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Yasin Agung Nugroho (15/379025/TK/42967) 20 Februari 2019

Properties

User defined compounds

1. Eugenol

Atom 1 Atom 2
Number Type Number Type Bond type
1 C 2 C Double bond
3 C 1 C Single bond
2 C 7 C Single bond
2 C 9 O Single bond
4 C 3 C Double bond
5 C 4 C Single bond
4 C 6 C Single bond
7 C 5 C Double bond
6 C 11 C Single bond
7 C 8 O Single bond
8 O 10 C Single bond
11 C 12 C Double bond

MW: 164,2011
Normal Boiling point: 254C
SG at 60F: 1,0652
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Yasin Agung Nugroho (15/379025/TK/42967) 20 Februari 2019

2. Caryophyllene

Atom 1 Atom 2
Number Type Number Type Bond type
1 C 4 C Single bond
2 C 1 C Single bond
3 C 2 C Single bond
4 C 5 C Double bond
5 C 9 C Single bond
6 C 7 C Single bond
8 C 7 C Single bond
9 C 8 C Single bond
10 C 3 C Single bond
6 C 11 C Single bond
11 C 10 C Single bond
4 C 12 C Single bond
10 C 13 C Single bond
10 C 14 C Single bond
7 C 15 C Double bond
3 C 6 C Single bond

MW: 204,3511
Normal Boiling Point: 130C
SG at 60F: 0,9075
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Yasin Agung Nugroho (15/379025/TK/42967) 20 Februari 2019

Parameter retrieved

Parameters Units Data set Component EUGENOL Component CARYOPHY

CHARGE 1 0 0

DGFORM CAL/MOL 1 -8522,02159 46964,2687

DGSFRM CAL/MOL 1 0 0

DHAQFM CAL/MOL 1 0 0

DHFORM CAL/MOL 1 -45858,4122 4241,90312

DHSFRM CAL/MOL 1 0 0

DHVLB CAL/MOL 1 13155,9435 8160,48204

DLWC 1 1 1

DVBLNC 1 1 1

HCOM CAL/MOL 1 0 0

HCTYPE 1 0 0

MW 1 164,2011 204,3511

OMEGA 1 0,673309058 0,428076137

OMGPRS 1 0,673309058 0,428076137

PC BAR 1 35,0957975 20,2722934

PCPRS BAR 1 35,0957975 20,2722934

PRSZRA 1 0,227925753 0,250946301

RHOM GM/CC 1 0 0

RKTZRA 1 0,227925753 0,250946301

S025E CAL/MOL-K 1 0 0

SG 1 1,0652 0,9075

TB C 1 254 130

TC C 1 462,766942 287,930771

TCPRS C 1 462,766942 287,930771

TREFHS C 1 25 25

VB CC/MOL 1 141,62145 220,573749

VC CC/MOL 1 452,5 716,5

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Yasin Agung Nugroho (15/379025/TK/42967) 20 Februari 2019

VCRKT CC/MOL 1 452,5 716,5

VLSTD CC/MOL 1 110,19875 187,554254

ZC 1 0,259547972 0,311362592

ZWITTER 1 0 0
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Yasin Agung Nugroho (15/379025/TK/42967) 20 Februari 2019

Simulation

Caryophyllene

B1

Eugenol

Summary

Minimum reflux ratio: 2,4953105

Actual reflux ratio: 4,99062

Minimum number of stages: 2,88015634

Number of actual stages: 4,17932678

Feed stage: 4,35446667

Number of actual stages above feed: 3,35446667

Reboiler heating required: 126716,424 cal/sec

Condenser cooling required: 316006,019 cal/sec

Distillate temperature: 131,411695 C

Bottom temperature: 250,149127 C

Distillate to feed fraction: 0,157

HETP:

Balance

Total Units In Out Rel. diff

Mole-flow kmol/hr 100 100 0

Mass-flow kg/hr 17022,36 17022,36 2,13717652E-16

Enthalpy cal/sec -853207,02 -1042496,62 0,181573343

Tugas Perpros
Yasin Agung Nugroho (15/379025/TK/42967) 20 Februari 2019

Results Summary

Name B1

Property method PENG-ROB

Henry's component list ID

Electrolyte chemistry ID

Use true species approach for electrolytes YES

Free-water phase properties method STEAM-TA

Water solubility method 3

Number of stages

Reflux ratio 4,99062

Light key component recovery 0,99

Heavy key component recovery 0,01

Distillate vapor fraction 0

Minimum reflux ratio 2,4953105

Actual reflux ratio 4,99062

Minimum number of stages 2,88015634

Number of actual stage 4,17932678

Feed stage 4,35446667

Number of actual stage above feed 3,35446667

Distillate temperature 131,411695

Distillate to feed fraction 250,149127

Total feed stream CO2e flow 0

Total product stream CO2e flow 0

Net stream CO2e production 0

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Yasin Agung Nugroho (15/379025/TK/42967) 20 Februari 2019

Stream Results

FEED CARYOPHY EUGENOL

Substream: MIXED

Mole Flow kmol/hr

EUGENOL 85 0,85 84,15

CARYOPHY 15 14,85 0,15

Total Flow kmol/hr 100 15,7 84,3

Total Flow kg/hr 17022,36 3174,185 13848,18

Total Flow l/min 34393,39 56,24631 198,1889

Temperature C 238,9628 131,4117 250,1491

Pressure bar 1 1 1

Vapor Frac 0,5 0 0

Liquid Frac 0,5 1 1

Solid Frac 0 0 0

Enthalpy cal/mol -30715,45 1585,251 -44814,66

Enthalpy cal/gm -180,4418 7,840891 -272,8068

Enthalpy cal/sec -853210 6913,455 -1049400

Entropy cal/mol-K -104,397 -138,1513 -115,5532

Entropy cal/gm-K -0,6132931 -0,6833172 -0,7034238

Density mol/cc 4,84589E-05 0,00465216 0,0070892

Density gm/cc 0,00824885 0,940561 1,16456

Average MW 170,2236 202,1774 164,2725

Liq Vol 60F l/min 203,0035 47,98083 155,0226

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Yasin Agung Nugroho (15/379025/TK/42967) 20 Februari 2019

FEED

Distillation Tower