Documente Academic
Documente Profesional
Documente Cultură
AND PERIODICITY
(General Chemistry I; Lecture 03)
NELSON M. PANAJON
Department of Chemistry
Central Luzon State University
ATOMIC THEORY OF MATTER
Early theories on atomic structure:
Democritus (460–370 BC) – proposed that the
world was made of two things: (1)
empty space and (2) fine but indivisible
particles called atomos
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GENERAL CHEMISTRY
Lecture 03 page 2
ATOMIC THEORY OF MATTER
Early theories on atomic structure:
Aristotle (384-322 BC) – proposed that matter
is a continuum and not made up of
smaller particles like atomos
– further proposed that nature is
composed of earth, air, fire and water
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GENERAL CHEMISTRY
Lecture 03 page 3
ATOMIC THEORY OF MATTER
Early theories on atomic structure:
Ludacris (95-55 BC) – described matter as
bodies composed of empty space that
allows movement
Robert Boyle – pushed on the
discontinuous view of matter which is
made up of particles
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GENERAL CHEMISTRY
Lecture 03 page 4
ATOMIC THEORY OF MATTER
Early theories on atomic structure:
John Dalton (1766–1844 AD) –
refined the atomic view of
matter thru his Dalton’s
Atomic Theories
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John Dalton GENERAL CHEMISTRY
Lecture 03 page 5
ATOMIC THEORY OF MATTER
Early theories on atomic structure:
Dalton’s Atomic Theories
1. Each element is composed of
extremely small particles called
atoms.
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John Dalton GENERAL CHEMISTRY
Lecture 03 page 6
ATOMIC THEORY OF MATTER
Early theories on atomic structure:
Dalton’s Atomic Theories
2. All atoms of a given element are
identical but they differ from
one element to another with
different properties.
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John Dalton GENERAL CHEMISTRY
Lecture 03 page 7
ATOMIC THEORY OF MATTER
Early theories on atomic structure:
Dalton’s Atomic Theories
3. Atoms of one element cannot be
changed into atoms of a
different element.
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John Dalton GENERAL CHEMISTRY
Lecture 03 page 8
ATOMIC THEORY OF MATTER
Early theories on atomic structure:
Dalton’s Atomic Theories
4. Compounds are formed when
atoms of more than one
element combine; with the
same relative number and kind
of atoms.
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John Dalton GENERAL CHEMISTRY
Lecture 03 page 9
ATOMIC THEORY OF MATTER
Dalton’s Atomic Theory
– explains several simple laws of chemical
combinations:
Law of Definite (or Constant)
Composition
Law of Conservation of Matter
Law of Multiple Proportions
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GENERAL CHEMISTRY
Lecture 03 page 10
ATOMIC THEORY OF MATTER
Dalton’s Atomic Theory
– explains several simple laws of chemical
combinations:
Law of Definite (or Constant)
Composition
– states that in a given compound, the
kinds and relative numbers of atoms are
constant
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GENERAL CHEMISTRY
Lecture 03 page 11
ATOMIC THEORY OF MATTER
Dalton’s Atomic Theory
– explains several simple laws of chemical
combinations:
Law of Conservation of Mass
– states that the total mass of the
materials present after a chemical
reaction is the same as the total mass
before the reaction NMPanajon
GENERAL CHEMISTRY
Lecture 03 page 12
ATOMIC THEORY OF MATTER
Dalton’s Atomic Theory
– explains several simple laws of chemical
combinations:
Law of Multiple Proportions
– states that when two or more elements
combine to form more than one
compound, they combine in a ratio of
small whole numbers NMPanajon
GENERAL CHEMISTRY
Lecture 03 page 13
EXERCISE 01
Illustrating the Law of Definite Composition
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GENERAL CHEMISTRY
Lecture 03 page 15
EXERCISE 03
Illustrating the Law of Multiple Proportions
A B
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GENERAL CHEMISTRY
Lecture 03 page 20
EARLY RESEARCH ON ATOMIC PARTICLES
– subsequent experiments using the
cathode ray tube lead to the discovery of
the following:
protons – in 1896 by Eugene Goldstein
electrons – in 1897 by JJ Thomson
neutrons – in 1932 by James Chadwick
X-rays – in 1895 by Wilhelm Roentgen
radioactivity –
in 1896 by Antoine Henri BecquerelGENERAL
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CHEMISTRY
Lecture 03 page 21
EARLY ATOMIC MODELS
A. The Plum-pudding Atomic Model
– proposed by JJ Thompson, states that
an atom is made up of negatively-charged
electrons (or e ) embedded in a
-
nebulous cloud of
positive charges of
protons (or p+)
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GENERAL CHEMISTRY
A classic English plum pudding Lecture 03 page 22
EARLY ATOMIC MODELS
A. The Plum-pudding Atomic Model
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GENERAL CHEMISTRY
A classic English plum pudding Lecture 03 page 23
EARLY ATOMIC MODELS
B. The Nuclear Atomic Model
– proposed by Ernest Rutherford,
disproves the Plum-pudding theory
through his alpha (α) - scattering
experiment in gold foil
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The alpha-scattering GENERAL CHEMISTRY
experiment Lecture 03 page 24
EARLY ATOMIC MODELS
B. The Nuclear Atomic Model
The alpha-scattering
experiment
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GENERAL CHEMISTRY
The nuclear atom Lecture 03 page 27
EARLY ATOMIC MODELS
D. The Quantum Mechanical Model
- developed by Erwin Schrodinger,
Werner Heisenberg and Louis de Broglie,
further enhances the planetary model by
stating that electrons move at various
energy levels with definite amount of
energy or quanta
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GENERAL CHEMISTRY
Lecture 03 page 28
ATOMIC AND MASS NUMBERS
- characterizes each atom of element
Atomic number, Z
- fingerprint of an atom; gives the
element’s unique number of protons
Mass number, A
- gives the total number of protons and
neutrons NMPanajon
GENERAL CHEMISTRY
Lecture 03 page 29
ATOMIC AND MASS NUMBERS
- characterizes each atom of element
M.N. = A.N. + nO
For 12C;
6 p+ = 6, e- = 6, nO= 6 NMPanajon
GENERAL CHEMISTRY
Lecture 03 page 30
EXERCISE 05
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GENERAL CHEMISTRY
Lecture 03 page 31
EXERCISE 06
24
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GENERAL CHEMISTRY
Lecture 03 page 32
ISOTOPES
- atoms with the same number of protons
(or same atomic number) but different
number of neutrons
The different isotopes of carbon
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GENERAL CHEMISTRY
Lecture 03 page 33
ISOTOPES
The different isotopes of sodium
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GENERAL CHEMISTRY
Lecture 03 page 34
ATOMIC MASS
– the average atomic mass of each element
in the periodic table is the sum of the
exact individual isotopes and their
corresponding abundance
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GENERAL CHEMISTRY
Lecture 03 page 35
ATOMIC MASS
– expressed either in atomic mass unit
(amu) or grams per mole (g/mol) and is
equal to:
amu = 1.66054 x10-24 g
or 1 g = 6.02214 x1023 amu
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GENERAL CHEMISTRY
Lecture 03 page 36
EXERCISE 07
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GENERAL CHEMISTRY
Lecture 03 page 37
EXERCISE 08
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GENERAL CHEMISTRY
Lecture 03 page 38
QUANTUM NUMBERS
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GENERAL CHEMISTRY
Lecture 03 page 39
QUANTUM NUMBERS
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GENERAL CHEMISTRY
Lecture 03 page 41
QUANTUM NUMBERS
n=1
Energy levels
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GENERAL CHEMISTRY
Lecture 03 page 43
QUANTUM NUMBERS
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GENERAL CHEMISTRY
Lecture 03 page 44
QUANTUM NUMBERS
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GENERAL CHEMISTRY
Lecture 03 page 45
QUANTUM NUMBERS
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GENERAL CHEMISTRY
Lecture 03 page 46
QUANTUM NUMBERS
The different shapes of an orbital ( Azimuthal Quantum
Number, l )
s orbital
p orbital
d orbital f orbital
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GENERAL CHEMISTRY
Lecture 03 page 47
QUANTUM NUMBERS
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GENERAL CHEMISTRY
Lecture 03 page 50
QUANTUM NUMBERS
five orientations
(d orbital) NMPanajon
GENERAL CHEMISTRY
Lecture 03 page 51
QUANTUM NUMBERS
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GENERAL CHEMISTRY
Lecture 03 page 52
QUANTUM NUMBERS
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seven orientations GENERAL CHEMISTRY
(f orbital) Lecture 03 page 53
QUANTUM NUMBERS
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GENERAL CHEMISTRY
Lecture 03 page 54
EXERCISE 08
b. n = 4, l = 3, ml = +2, ms = -1/2
c. n = 4, l = 1, ml = -1, ms = +1/2
d. n = 3, l = 1, ml = +2, ms = -1
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GENERAL CHEMISTRY
Lecture 03 page 55
ELECTRONIC CONFIGURATION
– a designation of how orbitals are filled
with electrons
– gives the total number of electrons in a
completely-filled main energy level given
by the equation;
total electrons = 2n2
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GENERAL CHEMISTRY
Lecture 03 page 56
ELECTRONIC CONFIGURATION
– shows the valence and the core
electrons
valence electrons – outermost
electrons or those electrons on the
highest energy level (or n-value)
1s22s22p63s23p64s2
core electrons = 18 e_ valence electrons = 2 e_
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GENERAL CHEMISTRY
Lecture 03 page 58
ELECTRONIC CONFIGURATION
– can be written through the expanded or
the abbreviated form
expanded form – identifies all the
electrons of the atom
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GENERAL CHEMISTRY
Lecture 03 page 59
ELECTRONIC CONFIGURATION
– can be written through the expanded or
the abbreviated form
abbreviated form – shows only the
noble gas element that is
isoelectronic with the configuration
of the core electrons and the valence
electrons
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GENERAL CHEMISTRY
Lecture 03 page 60
ELECTRONIC CONFIGURATION
– can be written through the expanded or
the abbreviated form
expanded form: 1s22s22p63s23p64s2
core electrons = 18 e_s valence electrons = 2 e_s
40[Ar]
abbreviated form: 18 4s2
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GENERAL CHEMISTRY
Lecture 03 page 61
ELECTRONIC CONFIGURATION
– guided by the following principles
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GENERAL CHEMISTRY
Lecture 03 page 62
ELECTRONIC CONFIGURATION
Aufbau (or building block) Principle
– in filling orbitals with electrons, orbitals
with the lowest energy is filled first
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GENERAL CHEMISTRY
Lecture 03 page 63
ELECTRONIC CONFIGURATION
Aufbau (or building block) Principle
– the subshells contain different
maximum number of electrons
depending on the shape
no. of total electrons
s orbital orientation
1 (s) 2 e -s
p orbital 3 (px, py, pz) 6 e-s
d orbital 5 10 e-s
f orbital 7 14 e-s NMPanajon
GENERAL CHEMISTRY
Lecture 03 page 64
ELECTRONIC CONFIGURATION
Hunds Rule of Maximum Multiplicity
– in filling degenerate orbitals with
electrons, each orbital is “half-filled”
with one electron each before they are
filled with any electrons in excess
1s 2s 3s 4s 5s 6s 7s s<2
2p 3p 4p 5p 6p 7p p<6
3d 4d 5d 6d 7d d < 10
4f 5f 6f 7f f<
1
4
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 NMPanajon
GENERAL CHEMISTRY
4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f14 6d10….. Lecture 03 page 67
ELECTRONIC CONFIGURATION
s block p block
(n) (n)
d block
(n-1)
f block
(n-2)
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 NMPanajon
GENERAL CHEMISTRY
4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f14 6d10….. Lecture 03 page 68
EXERCISE 09
electronic
configuration orbital diagram
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GENERAL CHEMISTRY
Lecture 03 page 69
EXERCISE 10
electronic
configuration orbital diagram
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GENERAL CHEMISTRY
Lecture 03 page 70
EXERCISE 11
electronic
configuration orbital diagram
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GENERAL CHEMISTRY
Lecture 03 page 71
EXERCISE 12
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GENERAL CHEMISTRY
Lecture 03 page 72
EXERCISE 13
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GENERAL CHEMISTRY
Lecture 03 page 73
DEVELOPMENT OF THE PERIODIC TABLE
Johann Dobereiner (1780–1849)
– the groups of three elements (or triads)
that have similar properties
ex. lithium, sodium and potassium
John Newlands
– expanded the group into eight
elements (or octaves) that have similar
properties NMPanajon
GENERAL CHEMISTRY
Lecture 03 page 74
DEVELOPMENT OF THE PERIODIC TABLE
Dmitri Mendeleev (1834–1907)
– enhances the work of
Newlands by
successfully proposing
an arrangement based
on the increasing
– atomic weight
had similar works with
Lothar Meyer NMPanajon
GENERAL CHEMISTRY
Dmitri Mendeleev Lecture 03 page 75
DEVELOPMENT OF THE PERIODIC TABLE
Dmitri Mendeleev (1834–1907)
– given much credit for
boldly predicting the
existence of
undiscovered elements
through blanks in his
table
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GENERAL CHEMISTRY
Dmitri Mendeleev Lecture 03 page 76
DEVELOPMENT OF THE PERIODIC TABLE
Dmitri Mendeleev (1834–1907)
– also was able to correct
the atomic weights of
indium, berryllium and
uranium; placing them
properly in the periodic
table
– Father of Modern
Periodic Table NMPanajon
GENERAL CHEMISTRY
Dmitri Mendeleev Lecture 03 page 77
DEVELOPMENT OF THE PERIODIC TABLE
Dmitri Mendeleev (1834–1907)
Mendeleev’s
periodic table
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GENERAL CHEMISTRY
Lecture 03 page 78
DEVELOPMENT OF THE PERIODIC TABLE
Henry Moseley (1887–1915)
– developed the concept of atomic
number and used it in arranging the
periodic table, two years after
Rutherford’s Nuclear Model of the
– atom
proposed that physical and chemical
properties of elements vary periodically
with increasing atomic number NMPanajon
(Periodic Law)
GENERAL CHEMISTRY
Lecture 03 page 79
PERIODIC TABLE: REVISITED
GROUPS
Modern
Periodic Table
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GENERAL CHEMISTRY
Lecture 03 page 80
PERIODIC TABLE: REVISITED
HALCOGENS NOBLE GASES
ALKALI METALS GROUPS
CHALCOGENS
ALKALINE-EARTH
Modern
Periodic Table
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GENERAL CHEMISTRY
Lecture 03 page 81
PERIODIC TABLE: REVISITED
PERIODS
Modern
Periodic Table
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GENERAL CHEMISTRY
Lecture 03 page 82
PERIODIC TABLE: REVISITED
TRANSITION
ELEMENTS
Modern
Periodic Table
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GENERAL CHEMISTRY
Lecture 03 page 83
PERIODIC TABLE: REVISITED
REPRESENTATIVE
ELEMENTS
Modern
Periodic Table
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GENERAL CHEMISTRY
Lecture 03 page 84
PERIODIC TABLE: REVISITED
s-BLOCK
Modern
Periodic Table
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GENERAL CHEMISTRY
Lecture 03 page 85
PERIODIC TABLE: REVISITED
p-BLOCK
Modern
Periodic Table
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GENERAL CHEMISTRY
Lecture 03 page 86
PERIODIC TABLE: REVISITED
d-BLOCK
Modern
Periodic Table
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GENERAL CHEMISTRY
Lecture 03 page 87
PERIODIC TABLE: REVISITED
Modern
Periodic Table
f-BLOCK NMPanajon
GENERAL CHEMISTRY
Lecture 03 page 88
PERIODIC TRENDS
– properties that varies through elements
down a group and across a period
A. Atomic Radius
– half the distance between two bonding
nuclei – implies the size of the
atom or molecule;
measured in
o
Angstrom units (A) GENERAL CHEMISTRY
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GENERAL CHEMISTRY
Lecture 03 page 91
PERIODIC TRENDS
– properties that varies through elements
down a group and across a period
A1. Ionic Radius
– radius when an atom loses electron/s to
become a cation or accepts electron/s
to become an anion
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GENERAL CHEMISTRY
Lecture 03 page 92
PERIODIC TRENDS
– properties that varies through elements
down a group and across a period
A1. Ionic Radius
– cations are smaller than their atom
counterparts; anion are larger than
their parent atom
– for ions carrying the same charge, ionic
radius increases down a group NMPanajon
GENERAL CHEMISTRY
Lecture 03 page 93
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Ionic Radius GENERAL CHEMISTRY
values Lecture 03 page 94
PERIODIC TRENDS
– properties that varies through elements
down a group and across a period
B. Ionization Energy, IE
– minimum energy required to release an
electron from a gaseous atom or ion to
become a cation
Ca(g) + IE Ca + e + -
Lecture 03 page 95
PERIODIC TRENDS
– properties that varies through elements
down a group and across a period
B. Ionization Energy, IE
– can be first and second IE
Ca(g) + IE Ca +
(g) + e- 1st IE
Ca +
(g) + IE Ca 2+
(g) + e- 2nd IE
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GENERAL CHEMISTRY
Lecture 03 page 97
Ionization Energy, IE
Ionization Energy and
atomic number
Ionization NMPanajon
Energy Values GENERAL CHEMISTRY
Lecture 03 page 98
Ionization Energy, IE
Ionization NMPanajon
Energy Values GENERAL CHEMISTRY
Lecture 03 page 99
PERIODIC TRENDS
– properties that varies through elements
down a group and across a period
C. Electron Affinity, EA
– energy change associated with the
addition of electron to a gaseous atom
Cl(g) + e- Cl(g)
+ EA
-
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Electron Affinity GENERAL CHEMISTRY
Values Lecture 03 page 102
PERIODIC TRENDS
– properties that varies through elements
down a group and across a period
D. Electronegativity
– ability of an atom to attract a shared
pair of electrons to itself
– related to an atom’s ionization energy
and electron affinity
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GENERAL CHEMISTRY
Lecture 03 page 103
PERIODIC TRENDS
– properties that varies through elements
down a group and across a period
D. Electronegativity
– related to bond polarity
– increases from left to right across a
period; decreases from top to bottom
down a group
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GENERAL CHEMISTRY
Lecture 03 page 104
Electronegativity
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Electron Affinity GENERAL CHEMISTRY
Values Lecture 03 page 105
PERIODIC TRENDS: Summarized
INCREASING Ionization Energy
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GENERAL CHEMISTRY
Lecture 03 page 106
PERIODIC TRENDS: Summarized
INCREASING Ionization Energy
INCREASING Electron Affinity
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GENERAL CHEMISTRY
Lecture 03 page 107
EXERCISE 14
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GENERAL CHEMISTRY
Lecture 03 page 108
EXERCISE 14
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GENERAL CHEMISTRY
Lecture 03 page 109
EXERCISE 14
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GENERAL CHEMISTRY
Lecture 03 page 110
EXERCISE 14
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GENERAL CHEMISTRY
Lecture 03 page 111