝟒𝟐𝟕𝟒𝟖, 𝜶(𝑻𝒓 ) = 𝑻𝒓 −𝟐
Now
0.238
𝛽 = 0.08664 ∗
1.056
𝜷 = 𝟎. 𝟎𝟏𝟗𝟓 → (𝒊′ )
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Also
𝜓𝛼(𝑇𝑟 )
𝑞=
Ω𝑇𝑟
1
0.42748 ∗ 1.056−2
𝑞=
0.08664 ∗ 1.056
𝒒 = 𝟒. 𝟓𝟒𝟕 → (𝒊𝒊′ )
Put (i’) and (ii’) in (5)
𝑍−𝛽
𝑍 = 1 + 0.0195 − 4.547 ∗ 0.0195 (𝑍+𝜖𝛽)(𝑍+𝜎𝛽)
Assume
𝒁 = 𝟎. 𝟗𝟐𝟖
0.928 − 0.0195
0.928 = 1.0195 − 0.08866
0.928(0.928 + 0.0195)
0.928 = 1.0195 − 0.08866 ∗ 1.033
0.928 = 0.928
Since
𝑳. 𝑯. 𝑺 = 𝑹. 𝑯. 𝑺
Therefore,
𝒁 = 𝟎. 𝟗𝟐𝟖 Answer
We know that
𝑃𝑉
𝑍=
𝑅𝑇
𝑍𝑅𝑇
𝑉=
𝑃
0.928 ∗ 8.314 𝐽 ∗ 298.15 𝐾 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 𝑐𝑚3
𝑉= ∗ ∗ ∗
𝑚𝑜𝑙 ∗ 𝐾 ∗ 12 𝑏𝑎𝑟 𝐽 101325 𝑁 1 𝑚3
𝒄𝒎𝟑
𝑽 = 𝟏𝟗𝟏𝟔. 𝟖 Answer
𝒎𝒐𝒍
(d)
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1 2
2)
𝛼𝑆𝑅𝐾 (𝑇𝑟 ; 𝜔) = [1 + {(0.480 + 1.574𝜔 − 0.176𝜔 (1 − 𝑇𝑟 )}]
2
1 2
2
𝛼𝑆𝑅𝐾 (𝑇𝑟 ; 𝜔) = [1 + {(0.480 + 1.574 ∗ 0.087 − 0.176 ∗ 0.087 ) (1 − 1.0562 )}]
Now
𝜓𝛼(𝑇𝑟 )
𝑞=
Ω𝑇𝑟
0.42748 ∗ 0.966
𝑞=
0.08664 ∗ 1.056
𝒒 = 𝟒. 𝟓𝟏𝟓 → (𝒊𝒊𝒊′ )
Put (i’) and (iii’) in (5)
𝑍−𝛽
𝑍 = 1 + 0.0195 − 4.515 ∗ 0.0195 (𝑍+𝜖𝛽)(𝑍+𝜎𝛽)
Assume
𝒁 = 𝟎. 𝟗𝟐𝟖
0.928 − 0.0195
0.928 = 1.0195 − 0.08803
0.9(0.9 + 0.0195)
0.928 = 1.0195 − 0.2383 ∗ 1.36
0.928 = 0.928
Since
𝑳. 𝑯. 𝑺 = 𝑹. 𝑯. 𝑺
Therefore,
𝒁 = 𝟎. 𝟗𝟐𝟖 Answer
We know that
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2013
𝑃𝑉
𝑍=
𝑅𝑇
𝑍𝑅𝑇
𝑉=
𝑃
0.928 ∗ 8.314 𝐽 ∗ 298.15 𝐾 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 𝑐𝑚3
𝑉= ∗ ∗ ∗
𝑚𝑜𝑙 ∗ 𝐾 ∗ 12 𝑏𝑎𝑟 𝐽 101325 𝑁 1 𝑚3
𝒄𝒎𝟑
𝑽 = 𝟏𝟗𝟏𝟕 Answer
𝒎𝒐𝒍
(e)
Now
𝜓𝛼(𝑇𝑟 )
𝑞=
Ω𝑇𝑟
0.42748 ∗ 0.9722
𝑞=
0.08664 ∗ 1.056
𝒒 = 𝟒. 𝟓𝟒𝟐 → (𝒗′)
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𝑍−𝛽
𝑍 = 1 + 0.0175 − 4.542 ∗ 0.0175 (𝑍+𝜖𝛽)(𝑍+𝜎𝛽)
Assume
𝒁 = 𝟎. 𝟗𝟐
0.92 − 0.0175
0.92 = 1.0175 − 0.07949
(0.92 − 0.414 ∗ 0.0175)(0.92 + 2.41 ∗ 0.0175)
0.92 = 1.0175 − 0.07949 ∗ 1.027
0.92 ≈ 0.93
Since
𝑳. 𝑯. 𝑺 ≈ 𝑹. 𝑯. 𝑺
Therefore,
𝒁 = 𝟎. 𝟗𝟐 Answer
We know that
𝑃𝑉
𝑍=
𝑅𝑇
𝑍𝑅𝑇
𝑉=
𝑃
0.92 ∗ 8.314 𝐽 ∗ 298.15 𝐾 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 𝑐𝑚3
𝑉= ∗ ∗ ∗
𝑚𝑜𝑙 ∗ 𝐾 ∗ 12 𝑏𝑎𝑟 𝐽 101325 𝑁 1 𝑚3
𝒄𝒎𝟑
𝑽 = 𝟏𝟗𝟎𝟎. 𝟒 Answer
𝒎𝒐𝒍
Problem 3.33:
Given Data:
𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇 = 50℃
𝑇 = (50 + 273.15)𝐾
𝑇 = 323.15 𝐾
𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃 = 15 𝑏𝑎𝑟
Solution:
(a)
𝐵 𝐶
𝑍 =1+ +
𝑉 𝑉2
𝑃𝑉 𝐵 𝐶
=1+ + 2
𝑅𝑇 𝑉 𝑉
𝑅𝑇 𝐵 𝐶
𝑉= (1 + + 2 ) → (1)
𝑃 𝑉 𝑉
Put in (1)
𝑐𝑚3 𝐵 𝐶
𝑉 = 1791 (1 + 𝑉 + 𝑉 2)
𝑚𝑜𝑙
Assume
𝑐𝑚3
𝑉 = 1625
𝑚𝑜𝑙
Therefore
𝑐𝑚3 𝑐𝑚3
1625 = 1791 (0.9072)
𝑚𝑜𝑙 𝑚𝑜𝑙
𝑐𝑚3 𝑐𝑚3
1625 = 1625
𝑚𝑜𝑙 𝑚𝑜𝑙
Since
𝐿. 𝐻. 𝑆 = 𝑅. 𝐻. 𝑆
Therefore
𝒄𝒎𝟑
𝑽 = 𝟏𝟔𝟐𝟓 Answer
𝒎𝒐𝒍
We know that
𝑃𝑉
𝑍=
𝑅𝑇
3
15 ∗ 𝑏𝑎𝑟 ∗ 1625 ∗ 𝑐𝑚 ∗ 𝑚𝑜𝑙 ∗ 𝐾 𝐽 101325 𝑁 1 𝑚3
𝑍= ∗ ∗ ∗
8.314 ∗ 𝐽 ∗ 323.15 ∗ 𝐾 ∗ 𝑚𝑜𝑙 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 𝑐𝑚3
𝒁 = 𝟎. 𝟗𝟎𝟕 Answer
(b)
𝐵𝑃
𝑍 =1+ → (2)
𝑅𝑇
We know that
𝑇
𝑅𝑒𝑑𝑢𝑐𝑒𝑑 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇𝑟 =
𝑇𝑐
𝑇 = 𝑇𝑟 𝑇𝑐 → (𝑎)
𝑃
𝑅𝑒𝑑𝑢𝑐𝑒𝑑 𝑃𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃𝑟 =
𝑃𝑐
𝑃 = 𝑃𝑟 𝑃𝑐 → (𝑏)
Put (a) and (b) in (2)
𝐵𝑃𝑟 𝑃𝑐
𝑍 =1+
𝑅𝑇𝑟 𝑇𝑐
Since
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𝐵𝑃
𝑅𝑒𝑑𝑢𝑐𝑒𝑑 𝑠𝑒𝑐𝑜𝑛𝑑 𝑣𝑖𝑟𝑖𝑎𝑙 𝑐𝑜𝑒𝑓𝑓𝑖𝑐𝑖𝑒𝑛𝑡 = 𝐵̂ = 𝑐
𝑅𝑇𝑐
Therefore
𝐵̂𝑃𝑟
𝑍 =1+ → (3)
𝑇𝑟
Also
𝐵̂ = 𝐵𝑂 + 𝜔𝐵1
Put in (3)
𝑃𝑟
𝑍 = 1 + (𝐵𝑂 + 𝜔𝐵1 ) → (4)
𝑇𝑟
𝝎 = 𝟎. 𝟏 → (𝒊)
𝐶𝑟𝑖𝑡𝑖𝑐𝑎𝑙 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 = 𝑇𝑐 = 305.3 𝐾
𝑻 𝟑𝟐𝟑. 𝟏𝟓 𝑲
𝑻𝒓 = = = 𝟏. 𝟎𝟓𝟖 → (𝒊𝒊)
𝑻𝒄 𝟑𝟎𝟓. 𝟑 𝑲
𝐶𝑟𝑖𝑡𝑖𝑐𝑎𝑙 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒 = 𝑃𝑐 = 48.72 𝑏𝑎𝑟
𝑷 𝟏𝟓 𝐛𝐚𝐫
𝑷𝒓 = = = 𝟎. 𝟑𝟎𝟖 → (𝒊𝒊𝒊)
𝑷𝒄 𝟒𝟖.𝟕𝟐 𝐛𝐚𝐫
Also we have
0.422
𝐵𝑜 = 0.083 −
𝑇𝑟 1.6
0.422
𝐵𝑜 = 0.083 −
1.0581.6
𝑩𝒐 = −𝟎. 𝟑𝟎𝟑 → (𝒊𝒗)
0.172
𝐵1 = 0.139 −
1.0584.2
𝑩𝟏 = 𝟑. 𝟐𝟔𝟔 ∗ 𝟏𝟎−𝟑 → (𝒗)
Put (i), (ii), (iii), (iv) & (v) in (4)
0.308
𝑍 = 1 + (−0.303 + 0.1 ∗ 3.266 ∗ 10−3 )
1.058
𝒁 = 𝟎. 𝟗𝟏𝟐 Answer
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We know that
𝑃𝑉
𝑍=
𝑅𝑇
𝑍𝑅𝑇
𝑉=
𝑃
0.912 ∗ 8.314 𝐽 ∗ 323.15 𝐾 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 𝑐𝑚3
𝑉= ∗ ∗ ∗
𝑚𝑜𝑙 ∗ 𝐾 ∗ 15 𝑏𝑎𝑟 𝐽 101325 𝑁 1 𝑚3
𝒄𝒎𝟑
𝑽 = 𝟏𝟔𝟑𝟑. 𝟑𝟔 Answer
𝒎𝒐𝒍
(c)
𝑍−𝛽
𝑍 = 1 + 𝛽 − 𝑞𝛽 (𝑍+𝜖𝛽)(𝑍+𝜎𝛽) → (5)
Where
𝑃𝑟
𝛽=𝛺
𝑇𝑟
From table 3.1
𝟏
𝝈 = 𝟏, 𝛀 = 𝟎. 𝟎𝟖𝟔𝟔𝟒, 𝜺 = 𝟎, 𝝍 = 𝟎. 𝟒𝟐𝟕𝟒𝟖, 𝜶(𝑻𝒓 ) = 𝑻𝒓 −𝟐
Now
0.308
𝛽 = 0.08664 ∗
1.058
𝜷 = 𝟎. 𝟎𝟐𝟓𝟐 → (𝒊′ )
Also
𝜓𝛼(𝑇𝑟 )
𝑞=
Ω𝑇𝑟
1
0.42748 ∗ 1.058−2
𝑞=
0.08664 ∗ 1.058
𝒒 = 𝟒. 𝟓𝟑𝟑 → (𝒊𝒊′ )
Put (i’) and (ii’) in (5)
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𝑍−𝛽
𝑍 = 1 + 0.0252 − 4.533 ∗ 0.0252 (𝑍+𝜖𝛽)(𝑍+𝜎𝛽)
Assume
𝒁 = 𝟎. 𝟗𝟎𝟔
0.906 − 0.0252
0.906 = 1.0252 − 0.114
0.906(0.906 + 0.0252)
0.906 = 1.0252 − 0.114 ∗ 1.044
0.906 = 0.906
Since
𝑳. 𝑯. 𝑺 = 𝑹. 𝑯. 𝑺
Therefore,
𝒁 = 𝟎. 𝟗𝟎𝟔 Answer
We know that
𝑃𝑉
𝑍=
𝑅𝑇
𝑍𝑅𝑇
𝑉=
𝑃
0.906 ∗ 8.314 𝐽 ∗ 323.15 𝐾 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 𝑐𝑚3
𝑉= ∗ ∗ ∗
𝑚𝑜𝑙 ∗ 𝐾 ∗ 15 𝑏𝑎𝑟 𝐽 101325 𝑁 1 𝑚3
𝒄𝒎𝟑
𝑽 = 𝟏𝟔𝟐𝟐. 𝟕 Answer
𝒎𝒐𝒍
(d)
1 2
𝛼𝑆𝑅𝐾 (𝑇𝑟 ; 𝜔) = [1 + {0.480 + 1.574𝜔 − 0.176𝜔2 (1 − 𝑇𝑟 2 )}]
1 2
2
𝛼𝑆𝑅𝐾 (𝑇𝑟 ; 𝜔) = [1 + {0.480 + 1.574 ∗ 0.1 − 0.176 ∗ 0.1 (1 − 1.0582 )}]
′
𝜶𝑺𝑹𝑲 (𝑻𝒓 ; 𝝎) = 𝟐. 𝟔𝟖𝟏 → (𝒊𝒊𝒊 )
Now
𝜓𝛼(𝑇𝑟 )
𝑞=
Ω𝑇𝑟
0.42748 ∗ 2.681
𝑞=
0.08664 ∗ 1.058
𝒒 = 𝟏𝟐. 𝟓𝟎 → (𝒊𝒊𝒊′ )
Put (i’) and (iii’) in (5)
𝑍−𝛽
𝑍 = 1 + 0.0252 − 12.50 ∗ 0.0252 (𝑍+𝜖𝛽)(𝑍+𝜎𝛽)
Assume
𝒁 = 𝟎. 𝟗𝟎𝟕
0.907 − 0.0252
0.907 = 1.0252 − 0.315
0.907(0.907 + 0.0252)
0.907 = 1.0252 − 0.315 ∗ 1.0429
0.695 = 0.695
Since
𝑳. 𝑯. 𝑺 = 𝑹. 𝑯. 𝑺
Therefore,
𝒁 = 𝟎. 𝟔𝟗𝟓 Answer
We know that
𝑃𝑉
𝑍=
𝑅𝑇
𝑍𝑅𝑇
𝑉=
𝑃
0.695 ∗ 8.314 𝐽 ∗ 298.15 𝐾 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 𝑐𝑚3
𝑉= ∗ ∗ ∗
𝑚𝑜𝑙 ∗ 𝐾 ∗ 12 𝑏𝑎𝑟 𝐽 101325 𝑁 1 𝑚3
𝒄𝒎𝟑
𝑽 = 𝟏𝟒𝟑𝟓. 𝟔 Answer
𝒎𝒐𝒍
(e)
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𝛼𝑆𝑅𝐾 (𝑇𝑟 ; 𝜔) = [1
2 2
+ {0.37464 + 1.54226 ∗ 0.087 − 0.26992 ∗ 0.0872 (1 − 1.056 )}]
Now
𝜓𝛼(𝑇𝑟 )
𝑞=
Ω𝑇𝑟
0.42748 ∗ 2.277
𝑞=
0.08664 ∗ 1.056
𝒒 = 𝟏𝟎. 𝟔𝟒 → (𝒗′)
Put (iv’) and (v’) in (5)
𝑍−𝛽
𝑍 = 1 + 0.0175 − 10.64 ∗ 0.0175 (𝑍+𝜖𝛽)(𝑍+𝜎𝛽)
Assume
𝒁 = 𝟎. 𝟕𝟗𝟑
0.793 − 0.0175
0.793 = 1.0175 − 0.1862
0.793(0.793 + 0.0175)
0.793 = 1.0175 − 0.1862 ∗ 1.2066
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0.793 = 0.793
Since
𝑳. 𝑯. 𝑺 = 𝑹. 𝑯. 𝑺
Therefore,
𝒁 = 𝟎. 𝟕𝟗𝟑 Answer
We know that
𝑃𝑉
𝑍=
𝑅𝑇
𝑍𝑅𝑇
𝑉=
𝑃
0.793 ∗ 8.314 𝐽 ∗ 298.15 𝐾 𝑁 ∗ 𝑚 1.01325 𝑏𝑎𝑟 ∗ 𝑚2 1003 𝑐𝑚3
𝑉= ∗ ∗ ∗
𝑚𝑜𝑙 ∗ 𝐾 ∗ 12 𝑏𝑎𝑟 𝐽 101325 𝑁 1 𝑚3
𝒄𝒎𝟑
𝑽 = 𝟏𝟔𝟑𝟖. 𝟏 Answer
𝒎𝒐𝒍
99