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Stephen P. Ruis
Skyline College, San Bruno. CA 94066
A comment made in a review of General, Organic, and mathematical skills to understand the model. I can onlv
Biological Chemistry by Feigl and Hill in this Journal com- conclude that quantum numhers have no meaning or value
pels me to respond.' The reviewer's comment regarding this for beginning chemistry students. A substantial introduc-
health sciences chemistry text was "In Chapter 2, for exam- tion to quantum numbers actually presents a barrier, rather
ple, the discussion of atdmic structure totally neglects even than an aid. to understanding atomic behavior. A mere men-
to mention the origin and significance of quantum numhers, tion of quantum numbers in-a text can only appear to be a
let alone define them." sop tossed to those chemistry professors who demand such
On the surface this statement seems rather innocuous and mentions; I can't believe there is educational value in just
common. On the contrary, I think there are two significant mentioning any term or concept.
issues, one specific and one general, raised by this statement. If not quantum numbers, then what? What needs to he
In specific, I question the use of quantum numbers not only taught to provide an appropriate theoretical base for hegin-
with health science chemistry students but with all begin-
ning chemistry students. In general, I feel that such state-
-
ning chemistrv students? What is imoortant for heeinnina-
students to understand is that the energies of atomic elec-
ments are indicative of the general state of mind of chemis- trons are measurable. The measured eneraies - indicate that
try teachers and that state of mind is having an adverse electron energies are quantized. And the periodic table
impact on the quality of textbooks. My criticism is not di- makes it abundantly clear that a primary factor in chemical
rected a t the reviewer but at all of us because I think we are and physical behavior of the elements is simply the number
all somewhat guilty of the mistakes I am addressing. of highest energy (valence) electrons in their atoms.
This paradigm is easily grasped by students because they
The Value of Quantum Numbers to Beginning Students intuitivelv understand that the highest enerav electrons in
The Task Force on Chemical Education for Health Pro- an atom are found furthest from thk nucleus &d the farther
fessionals recentlv oublished a svllabus for the course to electrons are from their own nucleus, the closer they are to
which the Feigl and- ill text is dl'rected.2 Nowhere do they other nuclei that might influence them. understanding this
even mention, nor do they exclude, discussion of quantum ureuares the around for discussion of the Lewis theory of
numhers. They do state though, that "Many of them (stu- chemical bonding and for more technical treatments~en-
dents of this course) are ooorlv
. .. prepared
. for chemistry and countered in subsequent chemistry courses.
particularly for the mathematical part of our science." Why then do many of us insist on the inclusion of discus-
I believe that an honest description of quantum numhers sions of quantum numbers and similar esoterica in our text-
is that they are partial, approximate solutions of an equa- books even when doing so is clearly inappropriate? I can't
tion that approximately describes the energies of atomic answer this question, but asking it brings me to my second
electrons. The equation stems from a desire to create a point-the impact this general state of mind has on the
mathematical model of atoms, and it requires mathematical quality of chemistry textbooks.
knowledge beyond that possessed by health science chemis-
try students, general chemistry students, and most (if not The Quality of Chemistry Textbooks
all) college freshmen. On this basis, quantum numbers can The reviewer's comment points to one of a body of topics
only be used descriptively as part of an explanation of atom- that have become sacred to chemistry teachers. I have often
ic behavior. But to be used in this manner, quantum num- heard the comment, "I could never teach out of a text that
bers must he understood in the context of the-mathematical didn't include. . . [fill in any pet topic here]." I perceive that
model. This is a Catch-22-the students lack the necessary we, as a group, have developed a very narrow view of what is
acceptable in chemistry texts and that narrow view restricts
our ability to teach. It is us who write, review, and finally
' J. Chem. Educ. 1987,64. A327-A328 order the textbooks for our students. Texts that don't con-
J. Chem. Educ. 1984,61,620-621. form to the norm get poor reviews. Texts that don't conform