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Preface
This manual, published by MaxFlow Membran Filtration GmbH, introduces design
and operational procedures for membrane bioreactors (MBRs) applying MaxFlow
module technology to its potential clients. Besides detailed safety regulations and
procedures for MaxFlow module technology, basic design concepts regarding
membrane bioreactors are described. The details are in general form, there is no
requirement of completeness and could be different from the actual achievement.
Non-observance of the instructions regarding the use, operation and handling of
MaxFlow membrane modules can lead to expiration of warranty.
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Email: info@maxflow-gmbh.com
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Table of contents
1 MaxFlow Membran Filtration GmbH................................................................. 7
4.3.1 Pre-treatment....................................................................................... 32
5.1 Basics for the design of the activated sludge tank ......................................... 35
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9.3 A3 MembranPlus............................................................................................ 64
11 Annex ............................................................................................................. 70
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Module data
Concentration, activated
[g/l] 8 - 15
sludge MLSS
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Module data
Grouting plastics
Dimensions
Height with aeration channel [mm] 2880 2350 3420 4490 2350 3420
# connections 4 6 12 18 20 40
Aeration
# tubes 5 15 50
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Picture
M70-5-2-z=1
1)
Weight without aeration unit
Module data
Concentration, activated
[g/l] 8 - 15
sludge MLSS
pH, cleaning 2 – 11
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Module data
Grouting plastics
Dimensions
Height with aeration channel [mm] 2880 2350 3420 4490 2350 3420
# connections 4 6 12 18 20 40
Aeration
# tubes 5 15 50
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Picture
1)
Weight without aeration unit
2 Safety instructions
Safety first!
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Only appropriate and intended handling and the compliance with the
requested maintenance procedures can guarantee the functionality and a
long life-cycle of the membrane modules and of all the parts of the
installation. Moreover, appropriate and intended handling will help to
avoid any industrial accident.
The staff performing the operation and the maintenance of the filtration
plant has to have read and understood this manual. All the instructions
mentioned in this manual should be followed in detail. In order to
guarantee a high system security and to avoid any industrial accidents,
only authorized and well trained staff should be instructed in handling the
installation. A technical briefing regarding potential risks which may occur
during the operation of the installation should have been given to the
staff.
The manufacturer will not be liable for personal injuries resp. material
damage caused by improper handling or by non-observance of the
mentioned security advices. This risk will only be covered by the owner
resp. the operator of the installation.
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3.1 Definitions
Biofouling
Biofouling is a biological contamination of the membrane due to microorganisms
and their excrements. These particles will create a “biofilm”, while first “pasting up”
and then, with increasing operation period, growing up at the membrane surface.
CIP treatment
Cleaning procedure where the module is cleaned without being removed. (Clean
in Place)
Concentrate
Portion of the flowrate which will be retained by the membrane (e.g. activated
sludge)
Covering layer
Deposit on the membrane caused by the filtration process comprising retained
organic and inorganic substances.
Cross-flux
The Cross-flux is the flowrate during the filtration process related to the membrane
surface ; unit: L/(m²*h).
Cross-flow
In this process type the feed flow constantly overflows the membranes parallel (the
membrane surface is installed parallel to the main flow direction) and the permeate
flow will be evacuated vertically to the main flow (cross-flow filtration). As this
overflow of the membranes will create shear forces at the membrane surface, a
balance between layer formation and layer removal is achieved. Considering
MBR-technologies with submerged membrane modules the cross-flow effect is
obtained by the aeration system in the bioreactor. In this way it is possible to limit
the layer formation.
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Dead-end-operation
Regarding the Dead-end-operation the membrane will be loaded vertically by the
main flow direction, compare „coffee filter“. The removal of detained particles is
achieved by a periodic back-flow of the membranes.
Feed
Flowrate charging the membrane, e.g. activated sludge.
Filtrate
Water separated from the feed by pore filtration (mixture of substances).
Flux
Specific filtrate per square and time ; unit: L/m²*h.
Fouling
Accumulation of particles at the membrane surface, at or in pores of the
membrane structure. Depending on the materials provoking the fouling it is
differentiated between colloidal fouling, inorganic fouling (scaling) and biofouling.
Fouling is provoking a reduction of the filtration capacity and the permeability.
In-place-cleaning
In-place-cleaning is a cleaning procedure adapted to the membrane bioreactor
technology (additional information in chapter 8.2.1.3 – Recovery-Cleaning (CIP)).
Maintenance cleaning
Regular cleaning during normal operation.
MBR
MBR = membrane bioreactor
Membrane
Barrier, which is provoking the retaining of particles (for further information see
chapter 3.2).
Membrane area
Membrane surface which is available for the filtration process.
Module
Component, which is ready for connection (functional) and which consists of the
membrane or the membrane element, collecting line and fittings.
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Net flux
Performance of the installation in a long term period (considering filtration breaks,
back-flow periods and the volume of filtrate needed for the backflow process).
Operational pressure
The operational pressure is the driving force for the physical separation process
with membranes. This operational pressure is necessary in order to guarantee a
filtration process. The operational pressure is consisting of the transmembrane
pressure and several pressure losses occurring in the connected periphery of the
system.
Permeability
Porosity of a membrane under defined conditions (e.g. temperature).
Permeate
Portion of the flow-rate which is passing the membrane.
Pore size
Average pore size of a porous membrane, relevant for the retaining performance
of a membrane. The pores of a membrane will usually not be homogenous – they
will be characterized by a particle size distribution ; unit: µm.
Porous membrane
Cyclic operation
Standard operation: filtration phase with subsequent back-flow phase resp.
standstill phase.
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Retentate
Portion of the flow-rate which will be retained by the membrane (e.g. activated
sludge)
Scaling
Accumulation of inorganic ingredients at the membrane surface, if limits of
solubility of dissolved salts will fall below as a result of concentration increase
Transmembrane pressure
Pressure difference between the filtrate side and the feed side.
Drinking water
Water, which is suitable for human usage: the pH-value of drinking water is
determined to be between 6.5 and 9.5; the water hardness should be between 0.9
and 4.4 mmol/l.
The membrane filtration is a physical process which can remove, depending on the
membrane type, a wide range of substances (from fine particles up to dissolved
ingredients) out of water or wastewater.
The classification of the membrane processes is depending on the cut-off size. The
transition between the different membrane processes is smooth.
Microfiltration (MF)
Ultrafiltration (UF)
Nanofiltration (NF)
Reverse osmosis (RO)
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Umkehrosmose
Reverse Osmosis Ultrafiltration
Membrane
process
Nanofiltration Mikrofiltration
Microfiltration
Size of the
100 200 10.000 20.000 100.000 500.000 molecular weight
retaining
substances [dalton]
reactive
Examples Pigmentfarbstoffe
pigment dye
dye
Enzyme
enzyme activated sludge
Belebtschlamm
flocken
flocs
Viren
viruses Bakterien
bacteria
Salze
salts
Tenside
tenside fat– and
Fett- undoil-
Öl-
Emulsionen
emulsions
Zucker
sugar Gelatine
gelatin Hefe
yeast
metal
Metall- colloidal
kolloidale
ionen
ion Silikate
silicate
Antibiotika
antibiotics
endocrinalwirksame
Endokrin effective
substances
Substanzen
The membranes are fine permeable layers (thickness approx. 0.1 µm – 0.5 µm),
which are superimposed on a support frame for stability reasons.
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The microfiltration (MF), which is prevalent used for the concentration of colloidal
suspensions, is usually operated in a pressure-difference-zone of 0.1 bar up to
0.3 bar.
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Transmembrane pressure
The driving force of the separation process is the pressure difference between
feed- and permeate-side, the transmembrane pressure. In case of the submerged
low-pressure-filtration the transmembrane pressure is created by a vacuum on the
filtrate side.
Specific flux
The flow rate of a membrane is an indicator of the capacity under certain
circumstances. If the flow rate is related to the membrane surface, the result is the
specific flux L/(m²*h) of the membrane. The temporary specific flux during the
operation process is defined as gross flux. The net flux is describing the
performance of a system in a long term period (considering filtration breaks, back-
wash periods and the volume of filtrate needed for the back-wash process); unit:
e.g. m³/d related to the membrane surface.
Permeability
The permeability is describing the permeably character of a membrane. It is
defined as the ratio of specific gross flux and transmembrane pressure, unit:
L/(m²*h*bar).
The permeability is directly depending on the condition of the membrane and the
filtration attributes of the fluid which should be permeated.
Critical flux
According to FIELD et al. (1995)2 there is no decrease of the membrane
performance observed, while operating the membrane below a certain flux
(„subcritical“). However while exceeding this critical flux („overcritical“), there
occurs a reinforced membrane fouling and a performance decrease of the
membrane is noticed.
2 FIELD et al. (1995): Critical flux concept for microfiltration fouling. Journal of Membrane Science.
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process configuration
A pre-treatment stage must eliminate particles and matters that can negatively
influence and/or damage the filtration process, such as abrasive solids, fats, oils and
fibres. Suitable methods have to be chosen according to the specific attributes of the
wastewater, as e.g.
screen unit,
precipitation/ flocculation…
In order to guarantee the performance of the membranes, methods for removing the
cake layer at the membrane surface must be considered. Two types of substances
are differentiated:
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Easily removable cake layers will usually be eliminated by the aeration device that is
installed below the membrane modules. As a result of the ascending air, a flow
parallel to the membrane surface generating shear forces is established. All deposits,
which cannot resist the shear forces, will be removed from the membrane surface.
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During the biological reduction process the micro-organisms oxidise the solids.
Besides the biomass production (cell growth) by the metabolism of the biomass
gases (e.g. elementary nitrogen) which will exit to the atmosphere will be produced.
The biological wastewater treatment processes were originally developed for the
elimination of carbon. Since the 90s there were appointed limiting values for
discharge of nutrients (nitrogen and phosphorus) in Germany depending on the size
of wastewater treatment plants (compare Abwasserverordnung, AbwV (2004)3).
Therefore in wastewater treatment plants there are operated aerated and non-
aerated reactors which will eliminate the nitrogen (nitrification and denitrification) and
carbon. As a biological phosphorus elimination based on the technology of anaerobic
reactors is not a standard solution, more often the chemical phosphorus elimination is
applied. In waste water treatment plants the microorganisms are supplied with
sufficient oxygen so that they remove as much solid matter as possible as quickly as
possible. But when this occurs bacteria increase and new biomass is formed from a
part of the organic substance.
3 AbwV (2004): Verordnung über Anforderungen an das Einleiten von Abwasser in Gewässer. BGBl. I
Nr. 28 vom 22.6.2004
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The higher the COD-value, the higher is the portion of the organic and the
inorganic compounds in the raw water.
pH-value
The pH-value is considering the concentration of hydrogen-ions and is so an
indicator of acidity in aqueous solution. The pH-value is the negative common
logarithm of the hydrogen-ion-concentration which is calculated as mol H+/L. The
smaller the pH-value, the higher is the acidity of the solution. The pH-value of the
activated-sludge-water-mix has to be between 6.5 and 8.5, otherwise the
metabolisms of the biomass will be interrupted.
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For a detailed analysis of the available acid-/ base volume in addition the acid
capacity resp. the base capacity has to be determined.
The result of the acid capacity is an indicator for the buffer capacity of the water
compared to acid and is so guaranteeing the pH-value-stability. The acid capacity
of the water indicates the volume of acid – in practice 0.1 mol/L hydrochloric acid -
which is dissipated until achieving a pH value of 4.3. Caustic soda is used for the
base capacity in order to reach a pH value of 8.2 for a defined amount of water.
Temperature
While operating of a biological wastewater treatment installation it has to be paid
attention to the temperature as it strongly affects the metabolism of the micro-
organisms. Extreme (too low or too high) temperatures may negatively harm the
biological degradation process and may even destroy the biomass in the reactor.
The optimized temperature for a biological wastewater treatment is set between
10°C and 30°C.
Conductivity
In wastewater is the conductivity a sum parameter for the concentration of ions
and the salt compounds. The results are stated based on a reference temperature
(usually 25°C); 0.1 mS/m at 25°C corresponds to 0.425 mg/L salt content (mg/L
TDS = total dissolved solids). The higher the electrical conductivity, the higher is
the rate of the dissolved salts. The measurement of the conductivity serves
amongst others for monitoring the salt-concentration of the influent. The
conductivity is measured in S/cm.
Nutrient rate
In order to guarantee a successful biological degradation the rate of BSB5 to
nitrogen to phosphorus should be approx. 100:5:1 (DWA, 19974). A lack of one of
these nutrients may harm the biological degradation process.
4 DWA (1997): Biologische und weitergehende Abwasserreinigung. Ernst & Sohn Verlag, 4. Auflage
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After the biological cleaning process the biomass (activated sludge) is not isolated by
the conventional sedimentation process in the clarifier, but by the membrane (micro-
or ultrafiltration). Due to the small pore size, the membrane is not only a barrier for
the activated sludge, but also for suspended substances, bacteria and viruses. The
high quality of the effluent, allows the use of the permeate as service water.
Optionally a subsequent membrane level may be considered, like nanofiltration or
reverse osmosis.
The “wet installation” is based on membranes which are directly submerged in the
activated sludge tank. Concerning the “dry installation” the membranes are installed
outside the aeration tank. The transport process will be provided by a pump, creating
the transmembrane pressure and the minimum flow-velocity. Apart from the
additional energy costs with this method of operation the mud flakes are under a
great deal of mechanical stress so that modules set up dry are not used in municipal
waste water treatment plants.
Regarding submerged modules the aeration device guaranteeing the necessary air
supply for the biomass degradation are installed under the membrane modules and
in the aeration tank. This upstream air flow will permanently pass the membrane
module and will relieve the cake layer from the membrane surface.
5 MUNLV (2006): Membrantechnik für die Abwasserreinigung. Ministerium für Umwelt, Naturschutz,
Landwirtschaft und Verbraucherschutz des Landes Nordrhein Westfalen, FIW-Verlag.
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Raw wastewater
Permeate
Aeration
Clarifier can be economised, as the membrane stage retains the solids totally
(cp. phosphate reduction by adsorption)
By installing further membrane modules, easy capacity upgrade of the MBR
installation possible
Smaller bioreactor volume due to higher TS compounds at constant sludge
loading
Obtaining a complete sludge generation interval of the biomass, due to a
higher sludge age
Flexible installation place due to low weight and small dimensions
Possible to influence the rate of the excess sludge by changing the sludge
loading
Flexible and modular construction possible, as no additional external piping
necessary and as all existing installation components can easily be used.
An automatic operation process is guaranteed by an independent control
system and a easy procedural principle
The installation can easily monitored by checking the transmembrane
pressure development
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Good acceptance in high populated areas due to smaller property and easy
enclosure
Reduction of residual organic contamination as well as hygienisation of the
plant’s outlet to the greatest possible extent whereby measures for
hygienisation or more extensive secondary treatment can be omitted.
A MBR-installation is less sensitive regarding the biological balance by
impulsive influent-charges, e.g. during heavy rain events
Safe separation process of all the particular solids even on mobile equipment
(e.g. on ships)
inlet outlet
Inlet
inlet outlet
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Furthermore the system will comply with the hygienic quality standards requested
e.g. in the „European council directive concerning the quality of bathing water“
(limiting value for faecal and total coliform-bacteria germs).
4.3.1 Pre-treatment
When pre-treating untreated water, all particles and waste water components that
may damage the membrane, modules or other parts of the plant must be removed
from the untreated water. Especially hairs, fibre tissues and fats in high
concentrations will provoke clogging on the membranes. Other materials may
damage the membrane by high mechanical stress or by sharp angles.
Compared with the plate modules used here, the risk of clogging is considerably
higher when hollow fibre modules are used. Nevertheless, good pre-cleaning should
be carried out in order to ensure fault-free operation. It must particularly be ensured
that the pre-cleaning process cannot be bypassed in the case of an error in the
sieving procedure and that thus no sewage, which has not undergone pre-cleaning,
can enter the membrane tank.
For eliminating bigger and fibered pollutants out of the inlet-flow, the installation of
screens or sieves is urgently requested.
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In the grit chamber (and/or the grease separator) the flow-velocity of the wastewater
will be reduced in order to allow the sedimentation of mineral solids. A roll-flow is
obtained by aerating the grit chamber/ grease separator. A scum baffle is installed in
the tank in order to accumulate the grease components of the wastewater in a flow-
depressed area of the tank. The installation of a grit chamber/ grease separator is
necessary in order to protect the membranes and pumps as the cleaning effect of grit
chambers and grease separators is reducing the wearing of membrane and pumps.
4.3.2 Bioreactor
The elimination of the solids in the bioreactor is achieved by the concentrated micro-
organisms. Due to the selective separation of the membranes, standard average
TSS-concentrations in the activated sludge tank of MBRs are between 8 g/L und
15 g/L. which is significantly higher compared to conventional WWTPs (factor 3 - 5).
The type and the arrangement of the aeration system (intermittent aeration, upstream
denitrification) is chosen depending on the necessary elimination processes
(nitrification, denitrification, carbon elimination).
The necessary volume of the activated sludge tank is mainly influenced by the sludge
loading and sludge age. Most of the municipal membrane bioreactors are operated
with a sludge age of 25 days, so they are called installations with aerobic sludge
stabilisation (DWA, 1997)6. Basically it can be assumed that the biological processes
of MBRs do not vary from those of conventional activated sludge systems.
6 DWA (1997): Biologische und weitergehende Abwasserreinigung. Ernst & Sohn Verlag, 4. Auflage
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Usually the sludge of MBR-systems possesses a smaller floc size. Although this is
combined to a bigger specific floc surfaces, the capability of drainage of the sludge is
usually not negatively effected.
The guideline A 131 of the German association for water, wastewater and waste
(DWA, 20007) is providing hints for estimating the volume of the excess sludge
production.
The treatment of the excess sludge is mainly achieved by the sludge dewatering (e.g.
centrifugal or chamber filter press) and/or by the sludge decomposition.
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10 Dohmann et al. (1991): Bemessung der Belebungsbecken nach dem Ansatz der Hochschulgruppe
(HSG-Ansatz). Korrespondenz Abwasser, Nr. 8, Jg. 38.
11 MUNLV (2006): Membrantechnik für die Abwasserreinigung. Ministerium für Umwelt, Naturschutz,
Landwirtschaft und Verbraucherschutz des Landes Nordrhein Westfalen, FIW-Verlag.
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The necessary membrane surface is achieved by the ratio of the maximum inlet flow
to the max. permeate flow.
Amembrane = Qinlet / Fu
Fu = Flux
Considering the water volume displaced by the membranes and the necessary
nitrification-volume, it should be controlled if the nitrification volume for the installation
of the membranes is sufficient or if additional volume has to be provided.
Moreover for the calculation of the minimum height of the tank, the minimum charging
level and a safety factor for intense rain events (resp. mixing pond and equalizing
reservoir) has to be considered.
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The individual bags are hollow inside and covered with a membrane on both sides.
The module is totally submerged in the liquid which has to be filtrated. All substances
smaller than the stated cut-off, will pass the membrane and will be extracted by the
filtration pipe.
Basically filtration modules will be arranged in MBR installations as follows (Figure 5):
The aeration unit is placed under the filtration module and will be fixed with retaining
plates on the filtration module. Above the filtration module the connection for the
lifting modules is screwed on. For flexibility reasons the collector line should be a
tube line.
lifting module
filtration module
brackets
aeration unit
Figure 5: Construction of a membrane module incl. aeration unit, filtration module and
lifting module – one-storied module (left) and 2-storied module (right)
Another possible arrangement is the multi-module (Figure 6): the aeration unit is
integrated in the module frame where max. 9 membrane modules can be installed in
total. As all the membrane modules can be dismounted completely, the installation/
disassembly effort is minimized. The main advantage of this arrangement is based on
the compact construction, minimized space requirements and the centralized air
supply.
The membrane modules will be installed in guide tubes. This must be done in such a
way as to prevent a lateral movement (slip) of the membrane modules (e.g. because
the tank or the water moves). Furthermore, the guide tubes must have lateral
reinforcements in order to prevent bulging of the module wall when back flushing the
module (counter bearings). The distance to the basement has to sufficient in order to
allow the formation of a roll-flow. To do this there must also be an open space next to
the module that is just as big as the area of the module (double area). The guide rod
ensures that the modules stay fixed in their place.
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Figure 6: Design of a Multi-module-system with three modules arranged next to one another
and three modules arranged one above the other.
Furthermore, a buoyancy security fixes the module unit in the tank and prevents that
the modules float. In order to remove the modules out of the tank, this buoyancy
security has to be arranged above the water surface.
Different module fixings, distances from the floor or the walls and
aeration equipment must be cleared with
MaxFlow Membran Filtration GmbH.
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For filtrate-pumps usually rotary piston pumps, eccentric screw pumps or self-priming
centrifugal pumps are used as these pumps are easily adjustable and operate at
constant flow-rates and varying operational pressures. Also, positive displacement
pumps are used as they are self-priming and allow pumping an air-liquid-mixture.
Positive displacement pumps are bi-directional and can minimize equipment
installation for small and average sized systems (e.g.: no pump exchange necessary
during CIP cleaning of the membranes).
The resistance of the selected pumps to the chosen cleaning chemicals must be
confirmed.
A de-venting device can also be integrated in the filtration line. This is always of
benefit when any build-up of air or gas is expected in the filtration line that cannot be
eliminated by the pump alone. The de-venting device is to be produced so that it
ensures complete de-venting at the highest point of the line e.g. during the pause
phase in filtration.
6.2.3 Aeration
The necessary aeration rate for each type of MaxFlow-membrane module is noted in
the specifications in chapter 1.2.1. The aeration rate is related to footprint of the
module, viz. if 2 or 3 modules are installed on top of each other, the aeration rate will
remain constant as the footprint is constant too.
To ensure proper aeration, the aerator cartridges in the aerator module must be
checked regularly for proper functioning (homogeneous distribution of bubbles over
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The aeration units is installed below the membrane modules by retaining plates and
they are serving for the air supply of the nitrification process as well as for the control
of the cake layer thickness – formation of the flow parallel to the membrane surface
(compare chapter 3.5).
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The process measuring and control technology are important equipments while
operating and controlling a MBR. For a higher operational safety the following
parameters should be measured online:
Transmembrane pressure
Permeate rate
7 Membrane modules
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1. Above the membrane module (1) a lifting module is installed and fixed. The
module can be lifted by a crane.
5. The tube adapter will be connected at the top of the filtration pipe (2) of the
module. The other end of the tube adapter is remaining unbolted in order to
make it possible that the air can escape from the module when the module is
emerged. Otherwise the module can be damaged! The ball valve must be
closed and the screwed connection must be tightened.
6. The aeration unit is connected with the compressor by a tube line (pay
attention to the temperature and sewage resistance of the tube).
8. The buoyancy security will be fixed at the tank edge in order to avoid a buoying
upwards-effect of the modules in operation.
10. The filtration pipe has to be unbolted to the atmospheric pressure in order to
allow air exhausting the module.
11. Control the tidiness of the tank. All impurities caused by the installation
process have to be cleaned.
12. Steady filling of the tank (directly after the installation of the modules), in order
to allowed trapped air to exhaust out of the membrane. The minimum distance
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between the top of the module and the water surface must not be less than
30 cm after the filling process.
1. Above the membrane module (1) a lifting module is installed and fixed. The
module can be lifted by a crane.
5. The tube adapter will be connected at the top of the filtration pipe (2) of the
module. The other end of the tube adapter is remaining in order to make it
possible that the air can escape from the module when the module is emerged.
Otherwise the module can be damaged! The ball valve (4) must be closed and
the screwed connection must be tightened.
6. The aeration unit is connected with the compressor via hose (pay attention to
the temperature and sewage resistance of the tube).
8. The buoyancy security will be fixed at the tank edge in order to avoid a buoying
upwards-effect of the modules in operation.
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Move the module only by using the lifting module. NEVER use
the filtration pipe as a carrying handle!
The module must not be installed by use of force! Avoid any kind
of blows impacting the module, e.g. hammer blows!
The minimum distance between the top of the module and the
water surface must not be less than 0.3 m after the filling
process!
7.2 Commissioning
2. Switching-on of the aeration unit. Never operate the modules with out aeration!
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The minimum distance between the top of the module and the
water surface must not be less than 30 cm after the filling
process!
7.3 Shutdown
2. Start filtration shortly to minimize the volume of filtrate in the module as far as
possible
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5. Pull the complete module block (on the buoyancy security) SMOOTHLY out of
the tank until the ball valve sticks out of the liquid.
In case of multi-storied modules pull the block SMOOTHLY out of the tank until
the first module sticks out of the liquid. Remove the tube adapter in order to
empty the module. Then pull the next module out of the liquid and open the
next hose adapter. Repeat this procedure until the ball valve of the last module
can be opened.
If the modules have an opening device for the lower ball valve which can be
operated from the tank surface, then the lower ball valve is to be opened
during lifting to allow the filtrate in the filter bags to escape and not accumulate
in the filter bags of the lower module.
6. Open ball valve at the last membrane module and empty the module
completely.
7. Remove the entire module block out of the tank. Relieve the filtration pipe and
the aeration pipe. Pay attention that no person is located in the pivot range of
the crane.
8. When putting modules down ensure that they are put on a level, clean surface
that has no sharp objects on it. Always put the modules down on the full
surface and do not tilt.
9. After having removed the retaining plates, the modules can separated from
each other!
10. You must ensure that the module is not exposed to strong sunlight and / or too
high (> +50°C)/ or too low (< +5°C) temperatures or start to dry or dry out.
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Move the module only by using the lifting module. Never use the
filtration pipe as a carrying handle!
The dismounted modules can be cleaned from rest of sludge by means of a SOFT
water-jet. Do never use a hard water-jet for the cleaning procedure (e.g. pressure
washer) as the membrane surface would be damaged!
The modules should be cleaned until all the rest of the sludge is removed from the
membrane or module surface and from the space between the membrane bags.
Cleaning is done from top to bottom in the module area which is in contact with the
activated sludge.
Prior to, during and after the cleaning, the modules must permanently be kept wet.
They must never become dry!
The membrane modules must be conserved if they are not used for a longer period in
order to avoid any formation of mould. For that purpose the membrane modules must
be cleaned (see chapter 8.2.1) and dismounted (see chapter 7.3.1).
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Modules with ultrafiltration membranes must never become dry (membrane must
always be moistened with water). Should these modules be stored for more than
24 hours they must be protected from biological fouling by using a preservative.
Membranes can be soaked and then stored with:
or
or
Here the whole membrane must be saturated with the preserving solution that must
be done with a short filtration with the solution. For longer storage the concentration
must be checked or changed regularly. Modules with ultrafiltration membranes must
not be exposed to frost at any time.
New filtration modules have to be stored in dry conditions. During the stocking the
modules should NOT be exposed to intensive solar irradiation, high temperatures or
frost. For storing the modules in dry conditions, the modules should be shrink-
wrapped in plastic bags by adding drying agent. The storage temperature should
never exceed 50 °C. Please note that the modules are shock-sensitive.
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Already used modules should be cleaned chemically before storage (see Chapter
8.2.1.4). No cleaning chemicals should remain in the membrane.
Used, cleaned modules can also be dried for storage. To do this they must be
preserved with a 20 – 40 % glycerine solution before drying. The solution must
penetrate the membrane which is guaranteed by a short filtration. After emptying, the
suction pipe must be sealed and the air drawn off from the filtrate outlet so that the
membranes lie flat during drying and the module also dries from the inside. The
modules must not contain any residual moisture for storage because otherwise
mildew or algae could build up. The dried modules must then be sealed in plastic
bags with drying agents added.
For the waste disposal of old submerged modules it has to be considered that these
are completely cleaned of sludge.
8 Intended Operation
MaxFlow-membrane modules should only be used for the intended application area
of wastewater treatment.
Every modification by the client regarding the membrane modules or the utilities and
cleaning chemicals must be communicated and confirmed by
MaxFlow Membran Filtration GmbH.
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The cyclic operation is needed for a minimization of the cake layer. In the interval
time there is no vacuum on the membrane and so the particles attached at the
membrane surface can easily be removed by the cross-flow provoked by the aeration
device.
The interval time with aeration must not be longer than 30 minutes. With longer
intervals, the scavenging air below the membrane modules must also be turned off,
in order to prevent destruction of the membrane modules. When filtration is carried
out again, heed that at first the scavenging air is turned on and only then filtration, in
order to ensure sufficient flushing of the membrane surfaces.
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8.1.1 Tests
REGULAR TESTS
frequency Check-list
daily - Visual check of permeate regarding suspended matter
- Visual check regarding leakages
- Visual check of bubble’s arrangement on water surface
- Checking and recording the operational parameters
- permeability
- MLSS-concentration
- Flow-rate
- Transmembrane pressure
- amount of scavenging air
-…
monthly - Checking amount of stocked spare parts
every 6-months or - chemical regeneration
when required
8.2.1 Service
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8.2.1.2 Maintenance-cleaning
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During the so-called recovery cleaning method, the modules remain in the filtration
tank and they will be cleaned in 2 steps.
First an alkaline cleaning solution is transported from the permeate side into the
membranes. Before starting the cleaning process, the remaining water volume in the
modules should be as small as possible, what could be done with a short filtration.
The cleaning chemicals added remain within the membrane pouches for the duration
of the reaction time when the membrane module is aerated for a short time (to mix
the cleaning solution thoroughly). Then the used cleaning solution is drawn off again
(filtration operation) and fed back into the cleaning container.
The inserted cleaning solution remains for the residence time inside the filter bags
while the modules are aerated. Then the used cleaning solution is evacuated again
(filtration operation) in the reservoir for the cleaning solution.
In a second cleaning step the procedure can be repeated with an acid cleaning
solution.
The used cleaning solutions may be reused by new concentration (control by pH-
measurement). After the third cleaning procedure the solutions should be discarded
at the latest.
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As a dilution effect is occurring inside the modules, the concentrations of the sodium
hypochlorite will be twice as high as mentioned in Annex 11.1.
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External cleaning containers are used for this. With materials that are used for wall
cladding (pipelines etc.) you must ensure that they are resistant to the cleaning
chemicals.
For an external cleaning the modules have to be dismounted and have to be cleaned
by fresh water or permeate. Do not damage the membrane by the water-jet.
In the next step an alkaline cleaning is needed. The washed up module is inserted in
the cleaning reservoir filled up with the alkaline cleaning solution. Please make sure
that the filtration pipe is installed and has a direct contact to the atmosphere. A
recirculation should be created inside the reservoir provided by pump or by a cyclic
aeration. The overall duration of aeration must not exceed 30 minutes, otherwise it
may result in a damage of the membrane. After a residence time of about 2 –
3 hours, the module should be removed out of the reservoir.
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Cleaning period:
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The membrane has a service life of 350,000 ppmh of chlorine under the specified
conditions.
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The membrane has a service life of 100,000 ppmh of chlorine under the specified
conditions.
For cleaning solutions which are not tested and confirmed by the
MaxFlow Membran Filtration GmbH there is given no warranty regarding the
consistency of the membranes and the cleaning success.
In order to achieve best cleaning results, the optimized cleaning solutions offered by
MaxFlow Membran Filtration GmbH can be used (see chapter 9).
The tube diffusers located in the aeration module underneath the membrane
modules, are subject to wear and must be checked and replaced from time to time.
Filtration without proper and sufficient aeration may lead to irreversible damage to the
membrane modules.
The aeration cartridges in the aeration module are to be checked for performance
regularly (even bubble distribution over the entire length of the cartridge) and
replaced if necessary to ensure proper aeration. A visual check of the aeration at
regular intervals by lifting out the aeration unit is also recommended. The life of the
aeration cartridges may vary greatly depending on the waste water.
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The old aeration devices are first removed and the condition of the ¾”
connection is checked. If necessary, the connection must also be replaced.
Ensure, when fitting the diffuser tubes, that the perforation is positioned
correctly to the module (left and right of diffuser tube).
8.4 Monitoring
During the monitoring process the following parameters should be controlled and
recorded in order to guarantee a reliable operation process and a high-class
permeate quality.
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Temperature [°C]
MLSS-concentration in
filtration tank [kg/m³]
pH-value in
filtration tank [-]
Conductivity in
filtration tank [µS/cm)
Sludge volume [ml/, %l]
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9 Approved chemicals
Application Chemicals
Conservation Glycerine
Conservation Ultrasil 73
Improvement of filtration A3 MembranPlus
Alkaline Cleaner A3 Activator A 101
Acidic cleaner A3 Activator S 101
Subsequent you will find notes concerning the chemicals. In case of questions please
contact the MaxFlow Membran Filtration GmbH and consider the relevant spec
sheets.
9.1 Glycerine
The modules must be preserved with a 20 – 40%- glycerine solution for dry storage.
To do this the membrane is soaked with the solution by means of a short filtration.
When storing damp a 40 – 60%- solution is necessary. After being treated with the
preserving solution the modules are emptied and sealed in foil in both cases.
9.2 Ultrasil 73
Ultrasil 73 is used as a biocide to preserve the membranes against mildew and algae
formation.
9.3 A3 MembranPlus
A3 MembranPlus
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delivered. The MaxFlow Membran Filtration GmbH is providing the system specific
dosing program as the optimized dosing rate is depending on a lot of site-specific
factors.
Continuous cleaning cycles with A3 Activator A 101 will result in long membrane life
cycles with high flux rates.
After usage it has to be flushed efficiently with fresh water in order to remove
deposits.
Close the reservoir always with the original closing and store the reservoirs in cool
conditions and without solar irradiation.
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Continuous cleaning cycles with A3 Activator S 101 will result in long membrane life
cycles with high flux rates.
A3 Activator S does not contain any organic bound halogens (AOX). But A3 Activator
S contains phosphates.
After usage it has to be flushed efficiently with fresh water in order to remove
deposits.
Close the reservoir always with the original closing and store the reservoirs in cool
conditions and without solar irradiation.
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10 Manufacturer´s declaration
Herewith we,
MaxFlow M20-002
MaxFlow M70-002
MaxFlow M70-003
MaxFlow M70-H-004
MaxFlow U20-002
MaxFlow U70-002
MaxFlow U70-003
MaxFlow U70-H-004
EN 292-1
EN 292-2
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11 Annex
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LISA LISA
Level Level
Reservoir Reservoir
for cleaning for cleaning
solution solution
f1
f2
PISA FICA
pressure flow
Blower f1
f2
FICA PISA
flow pressure
Filtrate,
permeate
Drive pneumatic
Spring -loaded
Non return valve
Valve flap Rotary piston pump
f1 Frequency changer
Label of the relevant
control -parameter
Removal of excess sludge
f2
Draining
Compensator Engine
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