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code=1110

Emerits Softwares

Subject: CHEMISTRY Branch: Head Office

Date: 13 Dec 2018 Marks: 70

SECTION - A

1 The number of ions formed when cuproammonium sulphate is dissolved in 01

water is:
[a] 1 [b] 2 [c] 4 [d] Zero

2 A terpene, Caryophyllene is found in 01

[a] Oil of turpentine [b] Oil of roses
[c] Oil of ginger [d] Oil of cloves

constant 01
3 The value of constant inNernst eqution E= E0 − In Q at 25°C is
n
(a) 0.0592 m V (b) 0.0592 V
(c) 25.7 m V (d) 0.0296 V

4 Insulin is 01
[a] Harmone [b] Antibiotic
[c] Antiseptic [d] Vitamin

5 Define: Molality. 01

6 Write IUPAC name of compound Isopropyl bromide 01

7 Explain a solid solution. 01

8 Define Proteins. 01

SECTION - B

9 Write the structure and give IUPAC name of following carboxylic acid 02
β− phenylbutyric acid

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OR
Calculate mole fraction of HCl in solution of HCl containing 24.8% of HCl by
mass. (H = 1, Cl = 35.5)

10 How does the equation, ∆G° =- nFE ° explain that an electrical potential is an 02
intensive property?

11 How is phosphine prepared? 02

12 The vapour pressure of 2.1 % solution of a non-electrolyte in water at 100 °C 02

is 755 mm Hg. Calculate the molar mass of the solute. (58.69 g cm −1)

13 Explain the term leaching. 02

14 Three moles of an ideal gas are expanded isothermally from a volume of 02

300 cm 3 to 2.5 L at 300 K against a pressure at 1.9 atm. Calculate the work done
in L atm and joules.

15 ∆G° for a redox reaction depends on the number of electrons transferred. 02

Explain.

SECTION - C

16 What are the limitations of V.B.T.? 03

17 A sample of gas absorbs 4000 kJ of heat (a) if volume remains constant 03

what is ∆U ? (b) Suppose that in addition to absorption of heat by the sample,
the surroundings does 2000 kJ of work on the sample. What is ∆U ? (c) Suppose
that as the original sample absorbs heat, it expands against atmospheric
pressure and does 600 kJ of work, on its surroundings what is ∆U ?

18 Derive the integrated rate law for first order reaction A → products. 03
OR
A solution used in hand lotion is prepared by mixing 90 g of H2 O, 9.2 g of
C2H5OH and 2.3 g of glycerol (C2H8O3) . Calculate the mole fraction of glycerol
present in it.

19 The gaseous reaction A 2 → 2A is first order in A 2 . After 12.3 minutes 65% of 03

A 2 remains undecomposed. How long will it take to decompose 90% of A 2 ?
What is the half life of the reaction?

20 How will you obtain Butanal -2 ol from: 03

(1) propanal (2) Butan-2-one (3) But-2-ene?

21 Explain lock and key fitting of substrate and enzyme and also drug and 03
enzyme.

03

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22 Arrange the following compounds in the decreasing order of the solubility in

water.

23 Explain the mechanism of cleansing action of soaps and detergents. 03

[Mar.13] [Oct 13]

24 Which species in each of the following pairs is better reducing agent under 03
standard state conditions? E° values are given. Give reasons for your answer :
( a) K (s) (−2 . 93 V) or Mg (s) (−2 . 36 V)
+ (1 . 81 V) or ln(s) (−0 . 14 V)
(b) CO2(aq)
+ (1 . 61 V) or Ti2 + (−0 . 37 V)
( c) Ce3(aq)
(d) Hg(l) (0 . 86 V) or Ni(s) (−0 . 23 V)

25 The following results were obtained in the decomposition of H2O2 in KI 03

solution at 30°C .
t/s 100 200 300 ∞
Volume of O2 7.3 13.9 19.6 65.0
collected/cm3
Show that the reaction is first order. Calculate the rate constant of the reaction.

26 A certain reaction occurs in the following steps: 03

( i) Cl (g) + O3(g) →ClO (g) + O2(g)
( ii) ClO (g) + O(g) →Cl (g) + O2(g)
(1) Write the chemical equation for overall reaction.
(2) Identify the reaction intermediate.
(3) Identify the catalyst.

SECTION - D

27 Write the structures and IUPAC names of all isomers of carboxylic acids 05
having molecular formula C5H10O2. How many of them are chiral ?
OR
State the type of hybridisation, magnetic behaviour, possible d-d transitions
and inner orbital or outer orbital octahedral complex in following examples.
(1) ⎢⎢ V (H2O) 6 ⎥⎥ 3+
⎡ ⎤
⎣ ⎦
⎤⎥ 3˘
(2) ⎢ Cr (CN) 6 ⎥
⎡⎢
⎣ ⎦
(3) ⎢ Co(NH3) 6 ⎥⎥ 3+
⎡⎢ ⎤
⎣ ⎦
⎤⎥ 3˘
(4) ⎢ Fe(CN) 6 ⎥
⎡⎢
⎣ ⎦

28 Explain the methods used to preserve the food. 04

OR
State the type of hybridisation, magnetic behaviour, possible d-d transitions
and inner orbital or outer orbital octahedral complex in following examples.
(1) ⎢⎢ V (H2O) 6 ⎥⎥ 3+
⎡ ⎤
⎣ ⎦
⎤⎥ 3˘
(2) ⎢ Cr (CN) 6 ⎥
⎡⎢
⎣ ⎦
(3) ⎢ Co(NH3) 6 ⎥⎥ 3+
⎡⎢ ⎤
⎣ ⎦
⎤⎥ 3˘
(4) ⎢ Fe(CN) 6 ⎥
⎡⎢
⎣ ⎦

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29 Predict whether, 05
(a) Ag+ can oxidize Pb to Pb 2+ understandard state conditions.
E°Ag = 0.799 V and E°Pb = − 0.126 V

(b) Cu2+ can oxidixe Cd to Cd2+

under standard state conditions.
E°cu = 0.337 V, E°cd = − 403 V
OR
State the type of hybridisation, magnetic behaviour, possible d-d transitions
and inner orbital or outer orbital octahedral complex in following examples.
(1) ⎢⎢ V (H2O) 6 ⎥⎥ 3+
⎡ ⎤
⎣ ⎦
⎤⎥ 3˘
(2) ⎢ Cr (CN) 6 ⎥
⎡⎢
⎣ ⎦
(3) ⎢ Co(NH3) 6 ⎥⎥ 3+
⎡⎢ ⎤
⎣ ⎦
⎤⎥ 3˘
(4) ⎢ Fe(CN) 6 ⎥
⎡⎢
⎣ ⎦

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