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GHS

A guide to Globally Harmonized System (GHS)


chemical labeling standards
1. Introduction . . . . . . . . . . . . . . . . . . . . .4

2. Participating Countries . . . . . . . . . . . . . . 5 Creative Safety Supply is a global


supplier of Safety and Lean products
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3. Timeline . . . . . . . . . . . . . . . . . . . . . . .6 such as LabelTac® Label & Sign Printers
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4. Important Dates . . . . . . . . . . . . . . . . . . 7 wide selection of floor signs, wall signs and
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5. Hazard Classifications & Categories . . . . . . .8 CSS also bridges the gap between
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6. GHS Safety Data Sheets (SDS) . . . . . . . . . . 9 or employees looking to learn more
about Safety, Lean Manufacturing, GHS,
Continuous Improvement and other topics.
7. GHS Label Elements . . . . . . . . . . . . . . . 10
Hundreds of Innovative
8. Creating GHS Labels . . . . . . . . . . . . . . . 17 Products and Solutions

9. Additional Resources . . . . . . . . . . . . . . 20 Knowledgeable Staff

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LEGAL DISCLAIMER
All contents copyright © 2015 by Creative Safety Supply. All rights reserved. No part of this document or accompanying files may be reproduced
or transmitted in any form, electronic or otherwise, by any means without the prior written permission of the publisher.

This ebook is presented to you for informational purposes only and is not a substitution for any professional advice. The contents herein are
based on the views and opinions of the author and all associated contributors.

While every effort has been made by the author and all associated contributors to present accurate and up-to-date information within this
document, it is apparent technologies rapidly change. Therefore, the author and all associated contributors reserve the right to update the
contents and information provided herein as these changes progress. The author and/or all associated contributors take no responsibility for any
errors or omissions if such discrepancies exist within this document.

The author and all other contributors accept no responsibility for any consequential actions taken, whether monetary, legal, or otherwise, by any
and all readers of the materials provided. It is the readers sole responsibility to seek professional advice before taking any action on their part.

Readers’ results will vary based on their skill level and individual perception of the contents herein, and thus no guarantees, monetarily or
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Introduction
What is GHS? Why now?
The Globally Harmonized System of Classification The UN published the first edition of the GHS
and Labeling of Chemicals (GHS) is a method in 2003, but these changes to chemical hazard
developed by the United Nations for communicating communication are just beginning to go into effect
chemical hazards. Under this system, chemical in the United States. The Occupational Safety and
containers must all display a specific label. This Health Administration (OSHA) integrated GHS into
label helps facilitate the safe shipping and use of its Hazard Communication Standard (HazCom)
hazardous substances. in 2012, and the new regulations are currently
being implemented by manufacturers, importers,
Before GHS, inconsistencies in labeling made distributors, and employers.
exporting and importing chemicals a challenge.
Countries were each using their own labeling system. The GHS unifies several important aspects of
The lack of international standards increased the communicating about hazardous chemicals. In
risk of accidents because recipients of chemical addition to standardizing the format and contents of
shipments could not quickly recognize the hazards labels on chemical containers, the system requires
presented by their packages. As a result of differing the use of a Safety Data Sheet, which includes
labeling from country to country, shipping costs specific, detailed information about a chemical, its
also rose for many companies as the global trade of hazards, and relevant first aid measures.
chemicals grew.
The GHS also creates standardized hazard
The GHS aims to eliminate this confusion by classifications that make it easier for those handling
providing clear guidelines for chemical labeling that these chemicals to understand what physical and
can be used across borders. health risks are associated with them.

GHS Labeling Guide | creativesafetysupply.com 4


Participating 70 participating countries (2014)

Countries Argentina Guatemala Peru


Australia Hungary Philippines
The GHS is not a legal requirement, but many
Austria Iceland Poland
countries are choosing to adopt this new standard
because it simplifies the transport and storage of Belgium Indonesia Portugal
chemicals. Those involved in the chemical trade Bolivia Ireland Romania
will no longer need to create multiple labels and Brazil Italy Russia
information sheets to sell their products to more than
Brunei Japan South Korea
one country.
Bulgaria Kyrgyzstan Senegal
The chemical business worldwide amounts to Cambodia Lao P.D.R. Serbia
more than $1.7 trillion annually, and in the U.S. it Canada Latvia Singapore
is a $450 billion industry. Consider the fact that Chile Liechtenstein Slovakia
OSHA estimates the GHS will save the country $585
China Lithuania Slovenia
million annually in productivity improvements and
$266 million related to reduced safety risks, and the Colombia Luxembourg South Africa
changes seem more than worthwhile. Cyprus Madagascar Spain
Czech Republic Malaysia Sweden
Additionally, the changes will prevent 43 deaths and D.R. of Congo Malta Switzerland
585 work-related injuries and illnesses in the U.S.
Denmark Mauritius Thailand
each year, according to OSHA.
Ecuador Mexico United Kingdom
Not all countries will adopt the GHS standards in Estonia Myanmar USA
the exact same way, but the UN does mandate Finland Netherlands Uruguay
that countries use the same basic components France New Zealand Vietnam
of the standard if they choose to adopt it: hazard
Gambia Nigeria Zambia
classifications, safety data sheets, and labels.
Germany Norway
Greece Paraguay

GHS Labeling Guide | creativesafetysupply.com 5


Timeline
1992 Later that year the 1st revised edition of the GHS
was adopted by the Committee of Experts.
The Globally Harmonized System (GHS) was
mandated at the United Nations Conference 2007
on Environment and Development (UNCED) to
internationally standardize classification and The 2nd revised edition of the GHS was published
labeling of chemicals. (included standardized precautionary measures).

2002 2009
Countries were encouraged to implement the new OSHA published a proposal to modify the Hazard
GHS as soon as possible, with a goal of having Communication Standard to conform with the
a fully operational system by 2008. In December GHS.
2002, the UN approved the 1st edition of the GHS
standards. 2011
OSHA released the final ruling on the updated
2003 Hazard Communication Standard.
The 1st edition of the GHS was published and
made available for implementation. 2012
The Office of Management and Budget
2004 concluded its review of OSHA’s revised Hazard
In December 2004, amendments to the GHS were Communication Standard, incorporating GHS
adopted at the 2nd session of the Subcommittee principles. OSHA passed its final ruling updating
of Experts. Amendments included revisions the Hazard Communication Standard to align with
on classification and labeling, new rules for the United Nations’ Globally Harmonized System
aspiration hazards and precautionary statements, (GHS) of Classification and Labeling of Chemicals.
pictograms, and preparation of safety data sheets.
2015
2005 E.U. current directives on classification, labeling,
OSHA Published an Advanced Notice of Proposed and packaging will be repealed (May 31).
Rulemaking and opened it to public comments. Expected E.U. deadline for mixture reclassification
after entry into force (June 1).

GHS Labeling Guide | creativesafetysupply.com 6


Important Dates
The GHS has been rolling out globally for years,
but has just begun to impact businesses in the
United States. Below is a list of relevant GHS
implementation dates that will be enforced by
OSHA. Keep in mind that it’s advisable to begin
implementing the GHS requirements sooner rather
than later, as the changeover will take time and effort.

Dec. 1, 2013 June 1, 2015 Dec. 1, 2015 June 1, 2016


What: Train employees What: Comply with What: Shall not ship What: Update workplace
on new label all final rule products labeled labeling and
requirements and provisions but by chemical HazCom
safety data sheet may ship products manufacturers or programs and
(SDS) format. labeled under the importers unless train employees
Who: Employers old system until the labels comply on newly identified
December 1, 2015. with GHS. physical or health
hazards.
Who: Chemical Who: Distributors
manufacturers, Who: Employers
importers,
distributors, &
employers !

Up to the effective completion dates, chemical manufacturers, importers, distributors, and employers may comply with either
29 CFR 1910.1200 (the final standard), the current standard, or both.

GHS Labeling Guide | creativesafetysupply.com 7


Hazard Flammables
Explosives Flammable Gases
Classifications & Flammable Aerosols Oxidizing Gases

Categories Gases Under Pressure


Flammable Solids
Flammable Liquids
Self-Reactive Substances
A main purpose of the new GHS is to standardize Pyrophoric Liquids Pyrophoric Solids
the types of chemical hazards that exist and the way
entities in the chemical industry classify chemicals Substances which, in
that have those hazards. To that end, the GHS names Self-Heating Substances contact with water emit
three main hazard groups: physical, health, and flammable gases
environmental. Oxidizing Liquids Oxidizing Solids
-Physical hazards pose a threat that could injure Organic Peroxides Corrosive to Metals
people or damage property. For example, a gas
might explode, causing physical damage.
Health Hazards
-Health hazards impact human health by causing
irritating symptoms or even deadly diseases. Acute Toxicity Carcinogenicity
Skin Corrosion/Irritation Reproductive Toxicity
-Environmental hazards negatively impact aquatic
environments. Serious Eye Damage/Eye Target Organ Systemic
Irritation Toxicity- Single Exposure
Each general group is divided up into more specific
classes, and each class into even more specific Respiratory or Skin Target Organ Systemic
categories. (Details about the classes and categories Sensitization Toxicity- Repeat Exposure
can be found in the GHS Purple Book.)
Germ Cell Mutagenicity Aspiration Toxicity
The following classes are used by the GHS:
Environmental Hazards
Acute Aquatic Toxicity Chronic Aquatic Toxicity

GHS Labeling Guide | creativesafetysupply.com 8


GHS Safety Data
Sheets (SDS)
Previously called MSDS (Material Safety Data Sheets) All chemicals that are shipped should have included
under the old OSHA HazCom standards, Safety Data with them a SDS for every unique substance or
Sheets are a critical part of GHS and are designed to mixture from the manufacturer or distributor. The first
communicate complete information about a chemical two sections of the SDS, Identification and Hazard(s)
or mixture and how to mitigate any issues with Identification, contain all the information about a
handling or storage. Additionally, first aid procedures substance that is required to create a GHS label.
are listed in case of accidental exposure.

Information on the SDS should include these


categories/headers, and in this order:
1. Identification
2. Hazard(s) identification
3. Composition/information on ingredients
4. First-aid measures
5. Fire-fighting measures
6. Accidental release measures
7. Handling and Storage
8. Exposure controls/personal protection
9. Physical and chemical properties
10. Stability and reactivity
11. Toxicological information
12. Ecological information
13. Disposal considerations
14. Transport information
15. Regulatory information
16. Other information

GHS Labeling Guide | creativesafetysupply.com 9


GHS Label Elements
1 Product Identifier

PENTANE
Name or number used for a
hazardous product on a label or
1 in the SDS
5 CAS 109-66-0

DANGER 2
2 Signal Words
“Danger” or “Warning” are
used to emphasize hazards
Extremely flammable gas. Contains gas under pressure.
and indicate the relative level of
May explode if heated. Gas may reduce oxygen in 3 severity of the hazard assigned to
confined spaces.
a GHS hazard class and category
Keep away from heat/spark/open flames/hot surfaces. No
smoking. Protect from sunlight. Store in a well-ventilated
place. Hazard Statements
Leaking gas fire: Do not extinguish, unless leak can be
3 Standard phrases assigned to a
stopped safely. Eliminate all ignition sources if safe to do so. hazard class and category that
describe the nature of the hazard
Eye contact: For liquified gas, flush eyes with lukewarm water,
Seek immediate attention. 4
Skin contact: Liquified gases may cause cryogenic burns. Precautionary
Treat burned or frostbitten skin by flushing or immersing the 4 Statements
affected area(s) in lukewarm water. Do not rub affected area.
Measures to minimize or prevent
Inhalation: If respiratory systems develop, move victim away adverse effects
from source of exposure and into fresh air. Seek medical
attention.
GHS Pictograms
Company XYZ | 7131 SW Warren Ave., Bangor ME 04401 | (207) 212-4815 6 5 Standardized set of symbols
which convey health, physical,
and environmental hazard
information

6 Supplier Identification
The prescribed symbols, signal words, and hazard statements can be readily selected from Annex 1 Company name, address, and
of the GHS Purple Book. These standardized elements are not subject to variation, and should appear phone number should be listed on
the label
on the GHS label as indicated in the GHS for each hazard category or class in the system. The use of
symbols, signal words, or hazard statements other than those that have been assigned to each of the
GHS hazards would be contrary to harmonization.

GHS Labeling Guide | creativesafetysupply.com 10


GHS Packaging Pictograms
Pictograms graphically represent a chemical’s
hazards. The pictograms used for GHS packaging Flammables
labels are built out of two elements: a red diamond
This symbol is used for:
and a black image. The space between these two
elements should be white. • Flammable gases (cat. 1)
• Flammable aerosols (cat. 1, 2)
When chemicals are shipped in boxes or other larger
containers, these 9 pictograms should be placed • Flammable liquids (cat. 1, 2, 3)
on the inner packaging inside the boxes. Transport • Flammable solids (cat. 1, 2)
pictograms (see page 15) should be placed on outer • Self-reactive substances and
packaging such as boxes or shipping containers. mixtures (types B, C, D, E, F)
• Pyrophoric liquids (cat. 1)
• Pyrophoric solids (cat. 1)
Oxidizing • Self-heating substances and
This symbol is used for: mixtures (cat. 1, 2)
• Oxidizing gases (cat. 1) • Substances and mixtures,
• Oxidizing liquids (cat. 1, 2, 3) which in contact with water,
emit flammable gases (cat. 1, 2, 3)
• Oxidizing solids (cat. 1, 2, 3)
• Organic peroxides (types B, C, D,
E, F)

Explosive
Corrosive
This symbol is used for:
This symbol is used for:
• Unstable explosives
• Corrosive to metals (cat. 1)
• Explosives (divs. 1.1, 1.2, 1.3, 1.4)
• Skin corrosion (cat. 1A, 1B, 1C)
• Self-reactive substances and
mixtures (types A, B) • Serious eye damage (cat. 1)
• Organic peroxides (types A, B)

GHS Labeling Guide | creativesafetysupply.com 11


NOTE: The Irritant pictogram should not be used in
Irritant conjunction with the Toxic pictogram; -OR- for skin
This symbol is used for: or eye irritation if either the Corrosive pictogram
also appears, or if the Health Hazard pictogram is
• Acute toxicity (oral, dermal, used to indicate respiratory sensitization.
inhalation) (cat. 4)
• Skin irritation (cat. 2, 3)
• Eye irritation (cat. 2A)
• Skin sensitization (cat. 1)
Toxic
• Specific target organ toxicity This symbol is used for:
following single exposure (cat. 3) • Acute toxicity (oral, dermal,
• Respiratory tract irritation inhalation) (cat. 1, 2, 3)
• Narcotic effects

Health Hazard
Compressed Gas
This symbol is used for:
This symbol is used for:
• Respiratory sensitization
(cat. 1)
• Compressed gases
• Germ cell mutagenicity • Liquefied gases
(cat. 1A, 1B, 2) • Refrigerated liquefied gases
• Carcinogenicity (cat. 1A, 1B, 2) • Dissolved gases
• Reproductive toxicity
(cat. 1A, 1B, 2)
• Specific target organ toxicity Environmentally
following single exposure Damaging
(cat. 1, 2)
This symbol is used for:
• Specific target organ toxicity
following repeated exposure • Acute hazards to the aquatic
(cat. 1A, 1B, 2) environment (cat. 1)
• Aspiration hazard (cat. 1, 2) • Chronic hazards to the aquatic
environment (cat. 1, 2)

GHS Labeling Guide | creativesafetysupply.com 12


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Transport Pictograms
Transport pictograms use a wider variety of colors Explosives (cont’d)
than packaging pictograms and are designed to • Division 1.5: Very insensitive substances which
communicate what chemicals are carried by a have a mass explosion hazard
vehicle. Additional information such as subcategory
numbers may be required. • Division 1.6: No hazard statement

These pictograms should be placed on outer Class 2: Gases


packaging. On large containers that do not contain
inner packaging, place both a transport pictogram Flammable Gases
and a GHS label.
• Gases having a flammable range
Class 1: Explosives with air at 20°C and a standard
pressure of 101.3 kPa.
Explosives
The symbol, number and border line may be shown in white instead of black.
• Division 1.1: Substances and
articles which have a mass
explosion hazard Non-Flammable,
Non-Toxic Gases
• Division 1.2: Substances and Layout for
articles which have a projection divisions 1.1-1.3 • Gases which are asphyxiant,
hazard but not a mass explosion oxidizing, or do not come under
hazard any other divisions.
• Division 1.3: Substances and The symbol, number and border line may be shown in white instead of black.
articles which have a fire hazard
and either a minor blast hazard or Toxic Gases
a minor projection hazard or both,
but not a mass explosion hazard Layout for • Gases which are known to be so
divisions 1.4-1.6 toxic or corrosive to humans as
• Division 1.4: Substances and to pose a hazard to health; or are
articles which are classified as presumed to be toxic or corrosive
explosives but which present no to humans because they have an
significant hazard LC50 value equal to or less than
5000 (ppm).

GHS Labeling Guide | creativesafetysupply.com 14


Class 3 and 4: Flammable Liquids and Solids
Substances which in contact
Flammable Liquids with water emit flammable
• Liquids which have a flash point gases
of less than 60 °C and which are • Substances which, by interaction
capable of sustaining combustion 3 with water, can become
spontaneously flammable or give
The symbol, number and border line may be shown in white instead of black. off flammable gases in dangerous
quantities
Flammable solids, self- The symbol, number and border line may be shown in white instead of black.

reactive substances and solid


desensitized explosives
Other GHS Transport Classes
• Solids which, under conditions
encountered in transport, are Oxidizing Substances
readily combustible or may cause
or contribute to fire through • Substances which, although not
friction; self-reactive substances necessarily combustible, can,
which are liable to undergo a through yielding oxygen, cause or
strongly exothermic reaction; solid contribute to the combustion of
desensitized explosives which may other material
explode if not diluted sufficiently

Organic Peroxides
Substances liable to • Organic substances which contain
spontaneous combustion the bivalent –O–O– structure and
may be considered derivatives of
• Substances liable to spontaneous
hydrogen peroxide, where one or
heating under normal conditions
both of the hydrogen atoms have
encountered in transport, or to
been replaced by organic radicals
heating up in contact with air and
then being liable to catch fire The symbol, number and border line may be shown in white instead of black.

GHS Labeling Guide | creativesafetysupply.com 15


Toxic Substances
• Substances with an LD50 value ≤
300 mg/kg (oral) or ≤ 1000 mg/kg
(dermal) or an LC50 value ≤ 4000 6
ml/m3 (inhalation of dusts or mists)

Corrosive Substances
• Substances which cause full
thickness destruction of intact skin
tissue on exposure time of less
than 4 hours; or exhibit a corrosion
rate of more than 6.25 mm per
year on either steel or aluminium
surfaces at 55 °C

Additional information about hazard categories,


pictograms, transport pictograms, and other
components of GHS can be found in the “GHS
Purple Book” or online through OSHA’s website at
https://www.osha.gov/dsg/hazcom/ghs.html

GHS Labeling Guide | creativesafetysupply.com 16


Creating GHS Labels
There are several options to create or acquire GHS per chemical with the required chemical information
labels for marking your chemicals. found in the chemical’s SDS sheet, submit it, and the
company will print the label for you and ship to your
facility.
NOTE: When creating GHS labels, the only given
regulation is that the hazard pictograms, signal
word, and hazard statements should be located
together on the label. Aside from this, the label Printing Paper GHS Labels
format or layout is not actually specified by GHS.

PROS: Inexpensive, utilize existing equipment, print on


demand, can save files for later quick recall
The three most common GHS labeling options are:
CONS: Not durable, requires extra protection from
• Order labels from a safety company water, wear and chemical damage, not practical
for smaller containers/labels
• Print your own paper labels from an inkjet or laser
printer
• Print your own labels using a thermal transfer Another option for creating GHS labels is to utilize an
printer (recommended) existing inkjet or laserjet printer to print labels onto
standard paper.

Ordering GHS Labels The obvious major downside to this is the durability
of paper labels. Because of the nature of GHS, GHS
labels are around chemicals- and a small amount
PROS: No equipment needed of certain chemicals or even water could obscure
CONS: High cost per label, wait time for delivery, or destroy the label. Additionally, ink on paper
impractical for high volume and/or repeat need exposed to UV will often fade and lose visibility, and
depending on the print method, these labels can
For companies with a limited need for GHS labels, wear very easily with contact.
ordering GHS labels from a catalog or website can
be a viable option. Some of these downfalls can be mitigated by
protecting the labels with heavy duty plastic sleeves
Typically you can fill out a printed or online order form or another protective means, but this often can be
difficult to do with smaller label sizes.

GHS Labeling Guide | creativesafetysupply.com 17


Printing GHS Labels with a
Thermal Transfer Printer
Using your SDS, simply copy and paste, or manually
PROS: Highly durable, weatherproof, chemical/UV/ enter the required information into the correct fields
water/wear resistant, can save files for later
and print your label(s). Any thermal transfer printer
quick recall, low cost per label vs ordering, print
on demand capable of printing GHS labels should have the
functionality to save labels so you can print them
CONS: Requires a thermal transfer printer
again later on.

By far, the most ideal option for creating GHS labels


is through the use of a thermal transfer printer.
Because of their superior lifespan and low cost per
label, for most companies dealing with a lot of GHS
labels, having a thermal transfer printer in-house
ends up being the easiest and most cost-effective
way to create these labels.

Thermal transfer printers connect to any PC but are


different than inkjet or laserjet printers in that instead
of laying ink on top of a paper surface, thermal
transfer printers work by heating a print ribbon resin
and thermally bonding it to a material, usually an
industrial vinyl. Through this method, you create
weatherproof labels capable of lasting many years-
even outdoors- without fading, smearing or wearing
away.

Although most thermal transfer printers are


monocolor systems (1 color at a time), many
companies that offer thermal transfer printers can
For additional information about LabelTac®
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