Kabiling, Amielyn B.

Separation Process

Take home Quiz 2

1.)
P(atm) 75993.75
component c1 c2 c3 c4 c5
Acetone 69.006 -5599.6 -7.0985 6.2237E-06 2
Water 73.649 -7258.2 -7.3037 4.1653E-06 2

A12 1.928799 A -0.286181

A21 1.642618 B 0.286181
T Acetone 363.4626 Twater 321.1083
T x1 x2 g1 g2 P1 P2 x1A x2A g1A g2A x1B x2B y1 y2
363.4626 0.001 0.999 6.850846 1.00000221 288214.8 70927.46 0.002661 0.99733864 6.800737 1.000016 0.002681 0.997319 0.069155 0.930845
361.344885 0.005 0.995 6.731015 1.0000553 271875.1 65425.3 0.005987 0.99401279 6.701866 1.000079 0.006013 0.993987 0.144179 0.855821
359.22717 0.01 0.99 6.585078 1.00022095 256265.7 60284.11 0.009646 0.99035398 6.595272 1.000206 0.009631 0.990369 0.214201 0.785799
357.109455 0.05 0.95 5.556194 1.00548087 241363.8 55485.12 0.01572 0.98428 6.423206 1.000545 0.0137 0.9863 0.279482 0.720518
354.99174 0.1 0.9 4.553817 1.02181191 227147.3 51010.22 0.024302 0.97569809 6.190089 1.001301 0.018389 0.981611 0.340244 0.659756
352.874025 0.15 0.85 3.786824 1.04907133 213594.2 46841.94 0.035347 0.96465301 5.90635 1.002746 0.023895 0.976105 0.396685 0.603315
350.75631 0.2 0.8 3.193665 1.08765098 200682.8 42963.49 0.049252 0.95074849 5.573392 1.005319 0.030505 0.969495 0.448975 0.551025
348.638595 0.25 0.75 2.730435 1.13825125 188391.8 39358.71 0.066427 0.93357279 5.196179 1.009652 0.038603 0.961397 0.497267 0.502733
346.52088 0.3 0.7 2.365464 1.20188893 176700.2 36012.08 0.087301 0.91269914 4.78317 1.016637 0.048706 0.951294 0.541699 0.458301
344.403165 0.35 0.65 2.075661 1.27991674 165587.3 32908.7 0.112319 0.8876814 4.345735 1.027503 0.061506 0.938494 0.582412 0.417588
342.28545 0.4 0.6 1.844019 1.37405419 155033 30034.29 0.141958 0.85804221 3.897097 1.043937 0.077929 0.922071 0.619567 0.380433
340.167735 0.45 0.55 1.657895 1.48642954 145017.2 27375.15 0.176749 0.82325059 3.450999 1.068266 0.099212 0.900788 0.653359 0.346641
338.05002 0.5 0.5 1.507804 1.61963327 135520.3 24918.19 0.217316 0.78268397 3.020355 1.103769 0.126998 0.873002 0.68404 0.31596
335.932305 0.55 0.45 1.386573 1.77678353 126523.1 22650.89 0.264433 0.73556749 2.616153 1.155229 0.163454 0.836546 0.711952 0.288048
333.81459 0.6 0.4 1.288735 1.9616042 118006.7 20561.3 0.319122 0.68087837 2.246796 1.229945 0.211403 0.788597 0.73757 0.26243
331.696875 0.65 0.35 1.210101 2.17851649 109952.5 18638.01 0.382806 0.61719438 1.91798 1.339741 0.274444 0.725556 0.761596 0.238404
329.57916 0.7 0.3 1.14744 2.43274448 102342.5 16870.16 0.457553 0.54244715 1.633112 1.505145 0.356992 0.643008 0.78515 0.21485
327.461445 0.75 0.25 1.098253 2.73043526 95158.86 15247.42 0.546495 0.45350456 1.394252 1.764914 0.464079 0.535921 0.810223 0.189777
325.34373 0.8 0.2 1.060602 3.07879367 88384.13 13759.96 0.654576 0.34542414 1.203745 2.200146 0.600644 0.399356 0.840907 0.159093
323.226015 0.85 0.15 1.032984 3.48623109 82001.31 12398.46 0.789975 0.21002472 1.067304 3.004503 0.770703 0.229297 0.887602 0.112398
321.531843 0.9 0.1 1.014237 3.9625268 77166.03 11393.98 0.931425 0.06857472 1.006585 4.302126 0.941359 0.058641 0.962175 0.037825
321.3200715 0.95 0.05 1.003469 4.51899932 76578.09 11273.48 0.967182 0.03281832 1.001482 4.731028 0.970122 0.029878 0.979031 0.020969
321.1506543 1 0 1 5.16868343 76110.33 11177.86 0.993642 0.00635817 1.000055 5.080397 0.993751 0.006249 0.995331 0.004669

VAPOR LIQUID EQUILIBRIUM ACETONE – WATER (ACETONE)

370
liquid
360
vapor
350
340
330
320
310
300
290
0 0.2 0.4 0.6 0.8 1 1.2

VAPOR LIQUID EQUILIBRIUM ACETONE – WATER (WATER)

370
360
350
340
330
320
310 liquid
300 vapor

290
0 0.2 0.4 0.6 0.8 1 1.2
In this problem, I first assumed the initial values of mole fraction of acetone. Then, the following C1 to C5 values must be obtained from Table 2-8 of Perry’s
Handbook. Upon obtaining the C values for Acetone and Water. The vapor pressure of each was calculated using this formula:

ln(Ps) = C1 + C2/T + C3ln(T) + C4T^(C5)

Get the two saturation temperature and divide into the interval. Then get P1sat and P2sat. First you must assume the x1 values and then you will
get x2 by 1-x1. Using the raoult’s law you can solve for the new x1 and x2, then you can solve for the gamma 1 and gamma 2. Repeat steps until
the values of x1 will converge.