T.S. Bowers· K.J. Jackson· H.C.

Helgeson

Equilibrium
Activity Diagrams
for Coexisting Minerals
and Aqueous Solutions at Pressures
and Temperatures to 5 kb and 600°C

Springer-Verlag
Berlin Heidelberg New York Tokyo 1984
TERESA S. BOWERS
Division of Geological
and Planetary Sciences
California Institute of Technology
Pasadena, CA 91125, USA
KENNETH J. JACKSON
Department of Earth Sciences
Lawrence Livermore National Laboratory
University of California
Livermore, CA 94550, USA
Prof. HAROLD C. HELGESON
Department of Geology and Geophysics
University of California
Berkeley, CA 94720, USA

ISBN-13: 978-3-642-46513-0 e-TSBN-13: 978-3-642-46511-6

DOl: 10.1007/978-3-642-46511-6

Library of Congress Cataloging in Publication Data. Bowers, T. S. (Teresa S.). Equilibrium activity diagrams.
Bibliography: p. Includes index. 1. Phase diagrams. 2. Mineralogical chemistry. 1. Jackson, K. J. (Kenneth J.).
II. Helgeson, Harold C. III. Title. QD503.B68. 1984.549'.133.84-20209.
This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned,
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Softcover reprint of the hardcover 1st edition 1984
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 PREFACE

This book represents a revision and expansion of an earlier set of diagrams for tempera-
tures from 25 to 300 C along the equilibrium vapor-liquid curve for H 20 (Helgeson, Brown,
0 0

and Leeper, 1969). The activity diagrams summarized in the following pages were generated
over a six year period from 1977 to 1983 in the Laboratory of Theoretical Geochemistry (oth-
erwise known as Prediction Centra!) at the University of California, Berkeley. They represent
the culmination of research efforts to generate a comprehensive and internally consistent set
of thermodynamic data and equations for minerals, gases, and aqueous solutions at high pres-
sures and temperatures. Among the many who contributed to the successful completion of
this book, we are especially indebted to David Kirkham, John Walther, and George Flowers,
who wrote program SUPCRT, Tom Brown, who created program DIAGRAM, and Eli Mess-
inger, who generated the Tektronix plot routine to construct the diagrams. Ken Jackson and
Terri Bowers both devoted an enormous amount of time and effort over the past six years to
produce the diagrams in the following pages; some of which went through many stages of
revision. Consequently, they appear as senior authors of this volume. It should be mentioned
in this regard that their equal dedication to the project made it necessary to determine their
order of authorship by flipping a coin. My own role in generating the diagrams was largely
supervisory, although I am responsible for the Introduction to the book. We would like to
express our appreciation to Carol Bruton, Dara Gilbert, Mike O'Leary, Tom Welsh, Laurel
Goodwin, Miki Moore, Ken Herkenhoff, Robert Woodward, Mary Gilzean, Cathy Wilson,
Eric Oelker~, Barry Draper, Sydney Dent, and Barbara Ransom, all of whom assisted to one
degree or another in generating the diagrams. Thanks are also due Mike Ryan, Greg Willi-
ams, Mike Salas, Robert Wong, Joachim Hampel, and Joan Bossart for drafting, photographic
reproduction, and typing the manuscript. We are particularly grateful to Robert Woodward
and Joan Bossart for their exceptional patience, talent, and dedicated effort toward completion
of this project. The research responsible for the diagrams was supported by the National Sci-
ence Foundation (NSF grants GA 35888, GA 36023, DES 74-14280, EAR 77-14492, and
EAR 81-15859), the donors of the Petroleum Research Fund administered by the American
Chemical Society (PRF grants 5356 AC2 and 8927 AC2C), the Miller Institute and Commit-
tee on Research at the University of California, Berkeley, and the Division of Physical
Research of the U.S. Energy Research and Development Administration in conjunction with
the Lawrence Berkeley and Livermore Laboratories of the University of California (ERDA
contracts UCB-ENG-4288 and W-7405-ENG-48). Computing funds contributed by the
University of California, Berkeley, are also acknowledged with thanks. Finally, we would like
to express our appreciation to Konrad Springer for his interest and support in undertaking
publication of this book.

June, 1984, Berkeley Harold C. Helgeson

 TABLE OF CONTENTS

Introduction ..................................................................................................................... IX
Figures ............................................................................................................................. XVII
Table 1. Fugacity coefficients of H 20 and CO 2 ................................................................ XXXI
Table 2. List of minerals and their abbreviations and formulas ....................................... XXXII
Table 3. Summary of hydrolysis reactions ...................................................................... XXXVI
References ....................................................................................................................... XLI
Activity diagrams ............................................................................................................... 1
Fugacity diagrams .............................................................................................................. 291
Appendix: Equilibrium constants for hydrolysis reactions ................................................. 307
Index of diagrams .................................. ..................................................................... ..... 369
 INTRODUCTION

Activity diagrams representing equilibrium among minerals and aqueous solutions facili-
tate considerably description and interpretation of phase relations in geologic systems. In
addition, they afford a convenient frame of reference for predicting the consequences of
mineral reactions, both in laboratory experiments and geochemical processes. Recent
advances in theoretical geochemistry make it possible to generate activity diagrams for pres-
sures and temperatures to 5 kb and 600°C. Diagrams of this kind are presented below for a
wide variety of multicomponent systems at the pressures and temperatures shown in figure 1.
The schematic arrangement of the diagrams depicted in this figure corresponds to that on two
facing pages of the book. The three schematic diagrams at the bottom of the left side of
figure 1 pertain to the liquid phase region along the vapor-liquid equilibrium curve for H 20.
Except in cases where the presence of amorphous silica is specified, or systems containing
CO 2 in which the activity of H 20 (aH 20) is less than unity, the diagrams in each set on two
facing pages represent phase relations in a single system subject to the constraints specified in
the caption at the bottom of each page. If the presence of amorphous silica is specified,
diagrams are depicted only on one page for a given system at temperatures ~ 300°C. For
systems containing CO 2 in which aH 20 < 1.0, diagrams are shown only on one page for a
given system at temperatures ~ 400°C. In the latter cases, a value of the mole fraction of
CO 2 (Xeo ) in the aqueous phase of 0.Q1, 0.05, 0.1, 0.3, 0.5, 0.7, 0.9, 0.95, or 0.99 is
specified in the caption at the bottom of each page of diagrams. The activities of H20 and
CO2 for the stipulated values of X eo2 were computed for X C02 + X H20 = 1 using equations
and parameters taken from Flowers (1979) and Flowers and Helgeson (1983), which provide
for nonideal mixing of eo2 and H20. The values of the fugacity coefficients used in the cal-
culations are given in table 1. The axes of the activity diagrams for specified values of X eo2
are labeled in terms of rr;, which is defined by (Walther and Helgeson, 1980)

(1)

where n H + and n; stand for the solvation numbers of the hydrogen ion and the ith aqueous
species other than the hydrogen ion, respectively, and Z; refers to the charge on the sub-
scripted species. By specifying the descriptive variables as log (aJ (rr; a ~~ )) in the diagrams
for stipulated values of XC02 , all phase relations can be portrayed accurately, regardless of the
actual state of solvation of the species in solution (Walther and Helgeson, 1980).
The compositions of the bulk of the rock-forming minerals in the Earth's crust can be
described in terms of the system MgO-CaQ-FeO-Na20-K2Q-AI203-Si02-C02-H20. If
the component HCI is added to the system, the major compositional characteristics of natural
aqueous solutions can also be described in terms of these components) Provision for ore
deposits and oxidation-reduction equilibria can be incorporated by adding the components
1 The term component is used in the present communication in its strict thermodynamic sense. A thermo-
dynamic component of a mineral corresponds to a chemical formula unit representing one of the minimum
number of independent variables required to describe the composition of the mineral. All stoichiometric
minerals are thus composed of a single component corresponding to the formula of the mineral. However,
because the term component has no physical connotation, .the minerals themselves are not components.
x
H 20, H 2S04, CU2S, PbS, ZnS, Ag 2S, etc. This set of components is one of several alternate
sets that can be chosen to describe the same geologic system (Helgeson, 1970a).
The activities of individual ions, complexes, or both may be used as descriptive vari-
ables in equilibrium activity diagrams. Four of the components listed above do not dissociate
to an appreciable extent in acid aqueous solutions. These are the components Si02, H 2S,
CO 2, and H 20, which occur primarily as neutral molecules. At low temperatures, the
remainder of the components are essentially completely dissociated. CO 2, H 2S, and Si0 2(aq)
dissociate at low temperatures only in alkaline solutions, where CO 2 reacts with OH- to form
HC03 , which then dissociates to H+ and C0 3- with increasing pH. Similarly, H 2S dissociates
to H+ and HS- as pH increases in alkaline solutions. At low temperatures and high pH,
Si0 2(aq) is apparently present primarily as H 3Si04 . At high temperatures, molecular species
predominate over their ionic counterparts in hydrothermal solutions.
Homogeneous equilibrium in an aqueous solution can be represented by writing reversi-
ble reactions among the thermodynamic components of the solution and their dissociated
counterparts. For example, we can write for the component Na20
Na20 + 2 H+ = 2 Na+ + H20 (2)

for which

where K(2) refers to the .equilibrium constant for reaction (2). Note also that we can write
Na20 + H20 = 2 Na+ + 2 OH- (4)

for which
(5)

where K(4) denotes the equilibrium constant for reaction (4). The ionic species in reactions
(2) and (4) predominate at low temperatures in acid and alkaline solutions, respectively.
However, in the supercritical region the molecules NaCI and HCI predominate over Na+ and
H+, respectively, in hydrothermal solutions (Quist and Marshall, 1968; Helgeson, 1969;
Helgeson, Kirkham, and Flowers, 1981; Franck, 1982). Equilibrium among these molecular
species can be expressed as
(6)

for which

where K(6) refers to the equilibrium constant for reaction (6). Similarly, equilibrium between
the component Na20 and the NaOH molecule can be represented by
(8)

for which
(9)

where K(8) designates the equilibrium constant for reaction (8). Combining equations (3),
(5), (7), and (9) leads to
 XI

and
(1)

which relate the various descriptive variables to one another. If we now take account of
f.LNap = f.L °Nap + 2.303 RT log aNap (2)

and
(13)

we can write for constant pressure and temperature,

d log (aNa+1 aH+) = (d log (aNapl aH 20)) I 2 = d log (aNacll aHC1)

= (df.LNap - df.LHp)1 2(2.303) RT (4)

and
d log (aNa+aOW ) = (d log (aNa20aHp)) I 2 = d log (aNaOH)

= (df.L Na20 + df.LH 20)1 2(2.303) RT (15)

where f.L Na 20 , f.L °Na20, f.LH 20, and f.L °H 20 stand for the chemical potential and standard chemical
potential of the subscripted components, respectively, R refers to the gas constant, and T
stands for temperature in Kelvins.
Equations (4) and (15) relate the change in the ratio or product of the activities of the
aqueous species corresponding to descriptive variables in various equilibrium activity diagrams
to the change in the chemical potentials of Na20 and H 20 in the system. Reactions and
equations analogous to reactions (2), (4), (6), and (8), and equations (3), (5), (7), and (9)
through (15) can be generated for any thermodynamic component. For most purposes in
geochemistry, the ratios of the activities of individual cations commonly found in minerals to
that of H+ (raised to the power of the charge on the cation) are probably the most suitable
choice of descriptive variables for activity diagrams at temperatures < 600°C. These ratios
can be converted to other ratios with the a{d (for example) of equation (0) and equilibrium
constants taken from sources cited in Helgeson and Kirkham (976).
Except for systems in which CO 2 is a component and values of XC02 in the fluid are
specified, the activity and fugacity diagrams presented in the following pages were generated
for aH 20 = 1, relative to the liquid standard state (see below). It can be shown that the
activity of H 20/iquid departs only slightly from unity in most natural aqueous solutions at the
temperatures and pressures considered in the present study (Helgeson, 1969, 1982a; Helge-
son, Kirkham, and Flowers, 1981).
The diagrams that follow are based on a standard state for minerals and liquid H20 of
unit activity of the pure solid or liquid at any pressure and temperature, but that for gases is
one of unit fugacity of the hypothetical perfect gas at 1 bar and any temperature. It follows
that the activities of components corresponding to stoichiometric minerals and pure liquid
H20 are unity, and the fugacities of gases are equal to their activities at all pressures and tem-
peratures. The standard state for aqueous species corresponds to unit activity of the species
XII

in a hypothetical one molal solution referenced to infinite dilution at any pressure and
temperature. The activity coefficients of aqueous species thus approach one at both high and
low temperatures and pressures as the activity of the solvent (relative to the liquid standard
state) approaches unity. In contrast, the fugacity coefficients of the components of gas mix-
tures approach the fugacity coefficients of the pure gases (which are not necessarily unity) as
the mole fractions of the gases approach unity at any pressure and temperature.
The thermodynamic data and equations for minerals, gases, and aqueous species used to
locate the stability field boundaries in the activity and fugacity diagrams presented below were
taken from Helgeson (1982b, 1984), Helgeson and Kirkham 0974a), Walther and Helgeson
(1977), Helgeson and others (1978), Bird and Helgeson (1980), and Helgeson, Kirkham, and
Flowers (1981). Equations and data taken from these sources were also used to generate the
curves shown in figures 2 through 14, as well as the equilibrium constants given in the
Appendix. The calculations were carried out on the CDC 6400 computer (since replaced) at
the University of California, Berkeley, with the aid of programs SUPCRT (written by D.H.
Kirkham, J.V. Walther, and G.C. Flowers) and DIAGRAM (written by T.H.Brown). The
diagrams were generated on a Tektronix digital plotter using a software package written by Eli
Messinger. Because the diagrams were generated by a computer, the labels on the abscissa
and ordinate of each diagram are printed in computer notation; e.g., log (a Mg++/ a ~+) appears
as LOG (A(MG++)/(A(H+»**2). The stoichiometric minerals considered in the present
study are listed in table 2, together with their abbreviations and formulas. The hydrolysis
reactions for the minerals are shown in table 3, and the equilibrium constants for the reac-
tions are given in the Appendix.
The equilibrium constant for a given stability field boundary on a logarithmic activity
diagram can be generated by adding and/or subtracting values of log K taken from the
Appendix. For example, the equilibrium constant for the stability field boundary correspond-
ing to
Ca2MgsSi8022(OH)z + Mg++ + 2 H+ = 2Mg 3Si 40 lO (OH)Z + 2 Ca++ (16)
(Iremalile) (talc)

can be calculated by subtracting 2 log K lalc hydrolysis from log Klremalile hydrolysis in the Appendix.
All of the equilibrium constants listed in the Appendix are consistent with the liquid standard
state for HzO. However, a number of the activity diagrams in the following pages were gen-
erated by adopting the gas standard state for HzO and COz, which permits calculation of the
fugacities of HzO and COz from specified mole fractions of the gases (for X H20 + XC02 = 1)
using the fugacity coefficients shown in table 1 and the relation
(17)

where P stands for pressure and Ii' Xi, and Xi refer to the fugacity, fugacity coefficient, and
mole fraction of the ith gas component. The difference in the standard molal Gibbs free
energy of HZOUiqUid) and Hz0(gas) divided by RT is depicted as a function of temperature and
pressure in figure 2. If the values shown in this figure are multiplied by the number of moles
of HzO in a given hydrolysis reaction in table 3, addition of the resulting values to those of
log K for the reaction given in the Appendix leads to corresponding values of log K con-
sistent with the gas standard state for HzO. Similarly, log K values given in the Appendix for
hydrolysis reactions written in terms of HC0 3 , HS-, and SO" can be converted to log K
values for corresponding reactions involving COZ(gas), SZ(gas), and 02(gas) by taking account of
the equilibrium constants plotted in figures 3 through 5. In certain cases, diagrams are
presented below for specified values of log (aH+a HS-). Corresponding values of logaH 2s(aq)
and log/H 2s(g) can be generated from the curves shown in figures 6 and 7.
 XIII

Thermodynamic relations and methods used in the construction and interpretation of

equilibrium activity diagrams have been summarized in a number of publications (c.f., Gar-
rels and Christ, 1965; Helgeson, 1968, 1970a; Helgeson, Brown, and Leeper, 1969; Walther
and Helgeson, 1980; Aagaard and Helgeson, 1983). The position and slope of a given stabil-
ity field boundary on such diagrams is determined by the stoichiometry of the minerals and
the equilibrium constant for the reversible reaction chosen to represent the equilibrium state.
For example, equilibrium among clinochlore, muscovite, quartz, and an aqueous phase can be
expressed as
3 Mg sAI(AISi 30 IO)(OH)s + 2K+ + 28 H+
(c1inochlore)

= 2KAI 2(AISi 30 IO) (OH)2 + 15 Mg++ + 3 Si02 + 24 H 20 (18)

(muscovite) (quartz)

for which the law oC mass action can be written for unit activity of Si02,
MgsAI(AISi 30 IO)(OH)s, and KAI 2(AISi 30 IO)(OH)2 as (Walther and Helgeson, 1980)

where (J" Mg++ and (J" K+ are defined by appropriate statements of equation (1) and K(ls) refers
to the equilibrium constant for reaction (18) at the pressure and temperature of interest. If
the activity of H 20 (relative to the liquid standard state) in the aqueous phase is unity, or
nearly so (which is commonly the case in geologic systems--see above) equation (19) reduces
to
(20)

However, if CO 2 or some other component is present in mole fractions greater than - 0.01,
the activity of H2 0 may differ appreciably from unity. Under these circumstances, equation
(19) must be used to describe accurately the equilibrium state. This is particularly true for
reactions in which the reaction coefficient of H 20 is large. Under these circumstances, the
effect of small departures of aH20 from unity on the positions of stability field boundaries may
be magnified considerably.
The value of (log K(lsY)/ 15 in equations (19) and (20) determines the intercept of the
linear curve separating the stability fields of clinochlore and muscovite on activity diagrams
with log (a Mg++/ «(J" Mg++a~+)) or (for unit aH 20) log (a Mg++/ a~+) on the ordinate and
log (a K+/ «(J" K+aH+)) or (again for unit aH 20) log (a K+/ a H+) on the abscissa. The slope of the
curve is equal to 2/15, which is related to the slopes of corresponding curves on other activity
diagrams representing the same equilibrium state by the quotient of appropriate differential
equations like those shown in equation (14). In all cases, a value is specified for aHp, which
is a constant for each diagram. In contrast, the activities of (in this case) aluminum species
in the aqueous phase vary from place to place in the diagram. Alternate diagrams with
different descriptive variables such as log (a Al+++/ a~+) on the axes are depicted below to
facilitate determination of the extent of this variation. These include diagrams generated by
choosing alternately A1 20 3, MgO, CaO, and Si02 as the balancing component in the reversible
reactions representing the stability field boundaries on the diagrams. For example, equili-
brium among K-feldspar, muscovite, and an aqueous phase can be expressed as
3 KAISi 30 s + 2 H+ = KAI 2(AISi 30 lO) (OH)2 + 2 K+ + 6 Si0 2 (aq) (21)
(K - feldspar) (muscovite)
XIV
or
KAISi 30 s + 2 Al+++ + 4H20 = KAI 2 (AISi 30 lO )(OHh + 6 H+ , (22)
(K - feldspar) (muscovite)

which correspond to only two of several reversible reactions that could be written to describe
the equilibrium state. If we now set aKA1Si 308 = aKA1 2(A1Si 30 IO)(OH)2 = aHp = 1 and designate
the equilibrium constants for reactions (21) and (22) as K(21) and K(22), respectively, it fol-
lows that we can write
(23)
and
log (a Al+++/ a ~+) = -log K(22)/ 2 (24)

which describe the stability field boundary separating K-fddspar and muscovite on
log (a K+/ a H+) vs log a Si0 2(aq) and log (a K+/ a H+) vs log (a Al+++/ a ~+) diagrams, respectively.
With the exception of analcime and cordierite (see below), only stoichiometric minerals
were considered in constructing the activity diagrams presented in the following pages. Provi-
sion for solid solution can be incorporated in the diagrams by taking account of activity
coefficients in a statement of the law of mass action for a given stability field boundary. In
some cases it may suffice simply to contour stability field boundaries for various activities of a
given thermodynamic component of a solid solution corresponding to 0.9, 0.5, etc. Although
many of the minerals considered in the calculations exhibit variable composition in nature, if
the extent of solid solution is of the order of five or ten percent (or less), solid solubility has
a slight effect on most of the phase relations depicted in the diagrams. Possible exceptions to
this generalization are iron-magnesian phyllosilicates such as chlorite and biotite, which can
be taken into account with the aid of equations summarized by Aagaard and Helgeson
(1983), Helgeson and Aagaard (1984), and others. Several examples of activity diagrams in
which provision for solid solution has been incorporated can be found in Bird and Helgeson
(1981), Aagaard and Helgeson (1983), and Frisch and Helgeson (1983).
Although an aqueous phase does not appear explicitly in the activity diagrams that fol-
low, it is a coexisting phase in all stability fields; i.e., the ~queous phase is saturated with the
minerals appearing in the stability fields of the diagrams. The dashed lines labeled in lower
case letters represent saturation limits in the aqueous phase for various minerals (identified in
the caption at the bottom of the page) that do not occupy stability fields in the diagrams.
Fluids with log (aJ ((1" i a ~~» less than those limits are undersaturated with respect to the
minerals represented by the labels on the saturation limits, and those at greater values of
log (aJ ((1" i a ~~ » are supersaturated. Both stable and metastable equilibria among minerals
and the aqueous phase are thus represented in the diagrams.
A number of the activity diagrams depicted below include provision for equilibrium
among the aqueous phase and ubiquitous minerals that coexist with those shown in the stabil-
ity fields of the diagram. For example, the presence of quartz may be specified (as in reac-
tion 18). In others, amorphous silica and albite, quartz and albite, quartz and K-feldspar, or
corundum, diaspore,2 or gibbsite (depending on which of the latter phases is stable at the
pressures and temperatures shown in figure 8) are stipulated to be in equilibrium with the

2 Boehmite is apparently metastable in the presence of H20 at all pressures and temperatures (Delany and
Helgeson, 1978).
 xv
aqueous phase, which is also in equilibrium with the various minerals shown in the stability
fields of the diagrams. Such specifications increase considerably the variety of phase relations
that can be represented in two dimensions. For example, equilibrium among amphibole, pla-
gioclase, garnet, and an aqueous phase can be represented on a log (a Ca++/ a ~+) vs
log (a Mg++/ a ~+) diagram by taking account of
NaCa2Mg4AI(AI2Si6022)(OH)2 + Ca++ + 6 H+
(pargasite)

= Ca3Al2Si3012 + NaAISi 30 8 + 4 Mg++ + 4 H 20 (25)

(grossular) (albite)

For unit activities of NaCa2Mg4AI(AI2Si6022) (OH)2, NaAISi 30 s, Ca3A12Si3012, and H 20, the
law of mass action for reaction (25) can be written as

log (a Ca++/ a ~+) = 4 log (a Mg++/ a ~+) - log K(2S) (26)

where K(2S) represents the equilibrium constant for reaction (25). Despite the fact that
log (a Na+/ a H+) is not a descriptive variable in the diagram, pargasite may occupy a stability
field because reaction (25) is balanced simultaneously on Al 20 3 and Na20.
Except where noted otherwise in the page captions and Index citations, all of the
minerals listed in table 2 were considered in the calculations. In certain cases diagrams are
presented below in which metastable chrysotile and/or metastable 7A-clinochlore were con-
sidered in lieu of their stable counterparts (antigorite and 14A-clinochlore, respectively).
Comparison of the phase relations shown in these diagrams with those in which antigorite
and/or 14A-clinochlore were considered permits evaluation of the consequences of metasta-
bility in these systems. Except where cited in conjunction with their monoclinic analogs,
enstatite and ferrosilite are used in the following pages to refer to the stable polymorphs of
MgSi0 3 and FeSi0 3 at any pressure and temperature. In contrast, zoisite is used to denote
only the orthorhombic form of Ca2AIJSi3012(OH). The terms K-feldspar, albite, dolomite,
and epidote refer to KAISi 30 8, NaAISi J0 8, CaMg(C0 3h and Ca2FeAI2Si3012(OH) in their
stable states of order/disorder at any pressure and temperature. Stability field boundaries for
the completely disordered and/or ordered analogs of these minerals can be generated from
those shown in the diagrams for the minerals in their stable states of order/disorder by taking
account of the equilibrium constants plotted in figures 9 through 12.
The terms analcime and cordierite are used below to refer to the equilibrium composi-
tion of NaAISi 20 6'(H 20)n and Mg2AI3(AISis018)' (H 20)n' respectively, where n corresponds
to the mole fraction of NaAISi 20 6·H 20 or Mg 2AI 3(AISi sOI8)'H 20 in the minerals. The com-
positions were computed for aH 20 = 1 assuming ideal mixing of the components which is
consistent with (Helgeson and others, 1978),

XNaAlSiP6' H20
-----=--=--=-- = K(29) (27)
1 - XNaAlSiP6'H20
and
XMg2Al3 (AlSis0 1S)' Hp
-c--------- = K(3O) (28)
1 - XMg2AI3(AlSis01S).H20
XVI

where K(29) and K oo ) correspond to the equilibrium constants for

NaAISi 20 6 + H 20 = NaAISi 20 6· H20 (29)
and
(30)

respectively. The equilibrium mole fractions of NaAISi 20 6 and Mg2Alj(AISis018) in the solid
solutions are shown as a function of temperature and pressure in figures 13 and 14.
The fugacities of CO 2, O2, and S2 {J co 2 , f O 2 , and f 52' respectively) are used as descrip-
tive variables in a number of the diagrams presented below. The fugacities of these gas
species are related to their activities by (for example)
(31)

where f °0 2 stands for the fugacity of O2 in the standard state. For the ga~ standard state
adopted in the present study (see above), f °0 2 = 1, so f O2 = a0 2. The ordinate and abscissa
in each of the fugacity diagrams are labeled in computer notation; e.g., log! O 2 appears as
LOG F(02).
The systems represented by the diagrams summarized below are designated in the page
captions and Index by the thermodynamic components considered in the calculations. Of
these, the balancing component is shown in parentheses. The components represented by the
descriptive variables on' the ordinate and abscissa are shown in italics in the Index, as (for
example) in the system HCI-H20-Na20-(AI20j)-K20-Si02 at quartz saturation. Accord-
ingly, all reactions among the minerals in this system that contain AI 20 j were balanced on
this component to generate the stability field boundaries in the activity diagrams. All other
minerals in the system are represented by saturation limits as a function of log (a Na +/ a H+)
and/ or log (a K+/ aH+), which correspond to the descriptive variables in the diagrams. It fol-
lows from equation (3) and its counterpart for log (a K +/ aH+) that with aH 20 = 1, those vari-
ables represent the activities of Na20 and K20, respectively. HCI and H 20 are components of
all the systems considered in the following pages.
Part of the purpose of generating the theoretical activity diagrams summarized in the
present communication is to stimulate critical comparison of the predicted phase relations
with those observed in laboratory experiments and geologic systems. It should perhaps be
emphasized in this regard that analytical- data for natural aqueous solutions can be used to cal-
culate the activities of species in these solutions. The requisite dissociation constants and
activity coefficients for aqueous species can be generated from experimental data and theoreti-
cal equations (Helgeson, 1969; 1982a; Helgeson and Kirkham, 1974b, 1976; Helgeson, Kirk-
ham, and Flowers, 1981). Such calculations make it possible to compare equilibrium activity
ratios taken from activity diagrams with those in natural solutions, and to interpret directly
phase relations observed in geologic systems in terms of their idealized counterparts in
activity diagrams. This approach affords considerable insight into the chemical environment
in which geochemical processes occur. It also facilitates prediction of mass transfer in geologic
systems (c.f. Helgeson, 1968, 1970b, 1979; Helgeson, Garrels, and Mackenzie, 1969; Helge-
son, Brown, Nigrini, and Jones, 1970; Helgeson and Murphy, 1983).
 XVII

T ~~~5.0 5.0 5.0 §§§5.0 5.0 5.0

§ 150~ I §
m

~~~
~

w
. 3.0 3.0 3.0 3.0 3.0 3.0
a::
:::>

GJ ~ ~ ~ G~
en
en
w
0:: 1.0 1.0 1.0 1.0 1.0 1.0
a..

~ §
0.001
1
300°1 0.005 0.086 § 0.5
150~1
0.5 § 0.5

TEMPERATURE, °c ~
Fig. l. Schematic arrangement of the activity diagrams for a given system on two facing
pages of the present communication. Each small rectangle represents an activity diagram for
the indicated temperature (in °C) and pressure (in kb).
XVIII

4.0 r-------------------......,

3.0

2.0
I-
a::

-...
"-

0
c.
1.0
0
0>
(!)
I 0
~
~
0-

-
°
(!) -1.0

-2.0

- 3. 0 '--_----1_ _........._ _-01.._ __'"__ _...1...-_---'

o 100 200 300 400 500 600

TEMPERATURE. °c
Fig. 2. Standard molal Gibbs free energy difference for H20Uiquid) and H 20(gas) divided
by RT as a function of temperature at constant pressure. SAT refers to the vapor-liquid
equilibrium curve for H 20.
 XIX

24~---------------------------------.

22

20

18

16

14

12

10

6~----~----~----~----~----~--~
o 100 200 300 400 500 600
TEMPERATURE, °c

Fig. 3. Equilibrium constant for the reaction HCO} + H+ = CO 2 (gas) + H 20(t;QUid) as a

function of temperature at constant pressure (see caption of figure 2).
xx
45r---------------------------------~

40

35

25

20

15~----~----~----~----~----~--~
o 100 200 300 400 500 600
TEMPERATURE.OC

Fig. 4. Equilibrium constant for the reaction H+ + 112 O2 + HS- = 112 S2(gas) +
H20Ulquid) as a function of temperature at constant pressure (see caption of figure 2).
 XXI

160~--------------------------------~

140

120

100

(!) 80
o
...J

60

40

20

o
o 100 200 300 400 500 600
TEMPERATURE. °C

Fig. 5. Equilibrium constant for the reaction 2 02(gas) + HS- = SO; + H+ as a func-
tion of temperature at constant pressure (see caption of figure 2).
XXII

-6.0 ~------.-------.,.-------,

-7.0

-8.0

-9.0
o 100 200 300
TEMPERATURE,oC

Fig. 6. Equilibrium constant for the reaction H 2S Caq ) = H+ + HS- as a function of tem-
perature at pressures corresponding to the vapor-liquid equilibrium curve for H 20 (Helgeson,
1969) .
 XXIII

-7~--~~--------~----~-----r-----

-8 ...-----

-9

~
-10
C!)
0
..J
-II

H2S(g)~H++ HS-
-12

-13 ' - - - - - - - & . - -.........- - . . . . & . - - - . . I . . . . -..........----I-..I....-~

o 100 200 300 400 500 600

TEMPERATURE, °c
Fig. 7. Equilibrium constant for the reaction H 2S(gas) = H+ + HS- as a function of
temperature at constant pressure (see caption of figure 2).
XXIV

5--------~~-------------r------~

m 4
~
.. GIBBSITE DIASPORE CORUNDUM
l&J
0:: 3
::>
U)
U)
l&J
0::
C- 2
o
C\I
:J:
CRITICAL
SAT" IPOINT (H 2 O)

0 100 200 300 400 500 600

TEMPERATURE. °c
Fig. 8. Stability fields of gibbsite, diaspore, and corundum in the system Al 20 3 - H20 as
a function of temperature and H 20 pressure (Helgeson et al., 1978)--see caption of figure 2.
 xxv
0.5

r (
KAISi30S
(K- FELDSPAR)
~ KAISi 3 0 S
(MAXIMUM MICROCLlNE)
)

~
° SAT, ',3.5KB
~==-......:::::::::::J

~'f..<O
(!) \~.
0-0.5 S~~· •
...J

KAISi3 Os ~ KAISi 3 0 8 )
(
L (K-FELDSPAR) (HIGH SANIDINE)
- 1.0

-1.5

° 100 200 300

TEMPERATURE ,oC
400 500 600

Fig. 9. Equilibrium constants for the metastable coexistence of completely ordered (mi-
crocline) and disordered (high sanidine) KAlSi 30 s with K-feldspar in its stable state of substi-
tutional order/disorder as a function of temperature at constant pressure (see caption of
figure 2).
 XXVI

0.5
NaAISi30a ~ NaAISi30~
f [
(ALBITE) (LOW ALBITE~

° 1--------SAT.,1,3,5KB
------
~

0.5
g
(!) -

-1.0 :# NaAISi 30 a l
(HIGH ALBITE~

-1.5
°
1.&.-_---'"_ _- - ' -_ __'___ _...1.--_ _' - - - _ - - . 1

100 200 300 400 500 600

TEMPERATURE,oC

Fig. 10. Equilibrium constants for the metastable coexistence of completely ordered
(jow albite) and disordered (high albite) NaAlSi 30 g with albite in its stable state of substitu-
tional order/disorder as a function of temperature at constant pressure (see caption of figure
2).
 XXVII

0.5
CoMg(C03)2
( (DOLOMITE)
CoMg (C0 3 )2)
(ORDERED
DOLOMITE)
l
o 1---------SAT,/,3,5KB--oiiiiI

~-0.5
(!)
o
.....J

-1.0
L (COM9(C0 3 )2 ~ COM9{C03)2~
(DOLOMITE) (DISORDERED
DOLOMITE)
-1.5

-2.0
o 100 200 300 400 500 600
TEMPERATURE,oC

Fig. 11. Equilibrium constants for the metastable coexistence of completely ordered
and disordered CaMg(C0 3)2 with dolomite in its stable state of substitutional order/disorder
as a function of temperature at constant pressure (see caption of figure 2).
XXVIII

0.25 I , , I

°
----
SAT. f.3,5KB ________
~
(!)

9 -0.25 .. C02FeAI2Si3012(OH) # C02FeAI2Si3012(OH).

(EPIDOTE) (ORDERED EPIDOTE)

-0.50 I I I I

° 100 200 300

TEMPERATURE.oC
400 500 600

Fig. 12. Equilibrium constants for the metastable coexistence of completely ordered
Ca2FeAI2Si3012(OH) with epidote in its stable state of substitutional order/disorder as a func-
tion of temperature at constant pressure (see caption of figure 2).
 XXIX

o ----~~--~----~----~----~-----,

-
-I
0(\J
I .
oW-2
(\J
(J)
<t
c
Z
X -3

-
I

-4

-5 ~--~~--------~----~----~----~
o 100 200 300 400 500 600
TEMPERATURE, °c

Fig. 13. Equilibrium composition of analcime computed from equation (27) as a func-
tion of temperature at constant pressure (see caption of figure 2).
xxx

-
-4~--~----~----~~--~--~~--~
o 100 200 300 400 500 600
TEMPERATURE,oC

Fig. 14. Equilibrium composition of cordierite computed from equation (28) as a func-
tion of temperature at constant pressure (see caption of figure 2).
 XXXI

Table 1. Fugacity coefficients of H20 (XH 20) and CO 2 (Xeo 2 ) in H20-C0 2 fluids computed
from equations and parameters given by Flowers (I979) and Flowers and Helgeson (I 983).

XH,o
PRESSURE - 0.5 KB
T:C X eo,
0.01 0.05 0.10 0.30 0.50 0.70 0.90 0.95 0.99
400 0.394 0.399 0.413 0.487 0.529 0.558 0.583 0.588 0.592
500 0.665 0.666 0.667 0.670 0.670 0.667 0.663 0.661 0.660
600 0.789 0.789 0.788 0.779 0.764 0.746 0.726 0.721 0.717
PRESSURE - 1.0 KB
400 0.248 0.250 0.257 0.303 0.353 0.398 0.439 0.448 0.456
500 0.462 0.464 0.468 0.488 0.505 0.517 0.526 0.527 0.528
600 0.641 0.641 0.641 0.637 0.628 0.616 0.602 0.598 0.595
PRESSURE - 3.0 KB
400 0.182 0.184 0.189 0.223 0.271 0.327 0.386 0.402 0.414
500 0.350 0.351 0.354 0.377 0.405 0.433 0.458 0.463 0.468
600 0.520 0.521 0.522 0.526 0.529 0.529 0.527 0.526 0.526
PRESSURE - 5.0 KB
400 0.223 0.225 0.231 0.276 0.342 0.422 0.514 0.538 0.558
500 0.414 0.416 0.420 0.451 0.491 0.533 0.574 0.584 0.592
600 0.605 0.605 0.607 0.616 0.625 0.632 0.636 0.636 0.637
Xco,
PRESSURE - 0.5 KB
T:C X co,
0.01 0.05 0.10 0.30 0.50 0.70 0.90 0.95 0.99
400 6.125 4.128 2.714 1.248 1.092 1.051 1.039 1.038 1.038
500 1.167 1.133 1.110 1.084 1.084 1.086 1.088 1.088 1.088
600 0.977 0.990 1.006 1.056 1.087 1.105 1.112 1.113 1.113
PRESSURE - 1.0 KB
400 6.650 4.812 3.474 1.700 1.333 1.226 1.195 1.193 1.192
500 2.026 1.815 1.640 1.356 1.284 1.262 1.257 1.257 1.257
600 1.193 1.196 1.202 1.233 1.260 1.276 1.284 1.284 1.284
PRESSURE - 3.0 KB
400 17.035 12.667 9.366 4.572 3.369 2.966 2.839 2.830 2.828
500 5.354 4.772 4.250 3.244 2.903 2.775 2.735 2.732 2.731
600 2.849 2.789 2.733 2.629 2.604 2.603 2.606 2.606 2.606
PRESSURE - 5.0 KB
400 50.607 37.496 27.549 13.004 9.309 8.054 7.656 7.628 7.619
500 13.950 12.338 10.880 8.033 7.035 6.650 6.523 6.514 6.511
600 6.596 6.407 6.225 5.840 5.708 5.665 5.655 5.654 5.654
XXXII

Table 2, Minerals, abbreviations, and formulas,

Index
Mineral Name Abbreviation Formula
Number
1501 Acanthite ACAN Ag 2S
1044 Akermanite AKER Ca2MgSi207
1092 Alabandite ALA MnS
1531 Albite ALB NaAISi 30 g
1560 Albite, High HI-ALB NaAISi 30 g
1025 Albite, Low LO-ALB NaAISi 30 g
1083 Alunite ALUN KAI 3(OH)6(S04h
1125 Amorphous Silica AMORPH SIL Si0 2'nH 2O
1022 Analcime ANAL NaAISi 20 6,H 2O
1021 Analcime, Dehydrated DEHYD-ANAL NaAISi 20 6
1001 Andalusite AND Al2Si05
1530 Andradite ANDRA Ca3Fe2Si3012
1081 Anglesite ANG PbS0 4
1078 Anhydrite ANHYD CaS04
1015 Annite ANNITE KFe3 (AISi 30 lO) (OH) 2
1030 Anorthite ANOR CaAl2Si2Og
1518 Anthophyllite ANTH Mg 7Sig0 22 (OH) 2
1542 Antigorite ANTIG Mg4gSi340g5(OH)62
1072 Aragonite ARAG CaC03
1053 Artinite ART Mg 2(OH)2C03,3H2O
1060 Azurite AZUR CU3(OHh(C03)2
1080 Barite BARITE BaS04
1116 Boehmite BOEH AIO(OH)
1503 Bornite BN CU5FeS4
1117 Brucite BRUC Mg(OHh
1040 Ca-AI Pyroxene CA-AL PYX CaAI (AISi06)
1073 Calcite CALC CaC03
1082 Celestite CELEST SrS04
1068 Cerussite CER PbC03
1128 Chalcedony CHALCED Si02
 XXXIII
Table 2 continued. Minerals, abbreviations, and formulas.

Index
Mineral Name Abbreviation Formula
Number
1504 Chalcocite CC CU2S
1502 Chalcopyrite CP CuFeS2
1007 Chrysotile CHRYS Mg 3Si20 S (OH) 4
1091 Cinnabar CINN HgS
1512 Clinochlore, 7-A 7-ACL Mg sAI(AISi 30 IO) (OH)g
1513 Clinochlore, 14-A 14-A CL Mg sAI(AISi 30 IO) (OH)g
1515 Clinozoisite CLNZ Ca2A13Si3012 (OH)
1102 Copper, Native COPPER Cu
1065 Cordierite ANH-CORD Mg2Al 3(AISi s0 1g)
1066 Cordierite, Hydrous HYD-CORD Mg2Al 3(AISi s0 1g)' H 2O
1108 Corundum COR aAl20 3
1086 Covellite COY CuS
1126 Cristobalite, Alpha A-CRIST Si02
1127 Cristobalite, Beta B-CRIST Si02
1112 Cuprite CUP CU20
1115 Diaspore DIAS AIO(OH)
1039 Diopside DIOP CaMg(Si03h
1075 Dolomite DOL CaMg(C03h
1070 Dolomite, Disordered DIS-DOL CaMg(C03h
1071 Dolomite, Ordered ORD-DOL CaMg(C03)2
1537 Enstatite ENST MgSi03
1545 Epidote, Ordered ORD-EP Ca2FeA12Si3012 (OH)
1559 Epidote EPID Ca2FeA12Si3012 (OH)
1049 Fayalite FAY Fe2Si04
1508 Ferrosilite FERROSIL FeSi03
1113 Ferrous Oxide FE-OXIDE FeO
1079 Fluorite FLUORITE CaF2
1048 Forsterite FORST Mg 2Si04
1087 Galena GALENA PbS
1047 Gehlenite GEHL Ca2Al2Si07
XXXIV

Table 2 continued. Minerals, abbreviations, and formulas.

Index
Mineral Name Abbreviation Formula
Number
1114 Gibbsite GIBBS AI(OHh
1100 Gold, Native GOLD Au
1103 Graphite GRAPHITE C
1529 Grossular GROSS Ca3A12Si3012
1106 Halite HALITE NaCI
1054 Hedenbergite HED CaFe(Si03)2
1544 Hematite HM Fe203
1050 Huntite HUNT CaMg3(C03)4
1062 Hydromagnesite HYDRO-MAG Mgs(OH)2(C03)4·4H20
1067 Jadeite JADEITE NaAI(Si0 3h
1507 Kalsilite KALS KAISi0 4
1004 Kaolinite KAOL Al 2Si 20 s (OH) 4
1028 K-feldspar K-SPAR KAISi 30 g
1002 Kyanite KYA Al 2SiO s
1132 Laumontite LAUM Ca(AI 2Si40 12)·4H2O
1516 Lawsonite LAWS CaAl2Si 20 7 (OH) 2· H2O
1110 Lime LIME CaO
1074 Magnesite MAG MgC0 3
1506 Magnetite MG Fe304
1059 Malachite MALACH CU2(OH)2C03
1119 Manganosite MANGAN MnO
1551 Margarite MARG CaAl2 (AI2Si20 IO) (OHh
1045 Merwinite MERW Ca3Mg(Si04h
1090 Metacinnabar M-CINN HgS
1027 Microcline, Maximum MAX-MICRO KAISi 30 g
1046 Monticellite MONTI CaMgSi04
1012 Muscovite MUSC KAI2(AISi 30 IO) (OH)2
1031 Nepheline NEPH NaAISi04
1558 Nesquehonite NESQ MgC0 3·3H2O
1013 Paragonite PARAG NaAI 2 (AISi 30 IO) (OHh
 XXXV

Table 2 continued. Minerals, abbreviations, and formulas.

Index
Mineral Name Abbreviation Formula
Number
1538 Pargasite PARG NaCa2Mg4AI(AI2Si6022) (OH) 2
1109 Periclase PER MgO
1014 Phlogopite PHLOG KMg 3(AISi 30 IO) (OH) 2
1123 Potassium Oxide K-OXIDE K20
1532 Prehnite PREHN Ca2Al(AISi301O) (OHh
1093 Pyrite PYRITE FeS2
1509 Pyrophyllite PYROPH AI 2Si 4O IO (OH)2
1555 Pyrrhotite PO FeS
1505 Quartz QTZ Si02
1552 Quicksilver MERCURY Hg
1085 Rhodochrosi te RHODO MnC0 3
1029 Sanidine, High HI-SAN KAISi 30 g
1023 Sepiolite SEPIO Mg4Si60 1S (OH)2 (OH 2h (OH 2)4
1076 Siderite SIDER FeC03
1003 Sillimanite SILL Al 2SiOs
1101 Silver, Native SILVER Ag
1064 Smithsonite SMITH ZnC03
1124 Sodium Oxide NA-OXIDE Na20
1088 Sphalerite SL ZnS
1120 Spinel SPINEL MgAl 20 4
1069 Strontianite STRONT SrC03
1107 Sylvite SYLVITE KCI
1510 Talc TALC Mg3Si 4OIO (OH)2
1111 Tenorite TO CuO
1517 Tremolite TREM Ca2MgsSig022 (OH) 2
1130 Wairakite WAIR Ca (AI 2Si40 12 )· 2H 2O
1084 Witherite WITH BaC03
1035 Wollastonite WOLL CaSi03
1089 Wurtzite WURT ZnS
1519 Zoisite ZOIS Ca2AI3Si3012(OH)
 Table 3" Summary of hydrolysis reactions"
><
><
><
Index Mineral Reaction -<
. -
1001 AND AI 2Si0 5 + 6H+ = 2AI+++ + Si0 2(aq) + 3H 2O
1002 KYA AI 2Si0 5 + 6H+ = 2AI+++ + Si0 2(aq) + 3H 2O
1003 SILL AI 2Si0 5 + 6H+ = 2AI+++ + Si0 2(aq) + 3H 2O
1004 KAOL AI 2Si 20 5(OH)4 + 6H+ = 2AI+++ + 2Si0 2(aq) + 5H 2O
1007 CHRYS Mg)Si 20 5(OH)4 + 6H+ = 3Mg++ + 2Si0 2(aq) + 5H 2O
1012 MUSC KAI 2(AISi)OlO)(OH)2 + lOH+ = K+ + 3AI+++ + 3Si0 2(aq) + 6H 2O
1013 PARAG NaAI 2(AISi)OlO)(OH)2 + lOH+ = Na+ + 3AI+++ + 3Si0 2(aq) + 6H 2O
1014 PHLOG KMg)(AISi)OlO)(OH)2 + lOH+ = K+ + 3Mg++ + AI+++ + 3Si0 2(aq) + 6H 2O
1015 ANNITE KFe)(AlSi)O10) (OH)2 + lOH+ = K+ + 3Fe++ + Al+++ + 3Si0 2(aq) + 6H 2O
1021 DEHYD-ANAL NaAlSi 20 6 + 4H+ = Na+ + AI+++ + 2Si0 2(aq) + 2H 2O
1022 ANAL NaAISi 20 6"H 20 + 4H+ = Na+ + AI+++ + 2Si0 2(aq) + 3H2O
1023 SEPIO Mg4Si6015(OH)2(OH2) 2" (OH 2)4 + 8H+ = 4Mg++ + 6Si02(aq) + llH20
1025 LO-ALB NaAISi)Og + 4H+ = Na+ + AI+++ + 3Si0 2(aq) + 2H 2O
1027 MAX-MIC KAISi)Og + 4H+ = K+ + AI+++ + 3Si0 2(aq) + 2H 2O
102~ K-SPAR KAISi)Og + 4H+ = K+ + AI+++ + 3Si0 2(aq) + 2H 2O
1029 HI SAN KAISi)Og + 4H+ = K+ + AI+++ + 3Si0 2(aq) + 2H 2O
1030 ANOR CaAl 2Si 20 g + 8H+ = Ca++ + 2AI+++ + 2Si0 2(aq) + 4HP
1031 NEPH NaAISi0 4 + 4H+ = Na+ + AI+++ + Si0 2(aq) + 2H 2O
1035 WOLL CaSiO) + 2H+ = Ca++ + Si0 2(aq) + H 2O
1039 mop CaMg(SiO))2 + 4H+ = Ca++ + Mg++ + 2Si0 2(aq) + 2H 2O
1040 CA-AL PYX CaAI(AISi0 6) + 8H+ = Ca++ + 2AI+++ + Si0 2(aq) + 4H 2O
1044 AKER Ca2MgSi207 + 6H+ = 2Ca++ + Mg++ + 2Si0 2(aq) + 3HP
1045 MERW Ca)Mg(Si0 4)2 + 8H+ = 3Ca++ + Mg++ + 2Si0 2(aq) + 4H 2O
1046 MONTI CaMgSi0 4 + 4H+ = Ca++ + Mg+; + Si0 2(aq) + 2H 2O
1047 GEHL Ca2Al2Si07 + lOH+ = 2Ca++ + 2AI+++ + Si0 2(aq) + 5H 2O
1048 FORST Mg 2Si0 4 + 4H+ = 2Mg++ + Si0 2(aq) + 2H 2O
1049 FAY Fe2Si04 + 4H+ = 2Fe++ + Si0 2(aq) + 2H 2O
1050 HUNT CaMg)(CO))4 + 4H+ = Ca++ + 3Mg++ + 4HCOJ"
1053 ART Mg2(OH)2C03"3H20 + 3H+ = 2Mg++ + HCOJ" + 5H 2O
1054 HED CaFe(Si0 3)2 + 4H+ = Ca++ + Fe++ + 2Si0 2(aq) + 2H 2O
1059 MALACH CU2(OH)2CO) + 3/4H+ + 1/4HS- = 2Cu+ + HCOJ" + H20 + 1/4S0;
 Table 3 continued. Summary of hydrolysis reactions.

Index Mineral Reaction

1060 AZUR CU3(OHMC03)2 + 5/8H+ + 3/SHS- = 3Cu+ + 2HCOi + 1/2H20 + 3/8S0';-

1062 HYDRO-MAG Mg s (OHMC0 3)4"4H 20 + 6H+ = 5Mg++ + 4HCOi + 6H 2O
1064 SMITH ZnC0 3 + H+ = Zn++ + HCOi
1065 ANH-CORD Mg2AI3(AlSis01S) + 16H+ = 2Mg++ + 4Al+++ + 5Si0 2(aq) + 8H 2O
1066 HYD-CORD Mg2AI3(AlSis01S)"H20 + 16H+ = 2Mg++ + 4Al+++ + 5Si0 2(aq) + 9H 2O
1067 JADEITE NaAJ(Si0 3)2 + 4H+ = Na+ + Al+++ + 2Si0 2(aq) + 2H 2O
1068 CER PbC0 3 + H+ = Pb++ + HCOi
1069 STRONT SrC0 3 + H+ = Sr++ + HCOi
1070 DIS-DOL CaMg(C0 3)2 + 2H+ = Ca++ + Mg++ + 2HCOi
1071 ORD-DOL CaMg(C0 3h + 2H+ = Ca++ + Mg++ + 2HCOi
1072 ARAG CaC0 3 + H+ = Ca++ + HCOi
1073 CALC CaC0 3 + H+ = Ca++ + HCOi
1074 MAG MgC0 3 + H+ = Mg++ + HCOi
1075 DOL CaMg(C0 3)2 + 2H+ = Ca++ + Mg++ + 2HCOi
1076 SIDER FeC0 3 + H+ = Fe++ + HCOi
1078 ANHYD CaS04 = Ca++ + SO"
1079 FLUORITE CaF 2 = Ca++ + 2F-
1080 BARITE BaS04 = Ba++ + S04'
1081 ANG PbS0 4 = Pb++ + SO"
1082 CELEST SrS04 = Sr++ + SO"
1083 ALUN KAVOHMS04)2 + 6H+ = K+ + 3Al+++ + 2S0" + 6H 2O
1084 WITH BaC03 + H+ = Ba++ + HCOi
1085 RHODO MnC0 3 + H+ = Mn++ + HCOi
1086 COY CuS + 1/2H 20 = Cu+ + 1/8S0" + 7/SHS- + 1/8B+
1087 GALENA PbS + H+ = Pb++ + HS-
1088 SL ZnS + H+ = Zn++ + HS-
1089 WURT ZnS + H+ = Zn++ + HS-
1090 M-CINN HgS + H+ = Hg++ + HS- ><
1091 CINN HgS + H+ = Hg++ + HS-
><
><
1092 ALA MnS + H+ = Mn++ + HS- <
.....
1093 PYRITE FeS2 + H 20 = Fe++ + 1/4S0" + 7/4HS- + 1/4H+ .....
.-
 Table 3 continued. Summary of hydrolysis reactions.
~
~
~
Index Mineral Reaction -<
......
......
......
1100 GOLD Au+ 9/SH+ + I/SS0 4 = Au+ + 1/2H 20 + 1/SHS-
1101 SILVER Ag + 9/SH+ + 1/8S04 = Ag+ + 1/2H 20 + 1/SHS-
1102 COPPER Cu + 9/SH+ + 1/SS04 = Cu+ + 1/2H 20 + 1/SHS-
1103 GRAPHITE C + H 20 + 1/2S04 = HCO] + 1/2HS- + 1/2H+
1106 HALITE NaCi = Na+ + CI-
1107 SYLVITE KCl = K+ + CI-
1108 COR aAl 20 3 + 6H+ = 2Al+++ + 3H 2O
1109 PER MgO + 2H+ = Mg++ + H 2O
1110 LIME CaO + 2H+ = Ca++ + H 2O
1111 TO CuO + 7/8H+ + 1/SHS- = Cu+ + I/SS04 + 1/2HP
1112 CUP CU20 + 2H+ = 2Cu+ + H 2O
1113 FE-OXIDE FeO + 2H+ = Fe++ + H 2O
1114 GIBBS Al(OH)3 + 3H+ = Al+++ + 3H 2O
1115 DlAS AIO(OH) + 3H+ = Al+++ + 2H 2O
1116 BOEH AIO(OH) + 3H+ = Al+++ + 2H 2O
1117 BRUC Mg(0H)2 + 2H+ = Mg++ + 2H 2O
1119 MANGAN MnO + 2H+ = Mn++ + H 2O
1120 SPINEL MgAl 20 4 + 8H+ = Mg++ + 2Al+++ + 4H 2O
1123 K-OXIDE K 20 + 2H+ = 2K+ + H 2O
1124 NA-OXIDE Na 20 + 2H+ = 2Na+ + H 2O
1125 AMORPH SIL Si0 2 = Si02(aq)
1126 A-CRIST Si02 = Si02(aq)
1127 B-CRIST Si0 2 = Si0 2(aq)
1128 CHALCED Si02 = Si02(aq)
1130 WAIR Ca(AI 2Si 40 12 )·2H 20 + 8H+ = Ca++ + 2Al+++ + 4Si0 2(aq) + 6H 2O
1132 LAUM Ca(AI 2Si 40 12)·4H 20 + 8H+ = Ca++ + 2Al+++ + 4Si0 2(aq) + 8H 2O
1501 ACAN Ag 2S + H+ = 2Ag+ + HS-
1502 CP CuFeS2 + 7/SH+ + 1/2H 20 = Cu+ + Fe++ + 15/SHS- + I/SS0;
1503 BN CU5FeS4 + 23/SH+ + 1/2H 20 = 5Cu+ + Fe++ + 31/SHS- + 1/SS0;
1504 CC CU2S + H+ = 2Cu+ + HS-
1505 QTZ Si0 2 = Si02(aq)
--
 Table 3 continued. Summary of hydrolysis reactions.

Index Mineral Reaction

1506 MG Fe304 + 1/4HS- + 23/4H+ = 3Fe++ + 1/4S0; + 3H 2O

1507 KALS KAlSi0 4 + 4H+ = K+ + Al+++ + Si0 2(aq) + 2H 2O
1508 FERROSIL FeSi0 3 + 2H+ = Fe++ + Si0 2(aq) + H 2O
1509 PYROPH AI 2Si 40\O(OH)2 + 6H+ = 2Al+++ + 4Si0 2(aq) + 4H 2O
1510 TALC Mg 3Si 40\O(OH)z + 6H+ = 3Mg++ + 4Si0 2(aq) + 4H 2O
1512 7-A CL Mg sAl(AlSi 30\O)(OH)g + 16H+ = 5Mg++ + 2Al+++ + 3Si02(aq) + 12H 2O
1513 14-A CL Mg sAI(AlSi 30\O)(OH)g + 16H+ = 5Mg++ + 2Al+++ + 3Si0 2(aq) + 12H 2O
1515 CLNZ Ca2AI3Si3012(OH) + 13H+ = 2Ca++ + 3Al+++ + 3Si0 2(aq) + 7H 2O
1516 LAWS CaAI 2Si 20 7 (OH}z-H 20 + 8H+ = Ca++ + 2Al+++ + 2SiO Z(aq) + 6H zO
1517 TREM Ca2MgsSis022(OH)2 + 14H+ = 2Ca++ + 5Mg++ + 8Si0 2(aq) + 8H 2O
1518 ANTH Mg 7Si s0 22 (OH)2 + 14H+ = 7Mg++ + 8Si0 2(aq) + 8H 2O
1519 ZOIS Ca2AI3Si3012(OH) + 13H+ = 2Ca++ + 3Al+++ + 3Si0 2(aq) + 7H 2O
1529 GROSS Ca3Al2Si3012 + 12H+ = 3Ca++ + 2Al+++ + 3Si0 2(aq) + 6H 2O
1530 ANDRA Ca3Fe2Si3012 + 1/4HS- + 39/4H+ =
3Ca++ + 2Fe++ + 3Si0 2(aq) + li4S0; + 5H2O
1531 ALB NaAlSi 30 s + 4H+ = Na+ + Al+++ + 3Si0 2(aq) + 2HzO
1532 PREHN Ca2Al(AlSi30\O)(OH)2 + lOH+ = 2Ca++ + 2Al+++ + 3Si0 2(aq) + 6H 2O
1537 ENST MgSi0 3 + 2H+ = Mg++ + Si0 2(aq) + H 2O
1538 PARG NaCa2Mg4Al(AI2Si6022)(OH)2 + 22H+ =
Na+ + 2Ca++ + 4Mg++ + 3Al+++ + 6Si0 2(aq) + 12H 2O
1542 ANTIG Mg4SSi340S5{OH)62 + 96H+ = 48Mg++ + 34Si0 2(aq) + 79H 2O
1544 HM Fe203 + 15/4H+ + 1/4HS- = 2Fe++ + 1/4S0; + 2H 2O
1545 ORD-EP Ca2FeAI2Si3012(OH) + 1/8HS- + 95/8H+ =
2Ca++ + Fe++ + 2Al+++ + 3Si0 2(aq) + 13/2H 20 + 1/8S0"
1551 MARG CaAI 2(AI 2Si 20\O) (OH)z + 14H+ = Ca++ + 4Al+++ + 2Si0 2(aq) + 8H 2O
1552 MERCURY Hg + 9/4H+ + 1/4S0" = Hg++ + 1/4HS- + H 2O
1555 PO FeS + H+ = Fe++ + HS-
1558 NESQ MgC0 3'3H 20 + H+ = Mg++ + HCO] + 3H 2O ~
1559 EPID Ca2FeAI2Si3012(OH) + l/sHS- + 95/8H+ = ~
~
2ea++ + Fe++ + 2Al+++ + 3Si02(aq) + 1/8S0; + 13/2H 2O >-<
1560 HI ALB NaAlSi 30 s + 4H+ = Na+ + Al+++ + 3Si02(aq) + 2H 2O ~
 REFERENCES

Aagaard, P., and Helgeson, H.C., 1983, Activity/composition relations among silicates and
aqueous solutions: II. Chemical and thermodynamic consequences of ideal mixing of
atoms on homological sites in montmorillonites, illites, and mixed-layer clays: Clays and
Clay Minerals (in press).
Bird, D.K., and Helgeson, H.C., 1980, Chemical interaction of aqueous solutions with
epidote-feldspar mineral assemblages in geologic systems: I. Thermodynamic analysis of
phase relations in the system CaO-FeO-Fe20rAI203-Si02-H20-C02: Am. Jour.
ScL, v. 280, p. 907-94l.
Bird, D.K., and Helgeson, H.C., 1981, Chemical interaction of aqueous solutions with
epidote-feldspar mineral assemblages in geologic systems: II. Equilibrium constraints in
metamorphic/geothermal processes: Am. Jour. Sci., v. 281, p. 576-614.
Delany, J.M., and Helgeson, H.C., 1978, Calculation of the thermodynamic consequences of
dehydration in subducting oceanic crust to 100 kb and> 800''C: Am. Jour. Sci., v. 278,
p. 638-686.
Flowers, G.C., 1979, Correction of Holloway's (1977) adaptation of the modified Redlich-
Kwong equation of state for calculation of the fugacities of molecular species in super-
critical fluids of geologie interest: Contr. Min. Pet., v. 69, p. 315-318.
Flowers, G.C., and Helgeson, H.C., 1983, Equilibrium and mass transfer during progressive
metamorphism of siliceous dolomites: Am. Jour. ScL, v. 283, p. 230-286.
Franck, E.D., 1982, Survey of selected non-thermodynamic properties and chemical
phenomena of fluids and fluid mixtures: in D. Rickard and F.E. Wickman, eds., Chem-
istry and Geochemistry of Solutions at High Temperatures and Pressures: Physics and
Chemistry of the Earth, v. 13 and 14, Oxford, Pergamon Press, p. 65-88.
Frisch, c., and Helgeson, H.C., 1983, Metasomatic phase relations in dolomites of the
Adamello Alps: Am. Jour. Sci., v. 283 (in press).
Garrels, R.M., and Christ, C.L., 1965, Solutions, Minerals, and Equilibria: New York, Harper
and Row, 450 p.
Helgeson, H.C., 1968, Evaluation of irreversible reactions in geochemical processes involving
minerals and aqueous solutions--I. Thermodynamic relations: Geochim. et Cosmochim.
Acta, v. 32, p. 853-877.
Helgeson, H.C., 1969, Thermodynamics of hydrothermal systems at elevated temperatures
and pressures: Am. Jour. ScL, v. 267, p. 729-804.
Helgeson, H.C., 1970a, Description and int-.. pretation of phase relations in geochemical
processes involving aqueous solutions: Am. Jour. ScL, v. 268, p. 415-438.
Helgeson, H.C., 1970b, A chemical and thermodynamic model of ore deposition in hydroth-
ermal systems: in, B.A. Morgan, ed., Fiftieth Anniversary Symposia: Mineral. Soc. Am.
Spec. Paper 3, p. 155-186.
Helgeson, H.C., 1979, Mass transfer among minerals and hydrothermal solutions: in, H.L.
Barnes, ed., Geochemistry of Hydrothermal Ore Deposits, 2nd ed., New York, John
Wiley and Sons, p. 568-610.
XLII

Helgeson, H.C., 1982a, Prediction of the thermodynamic properties of electrolytes at high

temperatures: in, D. Rickard and F.E. Wickman, eds., Chemistry and Geochemistry of
Solutions at High Temperatures and Presures: Physics and Chemistry of the Earth, v. 13
and 14, p. 133-177.
Helgeson, H.C., 1982b, Errata: Thermodynamics of minerals, reactions, and aqueous solu-
tions at high pressures and temperatures: Am. Jour. Sci., v. 282, p. 1143-1149.
Helgeson, H.C., 1984, Errata II: Thermodynamics of minerals, reactions, and aqueous solu-
tions at high pressures and temperatures: Am. Jour. Sci., v. 284 (in press).
Helgeson, H.C., and Aagaard, P., 1984, Activity/composition relations among silicates and
aqueous sohitions. I. Thermodynamics of intrasite mixing and substitutional
order/disorder in minerals: Am. Jour. Sci., v. 284 (in press).
Helgeson, H.C., Brown, T.H., and Leeper, R.H., 1969, Handbook of Theoretical Activity
Diagrams Depicting Chemical Equilibria in Geologic Systems Involving an Aqueous
Phase at One Atm and 0° to 300°C: San Francisco, Freeman, Cooper and Co., 253 p.
Helgeson, H.C., Brown, T.H., Nigrini, A., and Jones, T.A., 1970, Calculation of mass
transfer in geochemical processes involving aqueous solutions: Geochim. et Cosmochim .
. Acta, v. 34, p. 569-592.
Helgeson, H.C., Delany, J.M., Nesbitt, H.W., and Bird, D.K., 1978, Summary and critique of
the thermodynamic properties of rock-forming minerals: Am. Jour. Sci., v. 278-A, p. 1-
229.
Helgeson, H.C., Garrels, R.M., and MacKenzie, F.T., 1969, Evaluation of irreversible reac-
tions in geochemical processes involving minerals and aqueous solutions--II. Applica-
tions: Geochim. et Cosmochim. Acta, v. 33, p. 455-481.
Helgeson, H.C., and Kirkham, D.H., 1974a, Theoretical prediction of the thermodynamic
behavior of aqueous electrolytes at high pressures and temperatures: I. Summary of the
thermodynamic/electrostatic properties of the solvent: Am. Jour. Sci., v. 274, p. 1089-
1198.
Helgeson, H.C., and Kirkham, D.H., 1974b, Theoretical prediction of the thermodynamic
behavior of aqueous electrolytes at high pressures and temperatures: II. Debye-Hiickel
parameters for activity coefficients and relative partial molal properties: Am. Jour. Sci.,
v. 274, p. 1199-1261.
Helgeson, H.C., and Kirkham, D.H., 1976, Theoretical prediction of the thermodynamic
behavior of aqueous electrolytes at high pressures and temperatures: III. Equation of
state for aqueous species at infinite dilution: Am. Jour. Sci., v. 276, p. 97-240.
Helgeson, H.C., Kirkham, D.H., and Flowers, G.C., 1981, Theoretical prediction of the ther-
modynamic behavior of aqueous electrolytes at high pressures and temperatures: IV.
Calculation of activity and osmotic coefficients and apparent molal and standard and
relative partial molal properties to 600°C and 5 kb: Am. Jour. Sci., v. 281, p. 1249-1493.
Helgeson, H.C., and Murphy, W.M., 1983, Calculation of mass transfer among minerals and
aqueous solutions as a function of time and surface area in geochemical processes. I.
Computational approach: Mathematical Geology, v. 15, p. 109-130.
Quist, A.S., and Marshall, W.L., 1968, Electrical conductances of aqueous sodium chloride
solutions from 0-800° and at pressures to 4000 bars: Jour. Phys. Chem., v. 72, p.684-
703.
 XLIII
Walther, J.V., and Helgeson, H.C., 1977, Calculation of the thermodynamic properties of
aqueous silica and the solubility of quartz and its polymorphs at high pressures and tem-
peratures: Am. Jour. Sci., v. 277, p. 1315-1351.
Walther, lV., and Helgeson, H.C., 1980, Description and interpretation of metasomatic
phase relations at high pressures and temperatures: I. Equilibrium activities of ionic
species in nonideal mixtures of CO 2 and H20: Am. Jour. Sci., v. 280, p. 575-606.
ACTIVITY DIAGRAMS
 2
(:;; 20. 0r-........,~~--~--, (:;; 14. 0r-""",""",-~-~---' (:;; 10. 0r-~",""~-~-..,

A
** ~ 13.0 'C,G1 0SS b **
A

-:; 18.0
J:
v
«
v
!~ 12 . 0 ~'t,:
A fREI1N
-:; 9.0
J:
v
«
v
~ 16.0 ~ 1 1.0 ~ 8.0
+
+
«
t ;--~~ +
«+
u ~ 10.0 u
~ 14.0 v ~ 7.0 FlYROPH
v ~ 9.0 v
K L 1
(!) (!) (!)
g 12 . 0 L-.-~~-...L---'----J---l g 8.0 g 6.0
-7.0 -5.0 -3.0 -1.0 -4.0 -2.0 0.0 -3.0 -1.0 1.0
LOG CACSI02CAO))) LOG CACSI02CAO))) LOG CACSI02CAO)))
(:;; 20. 0r--~<""""""~--~.....,
* ,GRpSS 1 'c , 1 GRasS
* A

~± 18 . 0 "
RR11;.HNbI -:; 9.0
J:
v

~~ 16.0 ~S
~\G
'i'c v
~ I 1.0
«
v
~ 8.0
!u GIBBS 1 \ L.A.UM
+
+
~ 10.0
+
«+
u
~ 14.0 0 1 v ~ 7.0
1 PYROPH
v ~ 9.0 I
v
K L1
(!) (!) a (!)
o
...J 12_·'.0 -5.0 -3.0 -1.0
o
...J 8._04 . 0 -2.0 0.0 g 6.0
-3.0 -1.0 1.0
LOG CACSI02CAO))) LOG CACSI02CAO))) LOG CACSI02CAO)))
(:;; 20. 0 r-""",~~--~--' (:;; 10. 0r-<:---o-~-~-"'"
* "GRCjlSS 1 1GROSS
~ 'I I **
A

-:; 18.0 '1 b A

+ 9.0
~ p~~~' J:
v
«
~ a v
~ 16.0 I ~ 8.0
+ +
+ +
« «
u u
~ 14.0 v ~ 7.0
v ~ 9.0 I
v
(!) (!) a (!)
g \ 2 . 0~~~--'1.---'-....L....----.J g 8.0 g 6.0
-7.0 -5.0 -3.0 -1.0 -4.0 -2.0 0.0 -3.0 -1.0 1.0
LOG CACSI02CAO))) LOG CACSI02CAO))) LOG CACSI02CAO)))
(:;; 20. 0r--~~-::-::"'":-::-::r-~--' (:;; 9.0
** *
A

-:; 18.0
'"'-:;* 8.0
J: J:
v v
«
v
«
v
~ 16.0 ~ 7.0
+ +
+ +
« «
u u
~ 14.0 v ~ 6.0
v ~ 9.13 v
(!) (!) (!)

g 12_·'.L-0~_-5~.-0..L.L-_....J
3 "-.0~--'--'. 0 g 8·_\.0 -3.0 -1.0
g 5.0
-4.0 -2.0 0.0
LOG CACSI02CAO))) LOG CACSI02CAO))) LOG CACSI02CAO)))

Phase relations in the system HCl- H20- (AI 20 3) -CaO-Si0 2. Saturation limits: quartz (a),
amorphous silica (b), wollastonite (c).
 3

;:;; 9.13 @8.0 @8.a

** ** *
r.
~ 8.13
r.
~ 7.0
"~* 7.0
J: J: J:
v v v
« « «
,
v v v
;:: 7.13 ;:: 6.13 ;:: 6.0
+ + +
«+ «+ «+ COR
u u u
~ 6.13 PYROPH ~ 5.0 I PYROPH ~ 5.0
v v A v
(!) (!) (!)

35.13
-3. a -1 . a 1.a
34.0
-3.13 -1.13 1.0
g 4 .-"3 .L..0-~-"""'..w..----'
-1.0 1.0
LOG (A(SI02(AO))) LOG (A(SI02(AO))) LOG (A(SI02(AO)))
;:;; 9.13 @8.0 @8.0

~/
** * *
r.
r. "~* 7.O "~* 7.0

~"
+ 8.13
~:IR''c, ,
J: J: J:
v v v
«
v
«
v
M «
v
;:: 7.13 ;:: 6.13 ;:: 6.0 NOF C,
+ + I WAIR \ + COR I ,
«+ +
+
« COR 110----1 «
u
~ 6.13
u
~ 5.O
a u
~ 5.0 ~ WAIR'
v PYROPH v H v S II..
(!) (!)
I PYROPH (!) I PYROPH
g 5 ._133 .L-a-~-UL...-.-~-.....I
-1.13 1.13
o
4·_°3.0 -1.0 1.0
g 4.O
...J -3.O -1.13 1.0
LOG (A(SI02(AO))) LOG (A(SI02(AO))) LOG (A(SI02(AO)))
;:;; 9.13 @8.0 @6.a
...... G"EHL
** ** ~', G~OSS **

d;\'J
~ 8.13 ~ 7.13 "5.0
+
J:
+
J:
"+
v v ~ 4.0
~ 7.13 ~ 6.O «
v
"r.
t 6.13
""t 5.13 COR
NO
'
C,
;:: 3.0
+
« « +
u u ~ 2.0
v COR v
: WAIR v
~ 5.13 ~ 4.13 ~ 1.O
(!)
YROP (!)
g 4._134 .L..a---.............IL..--....J g 3.13 go ._04 .L..0----...w ........
(!)
-....J
-2.13 13.13 -4.0 -2.0 0.13 -2.0 0.13
LOG (A(SI02(AO))) LOG (A(SI02(AO))) LOG (A(SI02(AO)))
@8.a @3.0 ~1.0
**
I
** *
* 2.O
....... , a
~ 7.13 ~ 2.0
+
J:
v
+
J:
v
"+
5-3.O
'~~ROSS
~ 6.13 ~ 1.O «
v
J. WAIR
"t 5.0 ""t 0.O
r. ~4.0
+ N'I'R \
+
«
u
«
u ~5.0 COR I 'c,
v v v
~ 4.0 4-1.O
v ~6.0

°
(!) (!) (!)

g 3·-"4.0 -2.0 0.0

3-2 ._04 .L-0-~---1...L1-~----I
-2.0 O.O 3- 7._\. -3. a -1.0
LOG (A(SI02(AO))) LOG (A(SI02(AO))) LOG (A(SI02(AO)))
Phase relations in the system HCI-H 20-(AI 20 3)-CaO-Si02• Saturation limits: quartz (a),
amorphous silica (b), wollastonite (c).
4

<i" 14.0 "<i 8.0 "<i 4.0

"*
';.' 12.0
"*
"±6.0 "*
';.' 3.0
I I
v v v
« «
v
«
:::: 10.0 ...... :::: 2.0
"+ ';.' 4.0 "+
t 8.0 +
+
...J
GROSS
t
...J
1.0
...J
« « «
v ~ 2.0 v
~ 6.0 v
« 0.0
v
WaLL WaLL
(!) (!) (!) I
:l 4.0 :l 0.0 ~1.0 ~~~--~~~~
-13.0 -9.0 -5.0 -1.0 -1 2 .0 -8. 0 -4.0 0 .0 -11.0 -7.0 -3.0 1.0
LOG (A(SI02(AQ))) LOG (A(SI02(AQ))) LOG (A(SI02(AQ)))
"<i 1 4 . 0 .--~-,,--....~~---, "<i 8.0 "<i 3.0
"';.'*
MARG
""* "*
I
v
12.0
± 6.0
v
';.' 2.0
I
v
« «v «
:::: 10.0 ...... :::: 1.0
GROSS
"+ -c- - ';.' 4.0 "+
t 8.0 +
+
...J
t 0.0
...J
...J
«
v
« «
v
~ 2.0
~ 6.0 v ;:;-1.0
WaLL WaLL
(!) (!) (!)

:l4.0 ~2.0
-1 3 . 0 -9. 0 -5. 0 -1. 0 :l 0_'102. 0 -8.0 -4.0 0.0 -11.0 -7.0 -3.0 1.0
LOG (A(SI02(AQ))) LOG (A(SI02(AQ))) LOG (A(SI02(AQ)))
"<i 1 4 . 0 .----"T"'""--...,.---~---, "<i 6.0 "<i 2.0

"*
';.' 12.0
MARG\
\. "*
" 5.0 "*
';.' 1.0
I +
I \ I I
v v
« ~ 4.0 «
:::: 10.0 v
...... :::: 0.0
"+ ';.' 3.0 "+
t 8.0 +
+ t-l .0
...J
« :;;! 2.0 ...J
«
v v v
«v 6.0 ""-2.0 WaLL
~ 1.0 v
(!) (!) (!)

:l 4.0 :l 0.0 ~3.0

- 13.0 -9.0 -5.0 - 1 .0 -12.0 -8.0 -4.0 0.0 -11.0 -7.0 -3.0 1.0
LOG (A(SI02CAQ))) LOG (A(SI02(AQ))) LOG (A(SI02(AQ)))
"<i 1 4 . 0 r-~......---r-~~---, "<i 6.0 "<i 1. 0

"* MARls \. J "';.'* 5.0 "';.'* 0.0

';.' 12.0
I
I \ a I I
v \ \ I v
« ~ 4.0 «
:::: 10.0 ~b v
...... ~1 .0
"+
t 8.0 c~~~ ~~~~M ';.' 3.0
+
+
"+
t-2.0
...J
« RE ~I :;;! 2.0 ...J
«
v v
~ 6.0 f------, I l\ ~ 1.0 ""-3.0
v
(!) WaLL (!)

:l4.0 :l0.0
-13.0 -9.0 -5.0 -1.0 -12.0 -8.0 -4.0 0.0
LOG (A(SI02(AQ))) LOG (A(SI02(AQ)))

Phase relations in the system HCl- H 20 - Al 20 3 - (CaO) - Si0 2. Saturation limits: quartz (a),
amorphous silica (b), gibbsite (c), diaspore (d), corundum (e), andalusite (0, kyanite (g), sil-
limanite (h), kaolinite CD, pyrophyllite G).
 5
r.
<;' 2.0 " 1.0
<;' "<;' 1. 0
*
r.
r.
'"
r\
r\ ""*+
+ +
J: J: J:
~ 1.0 ~ 0.0 ~ 0.0
v v v
"- "- "-
r.
+
+
r.
+
+
"++
+ + +
;i 0.0 ;[1.0 ;[1.0
v v v
« « «
v v v
(!)
5-1 . 0 "----'-~.....:.c::i.::.........J......l.~~
-7.0 -4.0 -1.0 2.0
LOG CACSI02CAO)))
"<;' 1.0 "
<;' 0.0 " 0.0
<;'

ilO :Ej~l~
+
*
r.
r.
-d ""*+

!GR;Ji
J: J:
~ 0.0 ~1.0

~ \
v v
"- "-
r.
+ "++
~2'0/"OLL
+
+ +
;[1.0
v
«
;'"AI ;[2.0
v
«
9
v v
(!) ~ LIME (!)
5-3. 0 ~~~~~---4-"""""'" 5-3 . 0 ......,.r.........~~.........---4-.............
5-2 ._~ . 0 -4 . 0 -1. 0 2 .0 ":7 . 0 -4 . 0 -1. 0 2. 0 -7.0 -4.0 -1. 0 2.0
LOG CACSI02CAO))) LOG CACSI02CAO))) LOG CACSI02CAO)))
r\ r\ r\

<;' 0.0 <;'-3.0 <;'-7.0

*
r\
r\
*
r\
r\
'"
r\
r\
+ + +
J: J: J:
~1.0 ~4.0 ~8.0
v v v
"-
r. "-
r\
"-
r\
+ + +
+ + +
+ + +
;[2.0 ;[5.0 ;[9.0
v
«
v
«
v
«
'f,
v v v
(!) (!) (!)
\
5-6. 0 L..L~~~.:..L..~-l 5-10. 0'-----'..J......~~~...........~-'
5-3 ._07 . 0 -4. 0 - 1 .0 2 .0 -7.0 -4.0 -1.0 2.0 -7.0 -4.0 -1.0 2.0
LOG CACSI02CAO))) LOG CACSI02CAO))) LOG CACSI02CAO)))
"<;'-2.0 "<;'-15.0r-~~~~~~~ " . 0r-"T"''r'"''"~'''''''''''''''''~'''
<;'-24

"'+"
r\ "'"
"J:+ WAIR ""'+"
J: J:
~3.0
v
~16.0 GE~L ~25.0
v
"- "- "-
r\
+
+
"++ "++
\
+ + +
;[4.0
v
«
;[17.0
v
« \ ;[26.0
v
«
v
(!)
v
(!)
\ v
(!)
\
5-27 . 0L...L.o~~.-..J~~......LJ
5-5 ._~ . 0 -4.0 -1. 0 2 .0 5- 18__ ,. 0 -4 . 0 -1. 0 2 .0 -7.0 -4.0 -1.0 2.0
LOG CACSI02CAO))) LOG CACSI02CAO))) LOG CACSI02CAO)))

Phase relations in the system HCI- H 20- Al 20 3 - (CaO) -Si0 2• Saturation limits: quartz (a),
amorphous silica (b), gibbsite (c), diaspore (d), corundum (e), andalusite (0, kyanite (g), sil-
limanite (h), kaolinite (i), pyrophyllite G).
 6
~ 28 . 0 r--...~~~"""":---"'--' ~ 20 . 0 r--~r--""",,--""-' ~ 16.0r-~-r~~~~-.

,...** **
,...
GEHL : IGEHL
,... 18.0 ,... 14.0
'.;' 24.0 IGROSS + GRiIlSS ~ WOll I
I
v
<{
a
I ::5 16.0 OL
<{ ::512.0
j G~RS~
b
v v

I
~
~ 20.0 ~ 14.0 ~ 10.0 _ _ ,
+
+
MRG +
+ t ,...v-~
~ 8. 0
~LAWS
<{
~ 12.0 PREHN" MARG
u
v 16.0 v
~ I
;3
<{
v arz 10.0 v 6.0 arz K 0
(!) (!) (!)
g 12.0L.....~~-"---~~-'-"--' g8.0 g4.0 "
5.0 8.0 11.0 14.0 0.0 4.0 8.0 -2.0 0.0 2.0 4. '"
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)
~ 28.0 ~ <""--........,
20. 0.--.....,-......... ~ 16 . 0r--~---.;:~~~---'
I
,...** I
*
~
,... 18.0 OL
GEHL :
,... 14.0
,...
GkHL
I
'.;' 24.0 I + + WOLL
I GROSS /
v aI ::5 16.0 ::5 12.0

"t'EH~N2
<{ <{ <{
v v v
~ 20.0 ~ 14.0 ~ 10. 01 _ _ _~.
+ + +
+ + +
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<{
~ 12.0 ~ 8.0
~ 16.0 v v
<{
v ;3 10.0 arz +- MARG ;3 6.0
(!) (!) lo~ 8 y
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0 8.0 11.0 14.0 g 8. 00.0 4.0 8.0 ...J 4 '~3 . 0 -1.0 1. 0 3 .0

J
LOG CACAL+++)/CACH+»**3) LOG CACAL+++)/CACH+»**3) LOG CACAL+++)/CACH+»**3)
~ 28. 0r--......,~~~.......~.......-, ~ 20. 0.--......,~--.;::-~---., ~ 16.0r-~~-~-----.
*
,..,*
GEHL
* GEHL * I
"* ~ bGEHL
OL ;""0;
I 18.0 14.0
'.;' 24.0
I
v
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::5 16.0
WOL
GROSSI
I ± WOLL
<{ <{ ~ 12.0 GROSS
v
~ 20.0
v
~ 14.0 ? ~ 10.0 LNZ
+
+
<{
u
~ 16.0
/ PRE~~MARG
+
+
~ 12.0
v
6~ 8 .0 PREt~~;i ~ARG
aTZ '\~ ....
v arz ;3 10.0 v 6.0
(!) (!) (!)
g 12.0~~~u........~~....J 38.0 34.0
4.0 7.0 10.0 13.0 o . 0 2.0 4 . 0 6 . 0 -3. 0 -1.0 1. 0 3.0
LOG CACAL+++)/CACH+»**3) LOG CACAL+++)/CACH+»**3) LOG CACAL+++)/CACH+»**3)
~ 28. 01r-.....,...~~~~~......., ~ 20 . 0 ~ 16. 0r--"T'"---~----'
* GEHL * 18.0 ~* 14 . 0
"'.;'* 24.0 ~
"
GEHL
r.
I I GROSS + +
v OL ::5 16.0 ::5 12.0 WOLL
<{
v
«
v
«
v
~ 20.0 ;::: 14.0 ;::: 10.0
+ / t t --
«+
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u ~ 12.0 ~ 8.0 PRE~... ~RG
~ 16.0
v
v
;3 10.0
v
j 6.0 aTZ
~
arz ',------j
8 8
(!)

g 12. 0~~........u~-~--I KA AND

...J 8.0 ...J 4.0
4.0 7.0 10.0 13.0 0.0 2.0 4 .0 6.0 -4. 0 -2. 0 0. 0 2.0
LOG CACAL+++)/CACH+»**3) LOG CACAL+++)/CACH+»**3) LOG CACAL+++)/CACH+»**3)

Phase relations in the system HCI-H 20-AI 20 3 -CaO-(Si0 2). Saturation limits: diaspore (a),
gibbsite (b), corundum (c).
 7
~ 12, 0rT~~-,,""~~---' ~. 12.0r-~~--~~----' ~ 10.0r-~-'~~~~-'
* GEHL
~EHll * GEHl
J.. LL I :
~ I J.. 9.0 I
A GROSS h " Wall
+ 10.0 i + 10.0
c/
~ ~AA
J:
v (5 Oll
« ;3
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GROSS
v
;::; 8,0
A~ : : : t - - -......
+
+ ~/~ARG
;::;8.0
+ ---/c'CNZ'
«
u \ I ~ ~ .. ~ ARG ~ 6.0
~ 6.0 aTZ
~ 6.0 aTZ "\ v aTZ 1
v PY v kYA ;3 5.0 flIll
~ ~ ~ c
g 4.0-1.0 0.0 1.0 2.0
g4.0
-2 .0 -1.0 0.0 1 .0
g4.0
-2. 0 -1.0 0 .0 1 .0
lOG CA(AL+++)/(A(H+»**3) lOG (A(Al+++)/(ACH+»**3) lOG CACAl+++)/(ACH+»**3)
~ 12. 0..-~..,....- .......,..-~---, ~ 12 . 0r-~""<"'~~G-E~H~l--1-, ~ ! 0. 0
J..*
~
EHl
~ 10.0
J:
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GROSS *
"
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I "
';* 8.5 Wall

~ GROSS ~! ~
~
v
«
v
;::; 8.0
+
;::;8.0 ~ ;::;7.0 , AR
+
« ~ I---'-~ I R ~ ~NO~
u
~ 6.0 ~ 6.0 aTZ ~~ I ~ 5.5 aTZ \(
v v

g 4. 0 L-~~_~~--L.L.....I g,4. 0
~ ~ SIll

-3.0 -2 . 0 -1. 0 0. '" -3.0 -2.0 -!. 0 0 .0

LOG CACAL+++)/CA(H+»**3) lOG CACAl+++)/CACH+»**3)
~ 7.0
I I
o *
"'+* 5.5
t
l GEHl IGEHl
",...+ 9.0
I
GROSS
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C
all r

'\~ } ..
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c(
ROSS
v v C~I v

~l"A.G
;::; 7.0 ;::; 6.0 ;::; 4.0
+ + +
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+ +
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c(
u aTZ u u
~ 5.0 ~ 4.0 ~ 2.5
v v aTZ
I AND v aTZ \YAND
~ ~ ~
g3.0 g2.0 g 1.0
-3.0 -2.0 -1.0 0.0 -6.0 -5.0 -4.0 -3.0 -10.0 -9.0 -8.0 -7.0
LOG (ACAL+++)/CA(H+»**3) LOG CACAL+++)/CACH+»**3) lOG CACAl+++)/CACH+»**3)
~ 11 . 0;r-..,....:---~~----, ~ 5.0 ~ 0.0
*
"'+* 9.0
*
"'*+ 3.0
,c **
1'\0001.0
J: J: I "+
v
c(
v GROSS I 0-2.0
c( c(
v
;::; 7.0
v
;::; 1.0 ~-,=r v
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+ + ::::R: ARG +
+
c(
+
c(
+
u u ~4.0
~ 5.0 :;:-, .0 aTZ v
v v ~5.0 aTZ
lAND
~ I AND ~ ~
g3'_"s.0 -4.0 -3.0 -2.0 3- 3":108.0-17.0-16.0-15.0 3-6":~.0-26.0-25.0-24,0
lOG (ACAl+++)/CACH+»**3) LOG CA(AL+++)/CACH+»**3) lOG CACAL+++)/(A(H+»**3)

Phase relations in the system HCl-H20-AlP3-CaO-(Si02)' Saturation limits: gibbsite (a),

diaspore (b), corundum (c).
8
12.0 I 12.0r-----~~~1~'
KA S 9 KALS '"~
'"~ . KALS
~10'0~1
9*
10.0 10.0
; J: J:
~ 8.0 IK-SPA~ ::;;: 8.0
"-
~ 8.0
"-
KTSPt R
'"~ 6.0
\~:
'" I I A

~ 6.0 I ~ 6.0
v v v
<{ <{
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~ I (!) ~ DIAS " \ 1/
g 2.0 ~ 2.0 ~ 2.0 YRdJPH
K I
0.0 0._04 .0 -2. 0 0 .0
0._06 .0 -4.0 -2.0 -cS.0 -3.0 -1.0
LOG CACSI02CAQ))) LOG (ACSI02CAQ))) LOG CACSI02CAQ)))

12.0~: I I

~~~~0~KA a h
A
~ 10.0 KALS ~ 10.0 KALS T
l,

J: J:
S LSPAt ::;;: 8.0 ::;;: 8.0 KtSFfAR
;::; U I I "- "-

~\::
A A

~ 6.0 I ~ 6.0 ~ 6.0

v v v

~S\
<{ <{
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DIAS I
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52.0 ~ 2.0 ~ 2.0 -PYROPH

PY~OPH K L I
0._06 .0 -4.0 -2.0 0.0 0._04 .", 2 '"
-5.0 -3.0 -1.0 ... -.'" 0.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
12.0r----.~~1~I~--~

KALS
'" I
b 01 Il
A
'" 10.0 A 10.0 a A
~ 10.0 KALS u
+ + I I J: I I
J: J:
::;;: 8.0 ::;;: 8.0 _ K-rP~R ::;;: 8.0 ~-~PAR
"- "- "-

~\'
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~ 6.0
A

~ 6.0
v v US I I v
<{ <{ <{
v 4.0 v 4.0 DIAS I I v 4.0
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~ 2.0 ~ 2.0 ~ 2.0

K
0._07 .0 -5.0 -3.0 0._06 . 0 -4.0 -2.0 0._04 . ...
'" 2 '"
-.'" 0.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
12.0r-~~~~--~-' 12.0r---'--'~1~~~

aI bI
KALS
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A 10.0 ~ 10.0 KALS ~+ 10.0
J: J: J: KALS
::;;: 8.0 ::;;: 8.0 ::;;: 8.0
"-
A
"-
A
"-
A
~ 6.0 ~ 6.0 ~ 6.0
v v
<{ <{
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(!) ~

~ 2.0 ~ 2.0
K
0.0 0.0 0._04 .",
-7.0 -5.0 -3.0 -6.0 -4.0 -2.0 ... -2.0 0.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
Phase relations in the system HCl- HP - (Al 20 3) - K20 - Si0 2• Saturation limits: quartz (a),
amorphous silica (b).
 9
7.0 7.0 7.0
I I
aI A
KALS
aI A KALS
~ 6.0 A
+
6.0 A
+
6.0

\~
J: J: J:

,~ 5.0 ,~ 5.0 ,~ 5.0

C~
A A A

~ 4.0 ~ 4.0 ~ 4.0

v v v COR
« « «
v 3.0 v 3.0 v 3.0
(!) (!) (!)

~ 2.0 ~ 2.0 ~ 2.0

1.0 1.0
-3.0 -2.0 -1.0 0.0 1 ._02 . 0 -1 . 0 0 .0 -2.0 -1 .0 0.0
LOG (A(SI02(AQ))) LOG (A(SI02(AQ))) LOG (A(SI02(AQ)))
7.0
KALS 6 ,...
7.0
I ,...
7.0
KALS aI
I
9
A
6.0 6.0

-~;K-SPAR
A A ':;.' 6.0
+ +
J: J: J:
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~ 5.0 ~ 5.0 ,~ 5.0
A

~ 4.0 us "~ 4.0

A A

~ 4.0
v I v v
« DIAS 1/ « «
v 3.0 v 3.0 v 3.0
(!) (!) (!)
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~ 2.0 ~ 2.0 ~ 2.0 ROPH
A
1 ._03 . 0 -2.0 -1.0 0. 0 1 ._02 . 0 - 1. 0 0.0 1._02 . 0 -1.0 0.0
LOG (A(SI02(AQ))) LOG (A(SI02(AQ))) LOG (A(SI02(AQ)))
7.0 7.0 7.0
A
':;.' 6.0
A
':;.' 6.0 "':;.' 6.0 K LS
J: J: J:
,~ 5.0 ,~ 5.0 ,~ 5.0
A

~ 4.0
A

~ 4.0 "~ 4.0

v v v
« « «
v 3.0 COR v 3.0 v 3.0
(!) (!)
A~D
~ 2.0 ~ 2.0
PtRPI H
I
1._03 . 0 -2.0 -1.0 1 ._03 . 0 -2 . 0 - 1 .0 1.0
-2 . 0 -1 .0 0.0
LOG (A(SI02(AQ))) LOG (A(SI02(AQ))) LOG (A(SI02(AQ)))
7.0 6.0 6.0
A ,... KAL ,...
':;.' 6.0 ':;.' 5.0 I ':;.' 5.0 KA S
J: J:
a J:
,,...~ 4.0 \~:K-SPAR
I

,,...~ 5.0 ,~,... 4.0 a

: K-SPAR
~ 4.0
v
«
v 3.0
~ 3.0
v
«
v 2.0
co~RI ~ 3.0
v
«
v 2.0 COR
(!) (!) A~D (!)

~ 2.0 ~ 1.0 ~ 1.0

1._03 . 0 -2.0 -1.0 0._03 . 0 -2 . 0 -1 . 0 0.0

-3 . 0 -2 . 0 - 1 .0
LOG (A(SI02(AQ))) LOG (A(SI02(AQ))) LOG (A(SI02(AQ)))

Phase relations in the system HCl- H 20 - (A1 20 3) - K20 - Si0 2. Saturation limits: quartz (a),
amorphous silica (b).
 10
r.
<i" <i 8.0
r\

12 . 01""<:'~""""--"""'~'--' <i 8.0

""* "":;'* 6.0
I' '
, _" e,
I
I
I
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* 6~0
~ ,
10.0
+
I I
~:::,.\~-c- ± 'e I I MUSC
~ 8.0
,
v
",1"- ~ 4.0
,
v '-,
'l ....d
~4.0
v
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"
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I I

":;' 6.0 I
~
":;' 2.0 I ;:; 2 0
r-""'·
I' ~
KALS + .
+ a1 + I I"
+
~ 4.0
KJSPAR I
+
~ 121.0 IK-gPA~ , ~ 0.0 KALsjl } .. ~d
6
v KALS v v I Kl-Sf\AR' ,
;3 2.0 I I ~2.e I
~I ~2.0
6~ ,
I
(!)
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~0·_'7.0 -5.0 -3.0 -1.0 ..r 4·_'%.0 -3.0 -1.0 1.0
§.4.0
-4.0 -2.0
I I
121.0
\
2.121
LOG (A(SI02(AO))) LOG CA(SI02(AQ))) LOG (A(SI02(AO)))
,....
"<i 12.0 "
"<i 8.0
, <i 8.0
,e, 66
* "I I *
r.
"":;'* 6.121
~ 10.0 'd, ,,,,MUSCI r. 6.0 d, ~ I IMUSC I I
+
C ~C- ~- I - I
~ 4.0
, 'I I
- ,..,- - -C-
I
~ 4.0
I I MUSC
< 8.0
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v l' I ,
v , , I I

J'e I '{, ":;' 2.0

,
~~B-f--
,I I

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":;,6.0 I ":;' 2.0
KALS
t 9 I'
+
+
I I'"
+
+
:;l, 4.0 KALS K-SPAR :;;! 0.0 ~-S~AR , ~ 0.13 KALS I ~,'d,
v v v
;3
(!)
2.0 I I ;3..2.0
(!)
61 bI " ~2.0
(!)
I ~-SI<'AR'
I I , "
~ 0. 0 L...-~.L..--o-L~--"'--' 3-4.0 ~ 3-4.0
11 \
-7.0 -5.0 -3.0 -1.0 -5.0 -3.0 -1.0 1.0 -4 .0 -2. 0 0. 0 2.121
LOG (A(SI02(AO))) LOG (ACSI02CAO))) LOG (A(SI02CAO)))
"<i 12. 0'-~-r-~~,....,~..., "<i 8.0 "<i 8.0
-:..
":;' 10. 0
1',
d,
e, I
'I MUpC
I
~
*
6.0 "*
-; 6.0 , I I
I I
I
~ 8.0 r ""-.,- -'-~
~'\
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I
~ 4.0
I
~ 4.0
::::: I "I, ,
v
,
v

":;' 6.0 I}- , ":;' 2.0 ":;' 2.121

t
~ 4. 0 KALS
I
I
I '
I' ~
+
+
0.0
KALS I
a b ,
I"
~
+
+
0.0
1 1 ,
v v
~ KISPA~ KI-SIPAR
v 2.0 a b ~2.0 ~2.e
(!) 1 1
I I
(!) (!)

~ 0._'7 • 0 -5. 0 -3.0 -1.0

3-4.0 L-~~~~~~~
-6. 0 -4. 0 -2. 0 0 .0
3-4.0 I I
--S.0 -3.0 -1.0
,
1.0
LOG (A(SI02(AO))) LOG (ACSI02(AO))) LOG (A(SI02(AO)))
"<i r.
<i 8. 0
-:..
12. 0ir-"""~-.-"'-~-,
, I I * ,
r--r-~~~~~~
II
~ 6.0 ,e,
r\
":;' 10 . 0 'd, e, I J'1USC I MUSC ":;' 6.0 II
I d, , " ,0 b II
~ 8.0 ~ -,~~ J. -C- ~ 4.0
1 I
j
~ "'\........ ,
v - ~ ~ .L -f-
" ,
4.0 ' ,
e,
I I MUSC
I I
":;' 6.0
+ KAL I I ' ,'
'1-, ":;' 2.0
+ KALS
'\,
I, ,
t 2.0 I' ' d ' ob
~ 0.0 b::'~~- -f-
+ +
0.0 I I ,
~4.0 KLsPAR'
~

II ',
Kfs,AR,
?
v

~2.0 ~ ~2.0
I I ~2.0 KALS ~,
(!)
g KlfP~ ,
~ 0._'7 • 0 -5.0 -3.0 -1.0 3-4.0
-6. 0 -4.0 -2 . 0 0. 0 ..r 4 . 0
-5.0 -3.0 -1.0 1.0
LOG CA(SI02(AO))) LOG (A(SI02(AO))) LOG CACSI02(AQ)))

Phase relations in the system HCl- HlO - Ah03 - (KlO) - SiOl. Saturation limits: quartz (a),
amorphous silica (b), gibbsite (c), kaolinite (d), pyrophyllite (e)., diaspore (0, kyanite (g),
corundum (h), sillimanite (j), andalusite U).
 11
"<i 6.0
, I
"<i 6.0 I
"<i 6.0
""* 4.0 'e,
1
Muse
"';* 4.0 1
"+*
"4.0
1 Muse
+ I 1 Muse :r:
:r: a :r:
~ 2.0
v ~~~~-f- ~ 2.0
v ~I
.... a ~ 2.0
v ~I
..... ...., a1
"-
'; 0.0 1 ,, "-
'; 0.0
+
- - -:::...-1- - -h-
..... -g
"-
'; 0.0
+
-h- ~---
. . . . i-
,
+ + +
+ 1 KALS
;t2.0 KALS ;t2.0 KALS ;t2.0
v 1 v v
IK-SPARI. IK-SPAR
~4.0 ~4.0 Ie-SPAR ~4.0
(!)
1 ' (!) 1 (!) 1
0
5- 6 ._04 . 0 -2.0 5-6.0 ..r6 ._04 . 0 -2.0
0.0 2.0 -4.0 -2.0 0.0 2.0 0.0 2.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
r. ,..,
<i" 6.0 <i 6.0 <i 6.0
,, I I

""* 4.0 1
"*
'; 4.0
1 *
r.
'; 4.0
+ 'e ~ :r: 1 Muse :r: 1Muse
:r: MUSe
I
I
~ 2.0 , I ~ 2.0 a ~ 2.0 a
~ .....
~
v v v
-f- ~ 1 1
r -"'"
"- .,.\1 - - "- "-
'; 0.0 .~--"' '; 0.0 __ "::>....!::- _h __ '; 0.0 1
+
+
;t2.0 KALS
,, +
+
;t2.0 KALS
1 ..... i- +
+
;t2.0
I
1
....... j .....
v v v
~4.0
(!)
K-SPAA
, ~4.0
(!)
1 K-SPAR
1
~4.0
(!)
KALS
1 K-SPAR
1
5-6.0 5-6.0 5-6.0
-4.0 -2.0 0.0 2.0 -4.0 -2.0 0.0 2.0 -4.0 -2.0 0.0 2.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
"<i 4.0 "<i 0.0 I
r.
~2.0
1

""* 2.0 aI *
"A-2.0 *
~ "A-4.0
IMuse
+ + t- j _ 1 +
:r: ~_; 1 MuSe :r: :r:
~ 0.0 ~4.0 r- -h- ..j - ----= ~6.0
v
"- ~h- ~J-:- -- v
"- 1
v
"-
-:r-2 . 0 ';-6.0 1 ';-S.0
+
+ KALS
1 +
+
a +
+
I
;t4.0 ;tS.0 KALS ;t10.0 KALS
v v K-SPAR v
IK-SPAR 1 K-SPAR
~6.0 1 ~10.0 ~12.0 I
1
(!) (!) (!) I
5-s. 0 '--~~!.......!.~~-' 5- 12. 0"--~~~iL..o-~"""" 5- I 4 . 0 '-:--~~..........-'---~--'
-5. 0 -3. 0 - I .0 I .0 -5 .0 -3. 0 - I . 0 I .0 -"5 .0 -3 .0 - I . 0 I .0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
<i" 4.0 "C} 10.0 I " . 0r-~~-,~~~--,
C}20
~ ~ I ~ 1
~ I .0 Muse 1 -;- I 2 . 0 ~ Muse -;-22. 0 1 MUSe
a
~ ~ ~14.0~ 1 ~24.0~
=h"':.~-:-r;,~~--t I

7-2 .0
t
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1
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1
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1 ..... - j .....
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t
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~ I ~1S.0 ..J...2S 0 KALS

- 5 0 1 - KALS 1 K-SPAR ;3' K-SPAR
::t. KALS 1K-SPAR ~20 . 0 1 ~30 . 0
(!) I (!) (!)
5-8. 0 5-22. 0 5-32 0 '::-~~~----=-~~
-5.0 -3.0 -1.0 1.0 -5.0 -3.0 -1.0 1.0 ":5.0 -3.0 -1.0 1.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))

Phase relations in the system HCl-H20-Ah03-(K20)-Si02. Saturation limits: quartz (a),

amorphous silica (b), gibbsite (c), kaolinite (d), pyrophyllite (e), diaspore (0, kyanite (g),
corundum (h), sillimanite (j), andalusite G).
12
14.0r---~----~~-'

r.
I
KALS '; KALS I
v ;510.0~ 6
<
"-
r. ~ ~-S I
~ 6.0
v ~6.0
v
II~
~l!Js
<
v j aTZ \!.. KYA
KAOL 8 2 .0 I
...J K L
-2.0 -2.0 -2.0
6.0 10.0 14.0 18.0 0.0 3.0 6.0 9.0 -3.0 0.0 3.0 6.0
LOG CACAL+++)/CACH+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(ACH+))**3)
14. 0r--~-~~~--' 14.0~~~--~~~.
I r.
I KALS r.
aI ± 10.0
I KALS
6
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v
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~iKYA
r. r.
~ 6.0 ~ 6.0
v v v
< < <
v v aTz\DKYA v

KAOL I I
~AOL K L
-2.0 -2 . 00 . 0 3 .0 6 .0 9 .0 -2.0
6.0 10.0 14.0 18.0 -3.0 0.0 3.0 6.0
LOG CACAL+++)/CA(H+))**3) LOG CACAL+++)/CACH+))**3) LOG (A(AL+++)/(A(H+))**~)
14.0~~~~--~~~ 14.0r-~~~~--~-.

r.
KALS
I10.0 ~ALS II
';
v b
r.
~ 6.0
r.
~ 6.0
~~ 6.0 ~SP-+---
I
v
<
v
< ~ use
v v v aTZ \ I AND
KAOL 8 2 .0 'ir
...J t<; L
-2.0 ~~~~~~~~
-2.94 . 0 8.0 12.0 16.0 0.0 3.0 6.0 9.0 -2'_\.0 -2.0 i.0 4.0
LOG CACAL+++)/CA(H+))**3) LOG CACAL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3:
14.0~--~~--~~~ 14 .0~~~~~~~ 14.0~~~--~~~1

H
I KALS r. r.
I
I r. KALS r. I
± 10.0 ± 10.0 KALS

~~
v v
-SP < <
"- "-
r. I Muse r. r.
~ 6.0 ~ 6.0 ~ 6.0
v
<
? KYA v
< KYA
v
<
v aTZ v v
aTZ I
(!)
0
2.0 I KAOL 8 2.0 8 2 .0
...J
I ...J ...J K OL

-2 0 -2.0 -2.0
. 4.0 8.0 12.0 16.0 0.0 3.0 6.0 9.0 -~. 0 -2. 0 1. 0 4. 0
LOG (ACAL+++)/CA(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3:
Phase relations in the system HCI- H20 - Al 20 3 - K20 - (Si0 2). Saturation limits: gibbsite (a),
diaspore (b), corundum (c).
 13
8.0 8.0 7.0
KALS
""- "';' 7.0 KALS "" KALSI
±
v
6.0 J: ± 6.0
v
c
I
« ~ 6.0 «
"- "- "-
"-
~ 4.0
"-
~ 5.0
"~ 5.0
v v v
« « «
v 4.0 v

B 2.0 (!) KYA

...J g 3.0 aTZ

0·~1.0 0.0 1.0 2.0 2 '~1 .0 0. 0 1 .0 2. 0 3·~1.0 0.0 1.0

LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)
8.0 8.0 7.0
KALS I
"" I "
"7.0 KALS "
"±
v
± 6.0 +
J:
v
6.0
« ~ 6.0 «
"- "- "-
"~ 4.0 "~ 5.0 "~ 5.0
v v v
« « «
v
KYA v 4.0 v
(!)

g 3.0
o ._01 . 0
0.0 1.0 2 .0 2·~2.0 -1.0 0.0 1.0 3·~2.0 -1.0 0.0
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)
8.0 8.0 7.0
KALS
"" "';' 7.0 KALS I ""
v
± 6.0 J: I ± 6.0 KALS:
« ~ 6.0 cI v
« I
"- "- "- C
"~ 4.0 "~ 5.0 "~ 5.0
v v ~ v
I
«
v
«
v 4.0
K-SPr R ~/ «
v
aTZ K-Sp:r
(!)
AND B 4.0
g 3.0 ...J
aTZ /1
AND

o '~3 .L.0~~-"""""""-~...J
-2.0 -1.0 0.0 2'_\.0 -4.0 -3.0
3.0 ~--~~~--~~
-9.0 -8.0 -7.0
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)
8.0 7.0 6.0 r---~-~-,

"" KALS
"';' 6.0 KALS ""
v
± 6.0 J:
v
± 5.0 KALS
« ~ 5.0 «
"- "- "-
"~ 4.0
r\

~ 4.0 "~ 4.0

v v v
« « «
v v 3.0 v
aTZ (!)

g 2.0
aTZ
1.0 2.0
0'_\.0 -4.0 -3.0 -2.0 -17.0 -16.0 -15.0 -26.0 -25.0 -24.0
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)

Phase relations in the system HCl- H 20- Ah03- K20- (Si0 2). Saturation limits: gibbsite (a),
diaspore (b), corundum (c).
14
~ 20. 0,--.~~--"'-~~~-, ~ 14. 0,..................~~...-,,......,.--, ~12.0 'd a
* I
* : , 14-A I 1
~ 18.0 14-A a "* 12.0 ~ 10.0 ')0.. ,
CL I I
"+
C 16.0
"+
C 10.0
±
v8.0 -c -,- - U -
SIC"
-c( -c(
v
-c( ~ 1 I

~ 8.0 ~6.0 " b

+ +
+ +
~ 6.0 GIBBS ~ 4.0 DIAS
v v v

~ 10.0 ~ 4.0 K ~ 2.0 KA

(!) (!) (!)
0 80 30.0
32.0
...J ·-8 .0 -5.0 -2. 0 1 .0 -8.0 -5.0 -2.0 1.0 -8 . 0 -5 . 0 -2.0 1 ."
LOG CA(SI02(AQ») LOG (ACSI02(AQ») LOG (A(SI02CAQ»)
~ 20. 0,........~~........-~...-~--, ~ 14.0,..........~~~~~---, ~ 12. 0 ........~,·~~~.,o-r-........,
: d 1 *
" 18. 0, 14-A I ~ 12.0 ,
'd I 1
14-Aa
, CL I I l" 10.0 e '::-..'
'd 14-A I I
~ !L_ +- -I _ c _ +' r- C CL I I
~
v16.0 'd 1 C10.0
.:...c ~- T
'~Ib 38.0S ~ [~,~~-I-I.c-
-c( "', nI ~ ~ I ~ ~ 1I
~
+
14.O I T ~ 8.0
+
~6." "kD
+ + t 4.0 "~Qp
'
~ 12.0 GIBBS ~ 6.0 GIBBS ~ DIAS
v v
~ to.0 ~ 4.0 K ~ 2.0 1
(!) (!) (!)
KA 4
3 8 '_°8 . ° -5. 0 -2. ° 1.0
32.0
-8 .0 -5.0 -2 . 0 1.0 3 0 '~8 . 0 -5.0 -2.0 1 .0
LOG CACSI02tAQ») LOG CA(SI02CAQ») LOG (ACSI02(AQ»)
~ 20. 0.-..~-.....-.........~~--. ~ 12. " ...."~~~"""'T"or-........,
*
l"
I
9
I
~ 18 . 0 I 4-A ~ 10 . " 'dI 4-A ' 1
" CL ,,\ , CL II
+ ~ - - f- +- -c- +
C 8. as "- ~ _I L c -
C16.0 'd , I I
-c(
v
:,..
1 ~ ~\I'
~ 14.0 ~6.0 ~"1
+
+ t )'e,
~ 12.0 DIAS ~ 4.0 DIAS +~or
,
v
~ 10.0 ~ 2.0 KA Ii
(!) 1
3 2. 0
(!)
3 0. 0
(!)

38.0 L......~~~.u.Jo.L....~....J '--~~~~....&L..L~-......J

-8.0 -5. 0 -2.0 1. 0 -8 . 0 -5. 0 -2 . 0 1 .0 -8. 0 -5. 0 -2 . 0 1 .0
LOG CACSI02(AQ») LOG (A(SI02CAQ») LOG (ACSI02(AQ»)
~ 20. 01,.......~-....,.......,-~~...., ~ 14. 0,.......~-~...,-,........~...., ~ 12. "~~-~~rr'~"'"
*
"* 18.0
:
"12.0
'd IJ.
14-AOu **
" ' CL I I " 10. 0
"+ + ~,'T--n-C- "J:+
C 16.0 C 10.0 "I 1 ~ 8.0 s
-c(
v
~ 14.0
~
~ 8.0
"~ v
~6.0
+
+ t 1 +
+
~ 12.0 ~ 6.0 DIAS ~ 4.0
v v v DIAS
~ 10.0 ~ 4.0 K ~ 2.0
(!) (!) (!)

38.0 32.0 30.0

-8 . 0 -5.0 -2.0 1 .0 -8 . 0 -5. 0 -2. 0 1 .0 -8 . " -5 . 0 -2.0 1.0
LOG (ACSI02(AQ») LOG CA(SI02(AQ») LOG (ACSI02(AQ»)

Phase relations in the system HCl- H 20 - (AI 20 3) - MgO - Si0 2. Saturation limits: quartz (a),
amorphous silica (b), brucite (c), talc (d), antigorite (e), forsterite (f), periciase (g).
 15

I I
a a
r\
'd I "-:;:- 8.0
, I
-:;:- 8.0
J: , 14-A ICL J:
d I
v
...... ....".\- - i- -C v
«
\'4-A fL
~ S ......\
;::.; 6.0 ~"f~
v
;::.; 6.0 ~ " ~ - +- -c
+ + PIN ..... f~ I
~I' +
+
(!)
1:
DIAS
(!)
1: ~I"""
v 4.0 v 4.0
«
v
«
v COR ~I\OP COR
(!)
K A (!) A \ (!)
o 2 0 '--~~'----"~~ ~ 2 . 0 L--~~~---o.I.J.L.."---,-,
-' '-5.0 -3.0 -1.0 1.0 3 2 '_\.0 -3.0 -1.0 1.0 -5.0 -3.0 -1. 0 1 .0
LOG (A(SI02(AQ») LOG (A(SI02(AQ») LOG (A(SI02(AQ»)
~ 10. 0r-~~-~~~---' ~ 10. 0r-~~-~....,..~--'
I
a ** I
aI ** I
aI
r. 1 " "
~8.0 14-A l eL '; 8.0
J:
v
'; 8.0
J:
I
~ S ~.::::"- -I--C « ~ J;L
v v
I L "' ..... I
;::.; 6.0 \ ..... f ;::.; 6.0 ;:; 6.0
t ~I ...... +
+
+
+
(!) \ (!) (!)
1: 1:
~4.0 DIAS YROPH ~ 4.0 COR
v
«
4.0
v A \ v v COR
(!) \ (!) (!) S
2. 0
~ 2'_\.0 -3.0 -1.0 1.0
~
-~.0
'--~~~"""""~->-J
-3.0 -I _0 1.0 ~2·..\.0 -3.0 -1.0 1.0
LOG CA(SI02(AQ») LOG (A(SI02(AQ») LOG (A(SI02(AQ»))
~ 8.0 ~ 5.0
I I I
aI * a * a
'"*
'd,
'"
-:;:- 7.0 -:;:- 6.0
I
"*
'; 3.0
I

J: <:::" '>-.11:A-.iC,!" -C J: J:
v v v
« S I ...... \ I « «
~"":--1
v v
~ 'f ;::.; 4.0 ;::.; 1. 0
+ +
+
(!)
+
(!)
COR \ 1: 1:
PYROPH ~ 2.0 COR
,
COR ~1.0
D \ v v
(!) \ (!) (!)

~ 1._0. -3.0 ~ 0._0. 5-3. 0 '--~~~LL..~..:1

-~ 0 -1.0 1.0 -5 0 -3. 0 -1.0 1.0 -~.0 -3.0 -1.0 1.0
LOG CA(SI02(AQ») LOG (A(SI02(AQ») LOG (ACSI02(AQ»)
~ 8.0 ~ 1.0 ~4.0
I
** **
I
'd,
a ** aI
'"-:;:- 6.0 I ""£1.0 "~6.e 'd,
J: - " 1~-A. g,.. - C J:
141A CL
.... C'\.. I
v
«
v
« -,- -1-- -9
S v v
~\""I , I
~3.0 ~8.0
~\I~f +
..... + +
(!)
+
(!)
COR 1:
I P'V~OPH ~5.0 COR ~10.e
v v
D \ v
(!) (!) (!)

~0.\
- .0 -3.0 -1.0 I .0
5-7.a
-5.0 -3 . 0 -I. 0 I .0
5-12.e'--~""""''''''''~~---J
-~. 0 -3. 0 -1.0 1.0
LOG CACSI02(AQ») LOG (A(SI02(AQ») LOG (A(SI02(AQ»)
Phase relations in the system HCl- H 20 - (AI 20 3) - MgO - Si0 2. Saturation limits: quartz (a),
amorphous silica (b), brucite (c), talc (d), antigorite (e), forsterite (0, peric1ase (g).
16
~ 20. o,.......~~~~-~......, ~ 14. 12Ir--'........~-~--.,....., ~ 12.0r--'~~-~~~~

d b * 'd
;
~ 18.0
7-A
CL I I ** 12.0
~ ~ ~ 10.0 '
+ , I I + '+ S
~ 16.0 - , - -'-I-C- 51121.121
«
58.0
«
v ..... v v
~ 14.0 e" I I ~ 8.121 ~ 6.0
+ I + +
+ + GIBBS + DIAS
~ 12.0 ~ 6.0 ~ 4.0
v v v
~ 10.O ~ 4.121 ~ 2.0 KA J
~ ~ ~ I
3 ._°8 . 0
8 -5.0 -2.O 1.0
32.0
-8 .121 -5. 0 -2 . 0 1. 0
30.0
-8 .0 -5.0 -2 . 0 1. 0
LOG CACSI02CAQ») LOG CACSI02CAQ») LOG (ACSI02CAQ»)
~ 20. 0 .......~~-~-~......, ~ 14. 121,--..........~~-~-....---, ~ 12.0r--'~~--~~~

: 7-A b b : 'd 7-A 6~ * 'd ao

12. 0 ~ 10.0 ,7-A I I
~ 18.0, CL I I ~ ~ ,CL I I
.... , CL II
± ~ -- ~ -! -C- +
~
'-TT"c-
~ I I
+
58.0
S
~ 16.121 " I I 1121.121
«
v e, v v

"RdP
~ 14.121 ~ ~ 8.121 ~6.0 i.e
+ + +
"
I
+
~
v
12.121
GIBBS , RYRQPH +
~
v
6.121
GIBBS +
~
v
4.0 DIAS '

~ 1121.121
~
K 0" '
Id, ~ 4.0
~
~2.0
~
KA I 1 '
0 8121 32.0 30.0
...J '-8. 0 -5. 0 -2.0 1. 0 -8 .121 -5.121 -2 .0 1 .0 -8.0 -5.0 -2.0 1.0
LOG CACSI02CAQ») LOG CACSI02CAQ») LOG CACSI02(AC»)
~ 20. 0,.......~~~~-~..--, ~ 14. O,.......~~~-~--.-, ~ 12 . 0r--''',--~~.,.,..~--,
* bb
* ; 'd 7-A
I I
: , 7-A I I
A 18.O 7-A aI bI ~ 12.121 ~ ',CL I I ~ 1121.0 d, CL ?~
CL
- os; -, - i l - c -
A
+ ~--~+--c- + + ,
~16.0 ,\ I I 5,121.121 58.121 r-==.;:=:>-'-, " _I Lc-
« I I ~ ~ II
v e,., L I v
~ 14.121 " ~ 8.0 ~ 6.0
t I +
+
+
+
~
~
12.0
10 . 121
GIBBS I' ~YRQPH
K 10 !., 'd '
~
v
6.0

~ 4.0
DIAS
K
,, ~
v
~ 2.0
4.0 DIAS

I I ,
~ ~ ~
0 8 121 32.0 30.121
...J '-8.0 -5.121 -2.121 1.121 -8.121 -5.121 -2.0 1 .0 -8 .0 -5. 0 -2. 0 1.0
LOG (ACSI02CAQ») LOG CACSI02CAQ») LOG CACSI02CAQ»)
~ 20 .121 .......~~-~-~..--, ~ 14. 0r-'<'~~-~~-"""" ~ 12. 0r'('~~~--"~",,---,
; 6I ~I db ** 10.121
: 'd 7-A
~ 18.0 7-A ~ 12.0 'CL I I ,..,
,..,

~ 16.0 \d..t:L- :- ~ - C- +
~ 10.121
:.....~\--n-c-
'I I
+
58.121
v ,~ v
«
v
~ 14.121 '"" L ~ 8.0 ~ 6.0
+ I + +
+ + +
~ 12.0 ~ 6.0 DIAS ~ 4.0
v
GIBBS:' tRQ,PH v v
DIAS
~ 1121.121 K 0 , e, ~ 4.0 ~ 2.0
I ,
~ ~ ~

3 8 ·~8. 0 -5.0 -2.0 1.0 3 2 ·~8. 0 -5.0 -2.0 1 .0 3 0._08 . 0 -5.0 -2.0 1 .0
LOG CACSI02CAQ») LOG CACSI02CAQ») LOG CACSI02CAQ»)
Phase relations in the system HCl-H 20-(AI 20 3)-MgO-Si02. Metastable 7-A clinochlore was
considered instead of its stable counterpart, 14-A clinochlore. Saturation limits: quartz (a),
amorphous silica (b), brucite (c), talc (d), antigorite (e), forsterite (f), periclase (g).
 17
~

**
1000
, a
I
~

,...**
10.0
, I
a
~

,...**
10.0

I
r\
'd , I
'd \
I
a
,
-:; 8.0 7-A CL -:; 8.0 -:; 8.0 I
OJ: J: 7-A dL J:
v v v
<C ' - -I--c <C I <C
v v
- t- -c
~-!
v
~
;::; 6.0 ;::; 6.0 ;::; 6.0
+ + ~ +
+ + "I +
(!) (!) (!)
1: DIAS 1:
~ 4.0
~ 4.0 ~ 4.0 COR
, COR
<C
v v v
(!)
KA (!) (!) S
o ~ 2. 0 ,--~_ _.......u..L..-....-'"
~ 2'_\.0 -3.0 -1.0 1.0 ...J 2'_\.0 -3.0 -1.0 1.0 -5.0 -3.0 -1.0 1.0
LOG (A(SI02(AQ))) LOG (A(SI02(AQ))) LOG (A(SI02(AO)))
~ 10. 0r---~---~--" ~ 10. 0r--~--~~--' ~ 10.0r---------~--~
* * I * I
,...* *
I
,... 'd
, aI J,. , ~ ,... 'd a
I

! 8.0 ,7-A C1. -:; 8.0

J:
d, I
,7-A CL.:
-:; 8 . 0 ,
~
I
,7-A CL I
v
<C ~ I
v v v
;::; 6.0 ;::; 6.0 ;::; 6.0
+ + +
+
(!)
+
(!)
+
(!)
1: 1:
~ 4.0 ~ 4.0 ~ 4.0
v v
COR <C
v COR
(!) (!) (!)

~ 2._0.
·5 0 -3.0 -1.0 1.0 ~ 2·_°.0
-5 -3.0 -1.0 1.0 ~ 2'_\.0 -3.O -1.O 1.0
LOG (A(SI02(AQ))) LOG (A(SI02(AO))) LOG CA(SI02CAO)))
~ 9.0 ~ 8.0 ~ 5.0
I
I I
**
r\
a
I **
r\
a ,...** 'd , aI
I
! 7.0
r\
-:; 6.0
J: 7-A
-:; 3.0
J:
, 7-A FL
v
<C
v
<C
v
<C " - -1- -c
v v v
SPlNE~ I
;::; 5.0 ;::; 4.0 ;::; 1. 0
+
+
(!)
1: COR
, +
+
(!)
1:
+
+
(!)
1:
~ 3.0 ~ 2.0 COR ::(1.0 COR
v
(!)
PYROPH
o ,
,
v
(!) ,
v
(!)
,
~ 1._0.
-5 0 -3.0
LOG (A(SI02(AQ)))
-1.0 1.0 ~ 0._0.
-5 0 -3.0
LOG (A(SI02(AO)))
-1.0 1.0 9- 3 -5 ._°. LOG
° -3.0 -1.0 1.0
CACSI02CAO)))
~ 8.0 ~ 1.0 ~4.0
I
** I
r\
, a ,...** ,...** a
7-A ~L
I
-:; 6.0 d, -:;"1.0 -:;"6.0 \ 7-~ CL
J:
v
-~ - .J: - -c J:
v
J:
v - -1- -9-
~~:
<C <C <C
v v v
;::; 4.0 ~3.0 SPl~
~8.0
+ + +
+ +
(!)
+
~
(!)
COR
,
1: 1:
~ 2.0 ::(5.0 ::(10.0
v v v
8 (!) ' ( ! )

...J0._0.0
·5 -3 ....
... -1.0 10
• 9-7.0 ... -30
-li .... . -10
. 1'"
.... 9-12.0L--~-Uo.J.----:l--.J
-S.0 -3.0 -1.0 1.0
LOG (A(SI02CAQ))) LOG CACSI02CAQ))) LOG CA(SI02(AQ)))
Phase relations in the system HCI- H 20- (AI 20 3) - MgO-Si02o Metastable 7-A ciinochlore was
considered instead of its stable counterpart, 14-A ciinochlore. Saturation limits: quartz (a),
amorphous silica (b), brucite (c), talc (d), antigorite (e), forsterite (f), periciase (g).
18
,...
'"
<;>17. 0~'-""'~~\~.~""1""'-'T"'1 <;> 9.121 " 5.121
<;>
~ \ J CO D ,..."* \ ,...* "
""15.121
+ 0\~
PINEL \ I I ± 7.121
SPINEL\ r.
+
4.121
I \. a v
I
~ 3.121
~ 13.121 ~4\ \\~rlbl
«
v v
"- 14-A "-
';:' 11.121 ';:' 5.121 ';:' 2.121
+ + +
+ +
,j9121 -C- - -"./- --l ~
« :;i 1. 121
~. BRUC ~ r\LC v 3.121 BRUC v
~ 7.121 I \)
«
v ~ 121.121
(!)
ANTI }\ (!) (!)

~ 5.121 ~ 1.121 3-1.121

- 15 . 121 - 1121 . 121 -5. 121 121 . 121 -9.121 -6.121 -3.0 0.0 -6.0 -4.121 -2.121 121.121
LOG CA(SI02CAQ») LOG CACSI02(AQ))) LOG CACSI02CAQ)))
,... ,... ,...
<;> 17 .. 121...--.........~~~.....-.:--.-,--.-, <;> 9.121 <;> 4.121
,...* ,.I ,...*
,... ,...*
';:' 15.121 "3.121
I SPINEL
\
±7.121
v
+
I
~ 13.121 « ~ 2.121
v v v
"- "- "-
';:' 11.121 ';:' 5.121 ';:' 1. 121
+ + +
+ + +
:;i 9.121 ~
« :;i 121.121
v ~ 3.121 v
~ 7.121 v ~1.121
(!) (!)

~ 1.121 3-2.121
-9.121 -6.121 -3.121 121.121 -6.121 -4.121 -2.121 121.121
LOG CACSI02CAQ)) LOG CA(SI02CAQ»))
,... ,... ,...
<;> 17 .121 r-""",,"~"---"-~TT""""'-'-' <;> 8.121 <;> 3.121
,...* ,...* ,...*
,... 15.121 ';:' 2.0
I
+ ±6.121
v
I
~ 13.121 « ~ 1.0
v v v
"- "- "-
';:' 11.121 ';:' 4.121 ';:' 121.0
+ + +
+ + +
:;i 9.121 ~
« ;tl.0
v ~ 2.121 v BRUC
~ 7.121 v ~2.0
(!) (!)

~121.121 3-3.0
-9.121 -6.121 -3.121 121.121 -9.0 -6.0 -3.0 0.0

r r ..
LOG CACSI02CAQ»)) LOG CACSI02CAQ)))
,... ,... ,...
7 .• '; '. I ~ i B.. \ 'j ?b \.
\ I)
aD
~ 15 . 0 SP~~'\L 6\ §6 . 0 ~ 1 .0 ~?RD
X-
JI RD SPINEV,\:CPRD SPINEL
~13.0 ~ \\.~I ~0.0
--~~A~
II /'

1 11 . 0 ~4-~~tll 14 . 0 \-d-I~~il- / ~~,

::t
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Phase relations in the system HCI- H 20 - Ah03 - (MgO) - Si0 2. Saturation limits: quartz (a),
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limanite (h), kaolinite (i), pyrophyllite (j).
 19
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Phase relations in the system HCl-H 20-AI 20 3 -(MgO)-Si0 2. Saturation limits: quartz (a),
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Phase relations in the system HCl-H 20-AI 20 3 -(MgO)-Si0 2• Metastable 7-A c1inochlore was
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amorphous silica (b), gibbsite (c), diaspore (d), corundum (e), andalusite (f), kyanite (g), sil-
limanite (h), kaolinite (i), pyrophyllite (j).
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Phase relations in the system HCl-H 20-AI 20 3 -(MgO)-Si0 2. Metastable 7-A clinochlore was
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Phase relations in the system HCl-H 20-AI 20 3 -(MgO)-Si0 2. Metastable chrysotile was con-
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ca (b), gibbsite (c), diaspore (d), corundum (e), andalusite (f), kyanite (g), sillimanite (h), kao-
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Phase relations in the system HCl-H 20-Al 20 3 -(MgO)-Si0 2. Metastable 7-A c1inochlore and
chrysotile were considered instead of their stable counterparts, 14-A c1inochlore and antigorite.
Saturation limits: quartz (a), amorphous silica (b), gibbsite (c), diaspore (d), corundum (e), an-
dalusite (f), kyanite (g), sillimanite (h), kaolinite (j), pyrophyllite G).
 25
"~ 3.0 "~ 2.0 "~ 2. 0
,
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Phase relations in the system HCl-H 20-AI 20 3 -(MgO)-Si02• Metastable 7-A clinochlore and
chrysotile were considered instead of their stable counterparts, 14-A clinochlore and antigorite.
Saturation limits: quartz (a), amorphous silica (b), gibbsite (c), diaspore (d), corundum (e), an-
dalusite (f), kyanite (g), sillimanite (h), kaolinite (i), pyrophyllite (j).
26
A
N
17.13 ~ 12.13 ~ 12.13
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A* - b-I--- A
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__~ ::1
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~ 17. ar---~--.-~~.,.......~...., ~ 12.13 ~ 11.13 I
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Phase relations in the system HCl-H20-Ab03-MgO-(Si02)' Saturation limits: gibbsite (a),

brucite (b), diaspore (c), spinel (d), corundum (e), periciase (f).
 27
~ 8.0 ~ 7.0 ~ 7.0
d, d
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~ 8.0 ~ 7.0 , ~ 7.0

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v v v
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~ 7.0 ~ 5.0 ~ 3.0

1

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~6.0 (;1-1.0 (;1-6.0
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-f-,,--+
~ 5.0 14-A \1 £2.0 ~ 14-A CL £7.0 d, 1
::;: ANTI CL i ::;: \ 1 ::;: \ ~
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Phase relations in the system HCl- H 20 - Al 20 3 - MgO - (Si0 2). Saturation limits: gibbsite (a),
brucite (b), diaspore (c), spinel (d), corundum (e), periclase (f).
 28

r--b-1V->--
;:;; 17.0 ;:;; 12.0,......~~.,.....~~~..., ~ 12. 0r-~~-~"""T"""]~---,

** ** *
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?"I "r.*+ FORST
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10.0 7-A
v ANTIG I v v I CL
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~ 13.0 TALC ~ 8.0 ~ 8.0
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+ + +
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g 9.04.0 g4.0 g4.0

r\ --
7.0 10.0 13.0 0.0 3.0 6.0 9.0 -2.0 0.0 2.0 4.0
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)
;:;; 17.0 ;:;; 12 . 0r-~~T"'""~~-~"--' ~ 12. 0'r-~~-~,....~---'
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~ 17.0 ~ 12. 0,......~...-~~~""""7I ~ 12. 0r-~",""-~""""7~---'
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~ 17.0 ~ 12. 0'r-~"'~-~~""71
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LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+)) •• 3)

Phase relations in the system Hr.l-H20-AI203-MgO-(Si02). Metastable 7-A clinochlore was

considered instead of its stable counterpart, 14-A ciinochlore. Saturation limits: gibbsite (a),
brucite (b), diaspore (c), spinel (d), corundum (e), periciase (n.
 29
c;:; 8.13 c;:; 7.13 c;:; 7.13
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Phase relations in the system HCI- H 20 - Al 20 3 - MgO - (Si0 2). Metastable 7-A c1inochlore was
considered instead of its stable counterpart, 14-A c1inochlore. Saturation limits: gibbsite (a),
brucite (b), diaspore (c), spinel (d), corundum (e), peric1ase (f).
 30
A
17.0 ~ 12. er--"'~T""~~~~~'" ~ 12. er-~~~-Y-~~~-'
N
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v CHRYS a v v

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:l 9.13 :l4.e :l4.e

4.13 7.0 113.13 13.13 13 . 13 3.13 6.13 9 . 13 -2.13 13 . 13 2 .13 4 .13
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)
A
17.13 ~ 12.13 ~ 12. er--~~-r~~~~..,
N
r -b- - - J _
** * -b- : FORST ~
""*
CHRYS I ~ I
A
+ 15.13 ,'4-A CL + 113.13 'i-A CL + 113.13
a I
I
v
<{
v
TALC
~
v
I
<{
v TALC\~
I
v
<{
v
'L 14tA CL
;:::; 13.13 ~ ;:::; 8.13
KYA
;:::; 8.13 CHR~ - -:- -b-
+ + +
+ + +
TALC~I
(!) (!) (!)
L L KAOL L
~ I I.e KAOL ~ 6.13 ~ 6.13
aTZ I t----'.f- KY A
v v aTZ I v
(!) (!) a (!) aTZ K
g9.e g4.e g4.e
4 .13 7.13 I 13 • 13 I 3 • 13 13 . 13 3 .13 6.13 9.13 -2.13 13 . 13 2 .13 'I.e
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)

~ 17.13 ~ 12.13 ~ 1 I.e

I
* * - L -b- *
"* "* "*
FORST \ ~
I CHR S I
'.;' 15.13 I 14-A CL "+ 113.13 14t-A CL '.;' 9.13 1\4-iA CL
I I
a I

J
v v v
<{
v
TALC
<{
v TAL~I <{
v CH~y~b- ~~- -
;:::; 13.13 ;:::; 8.13 ;:::; 7.13
+ I + + I'd
(!)
+ +
(!)
KYA +
(!) TALC~I
KAOL
L
v I I.e aTZ
L
~ 6.13
L
~ 5.13 h AND
<{
v v aTZ v
aTZ K I \
(!) (!) (!)
\
I
g9.e g4.e g3.e
'I.e 7.13 113.13 13.13 13.13 3.13 6.13 9.13 -3.13 -I.e I.e 3.13
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)
~ 17.0 ~ 12.13 ~ I I.e
-t - -b- I
** * * cI
I "* C ysl- -b-
"*

TALen
A

I
+ I 14-A CL "I+ 113.13 I4I-A CL '.;' 9.13 1,4-A
I
v a v v \ I
TAL~~ -1-
<{ <{ <{
v v v
;:::; 13.13 ;:::; 8.13 I
KYA ;:::; 7.13 ~R~- b-
+ + I
+
+ I KYA + c + -- \
TAL~~
(!) (!)
I L..!. (!)
L
~ I I.e I KAOL
L
~ 6.13 ~AOL L
~ 5.13
v v aTZ I v
aTZ I L aTZ K
(!) (!) (!)
I
g9.e g4.e g3.e
4.13 7.13 113.13 13.13 13.13 3.13 6.13 9.13 -'I.e -2.13 13.13 2.13
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)

Phase relations in the system HCl-H20-Ah03-MgO-(Si02)' Metastable chrysotile was con-

sidered instead of its stable counterpart, antigorite. Saturation limits: gibbsite (a), brucite (b),
diaspore (c), spinel (d), corundum (e), periclase (0.
 31
~ 8.0 ~ 7.0 ~ 7.0
I
\ ,I
,...** FORST.
\ I
\ C ,...** -\-I-b
,...**
~ 7.0 - - -b- - \1 - ~ 6.0 \ I ~ 6.0
J:

14-A\~L
J:
v v 14-A \FL v
« « «v '\ I
CHRY'
I'd
v v
14\~ CL
;::; 6.0 ;::; 5.0 ;::; 5.0
+
+
(!)
~ I \j +
+
(!)
TALC I \
\
+
+
(!)
. TALC ~I :I: :I:
~ 5.0 ~ 4.0 IKY v 4.0
«
v
I------~, KY v
«
aTZ I
v
OTZ
(!)
OTZ PY (!) e (!)

34.0 33.0 33.0

-2.0 0.0 2.0 -2.0 -1.0 0.0 1.0 -2.0 -1.0 0.0 1.0
LOG (A(AL+++)/(A(H+))**3) LOG CA(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)
~ 8. 0 r--""--'-~-I~--' ~ 7.0 ~ 7.0
,...** *
FORS
:
,...
\ C
I - - """\-1- -b-
,...
,...*
~7.0 --\,I- b - ~ 6.0 \ I + 6.0
J: J:
v I~TA CL v
~ H~YS \1 «
v
«
v
;::;6.0 14-Am.. ;::; 5.0 l ;::; 5.0
+ + +
+ + TALC +
(!)
TALC (!) AND (!)
:I: :I: SILL
~
«v
5.0 ~ 4.0 \ ~ 4.0

OTZ PY
v OTZ 'd v
(!) (!) \ (!)

34.0 :l3.0 :l3.0

-2.0 0.0 2.0 -2.0 -1.0 0.0 I .0 -2 . 0 -1.0 0.0 I .0
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)
~ 7. 0 r--~-r-....-~--, ~ 5.0 ~ 3.0
: -4-J.b-: _I-b- *
,... \
I
e
,... \ I ~ FORST I ,...* - -\-b-I- - -
~6.0 ~I i: 4 . 0 \It-A CL + 2.0

~3 .
J: \ I

~5.. TAL~t
v
\1 «v FORST \

TAL~I\ ;::; 1.0

+
+ TALC
~ d ~ I 'd (!)
:I:
~4.0 I \ ~2.0 \ v 0.0
«v
v OTZ I AND v OTZ AN" OTZ ~
(!) e (!) \ (!) \
3 3.0 3 I. 0 3-1. 0 '--~~_...uL.....~.>.-J
-4.0 -2.0 0.0 -6.0 -5. 0 -4.0 -3.0 -I 0 . 0 -9. 0 -8. 0 -7.0
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3)

i-
~ 6. 0 ~I .0 ~6. 0 r-~.,..-~~~--,

! FORST -b -\ ! ! a
~ 5. 0 ~I ;[2.0 e ; [7.0
~ 4=.1 14-,6;.CL ~ \ I ~
~+ 4.0 CHRYS~I\
TALC I
;;'3.0~"
+ 1\
;;'8.0
+
ct
:I:
d ct
:I:
TALC \ AND ct
:I:
TALC
d
I \

~ 3. 0 I \ :;:-4 . 0 I :;:-9 • 0
~ OTZ I AND ~ OTZ I \ ~ aTZ

3 2 ·~6. 0 -4.0 -2.0 3- 5_'1'7.0 -16.0 -15.0 -14.0 3- 1_02".0 -26.0 -25.0 -24.0
LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(A(H+))**3) LOG (A(AL+++)/(ACH+))**3)

Phase relations in the system HCl-H20-Ah03-MgO-(Si02)' Metastable chrysotile was con-

sidered instead of its stable counterpart, antigorite. Saturation limits: gibbsite (a), brucite (b),
diaspore (c), spinel (d), corundum (e), periciase ([).
32
~ 17. 0,....~~~~,....--~......., ~ 12.0 ~ 12. 0r--~~-~.......,~--'
1I * *
:
,..,
- -b -
""*+
r- -b-
CHRYS
:~~7 "*
A
FORST
c
I
~ 15 . 0 CHRYS 9 v
J:
10.0 + 10.0
J:
v
I
v
< .----; <
<
I
v v TALC v
;::; 13.0 TALC ;::; 8.0 ;::; 8.0
KYA
t ~----l' +
+
I +
+
(!) KAOL (!)
KAOL
(!)
:I: L :I:
vl1.0 ~ 6.0 I ~ 6.0
<
v
aTZ v aTZ a v
I
(!) (!) (!) aTZ
I
39.0 '" :l4.0 :l4.0
4.0 7.0 10.0 13.~ o . 0 3 . 0 6 . 0 9. 0 -2.0 0 .0 2 .0 4. 0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)

~ 17.0 ~ 12.0 ~ 12.0

- -b-
,..,** 7-A ,..,** -b- *
,..,*
A 1
CL CHRYS C
-; 15.0 -; 10.0 + 10.0 FORST 7-A CL
J: J: J:
v , v v

V CHRYS\- :-b --
< < TALC <
v TALC v
KYA
v
;::; 13.0 ;::; 8.0 ;::; 8.0
+ KAOL
+ +
+ + +
(!) (!) ~AOL (!)
:I: :I: L TALC ').
~ 11.0 aTZ ~ 6.0 I ~ 6.0
v v aTZ a v
1 KYA
I aTZ K
(!I (!) (!)

39.0 :l4.0 :l4.0

4.0 7.0 10.0 13.0 0.0 3.0 6.0 9.0 -2.0 0.0 2.0 4.0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)

~ 17.0 ~ 12.0 ~ 12.0

,..,** --b-~
7-A CL ,..,** -b ,..,**
,.., I
a c
+ 15.0 CHRYS I -; 10.0 CHRYS I -; 10.0 FORS-f
J: J: J: , 7-A CL
v v v
< < < I
~/,
t----{,
v v TALC" v

ZH;Y~-\~~- -b
TALC ;::; 8.0
;::; 13.0 ;::; 8.0
+ I KAOL +
cI KYA +
+ + +
I<IAOL
,
(!)
:I: I (!)
L
(!)
L I'
~ 11.0 ~ 6.0 ~ 6.0 TALC '} AND
I I
v aTZ v aTZ v
I aTZ K L ,
(!) (!) (!)

39.0 :l4.0 :l4.0

4.0 7.0 10.0 13.0 0.0 3.0 6.0 9.0 -3.0 -1.0 1.0 3.0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)

'itr
~ 17.0 ~ 12.0 ~ 10.0
-b-
,..,** A
** ,..,** FORST, 7-A CL
, I

1-
-; 15.0 -; 10.0 -; 8.0

-C~R~ \
J: J: J:
v v b-

( Kd
v
< < <

~~
v v v
TALC
;::; 13.0 ;::; 8.0 ;::; 6.0
+
+
(!)
L KAOL
+
+
(!)
L
KYA
(!)
L
+
+
TALC
, ~
I
'AND

d\
~ 11.0 ~ 6.0 ~ 4.0
aTZ aTZ K~ L ,
v v v
(!) (!)
\ (!) I
39.0 :l4.0 32.0
4.0 7.0 10.0 13.0 0.0 3.0 6.0 9.0 -4.0 -2.0 0.0 2.0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)

Phase relations in the system HCl- H 20 - Al 20 3 - MgO - (Si0 2). Metastable 7-A ciinochlore and
chrysotile were considered instead of their stable counterparts, 14-A ciinochlore and antigorite.
Saturation limits: gibbsite (a), brucite (b), diaspore (c), spinel (d), corundum (e), periciase (f).
 33
~ 8.0 ~ 7.0 ~ 7.0
*
"*
':;' 7.0
FORST
- - --
*
"':;'* 6.0
*
"*
':;' 6.0 -b- - - \' T-
'd
, I
I
J: J: J:
v v v FORST, e 7
« CHRYS «
v
«
v
I L
v
~ 6.0 \ - - - - - " " - ~ 5.0 ~5.0 'I
+ + TALC +
+
(!) TALC +
(!)
+
(!)
TALC
::I: ::I: ::I:
~ 5.0 ~ 4.0 ~ 4.0
v v aTZ v
aTZ
(!)
aTZ PH (!) (!)

~3.0 ~3.0
~ 4·~2.0 0.0 2.0 -2.0 -1.0 0.0 1.0 -2.0 -1.0 0.0 1.0
LOG CACAL+++)/CACH+» •• 3) LOG CACAL+++)/CACH+» ••3) LOG CACAL+++)/CACH+» •• 3)
~8.0 ~ 7.0 ~ 7.0
** * * ~ORST ~
""± "':;'* 6.0 "*
"±8.0
, e
7.0 J: - \- -I-b-
v v v
«
v
«
v
«
v
~ 6.0 ~ 5.0 ~5.0
+ + +
+
(!)
+
(!)
+
(!)
::I: ::I: ::I: TALC
~5.0 ~ 4.0 ~ 4.0
v v aTZ v
(!) (!) ' ( ! ) aTZ
~ 4 '~2 . 0 0.0 2.0
~3.0 ~3.0
-2.0 -1.0 0 .0 1.0 -2.0 -1.0 0.0 1 .0
LOG CACAL+++)/CACH+» •• 3) LOG CACAL+++)/CACH+» •• 3) LOG CACAL+++)/CACH+» ••3)
N 7.0
*
~

**
5.0 ~
*
3.0
,
"':;'* 6.0 "':;'* 2.0 - -,- -I-b- -
J: J:
, I
v
«
v e
v
«
v FORST' I

~ 5.0 ~ 1.0 'I

+ TALC TALC +
(!)
+
::I:
~ 4.0
,,
'cJ (!)
::I:
+
~ 0.0
TALC

v
(!)
aTZ
(!)
aTZ
,
v
(!)
aTZ
,
~ 3.0 ~ 1.0 5-1.0
-4.0 -2.0 0.0 -6.0 -5.0 -4.0 -3.0 -10.0 -9.0 -8.0 -7.0
LOG CACAL+++)/CACH+» •• 3) LOG CACAL+++)/CA(H+» •• 3) LOG (ACAL+++)/(ACH+» •• 3)
~ 6.0
: - b- __ -\- J -
~1.0
:
~6.0
:
\
,
I
~
t: 5 .0
FORST e7 - A
\ I CL
~
£2.0
~
£ 7. 0
-f-"""\ - -f - -
e

~ LCHRYS "-1 ~ ~ FORST

'd, , ;~
11
I
~ 4.0 TALC ~3.0 ~8.0
+ Y\ + AND +
~ lid, ~ I' ~ TALC AND
~
« 3 .0
v aTZ
I
lAND
\
C-4 0
j' e,
I

I
'd ::I:
::tv 9.0
],
~~RD

(!) (!) \ (!) aTZ I \

~ 2.0 5-5.0 5-10.0 ~
-6.0 -4.0 -2.0 -17.0 -16.0 -1 5 .0 -1 4 . 0 -27.0 -26.0 -25.0 -24.0
LOG CA(AL+++)/CACH+» •• 3) LOG CACAL+++)/CACH+» •• 3) LOG CACAL+++)/CACH+»**3)
Phase relations in the system HCI- H 20 - Al 20 3 - MgO - (Si0 2). Metastable 7-A clinochlore and
chrysotile were considered instead of their stable counterparts, 14-A clinochlore and antigorite.
Saturation limits: gibbsite (a), brucite (b), diaspore (c), spinel (d), corundum (e), periclase (f).
34
14. 0.--~........~-.---~....., 9.0
EPH NEPH
'"' JADEI f '"'~ NAL I "'"' NA
I
a

~ ::: \1 ALB :I:

v
10.0
± 7.0
v
-~
<{ <{

""~ 5.0
i
~ 8.0
8.0 PARAG~ b +
I <{
zv
v ~ 6.O
~ 6.0 <{ <{ DIAS
v
~ 3.0
RaPH
g 4.0
(!)
I o
...J K L I
PY~OPH

2·~6.0 -4.0 -2.0 0.0 2._06 . 0 -4.O -2.0 0.O 1._°4 • 0 -2.O O.O
LOG CACSI02CAO))) LOG CACSI02CAO))) LOG CACSI02CAO)))
12 • 0r--~...,....~--r-~-....., 9.0
I EPH b ""
I I
"~ 14.0 ANAL I '"'~ I
NA a b
6 10.0
± 7.0
~:
PA.~:
:I: :I:
v v
~ 12.0 I
<{ <{ :ALB
"" "" ~I
~ 8.O
~ 10.0 +
<{ ~ 5.0 R GI
zv ~ 6.O
z I
~ v
<{
~ 8.0 <{
v v DIAS
GIBBS (!)3.0
86.0 0
P'I1ROP
...J ...J K LI

4 ._09 . 0 -5 .0 - 1 .0 2'_°6.0 -4.0 -2.0 0.0 1 ·~4.0 -2.0 0.0

LOG CACSI02CAO))) LOG CA(SI02CAO))) LOG (ACSI02(AO)))

9.0
I I NEP I I

pi;
"~ 14.0
ANAL "~ 9.0 "" NA I I
I
± 7.0
-~ : :
~~GI
:I: :I:
~ 12.0 6 v
<{
v
<{ ALB
"'"'~ 10.0 I
AI-B
~ 7.O
+
<{
""~ 5.0
zv z
~ 8.0
GIBBS
~~\
I
I
~ 5.0
<{
v
v
<{
v
DIAS 1/:
(!) 3.0
K LI
86.0 K o
...J ...J PJYROPH

4·~9.0 -5.0 -1.0 '·~6.0 -4.0 -2.0 0.0 1.~".0

.. -2.0 0.0
LOG (A(SI02(AO))) LOG (A(SI02(AO))) LOG (A(SI02(AO)))
9.0
I I
"~ 14.0 ANAL I b "~ 9.0 ""
± 7.0 I I

~~
-~ ~
:I: :I:

P~ !~
v v
~ 12.0 <{ <{ ?ALB

""~ 10.0 ""~ 5.0

~ 7.0 II
+
<{ GI
z
v ~ 5.0 zv I
~ 8.0 <{
v
<{
DIAS
GIBBS ~ 3.0
86.0 o
...J ...J
IpYROPH
1.0
4·~9.0 -5.0 -1.0 1 ·~6.0 -4.0 -2.0 0.0 -4.0 -2.0 0.0
LOG (A(SI02(AO))) LOG (A(SI02(AO))) LOG (A(SI02CAO)))

Phase relations in the system HCl-H20-(AI203)-Na20-Si02. Saturation limits: quartz (a),

amorphous silica (b).
 35
8.0 8.0
,... 8.0 ,...
,... I
NEP~ a "
~ 7.0 ± 7.0 ~~N~L :
~ 7.0
v v v
j 6.0 j 6.0
j 6.0
",... ,...
" ~AL' ""~ 5.0
~ 5.0 ~ 5.0
z zv zv
v COR r;~ j 4.0
j 4.0 j 4.0
K'r1
83.0 83.0 83.0
...J ...J I PYROPH ...J
I
2·~3.0 -2.0 -1.0 0.0 2._02 . 0 -1.0 0.0 2·~2.0 -1.0 0.0
LOG (A(SI02(AQ») LOG (A(SI02(AQ») LOG (A(SI02(AQ»)
8.0 8.0 8.0
I I
" "" a "" a
"±7.0
v v
±7.0 I ±
v
7.0
NEPH
I
I
j 6.0 j 6.0 j 6.0 IALB
ALB
""~ 5.0 ",...~ 5.0 ""
~ 5.0 I
zv zv zv COR
COR
j 4.0 j 4.0 j 4.0

83.0 PYROPH 83.0 PYROPH 83.0

...J ...J ...J
A
2.0
-3.0 -2.0 -1.0 0.0 2._02 . 0 -1.0 0.0
2.0
-2.0 -1.0 0.0
LOG (A(SI02(AQ») LOG (A(SI02(AQ») LOG (A(SI02(AQ»)

8.0 8.0 7.0

I
"" "
""
+ 7.0
NEPH a
±7.0 NEPH ALBI ±
" 6.0 I

~
I
v
j 6.0
NA : ALB v·
j 6.0
I
a
v
j 5.0
a
I

""~ 5.0 ""~ 4.0

I
"" P A!31
~ 5.0 AR GI
z COR zv zv
v COR
j 4.0 1/ j 4.0 j 3.0
NDI
83.0 83.0 82.0 PYROPH
...J ...J H ...J

2._03 • 0 -2.0 -1.0 2._03 • 0 -2.0 -1 .0

LOG (A(SI02(AQ») LOG (A(SI02(AQ»)
8.0 6.0 6.0
I
" " "
"±7.0 EPH a
I ~ 5.0
NEP(-; I
"±5.0
v
j 6.0
NA I v
j 4.0
~ ? v
j 4.0
"" ~: ""~ 3.0
""
ALB
ALB
~ 5.0 ~ 3.0
zv
j 4.0
z
v
j 2.0
COR I~ zv
j 2.0
A~DI~
83.0 I f>YROP,", 81.0
...J ...J
.I
2·~3.0 -2.0 -1.0 0._03 .0 -2.0 -1.0 0._03 . 0 -2.0 -1 .0
LOG (A(SI02(AQ») LOG (A(SI02(AQ») LOG (A(SI02(AQ»)

Phase relations in the system HCl- H20- (AI 20 3) - Na20-Si02' Saturation limits: quartz (a),
amorphous silica (b).
 36
A A A
c;? 20. 0r-~~-~~~---' c;? 15. 0r-~--~~~---' c;? 10.0
* *
r>. ... , * I I
-:; r'- PARAG I A , r>. 'd,PARAGI I
II5.0, I
b
± 10.0 ' PARAG I ± 5.0 "'---' 9~
? '- ... c
a v
~ r-- 'd, I
~
~
'd
~,,,,, ,
<{
v ~'
I-e- - --==-~ -.l - -
, ~c.,_''
-:; 10.0
+ I
-J
I
-~---':;iI"<"'~-r-'i
A
t·<J 5 '" .
-J--
'"I
-~
-:; 0.0
+
I
NEPH 1 I
,,
I-::-c,

~ PH I .... ,,~, ;i NEPH 1

+
...J I I
<{
~ 5.0 JADEITE I I' ~ 0.0 IANAL I ~5.0 ANA
1 I
v I ALB I ~LB ALB
1 I
80
(!) (!)
0 j :}-5.0 I. :}-10.0 11
...J '-7.0 -5.0 -3.0 -1.0 -7.0 -5.0 -3.0 -1.0 -5.0 -3.0 -1.0 1.0
LOG CACSI02CAQ))) LOG CACSI02(AQ))) LOG CACSI02CAQ)))
r>. A r>.
c;? 20.0 c;? 15.0 c;? 10.0
*
r>.
I
I
I
1
A* ,, A* r'-,
I I
PARAGI I
± 15.0 , , PARAG
r>.

± 10.0 ±
A A
PARAG
5.0 r--......... 'd" aI bI
b I I
I
v a v
a v

,
<{
v
I'
'd
'
1 1
,
<{
V
C _
'd
'
I 9 ,
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-:; 10.0
t--- -C, ,
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5.0
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v 0.0
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v ANAL I 1 , ~5.0 1
<{
v
<{
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1 ALB I I I
(!) (!) (!)
.1 1 :}-5.0 :}-10.0 J I
:l0._07 . 0 -5.0 -3.0 -1.0 -7.0 -5.0 -3.0 -1.0 -5.0 -3.0 -1.0 1.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
r>. A A
c;? 20. 0r-~~-~~~-" c;? 15. 0r-~--~------' c;? 10.0 --
11
*
r>. * *
± 5.0 r' , 'dPARAG bb
A
r>. I A A
1I
± 15.0 + ,

6,
' c:;10.0 'PARAG
v v

, , ~II
<{ <{
<{ " I
v
v
, "c
d, 0 b
I I
v , "-
f-e- -::,:~- ---
-:; 10.0- -:; 5.0 ' , , -:; 0.0
+ + -e- +
+
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<{
+
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NEPH
+
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<{
NEPH I I ' ::: '
I I ,
~ 5.0 ANAL ~ 0.0 ~5.0
A Al "-
v v
1 1 ALB
I I
(!) (!) (!)
0 0 0 0 5 0 :}-10.0 Jl
...J '-8.0 -6.0 -4.0 -2.0 J" '-7.0 -5.0 -3.0 -1.0 -5.0 -3.0 -1.0 1.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
r>. A A
c;? 20.0 c;? 15.0 c;? 10.0
I 1 I I I
*
r>. *
r>.
I
*
± 10.0 , ,
A

± 15.0 ,
A
I 1 A
~ I 1 A PARAG I I
PARAG I I ± 5.0
~ PARAG I " I I
v , a v v
'd ab
, , I I
,
<{ <{ <{
'd
::--:;.::>
"' c ' I I
v I v v
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I
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+
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+
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r-e- - ~~ +-
-:; 0.0 :.... -
+
I I
-:l:> - - e--=
+ + + I 1 :::: '
...J
<{ \jEP 1 '+ ...J
<{ NEPH I 1--.' ...J
<{
NEPH II "
~ 5.0 ANAL I I' ~ 0.0 ANAL I I ' ~5.0 NA II '
v v
I AL~ I AI-B I I ALB "
(!) (!) (!)
I 1 I j 11
:l 0.0 3-5.0 :}-10.0
-8.0 -6.0 -4.0 -2.0 -7.0 -5.0 -3.0 -1.0 -5.0 -3.0 -1.0 1.0
LOG CACSI02(AQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))

Phase relations in the system HCl-H20-Ah03-(Na20)-Si02' Saturation limits: quartz (a),

amorphous silica (b), kaolinite (c), pyrophyllite (d), diaspore (e), corundum andalusite (g), en,
kyanite (h), sillimanite (i), gibbsite (j).
 37
"
~ 10.0 "~ 10. 0r-~-~-~~, "~ 10 .0r-~-~-~~-'
1
""* ""* ""* PARAGI
± 5.0 1',
d, a
: PARAG ± 5.0 :PARAG ±5.0 1
v v
a v
a
«
, r-~' ,
« «
, ~;
~--"r-'~=-e"-";'-9
v v v
- -_.:::..~
1 -.Jt---=
, -h r f- -
""r-'-::::-_-:-"j_-I
,,
'.;' 0.0 '.;' 0.0 '.;' 0.0
+ + 1 - -h- +
+ NEPH 1 ' + +
NEPH 1 NEPH
...J 1 ...J ...J
A A « «
~5.0
« 1 ALB ' ~5.0 M 4 ALB ~5.0 ALB
v v v
1
(!) (!) (!)
L 0 ,0 0~~~~~~
3- 10_'.1'.0 -2.0 0.0 2.0 ..r -'4.0 -2 .0 0 .0 2.0 3- 10_'.1'.0 -2.0 0.0 2.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
" 10 .0r--~~-~~--'
~ "~ 10.0 "
: 10.0r--~--~1-----~
,...* 1

"± 5.0 "*

" 1 ~ 1
PARAG
±5.0 1 PARAG ±5.0 1 PARAG
,?
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v v
« d, aI ?
,
v
«
,
v
,~
v

'.;' 0.0
+
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1
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'.;' 0.0 ~
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~ ~.,.....::----t
+ I + I - _j .....
+ + +
...J ...J NEPH 1 ...J NEPH 1
« « «
~5.0 ~5.0 ~5.0 1
v ALB v A A~ ALB
v
1
ALB
(!) (!) (!)
3-,0. 0'---.......~-~~~ 0 '0 .0 I 3-,0. 0'--~~.L.o.:..~~--'
-4.0 -2.0 0.0 2.0 ..r -'4.0 -2.0 0.0 2.0 -4.0 -2.0 0.0 2.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
"~ 10 •. 0 "~ 5.0 r-~~~-~~-, "
~ 5.0
1 1
"* 1 "* PARAG 1 ""* 1
"
±5.0 PARAG 1 "± 0.0 I ± 0.0
v v a v PARAG 1
« «
,
v a
1
,
v ~I -"'-1
r- f - - =-1-+___ g
,«
v 1
aI
'.;' 0.0 ~ 1
?-5.0 '.;'-5.0

r-~
+ r-f - - + + 1
-g
+
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A Ll
1
«
+
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NEPH
ALB
+
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«
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f- ~ -
NEPH
1
- -g
v ALB v v
1 ALB
(!) (!) (!)
3-10 .0'--~...o....l...L...!.~~....J 3-1 5 • 0 ":---::-""'7""""""---:~~~ 1
3-15.0
-"5.0 -3.0 -1.0 1.0 -~.0 -3.0 -1.0 1.0 -"S.0 -3.0 -1.0 1.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CA(SI02CAQ)))
"~ 10.0 "~5.0 "~15.0
1
""* "*
"±-10.0 1 "*
±5.0 PARAG 1 1PARAG "±-20.0 : PARAG
v v v
« aI
,
v 1
aI
«
,
v a
I «
,
v
~
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1 1
'.;' 0.0 '.;'-15.0 ?-25.0 H - -
-g_
~
+ + -g + 1- -
+ + +
...J
« -g ...J ...J 1 NEPH
NEPH
« NEPH «
~5.0 1 ~20.0 1 ~30.0 1 ALB
v A~ y v
1
ALB v
1
(!) ALB (!) (!)

o..r 10~ J. J 1
_ .0 -3.0 -1.0 1.0 3-25_~.0 -3.0 -1.0 1.0
035~
..r _ .0 -3.0 -1.0 1.0
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))

Phase relations in the system HCl- H 20 - Al 20 3 - (Na20) - Si02. Saturation limits: quartz (a),
amorphous silica (b), kaolinite (c), pyrophyllite (d), diaspore (e), corundum (f), andalusite (g),
kyanite (h), sillimanite (i), gibbsite G).
 38
16.0r---~----------. 16.0 16.0
I NEPH

f
"I"+ JADEI
"
A
INEPH
A

"+ I
+
I 12.0 A L I I N~PH
v v v
<{
PARAG « C
I
« a
"- "- "- I

:t" :c" 8.0 :tz 8.0

A

8.0 B AARA
z
v
arz z
v
KYA v
<{
A «
v arz' «
(!)
4.0 KAOL (!)
4.0 I (!)
4.0
o 0 AO 0
K L
...J ...J ...J

0.0
o . 03 . 0
7 .0 1 1 . 0 15 . 0 o . 00 . 0
4 .0 8 .0 12 . 0 -5 . 0 - 1 . 0 3 .0 7.0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)
16.0r-~~~------, 16.0r-~~~------,

ANAL I NEPH
"" A
A
INEPH "+ I NEPH
+ + 12.0
I 12.0 I I I
I
v v v
ANA C

,i 1
<{ « I «
"- "- "-
":t 8.0 :c :tz 8.0
A A

8.0
zv z
v
AR KYA v
<{
v
«
v arz' « aTz
(!) 4.0 KAOL (!) 4.0 4.0
o o lAO (!)
o
...J ...J ...J

0.0 0.0 0.0

3.0 7.0 11.0 15.0 0.0 4.0 8.0 12.0 -5.0 -1.0 3.0 7.0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)

16.0 16.0
A
ANAL NEPH A

"I+ "+ "+ I NEPH

Y
C I I 12.0 I
v v v
<{ « «
"- PARAG/ "- "- a
:t" 8.0 :cz 8.0 :cz 8.0
A A
I
zv arz I KY v v / I PARAG
<{ « « II~
v
4.0 KAOL
v
4.0
v
4.0 arz / AND
(!) (!) (!)
0 o 0
...J ...J ...J L
0.0 0.0
o . 03 . 0
7.0 1 1 . 0 15 . 0 -5 . 0 - 1 . 0 3 .0 7.0 -5.0 -1.0 3.0 7.0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3:
16.0~~~------~~
I
A A A
A

I
+
A

± 12.0 ANAl: NE\:>H "± 12.0 NEPH

a
I
v v v
<{ « B I «
"- "- "-
:c" 8.0 :cz 8.0 ":c 8.0
A

v
z v
arz zv
« I «
v
«
v
v
(!) 4.0 IKAOL (!) 4.0 (!) 4.0
0 o o
...J I ...J ...J

0.0
o . 00 . 0
4 .0 8 .0 12 . 0 o ._\ . 0 - 1.0 3 .0 7 .0 -~.0 -1.0 3.0 7.0
LOG (ACAL+++)/CACH+))w*3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3:
Phase relations in the system HCl- HP - Al z0 3 - NazO - (Si0 2). Saturation limits: diaspore (a),
corundum (b), gibbsite (c).
 39
14.0 14.0 14.0
I
""+ I NEPH
""I+ N~PH
A
+
I I 10.0
v v v
<{ <{ <{ b
"- "- "- I
A

:t 6.0 ":t 600 f-.

A

:t 6.0 ~ARAG
z z !r~ARAG zv
v v aTZ aTZ
<{ <{
KYA <{
v SILL
(!) 2.0 (!) 2.0 (!) 2.0
0
PH 0 0
..J ..J ..J

-2.0 -2.0 -2.0

-S.0 -1.0 3.0 7.0 -S.0 -1.0 3.0 7.0 -S.0 -1.0 3.0 7.0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)
14.0r-----~----~, 14.0r-----~----~, 14.0r---~--~--~~

I NEPH
"" ""± 10.0 I ""
v
± 10.0 v v
± 10.0
<{ « <{
"- "- "-
":t 6.0 :t" 6.0
A

:t 6.0 SILL
zv zv zv
« aTZ « <{ aTZ
v v AND v
(!) 2.0 (!) 2.0 (!) 2.0
o PY PH o o
..J ..J ..J

-2.0 -2.0 -2.0

-:; . 0 - 1 .0 3. 0 7 .0 -5. 0 -1. 0 3 . 0 . 7. 0 -S . 0 - 1 . 0 3. 0 7 .0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)

14.0 14.0
I
A
A

± 10.0
: NEPH
bI
A
A
+
I 10.0
9
NEjPH
A
A

± 8.0 NePH
L.:
V
<{
"-
V
<{
"-
V
<{ ~
A A
"-
A
I

:t 6.0 :t 6.0 I
)'~RAG
:t 4.0 aTZ AND
zv z zv
<{
v
<{
aTZ <{
v AND v v
(!)
2.0 (!) 2.0 AND (!) 0.0
0 0 0
..J ..J ..J

-2.0 -2.0 -4.0

-S .0 - 1 . 0 3.0 7. 0 -10.0 -6.0 -2.0 2.0 -IS.0 -11.0 -7.0 -3.0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)
14.0r---~--~--~~ 12.0r---------~--~~ 12.0r---~--~----~

A
A

± 8.0
A
A

:i:v 8.0
~
v v NEjPH
<{ <{ <{
"- "- "- L.:
":t 6.0 A

:t 4.0
A

:t 4.0
z z z AND
v v v
<{
v
<{
AND <{ aTZ
(!) 2.0 (!)
0.0
(!)
0.0
o o 0
..J ..J ..J

-4.0 -4.0
-2-'100.0 -6.0 -2.0 2.0 -22.0 -18.0 -14.0 -10.0 -30.0 -26.0 -22.0 -18.0
LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3) LOG CACAL+++)/CACH+))**3)
Phase relations in the system HCl-H20-AI203-Na20-(Si02)' Saturation limits: diaspore (a),
corundum (b), gibbsite (c).
40
~ 18. 0,.......,........~-~~"T""........., ~ 15.0~~........~-~...,.............,
MERW
: ~ MERW I : ' , MERW ac
I I
~+ 16. 0 MOrr~, DIOP I ~ 13.0 MONT~ I I

I
I
v ~ V" I, Dlpr
C ~ 14.0 ~".0 \'tb
,.., I
,..," BRUC ;::; BRUC \ ,I I
t 19.0 t 12.0 t 9.0
«
1'1
« «
u u u
v v v
~ 17.0 ~ 10.0 ~ 7.0
(!) (!)

g
(!)
15. 0L-.........~~~........"'-..!.-'>.J g 8.0 g 5.0
-9.0 -6.0 -3.0 0.0
-10.0 -7.0 -4.0 -1.0 -9.0 -6.0 -3.0 0.0
LOGCACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))

~ 25.0 MERW ,.., 18. 0 .......C"<"'"~--~~......., ~ 15 .0....-~~~--~~

:
,.., i+MONT
,.., 2 3 . 0 : \
I
a
~ ~ MERW I I
~+ 16.0 M~~kDIOP II I
:
~ 13.0 MONT
~':\
MERW 9f
I
±
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:\ II ~~ 14.0
~b" ac
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~
~ 11.0
'"',\ ,Dlpf
'b
~ 'b I ;::; BRUC 'I I ;::; BRUC \ ' II
';.'
+ 19.0
BRUC 'I
:\ ! 12.0 \ r~ t 9.0
«
\ 1'1,
t3 'I. u
v
u
v
~ 17 . 0 ANTIG ~:\ «v 10.0 ~ 7.0

TALC I (!) (!)

g
(!)
15. 0 L-~.J..----'-~~L...L....i:>...II g 8.0
-9.0 -6.0 -3.0 0.0
g 5.0
-9.0 -6.0 -3.0 0.0
-1 1 . 0 -8.0 -5. 0 -2.0
LOGCACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))

~ 18.0~
* ,,~ MERW I I
* ~"
MON~ i
...------+-+---I
~ 16.0 Drplf
~ 'b ac
~ 14.0 ,I I
,.., " BRUC ' I I

«
t 19.0 t« 12.0 '1,1
u u
v v
~ 17.0 ~ 10.0

8 TALC....J. (!)

g 8.0
(!)

g 5.0
...J '~",0.0 -8.0 -5.0 -2.0 -9.0 -6.0 -3.0 0 .0 -9.0 -6.0 -3.0 0.0

,I
LOGCACSI02CAQ))) LOG CACSI02CAQ))) LOG '(ACSI02CAQ)))

,.., 25. 0[""""~--~"T"""-""'"

~ ~ MERW I MERW I I
*
~ 23. 0
~ I
~iMONT l'
oNt'l, DIOP I I
ac
~+
~'b,
:\ DIOP I I v

~ 21.0 'b 9Y ~ 14.0 I

I I
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+ 19.0
BRU 'I
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I "+ 12.0
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t3 ,I «
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17 • 0 ANTIG ' \ «v 10.0 NTI
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g
(!)
15. 0L............---L.~~.............I...::....L...J g 8.0 g 5.0
-11.0 -8.0 -5.0 -2.0 -9.0 -6.0 -3.0 0.0 -9.0 -6.0 -3.0 0.0
LOGCACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))

Phase relations in the system HCl- H 20-CaO- (MgO) -Si0 2• Saturation limits: quartz (a),
wollastonite (b), amorphous silica (c), lime (d).
 41
~ IS. 13r-----~--..., ~ 14. 13"'--_~d""""_-_-_~_-I-""" ~ 14. 13.-------~-~.....,
* * **
~* 13 .13 'b MERW ~ ,... 12.13 'b, MERW
I
aI
+ , I + I
;5 ~, 1
I
v aI
~11.13~ ~ 113.13
~ ~J, DI'I,P ,...
"- r0-
1

t9.13 " ,,(

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t 8.13 BRUC t 8.13
BRUC
QIQP

"'~
~ BRUC
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u u
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~ 7.13 ANTI ~ 6.13 ~ 6.13
l!) l!) l!)

:l4.13 :l 4.13
:lS._136 .13 -4.13-2.13 13.13 -6 .13 -4.13 -2 . 13 13 . 13 -6.13 -4.13 -2.13 13.13
LOG CACSI02CAQ))) LOGCACSI02CAQ))) LOGCACSI02CAQ)))
~ IS. 13r-----~--.., ~ 14. 13...-----~--....., ~ 14. 13.-------~----.
** * -d- - - - + **
~ 13.13 MERW d *
,...
~ 12.13 'b MERW
1
~ 12.13
+ +
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dI
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~ 113.13
~ 11.13
,...
"- "-
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ON -,;:
~I ,DI P r0-

t 9.13 t8.13 " , t 8.13

~ ~ BRUC '\ ~ ~ BRUC
u u
v v v
~ 7.13 ~ 6.13 FORST ~
v
6.13
v v
1
l!) T LC l!) l!)

:lS.13 :l4.13 :l 4.13

-6.13 -4.13 -2.13 13 . 13 -6.13 -4.13 -2.13 13 . 13 -6.13 -4.13 -2.13 13.13
LOG CACSI02CAQ))) LOGCACSI02CAQ))) LOGCACSI02CAQ)))

~ IS. 13.--_-d-:-_~_-~_-_-I-~...., ~ 12. 13.....------~d-.-----~--I~--..... ~ 113. 13.....------~~-.....,

: -d- L
*
~ 13.13 MERW
~ MERW ~ ~ 8.13 MERW
+
I
v
±
v
1 +
I
v
I
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~ 11.13 ~ 8.13 ~ 6.13
,...
"- ,...
"- "-
r0- 1, D.IOP

~
t 9.13
~
t 6.13 t 4.13
~
"\ "\
u u u FORST '\
v v v
~ 7.13 ~ 4.13 FORST ~ 2.13
l!) l!) l!)

:lS.13 :l2.13 :l13.13

-6.13 -4.13 -2.13 13 . 13 -6.13 -4.13 -2.13 13.13 -6.13 -4.13 -2.13 13.13
LOG CACSI02CAQ))) LOG CACSI02CAQ))) LOG CACSI02CAQ)))
7.13 3.13
,- -d- - -
~ 14. 13.---_....,d,..._~_-_-I--~..., ~
-1- ~

*
~ 12.13 MERW d **
~ S.13 'b MERW
**
~ I.e
- -d- - -
MERW
-1-

± I
+
I " I
+
I
v v a
~ 3.13 ~1.13 I
,... ,...
"- "-
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t 8.13 t I.e t-3.13
~ ~ ~ PER
u u FORST u
v v v
~
v
6.13 ~1.13 ~S.13
l!) l!) l!)

0 4 13 3-3.13 5-7.13
...J ·-6.13 -4.13 -2.13 13.13 -7.13 -S.13 -3.13 -I.e -7.13 -S. 13 -3.13 -1.13
LOGCACSI02CAQ))) LOGCACSI02CAQ))) LOGCACSI02CAQ)))
Phase relations in the system HCI-H 20-CaO-(MgO)-Si02• Saturation limits: quartz (a),
wollastonite (b), amorphous silica (c), lime (d).
 42
;:;J 25. 0 ""'~~---:M""E!:':R""'W""""'~-' r\ 18 . 0 ""'~---:~~-~r-t ;:;J 15. 0["'"'<;'~~~~-~,."
~~~M~O~N~T~~4-~ ~ ~ MERW I : 'b MERW

i~ 16 .0 1"""
: 1 1

~ 23.0, 13.0 ~'9c'

,

,\b,9
I I r\
MONT \ ,DIOP I I
~ MONTv"''''f
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~ 21.0 0 ::;:140
v .
1
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?« 9. 0
;:::: BRUC ,
t
r\

«
19.0
BRUC
112 . 0 '\ 1,1 BRUC '\ 'q
u u U
v v v
« 17.0 ~ 10.0 HRY «v 7 .0
v
(.!) (.!) (.!)
~ 1 5 . 0 L.....~..L.--='-"-.....L...u...::........J ~ 8.0 ~ 5.0
-11.0 -8.0 -5.0 -2.0 -9.0 -6.0 -3.0 0.0 -9.0 -6.0 -3.0 0.0
LOGCACSI02CAO))) LOGCACSI02CAQ))) LOGCACSI02CAO)))
;:;J 25.0 MERW ;:;J 18 • 0 ,......,.~---:~---.-,..--, ;:;J 15. 0",,~~~-~~,....,
* ~ ~ MERW I 1 : 'b MERW 1I
* ~ /~
~ 23.0
+ ±
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MONT \~'
DIOPI
II
1
~ 13.0 MON~ 0 1
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'b , 0' I ~ \/"\r, IC
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V 21.0 '
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;::::
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t
r\
9.0
BRUC ':
1 "-

~ 'l u U

~ 17.0 HRY
v v
CHRYS\rR ' «v 10.0 «
v
7 .0

(.!) TALCJ (.!) (.!)

~ 15. 0L-~..L.~~....J.......L....:......y ~ 8.0 ~ 5.0
-1 1 .0 -8.0 -5.0 -2.0 -9.0 -6.0 -3.0 0.0 -9.0 -6.0 -3.0 0.0
LOGCACSI02CAO))) LOGCACSI02CAO))) LOGCACSI02CAO)))

~ 25.0 ~ MERW
r\ 18. 01':""'~~~~~"""--' ;:;J 1 5 . 0 ....'T"---:~~-...........--,
:' ~ MERWI 1 ** 'b
, MERW IC
* ~, MONT I
~ ~~ ~13.0 ~ 61
~ :~.: ~~''b
16.0
+ MONT·, I I
~ '\ 'b D~OP J: MON!~'
~.
DIOP I
9
1
I ~ 14.0 BRUC \' 0: v
~ 11.0
"-
\./"
" D I AP
\~
II
I
r\
t 19.0
BRUC ,
,I
C ;::::
t 12.0
" C
~1 t
r\
9. 0
BRUC ,\'11~
«
« \'- \j 1 ~ R U

~ 17 . 0 CHRYS 'v-R ' I ~ 10.0

v
I
v
«v 7.0
(.!) TALC---..l (.!) (.!)
~ 15 . 0 L-~.L....~~--"--'--"'-U ~ 8.0 ~ 5.0
-1 1 . 0 -8. 0 -5.0 -2 .0 -9.0 -6.0 -3.0 0.0 -9.0 -6.0 -3.0 0.0
LOGCACSI02CAO))) LOGCACSI02CAO)) ) LOGCACSI02CAO)))
;:;J 1 8 . 0 ,--,~~~~~.,--..--, ;:;J 15. 0 ,....~---:~~-"""T'.......,
I ~ ~ MERWI I * , IC
~ 'b MERW .\
'1 13.0
-\b ~ ~I
1 r\ 16 . 0 'kMONT
I + I' I 1
I «~ 14 0 D 0P
1
1 ::;: 1 1 0 MONT~"'I ,
r\
C
I;::::
v' BRUC ,0
,'e ~.
r\

119.0 1 1 12 . 0 \ 'l~ 1~.0 BRUC

~ I ~ CHRY ~
~ 17 . 0 R~ ",I ~ 10 . 0 ~ 7 .0 HRY

8 TALC-oL (.!) (.!)

..J 1_5"10 .0 -8.0 -5.0 -2.0 ~ 8._09 . 0 -6.0 -3.0 0.0 ~ 5._09 . 0 -6.0 -3.0 0.0
LOGCACSI02CAO))) LOGCACSI02CAO))) LOGCACSI02CAO)))
Phase relations in the system HCl- H 20-CaO- (MgO) -Si0 2. Metastable chrysotile was con-
sidered instead of its stable counterpart, antigorite. Saturation limits: quartz (a), wollastonite
(b), amorphous silica (c), lime (d).
 43
15. 0r-~~-~--~'" 14.0
,
A
~
N

'" * ''"" ,- -d- - - - i

~
+
13 . 0 "-
U,
MERW
a A
+
I
12.0 'b A

I
+
12.0
'b, MERW
~11.0~
v v
1 ~ 10.0 « 10.0
v

;::; MONv,J, DtoP "-

A
"-
A

t !
:t+9'" ",' 8.0 8.0
u
.'" BRUC
" '1 , «
u BRUC
«
u
v v v BRUC
~ 7.0 F « 6.0 FORS « 6.0
v v FORST
~ ~ ~

g 5.0 g 4.0 g 4.0

-6.0 -4.0 -2.0 0.0 -6.0 -4.0 -2.0 0.0 -6.0 -4.0 -2.0 0.0
LOGCACSI02CAO))) LOGCACSI02CAO))) LOGCACSI02CAO)))
A
N
15.0 A
14.0 ;::; 14. 0r-~~-~--~..,
N
- -d- - - -1-
*'" ''"" , ''""
A
+
I
13.0 MERW
0
1
A

I
+
12.0
'b,
MERW
a ,..., 12.0
I
+

~'~IO~
v v
1 « 10.0 ~ 10.0
v

A
"-
,..., "-
,...,
t 9.0 BRUC t 8.0 t 8.0
«
u
v F
«
u
v
BRUC \ 1 "- «
u
v
BRUC
«v 7 . 0 «
v
6.0 FORST ~ 6.0
~ ~ ~

g 5.0 g 4.0 g 4.0

-6.0 -4.0 -2.0 0.0 -6.0 -4.0 -2.0 0.0 -6.0 -4.0 -2.0 0.0
LOGCACSI02CAO))) LOGCACSI02CAO))) LOGCACSI02CAO)))

~
*
15. 0r--~------
-d----I-
~ 12.0 -d - - - - I" - ;::; 1 0 . 0 . . - - - - - - - - - ,
! - -d- - - L -
*
~
+
13.0
MERW
'"
':;' 10.0 'b, MERW 6 A
, 'b ,
:8; , . 0 MERW aI
,
1 I ,
I
'b o1 v
I , 1

~ 8.0 ON ~6.0 ~N~ I

A

«
t 9.0
"-
A

«
t 6.0
BRU
\:~~P ;::;
++4.0 RU
I ~t'-
"
-QlOP
, l,
u
BRUC '\ "- «
u u
v v FORST v
~ 7.0 «
v
4.0 ~ 2.0 FORST
~ ~ ~

g 5.0 g 2.0 g 0.0

-6.0 -4.0 -2.0 0.0 -6.0 -4.0 -2.0 0.0 -6.0 -4.0 -2.0 0.0
LOGCACSI02CAO))) LOGCACSI02CAO))) LOGCACSI02CAO)))
12.0..-------:-1- - - , 7.0
~ ~
- -d- - ;::; 3.0
~ b, MERW 01 ''"" 'b "-
I
a ''"" - -d-- 1..
~ 10.0 ~ 5.0
, MERW 1 ~ 1.0 , MERW
± ONf- h.. I
v
+ 1 +
I 'b ,
~ 8.0 ---...j' 'DI6p ~ 3.0 :;-1 .0

""', ,
, " ,I "- "-
A BRU \ ) 'DIp1 P r-.
t 6.0 ! 1.0 !-3.0
« PER
« FORS «
u u FORST \ u
v v v
~ 4.0 C ;5-1.0 ;5-5.0 FORST
~ ~ ~

g2.0 3-3.0 3-7.0

-6.0 -4.0 -2.0 0.0 -7.0 -5.0 -3.0 -1.0 -7.0 -5.0 -3.0 -1.0
LOGCACSI02CAO))) LOGCACSI02CAO))) LOGCACSI02CAO)))
Phase relations in the system HCl- H20-CaO- (MgO) -Si02 . Metastable chrysotile was con-
sidered instead of its stable counterpart, antigorite. Saturation limits: quartz (a), wollastonite
(b), amorphous silica (c), lime (d).
 44
~ 12. 0r-.,.....~...-..,."...~~---, ~ 9.0
* I I **
*
"+ 17.0 ~11.0_f_ ?I 8.0
I
v v v
« « «
v
:::::16.0 f - - ;::; 10.0 ;::; 7.0
? MERW + +
+ +
(!)
+
(!)
(!)
L L
~ 15.0 v
«
9.0 v
«
6.0
«
(!) (!)

g 8.0
-12.0 -8.0 -4.0 0.0
g 5.0
-9.0 -6.0 -3.0 0.0
LOG(A(SI02CAO))) LOG(A(SI02(AO)))
~ 12 . 0 r--r-~"'--"'Tlr~~-'--, ~ 9.0
** ** ~'I
I
? 11.0 - f - "+ 8.0
I I
v v v
« «
v
«
v
;::; 10.0 ;::; 7.0
+ +
+
(!)
+
(!)
L L
v 9.0 v 6.0
« «
v
(!) (!)

g
(!)

14. 0L.L~~----'L.....J"""""---'
-14.0 -10.0 -6.0 -2.0
g 8.0
-12.0 -8.0 -4.0 0.0
g 5.0
-9.0 -6.0 -3.0 0.0
LOG(A(SI02(AO))) LOG(ACSI02(AO))) LOG(ACSI02CAO)))

~ 1 2. 0 ......,..-~..-",-~~---, ~ 9.0
** **
"+ 8.0
I I
v v v
« «
v
«
v
;::; 10.0 ;::; 7.0
bI +
+
+
+
(!) (!)
L L
~ 9.0 v 6.0
«
v v
(!)

g
(!) (!)

14. 0L.L-~~-~""""',,--,"--'
-14.0 -10.0 -6.0 -2.0
g 8.0
-12.0 -8.0 -4.0 0.0
g 5.0
-9.0 -6.0 -3.0 0.0
LOG(A(SI02(AO))) LOG(A(SI02(AO))) LOG(A(SI02CAO)))
~ 8.0
**
""I+ 7.0
v
«
v v
;::; 10.0 ;::; 6.0
+ +
+
(!)
+
(!)
L L
v 9.0 v 5.0
« «

g
(!) (!) (!)

I 4 . 0w...~~-""""""""'L....l.-'--J
-14.0 -10.0 -6.0 -2.0
g 8.0
- I2 . 0 -8 . 0 -4. 0 0 .0
g 4.0
-9.0 -6.0 -3.0 0.0
LOG(A(SI02(AO))) LOG(A(SI02CAO))) LOG(ACSI02CAO)))
Phase relations in the system HCl-H 20-(CaO)-MgO-Si0 2• Saturation limits: quartz (a),
amorphous silica (b), antigorite (c), talc (d), forsterite (e), brucite (0, peric~ase (g).
 45
~ 8.10 ~ 7.10 ~ 7.10
** ** *
';:' 7.10 ';:' 6.10
"*
"J:+ 6.10
J: J:
v v v
<{ <{ <{
v v v
;::; 6.10 ;::; 5.10 ;::; 5.10
+ + + MERW
+
(!)
+
(!)
+
(!)
l: l: l:
~ 5.10 ~ 4.10 v 4.10
<{
v v
(!) (!) (!)

g 4.10
-6 . a -4. a -2. a a .a
g 3.10
-6. a -4 . a -2. a
g 3.10
10.10 -6 . 10 -4. a -2. a 10. a
LOGCACSI02CAO))) LOGCACSI02CAO))) LOGCACSI02CAO)))
~ 8.10 ~ 7.10 ~ 7.10
* ** **
""+* 7.10 "+ 6.10 ';:' 6.10
J: J: J:
v v v
<{ <{ <{
v v v
;::; 6.10 ;::; 5.10 ;::; 5.10
+ + +
+ + +
(!)
l:
(!)
l:
(!)
l: MERW
v 5.10 v 4.10 v 4.10
<{ <{ <{

(!) (!) (!)

g 4.10
-6.10 -4.10 -2.10 10.10
g 3.10
-6.10 -4.10 -2.10 10.10
g 3.10
-6.10 -4.10 -2.10 10.10
LOGCACSI02CAO))) LOGCACSI02CAO))) LOGCACSI02CAO)))

~ 7.10 ~ 5.10 ~ 3.10

** ** *
*
';:' 6.10 "+ 4.10 ';:' 2.10
J: J: J:
v v v
<{ <{ <{
v v v
;::; 5.10 ;::; 3.10 ;::; 1.10
+ + +
+ +
(!)
+
(!)
(!)
l: l: l:
v 4.10 v 2.10 v 10.10
<{ <{ <{
v v
(!) (!) (!)

g 3.10 g 1.10 3-1.10

-7.10 -5.10 -3.10 -1.10 -6 . 10 -4 . 10 -2. 10 10 . 10 -6 . a -4 . a -2. a 10. a
LOGCACSI02CAO))) LOGCACSI02CAO))) LOGCACSI02CAO)))
~ 6.10 ~I.IO ~6.1O

* ** *
""+* 5.10 "+-2.10 ""*+-7.10
J: J: J:
v v v
<{ <{ <{
v v v
;::; 4.10 ~3.1O ~8.1O
+ + +
+ +
(!)
+
(!)
(!)
l: l: l:
v 3.10 v-4.1O v-9.1O
<{ <{ <{

(!) (!) (!)

o 2 a 3-5. a 3-1 10. a '--------.J.'"'-----~_-"-.ll.J

...J '-7.10 -5.10 -3.10 -1.10 -7.10 -5.10 -3.10 -1.10 -7.10 -5.10 -3.10 -1.10
LOGCACSI02CAO))) LOGCACSI02CAO))) LOGCACSI02CAO)))
Phase relations in the system HCl- H20 - (CaO) - MgO - Si02• Saturation limits: quartz (a),
amorphous silica (b), antigorite (c), talc (d), forsterite (e), brucite (f), peric1ase (g).
46
;:::; 26. 12I,.........~~-M~E-R~W.......-r-,.-, ;:::; 2121. 121 r-~'C"'""-~~.,...---, ;:::; I 4 . 121 '--~~-oo"'-E-R~W-o-r-.,
*
"-:;* 23.121 ** 18.121
~ "** I MONTI
+

A
~ I... ~~I.~M
WOLL 1M NT -:; 12.121 JLL / " I

;2Lc:
I
v
<[
v
5,6.121
<[
v WOLL ,/' ~ w~oP . "b
~ 2121.121 ~ 14.121
+ +
+ +
<[ (3 12.121 """\----'
~
T~E I <[
u /'
..;...J I
~ 17.121
<[
v
aTZ ......-1 I ~ 8.121 aTZ I
j 1121.121
v

g 14. 0'--~~L...L~~~""""
~ ~
ANTIG
, v
~
AL ANFG
g8.121 g6.121
9.121 12.121 15.121 18.121 6.121 8.121 1121.121 12.121 3.121 5.121 7.121 9.121
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

~ 26. 12Ir-~~~M-E~R~W-..f.v~"
. .,....., ;:::; 2121. 12Ir-~---"'-~~-'---' ;:::; I 4 • 12Ir-~~--.'--~~",,-,
: MERW I * ER I
~ M1~T ~ 18.121 I *
~ I 2 • 121 WOLL IMmJTI
~23.121 W p L L6,
§ I 6. 121 WOLL ~~TI
5 /"'
~ 2121.121 ~ 14.121 lOP' /? g 1121.121 /oIOP.
",~{REI1
/?
t
<[ ",./1
lOP
T~EM
I +
~ 12.121
,,----='~EM
\_i>---/ I
I
+
.!iu: f-/ I
~ 17.121 -...-.JI /'
~ 8.121 aTZ ANT~G
j aTZ \ I ANT~G j I 121 . 121 aTZ ANTJ:G v
Tel I AL I
g 14. 0L-.~~..L.."""'~""""........J
~ ~ ~

g 8.121 g 6.13
9.121 12.121 15.121 18.121 6.121 8.121 1121.121 12.121 3.121 5.a 7.121 9.13
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
~ 26. 12Ir-~~~M-E~R~W"'''I'''''''' ;:::; 2121. 121 ..-~""<"""'"-~~--.---. ;:::; 14. 12Ir-~""""~~~~,,---,
* MERW I *
~ M9~T "* 18.121
I "-:;*
"+
~ 23.121 WOLL ~ 5,6.121 WOLL TO~TI I
v
12.121

~6,
<[ <[

~ 2121.121
v v
: ~ 14.121 ~ 1121.121
t lOR 9 +
+ ~
+
+
(3 12.121
~ ~ '\!;.tI
<[
17.121 ANTlG v ANTtG u
~ 8.121
j aTZ ~;r I j 1121.121 aTZ I
Tel
g I 4. I2IL-.~~..L.."""'~............-J
~ ~ ~
g 8. 121 L-~----'-_lo.-~--,---.I g 6.13
9.121 12.121 15.121 18.121 6.121 8.121 1121.121 12.121 3.121 5.121 7.121 9.121
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
;:::; 26. 121,.........~~-~""""'....7"""""1 ;:::; 2121. 121 r--...............-~~...,.--, ;:::; I 4 • 121 r-"""". . . .
-~~--,..---,

**
"-:;
*
"* 18.121
MERWI :
""+
MERW
23.121 "+ 12.121
I
v 516.121 WOLL MO~TI v
I
<[ <[

~9
<[
v v v
~ 2121.121 ~ 14.121 ~ 1121.121
+ + +
+ + +
(3 12.121
'~
<[ <[
u I u
v 17.13 v
~ 8.121
j 1121.121 aTZ - ANTTG
<[
v T v
~ ~ I
g 14.9.121
~
0'--~~"""""""'~"""""""" g 8.13 g 6.121
12.121 15.121 18.121 6.121 8.121 1121.13 12.121 3.121 5.121 7.121 9.121
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CAC~+))**2)
Phase relations in the system HCl- H20-CaO- MgO- (Si0 2). Saturation limits: brucite (a),
periciase (b).
 47
;;:; 12 . 0 r-~~--'~~---''''-'''' ;;:; 1 1 . 0r-""~-~-""'::I~"" ;;:; 11 . 0r--~-~-....~-'

**
,....
A 11.0
I MOr--JT
**
,....
,.... 10.0 **
,....
,.... 10.0 MERW
+ + +
(; 10.0
«
v
WOLk~ (; 9.0
«
v
(; 9.0
«
v
DrOp /
;:::; 9.0
+
+ A/n ;:::; 8.0
+
+
;:::; 8.0
+
+
~ 8.0
v \~~ ~ 7.0
v
~ 7.0
v
:) 7.0 aTZ :) 6.0 :) 6.0
(!) (!) (!)

~ 6.0 ~ 5.0 ~ 5.0

2.0 4.0 6.0 8.0 3.0 5.0 7.0 3.0 5.0 7.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
,.... 12.0 ,.... 11.0
;;:; 11.0
(\J (\J

**
,.... 11.0
**
,.... 10.0
MERW **
,.... 10.0
,.... ,....

%'" :
r'o
+ + MON1r +
(; 10.0 Wall (; 9.0 (; 9.0
« « «v
v v
;:::; 9.0
+
;:::; 8.0
+ DIOP / ? ;:::; 8.0
+
I
a
+ + ~~ FORST + I
~ 8.0 ~ 7.0 ~ 7.0 FqRST
v v
'-:~
v
:) 7.0 :) 6.0 :) 6.0 I
aTZ AN rG
(!) Al 8 TALC
~ 6.0 ...J 5. 03 . 0 5.0 7 .0
2.0 4.0 6.0 8.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

;;:; 1 1 . 0 r--~o;:--~-r~-;-..., ;;:; 9.0 ;;:; 7.0

**
,.... 10.0 ** 8.0
,....
*
* 6.0
,....
,.... ,.... IMONTll ,....
+ + Wall ~ I +
(; 9.0 (; 7.0 (; 5.0
« «
v
«
v v
Drop / I
;:::; 8.0 ;:::; 6.0 ;:::; 4.0

~& FOR~T
+ + +
+ + + FOR~T
~ 7.0 ~ 5.0 ~ 3.0
v v v
I
aTZ
:) 6.0 :) 4.0 :) 2.0
AlC
(!) (!) (!)

~ 5.0 ~ 3.0 ~ 1.0

3.0 5.0 7.0 1.0 3.0 5.0 -1.0 1.0 3.0
lOG CACMG++)/CACH+))**2) lOG CACMG++)/CACH+))**2) lOG CACMG++)/CACH+))**2)
;;:; 10.0 ;;:; 4.0 ;;:; 0.0

l~
MERW~,
** 9.0 * **
,....* 3.0
,.... MONTII ,.... MERW
"""1.0
,....
"+ Wall
+ + MONTI 1
(; 8.0
«
v ~p/ ;
(; 2.0
«
v
;:::; 1.0 ~0 i
~2.0
«
v
Wall

/"""
l I

6
\~
;:::; 7.0 ~3.0 /Drop
"'~ O~S
I
+ + +
+ + +
~ 6.0 ~ 0.0 FORST tt 4 . 0 ~~ FORS~
v \ NT G v I v \T~M I
aTZ aTZ ./ I
:) 5.0 ~1.0 ~5.0
(!) (!) (!) T C I
~ 4. 0 ~2 • 0 0 6 0
2.0 4.0 6.0 -5.0 -3.0 -1.0 J' -'10.0 -8.0 -6.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
Phase relations in the system HCl- H20 - CaO - MgO - (Si0 2). Saturation limits: brucite (a),
peric1ase (b).
48

~ 26 . 0 r-~~-M~E-R~W--V:""~--' ~ 20. 0r-~<:"""'-~~,....---' ~ 14. 0~-~~~--""""""

* ** **
MER'+'
M NTI
, ,..., 18.0
,...,

/11
-:;: 23.0 + 1 NTI -:;: 12.0
I I
v ~ 16.0 WOll/"-l v
...: Wall ...: ...:
> 4.0 /DIO~
v v v
;:::; 20.0 ;:::; 10.0
+ lOP a + +
+
+ +
;
I
...: ("j 12.0 ~~ ...:
u
"'~
u v 8.0
CH~YS
;;: 17.0 v
\ CH~YS --- ...: aTZ
v
aTZ
1
:3 10.0 aTZ v
Al (.!) (.!)

3 1 4 • 0 L....o~---.JL..........L....-~-'-"'---'
(.!)

:l8.0 :l 6.0
9.0 12.0 15.0 18.0 6.0 8.0 10.0 12.0 3.0 5.0 7.0 9.0
lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2)

~ 26 . 0 ,........,~~~~~'<"TT""1 ~ 20.0 ~ 14.0

ER
**
1
** **
,..., 18.0
MER~

' -'- /",1

IMO~T
,..., Wall
-:;: 23.0 + -:;: 12.0
I Wall I
~ 16.0

Ib
v v
...: ...: ...:
v v v
;:::; 20.0 ;:::; 14.0 ;:::; 10.0 /oIOP
+ + +
+
...:
+
("j 12.0
+
...: ~~/ ~
u u ./' CHI'(Y
v 17.0 v v 8.0
...: ...: aTZ 1
v :3 10.0 v
Al
(.!) (.!) (.!)

:l 1 4 . 0 L........~~-"'---L.~.........."'---' 38.0 36.0

9.0 12.0 15.0 18.0 6.0 8.0 10.0 12.0 3.0 5.0 7.0 9.0
lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2)

~ 20.0 ~ 14.0
ERW
** **
MERWI
,...,
,..., 18.0 1
1
+
~ 16.0 Wall ~O~T
-:;: 12.0
I
v
WO~l MO~TI
...: ...:

~l~
v v
"')/IT
;:::; 14.0
+
;:::; 10.0
+
b
DIOP /
+
("j 12.0 :rRErJ:
+
...:
u
"'~rEM!
/fO~S
~
v CHRYS v 8.0 ..,/' CH~Y
...:
:3 10.0 aTZ 1 v aTZ
(.!) (.!) (.!)
3 14 . 0 '---'~~..L...--'--~........"'---' 38.0
6.0 8.0 10.0 12.0
36.0
9.0 12.0 15.0 18.0 3.0 5.0 7.0 9.0
lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2)

~ 26.0 ~ 20.0 ~ 14.0

MERW~
** ** **
MERWI
,..., M ,..., 18.0 ,...,
,..., ,...,
-:;: 23.0 + + 12.0
I MONTI I
v ~ 16.0 v
...: ...: ...:
v v v
;:::; 20.0 ;:::; 14.0 ;:::; 10.0
+ + +
+ + +
...:
u
("j 12.0 ...:
u
v 17.0 v ;;: 8.0
...:
v :3 10.0 v
(.!) (.!) (.!)
3 14. 0 L....o~~J........--"--~ ........."'---' 38.0
6.0 8.0 10.0 12.0
36.0
9.0 12.0 15.0 18.0 3.0 5.0 7.0 9.0
lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2)

Phase relations in the system HCl- H20 - CaO - MgO - (Si0 2). Metastable chrysotile was con-
sidered instead of its stable counterpart, antigorite. Saturation limits: brucite (a), periclase (b).
 49
~ 12. 0 r-~~----..~~--".--, ~ 1 1 • 0r-""'-~----r-:r--' ~ 1 1 • 0r----~-.--...,......,
*
-:.. 11.0
I
a **
~ 10.0
MERW I *
* 10.0
~
MONT

~
"+ I
+ MONtI +
510.0 59.0 59.0

;2:Pj'
WOkl I « WOll "'" «
« I
?
v v v
;::; 9.0 Drop ;::; 8.0 Drop ;::; 8.0
+ OR + +

""c§(
+ I + I +
;:'j 8.0
\ E I I
;:'j 7.0
v
FO~ST ;:'j 7.0
v '"_~ FO~ST
~~~
v
~ 7.0 aTZ ~ 6.0 OTZ I ~ 6.0 I
TALC OTZ
(!) (!) (!) Al
:l6.0 :l5.0 :l 5.0
2.0 4.0 6.0 8.0 3.0 5.0 7.0 . 3.0 5.0 7.0
lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2)
~ 12.0 ~ 1 1 . 0~-~-~-.-;r---, ~ 1 1 • 0r--~-~--r--"--'
* * *
"* 11 .0 "* 10.0 "* 10.0 MERW
"+ "+ "+ I
510.0
«
WOll 59.0
«
5« 9.0 MO~TI

v v v
;::; 9.0 ;::; 8.0 ;::; 8.0 I
+
+
+
+
+
+
aI
;:'j 8.0 ;:'j 7.0 ;:'j 7.0 FOPST
v v v
~ 7.0 ~ 6.0 ~ 6.0 I
(!) (!) (!)

:l 6.0 :l5.0 :l5.0

2.0 4.0 6.0 8.0 3.0 5.0 7.0 3.0 5.0 7.0
lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2)
~ 1 1 . 0r-'-""--O;:-c::'R.---r-~I;-----, ~ 9.0 ~ 7.0
* * **
-:.. i 0 .0 WOll MON-rr "* 8.0 I MONTII " 6.0
"; I "+ "+
5« 9.0 57.0 WOll "" I 55.0
v
«
v DrOp / a «
v

& FOR~T
;::; 8.0 ;::; 6.0 ;::; 4.0
+ + +
+ + +
;:'j 7.0 ;:'j 5.0 "" I ;:'j 3.0
v v v
~ 6.0 ~ 4.0 OTZ I ~ 2.0
(!) (!)
AlC I (!)

:l5.0 :l 3.0 :l 1.0

3.0 5.0 7.0 1.0 3.0 5.0 -1.0 1.0 3.0
lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2)
~ 10 . 0 "---M-E~R--:y""""",~~~'-I--, ~ 4.0 I ~ 0.0
* MONTi! **
"* 3.0
MERW
-:.. 9.0 ~ONTtr WOll
"'-1.0
"; W~ll "+ "+ MONTI I

~0i
58.0 I 52.0 ~2.0 WOll ~ I
~ Drop / a «
v
«
v
;:::-3.0 ~p ~
~~
;::;7.0 ~ I ;::; 1.0
t .----1'REM ~ FO~S
+ +
+ FORST +
;:'j 6.0 \ ;:'j 0.0 (3"4.0 ' " L1. FORS-r
v C YS I v \ I v \IR~M I
~ 5.0 OTZ ~1.0 OTZ I ~5.0 OTZ/ I
(!)
TALC (!) (!) C I
:l 4.0 5-2.0 ' 5-6.0
2.0 4.0 6.0 -5. 0 -3 .0 -1 .0 -10.0 -8.0 -6.0
lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2) lOG CACMG++)/CACH+)**2)

Phase relations in the system HCl- H20 - CaO - MgO - (Si0 2). Metastable chrysotile was con-
sidered instead of its stable counterpart, antigorite. Saturation limits: brucite (a), periciase (b).
 -~~~I;t-
50
~ 18.0 ~ 14.0 ~ 12.0

* ** **
'"*
'"+
16.0 '"
'"+
12.0 ANTIG '" 10.0
'"+ ANTIG:
- -b-
I
v
<{
14.0 C 10.0
<{
C 8.0
<{
-b-
v TALC I v v
...... 12.0 ;:::: 8.0 TALC ;:::: 6.0 TALC
'"+ IFAY + I FAY + FAY
+ I + +
(!)
10.0 ~ 6.0 I ~ 4.0 I
1:
v aTZ
a
I
v aTZ I
v aTZ a,
~ 8.0 I ~ 4.0 a, ~ 2.0
I
(!) FER OS~L (!)
FE SIL (!) FE
SIL
:l6.0 :l 2.0 :l 0.0
6.0 10.0 14.0 18.0 2.0 6.0 10.0 14.0 0.0 4.0 8.0 12.0

1-
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

c::J t8.0 ~ 14. 0r-~~-~~-r~-' ~ 12.0

- ~~T~; _A~~IG / _
** ** ANTIG **
,...
'" 16.0 '" 12.0 '" 10.0
+ '"+ -b- '"+
C 14.0 C 10.0 C 8.0
<{
v lALC <{
v
<{
v
I TALC TALC
;:::: 12.0 ;:::: 8.0 ;:::: 6.0 I
+ I FAY + FAY + I FAY
+ I + +
~ 10.0 ~ 6.0 I
~ 4.0
v
aTZ aI v aTZ a v aTZ
I
I a
I

~ 8.0 I ~ 4.0 ~ 2.0

I I
(!) FER 0SP:L (!)
FE SIL (!)
FER 1p_SIL
:l6.0 :l 2.0 :l0.0

1--
6.0 10.0 14.0 18.0 2.0 6.0 10.0 14.0 0.0 4.0 8.0 12.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

_:NT~/__
~ 18.0 ~ 14.0 ~ 12.0

**
'"
'"+
16.0 - ;:;'~~G **
'"
'"+
12.0
_A~~'~ / __
**
'" 10.0
'"+
C 1.4.0
<{
C 10.0
<{
C 8.0
<{
v TALC v v
I TALC
;:::: 12.0 ;:::: 8.0 I ;:::: 6.0 TALC I
I FAY FAY
+ + I + I FAY
+ I + +
~ 10.0 ~ 6.0 I ~ 4.0 I
v
aTZ
a
I
v aTZ I v aTZ ,
~ 8.0 I ~ 4.0 a ~ 2.0 a
I I
(!) FEF RO~IL (!) FER ~O~IL (!)

:l 6.0 52.0 I
50.0
6.0 10.0 14.0 18.0 2.0 6.0 10.0 14.0 0.0 4.0 8.0 12.e

I--
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

-A~~;G If--
~ 18.0 '" 14.0 ~ 12.0

:~b'~
N
I
* *
'"* 16.0
'"* 12.0 '"** 10.0
'"+ '"+ '"+ ANTIG:
I
v
<{
14.0
I
v
<{
10.0 C 8.0 -b- -l
<{
v 'AI I v v
...... 12.0 ;:::: 8.0 TALC I ;:::: 6.0
'"+ I FAy + I FAY + TALC FAY
+ I + +
(!)
10.0 ~ 6.0 I ~ 4.0
a
I
1:
v aTZ I v aTZ a, v
~·8.0 a
I ~ 4.0 ~ 2.0
aTZ I

(!) FER OSjIL (!) FER OJbL (!)

:l 6.0 :l 2.0 50.0

6,0 10.0 14.0 18.0 2.0 6.0 10.0 14.0 0.0 4.0 8.0 12.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

Phase relations in the system HCl-H 20-FeO-MgO-(Si0 2). Saturation limits: ferrous oxide
(a), brucite (b), periciase (c).
 51
~
*
8.0
FORST 1/ ~
*
8.0 ~
*
8.0

"* 7.0
"+
06.0
«
ANTIG 7
T. -b- "* 7.0
"+
06.0
«
- -'00"-"' V-b- "* 7.0
"+
06.0
«
v
TALC
I v r-f ANTIG v
~ 5.0 I ~ 5.0
TALC p ~ 5.0
+ + FAY +
+ I FAY + I +
~ 4.0 ~ 4.0 ~ 4.0
I I
,
aI
v OTZ v , v
~ 3.0 a ~ 3.0 OTZ a ~ 3.0 OTZ
(!) (!) I (!)
FER bSIL
~ 2.0 ~ 2.0 ~ 2.0
-3.0 1.0 5.0 9.0 -3 . 0 1.0 5 .0 9 .0 -3.0 1 .0 5 .0 9.0
LOG (A(FE++)/(A(H+» •• 2) LOG (A(FE++)/(A(H+» •• 2) LOG (A(FE++)/(A(H+» •• 2)

~O~S~ iJ- b-
~ 8.0 ~ 8.0 ~ 8.0

**
_-,,"o~s:r.!b _
* *
"* 7.0 "* 7.0
_
"7.0
"+
06.0
«
v
ANTIG

TALC
1
I
"+
06.0
«
v
"+
06.0
«
v
~ 5.0 I ~ 5.0 ~ 5.0
+ FAY + TALC +
+ I + FAY +
~ 4.0

"a
~ 4.0 ~ 4.0
I
a I
v OTZ v v
~ 3.0 I ~ 3.0 OTZ , ~ 3.0 OTZ
(!) I (!) I (!)

~ 2.0 ~ 2.0 ~ 2.0

-3. 0 1 .0 5. 0 9 .0 -3.0 1.0 5.0 9.0 -3.0 1.0 5.0 9.0

Y
LOG (A(FE++)/(A(H+» •• 2) LOG (A(FE++)/(A(H+» •• 2) LOG (A(FE++)/(A(H+» •• 2)
~ 8.0 ~ 6.0 ~ 4.0
*
"* 7.0
"+ _~o~s~/b_ *
"* 5.0
"+ -'ORS~ -b-
**
" 3.0
"+ -:R~T_Vb-
06.0
«
v
ANTIG I 04.0
«
v
02.0
«
v
~ 5.0 ~ 3.0 TALC P FAY ~ 1.0
TALC
+
+ I: FAY +
+
I +
+ TALC
I FAY
~ 4.0 ~ 2.0 I ~ 0.0
v 6 v I v I
~ 3.0 OTZ I ~ 1.0 OTZ a ~1.0 OTZ
I
I I
(!) (!)
I.
(!)
I
~ 2.0 ~ 0.0

t-
3-2.0
-3 . 0 1 .0 5 .0 9 .0 -4 . 0 0 .0 4 .0 8 .0 -7.0 -3.0 1 .0 5.0
LOG (A(FE++)/(A(H+» •• 2) LOG (A(FE++)/(A(H+» •• 2) LOG (ACFE++)/(A(H+» ••2)

-F:R~~-V -
~ 8.0 ~ 0.0 ~6.0
,

:oo~
*
~ 7.0 a **
1">-1.0
**
1">-7.0
"+ FORST I "+ b- "+
06.0 I 0-2.0 0-8.0
« « «
v v v TALC I
~ 5.0 ~3.0 ~9.0 I
+ ANTIG
FAY + TALC p FAY +
+ + + I FAY
~ 4.0 ~4.0
I ~10.0
TALC I
1: OTZ
I
v v
OTZ a v
a
~ 3.0 ~5.0 I ~11.0 I

OTZ I
(!) (!)
I (!)

~ 2.0 3-6.0 3-12.0

-3.0 1.0 5.0 9.0 -1 0 . 0 -6 .0 -2.0 2. 0 -1 6 .0 -1 2 .0 -8 .0 -4.0
LOG (A(FE++)/(A(H+» •• 2) LOG (A(FE++)/(A(H+» •• 2) LOG (A(FE++)/(A(H+».*2)

Phase relations in the system HCI- H 20 - FeO - MgO - (Si0 2). Saturation limits: ferrous oxide
(a), brucite (b), peric1ase (c).
52
~
**
'"'
'"'+
314.0
«
v
18.13

16.0 - -b;;-H;'S-

TALC
t I
~

**
'"'+
310.0
~
14. 0'-~--~--~71

'"' 12.13 CHRYS

-b- - - -
~~T~A~L~C~~
I
~

**
'"'
'"'+
38.0
«
v
12. 0r-~~-~~-~T"1

10.0 CHRYS
-b- -
;::: 12.0 ;::: 8.13 ;::: 6.13 TALC
+
+ ~AY +
+
IFAY +
+
FAY
~ 10.0 ~ 6.13 I ~ 4.13 I
v aTZ a
I
v aTZ a, v aTZ aI
~ 8.13 I ~ 4.13 ~ 2.~
I I
(!) FEF O~IL (!)
FER IL (!)
FER IL
:l6.a4.0 2 :l2. a :l0.0
8.13 1.13 I 6'"
.'" 0.13 4.0 8.13 12.13 -2.0 2.0 6.13 113.13
LOG (A(FE++)/CA(H+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CA(H+))**2)
~
**
'"'
'"'+
314.13
«
v
18.13

16.13
-~~.~s--1
TALC I
I
~
**
r\
r\
+
12. a

3113.13
«
v
14.13
CHRYS
- -b--

TALC
-(
~

**
r\
r\

«
v
+
~ 8.0
12. a.-~--~~-..."

10. a
CHRYS
-b-

;::: 12.13 ;::: 8.0 I ;::: 6.13

TALC
+ Fh + I FAY +
FAY
+ I + +
~ 10.13 aI ~ 6.0 I ~ 4.13
v
aTZ v aTZ a, v aTZ 1
~ 8.0 I ~ 4.0 ~ 2.13 a
FER OSfL 1 I
(!) (!)
FER O~IL
(!) FERR IL
:l6.a :l 2.0 :la .0
4.13 8.13 12.13 16.13 13.0 4.13 8.0 12.13 -2.13 2.0 6.0 10.13

1- I-
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CA(H+))**2)

-1-
~ 18.13 ~ 14.0 ~ 12. 0r-~--~~-...,....,

1:°;° _CH:~S -
** - -b-- ** 12.0
16.13
'"'I'"'+
r\

CHRYS '"'+ Y'·'C' -b

v 14.0 I ~ 10.0
« TALC «
v I v TALC 1
v
I
'- 12.13 ;::: 8.0 ;::: 6.0 TALC
r\
1------1 1 FAY
+
+ ~AY +
+
1 FAY +
+
(!)
113.13 aTZ ~ 6.0 1 ~ 4.0 1
l:
v I v aTZ a v aTZ a,
~ 8.0 a ~ 4.0
I
~ 2.0
I
I I
(!) FERF pS~L (!)
FER qpIL (!)
I
:l 6. a :l2.0 :la.0

1_
4.0 8.13 12.13 16.13 0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.13
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

1-
~ 18.0 ~ 14.0
*
* 16. a
r\
r\
+
- -b--
CHRYS
*
* 12.0
r\
r\
+
_c~;~s_
314.13 I ~ 113.0
« TALC «
v I v TALC 1
;::: 12.13 IFAY ;::: 8.0
TALC I
+ +
+
I FAY I-----{ I FAY
+ I
~ 10.13
a ~ 6.0 1 1
v aTZ I v aTZ a
I aTZ
aI
~ 8.0 I ~ 4.0
1 1
(!) FE~ RO~IL (!)
FE RpSIL (!)
I
:l6. a :l2.0 :l 0. a
4.13 8.13 12.13 16.13 13.0 4.0 8.0 12.13 -2.0 2.0 6.0 10.0
LOG CACFE++)/CACH+))**2) LOG (ACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
Phase relations in the system HCI-H 20-FeO-MgO-(Si0 2). Metastable chrysotile was con-
sidered instead of its stable counterpart, antigorite. Saturation limits: ferrous oxide (a), brucite
(b), periclase (c).
 53

-/
~ 8.0 ~ 8.0 ~ 8.0

~l
-~
* *
**
" 7.0 - ~O,::,S~b_ "* 7.0
FORST
"* 7.0 FORST
"+
~ 6.0
«
CHRYS
I "+
~ 6.0
«
- -b- -
"+
~ 6.0
«
- -b- -
v TALC I v v
~ 5.0 I ~ 5.0 TALC ft ~ 5.0
+ + +
+
~ 4.0 ,
IFAY +
~ 4.0
I +
~ 4.0
TALC Ii
I FAY I FAY
v QTZ a v
, v
QTZ I
~ 3.0 I ~ 3.0 a ~ 3.0 QTZ a
(!) FERR tIL (!) I (!) I
S 2.0
-5 . 0 - 1.0 3 .0 7.0
S 2.0
-5.0 -1.0 3.0 7.0
S 2.0
-5 . 0 - 1. 0 3 .0 7.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

-1
~ 8.0 ~ 8.0 ~ 8.0
:I<
:I<
" 7.0
FORST
----
b -
~- :I<
:I<
" 7.0 FORST
*
"* 7.0 FORST
"+ "+ "+
~ 6.0
CHRYS
I ~ 6.0
- -b--
~ 6.0 - -b--
« TALC « «
v v v
~ 5.0
+
+
~ 4.0
",
I
IFAY
~ 5.0
+
+
~ 4.0
TALC ~
I
~ 5.0
+
+
~ 4.0
TALC P FAY
I FAY I
v QTZ a v v
~ 3.0 I ~ 3.0 QTZ I ~ 3.0 QTZ I
(!) I (!) I (!) I
S 2.0
-5 . 0 - 1 .0 3 .0 7.0
S 2.0
-5 . 0 -1. 0 3.0 7 .0
S 2.0
-5. 0 - 1. 0 3.0 7 .0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

_~R~T_b~1-
-0
~ 8.0 ~ 6.0 ~ 4.0
*
"* 7.0
"+
~ 6.0
*:I<
" 5.0
"+
~ 4.0
_F~~~ ~ _ _
**
" 3.0
"+
~ 2.0
-
FORST
-b- -
«
v
;HK ';:', «
v
«
v
~ 5.0 ~ 3,0 ~ ~ 1.0
+
+
TALC
I: FAY +
+
TALC
I FAY +
+ TALC
~ 4.0 ~ 2.0 I ~ 0.0 I F.AY
I
v
, v I v I
~ 3.0 QTZ
a ~ 1.0
QTZ a ~1.0 QTZ
I
I
(!) I (!)
II.
(!)
I
S 2.0-5 . 0 -1.0 3.0 7 .0
S 0.0
-6.0 -2.0 2.0 6.0
5-2.0
-9 . 0 -5. 0 - 1 . 0 3 .0

y_ -1
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

~ 8.0 ~ 0.0 ~6.0

*
"* 7.0
"+
FORST
a
I
**
,",""1.0
"+ _F~R~~ _
**
'"'""7.0
"+
- -c- -
FORST
~ 6.0 5-2.0 5-8.0
« -b- - « «
v v v TALC I
~ 5.0 ~3.0 ~9.0 I
+ TALC I +
+ FAY I FAY
+ FAY + I +
~ 4.0 TALC ~4.0 ~10.0
QTZ I
v v
QTZ
I
a,
v
a,
~ 3.0 ~5.0 ~11.0
QTZ I
(!) (!)
I (!)

S 2.0
-5.0 -1.0 3.0 7.0
5-6.0
-12.0 -8.0 -4.0 0.0
5-12.0
- 18 .0 - 14 .0 - 10 .0 -6. 0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

Phase relations in the system HCl- H 20 - FeO - MgO - (Si0 2). Metastable chrysotile was con-
sidered instead of its stable counterpart, antigorite. Saturation limits: ferrous oxide (a), brucite
(b), peric1ase (c).
54
;;:; 20.0 ;;:; 16.0 ;;:; 12.0
\
,1
\ \
1
* *
** 'a
GROSS , \ 1

'"+* '"* a
,
1
,ql
b ,GROSS
'"
';' 18.0 -
~ _1 __
'"J: 14.0
\
,
'GROSS ';' 10.0
\
I
J: t- -b- -'-, - - -
,
J:
v PREHN v , 1 v
<{ <{
v ~ -tL- -~--
<{
v
PREHN \,
v
) CLNZ 1
I' ,,
;::; 8.0
,
;::; 16.0 ;::; 12.0 PREHN
+
+
LAWS +
+ ~ +
+ 1
LAWS
,,
,\
,
,, ,,
<{ <{ <{ I
u u u
\
~ 14.0 v 10.0 v 6.0 d
v GIBBS d <{
v KAOL c;l <{
v KAOL 1
(!) ,
I
(!)
1 (!) I
g 12.0
4.0 8.0 12.0 16.0
g 8.00.0 4.0 8.0 12.0
34.0
-2. 0 2 .0 6 .0 10 .0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2:
;;:; 20.0 ;;:; 16.0 ;;:; 12.0 y
GROSS\, I \
1 1
* 1
** 'a\ * 1
'"*
';' 18.0
- -b- ..1 _1- - '"
'"
+ 14.0
IGROSS '"*
'"
+ 10.0
GROSS', ,
J: PREHN '01 J: \ I J: f-- - -b-'+ - - -
v v v
\1 \ PREHN ~
,
<{ <{ <{

",
v
~
v b v
CLNZ 1\
;::; 12.0 ;::; 8.0
,
;::; 16.0 PREHN
+ LAWS + +
u
+
<{

v 14.0
1
\
,, u
~
+
<{

10.0
1\
1 ,, +
<{
u
~ 6.0
MARGJ'
9
I
\
a\
KAOL d KAOL
, ,
<{
1
v
d v KAOL
(!) I \ (!) (!) 1
312.0 38.0 34.0
4.0 8.0 12.0 16.0 0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
;;:; 20.0
* ,
\
1GROSS
;;:; 16.0
*
\
, 1
;;:; 12.0
* 1
\
\
'"';'* '"* '"+* a\
1
,
\ 1GROSS 1 GROSS
18.0 - -b- -, -+ - - ';' 14.0 a\ 1 '" 10.0 1
J: J: J:
v v 1 v
<{ PREHN \' <{ <{
PREHN \~ D
v
I.. v --b- ""\ L -- v

,
;::; 16.0 ;::; 12.0 PREHN 1 ;::; 8.0 CLNZ
+ ,\ + '\ +
,
+ + LAUM ___ I, + MARG
d ,,
<{ <{ <{
u
~ 14.0
\
a\
u
v 10.0 d \
u
v 6.0 ,
, ,
KAOL cO: <{
C
v 1 v
KAOL KAOL \
(!) 1 (!)
1 (!)
1

3,2.0 38.0 .1
34.13
4.0 8.0 12.0 16.0 13.13 4.13 8.13 12.0 -2. a 2.0 6.0 10. a
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
;;:; 20.13 ;;:; 16.13 ;;:; 12.13

,
\ \ \
IGROSS 1
* * \ I
**
\

'"* 1 '"*
';' 14.13
\
a\ d
I GROSS '"
'"+
a\ 1
C
GROSS
';' 18.13 f- -b- "\" + - - 113.0

,
J: J: I J: \ I
v v 1 v
<{ PREHN \1 <{ <{ \ I
v v
-b-
v
PREHN \i -b
;::; 16.13 ;::; 12.13 f- PREHN'"" I- ;::; 8.0
\ \1
+
+
<{
u
AUM
, +
+
<{
u
LAUM~ "
+
+
<{
u MARG
.N.

1'
d 'a ,
14.13 \
v ~ 10.0 ~ 6.0

, ,
<{ 1
v KAOL \ v
KAOL I \ v \
1 1 PYROPH 1
(!) (!) (!)

3 12 ".13 8.13 12.13 16.13

g 8.130.0 4.0 8.0 12.0
34.0
-2.0 2.0
I.
6.0 10.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
Phase relations in the system HCl- H 20- CAl 20 3) -CaO- FeO-Si0 2 in equilibrium with quartz.
Saturation limits: hedenbergite (a), wollastonite (b), fayalite (c), ferrosilite (d).
 55
~ 10.0 , ~ 10.0 , .~ 10.0 ,
I I * I
** GROSS \ I
\ *
"* 9.0
\
a, "* 9.0
\
aI
I I

,
"9.0
"+ -b- - -\T - - "+ GROSS \
C
I "+ C
~ 8.0 ~ 8.0 ~ 8.0 GROSS \ ;
<
CLNZ
<
v - -b- -.4 L - - <
v
v
~ 7.0 1\ ~ 7.0 V ~ 7.0 - -b- -\1- - -
+ MARG + CLNZ 1\ +
~\CLNZj
I \
+ + + ANOR
~ 6.0 I \ ~ 6.0 MARG ~ 6.0
v
I
aI v
I \ v
~ 5.0 PYROPH d ~ 5.0 ~ 5.0
I \ KYA I \ SILL I \
(!) (!) (!)

g 4.0 J \ g 4.0 I ~ g 4.0 I \

-4 .0 0.0 4 .0 8.0 -4.0 0.0 4 .0 8.0 -4 . 0 0.0 4.0 8. 0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 10.0 , ~ 10.0 , ~ 10.0 ,
I I I
** * *
\ \
"* 9.0 "* 9.0
GROSS \ a\
"9.0 \Y q I I
"+ -b---\t--- "+ C "+ C
I
~ 8.0 ~ 8.0 ~ 8.0 \
GROSS \ : GROSS \ I
<
v PREHN =:! ~ <
v -b- - .1. - - - <
v
~ 7.0 CLNZ 1\ ~ 7.0 CLNZ I' ~ 7.0 .b II
+ MARG I \ + 1\ + ~
+ + ANOR +
~ 6.0 I ~ 6.0 I\ ~ 6.0 ANOR 1\
v v v
I \
a I I \
~ 5.0 PYROPH \ ~ 5.0 \ ~ 5.0
I AND I SILL
I ,
(!) (!) (!)

g 4.0 L \ g 4.0 I \ g 4.0 1 \

-4.0 0.0 4.0 8.0 -4.0 0. 0 4 .0 8.0 -4.0 0.0 4.0 8.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 10.0 , ~ 8.0 , I ~ 6.0 . \
I I
..!.* 9.0 * \ C
**
\ \
"* 7.0
a C
I GROSS \ I "5.0 I
C GROSS \
"+ GROSS \
\
I
"+ a\ I "+ \ I
~ 8.0 f- - b - - ·Tl - - - ~ 6.0 ~ 4.0
<
v
<
v \' <
v b \1-
~ 7.0 CLNZ "4-PREHN ~ 5.0 1\ ~ 3.0 ANOR 1\
ANOR
+ 1\ + I\ + 1\
+ ANOR + +
~ 6.0 1 \ ~ 4.0 I \ ~ 2.0 I a\
v MARG I \ v
I v
I \
~ 5.0 I \ ~ 3.0 AND ~ 1.0 AND \
AND (!)
I I
(!) (!)

g 4.0-4.0 0. 0
I
4 .0
\
8.0
g 2.0
-8 . 0 -4 . 0 0.0
. I
4 .0
g 0.0
-10.0 -6.0 -2.0
I
2.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 8.0
GROSS' I
~ 3.0 , ~2.0
I
** ~E!lN_~ .l-b- _ ** 2,0
'" GROSS
\ **
""'3.0
GROSS \ I
'" 7.0 \ I I
'"+
~ 6.0
"+
~ 1.0 _b_
ql "+
~4.0
b {
CCLNZ 1\ 1\
<
v
<
v
\' <
v
ANOR
ANOR I \ ~ 1\
~ 5.0
+ MARG
~ 0.0
+
ANOR
I\
~5.0
+
a
+ + +
~ 4.0 I \ ~1.0 I \ ~6.0 I \
v I
a\ v I \ v C
\
~ 3.0 AND c ;:;"2.0 C ;:;"7.0
AND I
I \ AND I I
(!) (!) (!)
o J
3-3.0
I
3-8.0
I
..J 2._06 .0 -2.0 2 .0 6.0 -1 4.0 -1 0 .0 -6.0 -2. 0 - 18. 0 -1 4 .0 - 10 . 0 -6 . 0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
Phase relations in the system HCI-H 20-(AI 20 3)-CaO-FeO-Si02 in equilibrium with quartz.
Saturation limits: hedenbergite (a), wollastonite (b), fayalite (c), ferrosilite (d).
56
~ 40.0 ~ 24.0 ~ 20.0

07
-0
I
**
GEHL I
*
"* 20.0
GEHL
*
*

V
I ,/
I- - - -0- t- - -
"+ ~ 16.0 t- ~E~L-: -
GROSS,Y
'.;: 30.0 1 +
:r: :r:
v ;5 16.0 GROSS v
04:
v
04:
v ~ 12.0 GROSS ~/
;::; 20.0
+ LAWS I
;::; 12.0
+
LAWS
/1 "'"t B.0 CLNZ
/1
+
04:
+ 04: FAY
U I ~ B.0 I FAY U I
~ 10.0 v v
IFAY KAOL I I
v aTZ ~ 4.0 ~ 4.0 KAOL bI
FERF SILl I
(!) (!) (!)
J 1 L
:l0.0 :l0.0 :l0.0
6.0 10.0 14.0 18.0 2.0 6.0 10.0 14.0 0.0 4.0 B.0 12.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 40.0 ~ 24.0 _ _ _ _ _ _ _ ~ 20.0

-;,;c;7
I
= ** **
GEHL GEHL
" - - - - t-O- ~ 20.01-_ _ _-'-_
~ 16.0
'.;: 30. 0 1 - - - - - - , - - - - - j + +
~ GROSS ~ ;5 16.0 GROSS I
:r:
v
GROSS I
~ f- PREHN ~ 12.0
r- CLNZ
v
;::; 20.0 r-PREHN / ;::; 12.0 .1,' "'"t 8.0 I
+
+
+
~ B 0 LAWS
:r I
I FAY
MARG /1
04:
U . 04: I FAY
FAY
U
~ 10.0 v
U
v bI
v
KAOL I
~ 4.0 KAOL b ~ 4.0 KAOL
FER ost I I
(!) (!) (!)
I
:l0.0 :l 0.0 :l0.0
6.0 10.0 14.0 18.0 2.0 6.0 10.0 14.0 0.0 4.0 B.0 12.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
40.0 24.0 - 20. 0r-~~-~-~---,

-7--.
~ ~ ~
- - - -0--
*

V
I
** *
GEHL I
"* 20.0 GEHL : .//"
~ ;-E~ I
,Y
"'.;: 30.0 - - - - -1-0- 16.0 -
:r:
"+ i:v I
v ;5 16.0 GROSS
04: 04:
v GROSS v ~ 12.0 GROSS /
;::; 20.0
+
+
04:
PREHN / I
;::; 12.0
+
+
PREHN /
I
FAY
t
"'
04:
B. 0 CLNZ"-A
MARG
:J
I;
I FAY ~ 8.0 I
U ~ t---b
6
~ 10.0 v
v
KAOL
~ 4.0
KAOL
b1 ~ 4.0 KAOL
I
I
FAY

(!) FEF °11L (!) (!)

.1 .1
:l0.0 :l0.0 :l0.0
6.0 10.0 14.0 18.0 2.0 6.0 10.0 14.0 0.0 4.0 8.0 12.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)

-1-7--
~ 40.0 ~ 24.0 ~ 20. 0r-~~-~-~--,
- - -"1 - 0 - -
* GEHL I *
"* 20.0
=
"'.;:* 30.0 - GEHL I / I GEHL
- - - --l - 0-
~ 16.0 -0-
:r:
v
04:
v GROSSY
"+
;5
04:
v
16.0
GROSS V i:
~
~
12.0 I
I

;::; 20.0 ;::; 12.0 PREHN I' GROSSI/

+
+
PREHN I +
+
I "t B.0 MARG!.
FAY
bI FAY
04: I FAY ~ B.0
U ~r--- I
v 10.0 I v
KAOL v I
KAOL
04:
bI ~ 4.0
I ~ 4.0 KAOL ~
§ 0.00.0
(!) (!)
I i i
:l0.0 ...... :l0.0
6.0 10.0 14.", lB.", 2.0 6.0 10.0 14.0 4.0 B.0 12.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)

Phase relations in the system HCI-H 20-AI 20 3 -CaO-FeO-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limits: lime (a), ferrous oxide (b).
 57

:. 1
~ 14.0 ~ 14.0
- - -1-0- "N 14.0

~E~Li-Y
* GEHL * *
"* "* "*
12.0 12.0 GEHL
I 12.0
"+ "I+ "I+
;5
«
v
10.0 GROSS
_N.
17v v
«
v
10.0
GROSS
v
«
v
10.0

;::; 8.0 ;::; 8.0 LN ;::; 8.0 GROSS J

V
+
+
t3 6.0
MARG
~ FAY
+
+
t3 6.0
MARG
FAY
+
+
t3 6.0
CLNZ
ANOR ) FAY
v I v v I
:3 4.0 KYA ? :3 4.0 KYA :3 4.0 SILL I
(!)
I (!) (!)
I
:l 2.0 :l 2.0 :l 2.0
-2.0 2.0 6. 0 I 0 •0 -2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

*
"*
"+
;5
14.0

12.0

10.0
GEHL

GROSS
?: ..
1/
1 ~ 14.0

*
"*
"+
;5
12.0

10.0
- - ..1 -0-

GEHL
I

b
I
~

*
~
~
;5
14. 0r-~~~1~~-......,,,

12.0

10.0
.L
GEHL I
b

I
-0-

« «
v v GROSS I :3;::; 8.0 ~,
1
;::; 8.0 ;::; 8.0 I
+ MARG +
+ + MARG t CLNZjf'
t3 6.0 FAY t3 6.0 FAY ~ 6.0 ANOR I FAY
v I v
:3 4.0 KYA I :3 4.0 AND :3 4.0 SILL I
I I

1/
(!) (!) (!)

:l2.0 :l 2.0 :l2.0

-2.0 2.0 6.0 I 0.0 -2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

1
13.0 ~ 9.0
~14.0 ~

~ 12.0 GEHL I
*
"* 11.0
- - - J... -0- *
"* 7.0
GEHL b
I
~
;5
b "+
;5
GEHL
I
"+
;5
GROSS] :
I 0 . 0 ~=::-::-::-+-I 9.0 bI 5.0

/
:3 «v «

j
GROSS / v
;::; 7.0 G as I ;::; 3.0
ANOR

J
;::; 8.0
t MARG +
+ CCLNZ
+
+ I FAY
t3 6.0 FAY t3 5.0 ANOR FAY
t3 I. 0 I

~4.0
v v
I AND I
AND'l:
:3 3.0 AND
:3-1.0
(!) (!)
I
:l 2.0 :ll. 0 5-3.0
-2.0 2.0 6.0 10.0 -4.0 0.0 4.0 8.0 -8.0 -4.0 0.0 4.0
LOG CACFE++)/(ACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

GEHL bl '7
~ 13. 0r-~~-"""~-~71 ~ 6.0 ~ 2.0
** * *
"11.0 GEHL "* 4.0 "* 0.0 GEHL
~
I
"+
;5 ? "+
;5
"+
r - - - - '1/
9.0 2.0 l:il-<U::;::; I 5-2.0

I
« GROSS « «
v v v
;::; 7.0 ;::; 0.0 ANOR ~4.0 ANOR
+ ,--- MARG
+ +
+ + FAY + FAY
t3 5.0 ;:3-2.0 I ;:3-6 . 0 I

"
'---_ _ _ :11
FAY v v
v
AND I AND I
:3 3.0 AND :3-4.0
I
:3-8.0
I
(!) (!) (!)

5-6.0
II. 5-10.0
:l1 .0
-4.0 0.0 4.0 8.0 -10.0 -6.0 -2.0 2.0 -16.0 -12.0 -8.0 -4.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

Phase relations in the system HCI- H 20- AI 20 3 -CaO- FeO- (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limits: lime (a), ferrous oxide (b).
58
~ 2121.121 ~ 15.121 ~ 12.121

**
__ a~R~S~,1
* GROSS **
"*
"+ 18.121 0 / .. "";' 13.121 r- _a_G~O:_1 "";' 1121.13
J:
v
«
v
;:; 16.121
PREHN
I
/ J:
v
«
v
;:; 11.121
PREHN ./
/'
J:
v
«
v
;:; 8.13
PREHN ...,!
CLNZ /
LAWS LAWS /
«
u
+
+ j. SPAR «
u
+
+ -SPAR «
u
+
+
I<-SPAR

v 14.121 ~ 9.121 US ~ 6.121 ~US

«
v
US v v
(!)
GIBBS (!) KAOL (!) KAOL
o o o
-l 12.0 -l7 121 -l4 13
-3.121 1.121 5.121 9.121 '-3.121 1.121 5.13 9.13 '-3.13 I.e 5.13 9.9
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (ACK+)/A(H+))

.!
~ 2121.121 ~ 15.13 ~ 12.13
GROSS

_a:R:S~ /
* * **
"*
./
"";'* GROSS
";' 18.121
J:
v
>- -a~R;; -;- J:
v
13.121
.7- 0
"J:+
v
1121.121 >-
«
v
«
v . PREHN
- «
v
PREHN
/'
/
;:; 16.121 ;:; 11.121 ,/ ;:; 8.121 CLNZ /
+
+
LAWS ,{ SPAR +
+ LAWS-J -SPAR +
+ I MARG] • ,,-SPAR
« « «
u u r US u
~ 14.121 r US v 9.13 ~ 6.121 US
«
v
KAOL v KAOL v
(!)
o
(!)
o
(!)
o KAOL
-l 12 121 -l 7.121 -l 4.13
':3 • 121 1. 121 5 • 121 9 • 121 -3.121 I.e 5.13 9.13 -3.13 I.e 5.13 9.121
LOG (A(K+)/A(H+)) LOG CACK+)/ACH+))

I
LOG (ACK+)/ACH+))

7 1
~ 2121.121 ~ 15.13 ~ 12.121
GROSS
*
"*
*
"* GROSS ..
*
""+* GROSS
-a;R;H; -~;E~N -1- -
"+ 18.121 ";' 13.13 113.13
J: >- J: J:
v v
r- v -0-
« « «
v v v PREHN /
;:; 16.121 ;:; 11.121 ;:; 8.13
,/ ..9:J'!f
LAUMiT ~-SPAR
+ ,/ + + / K-SPAR
«
+ 1 -SPA~
«
+ + MARG /
u
«
u u
~ 14.121 r~s ~ 9.121 r us ~ 6.121 US
v v
(!) KAOL (!) KAOL v
(!) KAOL
o o o
-l 12.121 -l7 13 -l 4.121
-3.121 1.121 5.121 9.121 '-3 .121 1 • 13 5. 121 9 .121 -3 • 121 1 .13 5.121 9. 121
LOG (A(K+)/A(H+)) LOG (ACK+)/ACH+)) LOG (ACK+)/A(H+))

1
~ 2121. 12Ir-~~-~~~........, ~ 15.13 ~ 12 .12Ir-~~-~~~----,
* GROSS
* *
"* "";'* GROSS .•
""+*
-1--
GROSS
~ 18.121 -0- _ _ _ 13.121 1121.13

-~;E~N
J: J:
v v
~ PREHN « r «
v v v
;:; 16.121 ;:; 11.121 ;:; 8.121 PREHN
+ + ,/ +
+ + r----j".~ ~-SPAR + ~........uo.~/
« « LAUM «
u u u MARG /
~ 14.121 v 9.13
«v
r USr. ~ 6.121
v v US
8 KAOL (!)
o
KAOL
8 PYROPH
-l 12. 01.......~~-...............~--' -l 7.121 -l4.121
-3.121 1.121 5.121 9.121 -3.121 1 • 13 5.121 9 . 13 -3.121 1.121 5.121 9 .121
LOG (A(K+)/A(H+)) LOG (A(K+)/ACH+)) LOG (ACK+)/ACH+))
Phase relations in the system HCl- H 20- (Ah03) -CaO- K20-Si0 2 in equilibrium with quartz.
Saturation limit: wollastonite (a).
 59
~

**
r.
r.
10.0

f- _O_G~S~ _I- ~

**
r.
10.0

>- _o_G~:-c1
~

**
r.
10.0
GROSS

-L
F-J CLNZ .
+ 8.0 ';' 8.0 ';' 8.0
I I
I
v CLNZ _/' v v -0-
«
«
v
«
v CLNZ ) v
7
t MARG
I
~ 6.0 ~ 6.0 ~ 6.0 ANOR
t
I
+ I-SPAI< + MARG + I

«+ «+ I -SPAR «+ -SPAf
u ~ US u u
~ 4.0 ~ 4.0 M~S~ v 4.0 Ml C
«
v PYROPH v
(!)
KYA v
(!)
SILL
(!)
o o o
...J 2.0 ...J 2.0 ...J 2.0
-4 . 0 0.0 4.0 8 .0 -4.0 0.0 4.0 8.0 -4.0 0.0 4.0 8.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))
~

**
r.
';' 8.0
I
10.0

f-
GROS%
r-~E~N_ - -0-
CLNZ ;
~

**
r.
';' 8.0
I
10.0

~f-,=N!:.
GRO~:i
- I -0-
~

**
r.
';' 8.0
I
10.0

GROSS I
t
v v v
« / « « -0-
v
~ 6.0
MARG / v
~ 6.0 ANOR I v
~ 6.0 ANOR
+ 1 -SPAR + / + SPAR
«+ «+ -SPAI< «+
u ~ US u
M~~ C
u
~ 4.0 ~ 4.0 ~ 4.0 Ml JjC
PYROPH v AND v
v
(!) (!) (!) SILL
o o o
...J 2.0 ...J 2.0 ...J 2.0
-4.0 0 .0 4. 0 8. 0 -4.0 0.0 4.0 8 .0 -4.0 0. 0 4. 0 8. 0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))
~

r.
**
10.0

t=t: P~E~N _
GROS:!
~
**
r.
8.0
GROSS L ~

**
r.
7.0

,-0
r. r.
';' 5.0
GROSS /
+ 8.0 -0- + 6.0
I I
v
/ -0- I
v
v _N
« I « ANOR «
v
v ANOR v
~ 6.0
+ MARG ,~ -SPAR ~ 4.0
+
~ 3.0
+
ANOR
+ -SPAR
+
« « «+
u ~ US u M C u
~ 4.0 ~ 2.0 ~ 1.0 iJ<-SPAR
v
(!) AND v
(!)
AND v
(!)
AND
o o o
...J 2.0 ...J 0.0 ...J- 1 • 0
-4.0 0.0 4.0 8.0 -4.0 0.0 4 .0 8.0 -4. 0 0.0 4 .0 8.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))
~ 10.0 ~ 3.0 ~ 0.0
**
r.
r.
+ 8.0
GROSS_
L **
r.
';' 1.0
GROSS_Z

/-0- -
A
r.
**
+-2.0 GROSS_I

Z-
I I
t:P~E~N -
I
v r- -0- v v
« I- , «
v ANOR «
v
v t-
0- -
~ 6.0 CLNZ:J~ ~1.0 ~4.0
+
ANOR
+ ANOR + K-SPAR
+
« I-SPAR «+ «+ K-SPAR
u u MI ~C u
~ 4.0 MARG ~
~~C ~3.0 ~6.0
v v AND v AND
(!) (!) (!)
o AND o o
...J 2.0 ...J- 5 .0 ...J- 8 .0
-4.0 0.0 4.0 8_0 -4.0 0.0 4.0 8.0 -4.0 0.0 4.0 8.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))

Phase relations in the system HCI-H20-(AI203)-CaO-K20-Si02 in equilibrium with quartz.

Saturation limit: wollastonite (a).
60

/
22.0 ~ 16.0r-~~~~~~~

~20.0
~
* GEHLi * GEHL
"';'* "';'*
GROSS
19.0 ';' 17.0 13.0
J: J: J:
v
00( ~ GROSS
v
00(
GROSS
v v v
;::; 16.0 LAWS/ ;::; 14.0 ;::; 10.0~-----/~'
+ KALS t CLNZ
+
00(
u
v 13.0 MUSC
~ 11.01 LAWS j/ KALS j
~ 7.0
MARGj KALS
00( aTZ
v
(!)
o ~ ~[MUSC v
(!)
o
KAOL US
...J 8.0 ...J 4.0
...J 10_'30. '"
'" 3 . '"
'" 9.0 15.0 -3.0 3.0 9.0 15.0 -3.0 3.0 9.0 15.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

/
~ 22.0 ~ 20 . 0 .......~~=:-:r~~....-, ~ 16.0~~~~~~~~

* GROSS
** * GEHL
"';'* 19.0
"';' 17.0
"';'* 13.0r---------~/
J:
v
00( PREy
3
00(
GROSS J:
v
00(
v KALS v v
;::; 16.0 LAWS ;::; 14.0 ;::; 10 • 010-......,..".-
+
+ MUSC
t KALS +
00(
u
00(
u
~ MARG KALS
~ 13.0 KAOL vl1.0
00(
~
00(
7.0
v v v
(!) (!) (!)
o o o
...J 10.0 ...J 8.0 ...J 4. 0 L-~-L..._.J......~~.........J
-3. 0 3. 0 9.0 15 .0 -3.0 3.0 9.0 15.0 -3.0 3.0 9.0 15.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
22.0 16. 0,...~~~~~~..,......,

_I
~ ~ 20. 0 .......~~-G~E-H~L~~..---, ~

* GROSS * *
"';'* "';'*
~ GEHL
19.0 17.0 ';' 13.0
J: J: J: ~--------~'
GROSS
PREH~ KALS
v v
v
00( 00(
v j GROSS
;::; 16.0 ;::; 14.0 ;::; 10. 0t='7=~===1
+
+ tfLAWS MUSC
t ~------~ KALS + .l<..CLNj'
00( 00( ~ KALS
u u
~ 13.0 KAOL ~ 11.0 ~ 7.0 MARG
00(
v v
(!) (!) ~ USC
o o o
...J 10"':30.", 3.'" ...J 8.0 ...J 4.0
'" '" 9.0 15.0 -3.0 3.0 9.0 15.0 -3. 0 3 .0 9. 0 15.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

I
~ 22.0 ~ 20 .0r-~~~~~~........., ~ 16.0r-~~~~~~~

* GROSS * GEHL
*
"';'* 19.0
"';'* 17.0 "';'* 13.0 GEHL

v
J: ! J: J:
v GROSS v
00(
v PRE~ KALS 00(
v
00(
v GROSS
;::; 16.0 ;::; 14.0 ;::; 10.0f-_ __
+
+
00( MUSC
t
00(
1----7; +
+
00(
u u MARG KALS
~ 13.0 KAOL ~ 11.0
00( ~ 7.0
v v v
(!)
o
(!)
o 8 AOL usc
...J 10.0 ...J 8.0 ...J 4.0
-3.0 3.0 9.0 15.0 -3. 0 3.0 9.0 15 . 0 -3.0 3.0 9.0 15.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
Phase relations in the system HCl-H20-AI203-CaO-K20-(Si02) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature.
 61

/
c;J 14.0 c;J 11.0 c;J 11.0
*
"* 12.0
GEHL
/ *
"*
GEHL
/ *
"';'* 9.0
GEHL
"+
1 ';' 9.0 GROSS /
r
I
~ 10.0 GROSS ..
I
v v GROSS /
« «
v
CLNZ I «
v
v ,,~''''. I CLNZ /
~ 8.0 ~ 7.0 KALS ~ 7.0
+ MARG KALS + MARG / + ANOR / KALS
t3+ 6.0 «+ «+
u
~USC
u
v ~ 5.0 v 5.0
KYA ~ US « SILL MU~ C
:3
(!)
4.0 KYA v
(!)
v
(!)
o o o
3.0 ....J
....J 2 0 ....J
3 ._04 . 0 4 .0 12 . 0
~4.0 4.0 12.0 -4.0 4.0 12.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
c;J c;J c;J

/
11.0 11.0

/
14.0
* GEHL * GEHL *
"*
"+
12.0
/ "* "* GEHL

~ 10.0 GROSS /
';' 9.0
I
v
GROSS
CLNZ
/ ';' 9.0
I
v
GROSS
« « I « I

I'
v v v .NL I
[CLNZ /
~ 8.0
+
+ MARG
/ KALS
~ 7.0
+
«+
MARG KALS
~ 7.0
+
«+
ANOR I KALS
t3 6.0 u /
v ~USC v
«
5.0 ~ 5.0
:3 4.0
(!)
KYA v
(!)
AND f" US v
(!)
SILL Mp~C
o o o
....J 2 0 ....J 3.0 ....J 3.0
~4.0 4.0 12.0 -4.0 4.0 12.0 -4.0 4.0 12.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
c;J c;J c;J
/
14.0 9.0 7.0
* * GEHL * GEHL /
"* GEHL
""+* 7.0 '"*
/
12.0 rGROSS
"+ GROSS / ';' 5.0 ~ I

I
~ 10.0 I
v CLNZ I
v
«
v
GROSS ./ «
v I KALS «
v
ANOR
~ 8.0
+
+
('36.0
MARG /1 KALS ~ 5.0
+
«+
ANOR / ~ 3.0
+
«+ / KALS
u u
v
~US ~ 3.0 MU* ~ 1.0 Ml C
:3 4.0
(!) AND v
(!)
AND v
(!)
AND
o o o
....J 2.0 ....J 1.0 ....J_ 1 0
-4.0 4.0 12.0 -4.0 4.0 12.0 ~4.0 4.0 12.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
c;J 12.0 c;J 4.0 c;J
/
0.0
GEHL
*
"*
GEHL
/ *
"*
*
'"*
GEHL/

I
10.0
"+ GROSS /
';' 2.0
I
GROSS / ~2.0 [GROSS ,
L CLNZ
I
~ 8.0
I
v v
« « «
v
~ 6.0
+
MARG /1 KALS v
~ 0.0
+
ANOR
/ KALS
v
~4.0
+
ANOR KAlS

«+
+
('34.0 «+
US u u
v ~2.0 MJ~C
~6.0
:3 2.0 AND v AND v K- AR
(!) (!) (!) AND
o o o
....J 0 0 ....J_ 4 0 ....J- 8 .0
~4.0 4.0 12.0 ~4.0 4.0 12.0 -4.0 4.0 12.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

Phase relations in the system HCl-H20-Ah03-CaO-K20-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature.
62
~ 213.13 I @ 15.0 \

: r-" ~ **
7
IGROSS / "c \ GROl
~", J,.. '.La _ r. ' I
r.
" \ b
" \
r\ \.
':;.' 13.0 ':;.' 10.0
':;.' 18.13
~ PREHN'\ I
:I:
v
<t:
- 0 - ---...\-~- - J:
v
<t:
--"
PREHN
-0

~ "-L v PREHN "\I.f, v

14-t CLNZ
~ 16.13 LAWS ~"-fI4-A :::- 11.0
+ LAWS "CL
~ 8.0
+
t +
",
1\ "CL +
<t: <t: <t:
~ 14.13 6\ 'c,
U
v
<t:
v
9.0
KAOL
I \
I ~\
U
~ 6.0
v KAOL 'd
~ GIBBS: \ I (!)
\
(!)
\
5 12.9.13
eL--~~---""""'~....J
11.13 13.13 .15.13
57.0
4.0 6.0 8.0 10.0
54.0
2.0 4.0 6.0 8.0
LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2)

@2e.0 @ 15.0 @ 12. 0rc-~--r:-......-y~~--n

"c \
bl
-'-7.-
IGROSS
** , \ I ~/ ** ",,-
c, , , \
\ pROSS
**
----., TlO
r. r. r.
I
':;.' 18.0 ':;.' 13.0 ':;.' 10.0
:I:
v
c- -PREHN"
-" I
J:
v
J:
v
<t: <t: PREHN ,,~ <t:
v \)" v
~ 14-;-/
v
~ 16.0
+ LAWS ~ I~~~ ~ 11.0
+ ~LAWS ~L ~ 8. 0 1=1-:;:;::::::;:==1
+
<t: , +
<t:
I
I \ '
+
<t:

6 'cJ
U U U
~ 14.0 ~ 9.0 ~ 6.0
KAOL
I ~ 'd
v KAOL I v v KAOL
\ I \ \
(!) I (!)
\ (!)

5 12 13 .~.
1 1 .0 13 . 0 15 . 0
.\
57.0
4.0 6.0 8.0 10.0
5 4. 02.0
"::-~~::-,,-::,,,,,,:".......-:-,
4.0 6.0 8.0
LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2)

~ 213.0 " ~ 15.0

**
""
**
\
\ IGROSS
r. r. C' , d bI ./ r.
r. \
':;.' 18.0 + 13.0 ':;.' 10.0
:I:
v
J:
v
0- - __L L./ ; - J:
v
<t: <t: PREHN '\ I <t:
v v v
~ 16.13 ~ 11.0 \~ 14- ~ 8.0 t--rr1\l7--r;
t P=1:=====r'f'( +
+ CLAUM
CL
"- , +
+ MARG
<t: <t: I \
<t:
u U I U
v 14.13 ~ 9.0 ~ 6.0
I \
<t:
v
KAOL b v KAOL I \
v
KAOL
d
(!) I \
5 12. e'--~~~-..o.J.-...o>..---'
(!)
\ (!)

57.0 5 4. 0 '--~~~~~........-'

i'
9.0 11.0 13.0 15.0 4.0 6.0 8.0 10.0 2.0 4.0 6.0 8.0
LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2)
@20.0 I @ 15.0 r.
\ N \
** "c, ij
I GROSS
: 11.1
r.
" ? / r.
\i
l§ ", \
r.

~
18.01- -
" ' \ \i.'
PREHN
-.~\ '1 -0 - ':;.' 13.0
J:
v
<t: 0- - ~-'t-
\ +
39.3
<t:
\

v PREHN \1 v F-~.....-v"'t"'., -0-

~ 16.0 ~ "~4-A :::- 11.0
+
I" 14-,6 "':;.' 7.6 PREHN,
14-A
~ , ~L +
11\ " ~L, + " CL
" ,c,
<t: r-tLAUM <t:
~ 14.0 6\ ' U
~ 9.0 I \
U
~ 5.8
MARG
r----'; \
\
v KAOL I d v KAOL I \
v
PYROPH \
I -\ (!)
\
5 12. 0'---~~~'--~--,
(!) (!)

57.0 54.0
9.0 11.0 13.0 15.0 4.0 6.0 8.0 10.0 2.0 4.0 6.0 8.0
LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2)

Phase relations in the system HCI-H 20-(AI 20 3)-CaO-MgO-Si02 in equilibrium with

quartz. Saturation limits: wollastonite (a), talc (b), diopside (c), tremolite (d).
 63
" 11.0 ~ 11.0 ~ I I. 0.--.......---~~--71
N
* ** * I
"*
"+ 9.0
A

';.' 9.0
,, GROSS:
\ b
I
~
';.' 9.0
b;ROS~
~
I I \ I \
v v v
/ , \ I
«
v
;::; 7.0
CLNZ
14-A
CL
«
v
;::; 7.0
--""-
CLNZ ~~i 4-A
-0-
C
«
v
;::; 7.0
+ 'C , + +
+ + +
« \ « \' , «
u u u
v 5.0 5.0
v
«
5.0
PYROPH 'd «
v KYA
\ C,
,
v
«
v SILL
(!) (!)
d (!)
o 53.0
3 . 01 . 0 53.0
-.J 3.0 5.0 7.0 1.0 3.0 5.0 7.0 1.0 3.0 5.0 7.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

~ 11.0 ~ , I . 0r----rc~-~~--71 ~ , I . 0r--.....-~-~~--'71

** *
**
I \
I' ',GRdsS
, '
I / ~ G~OSS I
-
A
G~OSSI
-O-,--,~!
A

I
+ 9.0 ~9.0 " \ b ';.' 9.0
I \a bI
f
v v v
« « , \ I «
v CLNZ 14-A v --'>.- v
;::; 7.0 CL ;; 7.0 ;; 7.13
+
+
MARG ~ , +
ANOR 1~4-A C +
« \ C, + +
« f---- ,
«
u u u
5.0 \ c, 5.13
v
« PYROPH 'd ~ 5.0 v
«
\ AND v
'c ,
(!) 'd '
--"
(!) (!)

53.0 53.0 53.13

1.0 3.0 5.0 7.0 1.0 3.0 5.0 7.0 1.13 3.13 5.13 7.13
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
~ I I . 0r----.--.;~--~-~71 ~ 10.0 ~ 7.0
** ** *
';.' 9.0 "I"+ 8.0
GRdSS "';.'* 5.0
, ,d\ b
I I
v v
« v
« I «

"
v

A~o;1:~:~
v v
;::; 7.0 ;::; 6.0 - \J -0 - - ;::; 3.0
+ +
~I
+ + +
« CL +
<5 MARG u ANOR 4-A «
,
u
~ 5.0 ~ 4.0
, v 1.0 COR9 \ 'c
« ~
(!)
AND
(!)
C , v
(!)
AND I \
53.0 52.0 3-1.13
1.0 3.0 5.0 7.0 0.0 2.0 4.0 6.0 -3.13 -1.0 1.0 3.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
~ 10. 0r--.......,.....-~~-.,.......,,.., ~ 4.13 ~ 13.13
* I * ** ,,
I
~ ' , \ GR~SS "';.'* 2.13
GR'oSS
6
A

+ 8.0 ~2.a 'd

C,
I

~ f=P~...l
J: J: \
v v
« «
v v -0-
;::; 6.0 f.:CLNZ ;; 0.0 CL ~4.a
t ANOR + + 14-A

<5 t MARG «+ +
« CL
u u
~ 4.0 ::t2. a ~6.a
v AND «
v
(!)
AND AND
(!) (!)
52.0 3-4.13 3-8.13
0.0 2.0 4.0 6.0 -8 . a -5. a -2 . a , .a - , 2. a -, a . a -8. 0 -6. a
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

Phase relations in the system HCl-H 20-(AI 20 3)-CaO-MgO-Si0 2 in equilibrium with

quartz. Saturation limits: wollastonite (a), talc (b), diopside (c), tremolite (d).
64
:\120.0

,..,**
'.;' 18.0
J:
v
,
,
b\
',\ 1
\.
I
1 GROSS
~ - o-_:L
7
:\1'5.0

v
**
""J:+ 13.0
'
, , 'i
~
\ I
1 GROSS

- "-\-1- - 0-
~ 12.0
*
"'.;'*
J:
10.0
'c
" \ 1
- -0- "\1 -
\ ;GR07-
-
-<
v
PREHN ~, -<
v PREH~\I /. v
PREHN '\~ I
~ 16.0
~'c, ~ ~ 11.0 7-A ~ 8.0 CLNZ ~ ,,7C~
,
+
+
LAWS
1\ ct +
+
LAWS , \ " CL
, +
+ 1\ ,,
-<
U
~ 14.0 1 ' , -<
U
~ 9.0 KAOl
1\ C,
,
-<
U
~ 6.0 KAOL
I
bI
v GIBBS bI
\
\
v
I
b, \ v d \
<!) <.!)
\ <.!) 1
g 12.0
g.0 11.0 13.0 15.0
g 7.05.0 7.0 9.0 11.0
:J 4.02.0 4.0 6.0 8.0
-.l

LOG <ACMG++)/CA<H+»**2) lOG (A(MG++)/(A(H+»**2) lOG (A(MG++)/(A(H+»**2)

:\120.0 :\I 15. 0r-~....-~~~--' ~ 12.0
,
--'\-: -0-;
'c, 'c! * \ I

<
* :GROSS " b' GROSS *
"'.;'*
~ ,a "'.;'* 'c ' \ \ GRO~4
~ 13.0 ~E: Y,°A-
18.0 ~ 10.0 1
J: J: t::.--~-=- 0
v
\l,
v
7
j'
-<
v PREHN -<
v
PREHN ~
~ 16.0
+ LAWS ~ 'I, ~ 11.0 ~ ci ~ 8.0
+
ClNZ
r-
~y7-A
::::i ,Cl
+
t3t ,
+ [MARG 1 \ ,
-< , \ t7-~
LAWS 1
1\ 'c -<
b, d
U U
~ 14.0
KAOL ~ \ CL -< 9 •0
v
1
" ~ 6.0
v v KAOl 1 \ v KAOl

\
\
<!) 1 1
~h.0
<.!)

g 12.0
g.0 11.0 13.0 15.0
~
li.0 7.09.011.0
:J 4.02.0 ".0 6.0 8.0

G//
lOG CACHG++)/CA(H+»**2) LOG (A(MG++)/(A(H+»**2) LOG <A(MG++)/CACH+»**2l
:\120.0 :\1'5.0 c:;,j12.0
I' ,
,
GRO~y
\
* * *
""*+ ""*+ 13.0
1-%_ "'+* 10.0 ,C, \
, \ 1
~bRO~L
" I , \ 1 \
18.0 -~-1-0- -
J: ,\1 J: - _,L J:

I -0
v v v
-< -< -<
v PREHN \l, v PREHN \ 1 v PREHN '\ 1
~ 16.0 l C
,
7-A
CL
~ 11.0 'I' 7-A ~8.0 ClNZ
7-A
+ + , Cl + ~-". CL
+
-< LAUMJ I \ " +
-< LAUM::j ~ " +
-<
MARG J.\/ ,
,,
d ,
,
U
~ 14.0 1 U
~ 9.0 ~ C, U
~6.0 1
v
<!)
KAOL
I
b,
\
v KAOl
1
\ v KAOL 1 tJ
\
h
<!)
\ <!) 1
g 12.0
10.0 12.0 '''.0 16.0
g 7.05.0 7.0 9.0 11.0 :J ".02.0 \
".0 6.0 8.0
lOG CA(MG++)/(A(H+»**2) lOG (A(MG++)/(A(H+»**2) LOG CACMG++)/CACH+»**2)
:\120.0 :\1'5.0 :\I12.0r-,\-~"'-~--...
l l , l 'd,
fe. f··· . . '~,. .\..-T="'"9~-.:
.
GROSS

~ 13 .• - ____\:-0 -/- -
~ 16.0 ~ 11.0 PREHN \1, / 7-A ~ 8.0 PREHN '\

!u , .. 0 !e 9 0 LAUM] 1 \ 'f, CL
'c
!
U
~ • -< • I , ~ 6.0
v v KAOL b \ v
<!) <!) I \ <!) YROPH
g 12.0
10.0 12.0 '''.0 16.0
g 7.ali.0 7.0 9.0 11.0
g ".02.0 ".0 6.0 8.0
lOG <ACHG++)/CACH+»**2) lOG CACMG++)/CACH+»**2) lOG <A<HG++)/CACH+»**2)
Phase relations in the system HCI- H 20 - (Ah03) - CaO - MgO - Si0 2 in equilibrium with
quartz. Metastable 7-A c1inochlore was considered instead of its stable counterpart, 14-A c1ino-
chlore. Saturation limits: wollastonite (a), talc (b), diopside (c), tremolite (d).
 65

\ '"7
~ 1 1 . 0...-~-..,:--~~~--, ~ 11.0 ~ 11 . 0r-"'-~~-~~--'

J..* ~\ bI * ,...** \ GROSS

,...
+ 9.0
"
C, "'.;.'* 9.0 ,C, tJ I
b '.;.' 9.0
J:
v -o-~..l.!....-- J:
v
I I J:
v
c( « --' ....\-.!_-o- c(

7
v v v
CLNZ
;:; 7.0 ;:; 7.0 CLNZ'\ 7-A ;:; 7.0
+ + ~ CL + CLNZ~
+
c(
u
+
c(
u
MA~r. II
"- ,, +
c(
u
ANOR
~
v
(!)
5.0 PYROPH ~
v
(!)
5.0
KYA
1
1 \
, ~
v
(!)
5.0
SILL
:]3.0
I \ :]3.0
:]3.0
1.0 3.0 5.0 7.0 1.0 3.0 5.0 7.0 1.0 3.0 5.0 7.0
LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+» ••2)
~ 1 1 . 0...---"'r-~-~----' ~ 11 . 0r---.-~--~~--.
:
"
'\
'd
1 GROSS
I
l \ : GROSS GROSS
'.;.' 9.0 C, b '.;.'9.0' 'd
b
I

~
c(
-0- _'.1 ~ - - J:
•
'\
" \ I
b
I
v CLNZ v - - ..... --0-
;:; 7.0
+ MARG ~ 7.0 CLNZj-Ti 7-A
+ ~ ANOR:£ CL
q'
c(
u u ,
~5.0 ~ 5.0
v PYROPH v D C,
(!) (!) (!) SILL AND
:]3.0 :]3.0 :]3.0
1.0 3.0 5.0 7.0 1.0 3.0 5.0 7.0 1.0 3.0 5.0 7.0
LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2)
~

~
1 I . 0~..........~-~~~---,

d: GROSS
~

* ,
10. 0""--~-~-~--n ~

,...**
7.0

tJ b
1 GROSS
,...*
C, ,
'.;.' 9.0 ' \ b + 8.0 tJ ,... , I
+ 5.0
~ PRrHtJ';
I
v b I
v
I

~ t- - -'- - - 0- « , \ I «v -0-

,I
v
;:; 7.0 ;:; 6.0 _'\J --0- ;:; 3.0 7-A
+ ANOR + + CL
+ + !7-A CL
«
u
~ 5.0
MARG «
U
~
ANOR ~,
4.0 !---:lI<)('
u
~
+
c(

1.0
,,
v D' v
AND C, AND
(!) (!) AND (!)
:l 3.0
1.0 3.0 5.0 7.0
:l2.0
0.0 2.0 4.0 6.0
3-1 .0
-3.0 -1.0 1.0 3.0
LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2)

,, '"7
~ 10. 0~.......,:--,,-~-~--, ~ 4.0 ~ 0.0 \
= * *
,. . ',d, b
1 GROSS
,...
,...* ,...
,...* ,, d
\
I
b
~ 8.0 PREHN' I I
+ 2.0 ..... 2.0
J: c, I
~ ~-
v v
- '>.... --' - - 0-
7 7-A
c( c( \ 1
v v v
;:;6.0 tCLNZ 7-A ;:; 0.0 0-
~4.0 ,\ 1
! ANOR CL +
+
+
+ ANOR ~ CL
« « «
u
~ 4.0
u
~2.0
u
~6.0
I' ,,
(!) AND
v
AND
v
AND
?~~
3-4 . 0 .1 1\
(!) (!)

:l2.0
0.0 2.0 4.0 6.0 -7.0
'---",,---~__...L....>~.....J
-5 . 0 -3. 0 - I.0
3-8.0
-12.0 -10.0 -8.0 -6.0
LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2)
Phase relations in the system HCl- H 20- (AI 20 3) -CaO- MgO-Si0 2 in equilibrium with
quartz. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A clino-
chlore. Saturation limits: wollastonite (a), talc (b), diopside (c), tremolite (d).
66
~ 24. 0r--~-~-~---' ~ 22. 0 r--~-~-r--r---' ~ 19. 0r--~-~-~--:n
* * GEHL 1 : - - _1- boO
* GROSS '"'* I" I
GEHL:;/1
':;' 20.0 ~ 18.(3 I [ ':;' 15.0
J: J:

~
v v
« GR0j{SI «
v v
LAWS GROSS}
;::; 16.0 ;::; 14.0 14-A CL ;::; 11.0
+ + 1 + CLNZ 1 14-A CL
+ +
«
u ~ LAWS/ «
u MARG / 1 FORST
~ 12.0 v 10.0 v 7.0 I 4-
« c(
aI
v v v
OTZ KAOL
(!) (!) (!)

38.0 36.0 33.0

8 .0 12 . 0 16 . 0 20 . 0 5.0 9.0 13.0 17.0 2.0 6.0 10.0 14.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
~ 24. 0r--~-~-....,...---' @ 22.0 ~ 19.0
* * * b- - _1 _ _

'"'':;'* 20.0
GROSS
'"'':;'* *
'"' GEHL 1
18.0 ':;' 15.0 1
J: J: J:
v v
« ~ GROSS c(
v v v GROSS
;::; 16.0 LAWS ;::; 14.0 1 ;::; 11.0
+ 1----,' + 1'4-A CL
L-_--' + 114-A CL
+ + +
« (J LAWS I c(
MARG 1 FORST
u
v 12.0 ~ 10.0
a u
v 7.0 I L..-
« I c(
a
v v KAOL v
KAOL
KAOL I
(!)
3 6 .0
(!) (!)

38.0 '---........,~-L--~~---' 33.0

8 .0 12 . 0 16 . 0 20 . 0 5.0 9.0 13.0 17.0 2.0 6.0 10.0 14.0

I
LOG CA(MG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CA(MG++)/CACH+)) •• 2)
@24.0 ~ 22.0 ~ 19.0r--~--~~-,

* ~---I-b-~
Y
: GEHLI :
'"'':;'* 20.0 GROSS '"'
':;' 18.0
1
1 ~ 15.0 GEHL;
J: a
v
c(
v PREHN / I ~
v
GROSj{
1
;::; 16.0 14 J A CL g,I.0 GROSSI FORS
+ 1
~ 14.0 1 14-A CL + I
+
c(
1
~ PREHtf I + CLNZJI C
u
~ 12.0 T C
1 ~ 10.0 ? ~ 7 0 ~ARG 1 '1,4 - A
----I
CL
KAOL c( •
v v KAOL
1 v KAOL 1
§ 3.02.0
(!) (!)

38.0
I 3 6 .0 '--~'---~~~---' I.
8. 0 12. 0 16 . 0 20. 0 :;.0 9.0 13.0 17.0 6.0 10.0 14.0

I
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
@24.0 @ 22 . 0r---~-~--..,,........, @ 19. 0r--~--~----,
* : GEHL 1 *
'"'':;'* 20.0 GROSS '"'
':;' 18.01-----,-(
1
~
':;' 15.0 GEHL
-b-r---
I
J:
v a J:
v ;5 C
~ « «

I:
c(
GROSS { I
v PREHN / v v
~ 16.0 14 A CL ;::; 14.0 ;::; 11.0 GROSS
14-A CL FOR T
+
+ 1 +
+ PREH t 1
c(
u 1 c(
u
I
(J HARG 114-A CL
v 12.0 TI C 1 ~ 10.0
aI ~ 7.0 1
c(
v KAOL v AOL v
1
(!) (!) AO
3 6. 0
(!)

38.0
J '--..........~-'-~~---' 33.0
8 .0 12 . 0 16 . 0 20 . 0 :;.0 9.0 13.0 17.0 2.0 6.0 10.0 14.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

Phase relations in the system HCI-H20-AIP3-CaO-MgO-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limits: brucite (a), lime (b), spinel (c).
 67
~ 14.0 ~ 14.0 ~ 14.0
I
* ** **
~ 12.0 ~ 12.0 ~ 12.0 GEHLrb~
"+
:I:'
'" 10.0 GROSS 1 +
310.0
+
310.0 C
I

'f'
c( c( c(
v v v
;:; 8.0 'I FO ;:; 8.0 CLNZ FORS ;:; 8.0 FORST
MARG + + CLNZ A
+ + MARG +
+ lr-A CL ANOR
~6.0 ~ 6.0 ~ 6.0
v v v 114-
I ICL
j 4.0 KYA C j 4.0 KYA j 4.0 SILL I
I
(!) (!) (!)

g 2.00.0 4.0 8.0 12.0

g 2.00.0 4.0 8. 12.
0 0 g 2.00.0 4.0 8.0 12.
0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

~ 14.0 ~ 14.0 ~ 14. 01r-~--~~-"TT">

~
* 12.0 ~
* 12.0
*
~ 12.0
"+ "+ "+
310.0
c(
v
GROSS 7 310.0
c(
v GROSS
310.0
c(
v
;:; 8.0 CLNZ I~ T ;:; 8.0 ;:; 8.0
+ + MARG
+ CLNZJ1
+ MARG ~ + +
~ 6.0 ~ 6.0 ~6.0 ANOR II
v
4-A CL v v
j 4.0 KYA
I
j 4.0 j 4.0 lL
(!) (!)
AND (!) SILL C
g 2.00.0 4.0 8.0 12.0
g 2.00.0 4.0 8.0 12.0 g 2.00 • 0 4.0 8.0 12.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
~ 14. 0r-~~-~~~--" ~ 12. 0~~-:::!"-="'"=-=:-::lI= ~ 10. 0r--'~~~~~~---'
* * - b- -
**
-1- -
~ 12.0 GEHLI ~ 10.0 GEHLI
~
* 7.0
"+ C
+ I
GEHL
:I:
3 10 • 01-::-=-=-=-::-0; 38.0 v
c( c( t-~~;W c( [GROSS
v v v
;:; 8.0 ;:; 6.0 FORST ;:; 4.0
+ MARG + + ANOR
+ + +
~ 6.0 ~ 4.0 c(

v v
u
~ 1.0
j 4.0 AND j 2.0 AND v AND
(!)
g 2 .0
(!)
g 0. 0
(!)
~~_1-L~:-,":---Lo--' I-~_.J..L.~"""'_--' g..2. 0 ........--~...........~.......
0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0 -5.0 -2.0 1.0 4.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
~ 12.0 ~ 6.0 @3.0

~* 10.0 * *
GEHL I ---I--b_
"* 4.0
GEHL
"+
I
"+ "';* 0.0 GEHLI
I
38.0 :I:
32.0 v C
c(
v
c( c( I
v v
;:; 6.0 MARG ;:; 0.0 ~3.0
+ + + ANOR
+ + +
~ 4.0 ~2.0 c(
v v
u
AND AND <6.0
j 2.0 j..4.0 v
(!), (!)
g 0.0
(!)
g..6.0 g..9.0
-2.0 2.0 6.0 10.0 -10.0 -6.0 -2.0 2.0 -13.0 -10.0 -7.0 -4.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

Phase relations in the system HCI- H20 - Al 20 3 - CaO - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limits: brucite (a), lime (b), spinel (c).
68
;:;; 26. 0,........~~~-,--~r-<>--::-T'"~..., ;:;; 22. 0,........~~~~~.....--:,.--, ;:;; 19. 0,........~~~~~~....-,
I * : ---L-b-

GRos:t
: MO~TI GEHL
*

/1
GEHL I
9
A A
A
';:' 22.0 + 18.0 ~ 15.0 NTI
I I I

~
v v
..: ..: i---GR-O-SS-(f--'-'I
v v
A
;::; 18.0 1 L ;::; 14.0 ;::; 1 1 .0 1 FORST
+
+
AWS 1
+
+
..: CL t CLNZ ~
..: LAWS
u A~TIG u ~ MARG / l A CL
~ 14.0 T
C 1
~ 10.0 AN :j:G ~7.0 TL 1
v vAaL 1
v KAOL'"A C
(!) aT 1 (!) (!)
:l 10 • 0 '----'.L..I~~_'__~~'"--' :l 6. 0 L-o.~~~"""""'~------" :l3.0
1 1 .0 14 . 0 17 .0 20.0 1>.0 8.0 11.0 14.0 3.0 6.0 9.0 12.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
;:;; 26. 0,........~~~-...-,r-.-<>--.-..-, N 22 .0,........,~~~~~~.....--, ;:;; 19. 0,........~~~~~~....-,
: MO~TI ** GEHL : ----L-b-
A

~ 22.0 ~
GEHL
GROSS "+
I
18.0 ';:' 15.0
I

/~-A
v
~ GROSS ..:
v v v GROSS
;::; 18.0 I L ;::; 14.0 ;::; 11.0
+ + h='tror-71 + .......rrr-r--
+
..:
u ANUG u
+
..: LAWS
CL
~
+
MARG J. 7t A CL
~ 14.0 ~ 10.0 ~ 7.0 1
1 TA T 1 FOR,ST,
(!) (!) KAOL (!) KAOL '--<>-
:l 10 • 0 L......J...L..~.-....JL...o-...o-I.......... :l 6. 0 L...-..~........u"--'---,--~---, :l3.0
1 1 .0 14 • 0 17 . 0 20.0 1>.0 8.0 11.0 14.0 3.0 6.0 9.0 12.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

;:;; 26.0 .1. J ;:;; 22 • 0 o--~~~~-,-~-.-, N 19. 0r-~~~""""'~~""'--'

~ MO~~~ : GEHL 6 : - - -1- -b-
~ 22.0 ~
A I
"';:' I
GROSS ±
" 18.0 1 ~ON 15.0 GEHL ~ M TI

.: rI/!a
I
v
~ GROSS 1 ..:
v v
v
;::; 18.0 PREHN I 7-A ;::; 14.0 ;::; 11.0 GROSS
t
..: ~
1 CL ~ i-P-R-E-H-N-(1-/: 7~A CL +
+
..:
~ 14.0 T! r ANUG
II ANtIG u
..: r-- 1 ~ 10 . 0 TALC ~ 7.0
v
AO v KAOLY- ~ I T
(!) (!) (!) KAOL
:l 10 . 0 L-...........L...~~L.....--'--.........J :l 6. 0 L-...o~~"""""''"----'.~"""""", :l 3. 0 '---~"""""L...--L.....~~L-.J
1 1 .0 14.0 17 • 0 20 . 0 5.0 8.0 11.0 14.0 3.0 6.0 9.0 12.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
;:;; 26.0 ;:;; 22. 0 o--~~~~-,.-~-.--, N 19.0!r-~~~~~~~

* MONTI
: GEHL * 1
"*
'4>'-
1 ) "';:' ~ - - - I -b--
';:' 22.0 GROSS 18.0f-----,..,.,':. ';:' 15.0 GEHL 1
I I ON
v ;5 C
..:
v
I
7-A ~ GROSS} ..:
v
1
;::; 18.0 CL
f7~A ;::; 11.0 GROSS ('
1
+ PRE7 : ;::; 14.0 +
+
..: i-P-R-E-HN- 7~A CL +
..:
u
~ 14.0
v
T C
ANTIS
1 ~
v
10 . 0 T ALe
~WI
I ANiIG
u
~ 7.0
v
CL

AO
(!)
:l 10. 0'----'~.L....~.......---...L~..........
(!) KAOL 8..J 3. 0 AO
1 1 . 0 14 • 0 17 • 0 20 • 0 :l 6. \ L..0~~8~• ....lJ
0 0.L-.0- , - .0~'-'4 .0
, ....
'-::-'..........::-'-'"~~~""'O""---.J
3.0 6.0 9.0 12.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

Phase relations in the system HCl- H 20 - Al 20 3 -CaO - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A cIinochlore was considered instead of its stable counterpart, 14-A cIi-
nochlore. Saturation limits: brucite (a), lime (b), spinel (c).
 69
;:;:; 14. 0..-.~~~~~......,.,......., ;:;:; 14.0 ;:;:; 14.13
--b--t--
** GEHL C
I
** I
**
~ 12.0 I ~ 12.13 C ~ 12.13
+ + GEHL +
J: J: I J: GEHL ~
v v v
~ 10.0 GROSS ~ 113.13 ~ 113.13 I

"- ~~;-::;-- "- GROSS "-

"t 8.0
"t 8.13 CLNZ
"t 8.13
GROSS
« « « CLNZ
u u u
v MARG v
~ 6.0 ~ 6:13 « 6.13 ANOR
v v
T
KYA (!) KYA TA SILL T
3 4. 0
(!) (!)
'--'_.......L.<....J'-"-........~........... '" 34.13 34.13
2.0 5.0 8.0 11.", 13.13 3.13 6.13 9.13 13.13 3.13 6.13 9.13
LOG (A(MG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2)
;:;:; 14. 0""~~~~~~:r-1 ;:;:; 14.13 ;:;:; 13.13
---+-b- - - -'-b--
**
~ 12.0
GEHL
C
I
**
~ 12.13 GEHL
I
C
**
~ 11.13 GEHL C
I
+ I + I + I
J: J: J:
v v v
~ 10.0 GROSS ~ 113.13 ~ 9.13
~ p==;===t "- ~-------+~ "-
"t GROSS
"t 1--''''''''....,,''-.,'
t 8.0 ORS 8.13 7.13
CLNZ J
-A--+/r FORST
« « FORST
«
u u u ANOR
v v MARG v
~ 6.0 ~ 6.13 7-A ~ 5.13
CL SILL T
(!) KYA T
34.0 .........._----".J....o.L.~..........~...........
8 AND TA -'->-' (!) C
33.13
2.0 5.0 8.0 11.0 ...J 4. 1313 . 0 3 • 13 6 • 13 9 .0 13.13 3.13 6.13 9.13
LOG (A(MG++)/CACH+»**2) LOG (A(MG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2)
;:;:; 13. 0,...~~~r--~~y--, ~ 12. 0,...~----r,b--~-"'I~-~-~-' ;:;:; 10. 0,...~~~~........~---.,
: GEHL : - -b- _1- _
~ 11.0 t *
~ 10.13 GEHL ~ 8.0
I

± I +
J:
+
J:
GEHL C
I

~ 9. 0 GROSS I) v
~ 8.13
v
~ 6.0

17.0 MARG JI 7 - A ORS

,..
"-
t
«
6.13
GROSS

ANOR
,..
"-

«
t 4.0
ANOR
B 1 CL
ov o
v
~ 5.0 ~ 4.0 ~ 2.0
(!) AND T t: (!)
ANO ALC
L...,:.
I AND C
3 0.0
(!)

33.0 32.13 ........~~~.u....._......J

1.0 4.0 7.0 10.0 -2.0 1 . 13 4.0 7 .0 -~. 0 -2.0 1 .0 4 .0
LOG (A(MG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2)
;:;:; 12.0 ~ 6.0 ;:;:; 3.0
1 I 1
** GEHL 1 ** GEHL C
** 1.0 -b- -.- - -
~ 10.0 C ~ 4.0 I
~ C
+ + +
J: J: J:
v
GROSSi v v GEHL •
~ 8.0
I
~ 2.0 GROSS I ~1.0
"- ,..
"- CLNZ~JII ,..
"-
"t 6.0 MARG Y FORST t 0.13 ANOR V FORS:r t-3.0
« « « ANOR
o }7-A o o
v v v
~ 4.0 T tCL ~2.0 ~5.0
AND
AND 1 T C
(!) (!) (!) AND C
32.0 3-4.13 3-7.0
1.0 4.0 7.0 10.0 -8.0 -5.0 -2.0 1.0 -13.0 -10.0 -7.13 -4.0
LOG (A(MG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2) LOG (ACMG++)/(ACH+»**2)

Phase relations in the system HCl- H 20 - Ah03 - CaO - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A cli-
nochlore. Saturation limits: brucite (a), lime (b), spinel (c).
70
c::; 24.0 c::; 22 . 0'--~~-~-r"--"---' c::; 19.0r-~~--~~~

* * GEHL. I : - - _I-c-
"':;'* 20.0 GROSSt "* I
J:
"± 18.0 I
" 15.0
':;'
J:
GEHLI:Y1
v
~ v

I:
« GROSS (
v
/ I
~ GROSS ,{
~ 16.0
LAWS
I
14LA CL
~ 14.0 14-A CL ~ 11.0 I:
+
+
I t CLNZ 114-A CL
« I ~ LAWS/ I ~ MARG I I
u
~ 12.0
aTZ
HIC I ~
v
10.0 9 v
«
v
7.0
v KAOL
I (!)
g 6. 0
(!) (!)

g 8.08 . 0 12 . 0 16 . 0 20.0
I
5.0
L-~~-"-~~---'
9.0 13.0 17.0
g 3.02.0 6.0 10.0 14.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

c::; 24.0 c::; 22.0 c::; 19.0

___ Lc-
* * *
"':;'* 20.0 GROSS! "*
"+ 18.0
I
"*
':;' 15.0
GEHL ~
I
J:
?
J: J:
v ~ GROSS v
« PREHN / «v
v v GROSS
~ 16.0 LAWS / 14lA CL ~ 14.0 I ~ 11.0
114-A CL
+ I + I--~.....I + 114-A CL
«+ «+
+
I I « MARG I
u
~ 12.0
T C u aI u
~ 7.0
v KAOL
I ~ 10.0 KAOL v
I FORST
I KAOL I L-,...
g 6 .0
(!) (!) (!)

g 8.08 . 0 12 . 0 16 . 0 20 . 0
I
5.0
L------.1~_L_~~---I
9.0 13.0 17.0
g 3.02.0 6.0 10.0 l-t.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
c::; 24.0 c::; 22.0
* * GEHLI
""+* 20.0 GROSS! "*
':;' 18.0
I
J: J: I
v
«v PREHN / ? v
«
v
GROSS {
~ 16.0
+
+
14lA CL
I
~ 14.0
+ 1:14-A CL FOR
« I
+
« PREH~ I
114-A CL
u u aI
~ 12.0
v KAOL
T C
I
I
:3 10.0 KAOL
(!)
g 6. 0
(!)
g 8.08.0
(!)

12.0 16.0 20.0

I
5.0
L------.1~_L_~~__l
9.0 13.0 17.0
g 3.02.0 6.0 10.0 14.0

J
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
c::; 24.0 c::; 22 . 0.-~~-~~--.,,......., c::; 19.0
* * * I
"*
':;' 20.0
GROSS
"*
':;' 18.0~--~~' "* - - tC- -
GEHL

r
':;' 15.0 I
J: J: J:
v
«v
v
«v
v bI
PREHN / GROSS { «v
~ 16.0
+
+
14 A CL
I
~ 14.0
+
+ PREH
1:14-A CL
~ 11.0
+
+
« I « I «
u u aI u CL
~ 12.0
v KAOL
TI I
I
C
:3 10.0 KAOL ~ 7.0
v
(!) (!) (!) AO
g 8.0
.1
g 6.0 g 3.0 L-~L.....-L~~~.l-..J
8 .0 12 . 0 16 .0 20. 0 ~ •0 9 .0 13 • 0 17 • 0 2 .0 6 .0 10 . 0 14 .0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

Phase relations in the system HCI- H20- AI 20 3 -CaO- MgO- (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable chrysotile was considered instead of its stable counterpart, antigorite. Sa-
turation limits: brucite (a), spinel (b), lime (c).
 71
(\; 14.0 (\; 14.0 (\; 14.0
** 12.0 GEHL ** **
'" 12.0
'" '" 12.0
'"+ '"+ '"+
~ 10.0 GROSS, I ~ 10.0 ~ 10.0
« I «
v GROSS «
v
v
'I ORST ~ 8.0
~ 8.0 ~ 8.0
+ MARG + + CLNZ A
+ 1,4 - A + +
~ 6.0 ~ 6.0 ~ 6.0
ANOR' I
I CL
v v v
~ 4.0 KYA b
I
~ 4.0 ~ 4.0
SILL
~-
ICL
(!) (!) (!)

g 2.00.0 4.0 8.0 12.0

g 2.00.0 4.0 8.0 12.0
g 2.00.0 4.13 8.13 12.13
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
(\; 14.0 (\; 14.0 (\; I 4. er-~~-~~~'7'7"1
** 12.0 GEHL I * *
'" I -:.. 12.0 GEHLI ,..
-:.. 12.13
'"+ '"+ +
~ 10.0 ~ 10.0 ~ 10.0
«
v
«
v
«
v
~ 8.0
!.CLNZ ;:::; 8.0 FORST ~ 8.13
+ MARG + +
+ + + ANOR
~ 6.0 ~ 6.0 ~ 6.13
v v v
~ 4.0 KYA ~ 4.0 ~ 4.13
g 2. 0
(!) (!) (!)
g 2.00.0 4.13 8.13 12.0 13.0
",'~_...J....JL...---'_~-J
4.13 8.0 12.13
g2.e
13.13 4.13 8.13 12.13
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/(A(H+))**2)
(\; 14.0 (\; 12.0 (\; 10. e ......~~~~~~.....-,
**
'" 12.0 GEHLI
** : -C- - -1- -
'" 10.0 GEHLI ~ 8.13 GEHL I
'"+ I '"+ I +
~ 10.0 ~ 8.0 ~ 6.13
« « « t=GROSS I
v v v
~ 8.0 ~ 6.0 FORST ~ 4.13
+ MARG + ANOR + ANOR
+ + +
~ 6.0 ~ 4,0 ~ 2.13
v v v
~ 4.0 AND ~ 2.0 AND ~ 0.0 AND
(!) (!)
g 2.00.0
(!)

4.0 8.0 12.0

g 0.0-2 .0 2 .0 6.0 10 . 0
3-2. 13 L.....~~---o..IJ.....L~.....J
-~. 13 -2.0 1 .13 4. 0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG (A(MG++)/(ACH+))**2)
(\; 12.13 (\; 6.13 (\; 3.0

** 10.0
'"
GEH{:1Q~~
14- ** 4.13
,..
'"
GEHL ,..** ---'-C--

'"+ GEHL I
GROSS '/ + ';' 13.0 I

f
~ 8.0 ~ ;~.e J:
v b
« « «
v v tCLNZ v
~ 6.0 MARG FOR ~T ~ 13.13 ORS
ANOR ~3.e
+ I
+ + ANOR FORST
+ b +
«+
~ 4.0
'14 - A
tt 2 .0
v
I CL
v
AND ~6 . 13
«
~ 2.0 AND ~4.0 v AND C
I
(!) (!)
g 0.0
(!)
J
3-6.13 3-9.13
-2.0 2.13 6.0 I 0 •0 -113.13 -6.13 -2.0 2.13 - 13.13 -113.0 -7.13 -4.13
LOG CACM~)/CACH+))**2) LOG (A(MG++)/(A(H+))**2) LOG CACMG++)/CACH+))**2)

Phase relations in the system HCl-H 20-AI 20 3 -CaO-MgO-(Si0 2) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable chrysotile was considered instead of its stable counterpart, antigorite. Sa-
turation limits: brucite (a), spinel (b), lime (c).
72
~ 26.13 ~ 22. er-~~-~'--r--' ~ 19 .er-~~-~~~--n
** Mci~Bb * GEHL : b- __ L_
"r.*+
r. r. GEH~
~ 22.13
I
GRossl I
18.13 ~ 15.13
I
v v v
<C 17-A <C GROSSy <C I
v v v
I CL GROSS!
~ 18.13 TREM \..."l ~ 14.13 ~ 11.13
+ + ; ; 7-A CL +
+ "'- I + ? + CLNZ h~A CL
<C
U ~/ C~RYS <C
U
LAWS I <C
U MARG / 1
~ 14.13 a ~ 113.13 ~ 7.13
I
T v T CI
aTZTiA lC
ti
v v
(!) I (!) KAOL (!) KAOL
3113.13 3 6. 13 '--.o--I.-'L-.4.-~~""'" 33.13
2.13 6.13 113.13 14.13
8 • 13 1 2 • 13 1 6 • 13 213.13 ~.13 9.13 13.13 17.13
LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2)

A
~ 26.13 ~ 22 . er--~~-~~77---' ~ 19. 13r-~~-~~~----:;t
** MONT~
r. **
r. **
r.
r.
~ 22.13
I
GROSS ~ 18.13
I
+ 15.13
I
v 7-.A v GROSS I v
<C
v
I CL <C
v
<C
v
\.J..
71¥
~ 18.13 PREHN JREM ~ 14.13 ~ 11.13
+ + t--r.-,.",.,:n:ri 17-A CL + n"rl\lrr--{
+ LAWS I + +
«(
CHRYS
<C I <C CL
u U a
~ 14.13 ~ 113.13 I 87
<C •
13
KAOL T ~l C I T C1 T
v
aI v
KAOL
v
(!) (!) (!) KAOL
36.13 33·.13
3 113 '1.13 12.13 16.13 213.13 5.13 9.13 13.13 17.13 2.13 6.13 113.13 14.13
LOG (A(MG++)/(A(H+))**2) LOG (ACMG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2)

1
~ 26.13 ~ 22 .er-~~-~~~---' ~ 19.er---~-~-----,

* MONB(-/ : GEHLI : - - _I_ b _

"~* 22.13 GROSS "+
r.
18.13
I ~
± 15.13 GEHL
I
~
I I
v v v
<C <C <C
v -A v v
~ 18.13
+
PREHN / 6 )::L ~ 14.13
+ r---,· CL
~ 11.13
t f===~
+ / I +
«( <C I «( CL
u CHRY~ U a u
~ 14.13 ~ 113.13 I ~ 7.13
v KAOL T ~l C I v T C1
(!) I (!) KAOL ~ KAOr
o
Ie ,1.
13 1 2 • 13 1 6 . 13 213 . 13
3 6. 13 ~~~----'-~~--' 33.13
...J 5.13 9.13 13.13 17.13 2.13 6.13 113.13 14.13
LOG (A(MG++)/(A(H+))**2) LOG (ACMG++)/(A(H+))**2) LOG CACMG++)/(A(H+))**2)
~ 26.13 ~ 22 . er-~~-~~---;;"---' ~ 19. er-~~-~~~----,
* MON1;~ : GEHLI * I
"~* 22.13 {
r.
~ 18.131-----,"
I ~ - - I b- -
GROSS ~ 15.13 GEHL I
I
v j I
v (; C
<C I 7-A <C <C I
v v v
~ 18.13
+
+
PREHN /
/
? CL ~ 14.13
+
+
r----/ 17-A CL
~ 11.13
+
+
<C <C I <C
U
~ 14.13
v
CHRI(
KAO[T HC I ~le.e
v
T ? U
~ 7.13
v
I (!) KAOL
3 6. 13
(!)
o L-----.J~~~~--'
...J 113·1.13 12.13 16.13 213.0 5.13 9.13 13.13 17.13
LOG (ACMG++)/CACH+))**2) LOG (ACMG++)/(A(H+))**2)

Phase relations in the system HCl- H 20 - Al 20 3 - CaO - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore and chrysotile were considered instead of their stable coun-
terparts, 14-A clinochlore and antigorite. Saturation limits: brucite (a), lime (b), spinel (c).
 73
~ 14.a ~ 14.a ~ 14.a
**
r\ 12. a
**
~ 12.a
**
r\ 12. a
r\ r.
+ + +
;5 1a. a ;5 1a.a ;5 1a. a
<t <t <t
v v v
;:; 8.a ;:; 8.a FORST ;:; 8.a
MARG + + CLNZ
+ MARG
+ + + ANOR
;:"j 6.a ;:"j 6.a ;:"j 6.a
v v v
T T ;; 4.a C
;; 4.a KYA ;; 4. a
KYA SILt!
(!) (!) (!)

32.a 32.0 32.a

a.a 4.a 8.a 12.a 0.a 4.0 8.a 12.a 0.0 4.a 8.a 12.a
LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2) LOG CACMG++)/(A(H+))**2)

~ 14.a ~ 14.0 ~ 14.0

**
r\
r.
12.a **
r.
r.
12.0 GEHLI
*
* 12.0
r.
r.
+ + +
;5 1a.a ;5 1a.0 ;5 10.0 C
;; ~=GR=O=S=S.,J.,' <t I

'I
;; I==C="L=N='Z::=i9' v
;:; 8.a FORS ;:; 8.0
;:; 8 .0 FORST
+
+ MARG t
;:"j 6.0
MARG
~_ _{I 7C-LA
+
+ CLNZJt'
;:"j 6.a ;:"j 6.0 ANOR
v v I~ v
;; 4.a ;;4.0 T ;; 4.0 T C
(!)
AND SILL
(!) (!)

32.a 32.0 32.0

a.a 4.a 8.a 12.a a.a 4.0 8.0 12.a 0.0 4.0 8.0 12.0
LOG (A(MG++)/(A(H+))**2) LOG CA(MG++)/(A(H+))**2) LOG (A(MG++)/CA(H+))**2)
~ 14.a ~ 12.a ~ 10.0~~--~~~~~

** * : -b- - -1- -
r.
r.
12.a * 10.0
r.
r.
r.
+ + ';.' 7.0

I
;5la.a~--..,....( ;5 8.0 :x:
v r::GROSS
<t <t <t
v v v
;:; 8.a FORST ;:; 6.0 FORST ;:; 4.0
+ MARG + ANOR + ANOR
+ + +
;:"j 6.a ;:"j 4.a 7-A <t
U
v v CL
;; 4.a T ;; 2.0 TALC 1-1 ~ 1.0
v C
AND AND AND
(!) (!) (!)

32.a
a.a 4.a 8.a 12.a
3 a.a
-2. 0 2.0 6 .0 1a .0
3-2. 0 L.........~.........-...IL-~-.J
-s .0 -2. a 1 .0 4 .0
LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/CA(H+))**2)
~ 12. 0r-~~-O::-~"-7""""" ~ 6.0 ~ 3.0
* ** 4.0 ** - - - Lb--
:.. 10.0
r.
+
r.
r.
+
r.
';.' 0.0 GEHL d
;5 8.0 t - - - - - . " ;5 2.0 :x: I
v
<t
v
<t
v CLNZ ~ :1 <t
v
;:; 6.0 MARG ;:; 0.0 ANOR r FORST ;::-3.0
ANOR
+ + + FORST
+ + +
;:"j 4.0 ~2.0 <t
u
v
T
v T C ::(6.0
;; 2.0
AND ~4.0 AND v
AND
C
(!) (!)

3-6.0 3-9.0
- 10. 0 -6. a -2.0 2.0 -1 3 . a -1 a . 0 -7.0 -4 . a
LOG (A(MG++)/(ACH+))**2) LOG CACMG++)/CACH+))**2)

Phase relations in the system HCl-H 20-AI 20 3 -CaO-MgO-(Si0 2) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore and chrysotile were considered instead of their stable coun-
terparts, 14-A clinochlore and antigorite. Saturation limits: brucite (a), lime (b), spinel (c).
74
;::J 20,0 ;::J 16.0 ;::J 12.0
**
r.
GROSS
·0- -
*
*
r.
r. GROSS **
r. GROSS
':; 18.0 + 14.0 ':; 10.0
I I I - - - -0- -:7
v
« PREHN / v
« - - - - -O~/ v
« PREHN ./
.7
v v v
~ 16.0 ~ 12.0 ~ 8.0 CLNZ /
+ LAWS + PREHN , / +
+ + + ALB
« « LAWS ,../ ALB «
u
14.0
ALB u r--- u AR,G
v
« ~ 10.0 ~ 6.0
v P IF AG v !=tAR G v KAOL
(!)
GIBBS (!)
KAOL (!)
o o
...J 12 ...r. 0 6 .0 8.0 10 . 0 ...J 8 . 03 . 0 5.0 7.0 9.0
~ 4.0
1.0 3.0 5.0 7.0
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))
;::J 20.0 ;::J 16.0 ;::J 12.0
** GROSS **
r.
- - - - -0- -
**
r.
GROSS r. GROSS
':; 18.0 ':; 14.0 ':; 10.0
-

/
--/
/
I I I - -~-
v PREHN v v
«
v
~ 16.0
«
v
~ 12.0
«
v
~ 8.0
PREHN
CLNZ ,/'
/
+ LAWS / PREHN
+ + "MARGj..J
+
«
u ALB
+
« .....-. ALB
+
« ALB
u u
v 14.0 P ,~ AG ~ 10.0 FAR ~G ~ 6.0 AR G
«
v v v
KAOL KAOL KAOL
(!) (!) (!)
0--
12 '40. 0 6 .0 8 .0 10 . 0 ~ 8.0 ~ 4.0
...J 3.0 5.0 7.0 9.0 1.0 3.0 5.0 7.0
LOG (A(NA+)/A(H+)) LOG CACNA+)/A(H+)) LOG (A(NA+)/A(H+))
;::J 20.0 ;::J 16. 0r-~~-~~~--' ;::J 12.0
GROSS
**
r. **
r. GROSS
**
r. GROSS
':; 18.0
I
-----0-- "+ 14.0
r.
+ 10.0
I ,./'
v
« PREHN / ~ // v
« :-0
v
~ 16.0
+
~
':;
12.0 - -
PREHN
- -~-o
v
~ 8.0 L:LNL
PREHN
//
+ ./
+
« LAUMJ + + MARG / ALB
u
ALB ("j ,.-.-_ ALB «
u
~ 14.0 P ~AG ~ 10 . 0 FIA~ AG ~ 6.0 I ARI G
v
KAOL v
KAOL
v
KAOL
(!) (!) (!)

~ 12.0 ~ 8.0 ~ 4.0

4.0 6.0 8.0 10.0 3.0 5.0 7.0 9.0 1.03.05.07.0
LOG (ACNA+)/A(H+)) LOG CA(NA+)/ACH+)) LOG (A(NA+)/A(H+))
;::J 20.0 ;::J 16. 0r--~-~~~--, ;::J 12.0
GROSS
**
r. **
r.
GROSS
**
r.
GROSS
':; 18.0 - - - - -0-- ':; 14.0 ':; 10.0
I I I
v v

74-
v
« « «
v PREHN / v
~ 16.0
+
~12.0---V-
+ PREHN
-0 ~ 8.0
+
PREHN
«
+ I
.:t LAUM +
«
.N. /'
MARG / ALB
u
v
«
14.0 ALB ~ 10.0 ~ ALB u
~ 6.0
v ~ P R G v G
(!)
KAOL (!) KAOL (!)
PYROPHiR
o
...J 12 . ..r. 0 6 .0 8 .0 10 . 0 ~ 8.0
3.0 5.0 7.0 9.0
~ 4.0
1.0 3.0 5.0 7.0
LOG (A(NA+)/A(H+)) LOG CACNA+)/A(H+)) LOG (ACNA+)/ACH+))
Phase relations in the system HCl- H 20 - (Ah03) - CaO - Na20 - Si0 2 in equilibrium with
quartz. Saturation limit: wollastonite (a).
 75
;::J 10.0 ;::J 10.0 ;::J 10.0
** * *
"~* 8.0 "~* 8.0
GROSS /- GROSS GROSS
":c"+ 8.0
- - - - -0-

CLNZ
./II
:c
v
- - - - -a/ :c
v __ C~N~~_ 0.,/
v
;:::; 6.0
MAK~ /
<
v
;:::; 6.0
CLNZ
MA_Kl:I 7
/ <
v
;:::; 6.0 ANOR
/
+ ALB + ALB +
+ + +
< < < ALB
u I AR G u u
~ 4.0 ~ 4.0 P f~ AG ~ 4.0
v PYROPH v KYA v
SILL
(!) (!) (!)
o
....J 2.01 0 3.0 5.0 7.0
g 2.01.0 3.0 .5.0 7.0
g 2.01 . 0 3 . 0 5 . 0 7 . 0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
;::J 10.0 ;::J 10.0 ;::J 10.0
* * *
""+* 8.0 - - - - - 0 - "~* 8.0 "~* 8.0
GROSS /- GROSS
GROSS
:c
v
<
CLNZ
..- / :c
v
<
--~--a/ :c
v
< 4
/ /
v v v
MARG / ANOR
;:::; 6.0 ALB ;:::; 6.0 ;:::; 6.0 ANOR
+ + ALB +
+ + +
< < <
u fAR G u u ALB
~ 4.0 ~ 4.0 P~ AG ~ 4.0
v PYROPH v AND v
SILL
(!) (!) (!)
g 2.01.0 3.0 5.0 7.0
o
....J 2 . 01 . 0 3.0 5.0 7.0 g 2.01 . 0 3.0 5.0 7.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
;::J 10.0 ;::J 8.0 ;::J 6.0
.4-
;-a-
* GROSS * *
"* "~* 4.0
GROSS,~
"* GROSS
~ 8.0 _ ~R£Ht::!.-1_-;A ~ 6.0

/
:c :c
v
< <"L I v
< ANOR
v
< ANOR
v
AN OR / v v
;:::; 6.0 ;:::; 4.0 ;:::; 2.0
+ MARG / ALB + ALB +
+ + + ALB
<
u
< <
FjAf AG u u
~ 4.0 v 2.0 v 0.0
< AND < AND
v AND v v
(!) (!) (!)
o
....J 2 . 01 . 0 3.0 5.0 7.0
g 0.01.0 3.0 5.0 7.0 5-2 • 01 • 0 3.0 5.0 7.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
;::J 10.0 ;::J 4.0 ;::J 0.0
* * *

r::
"*
~ 8.0
GROSS
"~* 2.0 GROSS ""* GROSS

t
:c :c £2.0
v
<
v
_P~E~NJ:-~ v
<
v
v
<
v
;:::; 6.0 CLNZ"37 ;:::; 0.0 ~4.0
+ + ANOR + ANOR
+ ANOR, ALB + +
< < < ALB
u u u
~ 4.0 P ~~ AG <2.0 ALB <6.0
v v AND v AND
AND
(!) (!) (!)
o
....J 2 . 01 . 0 3.0 5.0 7.0 5-4'~1 .0 1.0 3.0 5.0 5-8.0 0
-1. 1.03.05.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
Phase relations in the system HCI-H20-(A1203)-CaO-Na20-Si02 in equilibrium with
quartz. Saturation limit: wollastonite (a).
76
;::J 22.0 ;::J 20.0 ;::J 16.0
*
"* 20.0
"+
GROSS ,I ,...,...** 18.0
C GEHL
,...**
"+
14.0
GEHL

~ 18.0 ./1 v
+
:r: 16.0 GROSS :r: 12.0
v GROSS
<t <t <t
v v v
LAWS / "- 10.0
~ 16.0 PH ~ 14.0
+ / N + "+ CLNZ /
I

+ + ....-; +
(j 14.0 - ~ADElTE (j 12.0 (j 8.0 MARG/ NEPH
v P R G LAW~ NEPH
v
<t 12.0 ;:) 6.0 PARA
aTZ PARAG AOL
<.!) <.!)
o 54.0
...l 10 ..r. 0 8 .0 12 . 0 16 . 0 6.0 10.0 14.0 1.0 5.0 9.0 13.0
LOG CACNA+)/ACH+)) CACNA+)/ACH+)) LOG CACNA+)/ACH+))
;::J 22.0 ;::J 20.0 ;::J 16.0
** 20.0
",...
GROSS
/1 *
"*
"+
18.0
*
""* 14.0
GEHL

/
+ +
~ 18.0 ~ 16.0
GROSS :r: 12.0
<t
PREHY <t
v
<t
GROSS
v v v
~ 16.0 LAWS / ~ EPH ~ 14.0 ~ 10.0
+ + +
+ r--- ANAL + PREHN NEPH +
(j 14.0 (j 12.0 (j 8.0 NEPH
v FAR G v
;:) 12.0 ;:) 6.0
<.!)
KAOL <.!) AN L <.!)

510.0 58.0 54.0

4.0 8.0 12.0 16.0 2.0 6.0 10.0 14.0 1.0 5.0 9.0 13.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
;::J 22.0 ;::J 20.0 ;::J 16.0
GEHL
** 20.0 ** *
"* 14.0
GEHL
,...
,... r\ 18.0
+ ":r:+ "+
~ 18.0 PREHN v 16.0 GROSS ~ 12.0
<t <t <t
v v v
~ 16.0 ~ 14.0 ~ 10.0
+ + +
+ + +
(j 14.0 (j 12.0 PREHN NEPH (j 8.0 NEPH
~ KAOL L v
v 12.0 ;:) 6.0
<.!) <.!) <.!)
o
...l 10.0.", 8 ....
'" 58.0 54.0
4... 12.0 16.0 2.0 6.'0 10.0 14.0 1.0 5.0 9.0 13.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
N 22.0 N 20.0 ;::J 16.0
GEHL
** 20.0 GROSS * *
,...
,...
"* "* 14.0 GEHL
+ -:;- 17.0
:r: "+
:r:
~ 18.0 v
GROSS v 12.0
<t <t <t
v v v GROSS
~ 16.0 ~ 14.0 ~ 10.0
+ EPH + +
+ + +
(j 14.0 ANAL <t
u (j 8.0 MARG NEPH
~ 11.0 v
~ 12.0 AO~ R G v ;:) 6.0
<.!) <.!) <.!) AO
o 58.0
10·.r.0 8.0 12.0 16.0 54.0
...l 2.0 6.0 10.0 14.0 1.0 5.0 9.0 13.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))

Phase relations in the system HCI-H20-AI203-CaO-Na20-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature.
 77
;:;; 14.121 ;:;; 11.121 ;:;; 1121.121
*
"';:'*
GEHL ** GEHL
/ *
"*
GEHL
/
""±9.121 GROSS
/ ';:' 8.121
GROSS /
/
11.121
J:
v
<I:
v
GROSS v
<I:
v
CLNZ j
J:
v
<I:
v
CLNZ )
/
/1 NEPH
l.LI~

~ 8.121 ~ 7.121 ~ 6.121 ANOR /

+ MARy( NEPH + MARG + NEPH
+ + +
<I:
r-- <I:
U
<I:
U P RI"G
~ 5.121 PARA( ::;: 5.121 ::;: 4.121
<I:
v KYA v KYA FAR~~ v
SILL
(!) (!) (!)

g 2.1211.121 4.121 7.121 1121.121

g 3.1211.121 4.121 7.121 1121.121
g 2.1211 .",'" 4.121 7.121 1121.121
LOG (A(NA+)/A(H+» LOG (A(NA+)/A(H+» LOG (A(~A+)/A(H+»

;:;; 14.121 ;:;; 11.121 ;:;; 1121.121

* ** *
GEHL GEHL GEHL
/
"';:'* 11.121
_/
"';:' 9.121
I /' "';:'* 8.121 GROSS
I
j
J:
v GROSS J:
v
GROSS J:
v
<I:
v
<I:
v
CLNZ <I:
v
CLNZ.J / ANOR
~ 8.121
+
+
<I:
MARG/
NEPH
~ 7.121
+
+
<I:
MARG /1 NEPH ~ 6.121
+
+
<I:
NEPH
U U
~ 5.121 PARAC ::;: 5.121 ::;: 4.121 L3
<I:
v KYA v AND PIAR~G v SILL '
(!) (!) (!)
o g 2.121I.e
g 2.1211 .",'" 4.121 7.121 1121.121 -J 3 • e1.e 4.121 7.121 1121.121 4.121 7.121 1121.121
LOG (A(NA+)/A(H+» LOG (A(NA+)/A(H+» LOG (A(NA+)/A(H+»
;:;; 14.121 ;:;; 1121. 12Ir--"~~~~~~-' ~ 8.9
* ** *
"';:'* 11.121
GEHL
"';:' 8.121 GEHL
"*
';:' 6.9
GEHL
J: /"'" J:
::;: GROSS
J:
~1--::!r~G=R=O=SS==i'('/
j I
v v
<I: <I:
v GROSSi v CLNZ v
~ 8.121
!~6.121
~ 4.121
+ ANOR + ANOR
+
<I:
MAR/ NEPH +
<I:
U
NEPH ::;: 2.121 1------:/ NEPH
U
v 5.121 u A 121 t - - - -

JI3
::;: 'T.
<I:
v ARA v v
(!)
AND (!) AND (!) AND
g 2.1211 .",'" g 2. 121", ...."'~~~-Lo... ........._ .......... g e. 121121 ....e~""':"'"~ .........- ' - -............
4.121 7.121 1121.121 '" '" 3.121 6.121 9.121 3.121 6.9 9.121
LOG (A(NA+)/A(H+» LOG (A(NA+)/ACH+» LOG CACNA+)/ACH+»
;:;; 12.121 ;:;; 4.121 ;:;; 121.121
* GEHL ** GEHL . / *
"';:'* 9.121 * GEHL
"';:' 2.121 GROSS / ""£2.121 I=G=RO=S=S,.£.?:.,
~7.:
J: J:
v v v
<I: <I: l:CLNZ / <I:
v
MARG
v ANOR v
ANOR /
~ 6.121 ~ 121.121 ~4.e
+ NEPH + /1 NEPH +
+
<I:
+
<I:
+
<I:
NEPH
U u u
::;: 3.121 AR G ~2.121 ~ ~6.e
v AND v AND v AND
(!) (!) (!)
g 121.121 o
..r 4 • l2Ie • 12I 3.121 6.121 9.121 3-8. 1219 ._....e-..-L"'::-'~~::-"""..............
121.121 3.121 6.121 9.121 3.121 6.9 9.121
LOG (ACNA+)/A(H+» LOG (A(NA+)/A(H+» LOG CA(NA+)/A(H+»
Phase relations in the system HCI-H20-AI203-CaO-Na20-(Si02) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature.
 78

\
::::: 13. er--~~-~~--..., ::::: 9.0 ::::: 6.13
N N N
* * * ANNITE
"*+ 5.13
"*
±
v
..:
v
12.13.,.. - b - ANNITE "+* 8.0
:r:
v
..:
v
~A:N~T~ -
:r:
v
..:
v
b-
KAOL
K - --

'"
~ 11.13 ~ 7.0 ~ 4.0
£
IJ..
GIBB , , _ _ _ _ _~
W
+
+
IJ..
KAOL
W
+
+
IJ..
US

~ 1 e. 13 ~ US ~ 6.0 US v
..:
3.0 K-SPAR
v K-SPAR v v
(!) (!) K-SPAR (!)
o o o
..J 9.13 ..J 5.13 ..J 2.0
13.13 4.13 8.13 12.13 -2.0 2.13 6.0 10.13 -2.0 2.0 6.13 113.13
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))

1\-
::::: 13. er-~~-~~--.., ::::: 9.13 ::::: 6.13

\~N~I~~
N N N

** *
"*+ 8.13
*
":r:*+ 5.13
-:;:- 12'13
~
..:
v
b- ANNITE
- - - :r:
v
..:
v
~:~NITE_ v
..:
v
-

~ 11.13 ~ 7.13 ~ 4.13 KAOL

+ ~ +
£
IJ.. KAOL "'-----~ +
w
IJ..
KAOL

US
+
W
IJ..
US
~ 113.13 ~ US ~ 6.13 ~ 3.13
K-SPAR
v K-SPAR v K-SPAR v
(!) (!) (!)
o o o
..J 9.13 ..J 5.0 ..J 2.0
13.13 4.13 8.13 12.13 -2.13 2.13 6.13 113.13 -2.13 2.13 6.13 113.13
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))

1\
::::: 12.13 ::::: 8.0 ::::: 6.13
N . -b----- N N

** * *
-:;:- 11.13
:I:
~ ANNlTE "*+ 7.13
:r:
"*+ 5.13
:r:
v ANNHE

'"
v v
..:
v
~ 113.13 KAOL
..:
v
~ 6.0 KAOL
..:
v
~ 4.13
r- - T~ - -0- -
+ + + KAOL
+ ~~S + US +
W w ~ w
IJ.. IJ.. IJ..
3.13
r US
~ 9.13 K-SPAR ~ 5.0 v
K-SPAR ..:
v v v K-SPAR
(!) (!) (!)
o o o
..J 8.13 ..J 4.13 ..J 2.13
13.13 4.0 8.0 12.0 -2 .13 2 . 13 6 . 13 113 .13 -2.13 2.13 6.13 113.13
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))

::::: 12.13 ::::: 8.13 ::::: 6.0

N N N

AbA~N~~ -
-b------
** ,..,** *
-:;:- 11.13
\ . ANNITE + 7.13
:r:
":r:+* 5.13 ANNITE
:I:
v v v
..: ..: ..:

'"
v v v

KAOL "'-
~ 113.0 ~ 6.13 ~ 4.13
+ KAOL - -0-
+ +
+ + +
W MUS W
~ US
w
IJ.. IJ.. IJ..
v 9.0 v 5.13 v 3.13
..: K-SPAR ..:
v K-SPAR ..:
v v K-SPAR
(!) (!) (!)
o o o
..J 8 0 ..J 4.0 ..J 2.13
. 0.0 4.13 8.0 12.0 -2.13 2.13 6.13 113.13 -2.13 2.13 6.13 113.13
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))

Phase relations in the system HCl- H 20 - (Al 20 3) - FeO - K20 - Si0 2 in equilibrium with quartz.
Saturation limits: fayalite (a), ferrosilite (b).
 79
~ 6.0 ~ 5.0 ~ 5.0

~ ANNlTE
N N N
*
'J:+* 5.0 ~\ ANNHE *
'J:*+ 4.0
*
"J:*+ 4.0 \ANNITE
v v v
« « «
v
~ 4.0
r - -K -b- - - v
r KYA ""~-o- - ~ v r- -0 - -1'1---""1
~ 3.0 ~ 3.0 SILL
+ PYROPH + +
+ + M~S +
W W W Ml C
IL. IL. IL.
v 3.0 ~ US ~ 2.0 K-SPAR ~ 2.0 K-SPAR
«
v K-SPAR v v
(!) (!) (!)
o o o
-' 2.0 -' 1 .0 -' 1 .0
-2.0 2.0 6.0 10 . 0 -2.0 2.0 6.0 10.0 -2.0 2.0 6 .0 10 . 0
LOG(A(K+)/A(H+» LOG(A(K+)/A(H+» LOG(A(K+)/A(H+»
~ 6.0 ~ 5.0 ~ 5.0
N N N
* * *
v
«
v
'J:*+ 5.0

~ 4.0
ANNITE

-0- -
'J:+* 4.0
v
«
v
~ 3.0
"J:+* 4.0
v
«
v
~ 3.0
I\~ITE
+
+
+
+
+
+ r- - 0 - -i(~~~-t
W W W SILL
IL. IL. IL.
~ 3.0 ~ 2.0 ~ 2.0 MU C
v K-SPAR v v K-SPAR
(!) (!) (!)
o o o
-' 2.0 -' 1.0 -' 1.0
-2 .0 2.0 6. 0 10.0 -2.0 2.0 6.0 10.0 -2.0 2.0 6 .0 10.0
LOG(A(K+)/A(H+» LOG(A(K+)/A(H+» LOG(A(K+)/A(H+»
~ 5.0 ~ 3.0 ~ \.0
N N N
* * *
'J:*+ 4.0
v
ANNITE 'J:*+ 2.0
v
I\ANNlTE 1:"* 0.0
v
ANNITE

«
v
«
v
«
v
O~ - i;-'~--;
~ 3.0 ~ 1.0 ~1.0
+ + AND
+
W
+
W
Ml C
at+ AND
IL. IL.
~ 2.0 ~ 0.0
IL. K-SPAR
K-SPAR ~2.0
v K-SPAR v v
(!) (!) (!)
o o o
-' 1.0 -'-1.0 -'-3.0 ~--~~~----~
-2.0 2.0 6 .0 10.0 -2.0 2.0 6.0 10. 0 -2.0 2.0 6.0 10.0
LOG(A(K+)/A(H+» LOG(A(K+)/A(H+» LOG(A(K+)/A(H+»

l~8'01\
~ 4.0 ~3.0
N N
**
\ ANNHE
* ANNITE
'J:*+ 3.0
v
«
v
~.ANNHE ';..4.0
J:
v
«
v
...-9.0
J:
~
v
r- - ·r-_-_-:O;::-_-_-~--1
Q- - i,-------i
~ 2.0 '-- - - '" -0 - - - ~5.0
AND ~10.0 AND
+ AND + +
+
W
+
W MU C +
IL. M~S IL. ~ K-SPAR
~ 1.0 ~6.0 K-SPAR ~11.0
v K-SPAR v v
(!) (!) (!)
o o o
-' 0.0 -'-7.0 -'-12.0~--~L-----~~
-2.0 2 .0 6.0 10 . 0 -2. 0 2. 0 6.0 10 . 0 -2 . 0 2 .0 6.0 10.0
LOG(A(K+)/A(H+» LOG(A(K+)/A(H+» LOGCACK+)/ACH+»
Phase relations in the system HCI- H20- (AI 20 3) - FeO- K20-Si02 in equilibrium with quartz.
Saturation limits: fayalite (a), ferrosilite (b).
80
~ 18. 0.--~~-~~-~-, ~ 12. 0..-~~-~~-~..., ~ 8.0
N N N
:I:
:I:
16.0 FAY :I:
7.0
:I:
"+ *
';' 10.0
FAY
:I:
"+ FAY
-0- :c ;S
;S 14.0 v 6.0 -0- -
« ANNITE « -0- - «
v v ANNITE v
;:::: 12.0 ;:::: 8.0 ;:::: 5.0
+ + "'-...----' +
+ + +
~ 10.0 w ~ 4.0 KAOL KALS
K LS lL. KAOL K LS
v OTZ ~ 6.0 v
Muse
~ 8.0 Muse v Muse ~ 3.0
(!) (!) (!)
o o o
...J 6 0 ...J 4.0 ...J 2.0
. 0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))
~ 18. 0r-~~-~~-~-' ~ 12. 0r-~~-~~-~..., ~ 8.0
N N N
:I: :I: :I:
16.0 FAY :I: :I: 7.0
:I:
FAY FAY
"+ "+ 10.0
:c
"+
~ 14.0 -0- v ;S 6.0
« « « -0- -
v ANNITE v v
;:::: 12.0 ;:::: 8.0 ;:::: 5.0
+ + "'-...---.' +
+ + + KALS
W
~ 10 .0 KAOL K LS lL. KAOL K LS ~ 4.0 KAOL
v
Muse
v
«
6.0 v
Muse
~ 8.0
(!)
v
(!)
Muse ~ 3.0
(!)
o o o
...J 6.0 ...J 4.0 ...J 2.0
0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))
~
N
18. 0r-~~-~~-~-' "N
A
12.0 ~
N
8.0

* 16.0 FAY
:I:
:I:
FAY
:I:
:I: 7.0
"+ "+ 10.0 "+
:c
;S 14.0 v ;S 6.0
« « «
v v -0- - v
;:::: 12.0 ;:::: 8.0 ANNITE ;:::: 5.0
+ + +
+ +
W
'.-----,' + KALS
~ 10.0 KAOL K LS ~ 4.0
v
lL.
v 6.0 KAOL K LS v Muse
~ 8.0 Muse «
v Muse ~ 3.0 KAOL
(!) (!) (!)
o o o
...J 6.0 ...J 4.0 ...J 2.0
0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0 -2 . 0 2.0 6.0 10.0
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))
~ 18. 0r--~~-~~-~..., ~ 12 .0r-~~-~~-~..., ~ 8.0
N N N
* 16.0 FAY
:I:
:I:
:I:
* 7.0
"+ -:;:- 10.0 FAY "+

H:~
:c
;S 14.0
-0- v ;S 6.0
« «v «
v v
;:::: 12 . 0 ANNITE ;:::: 8.0 ;:::: 5.0
+ + +
+ + ,>----( +
w 10.0 W ~ 4.0
~ KAOL K LS lL.
v 6.0 KAOL v
KALS
~ 8.0 Muse «
v Muse ~ 3.0 Muse
(!) (!) (!) KAOL
o o o
...J 6.0 ...J 4.0 ...J 2.0
0.0 4.0 8.0 12.0 -2 . 0 2. 0 6. 0 10 . 0 -2.0 2.0 6.0 10.0
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))

Phase relations in the system HCl- H 20 - Ah03 - FeO - K20 - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limit: ferrous oxide (a).
 81

mif.
~ 6.0 ~ 5.0 ~ 5.0
N N N
* FAY ,..** ** FAY ./
';' 5.0 + 4.0 _ -0- _AN ~_ ';' 4.0
J:
v
«
J:
v
«
/-
J:
v
«
~ -0- _A~E__
v v v
;::; 4.0 ;::; 3.0 KALS ;::; 3.0 KALS
+ + +
+ + ~US( +
W Muse W W M~S
II..
KYA
II.. KYA II..
2.0 SILL
~ 3.0 ~ 2.0 v
v v
«
v
(!) (!) (!)
o o o
...J 2.0 ...J 1.0 ...J 1.0
-2 . 0 2.0 6.0 10 . 0 -2 . 0 2. 0 6.0 10 . 0 -2.0 2.0 6.0 10.0
LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+))

FAYd If
~ 6.0 ~ 5.0 ~ 5.0
N N / N
**
';' 5.0
J:
A I E
**
';' 4.0
J:
FAY
r -0- _AN =-_
,..**
+ 4.0
J:
FAV/
v
« r -0- - - - v
«
v
« ANNITE
v
;::; 4.0
v
;::; 3.0 KALS
v
;::; 3.0 I- -0- - YI- - -
+ KALS + +
/
KALS
+
w
+ us +
Muse W W MJS
~ 3.0 KYA
II.. AND II..
« ~ 2.0 ~ 2.0 SILL
v v v
(!) (!) (!)
o o o
...J 2.0 ...J 1.0 ...J 1.0
-2.0 2.0 6.0 10 . 0 -2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+))
~ 5.0 ~ 3.0 ~ 1.0
/
FAvl1~
N N N
FAY
** ** ** FAY /
-0- _A~E__
';' 4.0 ';' 2.0 ';' 0.0
J: r -0- _ A _ J: r J:
ANNITE / /
,,- -\1 - - -
v v v
«
v /-
«
v
« I- -0-
v
;::; 3.0 KALS ;::; 1. 0 KALS ~1.0
+ + + KALS
+ ~use + ~ us +
W
AND
W
II.. AND W
II..
M c
~ 2.0 ~ 0.0 ~2.0 AND
«
v v v
(!) (!) (!)
o o o
...J 1.0 ...J- 1 . 0 ...J- 3 .0
-2.0 2.0 6.0 10 . 0 -2 .0 2. 0 6. 0 10. 0 -2. 0 2.0 6.0 10.0

b
LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+))
4.0
FAV
~ ~3.0 ~8.0
N N N
** ,..**
FAY ,/ *
';' 3.0
J:
v
«
v
I- -0- _ A ~ _ +-4.0
J:
v
«
v
r -0- Al!#~ -- *
~9.0
J:
v
«
v
;::; 2.0 KALS ~5.0 KALS ~10.0
+ + + K- AR
+
W ~use + I'US +
W W AND KALS
~ 1.0 AND II..
~6.0
AND II..
~11.0
«
v v v
(!) (!) (!)
o o o
...J 0.0 ...J- 7 .0 ...J- 12 . 0L--~""""~-~...J
-2.0 2.0 6. 0 10. 0 -2.0 2 .0 6. 0 10.0 -2.0 2. 0 6 .0 10.0
LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+))
Phase relations in the system HCI-H 20 - Ah03 - FeO - K20 - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limit: ferrous oxide (a).
82
~ 17. 0r---~~~-~----' ~ 12. 0..--~---~--, ~ 9.0

** *
,...* ,...**
'"~ '" 14-A CL 14-A CL 1
15.0 14-A CL I + 10.0 I '.;' 7.0 I
::5 I
:r
v
:r
v C
« C « ~ « 1
I v v -0
v T
~ 13.01----------.-; ~ 8.0 - -0-- ~ 5.0
- -0- - - ...!- +
o+
l:
I
+
+
(!)
l:
KAOL
I
I
+
(!)
KAOL
~ 11.0 GIBBS v 6.0 I ~ 3.0
v
«
v
«
v
1 (!)
I (!)
(!)

g 9.02.0 I
g 4.0
-3.0 1 .0 5.0 9.0
.1 g 1. 0
6.0 10.0 14.0 -3 . 0 1. 0 5 .0 9 .0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 17. 0..--~---~--, ~ 12. 0..--~---~---, ~ 9.0
* ,...** *
'"*
'.;' 15.0 14-A CL '.;' 10.0 14-A CL '"*
'.;' 7.0
14-A CL
:r I
:r :r
J
1
~ C v
«
C v
«
v ~ v
-0 -I
v a
"'.;' 13 . 0 r - - 0- - - 't - ~ 8.0 ~ 5.0

o
l: KAOL
I
I
+
+
(!)
l: KAOL
I +
+
(!)
l: KAOL
~ 11.0 ~ 6.0 I ~ 3.0
v I v v
I (!)
I I
(!) (!)

g 9.0
2.0 6.0 10.0 14.0
1
g 4.0
-3 . 0 1.0 5 .0 9 .0
.I g 1.0 I
-3 . 0 1. 0 5 .0 9.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 17. 0r---~---~--' ~ 12. 0..--~---~---, ~ 9.0
* I
,...** I ,...**
~ I
'.;' 15.0 14-A CL I 14-A CL I 14-A CL I
'.;' 10.0 '.;' 7.0
:r
v
~
C
1
I
:r
v
«
I
C
:r
v
«
6
v I v
~ 13.0 __ -0- __ !....- ~8.0 I-- -0 T- ~ 5.0 a
+ + +
o
I
+ I +
I (!) (!)
l:
KAOL l: KAOL I l: KAOL
~ 11.0 ~ 6.0 I
~ 3.0
v v v
I I
(!) (!) (!)

g 9.0
2.0 6.0 10.0 14.0
g 4.0
-3.0 1.0 5.0 9.0
I g 1.0 I
-3. 0 1 .0 5 .0 9. 0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 17. 0..--~---~--. ~ 12. 0r--~---~---' ~ 9.0

** ~* I ,...** I
'"
'.;' 15.0 14-A CL '.;' 10.0 14-A CL I '.;' 7.0 14-A CL I
:r
v
1 :r I :r
C v
« ~ C « b
v I v I v
~ 8. 0 I-:I---------;;O;----=--,!.--!- ~ 5.0 I
~ 13.01-- _ -0- __ 1__
a
o
l:
I o+
1
+
+
(!)
l:
I

v 11.0 KAOL ~ 6.0 KAOL I v 3.0 PYROPH

«
v v
«
v
(!)
I
(!) (!)
o g 4.0 g 1.0 I
-1 9 . 02 . 0 6.0 10.0 14.0 -3.0 1. 0 5.0 9.0 -3.0 1 .0 5.0 9.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
Phase relations in the system HCl- H20 - (A1 20 3) - FeO - MgO - Si0 2 in equilibrium with
quartz. Saturation limits: talc (a), fayalite (b), ferrosilite (c).
 83
~ 8.a ~ 8.a ~ 8.a
* *
** 14-A CL ""*+ 6.a 14-A CL I ""* I
"+ 6.a I I + 6. a 14-A CLI
I I I
v v v
< I < I < I
v a I
v v
;::; 4.a cI ;::; 4.a a ;::; 4. a a b
+
+
(!)
PYROPH
+
+
(!)
L
b I
+
+
(!)
L
I

L
2.a KYA 2.a SILL
~ 2.a ~ v
<
v v v
I I I
(!) (!) (!)

:l a.-4
a .a 1
:la.-4
a .a J o a a I
a .a 4.a 8.a a .a 4.a 8 .a ....J ·-4.a a.a 4.a 8.a
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 8.a ~ 8.a ~ 8.a
* * *
"*
';' 6.a
14-A CL "*
"+ 6.a 14-A CL "';'* 6.a 14-A CL
I I I I
v v v
<
v a
1 <
v
<
v ,I
;::; 4.a
+
+
b
I
;::; 4.a
+
+
a
b
;::; 4.a
+
+
a- .
b
(!)
L PYROPH
(!)
L I (!)
L I
v 2.a v 2.a AND I v 2.a SILL I
<
v
<
v
<
v
I I I
(!) (!) (!)
L I
:la .a
-4.a a.a 4.a 8.a :l a.-4
a .a a .a
1
4.a 8 .a :l a.-4.a
a a.a 4.a 8.a
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 8.a ~ 6.a ~ 4.a
* * *
"';'* 6.a "* 14-A CL ""+* 2.a 14-A CL I
I
14-A CL "I+ 4.a I I
v v v
<
v
<
v
<
v
;::; 4.a a ;::; 2.a ;::; a.a
+
+ b +
+
+
+
(!)
L
I (!)
L AND
(!)
L
~ 2.a AND va.a ~2.a
I < AND
v v v
I I I
(!) (!) (!)
I I
:la.-4
a .a a .a 4 .a 8 .a
3-2.a
-8. a -4. a a. a 4. a 3-4.a
-la.a -6.a -2.a
I
2.a
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 6.a ~ l.a ~ 5.a
* * *
"';'* 4.a 14-A CL
""*+-1.a "';'* a.5
I I 14-A CL I I
v
a v v 14-A CL I
~
<
v
<
v
<
v
;::; 2.a
+
~3.a
+
CORD :t ~4.a
+
b
I
+
(!) AND
+
(!) a +
(!)
L L L
~ a.a I v-5.a
< AND
v-8.5
<
v v v
I I AND I
(!)
(!) I L
3-2.a
-6 . a -2. a 2 .a 6 '"
.00
3-7.a
-1 4 . a-I a . a -6 . a -2. a 3- -
18 1
. a-I3 .a
4 . a-I a .'a -6. a
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
Phase relations in the system HCl-H 20-(AI 20 3)-FeO-MgO-Si0 2 in equilibrium with
quartz. Saturation limits: talc (a), fayalite (b), ferrosilite (c).
 84
~ 17.121 ~ 12.121 ~ 9.121
**
r.
**
r.
**
r. 7-A CL
r. 7-A CL r. 7-A CL r.
+ 15.121 + 1121.121 + 7.121
J: J: J:
v v v
4: I 4: 4:
v v v -0- - -
;:; 13.121 1 ;:; 8.121 -0- - - - _1_ ;:; 5.121
+ -0- - - - ~- + 1 + I
+ I + + C
(!)
1: GIBBS
(!)
1: KAOL
(!)
1: KAOL I
vl1.e I
~ 6.121 ~ 3.121
4:
v s: y v
1
(!) (!) (!)

g 9.1212.121 6.121 1121.121 14.121

g 4.121-3.1211 .121 5 . 121 9 . 121
g 1.121
-3.121 1.121
1
5.121 9.121
LOG CACFE++)/CACH+))MM2) LOG CACFE++)/CACH+))MM2) LOG CACFE++)/CACH+))MM2)
~ 17. 12Ir-~~~-~-~..., ~ 12.121 ~ 9.121
**
r. 7-A CL
**
r. 7-A CL
**
r. 7-A CL
r. r.
+ 15.121 + 1121.121 ':;: 7.121
J: J: J:
v v v
4:
v
4:
v
4:
v -0- !..
;:; 13.e r -0- - ;:; 8.121 -0- -l - ;:; 5.121 1
+ + I + I
+
(!)
1: KAOL
+
(!)
1: KAOL
C
I
+
(!)
1:
KAOL 9
~ 11.121 ~ 6.121 1 v 3.121 1
4:
v 1 v v
1 1
(!)

g 9.1212.121 l (!)

g 4.121-3.121 .1
(!)

g 1.121 l
6.121 1121.121 14.121 1.121 5.121 9.121 -3.121 1.121 5.121 9.121
LOG CACFE++)/CACH+))MM2) LOG CACFE++)/CACH+))MM2) LOG CACFE++)/CACH+))MM2)
~ 17. er--~~-~~-~..., ~ 12.0 ~ 9.121
**
r. 7-A CL **
r. 7-A CL **
r.
r. r. r. 7-A CL
+ 15.121 + 1121.121 + 7.121
J: J: J:
v v 1 v
4: 4: 4:
v v 1 v -0-1-
;:; 13.121 - - - - -O-
r- ;:; 8.121 r--O - - - , - ;:; 5.121
+
+
(!)
KAOL 1
+
+
(!)
KAOL
1
+
+
(!)
KAOL
b
I
1: C 1: C 1:
~ 11.121 ~ 6.121 ~ 3.121 1
1 1
v v v
(!) 1 1
(!)

g 4.121
(!)

g 9.1212.121 6.121 1121.121 14.121 -3.121 I.e 5.121 9.121

I g 1.121 1
-3.121 1.121 5.121 9.121
LOG CACFE++)/CACH+))MM2) LOG CACFE++)/CACH+))MM2) LOG CACFE++)/CACH+))MM2)
~ 17.121 ~ 12. 12Ir-~~--~-~--' ~ 9.121
**
r.
7-A CL **
r.
r. 7-A CL I **
r.
7-A CL
':;: 15.121 + 1121.121 C ':;: 7.121 I
I
?
J: J: J:
v v v
4: 4: 4:
v v v
;:; 13.121
+ I- - -0-1- -
;:; 8.121 :... - - - -0- l - ;:; 5.121 - - 0- ~ -
+ 1 + 1
+
(!) 1 +
(!)
+
(!)
1: KAOL C 1: KAOL 1
1:
~ 11.0 v 6.121 ~ 3.121 PYROPH :
4: 1
v v
1 1
(!)

g 9.1212.121
(!)

g 4.121-3.121 I g 1

6.121 10.121 14.121 1.121 5.121 9.121 ...J 1 ._1213 . 121 1 .121 5 . 121 9 . 121
LOG CACFE++)/CACH+))MM2) LOG CA(FE++)/CACH+))MM2) LOG CACFE++)/CACH+))MM2)
Phase relations in the system HCI-H 20-(AI 20 3)-FeO-MgO-Si0 2 in equilibrium with
quartz. Metastable 7-A dinochlore was considered instead of
its stable counterpart, 14-A dino-
chlore. Saturation limits: talc (a), fayalite (b), ferrosilite (c).
 85
~ 8.0 ~ 8.0 ~ 8.0
* * *
"*
'; 6.0
7-A CL
""*+ 6.0 7-A CL "';* 6.0 7-A CL 1
J: J: J: 1
v
«
v
- - -a- _I _ _
v
«
v
« ~~I
;::; 4.0 1
v
;::; 4.0 r - -a- -1- - -
v
;::; 4.0 a -I -
+ 1 + + I
+
(!) PYROPH 9 +
(!)
::I: KYA ~ +
(!)
::I: SILL ~
~ 2.0 ~ 2.0 ~ 2.0
«
v
1
v
1
v
1 1 1
(!) (!) (!)

g 0.0
-4.0 0.0
i
4 .0 8 .0
g 0.0
-4.0 0.0 4.0
1
8.0
g 0.0
-4 . 0 0 .0 4 .0
I
8 .0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 8. 0 r-~~-~-~--, ~ 8. 0 r-~~-~~---, ~ 8.0
* * * 1
"*
'; 6.0
7-A CL
"';* 6.0 7-A CL "';* 6.0 7-A CL
1
J: J: 1 J: 1
v
«
v
- - -a- _I __ v
« CORD~ 1 v
« CORD~ 1
v v
;::; 4.0 1 ;::; 4.0 - - -a- -+ - - ;::; 4.0 r- -y-
~
1
+ + +
+
(!) PYROPH ~ +
(!)
~ +
(!) 1
~ 2.0
«
v
1
::I:
~
v
2.0
AND
1
::I:
~
v
2.0 SILL ?
1 1 1
(!) (!) (!)

g0.0
-4.0 0.0
i
4.0 8.0
g 0.0
-4.0 0.0
1
4.0 8.0
g 0.0 I
-4.0 0.0 4.0 8.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 8.0 ~ 6.0 ~ 4.0
* **
1
*
"';* 6.0 7-A CL "'; 4.0
7-A CL 1 "';* 2.0 7-A CL
1
CORD~
,
J: J: J:
CORD~
v
«
v
«
v
« I CORD~~I----;
- -a- - +- - -
v v
;::; 4.0 ;::; 2.0 a r v
;::; 0.0 a l
+ 1 + 1 +
+
(!)
+
(!)
+
(!)
AND 1 ::I: AND 1 ::I:
~ 2.0 ~ 0.0 I :;:-2.0 AND
«
v
~ v
? v ~
I
g 0. 0
(!) (!)
(!) ~ 1
L-~_ _"""':-",:~-::-,
5-2.0 5-4.0 i
-4.0 0.0 4.0 8.0 -8.0 -4.0 0.0 4. 0 -1 0 . 0 -6. 0 -2.0 2. 0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 6.0 ~ 1.0 ~ 5.0
* 7-A CL 1
**
1
*
"*
'; 4.0 ~I ""£1.0 7-A CL
1
"';* 0.5
J: 1
-a- -r
J:
v v v
« « I
« 7-A CL
v
;::; 2.0 1
v
~3.0 ? v
~4.0
+ 1 + CORD 1 +
+ + -0 +
(!)
AND ~ (!)
::I: 1 (!)

~ 0.0 :;:-5.0
::I:
:;:-8.5
«
v v
AND 1
v
(!)
1 1 AND
(!) (!)
5-2.0 i 1
5-7.0 5-1 3 . 0 '-:---:-~~..........~::-'
-6.0 -2.0 2.0 6.0 -14.0 -10.0 -6.0 -2.0 -1 a-•0 - I 4 . 0 - 10 . 0 -6 . 0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/(ACH+))**2) LOG CACFE++)/CA(H+))**2)
Phase relations in the system Hel - H 20 - (AI20 3) - FeO - MgO - Si02 in equilibrium with
quartz. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A cIino-
chlore. Saturation limits: talc (a), fayalite (b), ferrosilite (c).
86
;:;; 22. 0r--~~-~......~---' ;:;; 20 . 0r--~~--,.....~--' ;:;; I 'I . 0 F====-=-""T
i===-==9
* ,..** : FORST-.-:i I
"?* 18.0 I'I-A CL ~ 16.0 :::
+ 10.0 I'I-A CL ,I

~ -0- - - J J:
~
I'I-A CLI
I
b
~ -0- - - 9- /-
v
~ 1'1.0
fANTIG v
~12.0 .~_/ ~6.a /
~
~
+

10.0
\---/
tTALC ~8.0 - - -o;:p . t
~
:I:
~ 2.0 KAOL
I
FAY

v b ~ KAOL I FAY
I
v
I
~ FE R I
3 'I. 0
~ ~
L-..._~I......-..L...-~-l L
36.0 '" 5-2.0
10.0 12 ..... 1'1.0 16.0 ~.0 7.0 9.0 11.0 2.0 '1.0 6.0 8.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
;:;; 22. 0r-~~--"""'r~--' ;:;; 20. 0r--~~--....-~--' ;:;; 1'1.0 -1
* * FORST --..r I
6 :
"?* 18.0
"?* 16.0
I "
? I0 .0 I 'I-A CL I
I
J: J:
v
«
v
«
v
I'I-A CL I
I ~ f- - - -0-'; -/-
~6.0
v
~ 1'1.0 I ~ 12.0 I /
+ 1----.-, + - - -0- T t I
+ TALC I +
~ ~
I FAY I ~ I FAY
:I:
~ 10.0
KAOL
~
«
8.0
I FAY
~ 2.0 KAOL b
~ I
v v KAOL v
~ FER SIL ~
I ~

36.0 3 'I. 0 .L0~~-L--.l~--l I

5-2.0
10.0 12.0 1'1.0 16.0 :; 7.0 9.0 11.0 2.0 '1.0 6.0 8.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2)
;:;; 22 . 0r--~~-~r-~---' ;:;; 20 . 0r--~~-"""'-~~--, ;:;; 1'I.0~==~==~====~
* ,..,** : I FORST1
"*

--or
I'I-A CL ::: I
?J: 18.0 ?J: 16.0 + 10.0
J:
v -0- - -1- v I'I-A CL I v
«
v
«
v I «
v
TALC;.':
~ 1'1.0 I ~ 12 .. 0 ~ 6.0
+ + +
+ I + +
~
FAY ~ ~ FAY
bi
:I: :I: :I:
~ 10.0 KAOL ~ 8.0 ~ 2.0 KAOL
I FAY
v v v
KAOL
FE OSIL ~
3 'I. 0
~ ~ ~

36.0 L - - _............--....L~~-l
5-2.0
10.0 12.0 1'1.0 16.0 5.0 7.0 9.0 I 1.0 2.0 '1.0 6.0 8.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2)
;:;; 22 .0r-~~-...-~~--' ;:;; 20. 0r-~~-...-~~--,
;:;; 1'1. 0r-~~-"""""F"'O!:":R::-'S::-!T"""""
,..** ,..,** 6I *
"* II 'I-A CL
?J: 18.0 ?J: 16.0 ?J: 10.0 I

-a-y
v v I'I-A CLI
« « I ~ I
v
~ 1'1.0 TALCZ
v
~ 12.0
v c- -,.
~ 6.0
+
~
+
~
+
+ t I
:I: :I: ~ I FAY
~ 10.0 KAOL ~ 8.0 v 2.0 I
v
I FAY ~ KAOL b
KAOL
I
3 'I. 0
~ ~ ~
36.0 '---,.....~-~-~-' L--_-"---'-~_-l 5-2.0
10.0 12.0 1'1.0 16.0 5.0 7.0 9.0 11.0 2.0 '1.0 6.0 8.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2)

Phase relations in the system HCI-H 20-AI20 3 -FeO-MgO-(Si0 2) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limits: brucite (a), ferrous oxide (b), spinel (c).
 87
~ 113. elr-~~-~--~--' ~ 113. elr-~~-~--~--' ~ 113. elr-~~-~--~....,

* I * FORST I *
~ b ~
""+* 8.13

Y 1
I
FORST I
';:' 8.13 14-A CL i:" 8.13 b
~
:r: :r:
v

-~~-~ ~v
<{
v v
;::; 6.13 t- - -C- -
;::; 6.13 I
6 14"';;' CL I
+ •• +
+ + - -C-
(!)
I FAy (!)
L
~ 4.13
<{ I ~ 4.13 I FAY v 4.13
KYA v KYA
<{
v FAY
I I SILL
(!) (!) (!)

~ 2.13 -.l ~ 2.13

I.
~ 2.13
13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 113. el.--~--~--~....., ~ 113.13 ~ 113. elr-~~-~--~...,

~ ~ ** FORST: *
""+* 8.13 FORST I

-y V
';:' 8.13 "+ 8.13
:r: 14-A CL :r: :r:
b
:/
v
<{
v
'c- - ;
V-__
v v
;::; 6.13 ;::; 6.13 14-A CLI ;::; 6.13
+
+
(!) t - - - - -......... I
+
+
(!)
r -c- _.J -- +
+
(!) l_t~ :'L
L L
~ 4.13
<{ KYA
I FAY v
<{
4.13 I FAY v
<{
4.13
v
I
v
I AND ,:1 FAY
(!) (!) (!)
SILL 1IJ
I I
~ 2.13 ~ 2.13 ~ 2.13
13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 113. el~===jI==~ ~ 8.13 I ~ 5.0
: FORSTll * * I
""*+ 6.13 ""+* 3.0
FORST I
"';:' 8.0 I I FORST I
:r: :r: :r: b
1/
-'~~~~y
v

~L_V;
<{
v v v
;::; 6.0
+
;::; 4.13
+
14-A
r- -C-
_ ;::; 1.0
+
C - ~-.A Q.--:;Y- -
+ + +
(!) (!) (!) CORD] I
L I FAY L FAY
~ 4.0
<{
I FAY v
<{
2.13 v-l.0 I AND
AND I v AND I
<{
v
I
(!) (!) I (!)

~ 2.13 ~ 13.13 3-3.0 II

13.13 2.13 4.13 6.13 -2.13 13 . 0 2.13 4.13 -5.0 -3.0 -1.0 1 .0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 9.13 ~ 1.13 ~4.0
~ ..!
* ** * I
"*
FORST
~ ""..... "* b

y
';:' 7.0
:r: :r:
1.0 "..... 6.0
:r:
FORST
I ~

_1~-~_ '= _
-y
v
14-A CL <{
v I v v
;::; 5.13 >-3.0
r- f14-A CL
>-8.13
+
+ - -C- - +
+ I +
+
'I
-C-
(!) (!) (!) CORD] FAY
L IFAY
~ 3.0 I v-5.0
L
v-Iel.el AND
<{
I FAY
<{ AND I <{
v AND
(!) I (!) (!)

~ 1.0 3-7.13 3-12.elL-~---~~---~

-2.0 0.0 2.0 4.0 -9.13 -7.13 -5.13 -3.13 -13.13 -1 1 .13 -9.13 -7.13
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

Phase relations in the system HCI- H 20 - Al 20 3 - FeO - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limits: brucite (a), ferrous oxide (b), spinel (c).
88
c:;J 22.0 I c:;J 20.0 c:;J 14.0
FORST FORST I
** 7-A CL * I
**
"':;:'*
Y
,.... I ,....
I ,....
':;:' 18.0 I 16.13 + 10.13

a-~)(-
J: J: I J:
7-A CL
v v v
« « 7-A CL I « -0---1- -
v v
0 v
~ 14.0
+
+
[TALC 1) ~ 12.13
+
+
- -0- - - : /
~ 6.0
+
+
TALd- 9 I

(!)
I
I FAY
(!)
1:
ANTI~ ./j (!)
1: I FAY
~
«
10.0
aTZ
v
«
8.0 TALC} IFAY ~ 2.0 KAOL
I
v I KAOL v
I I
FER R'SIL I
(!)

~ 6.010.0 6
84 (!)

3-2.13 .1
12.0 14.0 1 .0 ...J . 05 . 0 7.0 9.13 11.0 2.13 4.13 6.0 8.13
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)

c:;J 22.0 I c:;J 213.13 c:;J 14.0

FORST FORST I
** ,....* **
7-A CL
,.... I
* I
,....
':;:' 18.0 ':;:' 16.0 ':;:' 113.13
r~TIG~_

---o-v
J: J: I J:
v v 7-A CL v 7-A
0- - C
- -1L o
--/
« « «
b
t--
v v v
(ALC I
~ 14.0
+ - b ~ 12.0
+
~ 6.13
+ TALC
I
I
+ I + +
(!)
FAY
(!) ANTIG . / I (!)
I FAY
1: 1:
v 10.13 I ~ 8.0 TALC:] I FAY v 2.0 KAOL
«
~
KAOL « «
v I v v
FEF OSIL KAOL I
(!) I (!) (!)
I
~ 6.13 ~ 4.13 3-2.13
10.0 12.13 14.0 16.0 5.0 7.0 9.0 11.13 2.0 4.0 6.13 8.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
c:;J 22.13 I c:;J 20.0 c:;J 1 4 . ar-~~-~~~----,
FORST
: 7-A CL I **
,....
:
,....
I FORST

~ 18.13 I /' ':;:' 16.13

I
':;:' 113.13
~« I- - -~-I -0-
J:
v
«
I
7-A CL I
J:
v 7-A CL
- - - -c

0
ANTIG I « ~
v v
~ 14.13 [TALC I ~ 12.0 ~ 6.13
b, +
f
+ 1--'-- + TALCJ-
+ + ANTI +
(!) FAY
~
(!)
I FAY 1:
v 113.13 KAOL v 8.0 TALd b 1:
v 2.13 KAOL
~ I « I FAY «
v v
(!) FEFROSIL I KAOL I
(!) (!)

~ 6.13 ~ 4.13 3-2.0

113.13 12.13 14.13 16.13 5.13 7.13 9.13 11.13 2.13 4.13 6.0 8.13
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
c:;J 22.13 I c:;J 213. ar-~~---r-~~----' c:;J 14.0
I
* FORST
: I FORST
: 7-A CL
*
---/rJ
,....
" I
~18.a I / ';' 16.13
J: ';'113.13 ~
«~ -0-
v 7-A CL ~ 7-A CLI
ANTIG «
~ 14.13 fTALC I
v
~ 12.13
v
~ 6.0
r-f'TALC - -c - -
+ -'---- r---
o I FAY
+
+
(!)
fANTIG
-0-
o
+ I
FAY
J I
b
1: 1:
~ 113.13 v
«
8.13 FAY ~ 2.13 KAOL
;:; KAOL U
v KAOL b
(!) (!) I (!)

~ 6.13 ~ 4. a '---~--L.-...L.~~",,--, 3-2.13

.1
113.13 12.13 14.0 16.13 5.0 7.13 9.0 11.0 2.0 4.0 6.0 8.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)

Phase relations in the system HCI- H 20 - Al 20 3 - FeO - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A cli-
nochlore. Saturation limits: brucite (a), ferrous oxide (b), spinel (c).
 89
~ 10.0 ~ 10. 0.---~-~-~---, ~ 10.0
I * * I
**
FORST I
"'; 8.0 "* I "* I

--y
'; 8.0 FORST '; 8.0 I
b
~ ~ /
J: 7-A CL J: FORST
ti
v v
« «

1
v v
f- - -C-
;::; 6.0 ;::; 6.0
+ TALC , I
6 .0 !~ ~L_.~C_ + I

-f--'
+ + -C-
(!)
::E:
I ~ f-l--I
(!)
::E:
~ 4.0 I FAY ~ 4.0 TALC I FAY ~ 4.0 TALC I FAY
v KYA v v
I KYA I (!) SILL
5 2. 0
(!) (!)
I I L....-~~_..u.~~---J
52.0 52.0
0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 10.0 ~ 10.0 ~ 10.0
I ...
**
FORST I *
"'; 8.0
I
"';* 8.0 FORST
I "';* 8.0 FORST

-~:-~-v ~/
J: J: J:
v v v
« « « I
v v v
b
r-
;::; 6.0 ;::; 6.0 ;::; 6.0
+
+ ,-tTALC I +
+
7-A CL-Y_C_ ..., +
+ TALC
I
(!)
::E:
I
I FAY
(!)
::E:
AL 'I
FAY
(!)
::E:
4.0
,
~ 4.0 ~ 4.0 I v
« I FAY
v v v
KYA I AND I SILL
(!) (!) (!)
I I
52.0 52.0 52.0
0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 10.0 I ~ 8.0 I ~ 5.0
* * ...*
"';* 6.0
I
"*
FORST I
FORST I "'; 3.0
'; 8.0 b

V
FORST I
J:
v
/ J:
v
J:
v

~A_C~ ~_ I=--~~J=-~-=-.:,~
«
v
«
v
«
v
;::; 4.0 ;::; 1.0
·,f-
;::; 6.0 _ : 7-A CLJ_:
+ C' + + -C-
+ _A _ _ _ + 'AI 'I -C- - +
(!) (!)
FAY
(!) CORD I FAY
::E: LTALC I FAY ::E:
I ::E:
~ 4.0 ~ 2.0 ~1.0 AND
v I v AND I v
AND I
(!)

52.0
0.0 2.0 4.0 6.0
I (!)

50.0
-2.0 0. 0 2 .0 4. 0
I
3-3. 0.L-~~~.......J..L......I-.J
0 -3.0 - .0
-~ .0 I I
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~9.0 I ~ 1.0 ~4.0
......
* * I
"';* 7.0 ""*+-1.0
FORST I
I "';-6.0
~
FORST FORST
J: J:
b J:

Y
v v v
« « «

~: ~L_-;¥
v v v
;::; 5.0 ;:::-3.0 fA , C ;:::-8.0
+ __ + +
+ + I +
(!)
::E: I--t--
TALC IFAY
(!)
::E: IFAY (!)
::E:
v-10.0
CORD=.i FAY
~ 3.0 ~5.0 AND AND
v I v
I «
v
(!)
A.~D
I (!) I (!)

5 1.0
-2 . 0 0. 0 2.0 4.0
3-7.0
-9. 0 -7.0 -5.0 -3.0
3-12.0L....---~-~~-----J
- I 3.0 - I I .0 -9.0 -7.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
Phase relations in the system HCI-H 20 - Al 20 3 - FeO - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A cli-
nochlore. Saturation limits: brucite (a), ferrous oxide (b), spinel (c).
 90
~ 22. er-~~--.....,-~..., ~ 213. er--~~--....,...-~..., ~ 14. ef===~;====9
:I<
:I<
:I<
:I<
b : FORST j b
""+
--o-y
I
"+ "I+
" I
18.13 14-A CL 16.13 113.13 14-A CL I
I I

-o--y
v v 14-A CL I v
« - -0·- « I «
v v
:::; 12.13 :::; 6.13
+ +
I +
(!)
+
(!)
FAYI l: 1: FAY
~ 113.13 aTZ ~ 8.13 v 2.13 KAOL
IFAY «
v I KAOL v
FE SIL I I
(!) (!) (!)
I.
36.13 34.13 5-2.13
113.13 12.13 14.13 16.13 5.13 7.13 9.13 11.13 2.13 4.13 6.13 8.13
LOG CACFE++)/(ACH+))**2) LOG (ACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 22. er--~~----""'-~..., ~ 213.13 ~ 14.13 ~
b
:I< :I<
:I< I :I< : FORST I

--o--y
""+ 18.13
14-A CL I "~ 16.13
I "
~ 1e . e 1 4-A CL I
I
I I
..l-
~
v - -0- - v 14-A CL
«
v
«v
~ 14.0pN~{ :::; 12.13 :::; 6.13
- -0--
+
(!)
I
+
+
(!)
T t 0
1:
v 113.13 KAOL
FAYI l:
v 8.13 ~2.e KAOL I FAY
«
v I «v FAY «
v
KAOL I
(!)
FE SIL I (!) (!)
I
36.13 34.13 5-2.13
10.13 12.13 14.0 16.13 5.13 7.13 9.13 11.13 2.13 4.13 6.13 8.13
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 22. 0r-~~--"""--~-' ~ 213. er-~~-....--~...,
~ 1 4 .er=A-====;===::::::j
:I< :I<
:I< :I< : tFORST I
""+ I
I
18.13 14-A CL
- -0- -1-
"+
I
16.13
14-A CL I
" 113.13
± 14-A cyl
--0-/
v v
« ~
~ fTALC
«
v
:::; 12.13
b :::; 6.13
'--c--l---,
" 14.13
+
+
b +
+ + I
(!)
I (!) ct b FAY
1: FAY 1: l:
~ 10.0 KAOL ~ 8.13 ~ 2.13 KAOL
I FAY
v KAOL
(!)
FE OSIL I (!) (!)
I
36.13 34.13 ,/
5-2.13
113.13 12.13 14.13 16.13 5.13 7.13 9.13 11.13 2.13 4.13 6.13 8.13
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 22. er-~~-......,,......-~-' ~ 213. er--~~-....--~-, ~ 14. 13 r--~~-=-=O::R=-=T~--'
*
:I< :I<

"*
:I< :I<

--or
"+ ""+ I
18.13 14-A CLI 16.13 "I+ 113.13 1'4-A CL
I
v -0- .J v
I
14-A CL I v q
b
« « «
v
:::; 14. 13 TAL~
v
:::; 12.13
v
:::; 6.13
-c· I"
+ b +
+
+
+ I FAY +
(!)
l:
(!)
l:
(!) FAY
l:
v 113.13 ~ 8.13 FAY ~ 2.13
« KAOL KAOL
KAOL
(!) (!) (!)

36.13 34.13 5-2.13

113,13 12.13 14.13 16.13 5.13 7.13 9.13 11.13 2.13 4.13 6.13 8.13
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

Phase relations in the system HCl- HzO - Al z0 3 - FeO - MgO - (SiO z) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable chrysotile was considered instead of its stable counterpart, antigorite. Sa-
turation limits: brucite (a), ferrous oxide (b), spinel (c).
 91
~ 10. 0r-~~--~~----' ~ 10.0 ~ 10. 0.--~~--~~---.
: I * FORST I
*
""*+ 8.0 "'.;'* 8.0
I
::: I

-7
FORSTI

CL.V
+ 8.0 b
b
14-A CL
J: J:
v
J:
v ~
j r-- - -C- - 1- <0(
v
<0(
v
I

I
~
~ 6.0 ~ 6.0 14-A ~ 6.0
+ + - -C- - - - + 14-A CLI
+ +
t!)
+ - -C--
~ I ::E
t!)
::E FAY
~ 4.0 IFAY ~ 4.0 I FAY ~ 4.0
v KYA I v
KYA I
v
SILL
t!) t!) t!)

g 2.00.0 2.0 4.0 6.0

I
g 2.00.0 2.0 4.0 6.0
I.
g 2.00.0 2.0 4.0 6.0
LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2)
~ 10. 0.--~~--~~---. ~ 10.0 ~ 10.0
* I * FORST *
"~* 8.0 14-A CL
0I "'.;'* 8.0 "*
'.;' 8.0 FORST I
I
J:

-YI ~~6.0 ~ ~
v

~
<0(
v
" 6.0
- - -C- ~ 6.0
.

./ .
+
+
~
~ 4.0 KYA
I
I FAY
+
+
t!)
::E
~ 4.0 FAY
i
~ 4.0
~t~ -=LV- --
/1 FAY
v I v
AND v SILL I
§ 2.00.0
t!) t!)

g 2.00.0 2.0 4.0 6.0

I
g 2.00.0 II
2.0 4.0 6.0 2.0 4.0 6.0
LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2)

~ 10. 0r:r-=A===:::r::===1 ~ 8.0 I ~ 5.0

** *
: lFORST I I
"'.;'* 3.0
FORS-rl
" ""+ 6.0 I FORST I
~8.0 14-A C L v
l
v
J: J:
v t>
/
f _ _~:A~L_V
<0( <0( I

~6.0
v v
~ 4.0 ~ 1.0 C- ~-~ £k.~r- -
--C-_ + +
+
t!)
+
t!)
+
t!) CORD-=.f I
::E I ::E FAY
~ 4.0 I FAY ~ 2.0 FAY ~1.0 I
v AND I v AND I v AND
I
t!) I t!) I (!)

32.0
0.0 2.0 4.0 6.0
g 0.0
-2. 0 0. 0 2. 0 4 .0
3-3.0
I
-'5. 0 -3 .0 -1.0 1 .0
LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2)
~ 9.0 ~ut<~ ~ 1.0 ~4.0

** ** *
I
"'.;'
I
"';-1.0
FORST
*
"';-6.0

_~~:_C~-y
I
7.0 0 FORST
J:
v
<0(
v
I J:
v
<0(
v 14-A CL_y-
b J:
v
<0(
v
14-A
~ 5.0 ;::-3.0 ~--C--- - ;::-8.0
+ + I +
+
t!)
+
(!)
+
(!)
::E WAY ::E FAY
~ 3.0 I FAy ~5.0 AND ~10.0 AND
<0(
v I v
I v
AND
(!) I (!) I (!)

g 1.0
-2.0 0.0 2.0 4.0
3-7.0
-9.0 -7.0 -5.0 -3.0 3-1.E!d'.L.0-_-I-I~.~0-_..J.9J....0-~_7...J. 0
LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»MM2) LOG CACFE++)/CACH+»MM2)

1;»hase relations in the system HCI-H 20-AI 20 3 -FeO-MgO-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable chrysotile was considered instead of its stable counterpart, antigorite. Sa-
turation limits: brucite (a), ferrous oxide (b), spinel (c).
 92
~ 22.0 ~ 20 . 0r--~~-~-""-~-' "N 14.0
7-A CL
I
* FORST FORST 1
** I
* '*" t-
"+ "+ "+
_C~~Y~y
18.0 16.0 10.0
I I I 7-A CL
v
«
v
v
~ 7-A CL b v
«
v
- -O- f-
"- 14.0 ~ 12.0 I ~ 6.0
"+ TALC b t -CHRYS -0- + TALCj
I
+ I + b
(!)
1:
v 10.0
IFAY ~
~ 8.0 TALC
=l; 1
FAY
(!)
1:
v 2.0 KAOL
I FAY
« aTZ «
v 1 v v
(!) FEF RJSIL 1 (!) KAOL (!)

36.0 34.0 5-2.0

10.0 12.0 14.0 16.0 5.0 7.0 9.0 11.0 2.0 4.0 6.0 8.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+)**2)
~ 22.0 ~ 20.0 FORST "
N
14.0
FORST
* 7-A CL: ** ** 1

"*
"+
I
v
«
18.0
a_-"H~y
"+
I
v
«
16.0
7-A CL
?
1
"+
I
v
«
10.0
7-A CL
-j
1
-0
v v v

b
I

-TALC:-:l,~ j' ?
~ 14.0 ~ 12.0 ~ 6.0
TALC + +
+ TALC
+ I + +
(!) (!) (!) FAY
1: 1 FAY 1: 1:
KAOL
v 10.0 KAOL v 8.0 FAY v 2.0
« « 1 «
v 1 v KAOL
(!)
FE)'; RpSIL 1 (!) 1 (!)

36.0 34.0 5-2.0

10.0 12.0 14.0 16.0 5.0 7.0 9.0 11.0. 2.0 4.0 6.0 8.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/(ACH+))**2) LOG CACFE++)/CACH+))**2)
~ 22.0 ~ 20.0 FORST "N 14.0

*'" ** 1 FORST
* 7-A CL
"':;'* 18.01------+---/ "+ 16.0
I
b "+ 10.0
I I I I 1
v - - -0- 1 v
7-A CL v 7~A _C,=- ~
« CHRYS « 1 «
v
b v v

T";:ci~
~ I 4 . 01-nrr-r...--,r' I ~ 12.0 ~ 6.0
+ + +
+ 1 FAY + +
(!) (!) (!) FAY
1: 1: 1:
1 8.0 2.0 KAOL
~ 10.0 KAOL v
« FAY v
«
1 1
v KAOL
(!) FE OSIL 1 (!) 1 (!)

36.0 34.0 5-2.0

10.0 12.0 14.0 16.0 5.07.09.011.0 2.0 4.0 6.0 8.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
;:::.; 22. 0.-~~-~~-~-, ;:::.; 20.0 "N 14.0
FORST
*'" * 1
,...: 7-A CL 1 FORST
"" I
""* 1

± I 8 . 0 r--------,----,
,... 1
+ 16.0 bI + 10.0

~-~~-
I I
~ CHRY~-O v
«
v
7-A CL
v
«
v
~ 14.0 b "- 12.0
"+ -0-
~ 6.0
+
TALC
~'I
62: I FAY +
(!) TALCl. +
(!) I FAY
~ 10.0 KAOL
1:
v 8.0
1:
v 2.0 b
« FAY « KAOL I
v KAOL 1
(!) (!) (!)
I
36.0 34.0 5-2.0
10.0 12.0 14.0 16.0 5.0 7.0 9.0 11.0 2.0 4.0 6.0 8.0
LOG CACFE++)/CACH+)**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

Phase relations in the system HCl-H 20-AI 20 3 -FeO-MgO-(Si0 2) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A c1inochlore and chrysotile were considered instead of their stable coun-
terparts, 14-A c1inochlore and antigorite. Saturation limits: brucite (a), ferrous oxide (b), spinel
(c) .
 93
~ 10.0 ~ 10.0 ~ 10. 0r-~--~~---'
FORST I I
* * *
"';'* 8.0 "';'* 8.0 FORST
I "';'* 8.0
?/
I
:I: :I: :I: FORST
v
«
v __ 7~~_C=- ~y v
«
v
v
«
v

.J~ .fL_ ;/-c-

~ 6.0 ~ 6.0 ~ 6.0
+ TALC , I + +
+ + +
(!)
z:
~ 4.0
IFAy
I
(!)
z:
~ 4.0 TALC
3- 1I FAY
(!)
z:
~ 4.0 TALC:j-1 FAY
v
KYA v v
I KYA I I
SILL
32. 0 L-_~~""""'__~
(!) (!) (!)

32.0
I
32.0 '-
0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0
LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2)
~ 10.0 ~ 10.0 ~ 10 .0r--~~--~---'
I I
* FORST * *
"';'* 8.0
I
"* I "';'* 8.0
~ 8.0
?
FORST

__7;~ ~L_J(
I
:I: :I: FORST I

_~-A~J;~
v v v
« « «
v
~ 6.0
v
~ 6.0
v
~ 6.0 ~
+
+ j_ I +
+
rAI
+
+
(!)
(!)
z: TALC I FAy (!)
z: 'I z:
4.0 FAY 4.0
~ 4.0 I ~ I ~ FAY
v v v
I AND I
(!) KYA (!) (!) SILL
I I
32.0 32.0 32.0
0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0
LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2)
~ 10.0 T ~ 8.0 I ~ 5.0
* * *
""+* 3.0
I
"';'* 8.0 "*
FORST I
b ';' 6.0 FORST I

CLJV
FORST
:I:
v
/ :I:
v
:I:
v b
_~~_C:,~ .~
«
v
«
v
«
v
~ 6.0 ~ 4.0 7-A ~ 1.0
+ + AI ~I-C- - +
+ + + -£CORD
(!)
TALC=V I FAY
(!)
z: FAY
(!)
z: I FAY
~ 4.0 ~ 2.0 I ~1.0
« AND I
v AND I v AND I v
I
(!) I (!) I (!)

32.0 30.0 9-3. 0 L..-~~_....u.I~---I

0.0 2;0 4.0 6.0 -2.0 0.0 2.0 4.0 -5.0 -3.0 -1.0 1.0
LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2)
~9.0 I ~ 1.0 ~4.0

* * *
"';'* 7.0 "* ""*r6.0
FORST I
FORST I
9 ';-1 . ~
?
FORST

,¥ }:
:I: :I: :I:
v v v
« « «
__6__A~L_
v v v
~ 5.0 ;:::-3.0 ;:::-8.0
+ + +
+ + +
(!) (!) TALCj : FA' (!) tCORD FAY
TALC:3- IFAY z:
~ 3.0 ~5 . 0
« AND ~10.0
« AND I v v AND
v
(!) I (!) (!)

9-7.0 9-12.0L-~~-~~~~
31.0 -9.0 -7.0 -5.0 -3.0 -13.0 -11 .0 -9.0 -7.0
-2.0 0.0 2.0 4.0
LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2) LOG CACFE++)/CACH+»**2)

Phase relations in the system HCI-H20-Ah03-FeO-MgO-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore and chrysotile were considered instead of their stable coun-
terparts, 14-A clinochlore and antigorite. Saturation limits: brucite (a), ferrous oxide (b), spinel
(c).
94
~ 16.0 ~ 12. 0,...~~....~~~~--, ~ 10. 0r-~~~,......~~~-'

14~
* * *
"* PHLOG ""*+ 10.0
PH LOG "*
';' 8.0
';' 14.0 CL J:
J: J:
v v v
<t
v
f-
',----.
-0- f-
<t
v
<t
v
~ 12.0 ~ 8.0 ~ 6.0
+ + +
+
t!)
GIBBS +
(!)
+
t!)
1: 1: KAOL 1: KAOL
v 10.0 ~US( v 6.0 US ~ 4.0 USC
<t <t
v ,,-SPAR v v
K- PA
t!) (!) t!)

0 8 0 ~ 4.0 O 2 0
...J • 0.0 3.0 6.0 9.0 -2.0 1.0 4.0 7.0 ...J '-3.0 0.0 3.0 6.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))
~ 16.0 "
(\J
12.0 ~ 10. 0r-~~~,......~~~-'

** ** *
""*+ 8.0
PHLOG PHLOG
14-A ""
';' 14.0 CL + 10.0
J:
v v
J: 14-A CL v
J:
14-A
<t
v I- -o- j:- <t
v
<t
v
~ 12.0 ~ 8.0 -0- - ~ 6.0
+ KAOL + +
a
+ + KAOL +
t!)
1: ~US(
(!)
1:
t!)
1: KAOL
~ 10.0 ~ 6.0 US ~ 4.0 USC
K-SPAR K SPA v
t!) t!) t!)
K- PA
~ 8.0 ~ 4.0 O 2 0
0.0 3.0 6.0 9.0 -2.0 1.0 4.0 7.0 ...J '-3. 0 0. 0 3 .0 6.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))
~ 16.0 ~ 12.0 ~ 10.0
* PHLOG * *
""+* "';'* "';'* 8.0
14-A PHLOG
14.0 CL 10.0 PHLOG
J: J: J:
v r-.. v 14-A CL v
14-A
«
-
-
<t f- - 0 - t- <t
v v v
~ 12.0 ~ 8.0 I- 0- ~
~ 6.0
+ KAOL + + 0 :::..
+
t!)
+
(!)
KAOL +
(!)
1: US l:
USI
1: KAOL
~ 10.0 ~ 6.0 ~ 4.0
v v v
K-SPAR K SPAF K PA
t!) t!) (!)

~ 8.0 ~ 4.0 o
0.0 3.0 6.0 9.0 -2.0 1.0 4.0 7.0 ...J 2._03 . 0 0.0 3.0 6.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))
~ 16.0 ~ 12.0 ~ 10. 0r-.............."\'---...-......,
* * **
"';'* "';'* 10.0
PHLOG
":t" 8.0
14-A PHLOG
14.0 CL PHLOG
J: J:
v v 14-A CL v
« ~ « « 14-A CL
v I- - 0 - - v v
~ 12.0
+
+
(!)
KAOL
~ 8.0
+
+
(!)
0
KAOL
-=-=-= ;::: 6.0
+
+
(!)
l: US l:
~ 10.0 ~
«
6.0 ~US ~ 4.0
v K-SPAR v v
K SPAR
(!) (!) (!)

~ 8.0
0.0 3.0 6.0 9.0
g 4.0
-2.0 1. 0 4. 0 7.0
~ 2.0
-3.0 0.0 3.0 6 .0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG CACK+)/ACH+))
Phase relations in the system HCl- H20 - (AI 20 3) - K20 - MgO - Si02 in equilibrium with
quartz. Saturation limit: talc (a).
 95
;:.:; 8.0 ;:.:; 8.0 ;:.:; 8.0

~
14-A~
,..,** PHLOG
,..,** PHLOG ,..,**
':; 6.0 ':; 6.0 ':; 6.0
J: 14-A C J: J: 1 4 - i PHLOG
v v v
4: 1-0--"""'- 4: 4:
v v v
;::; 4.0 ;::; 4.0 t - 0 - ;::; 4.0 1-0~;--~~"--""1

+ PYROPH + +
+ + KYA +
(!)
SILL
(!) (!)
:1: :1:
v 2.0 ~US( ::;;: 2.0 ~ US ~ 2.0 M C
4: 4:
v v
v K-SPAR K-SPAR K-SPAR
(!) (!) (!)

30.0 '" 30.0 8 .'"

'" 30.0
-1.0 2.0 5.0 8.", -1.0 2.0 5.0 -1.0 2.0 5.0 8.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
;:.:; 8. 0 ;:.:; 8.0

14-1
;:.:; 8.0 I~"\"~~~~~'

~
,..,** PHLOG ,..,** PHLOG ,..,**
':; 6.0 ':; 6.0 ':; 6.0
J: 14-A J: J: PHLOG
v v 14-A C v
4: 1-0----- 4: 4:
v
;::; 4.0 ~o=-=-=-n---"
+ PYROPH
+
(!) SILL
:1:
v 2.0 ~US( Ml5C
4:
v K-SPAR K-SPAR
v
K-SPAR
(!) (!) (!)

30.0 30.0 30.0

-1.0 2.0 5.0 8.0 -1.0 2.0 5.0 8.0 -1.0 2.0 5.0 8.0
LOG (ACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
;:.:; 8.0 ;:.:; 8.0 ;:.:; 4.0

14~
* * *
"*
"J:+ 6.0
PHLOG
"*
"J:+ 6.0 "':;* 2.0 PHLOG
PHLOG
v
CL v
J:
v
4: 4: 4:
v v
;::; 4.0 t-o~ -- ;::; 0.0
+ +
+
(!)
AND +
(!)
:1: :1:
v 2.0 US v-2.0
4:
v
4:
v
K-SPAR
K-SPAR C AND
(!) (!) K-SPAR (!)

30.0 30.0 3-4.0

-1.0 2.0 5.0 8.0 -1.0 2.0 5.0 8.0 -1.0 2.0 5.0 8.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
;:.:; 8.0 ;:.:; 0.0 ~6.0

I~
* ** * \ 14-A CL
"* ""*-1-8.0 .1--/
""£2.0
PHLOG
':; 6.0 PHLOG \ PHLOG
J: J:
~~
v
4:
v
CL
·U
v
4:
v r-=-+-
~4.0 ~10.0 CORD
+ +
~-.;:,...---~
+
(!) AND +
(!)
AND :1: :1:
~6.0 M C ~12.0
US v v AND K-SPAR
(!)
K-SPAR (!)
K-SPAR (!)

30.0 3-8.0 3-14.0~~~~~~~~~

-1.0 2.0 5.0 8.0 -1.0 2.0 5.0 8.0 -1.0 2.0 5.0 8.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/A(H+))
Phase relations in the system HCl- H20- (Ah03) - K20- MgO-Si02 in equilibrium with
quartz. Saturation limit: talc (a).
96
~ 18.B
** 7-A CL ~14.121 ~ ~ 112I.12lr-~--.\,""-~----'

A
Y PHLOG
*
~
7-
CL PHLOG ~ 7-A CL\ PHLOG
± 6.121 -=-=-_
A
+ 14.0 + 10.121
1:
~----
o- - i:::-=.-
I
~ I- - 0 - ::::-::::--- r - - -
-0-

'-' v v
;::: 10.0 ;::: 6.121 ;::; 2.121
+ GIBBS + + K SP R
+ + + KAOL
t') K-SPAF t') KAOL -SPAR t')
L L L
'-' 6.0 ~USC v 2.121 ~2.0
« « ~USC :USC
t') (!) t')

~ 2.0 3-2.121 3-6.121

L\
0.0 3.0 6.0 9.0 -2.0 1 .121 4.0 7.0 -3.121 121.121 3.121 6.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
~ 18.0
~14.121 ~ 1121.121 1\
<
** \7-A CL
* 7-A PHLOG ~ ~-A CL ~ PHLOG

-----
A PHLOG CL
"+
A
14.121 + 1121.0
I f - - - - '______
-:;: 6.121 0 -~;--
1: I
v f- -0- t-- v
« ~ r- -0- - ::::---""r--
«
v v v
;::: 10.121 ;::: 6.121 ;::: 2.0
+ + + KAOL
+ KAOL + KAOL + K SP,R
t') K-SPAF (!)
K-SPpR t')
L L L
~ 6.0 USC ~ 2.0 USC ~2.121 ~USC
v v
(!) t') t')

S 2.121121.121 3.0 6.121 9.121

3-2.121
-2.121 1.121 4.121 7.0
3-6.121
-3.121 121.121 3.121 6.121
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
~ 18.0 ~ 14.0 A
1121.121
f\ 7-A
,~
N
**
./
CL
PHLOG
*
"* CL PHLOG
** 7-A C~. PHLOG
"+ 14.121 t---\....---.. "+ 1121.121 -:;: 6.121 o -::::---r--
I
v f- -0- t=- I
f---O:-
I
v
« «
v v v
;::: 1121.0 ;::; 6.121 ;::: 2.121
+ + +
+ KAOL + + KAOL K Sp, R
(!)
L
K-SPA~ t') KAOL K-SP R (!)
L L
~ 6.121 US v 2.121 ~2.121
« USC ~USC
v
(!) t') (!)
O 2 0 3-2.121 3-6.121
--l • 121.121 3.0 8.121 9.121 -2.121 1 .0 4.121 7.121 -3.121 121.121 3.121 6.121
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
~ 18.121 ~ 14.121 ~ 1121.0
** y'\
'\I-A CL
PHLOG **
** ~ PHLOG
--
CL \ 7-A CL
"+ 14.121 -:;: 1121.121 ' P"LOG -:;: 6.121
1:
v
«
v
'-----'-0-
----:::- I
v
«
v
t-- -0- -
,
I
v
«
v
o ~,-

;::; 1121.0 ;::: 6.121 ;::: 2.121

+ + +
+ KAOL K-SPAR
+
KAOL + PYROPH
(!)
L
t')
L
K-SP R (!)
L
K SPAR
v 6.121 ~ US ~ 2.121 ~2.121
« USC '1USC
v v
(!) (!) t')

~ 2.121 3-2.121 3-6.121

121.121 3.121 6.121 9.121 -2.121 1 .121 4.0 7.121 -3.121 121.121 3.121 6.121
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

Phase relations in the system HCI- H 20 - (AI 20 3) - K20 - MgO - Si02 in equilibrium with
quartz. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A clino-
chI ore. Saturation limit: talc (a).
 97
~
:I:
:I:
,....
1121.121

':;' 6.121
:z::
v
<{
7-A\
CL
r-
PHLOG

0
~
*
"*
~ 6.121
v
<{
1121.121

,-\-
CL
r- ·U
PHLOG
~1121.121
,....
':;' 6.121
:z::
~ F
\
7-A
CL
t: CORD --"..
PHLOG

,..--0-
v v v
;:::; 2.121 ;:::; 2.121 ;:::; 2.121
+ + +
+ PYROPH + +
(!) K-SP R (!) KYA K-SP R ~ SILL K-SPA~
1:
~2.121 USC 4'2.121
f"~S 3"2.121 Ml C
v v
(!) (!) (!)

5-6.121 5-6.121 5-6.121

-2.121 1.121 4.121 7.121 -2.121 1.121 4.121 7.121 -2.121 1.121 4.121 7.121
LOG CACKT)/ACHT)) LOG CACKT)/ACHT)) LOG CACK+)/ACHT))
~ 1121.121 ~ 1121.121 ~ 1121.121

7-~
:I: :I: :I:
:I:
PHLOG :I:
7-A PHLOG ,....
:I:
7-A
CL CL CL PHLOG
':;' 6.121 "+ 6.121 ':;' 6.121
:z::
v 0- - :z::
v
:z::
v
0
<{
v
<{
v
CCORD- <{
v -tCOR;:~
;:::; 2.121 ;:::; 2.121 ;:::; 2.121
+ + +
+ PYROPH + +
(!) K-SP R (!) AND K-SP R (!)
SILL K-SP R
1: ::E ::E
4'2.121 ~ USC 4'2.121 4'2.121
v v MS v MU C
(!) (!) (!)

5-6.121 5-6.121 5-6.121

-2 . 121 1 .121 4 . 121 7.121 -2.121 1.121 4.121 7.121 -2.121 1 .121 4 . 121 7.121
LOG CACKT)/ACHT)) LOG CACKT)/ACHT)) LOG CACKT)/ACHT))
~ 1121.12Ir--~---~---' ~ 1121.121
:I: :I:
,....
:I:
7-A PHLOG ,....
:I:
"

~
':;' 6.121 CL ":z::+ 6.121 PHLOG ':;' 6.121
:z:: :z:: PHLOG
v =- 0 v v
<{
ECORD~ <{
v
<{
v
v
-0 CL
;:::; 2.121 ;:::; 2.121 ;:::; 2.121
+ + +
+ + + -o~---
(!)
AND K-SPA (!)
::E
(!)
CORd
1:
v-2.121 4'2.121 AND K-SPA 5..2 121
<{ S
<{ •
AND K-SPAR
v v M C v
(!) (!) (!)

5-6.121 5-6.121 5-6.121

-2. 121 1 .121 4. 121 7 . 121 -2.121 1.121 4.121 7.121 -2.121 1.121 4.121 7.121
LOG CACKT)/ACHT)) LOG CACKT)/ACHT)) LOG CACKT)/ACHT))
~ 4.121 ;;;4.121
:I: :I: \ 7-A
,.... :I: :I:
lS.CL
PHLOG PHLOG PHLOG
':;' 6.121 ~ 121.121 ';-8.121
:z::
v
:z::
v
:z::
v
F E -=::--:"'-0-
<{ <{ <{ CORD
v v v
;:::; 2.121 ~4.121 ~12.121
+ + +
+ +
(!)
+
(!)
(!)
AND K-SPA ::E AND ::E AND K-SPAR
5..2.121 4'8.121 K-SPAR v-16.121
<{ <{
MS v MU C v
(!) (!) (!)

5-6.121 5-12.121 5-2121.121

-2.121 1.121 4.121 7.121 -2.121 1.121 4.121 7.121 -2.121 1.121 4.121 7.121
LOG CACKT)/ACHT)) LOG CACKT)/ACHT)) LOG CACKT)/ACHT))
Phase relations in the system HCI- H 20 - (Ah03) - K20 - MgO - Si02 in equilibrium with
quartz. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A clino-
chlore. Saturation limit: talc (a).
 98
~ 18. 0r-~~-~~-~-' ~ 12.0 ~ 10.0

**
r.. 14-A CL **
r.. **
r..
14-A CL

':;: 16.0 ':;: 10.0 ':;: 8.0 0- - -

I I I
v v v
« « «
v
v v
.-/
~ 14.01----:-c-:::c::::-:::-,' ~ 8.0 ~ 6.0 ~--
+ +
+
+
+
+
(!) (!) (!) KALS
1: 1: 1:
v 12.0 ~ 6.0 MUSC v 4.0 Muse
« «
v
v v KAOL KAOL
(!) (!)

3 10. 0'--~....J.o.-~~-L--'
(!)
0 4 0 O 2 0
0.0 4.0 8.0 12.0 ...J '-2 .0 2 .0 6.0 10 .0 ...J '-2.0 2.0 6.0 10.0
LOG (A(K+)/A(H+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
~ 18. 0.--~~-~~-~--, ~ 12.0 ~ 10.0
**
r..
14-A CL **
r..
**
r.. 14-A CL
0- - - - -
':;: 16.0 ':;: 10.0 14-A CL ':;: 8.0 0- - -
I I I
v v v
« « ~
«
v
v \.ANTIG; v
~ 8.0 ~ 6.0
--------
~ 14.0 -\

(!)
t ITT~AL~e~/~----~' +
+
(!)
+
+
(!)
KALS
1: 1: MUSC 1:
v 12.0 Muse v 6.0 v 4.0 Muse
« « «
v v KAOL v
KAOL
KAOL (!)
(!) (!)
3 10. 0'--~......L-~~-.L--' 34.0 32.0
0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOG (A(K+)/ACH+)) LOG CACK+)/ACH+)) LOG (ACK+)/ACH+))
~ 18 .0r-~~-~~-~.., ~ 12. 0.--~~--~-~--, ~ 10. 0r-~~-~~-~-,

** 0- - -- **
r..
r..
0- - --
14-A eL
**
r.. 14-A eL
':;: 16.0 + 10.0 ':;: 8.0 b- - -
I
v 14-A CL I
v
I
v
« PHLOG « «
v v v
~ 14.0 ~ 8.0 ~ 6.0
t rr.IT?~------1 +
+
LS +
+ KALS
(!) (!) (!)
1: Muse 1: MUSC 1:
~ 12.0 ~ 6.0 ~ 4.0 Muse
v v KAOL v KAOL
KAOL
(!) (!) (!)
3 10. 0'--~.....L._~~---J"--...J 0 4 0 32.0
0.0 4.0 8.0 12.0 ...J '-2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOG CACK+)/A(H+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
~ 18. 0.--~~-~~-r-.., ~ 12. 0.--~~-~~-r---, ~ 10. 0r-~~-~~-~-,

r..
** 14-A CL **
r..
0- - --
**
r..
0-----
':;' 16.0 ':;: 10.0 14-A CL ':;: 8.0
I I I
v v v
« « « b-
v v v
~ 14.0 ~ 8.0 ~ 6.0
+ + +
(!)
+ +
(!)
+
(!)
1: 1: Muse 1:
~ 12.0 ~ 6.0 ~ 4.0 Muse
v v v KALS
KAOL KAOL
(!)
3 10 . 0 L--~-'-'-_~~----L~--'
(!) (!)

34.0 32.0
0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0 -2.0 2 0 6.0 10.0
LOG CACK+)/ACH+)) LOG CA(K+)/ACH+)) LOG (A(K+)/A(H+))

Phase relations in the system HCI- H 20 - Al 20 3 - K20 - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limits: brucite (a), spinel (b).
 99
~ 10. 0r-~~-~-----' ~ 10. 0r--~~-----~ ~ 10. 0r--~~----~~
* FORST *
** ""* *
"" FORST
':;:' 8.0 14-A CL "I+ 8.0 ':;:' 8.0
I
I
v V 14-A CL V
« «V «
v V

~6 0 ~ 60 p OG ~ 6.0
+
+ f---~-
+
+ b- - +
+
(!) (!) (!)
L L L
v4 0 MUSC V 4.0 V 4.0
« KALS
« US «
KYA
V
KALS V

(!) (!) KYA (!)

S 20
-2. o 2.0 6.0 10.0
S 20
-2.0 2.0 6.0 10.0
S 20
-2.0 2.0 6.0 10.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

"
N
10. 0 ~ 10. 0r-~~------' ~10 .0
* **
FORST *
"*
':;:'8 0 14-A
""
':;:' 80
"*
':;:'8 0 FORST
I I I
v V V
« « 14-A «
v b- - - - V V

~ 6. 0 ~ 60 ~ 6. 0
+ + b- +
+
(!)
t-----,.~- +
(!)
+
(!)
L L L
v 4. 0 MUSC V 4.0 V 4. 0
« KALS
« «
v V V M
KYA AND
(!) (!) (!) SILL
S 20
-2 . 0 2 .0 6 .0 I 0 .0
S 20
-2.0 2.0 6.0 10.0
S 20
-2 .0 2.0 6.0 10 .0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

~ 10. 01==\:=====:::::j ~ 80 ~4 .0
* \:::::FORST ** *
"':*;:' 8.0
FORST *
"':;:'2 .0
I
v 14-A V
I
V
«
V
« «
V

~ 60 ~0 .0
+ b- - - +
+
(!)
+
(!)
L L
4.0 '-'-2 .0
V
« usc « AND
KALS V

(!) AND (!) AND (!)

S 2.0
-2.0 2.0 6.0 10.0
S 00
-2.0 2.0 6.0 10.0
3-4.0
-2 . 0 2 .0 6 .0 I 0 .0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
~ 10. 0r-~~----~-' ~2 0 ~4 0
* FORST * **
"':*;:' 80 ""* FORST "".y.-6
"I+ 0. 0 I
.0 FORST
I

~
V V
// V
« 14-A CL « «

t-b- - ~-­
V V V

~ 60 ~2.0 14-A CL ~8.0

+ + +
+ + + KALS
b- -
(!) (!) (!)
L L '- KALS L
V
«
4.0 '-'-4.0
« ~10.0 K- AR
f-----:-~ KALS V ~ US V
USC AND AND
(!) AND (!) (!)

S 20
-2.0 2.0 6.0 10.0
3-6.0
-2 . 0 2 .0 6 .0 I 0 .0
3-12.0L-~~-L~~-~~
-2.0 2.0 6.0 10.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

Phase relations in the system HCl- H 20 - Al 20 3 - K20 - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limits: brucite (a), spinel (b).
 100
~ 18. 0r-~~-~~-"""""" r. 12.0 ~ 10.0
N

** ** !,-!, , : L _ /O *
r. r.
r.
f--
*
r. 7-A CL
';:' 16.0 -0 + 10.0 ';:' 8.0 0- - -
J: J: ANTIG / PHLO/ J:
ANTIG v
«
v
«
v v v
~ 14.0 ~ 8.0
~- ~ 6.0 TALC ) - - -
+ TALC ~I +
+ K LS + KALS
+
(!)
+
(!) (!)
1:
56 MUSC 1:
MUSC
v
«
12.0 « .0 v
«
4.0
v v KAOL v KAOL
(!) (!) (!)
o
...J 10 '1. 0 4 .0 8 .0 12 . 0
~ 4.0
-2.0 2.0 6.0 10.0
~ 2.0
-2.0 2.0 6 .0 10 . 0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
r. 18.0 ~ 12.0 ~ 10.0
!-~~L00
N
** **
f-- ** 7-A CL
r.
r. - - -- -0 r. r.
r. 0- - -
+ 16.0 ':;' 10 .. 0 + 8.0
J:
v
ANTIG J:
v
ANTIG / PHLOY J:
v
« « «
v v ~TALC ' v
TALCr--
"-
r. 14.0 ~ 8.0 ~ 6.0
+ + K!A.LS +
+ TALC / + + KALS
(!) (!) (!)
1:
MUSC
1: MUSC 1:
MUSC
~ 12.0 ~ 6.0 ~ 4.0
v KAOL v KAOL
(!)
KAOL (!) (!)
~ 10. 0L-~""""-~~-i..-....J ~ 4.0 ~2.0
0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
~ 18.0 ~ 12.0 ~ 10 .0r-~~-~~-~~

-A:~)-
**
r.
**
r.
- - -0- **
r.
r. r. 7-A CL r. 7-A CL
+ 16.0 + 10.0 + 8.0 b- - -
J: J: J:
v v v
« PHLOG « «
v v v
"-
r. 14.0 ~ 8.0 ~ 6.0
+ ALC/ + +
+
(!)
+
(!)
+
(!)
KALS
1:
12.0 MUSC
1: MUSC 1:
4.0 MUSC
~ ~ 6.0 ~
v
KAOL v KAOL KAOL
(!) (!) (!)
o ~ 4.0 O 2 0
...J 10.Jl."
'" '" 4."
'" 8.0 12.0 -2.0 2.0 6.0 10.0 ...J '-2.0 2.0 6.0 10 . 0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
~ 18.0 7-A CL (:;J 12.0 ~ 10.0
/ 7-A CL
*
* ** *
*
O:N~fL~G-
r. r. 0- - - r.
r. r.
':;' 16.0 + 10.0 + 8.0 7-A CL
J:
v
J:
v
fANTIG J:
v
«
v
« « b- - -
v v

~/ /
~ 14.0 ~ 8.0
(TALC ~ 6.0
+ + + TALC/
+
(!)
+
(!)
+
(!)
1:
12.0 MUSC
1: MUSC 1:
~ ~ 6.0 ~ 4.0 MUSC
v
KAOL K~LS v KAOL v
KAOL KALS
(!) (!) (!)

~ 10.0 ~4.0 ~2.0

0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
Phase relations in the system HCI- H 20 - Al 20 3 - K20 - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A cli-
nochlore. Saturation limits: brucite (a), spinel (b).
 101
r;; r;; r;;

fi
10.0 10. 0.---~---~---, 10. 0r--~--~----'

,...**
FORST
/' ,...** ,...**
78.0
FORST 78.0 FORST
78.0
:I: A :I: :I:
v 7- HLO v
oc(
v
oc(

d
oc(
v -b- - - - - v v
~ 6.0 ~ 6.0 ~ 6.0

,......--r;-" -7:b
+ TALC , - - + + TALC
+
(!)
+
(!)
+
(!)
KALS ::L ::L
- KALS
~ 4•0 ~ 4.0 ~ 4.0
oc(
v MUSC v US v
(!)
KYA (!) KYA (!)
SILL
3 2 ._02 .",
... 2.'"
'" 6.0 10.0 3 2 ._02 • 0 2.0 6.0 10.0 3 2·~2.0 2.0 6.0 10.0
LOG (A(K+)/A(H+» LOG (A(K+)/A(H+» LOG (A(K+)/A(H+»
r;; 10.0 r;; 10. 0r--~--~~---' r;; 10 .0r--~--~---'
FORST *
,...** ,...**
"*
78.0 FORST 78.0
78.0 FORST
:I:
v 7-A CL :I:
v
:I:
v
oc( oc( oc(
v v v
~ 6.0 ~ 6.0 ~ 6.0
+ + 7-~ .£L -b +
+
(!) KALS +
(!)
+
(!)
::L ::L j-~ ::L
v
oc(
4.0 MUSC v
oc(
4.0 TALC US ~ 4.0 KALS
v v v M
KYA AND (!) SILL
(!) (!)
o o 32.0
...J 2 ._02 . 0 2 .0 6 .0 I0 . 0 ...J 2._02 . 0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOG (A(K+)/A(H+» LOG (A(K+)/A(H+» LOG (A(K+)/A(H+»
r;; 10. 0.---~-~-~--, r;; 8.0 r;; 4.0
,...** FORST ,...** ,...**
78.0 76.0 FORST 72.0
:I: :I: :I:
v v v
oc( oc( oc(
v v v
~ 6.0 ~ 4.0 ~ 0.0
+
+
(!)
t I-I,"""~;c... +
+
(!) (!)
::L
v 4.0 KALS ::L
v 2.0
::L
USC <2.0 KALS
oc(
v
oc(
v KALS v AND
(!)
AND (!)
AND (!)
0 20
...J '-2.0 2.0 6.0 10.0 3 0 ._02 . 0 2.0 6.0 10.0 3-4.0
-2.0 2.0 6.0 10.0
LOG (A(K+)/A(H+» LOG (A(K+)/A(H+» LOG (A(K+)/A(H+»
r;; 10. 0r---~-~-~----. r;; 2. 0 r-~--~----' ~4.0
*
,... ,...** ,...,...**
,...*
±8.0 FORST ~ 0.0 £6.0

~FORSTL
v v v
oc( oc( oc(
v v TALC v
~ 6.0 ~2.0 ~8.0
+ + +
+
(!)
+
(!) t· -b - - - +
(!)
::L ..... KALS ::L
~ 4.0 ~4
oc( •
0 <10.0 K- AR
v v v KALS
(!) (!) AND (!)
AND
32.0 3-6.0 6 .0 3-12.0~--~~~~--~
-2 . 0 2 .0 6 .0 I 0 .0 -2.0 2.0 10.0 -2.0 2.0 6.0 10.0
LOG (A(K+)/A(H+» LOG (A(K+)/A(H+» LOG (A(K+)/A(H+»
Phase relations in the system HCI-H 20 - Al 20 3 - K20 - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A c1i-
nochlore. Saturation limits: brucite (a), spinel (b).
 102
~ 18. 0...-~~-~~~--, ~ 12. 12Ir-~~-~~~----. ~ 10. 0r-~~--~~~

A
** ,.,** ----0-- ,.,**
A
';' 16.0 + 1121.0 14-A CL ';' 8.0
:z:: :z::
v
:z::
v
v
« «
v
«
v
v
;:: 14.0 .;:: 8.0
1 - - - ,....... ;:: 6.0
+ 1----' + +
~ TALC)----f +
(!)
K LS +
(!)
:t: KAOL Muse MUSC
~ 12.0 ~ 6.0 ~ 4. 0
« KAOL
;:; MUSC v v
(!) (!) (!)
0 40 O 2 0
310.00.0 .0.0
..8.0 12.0 ..J ·-2.0 2.0 6.0 10 . 0 ..J ·-2.0 2.0 6.0 10.0
LOG CACK+)/ACH+» LOG CACK+)/ACH+» LOG CACK+)/ACH+»
~ 18. 0r--~~-~~~----. ~ 12. 0r--~~-~~~~ ~ 10. 0r-~~--~~----.

** ** ----0-- *
"*
A ___ -0- A
14-A CL
~ 16.0 14-A CL ';' 10.0
:z::
';' 8.0
:z::
v v v
« « «
v v 1----,.-/ v
;:: 6.0 t----:~-
;; 14. 0~lli~(_ _-.1
;:: 8.0
+ I TALC) + +
(!)
+
(!) MUSC +
(!)
:t: KAOL :t: MUSC KALS
~ 12.0 MUSC ~ 6.0 K LS ~ 4.0 KAOL
;:; KAOL v v
(!)
K LS
(!) (!)
o
..J 10 ·1. 0 4.0 8 .0 12 • 0
0
..J
40
·-2.0 2. 0 6. 0 10 .0
32.0
-2.0 2.0 8.0 10.0
LOG CACK+)/ACH+» LOG CACK+)/ACH+» LOG CACK+)/ACH+»
~ 18. 0...-~~-~~~---, ~ 12. 0r-~~-~~~--' ~ 10. 0...-~~-~~~----.

A** *
"*
**
"';' 8.0
';' 16.0 ';' 10.0
:z::
v
:z:: :z::
v v
«
v
«
v
«
v
;:: 14.0 ;:: 8.0 ;:: 8.0
t 1"=i=A;--r~ ___l + +
(!)
+
(!)
+
(!) KALS
:t: :t: :t:
MUSC
~ 12.0 KAOL ~ 6.0 KAOL ~ 4.0 KAOL MUSC
v K LS v v
(!)
3 10. 0 '--.o.-JL.-~~...L...--J
(!) (!)

34.0 32.0
0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10 • 0 -2 • 0 2 •0 8. 0 10 • 0
LOG CACK+)/ACH+» LOG CACK+)/ACH+» LOG CACK+)/ACH+»
~ 18. 0...-~~-~~~---, ~ 12. 0r-~~-~~~----. ~ 10.0r-~~--~~~

** ** *
"';' ""*
A

';' 16.0
:z::
v
:z::
v
10.0
14-A CL ±8.0 14-A CL
v
« «
1
v v «
v
14 • 0 rALC ____ -r ;:: 8.0
+
;:: 8.0
+
+ +
~ (!) (!)

v 12.0 ~ 8 .0
« KAOL ~4 0 MUSC KALS
;:; KAOL MUSC v ;:;. KAOL
(!)

3 10. 0,":-.-.I~~~-'--""" ~
(!)

..J 4.0 32.0

!J.0 4.0 8.0 12.0 -2 • 0 2 •0 8 •0 10 • 0 -2 . 0 2 .0 8 .0 10 . 0
LOG CACK+)/ACH+» LOG CACK+)/ACH+» LOG CACK+)/ACH+»

Phase relations in the system HCI-H20-AI203-K20-MgO-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable chrysotile was considered instead of its stable counterpart, antigorite. Sa-
turation limits: brucite (a), spinel (b).
 103
~ 10. 01r-~~-~~~--. ~ 10. 0.---~~-~~~--, @ 10. 0r-~~-~~~---.
*
**
FORST
**
1"\
1"\ 14-A CL
*
1"\ 1"\
FORST
+ 8.0 -; 8.0 -; 8.0
J: J: 14-A CL J:
v v v
c( c( c(
v v v
~ 6.0 ~ 6.0 ~ 6.0
+ + +
+
(!)
I---~- +
(!)
+
(!)
:!: :!: :!:
~ 4.0 KALS ~ 4.0 ~ 4.0
v MUSC v v
KYA KYA (!) SILL
3 2. 0
(!) (!)
o o L--~~_L-L....~----l
...J 2·~2.0 2.0 6.0 10.0 ...J 2 ·~2 . 0 2 .0 6 .0 10 • 0 -2.0 2.0 6.0 10.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
@ 10 .0r-~~-~~----. @ 10. 0r--~~-~~~---' ~ 10. 0r-~~-~~~----.
** ** FORST **
! 8.0
1"\ 1"\ 1"\

±8.0
1"\ 14-A CL -; 8.0
J:
FORST
v v v
c( c( c(
v v v
~ 6.0 ~ 6.0 ~ 6.0 f - - - - - - - y "
+ + - -b- +
+
(!)
+
(!)
+
(!)
:!: KALS :!: :!:
~ 4.0 ~ 4.0 ~ 4.0 KALS
v MUSC v v
KYA AND
3 2. 0 3 2. 0
(!) (!) (!)
o L--~~___L~..L....~___I L-~~_.L.....L....~---I
...J 2._02 . 0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0 -2.0 2·.0 6.0 10.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
@ 10.0 ~ 8.0 ~ 4.0
** i--EFORST
* **

#-
1"\
"* FORST 1"\

±8.0
1"\
-; 6.0
J:
-; 2.0
J:
v v v
c( c( c(
v 14-A v v
~ 6.0 ~ _ -b- _ R _ G ~ 4.0 ~ 0.0
+ + +
+
(!)
+
(!)
+
~:..- (!)
:!: :!: :!:
~ 4.0 KALS ~ 2.0 ~2.0
v v v
AND
MUSC
(!) AND (!) (!)
O 2 0 30.0 3-4.0
...J ·-2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
@ 10. 0r--~~-~~~----. @2.0 ~4.0
* ** **
FORST
* FORST
r 6 .0
1"\ 1"\ 1"\

"±8.0 "±0.0 1"\

FORST

r
v v v
c( c(
v 14-A CL v
14-A ~~8.0 ....,._C_L_
14 - A
~ 6.0 ~2.0
+
+
(!)
+
+
(!)
-b- l t.: CORD''''- KALS
:!: :!: :!:
~ 4.0 ~4.0 ~10.0 K- AR
v v v
AND AND AND
(!) (!) (!)
o o 3-12.0~~~~~--~
...J 2 ·~2 . 0 2 .0 6 .0 10 .0 ....r6·~2.0 2.0 6.0 10.0 -Z.0 2.0 6.0 10.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

Phase relations in the system HCI-H 20 - Ah03 - K20 - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable chrysotile was considered instead of its stable counterpart, antigorite. Sa-
turation limits: brucite (a), spinel (b).
 104
;::; 18. 0r-~--~~-ry-...., ;::; 12. 0r-~~-~~-~--' ;::; 10. 0r-~~--~-~..,.,
* * 7-A CL *
""*+ ""* ""+* 8.0
- - -0- 7-A CL
J:
16.0 - - -0- - - ± 10.0 ~CHRYS PHLOG J:
v CHRYS PHLOG v v
<{
v
<{
v TALC \_--
<{
v
~ 14.0~__~ ~ 8.0 ~ 6.0 TALC ) - - -
+ + +
+ TALC)---' + + KALS
MUSC KjLS
(!) (!) (!)
L L L
::;: 12.0 ::;: 6.0 ::;: 4.0 MUSC
KAOL KAOL
(!) (!) (!)
o 34.0 32.0
...J 10.",0.", 4.'" -2.0 2.0 6.0 10.0 -2.0 2.0 6.0 10.0
'" '" '" 8.0 12.0
LOG CACK+)/ACH+)) LOG (ACK+)/A(H+)) LOG (A(K+)/A(H+))
;::; 18.0 ;::; 12.0 ;::; 10.0
* * - - -0- *
"* ""* "';* 8.0
- - -0-
7-A CL
';' 16.0 + 10.0 7-A CL PHLOG
J:
v CHRYS PHLOG v
J: J:
v
<{ <{ )-- <{
v v v
~ 14.0 ~ 8.0 ~ 6.0 TALCr-
+ TALC \ + K LS +
+
(!)
/ +
(!)
+
(!)
L K LS L MUSC L
KAOL MUSC KALS
v 12.0 MUSC ::;: 6.0 ::;: 4.0
<{
v v
KAOL v
KAOL
(!) (!) (!)
3 10. 0L......~-4-~~-'--...J 34.0 32.0
0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0 -2.0 2. 0 6 .0 10 . 0
LOG CACK+)/ACH+)) LOG (A(K+)/ACH+)) LOG (A(K+)/A(H+))
~. 18.0 ;::; 12. 0r-~--~~-orr---, ;::; 10. 0r-~---~-~-'
* * *
"* "*
7-A CL
';' 16.0
- - -0-
"*
';' 10.0 ';' 8.0
J: CHRYS J: J: - -b-
v PHLOG v v
<{ <{ <{ HLOG
v v v
~ 14.0 ~ 8.0 ~ 6.0
+ TALC \ + +
+
(!)
+ +
(!)
L
v 12.0
K LS ~ 6 .0 KAOL MUSC L
::;: 4. 0 KAOL MUSC KALS
<{
v MUSC <{
v
KAOL
(!) (!) (!)
3 10. 0L-~"""'-~~-..J""""'...J 34.0 32.0
0.0 4.0 8.0 12.0 -2 . 0 2. 0 6.0 10 . 0 -2.0 2 .0 6. 0 10 .0
LOG CA(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))
~ 18.0 ;::; 12. 0r--~--~~-....,......., ~ 10. 0r-~--~~--....,
7-A CL / * 7-A CL
* * **
"';'*
~c:0L:-
-0- r.
16.0
"';' 10.0 ';' 8.0
J: J: PHLOG J:
v v v
<{ <{ <{

/
v v v
~ 14.0
+
+
~
~/
~ 8.0
+
+ K LS
~ 6.0
+
+
(!) (!) (!) KALS
L
K LS L Muse L
::;: 12.0 ::;: 6.0 ::;: 4.0 KAOL Muse
MUSC KAOL
v KAOL v v
(!) (!) (!)

34.0 32.0
3 10 '00. 0 4 .0 8 .0 12. 0 -2 . 0 2.0 6 .0 10 . 0 -2 . 0 2 .0 6. 0 10 .0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/ACH+))
Phase relations in the system HCI- H 20 - Al 20 3 - K20 - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore and chrysotile were considered instead of their stable coun-
terparts, 14-A clinochlore and antigorite. Saturation limits: brucite (a), spinel (b).
 105

~ 10.0 ~ 10. 0r-~~-~~~--' ~ 10. 0r-~~-~~~---'

FORST
r.
** /'
*
"~* 8.0 FORST **
"~ 8.0
+ 8.0
J: J: J:
v FORST
v
<(
7 - A CHL/ ¥ v
<{ <{
v f- -b- - - - v v
~ 6.0 ~ 6.0 7-A CL ~ 6.0
+ TALC , , - / + +
+
(!)
+
(!)
+
(!)
l:
~ 4.0
KALS l:
~ 4.0 ~40
v
MUSC v
<{
v
•
KALS
KYA SILL
(!) (!) KYA (!)
0 20 0 20 g 2.0
...J '-2.0 2.0 6.0 10.0 ...J '-2. 0 2 .0 6.0 10 . 0 -2.0 2.0 6 .0 10.0
LOG CACK+)/ACH+» LOG (ACK+)/A(H+» LOG (A(K+)/A(H+»
~ 10.0 ~ 10.0 ~ 10. 0r-~~-~~~--,
FORST
,...** * *
~ 8.0
"~* 8.0 FORST "*
~8.0
J:
v 7-A CL J:
v
J:
v FORST
<{ <{ <{
v v v
~ 6.0 ~ 6.0 ~ 6.0
+ + +
+
(!)
l:
t TALC '----

KALS
+
(!)
+
(!)
l:
v 4.0 ~40 ~ 4.0
<{ MUSC <{•
v v v
(!)
KYA (!) (!)
SILL
020
'-2 .0 2.0 6 .0 10 . 0
g 2.0
-2 . 0 2.0 6 .0 10 . 0
g2.0
...J -2.0 2.0 6.0 10.0
LOG CACK+)/ACH+» LOG (A(K+)/A(H+» LOG (A(K+)/A(H+»
~ 10. 0r-~~-~~~--' ~ 8.0 ~ 4.0
,...** * *
"~* 6.0 "~* 2.0
FORST
~ 8.0 FORST FORST
J: J: J:
v v v

7~A~~L_b
<{ <{ <{
v v v
~ 6.0 ~ 4.0 ~ 0.0
+ + + KALS
+
(!)
+
(!)
+
(!)

4.0 {TALC \
l: l:
v ~ 2.0 ~2.0 H C
<{
v USC KALS v v AND
(!)
AND (!) (!)
g 2.0
-2. 0 2.0 6. 0 10 . 0
g 0.0
-2.0 2.0 6.0 10.0
:t4.0
-2.0 2.0 6.0 10.0
LOG CACK+)/ACH+» LOG (A(K+)/A(H+» LOG (A(K+)/A(H+»
~ 10 .0r-~~-~~~--' ~ 2.0 @-4.0
* * *
"~* 8.0 FORST "~* 0.0 "*
';.6.0
J: J: J: FORST
v v v
<( <{ <{
v v v
fo G

i
~ 6.0 _ ~2.0 ~8.0 - -b
+ + '
7~A ~/_b~L_ +
(!) ct l.CORD
~ 4.0 l--" KALS
l:
:;:-4.0 5. 10
<{ •
0 K-
TALC US v v
v AND
(!) AND (!) AND (!)

g 2.0
-2.0 2.0 6.0 10 . 0
:t6.0 L-~~J-~~~~
-2.0 2.0 6.0 10.0
:t 12 . 0L--.~~u.....~~-----.J
-2.0 2.0 6. 0 10 . 0
LOG CACK+)/A(H+» LOG (A(K+)/A(H+» LOG (ACK+)/ACH+»
Phase relations in the system HCl- H 20 - Ah03 - K20 - MgO - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A c1inochlore and chrysotile were considered instead of their stable coun-
terparts, 14-A c1inochlore and antigorite. Saturation limits: brucite (a), spinel (b).
 106
14.0

'"
'" '"
'" 9.0 '"
'"± ALB
± 11.0
v
ALB ±
v
ALB
v
7.0
« «
......
«
......
...... PARAG
'"~ 8.0 7 '" 6.0
~ '"~ 4.0
zv zv zv
«
v
« «
v
(!) 5.0 US ~ 3.0 1.0 AOL
0 GIBBS o KAOL (!)
o
...J ...J ...J

-2.0
2.00 . 0 3.0 6.0 9.0 0.00.0 3.0 6.0 9.0 0.0 3.0 6.0 9.0
LOG (ACK+)/A(H+)) LOG (ACK+)/A(H+)) LOG (A(K+)/A(H+))

'"
'" '"
'"±9.0 '"'"
± 11.0
v
ALB
v
ALB ±7.0
v
ALB
«
......
«
......
«
......
'"~ 8.0 '"~ 6.0 '"~ 4.0 PARAJT K-SPAR
z
v
z zv
«
v
« K-SPAR «
v v v US
(!) 5.0 (!) 3.0 1 .0 AO
3
(!)
KAOL o o
...J ...J

-2.0
2.00 . 0 3.0 6.0 9.0 0.00.0 3.0 6.0 9.0 0.0 3.0 6.0 9.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A<K+)/A(H+))
12.0

'"
'" 11.0 '"
'" 9.0 '"
'"
±
v
ALB ±
v
ALB
± 7.0
v
ALB
« « «
......
...... ......
'"~ 8.0 '"~ 6.0 PARAG '"~ K-SPAR
z
v K-SPAR zv 171 zv
4.0
« « K-SPAR «
v v v
5.0 US 3.0 1 .0
(!)
(!) US (!)
o KAOL 0
KAOL o
...J ...J ...J

2.00 . 0 3.0 6.0 9.0 0.00 . 0 3.0 6.0 9.0 -2.0

0.0 3.0 6.0 9.0
LOG (A(K+)/A(H+)) LOG (A(K+)/ACH+)) LOG (A(K+)/A(H+))
14.0 12 .0,......--~~~.....-,

'"
'" 11.0
±
v
«
......
'"~ 8.0
ALB/
.......
'"
'" 9.0
±
v
«
......
'"~ 6.0 PARAG
ALB '"
'" 7.0
±v
«
......
'"~ 4.0
ALB

zv zv f-; zv
« K-SPAR « K-SPAR «
v v
(!) 5.0 I US (!) 3.0 ~ 1.0
o o KAOL US o
...J KAOL ...J ...J

0.00.03.06.09.0 -2.0
2.00 . 0 3.0 6.0 9.0 0.0 3.0 6.0 9.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (ACK+)/ACH+))

Phase relations in the system HCI- H 20- CAI 20 3) - K20- Na20-Si02 in equilibrium with
quartz.
 107
10.0
A
A
ALB
,..," ALB
± 7.0
v
± 7.0
v
<I( <I(
"-
A ,..,
"- 'tARA:....-.
~ 4.0 ~ 4.0 K-SPAR
zv z
v
<I( <I(
v v M C
(!) 1.0 (!)
1.0 ~ 1.0
o YRO 0 KYA o SILL
..J ..J ..J

-2. 00 . 0 3.0 6 .0 9 .0 -2.0 -2.0

0.0 3.0 6.0 9.0 0.0 3.0 6.0 9.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))

A ,..,
,.., A

±7.0
A A

v
ALB
± 7.0
v
ALB
± 7.0
v
<I( <I( <I(
"- "-
....-. ,..,
"-
"~ 4.0
A

~ 4.0
PARAPO""-'
K-SPAR K-SPAR ~ 4.0 K-SPAR
zv zv zv
<I(
v US
<I(
v
M <I(
v MI ~C
(!) 1.0 1.0 1.0 SILL
YRO H (!) AND (!)
0 o o
..J ..J ..J

-2. 00 . 0 3.0 6 .0 9. 0 -2.00 . 0 3.0 6.0 9.0 -2. 00 . 0 3.0 6.0 9.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))

A
",.., A

±7.0
A A

v
± 7.0
v
ALB ±
v
7.0 ALB
<I( <I( <I(
"- "- "-
A

~ 4.0 "~ 4.0 K-SPAR "~ 4.0 r----{

zv zv zv K-SPAR
<I( <I( <I(
v v M C v
1.0 (!) 1.0 (!) 1.0 AND
~ AND o AND o
..J ..J ..J
-2.0 ~~-L~~ __ ~~
-2.00 . 0 3.0 6.0 9.0 0.0 3.0 6.0 9.0 -2.00 . 0 3.0 6.0 9.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))

,...
"±7.0
A

"±7.0 ""
v
ALB
v v
±7.0 ALB
<I( <I( <I(
"- PARAG "- "-
"~ 4.0 K-SPAR "~ 4.0 "~ 4.0
zv zv zv
<I( <I( <I(
v v v
K-SPAR
(!) 1.0 (!)
1.0 M (!) 1.0
0 AND o o AND
..J ..J AND ..J

-2 0 -2.0 -2.0
·0.0 3.0 6.0 9.0 0.0 3.0 6.0 9.0 0.0 3.0 6.0 9.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG (A(K+)/ACH+))

Phase relations in the system HCl- H 20- (AI 20 3) - K20- Nap-Si0 2 in equilibrium with
quartz.
 108
18.121
NEPH
"" NEPH ""+ 8.121
NEPH
±
v
14.121 "+ I 1.121
l--------~.-- /
:I: :I:
-.{ v v
"" "" ""
JADEI/
.:tz 1121.121 .:tz 8.121
PAR~G .:tz 6.121 PARAG / KALS

r:-r
PARAG/
v
-.{
Muse
v
-.{
KA S v
-.( !Muse
86 • 121
...J arz
v
8 5 • 121
...J
Muse
f K~OL I. AOL
2.121 2.121
2.121121 • 121 3.121 6.121 9.121 121.121 3.121 6.121 9.121 121.121 3.121 6.121 9.121
LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+))
18.121

" NEPH NEPH

" 14.121 "':;' NEPH "':;'
±
v :I:
I 1.121
:I:
8.121
-.{ v v

".:t" 1121.121 ANA/ ".:t" 8.121 ""

.:tz 6.121 KALS
zv PARAG/ z PARAG PARAG
Muse
v KA S v
Muse
84 ,121
-.{ -.{ -.(

86 • 121
...J KAOL
v
8 5 • 121
...J KAOL
Muse
...J

2.121 2.121
2 • 121121 • 121 3 • 121 6 • 121 9 • 121 121.121 3.121 6.121 9.121 121.121 3.121 6.121 9.121
LOG(A(K+)/A(H+)) LOG(A(K+)/A<H+)) LOG(A(K+)/A(H+))
18.121

"" NEPH
± 14.121
""+ I 1.121
NEPH "" NEPH
v
+ 8.121
:I: :I:
-.{ v v

".:t" 1121.121 AN/ ""

.:t 8.121 ".:t" 6.121
z zv z PARAG/ KALS
v PARAG/ v
-.{
Muse -.{
!Muse
86 • 121
-.(

...J KAOL
v
8 5 • 121
...J
84 • 121
...J
AO
2.121 2.121 2.121
121.121 3.121 6.121 9.121 121.121 3.121 6.121 9.121 121.121 3.121 6.121 9.121
LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+))
18.121
NEPH NEPH
"':;' 14.121
""+ I 1.121
""+ 8.121 NEPH

1-
:I: :I: :I:
v v
r ANAL v

".:t" 1121.121 ANy "".:t 8.121 f==.J'-==

-==~.-- "".:t 6.121
zv zv zv PARAG
PARAG/ K LS
-.{
v Muse -.(
v
-.(
Muse KALS
8 6 • 121 KAOL
8 5 • 121
...J
Muse
...J
AO
2.121121 • 121 3.121 6.121 9.121 2.121
2.121121 • 121 3.121 6.121 9.121 121.121 3.121 6.121 9.121
LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+)) LOG(A(K+)/A(H+))

Phase relations in the system HCI-H20-Ah03-K20-Na20-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature.
 109

/ /
9.0 9.0 9.0
NEPH
"" "" NEPH
"~ NEPH
v
± 7.0 ± 7.0
v J:
7.0
« « v
"- "- "- PARA(?j
"~ PARA1 "~ 5.0
"~ 5.0 PARAG
5.0 KALS
zv KALS z KALS zv
v
« « « us
Muse· v
g 3.0 Muse ~
~ 3.0 3.0
SILL
-.J
KYA -.J KYA -.J

1.0 1 .00.0 3.0 6.0 9.0 1.00 . 0 3.0 6.0 9.0

0.0 3.0 6.0 9.0
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/A(H+))

/
9.0 9.0 9.0

"
'" 7.0
±
v I-~---:/
NEPH ,/ "
A

± 7.0
v
NEPH
"
~ 7.0
J:
NEPH /
« « v
"- "- "- ALB 7
"~ 5.0
zv
« r----
I
PARAG/
KALS
"~
z
v
«
5.0
PARAG/
KALS
"~ 5.0
zv
«
KALS
v
g 3.0 Muse Muse ~ 3.0 ~US

-.J AND -.J SILL

KYA
1 . 00 . 0 3.0 6.0 9 .0 1.00.03.06.09.0 1.00.03.06.09.0
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))

/
9.0 9.0 9.0

""
± 7.0
v
NEPH
A
A

± 7.0
v
NEPHI "~
J:
7.0 NEPH7
« « v
"- "- ...--; "-
"
~ 5.0 PARAY
A

~ 5.0 PARAGj "~ 5.0 ALB 7

zv KALS z zv KALS
« =----- KALS
«
~ 3.0 Muse 1USC Mice
-.J AND AND AND
1.0 1 .0
1.00 . 0 3.0 6.0 9.0 0.0 3.0 6.0 9.0 0.0 3.0 6.0 9.0
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))
9.0 9.0 9.0

"
" 7.0 NEPH
A

" 7.0 "

" 7.0
±
v
±
v NEPH ±
v NEPH
« « «
"- "- "-
"~ 5.0 PARAYl
'"~ 5.0 "~ 5.0
zv KALS zv zv KALS
« f--A""'L--:B=---:/ KALS «
«
v
g 3.0 Muse ~ 3.0
us
-.J
-.J
AND AND K S AR
AND
1.0
1.00.03.06.09.0 1 . 00 . 0 3 .0 6. 0 9.0 0.0 3.0 6.0 9.0
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))

Phase relations in the system HCl- H 20 - Ah03 - K20 - Na20 - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature.
110
~ 18.13 ~ 14.9 ~ 12.9
** * *

,-,-- ,--
~ 16.13 14-A CL "* 12.13 "* 19.9
+ "+ 14-A CL "+ 14-A CL
~ 14.13 019.13 08.13
« « «
v
;::; 12.9 ,... - 0 - - - -- v
;::; 8.9 0- -
v
;::; 6.13
-a:
+ + +
+ ALB + ALB +
~ 113.9 ~ 6.9 ~ 4.9 ALB
v P RiI'G v FAR G v I ARAB
GIBBS
j 8.9 j 4.9 KAOL j 2.13 KAOL
(!) (!) (!)
o o o
-' 6 9 -' -' 9.9
• 4.9 6.9 8.13 113.9 2.92 . 9 4.9 6.9 8.9 1.9 3.13 5.9 7.9
LOG CACNA+)/ACH+» LOG CACNA+)/ACH+» LOG CACNA+)/ACH+»
~ 18.9 ~ 14.9 ~ 12.9
* * **
"* 16.9 14-A CL "* 12.9 " 19.13
14-A CL
"+ "+ "+ 14-A CL
~ 14.13
«
v
;::; 12.13
+
I- - 0 - - -
-.----
1---
~ 19.13
«
v
;::; 8.9
+
--,~
08.13
«
v
;::; 6.9
+
--;;:
+ ALB + ALB + ALB
~ 113.13 ~ 6.13 ~ 4.9
v
P IF AG v P~R G v ARIG
j 8.13 KAOL j 4.13 KAOL j 2.13 KAOL
(!) (!) (!)
o o o
-' 6 a -' 2.13 -' a 9
• 4.13 6.9 8.13 113.13 2.13 4.13 6.13 8.13 • 1.9 3.13 5.9 7.9
LOG CACNA+)/ACH+» LOG CACNA+)/ACH+» LOG (ACNA+)/A(H+»
~ 18. ar-~~-~~~---' ~ 14.13 ~ 12.9

**
" 16.13 14-A CL
*
"* 12.13 **
" 19.9
"+ "+ 14-A CL "+ 14-A CL

-----
014.13 ~ 113.13 08.13
« ~-----r;-- « «
1---- - -0-
~
v v v
;::; 12.13
+
;::; 8.13
+
;::; 6.13
+
,~
+ ALB + ALB +
~ 113.13 ~ 6.13 ~ 4.9 ALB
v
PA AG P Rr-G AR G
v v
j 8.13 KAOL j 4.13 KAOL j 2.13
(!) (!) (!)
KAOL
o o o
-' 6 13
· 4.13 6.13 8.13 113.13
-' 2.13 -' a 9
2.13 4.13 6.13 8.13 • 1.13 3.9 5.9 7.9
LOG CACNA+)/ACH+» LOG CACNA+)/ACH+» LOG CA(NA+)/A(H+»
~ 18. ar-~~-~~~---' ~ 14.13 ~ 12.9

~*
*
"*
*
16.13 14-A CL 12.13 ,.."* 19.9
"+ "+ 14-A CL
+ t4-A CL
014.13 ____ 0113.13 08.9
« ~----r- « «
-~
v I- - - - - -0- v v
;::; 12.13 ;::; 8.13 ;::; 6.13
+
+ ALB
+
+ ALB
+
+ I~
~ 113.13 ~ 6.13 ~ 4.13 ALB
PA AG v P~R ~G v
v
I AR~G
j 8.13 KAOL j 4.9 KAOL j 2.9
(!) (!) (!) PYROPH
o o o
-' 6 a -' 2 a -' 9.9
• 4.9 6.9 8.9 19.9 • 2.13 4.9 6.9 8.9 1.9 3.9 5.9 7.9
LOG CACNA+)/ACH+» LOG CACNA+)/ACH+» LOG CACNA+)/ACH+»

Phase relations in the system HCl- H 20- (Ah03) - MgO- Na20-Si02 in equilibrium with
quartz. Saturation limit: talc.
 111
~ 8.0 ~ 8.0 ~ 8.0
** ** **
r\
14-A CL 14-A CL r\
r\ 14-A CL
+ 6.0 ':;.' 6.0 + 6.0
I I I

,~
v v v

r-~~--,~~
« « «
v v v
:;::; 4.0 :;::; 4.0 :;::; 4.0 - -0-
+ ALB + +
+ + ALB +
(!)
1:
(!)
1: P IF AG
(!)
1: ALB
~ 2.0 ~ 2.0 ~ 2.0 SILL
v v KYA v
(!) (!) (!)
o o o
....J 0 0 ....J 0 0 ....J 0 0
· 2.0 4.0 6.0 8.0 . 2.0 4.0 6.0 8.0 . 2.0 4.0 6.0 8.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 8.0 ~ 8.0 ~ 8.0
**
r\
** **
14-A CL 14-A CL
~ 6.0 ':;.' 6.0
I
v v v
«
v
«
v
«
v
:;::; 4.0 :;::; 4.0 :;::; 4.0
+ ALB + +
+ + ALB + ALB
(!)
1: AR'IG (!)
1:
(!)
1:
~ 2.0 ~ 2.0 P RAG ~ 2.0 SILL
v PYROfH v AND v
(!) (!) (!)
o o o
....J 0.0 ....J 0.0 ....J 0.0
2.0 4.0 6.0 8.0 2.0 4.0 6.0 8.0 2.0 4.0 6.0 8.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 8.0 ~ 6.0 ~ 4.0
r\ ** **
r\
**
r\
r\
14-A CL r\ 14-A CL r\ 14-A CL
+ 6.0 + 4.0 + 2.0
I I I

-=<
v v v
«
v
:;::; 4.0
«
v
:;::; 2.0
~ «
v _fCORD_,~
:;::; 0.0 = - - - - 1- - 0-
+ + ALB +
+ ALB + +
(!)
1: P~R ~G
(!)
1: AND
(!)
1: ALB
~ 2.0 ~ 0.0 ~2.0
v AND v v AND
(!) (!) (!)
o o o
....J 0 0 ....J- 2 . 0 --!.4.0
· 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 7.0 ~ 0.0 ~4.0

**
r\
r\ 14-A CL
**
r\
r\
**
r\
r\
+ 5.0 -1-2.0 -1-6.0 14-A CL
I I I
v v v

4
« « «
v v
;:::"4.0 ;:::"8.0
ALB + + -0-
+
(!)
ALB +
(!)
PIR ft.,G
v 1.0 3..
« 6 .0 AND
1:
~10.0 ALB
« AND v v
v
(!) (!) (!) AND
o o o
....J_ 1 0 ....J_ 8 0 ....J-12.0~~~--~~--~~
· 0.0 2.0 4.0 6.0 • 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))

Phase relations in the system HCI-H20-(AI203)-MgO-Na20-Si02 in equilibrium with

quartz. Saturation limit: talc.
112
~ 18.0 ~ 14.0 ~ 12.0
* * J..*

-.-- -.--
"* 16.0 7-A CL "* 12.0 7-A CL
10.0
"+ "+ "+ 7-A CL
;5 14.0 :~ ;5 10.0 ;5 8.0
<
v
<
v
<
v
~ 12.0 ~ - -0- - --,
~ 8.0 - -0-- - -- ~6.0 -0- - 1-- - -
+ ALB + ALB + ALB
+ + +
~ 10.0 ~ 6.0 ~ 4.0
v P R AG v P~R~G v ARA~
~ 8.0
(!)
GIBBS ~ 4.0 KAOL ~ 2.0
(!) KAOL
(!)
o o o
..J 6.0 ..J 2 0 ..J 0.0
4.0 6.0 8.0 10.0 · 2.0 4.0 6.0 8.0 1.0 3.0 5.0 7.0
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))

---
~ 18.0 ~ 14.0 ~ 12.0

-,-- ---
J..* 16.0 7-A CL *
"* 12.0 7-A CL
*
"* 10.0
"+ "+ "+ 7-A CL
;5 14.0 ;5 10.0 ;5 8.0
< < <
v - - -0- - 1--- v v
~ 12.0 ~ 8.0 - -0- - --- ~ 6.0 -0- - - - -
+ ALB + ALB + ALB
+ + +
~ 10.0 P AG ~ 6.0 P~R G ~ 4.0
v
.~
v v ARIG
~ 8.0 KAOL ~ 4.0 KAOL ~ 2.0
(!) (!) (!)
KAOL
o o o
..J 6 0 ..J 2 0 ..J 0 0
· 4.0 6.0 8.0 10.0 · 2.0 4.0 6.0 8.0 · 1.0 3.0 5.0 7.0
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))
~ 18.0 ~ 14.0 ~ 12.0

J..* 16.0 7-A CL *

"* 12.0
*
"* 10.0
7-A CL

.---
" "+ "+ 7-A CL
§< 14. 0t-----.---
v - -0- - ---
;5 10.0
<
v
- -0-
,---
t---
;5 8.0
<
v
~ 12.0 ~ 8.0 ~ 6.0
+ ALB + ALB + -0- - - 1---
+ + + ALB
~ 10.0 PA AG ~ 6.0 P R G ~ 4.0
v v v F AR~G
KAOL KAOL
~ 8.0 KAOL ~
(!)
4.0 ~ 2.0
(!)
(!)
o o o
..J 6 0 ..J 2 0 ..J 0 0
· 4.0 6.0 8.0 10.0 · 2.0 4.0 6.0 8.0 · 1.0 3.0 5.0 7.0
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))
~ 18.0 ~ 14.0 ~ 12.0

---
J..* 16.0 7-A CL *
"* 12.0
*
"* 10.0

----
7-A CL
"+ "+ "+

-----
7-A CL
;5 14.0 ;5 10.0 ;5 8.0
< < <
v
~ 12.0
I- -0- - --- v
~ 8.0 - -o- r- - --
v
~ 6.0
+
+
10.0
ALB +
+
~ 6.0
ALB +
+
4.0
-0- - - ALB
--
~ PA AG P R~G
~
v v v I AR~G
~ 8.0 KAOL ~ 4.0 KAOL ~ 2.0
(!) (!)
o
(!) PYROPH
o o
..J 6 0 ..J 2 0 ..J 0 0
· 4.0 6.0 8.0 10.0 · 2.0 4.0 6.0 8.0 · 1.0 3.0 5.0 7.0
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))

Phase relations in the system HCI- H20- (AI 20 3) - MgO- Na20-Si02 in equilibrium with
quartz. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A clino-
chlore. Saturation limit: talc.
 113
~ 8.0 ~ 8.0 ~ 8.0

**
r\ 7-A CL ~ **
r\
7-A CL
**
r\
r\ 7-A CL
';' 6.0 + 6.0 ';' 6.0
r---~
,~
I I I
v v
r CORD
v
4:
v
r -0- - 4:
v
4:
v
;::: 4.0 ;::: 4.0 0-- - ;::: 4.0 - -0--
+ ALB + ALB +
+
t!)
+
t!)
+
t!) ALB
1: fAR G 1: P AG 1:
v 2.0 ~ 2.0 ~ 2.0
4:
v PYROP~ v KYA v
SILL
t!) t!) t!)
o o o
...J 0.0 ...J 0.0 ...J 0.0
2.0 4.0 6.0 8.0 2.0 4.0 6.0 8.0 2.0 4.0 6.0 8.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 8.0 ~ 8.0 ~ 8.0

** 7-A CL ** 7-A CL **
r\ r\ r\
r\
7-A CL
';' 6.0 ';' 6.0 + 6.0
,~/~
I I I

I{~.~
v v v
4: -0- - 4: 4:
v v v
;::: 4.0 ;::: 4.0 - -0- ;::: 4.0 / -0--
+ ALB + +
+ + ALB +
t!) AR G t!) t!) ALB
1: 1: P RAG 1:
~ 2.0 ~ 2.0 ~ 2.0
v
YRO H v
AND v SILL
t!) t!) t!)
o o o
...J 0 0 ...J 0 0 ...J 0 0
· 2.0 4.0 6.0 8.0 . 2.0 4.0 6.0 8.0 . 2.0 4.0 6.0 8.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 8.0 ~ 6.0
** **
7-A CL
r\
7-A CL r\
7-A CL
';' 6.0 + 4.0

i-----
I I
v
4:
v
4: JRJ:
v
4: .. ~
- .-------- - CORD
v v v
;::: 4.0 r - -0- - -- ;::: 2.0
1-0--
;::: 0.0 -- Lo- -
+ + +
+
t!)
ALB +
t!)
ALB +
t!) ALB
1: P R G 1: AND 1:
v 2.0 ~ 0.0 ~2.0
4:
v AND v v AND
t!) t!) t!)
o o o
...J 0 0 ...J- 2 . 0 -1..4.0
· 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 7.0 ~ 0.0 ~4.0

** ** 7-A CL
**
7-A CL r\
r\
r\
r\
7-A CL
';' 5.0 .y-2.0 .y-6.0

i~
I I I
?~
v v v
4:
v r-f- CORD 4:
v CORD
4:
v
;::: 3.0 r - -0- - r-- ~4.0 - -0- - ~8.0
+ ALB + ALB +
+
t!)
+
t!)
+
t!)
1:
v 1.0 P ~R ~G 1:
~6.0
1:
~10.0
4: AND
v AND v v AND
t!) t!) t!)
o o o
...J_ 1 0 ...J- 8 . 0 ...J-12.0~~~--~~--~~
· 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0 0.0 2.0 4.0 6.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
Phase relations in the system HCI-H20-(AI203)-MgO-Na20-Si02 in equilibrium with
quartz. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A clino-
chI ore. Saturation limit: talc.
114
~ 18.0 ~ 14.13 ~ 12.13
:I< :I< :I<
:I< :I<
A
:I<
16.0 r - .JtA_C~o_ - " 12.0 14-A CL A 113.0
"+ "+

--
A
+
::5« 14.0 ::5 10.0
I- - - -0- - - ..,
::5 8.0 r -O~~A_7-
v
;::; 12.0
ANI.H'
TA C ./
/ «
v
;::; 8.13
---/ «
v
;::; 6.13
+ + +
+ J DEI E + ~EP~ + NEPH
~ 10.0 ~ 6.0 PARA~ ~ 4.0
v aTZ P R G v KAOL v KAOL PARAC
~ 8.0 ~ 4.0 ~ 2.0
(!) (!) (!)
o o o
..J 6 0 ..J 2.0 ..J 0.0
• 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 0.0 4.0 8.13 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))

~ 18.0 ~ 14.0 ~ 12.0

:I< :I< :I<
:I< :I<
16.0 t- -
:I<
" 14-=A-cCO- - "A 12. a 14-A CL "A 10.0
"+ + r - - -0- - -.., +
;5 ANTIG=t--;:,~ ::5 ::5 8.0 I- _ O~4=-A ~y
«
v
14.0
TALC /- «
v
10.0
----/ «
v
;::; 12.0
+
+
~ 10.0
t NAL
;::; 8.0
+
+
~ 6.0
NEPH
;::; 6.0
+
+
~ 4.0
---- NEPH
KAOL PARAG
v v KAOL v KAOL PARA(
P~RtG
~ 8.0 ~ 4.0 ~ 2.0
(!) (!) (!)
o o o
..J 6 0 ..J 2.0 ..J 13.0
. 0.13 4.0 8.0 12.0 0.0 4.0 8.0 12.13 0.0 4.0 8.0 12.13
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))

~ 18.0 ~ 14.0 ~ 12.0

:I< :I<
:I<
r - - - -
7
:I< -0- - :I< :I<
A 16.0 14-A CL A 12.13 A 10.0
_oJ1:: A_ C,=-
A A A

+ + - + 14-AY
::5 14.0 ~ ::5 10.0 ::5 8.0 '-- -b- - - - ...;
« «

----
« v v
v
;::; 12.0
+
+
~ 10.0 KAOL
ANAL
;::; 8.0
+
+
~ 6.0
KAOL A ~L
NEPH
;::; 6.0
+
+
~ 4.0
----
PARA(
NEPH

v v v KAOL
P R G
~ 8.0 ~ 4.0 PARAG ~ 2.0
(!)
(!) (!)
o o o
..J 6.13 ..J 2.0 ..J 0.0
0.0 4.0 8.0 12.0 13.0 4.0 8.0 12.0 0.0 4.13 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))

~ 18.13 ~ 14.0 ~ 12.13

:I< :I< :I<
:I< :I<
:... 16.13 t- -
--7
-'4-A- CL -0 A 12.13 14-A CL "A 10.0
"+
A
+ r -0- - +
::5 -Y'~ ::5 ::5 8.0 14-A~

---
14.0 TALC1- 10.0
« «
v
«
v r -b- - - - - -
v
;::; 8.13 ;::; 6.0

----
;::; 12.0
+ + +
+ + KAOL NEPH + NEPH
~ 10.13 ANAL ~ 6.0 ~ 4.13
KAOL v A i'lL v
v
P R G PARA(
PARAC KAOL
~ 8.13 ~ 4.0 ~ 2.13
(!) (!) (!)
o o o
..J ..J 2.0 ..J 0.13
6.130 . 13 4.0 8.0 12.0 0.13 4.13 8.13 12.0 0.0 4.13 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG (ACNA+)/ACH+))

Phase relations in the system HCI- H 20 - Al 20 3 - MgO - Na20 - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limits: brucite (a), spinel (b).
 115
~ 12.0 ;:;; 9.0 ;:;; 9.0
FORST Ufo(S

'f*.. * *
""*+ 7.0 ""+* 7.0
10.0 FORST
"+ /
C 8.0 J: J:
<{
v
;::; 6.0
r- _b~4~A~/ v
<{
v
;::; 5.0
v
<{
v 14-A C L / ,
;::; 5.0 r- - - - -b--

~
+
+
4.0 --- NEPH
+
+
(.!)
1:
P~R G
NEPH
+
+
(.!)
1:
-"'

NEPH
v PARA v 3.0 v 3.0
<{ <{ SILL
~ 2.0
(.!)
KYA v
(.!)
KYA v
(.!)
P l~ lAG
a a a
...J 0.0 ....J 1 0 ....J 1.0
0.0 4.0 8.0 12.0 . 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))

__~~,_c/
;:;; 12.0 ;:;; 9.0 ;:;; 9.0
FORST FORST
* * *
"* 10.0 ""+* 7.0 "'.;'* 7.0 FORST /
"+
C 8.0 J: J:

r-~~-~Y
v v
<{ <{ <{
v v v
;::; 5.0 14-A CY-I
---
;::; 6.0 ;::; 5.0
+ + + ----:., -b--
+ + +
~ 4.0 ~ NEPH (.!) NEPH (.!)
NEPH
ARA 1:
3.0
1:
v
KYA v
<{ P R G ~ 3.0
B
~ 2.0 v AND v SILL
(.!) (.!) (.!)
a a a
....J 0.0 ....J 1.0 ....J 1.0
0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
10.0 ;:;; 7.0 ;:;; 4.0

cL
~
FORST ~-'-- FORST
* * / *
"* 8.0 "* ""+* 2.0 FORST /
C 6.0 - -14-'.~
"+ "J:+ 5.0 J:
v 14-' v
<{ - - -b-- <{ <{ ....!~A_CV_ -b--
v
;::; 4.0
v
;::; 3.0 -- - -
.....,
-b-- v
;::; 0.0
+ + + NEPH
+ NEPH + NEPH +
~ 2.0 PARpG
(.!)
::E
(.!)
1: ~ B
v v 1.0 P ~R AG ~2.0
AND <{ AND
~ 0.0 v
(.!)
AND v
(.!) (.!)
a a a
....J_ 2 0 ....J- 1 . 0 ....J- 4 .0
. 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
;:;; 10 .0..-~~-~~-~..., ~ 1.0 ;:;;-5.0
* FORST
* *
'f.. 8.0 ""*+-1.0 FORST,/
""*+-7.0 FORST
"+
C 6.0
<{
v
J:
<{ 14-A CL /
v
J:
<{
v v v
;::; 4.0 ~3.0 r.---/--b-- ~9.0
+ + I---- + NEPH
+ + NEPH +
~ 2.0 NEPH (.!) (.!)
1: 1: B
v PI'IRIG ~5.0 t B ~11.0
~ 0.0 AND v AND v AN
(.!) (.!) (.!)
a a a
....J2 0 ....J_ 7 0 ....J- 13 0L-~~----~__--J
- . 0.0 4.0 8.0 12.0 . 0.0 4.0 8.0 12.0 '0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))

Phase relations in the system HCl-H20-AI203-MgO-Na20-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Saturation limits: brucite (a), spinel (b).
116
~ 18.e ~ 14.0 ~ 1 2 . er-~--"""""''5"><''''--~--'

**
'" 16.e .... - 0 - - - - - - **
'" 12.e 7-A CL **
'" Ie. €I
'"+ ANTIG '"+ 0- - - - --~
A
+ 7-A CL
(;; 14.e (;; 10.0 (;; 8.0 - - -0-
e
/ <t ANTI~
/ <t
<t
v AL ./ v v ALC/,,-,--
~ 12.e ~ 8.0 ~j ~ 6.e
+ + +
+ PEIT
,J~ + EPH + NEPH
~ le.e ~ 6.e PARAG
v aTZ P R G v KAOL ~ 4.0 KAOL PARA
j 8.e j 4.e j 2.e
(!) (!) (!)
o o o
..J 6.e ..J 2.e ..J 0.e
€I.e 4.e 8.e 12.e 0.e 4.e 8.e 12.e 0.e 4.e 8.e 12.e
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))

~ 18.e ~ 14.0 ~ 12.e

** ** **
I- -0"- - - - - - FORST::J-
'" 12.0 7-A CL 10.e
'" 16.e ANTIG A

'"+ '"+ f--O----/

rf;£A-~/
A
+
(;; 14.e _/ (;; Ie. €I ANTIG _____ (;; 8.0
<t
v
rA /' <t
v
<t
v
/'
~ 12.e ~ 8.0 TALd ~ 6.e
+ + EPH + NEPH
+ t NAL + +
~ le.e KAOL
~ 6.0 PARAG ~ 4.0 PARAe
v v KAOL v
FII\RtG KAOL
j 8.e j 4.e j 2.0
(!) (!) (!)
o o o
..J 6.e ..J 2 0 ..J €I.e
€I.e 4.e 8.e 12.e . 0.e 4.e 8.0 12.0 e.e 4.e 8.e 12.e
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))

~ 18.e ~ 14.e ~ 12.er-~~F~O~R~S=T~~--'

**
'" 16.e
1--0------
**
'" 12.0 7-A CL ** le.e
ANTIG A

'"+ '"+ ~-o----/

A
+
(;; 14.e
I-f-TALC /" (;; le.0 (;; 8.e

----
<t <t <t
v v v
~ 12.e ~ 8.0 TALCr ~ 6.e
+ + ~EPH + NEPH
+ + +
~ le.e P R G ~ 6.0 /PARAE ~ 4.0
v KAOL v ARA
ANAL KAOL A AL v KAOL
j 8.e j 4.0 j 2.e
(!) (!) (!)
o o o
6 €I ..J
..J ..J €I.e
. €I.e 4.0 8.0 12.0 2.00 . e 4.e 8.0 12.0 e.0 4.e 8.e. 12.e
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))
~ 18.0 ~ 14.0 ~ 12.elr-~~--~~---.

** 7-A CL:J- *
**
FORST
0- - - - - - -
~ le.er-------------~
t -,Y
'" 16.0 '" 12.e 7-A CL
ANTIG
'"+ '"+ ~ '"+
(;; 14.0
<t
/ (;; 10.0
<t ,....1
NTIG -
;::?'
(;; 8.e
<t
v v v
~ 12.0 TALCj ~ 8.0 TALCr ~ 6.0
+ + ~EPH +
+ ANAL + + NEPH
~ 10.0 ~ 6.0 PARAE ~ 4.e
v
KAOL KAOL
P R G v v KAOL PARA
j 8.0 j 4.0 A ~L j 2.e
(!) (!) (!)
o o o
..J 6 0 ..J 2.0 ..J €I €I
. 0.0 4.0 8.0 12.0 0.e 4.0 8.0 12.0 . €I.e 4.0 8.e 12.e
LOG (A(NA+)IA(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))

Phase relations in the system HCI- H 20 - AIP3 - MgO - Na20 - (Si0 2) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A c1inochlore was considered instead of its stable counterpart, 14-A c1i-
nochlore. Saturation limits: brucite (a), spinel (b).
 117
~ 12.0 ~ 9.0 ~ 9.0
* * *
"* ""+* 7.0
FORST
"* 10.0 FORST /
"+ ~ 7.0
:I: :I:
FORST
~ 8.0
.l-~ £L_~
v v
<
v
~ 6.0
_ <
v
~ 5.0
7-A CL
t---- .L-b- - <
v
~ 5.0
+ + ~~./ +
+ + NEPH +
~ 4.0 NEPH (!)
::E
(!)
::E
v PARA ~ 3.0 P~R G v 3.0
KYA KYA < SILL
~ 2.0
(!)
v
(!)
v
(!)
o a a
...J ...J 1.0 ...J 1 0
0.00.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 · 0.0 4.0 8.0 12.0
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))
~ 12.0 ~ 9.0 ~ 9.0

J..* * *
"~* 7.0
FORST
10.0 "~* 7.0 FORST/

4
"+ :I: :I:
FORST
~ 8.0 v v
< < <
v 7-A CL
-b--
v 7-A CL .L -b-- v
~ 6.0 t - - - - ~ 5.0 t - - - - ~ 5.0
+ + r---!J + t---~-:-"7."- - b-
~
+
4.0
~a NEPH +
(!) TALC NEPH +
TALCj- NEPH
ARA~ ::E ~
v ~ 3.0 P R G v 3.0 B
~ 2.0 KYA v AN~
<
v SILL
(!) (!) (!)
o a a
...J 0.00.0 ...J 1 0 ...J 1 0
4.0 8.0 12.0 . 0.0 4.0 8.0 12.0 · 13.0 4.0 8.0 12.0
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))
~ 10.0 ~ 7. 0 r-~~-~~~--, ~ 4.0
** 8.0 FORST * *
"* "*
A
.... /' FORST FORST
"+ ~ 5.0 ":I:+ 2.0
7-A CL :I:
~ 6.0
< f---- -b-- v
~ 7-A CLl __ b-
v
< -b- -
v v
~ 4.0 ~ALC ~ 3.0 j-':':":":=-j/ ~ 0.0
+ NEPH + +
+ + NEPH + NEPH
~ 2.0 I AR G (!)
::E
(!)
::E
v
AND ~ 1.0 P G :;;-2.0
~ 0.0 v AND v
AND
(!) (!) (!)
o a a
-l2 0 ...J_ 1 0 L-~~-'--'~..........~---' ...J_ 4 0
. 0.0 4.0 8.0 12.0 . 0.0 4.0 8.0 12.0 · 0.0 4.0 8.0 12.0
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))
~ 10 . 0 ~ 1.0 (:J-5 • 0

J..* 8.0 J..* J..* FORST

~ ';-1 . 0 FORST ';-7 . 0
~ 6.0 ~ ~
~ < TALC < f~R.£. - - b- -
~+ 4 . 0 '-3
~ .0 V./ - - b - - '-9 . 0
~
+ + NEPH +
NEPH
~ 2.0 ~ ~ B
~ :;;-5 . 0 B :;;- 1 1 . 0 AND
~ 0.0 ~ AND ~
a a 0
...J-2 . 0 ...J-7. 0 ...J- 13 0":-..................:--~--:-~--'
0.04.08.012.0 0.04.08.012.0 '0.04.08.012.0
LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+)) LOG (A(NA+)/A(H+))
Phase relations in the system HCl-H20-Ah03~MgO-Na20-(Si02) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A cli-
nochlore. Saturation limits: brucite (a), spinel (b).
118
N 18.0 N 14.0 N 12.0
** 16.0 r- - - 14-A
- - CL- ** **
--7
~ -0 ~ 12.0 14-A CL A 10.0
~ ~ A
+ + r- -0- - + 14-AY

---
C; 14.0 C; 10.0 C; 8.0 ~ -0- - - - -

---- ---
<{ <{ <{
v TALC /' v v
~ 12.0 ~ 8.0 ~ 6.0
+ + +
+ JDEI E + NEP~ + NEPH
~ 10.0 ~ 6.0 PARAG ~ 4.0
v aTZ v KAOL v PARA(
P R G KAOL
:) 8.0 :) 4.0 :) 2.0
m m m
o o o
..J 6 0 ..J 2 0 ..J 0.0
• 0.0 4.0 8.0 12.0 . 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+» LOG C~0NA+)/ACH+» LOG CA~NA+)/ACH+»

N 18.0 N 14.0 N 12.0

** 16.0
r- - - - - - -0- *
:.. 12.0 ** 10.0
~
~
14-A CL A 14-A CL A
A
+ + ~-o-----...,
+ 14-AY
r-
-----/
C; 14.0 ~ C; 10.0 C; 8.0 -0- - - - -
<{ TALC ./ <{ <{

----
v v v
~ 12.0 ~ 8.0 ~ 6.0
+ + +
+ NAL + ~EPH +. NEPH
~ 10.0 ~ 6.0 PARAG ~ 4.0 PARA(
v P,A.R~G v KAOL v KAOL
KAOL
:) 8.0 :) 4.0 :) 2.0
m m m
o o o
..J 6.0 ..J 2.0 ..J 0.0
0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+» LOG CACNA+)/A(H+» LOG CACNA+)/ACH+»
N 18.0 N 14.0 N 12.0
** t- - - - - -0 - - ** ** 10.0
~
~

+
16.0

C; 14.0
14-A CL

~
A
A
+
12.0

C; 10.0
r-
14-A CL
-0- - --7 A
A
+ 14-AY
C; 8.0 : - - b - - - - -

---- ---
<{ <{ <{
v v v
~ 12.0 ~ 8.0 ~ 6.0
+ + +
+ f.NAL + ~EPH + NEPH
~ 10.0 ~ 6.0 PARAG ~ 4.0
v
P R G v KAOL v PARA(
KAOL KAOL
:) 8.0 :) 4.0 A AL :) 2.0
m m m
o o o
..J 6 0 ..J 2.0 ..J 0.0
• 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+» LOG CACNA+)/ACH+» LOG CACNA+)/ACH+»
N 18.0 N 14.0 N 12.0,...--~~-~~~---,
*
:"16.0
*
:"12.0
*
:"10.0
~ ~ ~

+ + + 14-A CL
C; 14.0 C; 10.0 C;8.0
<{ <{ <{
v v v -b- - -
~ 12.0 ~ 8.0 ~ 6.0
+ + +
+ + + NEPH
~ 10.0 ~ 6.0 ~ 4.0
v v v ARA
:) 8.0 :) 4. 0 :) 2.0 KAOL
m m m
0 0 0
..J 6.0",.", ..J 2.0",.", ..J 0.0",.L..",~--...l.~~L.......-_..J
'" '" 4.0 8.0·12.0 '" '" 4.0 8.0 12.0 '" '" 4.0 8.0 12.0
LOG CACNA+)/ACH+» LOG CACNA+)/ACH+» LOG CACNA+)/ACH+»

Phase relations in the system HCI-H20-AI203-MgO-Na20-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem·
perature. Metastable chrysotile was considered instead of its stable counterpart, antigorite. Sa·
turation limits: brucite (a), spinel (b).
 119
~ 12.9 ~ 9.9 ~ 9.9
FORST
J..* * *
"* "~* 7.9
19.9 FORST
"+
~ 8.9
"± 7.9 14-A CL J:
/

-
14-A C / -
CL~
v v
c{ c{ c{
v
- -b- - - -- v
-b- - v 14-A
~ 6.9 ~ 5.9 ~ 5.9 f-- - - - -b--
+ + + .....,
+ + +
~ 4.9 NEPH (!) NEPH (!)
NEPH
l: l:
v ~ARA ~ 3.9 P R G ~ 3.9 ~I<AG
~ 2.9 KYA v KYA v SILL Pf
(!) (!) (!)
o o o
....I 9 121 ....I I 9 ....1 19
• 9.9 4.121 8.9 12.121 · 9.9 4.9 8.9 12.9 • 9.9 4.9 8.9 12.9
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CA(NA+)/ACH+))
~ 12.9 ~ 9.9 ~ 9.9
FORST FORST
J..* * *

"-AC/
"+
19.9
"~* 7.9 ""+* 7.9 FORST
J: J:

~-bl~-~~
~ 8.9 v v
c{ c{ c{
v v v

--
~ 6.9 ~ 5.9 l- -b- - - - .... ~ 5.9 14-A CL
+ + + -b-
+ + +
~ 4.9 (!) NEPH (!)
NEPH
v ~ NEPH l: l:
ARA ~ 3.9 P R G ~ 3.9
~ 2.9
(!)
KYA v
(!)
AND v SILL
(!)
o o o
....I 9 9 ....I I 9 ....I 1.9
• 9.9 4.9 8.9 12.9 • 9.9 4.9 8.9 12.9 9.9 4.9 8.9 12.9
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))

FORST/
~ 1121.9 ~ 7.9 ~ 4.9
---'-- LFORST FORST
* * / *
"* 8.9
,... "* "~* 2.9
14-A~ ~ 5.9
C~
+ J: J:
~ 6.9
c{
v
- - - -
.-
-b-- v
c{
v
"-A v
c{
v - 14-A
- - 0/- -b - -
- - - - -b--
~ 4.9 ~ 3.9 ....., ~ 121.9
+ NEPH + + NEPH
+ +
(!) NEPH +
(!)
~ 2.9 ~ B
v
AR G l: l:
AND F ~ 1.9 P ~R~G ~2.9 AND
~ 9.121
(!)
v
(!)
AND v
(!)
o o o
....1_2 121 ....1- 1 . 9 ....1- 4 • 9
• 9.9 4.9 8.9 12.9 9.9 4.9 8.121 12.9 9.9 4.9 8.9 12.9
LOG (ACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 19.9 ~ 1.9 ~5.9
FORST
*
,...J.. 8.9 ** FORST ,...**

..-.;C(
FORST
,...
"+-1.9
+ "+-7.9
J: J:

I~A_~_b_
~ 6.9 v v CORD
c(
v
- - - - -b--
c{
v
c{
v - r - - - -b -
~ 4.9 ~3.9 ~9.9
+ + NEPH
+
+ NEPH + NEPH +
~ 2.9
(!)
l:
(!)
l:
B
v iARf G ~5.9 B ~11.9 AN
ANDF AND
~ 9.9 v
(!)
v
(!)
(!)
o o o
....1-2 .99 . 9 ....1_ 7 0 ....1- 13 9'---.........L..o.....~~~~....J
4.9 8.9 12.9 · 9.9 4.9 8.9 12.9 '9.9 4.9 8.0 12.9
LOG CA(NA+)/ACH:t-) LOG CACNA+)/ACH+)) LOG CA(NA+)/ACH+))

Phase relations in the system HCI-H20-AI203-MgO-Na20-(Si02) in equilibrium with

gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable chrysotile was considered instead of its stable counterpart, antigorite. Sa-
turation limits: brucite (a), spinel (b).
120
~ 18.0 ~ 14.0 ~ 12.0r-~~~~~~~

* * *
"* 10.0
"* 16.0 r- - - - - -0- - "* 12.0 7-A CL
"+
;5 14.0
CHRYS
./
"+
;5 10.0 r- -CHRYS - -0/ "+
;5 8.0 -
7-A CL
- - -0- -
« TALC « ;?'-- « TAU~ ____
v .// v fA ./ v
~ 12.0 ~ 8.0 ~ 6.0 Y
+ + r EPH +
+ JIDEI E + +
~ 10.0 ~ 6.0 ~ 4.0
v aTZ v KAOL v KAOL PARA
j 8.0 PflR G j 4.0 PARAG j 2.0
(!) (!) (!)
o o o
...J 6 0 ...J 2 0 ...J 0 0
· 0.0 4.0 8.0 12.0 . 0.0 4.0 8.0 12.0 . 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 18.0 ~ 14.0 ~ 12.0
* * *
"* 10.0
\::::FORST
"* 12.0
~ - - - - -0- -
~ 16.0 CHRYS 7-A CL
"+ "+ "+
;5
«
v
14.0
TALC /
./
;5 10.0
«
v
~1~/ ;5
«
v
8.0 ~TA:~A_~~
~ 12.0 ~ 8.0 ~ 6.0
+ + EPH + NEPH
+ fNA + +
~ 10.0 KAOL ~ 6.0 KAOL ~ 4.0 PARA(
v v
PARAG v KAOL
j 8.0 F~RJG j 4.0 j 2.0
(!) (!) (!)
o o o
...J 2 0 ...J 0 0
...J 6.00 . 0 4.0 8.0 12.0 . 0.0 4.0 8.0 12.0 . 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 18.0 ~ 14. 0r-~~-~~~---' ~ 12. 0r-~~;=F;:;O"S<'CT:;:O-~---'
*
"*
- - - - -0- - *
"*
*
"* 10.0
~
16.0 CHRYS 12.0 7-A CL
"+ "+ 7-A CL
/
"+
;5 14.0
TALC ;5 10.0 ;5 8.0 -b
« ../ «
v v j (TALC
~ 12.0
ANAL ~ 8.0 ~ 6.0 ---;;r-I
+ + +
+ + + NEPH
~ 10.0 KAOL ~ 6.0 A ~ 4.0 ARA
KAOL
v v v AOL
j 8.0 PflR G j 4.0 j 2.0
(!) (!) (!)
o o o
...J 6 0 ...J 2.0 ...J 0.0
· 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 18.0 ~ 14. 0r-~~-~~~---' ~ 12. 0r-~~-~~~--'
~\::7-A CL *
~* 16.0 r- - 0 - - - - - * FORST
"*
-
12.0 7 A CL ~ 10. 0 r - - - - - - - - - j
"+ CHRYS "+

i:·~·~~~1C
;5 14.0 /' ;5 8.0 7-A CL
« TALC /' «
v v -b
~ 12.0 ~ 6.0
+ ANAL
+ +
+
~ 10.0 KAOL ~ 6.0 KAOL ANAL ~ 4.0 NEPH
v v
P R G
j 8.0 j 4.0
v ;1 j 2.0 AOL ARA
(!)
o g PARA 'I (!)
o
...J 6 0 ...J 2. 00 .L.0~-4-.~0'--'--8~•.u0~-1...J2 . 0 ...J 0.0
· 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
Phase relations in the system HCI-H20-AIP3-MgO-Na20-(Si02) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A c1inochlore and chrysotile were considered instead of their stable coun-
terparts, 14-A c1inochlore and antigorite. Saturation limits: brucite (a), spinel (b).
 121
~ 12.0 ~ 9.0 ~ 9,0

~* 10.0 FORST ** **
"+
~ 8.0
!" 7.0 FORST / "-:;:-
J:
7.0 FORST

..I-b--
v v
oct oct oct
v 7-A CL / . v 7-A- CL- v
-b- I- -
tTALC /
I- - - - -
~ 6.0 ~ 5.0 ~ 5.0 -b-
+ + +
+ + +
~ 4.0 NEPH (!)
:E:
NEPH (!)
:E:
v
KYA ~ 3.0 P~R G ~ 3.0
j 2.0 ARA v KYA v
(!) (!) (!)
o o o
.J 0.00.0 .J 1 0 .J 1 0
4.0 8.0 12.0 · 0.0 4.0 8.0 12.0 · 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/A(H+))
~ 12.0
*
~ 10.0 FORST
FORST/
"+
~ 8.0 v v FORS,L
oct 7-A C L 4 oct oct
v
~ 6.0 r - - - -b--
v
~ 5.0
7-A - CL-
l:- -
.L -b-.., v
~ 5.0 TALC
+ +
AL /'
+ r--r~- -b--
+
~ 4.0
~ALC NEPH
+
(!)
NEPH
+
(!) NEPH
:E: :E:
v ARA~ ~ 3.0 P ~R G ~ 3.0
j 2.0 KYA v AND v
SILL t B
(!) (!) (!)
o o o
.J 0.00.0 .J 1 0 .J 1 0
4.0 8.0 12.0 · 0.0 4.0 8.0 12.0 · 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG (ACNA+)/ACH+)') LOG (A(NA+)/ACH+))
~ 10.0 ~ 7.0 ~ 4.0
* FORST * *
"* 8.0 /' "-:;:-* 5.0 FORST "* FORST
"+ -:;:- 2.0
~ 6.0 7-A CLL, J:
v
J:
v
oct - - - - -b-- oct 7-A CLi oct f_Cr:R,D - -b-
v v v
~ 4.0
+
llic\" ~ 3.0
+
f--'..t::I.Io.lo<..,/-, - -b- ~ 0.0
+ NEPH
+ NEPH + NEPH +
~ 2.0 AR~G
(!)
:E:
(!)
B
v ANDF P AG :E:
v-2.0
~ 1.0 AND oct AND
j 0.0 v v
(!) (!) (!)
o o o
.J 2 0 .J- 1 • 0 .J_ 4 0
- . 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 · 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG (ACNA+)/ACH+))
~ 10. 0r-~~--~~---, ~ 1.0 ~5.0
* * *
"* ""*r7.0
~ 8.0 FORST FORST
"+ "£1.0 FORST
J:
~ 6.0 v v
oct 7-A CL oct oct
v v
-b- v
~ 4.0 ;:::-3.0 t-n,.,...,..././- - - b - ;:::-9.0
+ TALC\" + + NEPH
+ NEPH + NEPH +
~ 2.0 R G
(!)
:E:
(!)
:E:
v AND ::;-5.0 B ::;-".0 AND
j 0.0 v AND v
(!) (!) (!)
o o o
.J_ 2 . 00. 0 -L7 0 .J-13.0L-~~-----~~
4. 0 8.0 2
1.0 · 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CA(NA+)/ACH+)) LOG CACNA+)/ACH+))
Phase relations in the system HCI-H20-AI203-MgO-Na20-(Si02) in equilibrium with
gibbsite, diaspore, or corundum, depending on which mineral is stable at each pressure and tem-
perature. Metastable 7-A clinochlore and chrysotile were considered instead of their stable coun-
terparts, 14-A clinochlore and antigorite. Saturation limits: brucite (a), spinel (b).
122
~ 21.0 ~ 13. 0r-~d~~~""""~~""""'"
**
"+
I
19.0 ~ 1 1 .0 \ ~~O~S
v
«
v
"- 17.0
~ ~~t/_ -0-
CL ;::; 9.0 14-A CL
"+ +
+ +
« «
u u
v 15.0 ~ 7.0
«
(!) (!) (!)
S 13 . 0 L-~~.L..lL....~'>"""'~-" S 9.05.0 S 5.02.0
9.0 12.0 15.0 18.0 8.0 11.0 14.0 5.0 8.0 11.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

~ 21 . 0r---"""I~-I~-/"""""~--' ~ 17 • 0 rT~~-::-:'C~"'-7"""" ~ 13. 0r-......,..~---....,...---...,

* d 1
**
1;-0--
~ 'GRO~S * \
"+ 'cdb "+ "+ \ G~O~S
c:5
19.0~_\~-4--~
- _\J..
I
v
«
15.0
I
11.0
\ \b
-,) v v
_\--1 ~ - -0-
;::; 17.0 PREHN"" 14-A CL ;::; 13. 0~-=-"=-=f - -0- ;::; 9.0 14-A CL
t 1\
~
+
14-A CL
+
+
«
c:3 LAWS "" u u
v 7,0
v 15.0 \ ~ 1 1 • 0 t-------tl
« 1 «
PARA~ \ \ PARAq> \
5 1 3. 0
9.0
'--~~_u..L..I,,-~\~......J
12.0 15.0 18.0
(!)

S 9.05,0 8.0 11.0 14.0

\ (!)

S 5,02.0 5.0 8.0 11.0

LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

~ 2 I . 0,...-..-,.-------...,.---..., ~ 17.0 1 // ~ 13, 0r-.....~---...---...,

* ~ ~: PA~/ * PARG
*
':;.' 1 9 • 0 ~""-'---_;_--7'
""+* 11.0
I
\\ b c':;.' 15.0 \GR9ss1 I
I

\ \ b
-\Ii! -
-0-
v
-It- :5 v
- 0-
;::; 17.0 \~ 14-A C ;::; 13.0 I 14-A CL ;::; 9,0 t----"-rt-i -14-A CL
+
+
PREHN \1\ t - 0 - - - +
+
«
u
v 15.0
\

'c\
8« 11 . 0 PREH~
«
u
~ 7.0

r
«
(!) \ v PARAf},
I
'c\ (!)
S 13 , 0 L-..,~~---'...J--"-~~~--'
(!)
S 9,05,0 S 5.02.0
9.0 12.0 15.0 18.0 8.0 11,0 14.0 5.0 8.0 11.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CA(H+))**2)

-, f
~ 21 ,0
~17,0 \ b
GR~~AW,
*
""+* 19.0
\ \GRdss
q 1
/
150 \
"
':;.' 1 1 • 0 GRopS
I

~~t! -0--
I I I

v ~
;::; 13.0 \
\b 14-A CL
~
~
\ d\ I
\ I
;::; 17.0 \{ 14-A CL I ,,9.0 -0--
«t
+
+ PREHN\ + ~\...l -0 - - PR~(
«
u \ ~ "I u
14-A CL
v
«
15.0 ~ 11,0 PREH~ ~ 7,0 tfLNZI \
'c \
\

PARAG C\ v
PARA \
s 9. 05.0
1 \
(!) (!) PARAd (!)

S 13,0
9,0 12,0 15,0 18.0
I '\ L-~-...L.u.....->.~~~-,
8.0 11.0 14,0
S 5.02.0 5.0 8,0 11.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG (A(MG++)/CA(H+))**2)

Phase relations in the system HCl-HzO-(Ah03)-CaO-MgO-NazO-SiOz in equilibrium

with quartz and albite. Saturation limits: wollastonite (a), talc (b), diopside (c), tremolite (d),
 123
(;;; 10 . 0,.......--..~........~.,.-~..,..., (;;; 10. 0",~...~......,.~~....., (;;; 10 .0,......~.,....~~~~.....,
~ **
**
: \ 1
,",9.0 ~ 9.0 ~O~SI ,",9.0
'"'+ + 8.0 \ \ b'
'"'+
;:; 8.0 ;:; ;:; 8.0
<{
v ~ -~r-l--o- <{
v
~ 7.0 t - - - - - \ i 14-A C -0
+ 1\ ~ 7.0 CLNZ~ 14-A CL
~ 7.0
+
+ +
~ 6.0
v PARAG
1\'c, ~ 6.0
v
, ~
v
6.0
\
14-A CL
1d \ PARAG \ C, f-----I,\ \
~ 5.0 ~ 5.0 ~ 5.0
(!) 1 \ \ (!)
1 \ \ (!)
SILL \ \
~ 4.0 ~ 4.0 ~ 4.0
0.0 3.0 6.0 9.0 . 0.0 3.0 6.0 9.0 0.0 3.0 6.0 9.0
LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2)
(;;; 10 . 0,.......~...........~..,....~"ry""1 (;;; 10. 0rT'~"T.""~--'-~~""" (;;; 9.0
**
,",9.0
: \ ~ **
,",8.0
~ 9.0 GRO~SI
'"'+
;:; 8.0
± \ \ bPARG '"'+
;:; 7.0
<{
v
~8.0 _ ~~ _ -0- <{
v
~ 7.0 ~ 7.0 CL Z ~ 6.0
CL
+ +
+
~ 6.0
t
~ 6.0
r-_A_N_0_R_~~J\14-A
r CL +
~ 5.0
v PARAG v v
~ 5.0 ~ 5.0 \ , ~ 4.0 SILL
PARAG \ C,
(!) (!) (!)

~ 4.0 ~ 4.0 ~ 3.0

0.0 3.0 6.0 9.0 0.0 3.0 6.0 9.0 0.0 3.0 6.0 9.0
LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2)
(;;; 10 . 0 .--.,--.-...-~--.-,~~-.--, (;;; 8.0 (;;; 6.0
* \ d 1 d
**
1
**
ARG
~ 9. 0 GRO~sI '"' 7.0 G\05SI
\ b PARG " 5.0
'"'+ '"'+
§ 8.0 PREH\I\ b ;:; 6.0 - -
\ \ 1
- - -0 ;:; 4.0
~ +~-o- <{
v \
<{
v
~
+
+
7.0 CLNZ
ANOR
14-A CL ~ 5.0
+
+
ANOR l',4-A CL ;::; 3.0
+
+
CL
~ 6.0
v
t-----!i\ , ~
v
4.0 (32.0
v
1 \ C,
~ 5.0 PARAG: \ C, ~ 3.0 AND 1 \ \
::3 1.0
(!) \ \ (!) (!) AND
~ 4.0 ~ 2.0 ~ 0.0
0.0 3.0 6.0 9.0 -2 . 0 1 .0 4 .0 7. 0 -4.0 -1.0 2.0 5.0
LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2) LOG CACMG++)/CACH+))**2)
(;;; 9.0 (;;; 3.0 (;;;-1.0

**
,",8.0
** 2.0
'"' **
"'-2.0
'"'+ '"'+ '"'+
;:; 7.0 -0- ;:; 1.0 5-3.0
<{ <{ <{
v v v
~ 6.0 CL ~ 0.0 14-A CL ~4.0
+ ANOR + +
+ + + CL
~ 5.0 f - - - - - i ! \ <:r1 .0 <:r 5 . 0
\
v 1 \ v v
::3 4.0 PARAG Id \ ~2.0 \ C, ~6.0
(!) \ \ (!) AND \ \
3-3. 0 ~~..oILJ'---o...._ _---J
~ 3.0
-1.0 2.0 5.0 8.0 -7.0 -4.0 -1.0 2.0
LOG CA(MG++)/CACH+))**2) LOG CA(MG++)/(ACH+))**2)
Phase relations in the system HCI-H20-(AI203)-CaO-MgO-Na20-Si02 in equilibrium
with quartz and albite. Saturation limits: wollastonite (a), talc (b), diopside (c), tremolite (d).
124
N 21 . 0,.,,.......~~-~""""7........, N 17. 0n--~~~---r~...., N 13. 0,.,....~~-r-~..........,
**
.....
:
.....
\
e **
.....
~ 19.0 ~ 15.0 \ ~ 11.0
J: J: ,GRklSS J:

-I--d-
v v

~
« «
v v
~ 17.0 13.0 b, \ : ~ 9.0
+ ~----TIr---j +
+ ~ +
« CL N/ 7-A CL « I7-A CL
u u \ \
~ 15. 0r-----!IT-i-. ~ 11 .0!=t:;;fl;l;~~ ~ 7.0 PARAGI \ \
v v
v \ I b
(!)
g 13. 0L.....~~................-:-'~~
(!) (!)
g 9. 0 '---o~""""",,---,""""'~----:-,
g5.02.0
9.0 12.0 15.0 18.0 5.0 8.0 11.0 14.0 5.0 8. 0 110
.

J
LOG (A(HG++)/(A(H+»**2) LOG (A(HG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2)

N 21.0 N 17. 0rT~~~-----r~.........., N 13.0

-r--
*
**
..... \ \G.~SS
\ \ 0
.....*
ARG
.....*
* PARG
~ 19.0 ~ 15.0 ~ 11.0
J: J: J:
v v v
« - -"- r « «
v
~ 17.0 PR~~ v
~ 1 3 . 0 ~-=:''=;-=
v
~ 9.0
F--'=-='\':-j==-.'7 - d -
+
+
«
n
LAWS ~ -,J7-A CL
+
+
«
+
+
«
CL
u u
~ 15.0 \ ~ 1 1 .0r---r"i ~
« 7 .0
PARAGI \
,
v \
Ie\ b v PARA~\ \
v
(!) (!) (!)
~ o °50'-:--~~...J...o...l...lo-.-~~'--'
g 13 '90. 0 12 . 0 15 • 0 18 • 0 ...J 9·~.0 8.0 11.0 14.0 ...J • 2.0 5.0 8.0 11.0
LOG (A(HG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2)
N 21 . 01r-...,.,~~~~~...., N 17 .0rr~~~~"""""T~""""" N 13. 0r-.....~~~...-~..........,
*
* \ **
.....
.....
\
e I .....*
*
~ 19 . 0 r--""",,~..,.---, + 15.0 \ GRpSS ~ 11.0
J: J: \ J:
v
« d- v I v
«
v :3 0 \ \ v
~ 17.0 ~ 13 • 0 r--T+~I,--_: ~ 9.0 -d-

~ ~~~N\-/;_~~~
+ +
+ + Cl
« CL «
u
~ 15.0
v
~ 11.0 /
u
~ 7.0
v v
(!) (!)

g 13 •9.0
(!)
0'-:--~~~-"-:-::--~~
12.0 15.0 18.0
o
...J 9·~.0 8.0 11.0 14.0
g 5.02.0 5.0 8.0 11.0
LOG (A(HG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2)
N 21 .0 N 17. 0n-'~~~~""~"""""
* * I PARG
.....* .....* e I ..... PARG
~ 19.0 ' \ ~ 15.0 \ GRpSS ~ 1 1 .0
J: \\0 J: \ J:
~ -'+ L - -d- ~ \ ~ / ~
v
~ 17.0 PRE~ v
~ 13.0 \ I !:::
..... 9.0
+ \ + ~..J.---d- +
+ \ 7-A CL + ~ +
~ ~ PR"'I~N 7-A CL ~ 7-A Cl
~ 15.0 'b ~ 11 .0 ~ 7.0
~ PARAGI \ \ ~ PARAe 'b ~
g 130 g9.0 g5.0
'9.0 12.0 15.0 18.0 5.0 8.0 11.0 14.0 2.0 5.0 8.0 11.0
LOG (A(HG++)/(A(H+»**2) LOG (A(HG++)/(A(H+»**2) LOG (A(HG++)/(A(H+»**2)

Phase relations in the system HCl- H 20- (AI 20 3) -CaO- MgO- Na20-Si02 in equilibrium
with quartz and albite. Metastable 7-A clinochlore was considered instead of its stable counter-
part, 14-A clinochlore. Saturation limits: talc (a), diopside (b), tremolite (c), wollastonite (d).
 125
~ 1121.121 ~ 1121.121 ~ 112I.12I1't"""""'~..-~-r-~~......,
*
,!. 9.121
r\
** 9.121
r\
r\
=
~ 9.121
\ C
b;R~Ssl
a
+ + PARG
~ 8.121 ~ 8.121 ~8.121 \\1 PARG
<{ <{
v
<{ 0.. \ I
v
;::; 7.121 CL ;::; 7.121
v
;::; 7.121
--A -d--
+ + +
+ + + AN OR
t'j 6.121 t'j 6.121 t'j 6.121
v v CL v
;3 5.121 ;3 5.121 ;3 5.121 SILL CL
(!) \ (!) (!)
~ 4. 121 '--~~~..J...JL.Io....~...>.........J ~ 4. 121 '-:-~-::-'"~~:-'":~~ ~ 4.121
121.121 3.121 6.121 9.121 121.121 3.121 6.121 9.121 121.121 3.121 6.121 9.121
LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2)
~

*
1121. 121 r-~<:"""""'"...-~--,-~............, ~ 1121.121
** 9.121
~ 9.121
** 8.121
\ C 1/
,!. 9.121 PARG
r\ 1"\ ~~~Sl

'\~7
r\ r\ r\
+ + +
~ 8. 121 ~=p~i'!H;ffi ~ 8.121 ~ 7.121
<{
v
;::; 7.121 t-----'n7-A CL
<{
v
;::; 7.121
<{
v
;::; 6.121
\1 - -d-
ANOR'
+ 1\ + +
+ + +
t'j 6.121 I \ t'j 6.121 t'j 5.121 7-A CL
v PARAG I \ v CL v \
SILLC
;3 5.121 b ~ 5.121 ;3 4.121 D\
I
a \ \ I \
(!) (!) (!) \
~ 4.121 ~ 4.121 ~ 3.121
121.121 3.121 6.121 9.121 121.121 3.121 6.121 9.121 121.121 3.121 6.121 9.121
LOG CACMG++)/CACH+»**2) LOG (A(MG++)/CA(H+»**2) LOG CACMG++)/(A(H+»**2)

~ 1121 • 12I1"r-'-'-'~"""~~""""" ~ 8.121 ~ 6.121

,!.* 9.121
r\ PARG **
" 7.121
** 5.121
1"\
1"\ 1"\
+ + +
~ 8.121 ~ 6.121 ~ 4.121
<{ d- <{ <{
v v v
;::; 7.121 ;::; 5.121 ;::; 3.121
+ + +
+ CL + CL +
t'j 6.121 t'j 4.121 t'j 2.121
v v v CL
;3 ~ 3.121 D\ AND
5.121 'b ~ 1.121
(!) \ (!) \ (!)
~ 4.121 ~ 2.121 ~ 121.121
121.121 3.121 9.121 -2.121 1.121 4.121 7.121 -4.121 - 1 • 121 2.121 5.121
LOG CA(MG++)/CACH+»**2) LOG (ACMG++)/(A(H+»**2) LOG (A(MG++)/(ACH+»**2)
~ 9.121 ~ 3.121 ~1.e

,!.* 8.121
1"\
**
~ 2.121 PARG **
~2.e
1"\
+ + +
~ 7.121 ~ I.e ~3.e
<( <{ <(
v v v
;::; 6.121 ;::; 121.121 ~4.e
+ CL + +
+ + +
t'j 5.121 ~1.121 7-A CL ~5.e
v v \ v
~ 'I.e ~2.e D\ ~6.e R -A CL
(!) (!) AND \ (!) AND I\ \
~ 3.121 ~3. 121 L:---~-":-"~--o..:--:-' ~7.e
-1.121 2.121 5.121 6.121 -7.121 -4.121 - 1 .121 2.121 -13.121 -1121.121 -7.121 -4.121
LOG CACMG++)/CA(H+»**2) LOG (A(MG++)/(A(H+»**2) LOG (A(MG++)/(A(H+»**2)

Phase relations in the system HCl- H20- (Ah03) -CaO- MgO- Na20-Si02 in equilibrium
with quartz and albite. Metastable 7-A clinochlore was considered instead of its stable counter-
part, 14-A clinochlore. Saturation limits: talc (a), diopside (b), tremolite (c), wollastonite (d).
 126

~ 40. 0r-~~-~--~-' ~ 24.0 -b- - - -r- ~ 24.0

** --b--f- **
,-.. I **
,-..
,-..
':;' 30.0 + 18.0 + 18.0 -b- - I -
I I I
v ARAG v ARAG v CALC
« I « I « I
v a v a v
I
I "- 12.0 I "- 12.0
~
+
20.0 +
+ I
+
+
aI
« « «
u u u
v v v
«v 10.0 «v 6.0 « 6.0
SIDER SIDER v SIDER
(9 (9 (9
o o o
-l 0.0 -l 0.0 -l 0.0
10.0 12.0 14.0 16.0 4.0 6.0 8.0 10.0 3.05.07.09.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 40.0 ~ 24.0 - - b- - - ~ 24. 0,--~~-~~--...,
**
,-.. -b- - -1-
**
,-.. **
,-..
+ 30.0 '"'+ 18.0 '"'+ 18.0 -b- +
I I I
v CALC v CALC I v
« I « « CALC
v aI v a v
"- 12.0 I "- 12.0
~ 20.0 + +
+ + I +
« « «
u u u
v v v
« 10.0 «v 6.0 « 6.0 SIDER
v SIDER SIDER v
(9 (9 (9
o o o
-l 0.0 -l0 0 -l 0.0
10.0 12.0 14.0 16.0 . 4.0 6.0 8.0 10.0 3,0 5.0 7.0 9,0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 40.0 ~ 24.0 - - b __ _ ~ 24.0
* T **
** - b- - + "*
,-.. '"'
':;' 30.0 + 18.0 '"'+
I
18.0 -I--b--
I I
v CALC I v v
« « «
v a v v CALC
I "- 12.0 12.0
~ 20.0 + ~
+ + +
« « «
u u u
v v v
« 10.0 «v 6.0 « 6.0
SIDER SIDER v
(9 (9 (9
o o o
-l 0.0 -l 0.0 -l 0.0
10.0 12.0 14.0 16.0 4.0 6.0 8.0 10.0 3.0 5.0 7.0 9.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 40. 0r-~~-~--~-' ~ 24.0 __ b- __ I' ~ 24. 0.--~~-~~-~...,
* I *
*
':;' 30.0
-b- - 1- '"'*
'"'+ 18.0
'"''"'+* 18.0
I I
v
CALC I
v
_1- - - - b-
v
« CALC « «
v v v CALC
~ 20.0 ~ 12.0 ~ 12.0
+ + +
« « «
u u u
v v v
« 10.0 SIDER « 6.0 « 6.0
v SIDER v
(9 (9 (9
o o o
-l 0.0 -l 0.0 -l 0.0
10.0 12.0 14.0 16.0 4.0 6.0 8.0 10.0 3.0 5.0 7.0 9.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)

Phase relations in the system HCI- H 20-CaO- (C0 2) - FeO. Saturation limits: ferrous oxide
(a), lime (b).
 127

~ 16. 0r-_~_~b~_-_~_~-r~-_"" ~ 16. 0r-~~-~~~--' ~ 16. 0r-~~-~~~--'

* 1 **
"':;:* 12.0
:..
A
+ 12.0
--b----j- A
':;: 12.0 - - - -b- 1 -
1
J:
v
«
CALC
I
J:
v
« CALC
, J:
v
« I
v a
I
v aI v CALC a
-:;:- 8.0 -:;:- 8.0 -:;:- 8.0 I
+ + +
«
u
«
u
«
u
v v v
«v 4.0 « 4.0
v
« 4.0
v
SIDER
(!) (!) (!)
o o o
...J 0.0 ...J 0.0 ...J 0.0
0.0 2.0 4.0 6.0 -1.0 1.0 3.0 5.0 -1.0 1.0 3.0 5.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(ACH+))**2)
~ 16. 0r--_~b-_-_~_-_-I_-_--' ~ 16. 0r--~~-~~~--' ~ 16. 0r-~~-~-~--'
*
**
1
*
" I :.. - - - -b- I-- - A 1
~ 12.0 a A
+ 12.0 '; 12.0 - - -b- -1--
~ CALC I J:
v CALC I
J:
v
« « « CALC
v v aI v
I
-:;:- 8.0 -:;:- 8.0 -:;:- 8.0
+ + +
aI
«
u
«
u
«
u
v v v
«
v
4.0 «
v
4.0 «
v
4.0
SIDER
(!)
o
(!)
o B SIDER
...J 0.0 ...J 0.0 ...J 0.0
0.0 2.0 4.0 6.0 -1.0 1.0 3.0 5.0 -1.0 1.0 3.0 5.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 16.0 ~ 16.0 ~ 16. 0,~~-~-~--,
--b-- I- - - 1
** 1
** **
A A 1 A
A CALC
':;: 12.0
J: 1 ':;: 12.0
J:
-b- -1- - - - + 12.0
J:
v CALC v
CALC v
« « « 1
v v
I
v - r -b- - - -
-:;:- 8.0
+
-:;:- 8.0
+
a -:;:- 8.0
+
I
«
u
«
u
«
u
v v v
«
v
4.0 «
v
4.0
SIDER
« 4.0
v
(!) SIDER (!) (!)
o o o
...J 0.0 ...J 0.0 ...J 0.0
0.0 2.0 4.0 6.0 -1.0 1.0 3.0 5.0 -2.0 0.0 2.0 4.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(ACH+))**2)
~ 16.0 ~ 8.0 ~ 4.0
- - - -b- -I-
** ** **
1
-b- -,- - - - I - - -b- - - -
A
"
?
A

':;: 12.0
J: CALC
~ 4.0 CALC ,':;: 0.0
J:
v
« I v
« I v
«
v a v
1
v
-:;:- 8.0 I -:;:- 0.0 CALC
':;:--4.0
«
+ 1
«+ «
+
u u u
v
~ 4.0 SIDER ~4.0 <f-8.0
v v v
(!)
SIDER
(!) (!)
o o o
...J 0.0 ...J- 8 . 0 ...J-12.0~~~-~~~~
0.0 2.0 4.0 6.0 -9.0 -7.0 -5.0 -3.0 -18.0 -16.0 -14.0 -12.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)

Phase relations in the system HCl-H 20-CaO-(C02)-FeO. Saturation limits: ferrous oxide
(a), lime (b).
128
~ 16. ar-~~-~-;;~~71 ~ 16.13 ~ 16.13
* * *
"* 14. a
"+ ""+* ·14.13 MAG "*
"+
14. a
:r: 12.13 C 12.13 MAG
C
«
12.13 v
« «
v v
I
;::; 113.13 ;::; 113.13 b
+ + I
+ +
ARAG ~ 8.13 ~ 8.13
v v ARAG v
~ 6.13 ~ 6.13 ~ 6.13 CALC
(') (!) (')

:3 4.136.13 113.13 14.13 18.13

:3 4.136.13 113.13 14.13 18.13
:3 4.136.13 113.13 14.13 18.13
LOG (A(CA++)/(A(H+))**2) LOG (A(CA++)/(A(H+))**2) LOG (A(CA++)/(A(H+))**2)
~ 16.13 ~ 16.13 ~ 16.13
** ** *
r\ 14. a r\ 14. a MAG "* 14.13
r\
+
:r: 12.13
r\
+
:r:
"+ MAG
v
«
v 12.13
«
C
«
12.13 I
v v v b
"- "- 113.13 ;::; 113.13 I
r\
+ "+ +
+ + +
~ 8.13 ~ 8.13 ~ 8.13
v CALC v v
CALC CALC
~ 6.13 ~ 6.13 ~ 6.13
(') (') (!)

:3 4.136.13 113.13 14.13 18.13

:3 4.136.13 113.13 14.13 18.13
~ 4.13
6.13 113.13 14.13 18.13
LOG (A(CA++)/(A(H+))**2) LOG (A(CA++)/(A(H+))**2) LOG (A(CA++)/(A(H+))**2)
~ 16. ar-~~-~-r-....,-' ~ 16. ar-~~-~~~~T1 ~ 16. al~~-~~-"'771
* * *
~ 14.0 "* 14.0 MAG ~ 14. 0r------~
"+ "+ "+
C
«
12.13 C 12.13 C 12.0
«
v
«
v
;::; 113.13 ;::; 113.0
+ + 1
+ +
CALC ~ 8.13 ~ 8.13 -I
v v CALC v
~ 6.13 ~ 6.13 CALC 1
~ 6.13
(!) (!) (!)
1
~ 4.13 ~ 4.13 ~ 4.13
6.13 113.13 14.13 18.13 6.13 113.13 14.13 18.13 6.13 113.13 14.13 18.0
LOG (A(CA++)/(A(H+))**2) LOG (A(CA++)/(A(H+))**2) LOG (A(CA++)/(A(H+))**2)
~ 16. 0r-~~-~-r--"7-' ~ 16. 0r-~~-~---'-r~T1 ~ 16. 01r-~-~~--~77I
* * * HYDRO-MAG
~_14.a "* 14.0 MAG * 14.0r-------; 1
~
"+ "+ + 1
C
«
12.0 C 12.0 C 12.0
v
«
v
«v 1
;::; 113.0 ;::; 10.13 ;::; 113.0 ~
+ + + 1
+ + +
~ 8.0 CALC ~ 8.13 ~8.0 _.J
v v CALC v
~ 6.0 ~ 6.0 1
~ 6.0 CALC
(!) (!) (!)
1
~ 4.136 . 0 10.0 14.0 18.0 ~4.0
6.0 10.0 14.0 18.0
~ 4.13
6.0 10.0 14.0 18.0
LOG (A(CA++)/(A(H+))**2) LOG (A(CA++)/(A(H+))**2) LOG (A(CA++)/(A(H+))**2)
Phase relations in the system HCI-H 20-CaO-(C0 2)-MgO. Saturation limits: brucite (a),
lime (b), peric1ase (c).
 129
~ 16. 0r-~~-~~-~-" ~ 16. 0r-~~-~~----' ~ 16. 0r-~~-~~-~,
:
" 14.0
HYDRO-MAGI *
"* 14.0
*
"* 14.0
~ r-----,/ "+ "+
;5 12.0 ;5 12.0 ;5 12.0
MAG
<t <t <t
v v v
;::: 10.0 ;::: 10.0 ;::: 10.0
+ + +
+ + +
~ 8.0 ~ 8.0 ~ 8.0
v v v CALC
~ 6.0 ~ 6.0 ~ 6.0
(!) (!) (!)

g 4.06.0 10.0 14.0 18.0

g 4.06.0 10.0 14.0 18.0
g 4.06.0 10.0 14.0 18.0
LOG CACCA++)/CACH+))**2) LOG CACCA++)/CACH+))**2) LOG CACCA++)/CACH+))**2)

~ 16.0 ~ 16.0 ~ 16.0

* * HYDRO-MAG *
:.. 14.0 "* 14.0 I "* 14.0
"J:+ "J:+ "+
v 12.0 v 12.0 ;5 12.0
<t <t <t
v v v
...... 10.0 I
b ,.,...... 10.0 ;::: 10.0
"++ I +
+
+
+
~ 8.0 ~ 8.0 ~ 8.0 CALC
v v v
~ 6.0 ~ 6.0 ~ 6.0
(!) (!) (!)

g 4.06.0 10.0 14.0 18.0

g 4.06.0 10.0 14.0 18.0
g 4.06.0 10.0 14.0 18.0
LOG CACCA++)/CACH+))**2) LOG CACCA++)/CACH+))**2) LOG CACCA++)/CACH+))**2)

~ 16.0 ~ 16.0 "

N
12.0
* * *
"* 14.0 ,.,"* 14.0
"* 10.0
"J:+ + "+
J:
;5 8.0 MAG
v 12.0 v 12.0
<t <t <t
v v v
;::: 10.0 ;::: 10.0 ;::: 6.0
+ + +
+ + +
~ 8.0 ~ 8.0 ~ 4.0
v v CALC v
-0
~ 6.0 ~ 6.0 ~ 2.0
(!) (!) (!)

g 4.06.0 10.0 14.0 18.0

g 4.06.0 10.0 14.0 18.0
g 0.02.0 6.0 10.0 14.0
LOG CACCA++)/CACH+))**2) LOG CACCA++)/CACH+))**2) LOG CACCA++)/CACH+))**2)

"
N
16.0 ~ 8.0
HYDRO-jMAG
~ 4.0
* HYDRO-MA~ * *
""* 14.0 "* 6.0 "* 2.0
+ "+ MAG "+
MA~
v
J:
12.0 ;5 4.0 ;5 0.0
<t <t <t
v v v
,.,...... 10.0 ;::: 2.0 ;:::-2.0
+ + +
+ + +
~ 8.0 ~ 0.0 CALC ~4.0
v v v CALC
~ 6.0 ~2.0 ~6.0
(!) (!) (!)

g 4.06.0 10.0 14.0 18.0

5-4.0
0.0 4.0 8.0 12.0
5-8.0
-4.0 0.0 4.0 8.0
LOG CACCA++)/CACH+))**2) LOG CACCA++)/CACH+))**2) LOG CACCA++)/CACH+))**2)

Phase relations in the system HCl- H 20-CaO- (C0 2) - MgO. Saturation limits: brucite (a),
lime (b), periciase (c).
 130

~ 20.0 ~ 15.0 ~ 13.0

ART
** ART ** ART **
::::: 18.0 ::::: 13.0 ::::: 11.0
+ + +
:c :c :c
v v v MAG I
~ 16.0 - MAG
- -- 0- ~ 11.0 - -0--
I ~ 9.0
__ 1-
"- "- MAG "- -0- -
"t "t "t
(!)
l:
14.0 bI (!)
l:
9.0
I SIDER (!)
l:
7.0
SIDER
v v v
~ 12 .. 0 SIDER I
I
~ 7.0 bI «
v
5.0
9
I

(!) (!) (!)

:] 10. 0L-~~~~.L--~-...J :]5.0 :]3.0
9.0 13.0 17.0 4.0 8.0 12.0 3.0 7.0 11.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 20.0 ~ 15.0 ~ 13.0
ART ART
** ART ** **
::::: 18.0 ::::: 13.0 ::::: 11.0
+ + + I
:c :c :c
v - -0- - - -- v v MAG I
~ 16.0 ~ 11.0 - - 0- ...J ~ 9.0
"- MAG I "- "- - -1- - -0--
"t 14.0 I "t 9.0
MAG SIDER "t 7.0 SIDER
(!) (!) I (!)
l:
v
~ 12.0 SIDER ~ l:
v
~ 7.0
bI l:
v
~ 5.0
I
bI
(!) (!) (!)

:] 10 0 .&'.
13 . 0 17 . 0 :]5.0
4.0 8.0 12.0
:]3.0
3.0 7.0 11.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 20.0 ~ 15.0 ~ 13.0
ART I ART
: ART * **
::::: 18.0 * 1J3. 0
::::: ::::: 11.0 I
+ ~------~~.~ + + I MAG
:c :c
~ - -0- - v v
I
~ 16.0 ~ 11.0 -O-_L-- ~ 9.0
"- MAG "- MAG "- _.1 - -0--
SIDER
"t 14.0
"t 9.0 "t 7.0 I
: SIDER SIDER
(!) (!) I (!)
I
l:
v
l:
v bI l:
v I
~ 12.0 ~ 7.0 ~ 5.0 bI
I
(!) (!) (!)

.&'.
0
...J 5.04 . 0 :]3.0
:] 10 0 13.0 17.0 8.0 12.0 3.0 7.0 11.0
LOG (A<FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
~ 20.0 ~ 15.0 ~ 13.0
ART ART
: ART ** **
~ 18 • 0 f--------.---r'" :::::
+
13.0 :::::
+
11.0
:c :c :c MAG
v v
~ 16.0 - - 0- - 11.0 -0- - I 9.0
I

:::: MAG
~ ~ bI
"- MAG "-
"t 14.0
"t 9.0
"t 7.0
-1- - -0--
SIDER SIDER
(!)
l:
(!)
l:
(!)
l: SIDER
v v I v
«v 12.0 5.0
(!)
~
(!)
7.0
9 ~
(!)

:] 10. 0'---~-"""'--"""" :]5.0 :]3.0

9.0 13.0 17.0 4.0 8.0 12.0 3.0 7.0 11.0
LOG (A(FE++)/(ACH+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
Phase relations in the system HCI- H20- (C~) - FeO- MgO. Saturation limits: brucite (a), fer-
rous oxide (b), peric1ase (c).
 131

~ 13.0 ~ 13.0 ~ 13.0

** ** 11.0 ** 11.0
ART ART ART
~ 11.0 ~ ~ 1
+ + + 1
:I: :I: :I:
v MAG v v
b
I
~ 9.0 bI ~ 9.0 MAG ~ 9.0 MA6'
I
"- "- "- I
"t 7.0 - -0-- "t 7.0 ~ "t 7.0 1
(!)
:I:
v
(!)
:I:
v
(!)
:I:
v
-'- - -0-
SIDER
~ 5.0 ~ 5.0 SIDER ~ 5.0 SIDER
(!) (!) (!)

g 3.03.0 7.0 11.0

g 3.02.0 6.0 10.0
g 3.02.0 6.0 10.0
LOG CACFE++)/<A<H+))**2) LOG <A<FE++)/<A<H+))**2) LOG <A<FE++)/<A<H+))**2)
~ 13.0 ~ 13.0 ~ 13.0
ART
** ** ART ** ART
~ 11.0 ~ 11.0 ~ 11.0
+ + +
:I: :I: :I:
v v v
~ 9.0 MAG ~ 9.0 MAG ~ 9.0 MAG
I I I
"- "- "-
"t _I-
b "t ~ "t 9
7.0 - -0-- 7.0 7.0
(!)
:I:
(!)
:I:
v
--+ - - -0- (!)
:I:
v
L - - -0-
v
~ 5.0 SIDER ~ 5.0 SIDER ~ 5.0 SIDER
(!) (!) (!)

g 3.03 . 0 7.0 11.0

0
3.02 . 0
...J
6.0 10.0
0
3.02 . 0
...J
6.0 10.0
LOG CA<FE++)/<A<H+))**2) LOG <ACFE++)/<A<H+))**2) LOG <A<FE++)/<A<H+))**2)
N 12 ..0 N 10.0 N 5.0
ART:J 1
** ** ** 1 MAG
~ 10.0 ~ 8.0 ~ 3.0
+
:I:
+
:I: MAG +
:I: - +- - -0-
v v v
8.0 6.0
I
~ 1.0 1
~ ~ bI
"- "- "-
"t 6.0 "t 4.0 - - .,. - - -0- "t-l.0
(!) (!) (!) SIDER
:I: SIDER :I: :I:
v v SIDER v I
~ 4.O ~ 2.O ;:;-3. ° bI
(!) (!) (!)

g 2·°2.O 6.O 10.O

g 0.0
-1.O 3.0 7.O
5-5.O
-3.0 1.0 5.0
LOG <A<FE++)/<A<H+))**2) LOG <A<FE++)/<A<H+))**2) LOG <A<FE++)/<A<H+))**2)
N 10.0 N 3.0 ~ 0.O
1
** MAG ** ** ART=t
~ 8.0
+ b
I
~
+
1.0
I
MAG ~2.0
+
:I: :I: :I: MAG
v
~ 6.O 1
v
;:;-1.0 ~ v
;:;-4.0
I

"- T - 0- - - -
"- -1- - -0- "- ~
"t 4.O "t-3.0 1 "t-6.0 1
SIDER (!) (!)
-1- - -c-
~ :I: SIDER :I:
v v v
oc( 2.0 ;:;-5.0 ;:;-8.0 1 SIDER
v
(!) (!) (!)

g O·°2.O 6.0 10.O 5-7 '~6.0 -2.0 2.0 5- 1_0(1°.0 -7.0 -3.0
LOG <A<FE++)/<A<H+))**2) LOG <A<FE++)/<A<H+))**2) LOG CA<FE++)/<A<H+))**2)
Phase relations in the system HCI-H20-(C~)-FeO-MgO. Saturation limits: brucite (a), fer-
rous oxide (b), periclase (c).
132
12.0 12.0 12.0

'"'
'"' 6.0 '"'
"± '"'
'"' 6.0
±
v v
6.0 ±
v SILVER
<{ <{ SILVER <{
'- SILVER '- '-
'"' '"'~ 0.0 '"'~ 0.0
-
-
~ 0.0
<{ <{ <{
0.-
v V V
<{ <{ <{

-
v v r- v ACAN
(!)-6.0 (!)-6.0 (!)-6.0
0
...J - ACAN
0
...J

-12.0~----~--~~~
ACAN 0
...J

-13f f.0 -8.0 -4.0 0.0
LOG (A(S04--)*(A(H+»**2)
12.0r-~--~~~~~
-12.0~----~--~~...J
-I 2. 0
-8. 0 -4. 0 0. 0 -I 2 . 0 -8 . 0 -4 . 0 0 .0
LOG (A(S04--)*(A(H+»**2) LOG (A(S04--)*(A(H+»**2)
12.0r-~--~--~~~ 12.0r-~--~--~~~

'"'
'"'
1'\

'"' "'"'
±6.0
v
±6.0
v
±
v
6.0 SILVER
<{ <{ SILVER <{
'- SILVER '- '-
'"'
~ 0.0 '"'~ 0.0 '"'~ 0.0
-
-'
<{
v
<{
v
<{
v ......-
<{ v
<{ _ <{
v v
ACAN
(!)-6.0 (!)-6.0
ACAN (!)-6.0
0 r- o 0
...J ACAN ...J ...J

-12.0~----~--~~...J -12.0~----~--~~~ -12.0~----~--~~...J

-I 2 .0
-8.0 -4. 0 0.0 -12.0 -8.0 -4.0 0.0 -12.0 -8.0 -4.0 0.0
LOG (A(S04--)*(A(H+»**2) LOG (A(S04--)*(A(H+»**2) LOG (A(S04--)*(A(H+»**2)
12.0r-~--~--~~~ 12.0 12.0

'"'
1'\ 1'\

'"' '"' 6.0

±
±6.0
1'\

± 6.0
v v v SILVER
<{ <{ SILVER <{
'- SILVER '- '-
"~ 0.0
-
1'\ 1'\

~ 0.0 ~ 0.0
<{
v
<{
v
<{ - <{
v
,..-

-
<{ <{
v v fo-- v
(!)-6.0 (!)-6.0 (!)-6.0 ACAN
ACAN
3 r- ACAN
0
...J
0
...J

-13,.f.0 -8.0 -4.0 0.0

-12.0~----~--~~~
- I 2 . 0 -8.0 -4 .0 0.0
LOG (A(S04--)*(A(H+»**2) LOG (A(S04--)*(A(H+»**2)
12.0r-~--~--~~~ 12.0 12.0r-~--~----~~

" "'"' 1'\

'"' 6.0
±6.0
1'\

v
± 6.0
v
±
v SILVER
<{ <{ SILVER <{
'- SILVER '- '-
'"' -
1'\ 1'\

~ 0.0 ~ 0.0 ~ 0.0

<{
v
<{
v
- <{
v r--

-
<{ <{ <{
v v r-- v
ACAN
(!)-6.0 (!)-6.0
ACAN (!)-6.0
o r- 0 0
...J ACAN ...J ...J

-12.0~----~--~~...J -12.0~~~~~~--...J
- I 2 . 0 -8 .0 -4.0 0.0 -12.0 -8.0 -4.0 0.0
LOG (A(S04--)*(A(H+»**2) LOG (A(S04--)*(A(H+»**2)
 133
12.0 12.0 12.0
,...
,... ,...,... ,...
,...
SILVER
iv 6.0 SILVER iv 6.0 SILVER iv 6.0
00(

,...
"-
<10.0
oo( - -
00(

,...
"-
<10.0 r-
00(
- 00(

,...
"-
<10.0
00(
- -
v v v
00( < 00(
ACAN
v ACAN v ACAN v
(!)-6.0 (!)-6.0 (!)-6.0
0 0 0
...J ...J ...J
-12.0~~~--~~~~ -12.0L---~~~--~...J
-1_21"1.0 -8.0 ":'4.0 0.0 -1 2.0 -8. 0 -4. 0 0. 0 -1 2 . 0 -8. 0 -4.0 0. 0
LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2)
12.0r-~~~~~~, 12.0r-~~--~~~--' 12.0r-~~~----~~

,... ,...
,... ,...
,...
,... SILVER
iv SILVER iv 6.0 SILVER iv 6.0
-
6.0

-
< <
-
00(

,...
"- ,...
"- ~
,...
"-
<1 0.0 r - - - - - <10.0 r- <10.0
00( <
v
<
v
v
< <
v ACAN 00(
v
ACAN
v ACAN
(!)-6.0 (!)-6.0 (!)-6.0
o 0 0
...J ...J ...J
-12. 0L-~~~~~----' -12.0L-~~~--~~~ -12.0L---~~------...J
-1 2 . 0 -8.0 -4.0 0. 0 - 12 . 0 -8.0 -4.0 0 .0 -1 2 . 0 -8. 0 -4.0 0 .0
LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2)
12. 0.-~~~~~--, 12.0
,...
,... ,...
,... ,...,...
SILVER SILVER
iv 6.0 SILVER iv 6.0 iv 6.0
<
,..."-
<10. 0
<
~
<10.0
L_--------- <
,...
"-
<10.0
,--

00(
v
<
v
<
v
< < < ACAN
v
ACAN
v ACAN v
(!)-6.0 (!)-6.0 (!)-6.0
o o 0
...J ...J ...J
-12. 0L-~~~~~----' -12.0~~~----~~~ -12.0L---~----~--~
-1 2 . 0 -8.0 -4.0 0 .0 -1 2 .0 -8 . 0 -4.0 0. 0 -12.0 -8.0 -4.0 0.0
LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2)
12.0r-~~~--~~-' 12.0r-~~--~~~--' 12.0r-~~~~--~,

,...
,... ,...
,... ,...
,... SILVER
SILVER
iv iv
- iv
6.0 SILVER 6.0 6.0

---------------
< < <
"- ,...
"- .- ,...
"-
,...
<10. 0 r- <10.0 <10.0
<
v
<
v
00(
v ACAN
<
v
<
v ACAN <
(!)-6.0
ACAN (!)-6.0 ~-6.0
o 0 o
...J ...J ...J
-12.0L---~~--~~...J -12.0L---~----~~~ -12.0~~~--~~~~
-1 2 . 0 -8 . 0 -4 .0 0.0 -12.0 -8.0 -4.0 0.0 -12.0 -8.0 -4.0 0.0
LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2)
134
20.0~--r-----------' 20.0~-----T--------'

A
A "" ""
± 10.0
v
± 10.0 ± 10.0t'- ......
<{
COy ~ ................. COy ~ ... COy
...... ...... ......
A ~ ':;: - -0- _...... - - -
r- - -........, - - -0
~ 0.0
u
r- ~ - - - -0- -
13':;: 0 . 0 i' ...... ;:)0.0
u
I'
.... b
v TO ...... V ....
<{ ...... ~ TO .... b . . . <{ ......
v .... b V V TO
(!)-10.0 ..... (!)-10.0 ...... (!)-10.0
o ......
......
o o
...J ...J ...J

-20 0'-----'-~-~--' -20.0'--~-~-~--' -20.0'--~~~~~--~

-4"0.0 -20.0 0.0 -40.0 -20.0 0.0 -40.0 -20.0 0.0
LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+))
20.0r--'-~----' 20.0~~-~----~ 20 . 0 r-~--.,-~-----,

""± 10.0 "

A
A

± "± 10.0~
v
<{
10.0
......
COy ~ " COy <
......
......
... ......
cov
r-- ~ ......
A ':;: I- -0 - _...... - - -
~0.0 r-~ - - - -0-- ~0.0 ~--...... - -
...........
-0- ;:) 0.0 r--
U u u ......
v ......
<{ TO ......
V
... b ~ TO .... b ....
v .... b ~ TO .... V
(!)-10.0 ..... (!)-10.0 ...... (!)-10.0
o ...... o o
...J ...... ...J ...J
-20.0L-~~-L--~---...J -20.0'--~~~~~--~
-2_04 1.0 -20.0 0.0 -40.0 -20.0 0.0 -40.0 -20.0 0.0
LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+))
20. 0r----r----~-----, 20.0r----~--~--~ 20.0r-~--ry-~-----,

"" "i5"+
A

±10.0
A

± 10.0 v
10.01' ......
v
<{ COy <{ ......
COy <{ ...... COy
...... ...... ......
A ..... ~ ......
':;: I- - - _...... [- - -0
~0.0 '-~----O-­ ~ 0.0 - - -'-...... - - 0 - - ;:)0.0 I'
U u ...... u ......
v ...... v .... b
<{
V TO ......
.... b
~ TO .... b ..... ~ TO ....
(!)-10.0 ..... (!)-10.0 ...... (!)-10.0
o ......
......
o o
...J ...J ...J

-20.0'--~~-U--~--~ -20.0'--------~------'
-2_041.0 -20.0 0.0 -40.0 -20.0 0.0 -40.0 -20.0 0.0
LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+))
20. 0r----r----~-----, 20. 0r-~-..--~-----' 20.0r----~r----,

"± 10.0 "

"± "
" 10.01'
V v
10.0 COy ±
~ ............ COy
<{ <{ ......
~..... COy ;::; ...... ~ ......
~0.0 ;...~ - - - -0-- ~ 0.0 - - -'-I' - -0- - ~ 0.0 I- - - """', - -0
u u ...... u ......
......
V
<{ ...... ~ TO ...... .... b ~ .. b
V TO ...... V v TO ....
(!)-10.0 .... b cD '0 . 0 .... (!)-10.0
o .... o o
...J ...... ...J ...J

-20.0'--~-~~~~-'
-2_04.1.0 -20.0 0. 0 -2~4'00. 0 -20.0 0.0 -40.0 -20.0 0.0
LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+))
Phase relations in the system HCl-H 20-CuO-H 2S-(H2S04). Saturation limits: cuprite (a),
chalcocite (b).
 135

,... ,...
,. . r- "± 10.0 ~ 1',
± 10.0 ' COY
......
.... b COY ! 10.0 .... b .... COY
,<
v .... b
.... ,
v
<
......
....
, <
;:::; - -0- -
......
""" - - -
,...
:j0.0
f- - - - .... - 0 - -
, ":j 0.0 - -0- - ...... -
......
- -
~ 0.0 "
U , ...... u ,
U
v v v
<
v
<
v
<
v
TO TO TO
(!)-10.0 (!)-10.0 (!)-10.0
o o o
-l -l ...J
-20.0~~-~....1---...J -20.0~~-~~--...J
-40.0 -20.0 0.0 -2~41.0 -20.0 0.0 -40.0 -20.0 0.0
LOG (A(HS-)*A(H+» LOG (A(HS-)*A(H+» LOG (A<HS-)*A(H+»
20.0.--~---r~---' 20. 0r--~-~-.-~---' 20.0r-----~-r~-,

,...
,...
± 10.0
r'-
,
"';' ..... , ~
± 10.0
.....
.......... b
COY ~ 10.0 .... b
,,...
~ .... b ....
, <
...... , .... COY ~
;:::; - -0- -
..........
...... -
COY
- -
:j 0.0
I- - - -- ...
,- 0,- - "
~ 0.0
- - 0 - - .... - - -
, ~ 0.0 "
U
v
uv ' , ~ ......
< < <
v
(!)-10.0
o
TO
cio - 10 . 0 TO v
(!)-10.0
o
TO

...J -l -l

-20 . 0L--~-~.1..-~----' -20.0~~-~~---...J

-40.0 -20.0 0.0 -2~4·1.0 -20.0 0.0 -40.0 -20.0 0.0
LOG (A(HS-)*A(H+» LOG <A<HS-)*A(H+» LOG (A<HS-)*A<H+»
20 . 0r--~-"""--'r--~---' 20.0r---~--'-~---' 20.0r---~--~--~---'

"" "" ,...,...

±10.0 r-, ,, COY ± 10.0 :-.., ,, COY +
~ 10.0
i'
.... b COY
,,... ,
v v
< < < ....
......

:j 0.0
I- - - -'
,- 0 - -
......
"~ 0.0 - - --' ~,- 0 - - ,...
:j0.0
--0-...:>...1----
,
U u u ......
v .... b v .... b v ,
< .... < .... < ,
v v v
(!)-10.0 TO (!)-10.0 TO (!)-10.0 TO
0 0 o
..J -l ...J
-20.e~----~J-~--~ -20.0~------~----~ -20.0~~-~~---...J
-40.0 -20.0 0.0 -40.0 -20_0 0_0 -40.0 -20.0 0.0
LOG <A(HS-)*A<H+» LOG <A(HS-)*A<H+» LOG <A<HS-)*A<H+»
20.0.----~r----, 20.0.---~~--~---, 20.0.----T----------,
,...
,... ,...
""
± 10.0~, ± 10.0 COY ± 10.0 COY
,
v v
~ , COY
...... <
...... , <
;:::;
~
,
,...
:j 0.0
f--O--'
,
--- "~ 0.0 ..... - -,
,- -0-- +'"
:) '" 1--'-I'--0---
"'. '"
u
v
' .. b
u
v ~
<
, ,
<
v
<
v
~-10 . 0 TO 'b ....
(!)-10.0 TO (!)-10.0
TO o ......
o o
...J -l -l

-20.0~~~~--~--~
-2_041.0 -20.0 0.0 -2_041.0 -20.0 0.0 -40.0 -20.0 0.0
LOG <A<HS-)*A<H+» LOG <A<HS-)*A<H+» LOG <A<HS-)*A<H+»
Phase relations in the system HCl-H 20-CuO-H 2S-(H 2S04). Saturation limits: cuprite (a),
chalcocite (b).
136
12.13 12.13
,...
,... ,...,...
"
"±
v
6.13 COPPER ± 6.13
v
COPPER ± 6.13
v
COPPER
« « «
...... ,...
...... ......
-a
"~ 13.13 a ~ 13.13
-0- "~ 13.13 CC
u
v
r- u
v CC u
v
«
v
(!)-6.13
CC «
v
(!)-6.eJ - «
v
(!)-6.eJ
COY
o o COY 0
....J r- ....J ....J
COY
-12.eJ~~~~~~--~ -12.eJ~~~~~--~~
-12_·~.eJ -6.13 -3.13 13.13 -9.13 -6. 13 -3 . 13 13 . 13 -9.13 -6.13 -3.13 13.13
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2)
12. eJ....---~-~~~--, 12. eJ....---~-~~~......-, 12.eJ,........~--~~~---,

,...
,... ,...
,...
"" COPPER
v
± 6.13 COPPER ±
v
6.13 COPPER ±
v
6.13
« « «
...... ,...
...... ,...
......
a
"~ 13.13 a ~ 13.13 ~ 13.13 CC
u
v
r- u
v CC u
v
« «v «
v CC v
<D 6 . eJ (!)-6.eJ (!)-6.eJ
o o 0 COY
....J ....J COY ....J
COY
-12. eJL.....-~~~~~ -12.eJ~~--~----~~ -12.eJL.....~~--~~_....J
-9.13 -6.13 -3.13 13 . 13 -9.13 -6.13 -3.13 13.13 -9. 13 -6.0 -3. 13 13 . 13
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2)
12. eJ....---~-~~~--, 12.13 12.13
,...,... ,...,...
"" COPPER
± 6.13
v
COPPER ±
v
6.13 COPPER ±
v
6.0
« « «
...... ,...
...... ,...
"-
r-- a
"~ 13 . 13 I=..!a:!.=-=c...=~-"-==--=, ~ 13.13 a ~ 13.0 CC
u
v
«v CC
u
v
«
v
CC u
v
«
v
-
(!)-6.eJ (!)-6.13 (!)-6.13
o 0 COy 0 COY
....J ....J ....J
COY
-12.eJ~~~~~~~~ -12.eJ~~~~--~--~ -12.13
-9.13 -6.13 -3.13 13.13 -9.13 -6 . 13 -3 . 13 13 . 13 -9 . 13 -6. 13 -3. 13 0 .0
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2)
12 .eJ,........~~~~~......-, 12.eJ,........~~--~--~, 12.eJ,........~~--~--~,

,...
" ,...,... "
± 6.13 ± 6.13 COPPER "± 6.13
COPPER
v COPPER v v
« « «
,...
......
~ 13.13 a
......
"~ 13.13 a - "-
" 13.13 - - - - - -a-
~ ce
u u CC u
v v v
« « «
v CC v v
(!)-6.eJ (!)-6.13 (!)-6.eJ
COY
0 o COY o
....J ....J ....J
COY
-12.eJ~~~~~~--~ -12.eJ~~----~~_....J
-9.13 -6.13 -3.13 13.13 -9 . 13 -6.0 -3.13 0 .0
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H.))**Z)

Phase relations in the system HCl-H20-CuO-(H2S)-H2S04. Saturation limit: cuprite (a).

 137
12.0 12.0

"
"± 6.0
COPPER ""± 6.0 COPPER ""± 6.0 COPPER
v v v
« « «
"" "
" 0.0
:!,
""
:!, 0.0 CC ~ 0.0
u u u
v v v
«
v
«
v
«
v
(.!)-6.0
COV (.!)-6.0
COV
(.!)-6.0 COV
0 0 o
.-J .-J .-J

-12.0~~------~~--l -12.0~~~------~~ -12.0~~~--------~

-I 8. 0 -I 2. 0
-6.0 0. 0 - 18 . 0 - 1 2 . 0 -6 . 0 0 .0 - 18. 0 -I 2 . 0 -6. 0 0. 0
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2)
12.0~~~~--~--~ 12.0~~--~~--~--, 12.0~~~~--~~-,

"" COPPER "" COPPER 1'\

1'\
COPPER
v
± 6.0 ± 6.0
v
± 6.0
v
« « «
""
:!, 0.0
""~ 0.0 "~" 0.0
u u u
v v v
«
v
«
v
«
v
(.!)-6.0
COV (.!)-6.0 COV t!i'6.0 COV
o o o
.-J .-J .-J

-12 . 0L--o.-~~~-"""""" -12.0~~~~------~ -12.0~~---~~--~

-1 8 . 0 -12.0 -6. 0 0. 0 -18.0 -12.0 -6.0 0.0 -1 8 . 0 - 12 . 0 -6. 0 0.0
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2)
12.0 12.0

" COPPER
" ""± 6.0
1'\
COPPER 1'\ COPPER
± 6.0
v v
± 6.0 v
« « «
"" "" 0.0
:!, CC "
" 0.0
:!, 0.0 ~
u u u
v v v
«
v
«
v
«
v
(.!)-6.0 t!i'6.0 COV (.!)-6.0
COV
COV
o 0 0
.-J .-J .-J

-12.0 -12.0 -12.0

-18.0 -12.0 -6.0 0.0 -18.0-12.0 -6.0 0.0 -18.0 -12.0 -6.0 0.0
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2)
12.0 12.0 12.0
COPPER
"'"' COPPER "" COPPER ""
± 6.0
v v
± 6.0 v
± 6.0
« « « CC
":!," 0.0 ":!," 0.0 CC ""
:!, 0.0
u U U
v v v
«
v
«
v
«
v
COV
(.!)-6.0 COV (.!)-6.0 COV t!i'6.0
0 0 0
.-J .-J .-J

-12.0~~------~~~ -12.0~---~~~--~ -12.0~------------~

- 18 . 0 - 12 . 0 -6. 0 0 .0 - 18 . 0 -1 2 . 0 -6 .0 0. 0 -I 8 . 0 - 12 . 0 -6.0 0 .0
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(ACH+))**2)

Phase relations in the system HCI-HP-CuO-(H 2S)-H 2S0 4. Saturation limit: cuprite (a).
138
c:;J 22. 0r--........~-~~~~.., c:;J 22. 0r---""---~~-~.., c:;J 22. 0r-,,~~~-~~--,
*
""*
*
"~*
: ' 'b,
± 12.01----," -a- J:
12.0
r\
~ 12.0
J:
MG
,
- -a- -"-,
v v
« «
v
~ 2.0
HM
v
~ 2.0
+ HM
,,
+
+ +
w w
u... PYRITE
u...
v-S.0 v-S.0
«v « PYRITE
v v
(!) (!) (!)
5t1S.0L-~---~~---~ 5t1S.0L-~---~~---~ 5t18.0L-~~-~~---~
-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0-20.0-10.0 0.0
LOG <A<HS-)*A<H+)) LOG <A<HS-)*A<H+)) LOG <A<HS-)*A<H+))

",
c:;J 22.0 c:;J 22.0 c:;J 22.0
* * *
"* "~* MG ""* MG 'b,
~ 12.01----"
J:
v
J:
v
12.0
-a- v
+
J:
12.0 ,
« «
j
~ 2.0
+
HM v
~ 2.0
+
HM ,
v
~ 2.0
+
,,
+ + + HM
w w w
u... u... u...
~S.0 PYRITE v-8.0 v-8.0
« «
v v
(!) (!) (!)
5t1S.0L-~~-~~~~ 5t18.0L-~---~~---~ 5t18.0L-~~-~~---~
-30.0 -20.0 -10.0 0.0 -30.0-20.0-10.0 0.0 -30.0-20.0-10.0 0.0
LOG <A<HS-)*A<H+)) LOG <A<HS-)*A<H+)) LOG <A<HS-)*A<H+))
c:;J 22.0
* MG' ,
c:;J 22.0
* 'b,
c:;J 22.0
*
,
,
"* - -"" , - a- "~* "* 'b,
~ 12.0
J:
v , J:
v
12.0
-a-
"J:+ 12.0 , ,MG
« « -a-
'b,
,
v
~ 2.0 HM ,,
w
+
+
u...
HM ,
PYRITE
~8.0 PYRITE
v
PYRITE
(!) (!) (!)
5t1S.0L-~---~~---~ 5t18.0 . 5t18.0L-~~-~~---~
-30.0 -20.0 -10.0 0.0 -30.0 -20 .0 -1 0.0 0.0 -30.0 -20.0 -10.0 0.0
LOG <A<HS-)*A<H+)) LOG <A<HS-)*A<H+)) LOG <A<HS-)*A<H+))
c:;J 22. 0r--.......~-~~--,r-..., c:;J 22.0 c:;J 22. 01"',
___~~~-~~--,

:..* , , MG * 'b, : 'b

"* " ,
! 12.0 -a- " ~ 12.0
MG
~ 12.0
J:
,MG
,

~ HM '
J:
v
« -a- v
« ,
'b, v v -a-
, ~ 2.0
+
+
HM , ~ 2.0
+
+ HM ,,
w w
u... u...
PYRITE ~8.0 v-8.0
« PYRITE
(!) (!) (!)
5t1S.0L---~-----~~ 5t18.0L-~-----~--~ 5t18 0L-~-L-~~---~
-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -3'0.0 -20.0 -10.0 0.0
LOG <A<HS-)*A<H+)) LOG <A<HS-)*A<H+)) LOG <A<HS-)*A<H+))

Phase relations in the system HCl- H 20 - PeO - H 2S - (H 2S04). Saturation limits: ferrous oxide
(a), pyrrhotite (b).
 l39
N 22. 0r-~,,-~~-~~--, N 22.0 N 22.0'--,,~~--~--'

~* 'b, * " 'b, **

"*
"+ MG "+
~ 12.0
:r:
v
«
"
""
MG
:r:
v
«
12.0
" :r:
v
«
12.0

v -0- v -0- v
;:::; 2.0 ;:::; 2.0 ;:::; 2.0
+
+
lJJ
HM "" +
+
lJJ
HM
"
+
+
lJJ
""
lL. u.. lL.
v-8.0 v-8.0 ~8.0
« PYRITE « PYRITE
(!) (!) (!)

~18.0~~~~~~-~~ ~18.0L-~~~~~-~~ ~18.0L---~L-~~---~

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+))
N 22.0 N 22.0 N 22.0
* " 'b, * " 'b, * " , b,
"*+ 12.0 ""* 12.0 ""* 12.0
" MG MG MG
:r:
v v
+
:r: "" +
:r:
v ""
«
v
;:::; 2.0
«
v
;:::; 2.0
- 0- - " «
v
;:::; 2.0 -0- - "
+
+
+
+ HM "" +
+ HM ""
" "
lJJ lJJ lJJ
lL. u.. lL.
v-8.0 v-8.0 ~8.0
«
v
PYRITE « PYRITE PYRITE
(!) (!) (!)

~18.0L-----~~~-~~ ~ 18'. 0'---~~'--~~-~~

~1_83·J'.0 -20.0 ~'10.0 13.0 -30.0 -20.0 -10.0 0.0 -30.0-20.0-10.0 0.0
LOG CACHS-i*ACH+)) LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+))
N 22.0 " N 22.0 N 22.0
* * *
""* 12.0
'b,
""* 12.0 " 'b, "*
MG ":r:+ 12.0 " , b,
+
:r: "" +
:r: MG MG
v
«
"
v
« "" v
«
v
;:::; 2.0
-0- v
;:::; 2.0 -0-
"
v
;:::; 2.0 ""
+ "" + + -0- -":>..
+
lJJ
lL.
HM
"
+
lJJ
u.. HM "" +
lJJ
u.. HM ""
PYRITE "
v-8.0 V-8.0
""
~8.0
« PYRITE «
v PYRITE
(!) (!) (!)
~18.0~--~~~~~~~ ~18.0'---~~-~~---~ ~18.0~---L------~~~
-30.0-20.0-10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+))
N 22.0 N 22. 0.-~--~--~-., N 22. 0.-~--~--~---.,
* **
""* 12.0 " 'b, "+
*
"*
+
:r:
MG
:r:
12.0 MG "+ 12.0
:r:
v
«
v
"" v
«
v
v
«
v
MG

;:::; 2.0 -0- -~ ;:::; 2.0 ;:::; 2.0

+ + +
+
lJJ
u..
HM "" +
lJJ
u..
t1i
u..
'b, PYRITE
PYRITE " "
v-8.0 ~8.0 v-8.0
« HM « -0- -
(!)
(!)
" "

~18.0
(!) "
~18.0L---~~~~~~~ " ~18.0L-~---~~---~
-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+)) LOG CACHS-)*ACH+))
Phase relations in the system HCI-H 20-FeO-H 2S-(H 2S0 4). Saturation limits: ferrous oxide
(a), pyrrhotite (b).
140
~ 24. ar-~~-~~-"7"--' ~ 24. ar-~~-~~--.., ~ 24. a.---~~-~~----,

**
MERCURY **
r.
**
r.
r.
r. r. MERCURY r.
+ 18.13 + 18.13 + 18.13 MERCURY
:x: :x: :x:
v v v
<t <t <t
v v v
~ 12.13 ~ 12.13 ~ 12.13
+ CINN + +
+
(!)
+
(!)
+
(!)
:x: :x: CINN :x:
~ 6.13 ~ 6.13 ~ 6.13
v v v
(!) (!) (!)

:3 13.13
-24.13 -16.13 -8.13 13.13
313.13
-24. a -16. a -8. a a .a 313.13
-24. a -16. a -8. a a. a
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2)
~ 24. ar-~~-~~-.....",.., ~ 24. a,--~~-~~----, ~ 24. a.---~~-~~--...,
* MERCURY ** **
"~*
r. r.
MERCURY
18.13 ~ 18.13 ~ 18.13 MERCURY
:x: :x: :x:
v
v v
<t <t <C
v v v
~ 12.13 ~ 12.13 ~ 12.13
+ CINN + +
+ +
(!)
+
(!)
(!)
:x: :x: :x:
~ 6.13 ~ 6.13 CINN ~ 6.13
v v v
(!) (!) (!)

313.13 313.13 313.13

-24 . a -16. a -8. a a.a -24. a -16. a -8. a a .a -24. a -16. a -8. a a. a
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2)
~ 24. ar-~~-~~--,., ~ 24. ar-~~-~~--..., ~ 24. ar-~~-~~--...,

** *
*
r.
**
r. MERCURY r.
~ 18.13 ~ 18.13 + 18.13
:x: :x: :x: MERCURY
v v v
<t <C <C
v v v
~ 12.13 ~ 12.13 ~ 12.13
+ CINN + +
+
(!)
+
(!) (!)
+
:x: :x: CINN :x:
~ 6.13 ~ 6.13 ~ 6.13
v v
(!) (!) (!)

313.13. 313.13 313.13

-24.13 -16.13 -8.13 13.13 -24.13 -16.13 -8.13 13.13 -24.13 -16.13 -8.13 13.13
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2)
~ 24. ar-~~-~~--~ ~ 24. ar-~~-~~--.., ~ 24. ar-~~-~~----'
*
"~* **
r.
MERCURY **
r.
r.
18.13 ~ 18.13 + 18.13
:x:
v
:x:
v
:x:
v
MERCURY
<C <t <C
v v v
~ 12.13 CINN ~ 12.13 ~ 12.13
+ + +
+
(!)
+
(!)
+
(!)
:x: :x: CINN :x:
~ 6.13 v 6.13 ~ 6.13
<t
v v v
(!) (!) (!)

313.13 313.13 313.13

-24.13 -16.13 -8.13 13.13 -24.13 -16.13 -8.13 13.13 -24.13 -16.13 -8.13 13.13
LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*(A(H+))**2) LOG (A(S04--)*CACH+))**2)

Phase relations in the system HCl- H 20 - HgS - (H 2S) - H 2S04.

 141
~ 12. 0..-~--~--~......., ~ 12. 0r-~--~--~--' ~ 12. 0r-~--~--~---'

** MERCURY * MERCURY *
-:;:- 6.0
'"*
'"+ 6.0 '"*
'"I+ 6.0
MERCURY
I I
v v v
« « «
v v v
~ 0.0 ~ 0.0 ~ 0.0
+ + +
+ + +
(!) CINN (!) (!)
I I M-CINN I
v-6.0 M-CINN
~6.0 ~6.0 «
v v v
(!) (!) (!)
grI2.0L-~~-~~-~~ gr 12.0 gr 12. 0 '--~~~~~-~-'
-24.0 -16.0 -8.0 0.0 -24.0 -16.0 -8.0 0.0 -24.0 -16.0 -8.0 0.0
LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2)
~ 12. 0r--~~-~~----' ~ 12. 0r-~--~--~--' ~ 12. 0r-~--~--~---'
* MERCURY
:I:
*
'"* '"*
:I:
'" MERCURY MERCURY
-:;:- 6.0 -:;:- 6.0
I
'"+ 6.0
I
I
v v v
«
v
«
v
«
v
~ 0.0 ~ 0.0 ~ 0.0
+ + +
+ + +
(!)
I
CINN (!)
I M-CINN
(!)
I
~6.0 ~6.0 ~6.0 M-CINN
v
(!) (!) (!)
grI2.0'--~~-~~-~~ gr12.0 grI2.0L-~-~~-~~~
-24.0 -16.0 -8.0 0.0 -24.0 -16.0 -8.0 0.0 -24.0 -16.0 -8.0 0.0
LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2)
~ 12. 0..-~------, ~ 12. 0r-~--~--------' ~ 12. 0r-~--~--~--'
** MERCURY
:I:
:I:
MERCURY
**
I
-:;:- 6.0 -:;:- 6.0
I
"I"+ 6.0 MERCURY
v v v
« « «
v v v
~ 0.0 ~ 0.0 ~ 0.0
+ + +
+ + +
(!)
I
M-CINN (!)
I
(!)
I
~6.0 ~6.0 M-CINN ~6.0 M-CINN
v v v
(!) (!) (!)

gr12.0 gr12.0 grI2.0L-~---------J

-24.0 -16.0 -8.0 0.0 -24.0 -16.0 -8.0 0.0 -24.0 -16.0 -8.0 0.0
LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2J
~ 12. 0r-~--~--~-----' ~ 12. 0r-~--~--~--' ~ 0.0
:I: :I: :I:

""*-+-6.0
:I: :I:
MERCURY MERCURY
""I+ 6.0 "I'"+ 6.0 MERCURY I
v v v
« « «
v v v
~ 0.0 ~ 0.0 ~12.0
+ + +
+
(!)
+
(!)
+
(!)
I M-CINN I I M-CINN
~6.0 ~6.0 ~18.0
v M-CINN
(!) (!) (!)

3-12.0 0 12 .0 0 24.0'--~~-~--~-'
-24.0 -16.0 -8.0 0.0 J -24.0 -16.0 -8.0 0.0 J -24.0 -16.0 -8.0 0.0
LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2) LOG CACS04--)*CACH+))**2)

Phase relations in the system HCl- H 20 - HgS - (H 2S) - H2S04.

 142
'"''"'
N
12.0
"N'"'
12.0 '"'
'"'
N
12.0

** ** *
';' 6.0
I
"+
I
6.0 '"'*+ 6.0
I
v v v
«
v
«
v
«
v
GALENA GALENA GALENA SL
:::: 0.0 :::: 0.0 SL :::: 0.0
+ SL + +
+
(lJ
+
(lJ
+
(lJ
Cl. Cl. Cl.
v-6.0 v-6.0 v-6.0
« « «
v v v
l') l') l')
o o o
~-12.0L-~------~--~~ ~-12.0~--------~----~ ~-12.0L---------~--~~
-12.0 -4.0 4.0 12.0 -12.0 -4.0 4.0 12.0 -12.0 -4.0 4.0 12.0
LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2))
~ 12. 0r-~--~----..., ~ 12. 0r-~--~--~---' ~ 12. 0 r-~--~------,...,
N N N
* * **
"I+* 6.0 "+*
I
6.0
r.
+ 6.0
I
v v v
« « «
v v v
GALENA GALENA GALENA SL
:::: 0.0 :::: 0.0 SL :::: 0.0
+ SL + +
+ +
(lJ
+
(lJ
(lJ
Cl. Cl. Cl.
~6.0 v-6.0 v-6.0
« «
v v v
l') l') l')
o o o
~-I 2 . r '--........------~--~--' ~-12.0~--------~----~ ~-12.0L---------~~~~
-12 0 -4.0 4.0 12.0 - 12 . 0 -4.0 4.0 12.0 -12.0 -4.0 4.0' 12.0
LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2))

~ 12. 0r-~--~----..., ~ 12. 0r-~--~----..., ~ 12. 0r-~--~------,..,

N N N
* * **
'"'*+ 6.0 "+* 6.0
r.
+ 6.0
I I I
v v v
«
v
«
v
«
v
GALENA GALENA GALENA SL
:::: 0.0 :::: 0.0 SL :::: 0.0
+ SL + +
+
(lJ
+
(lJ
+
(lJ
Cl. Cl. Cl.
v-6.0 v-6.0 v-6.0
« « «
v v v
l') l') l')
o o o
~-12.0L-~------~----~ ~-12.0~-------------~ ~-12.0L---~------~~
-12.0 -4.0 4.0 12.0 -12.0 -4.0 4.0 12.0 - 12 . 0 -4 . 0 4 .0 I2 . 0
LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2))

"'"' '"'
12.0 r. 12.0 ~ 12. 0r-~--~-""""--",-,,,,,
N N N
** ** *
';' 6.0
I
r.
I
+ 6.0 '"'+* 6.0
I
v v v
« « «
v
GALENA
v
GALENA v GALENA
:::: 0.0 :::: 0.0 SL :::: 0.0 SL
+ SL + +
+
(lJ
+
(lJ
+
(lJ
Cl. Cl. Cl.
v-6.0 v-6.0 ~6.0
« «
v v v
l') l') l')
o o o
~-12.0'--~------------~ ~-12.0~--------~----~ ~-12.0'----------~----~
-12.0 -4.0 4.0 12.0 - 12 . 0 -4 . 0 4.0 12 . 0 -12.0 -4.0 4.0 12.0
LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2))
Phase relations in the system HCl- H20 - PbS - (H 2S) - ZnS.
 143
A 12. er--~-~~-'7'-' ;:: 12. er---~--~......,.---' ;:: 12. er---~---""'T'--'
N N N

**
';:' 6,13
A
**
+ 6.13 ';:'
*
* 6.13
I I I
v v v
« « «
v GALENA v GALENA v GALENA
~ 13.13 SL ~ 13.13 SL ~ 13.13 SL
+ + +
+ + +
aJ aJ aJ
Cl. Cl. Cl.
v-6.e ::;-6 . 13 ::;-6.13
«
v v v
(!) (!) (!)
o o o
~-12.e~~~-~~---~ ~-12.eL-~---~---~~ ~-12.eL-~~----~~~
-12.13 -4.13 4.13 12.13 -12.13 -4.13 4.13 12.13 - 12 .13 -4.13 4 .13 12 .13
LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2))
;:: 12. er---~--~-T"l ;:: 12. er-~-~--~--'-'_ ;:: 12 . 13 r-~-~--~--,----,
N N N

*+* 6.13
A **
';:' 6.13
**
A
+ 6.13
I I I
v v v
« « GALENA « GALENA
v GALENA v v
~ 13.13 SL ~ 13.13 SL ~ 13.13 SL
+ + +
+ + +
aJ aJ aJ
Cl. Cl. Cl.
v-6.e v-6.e ::;-6.13
« «
v v v
(!) (!) (!)
o o o
~-12.eL-~~--~~~~ ~-12.eL----~--~----~ ~-12.e~~-~~~~~~
-12.13 -4.13 4.13 12.13 -12.13 -4.13 4.13 12.13 -12.13 -4.13 4.13 12.13
LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2))

12.13 12.13 " 12.13

A
N
A
N "N
** **
A
**
A
';:' 6.13 + 6.13 + 6.13
I I I
v v v
« « GALENA « GALENA
v GALENA v v
~ 13.13 SL ~ 13.13 SL ~ 13.13 SL
+ + +
+ + +
aJ aJ aJ
Cl. Cl. Cl.
v-6.e v-6.e v-6.e
« « «
v v v
(!) (!) (!)
o o o
~-12.eL-~------~--~ ~-12.eL-~---~-----~ ~-12.e~--~--~~---~
-12.13 -4.13 4.13 12.13 -12.13 -4.13 4.13 12.13 -12.13 -4.13 4.13 12.13
LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2))

"
N
12.13 "N
A
12.13 A
N
12.13

** ** ** GALENA
';:' 6.13 ';:' 6.13 ';:' 6.13
I I I
v v v
« « GALENA «
v GALENA v v
~ 13.13 SL ~ 13.13 SL ~ 13.13 SL
+ + +
+ + +
aJ aJ aJ
Cl. Cl.
~6.e
«
v-6.e
«
v-6.e
«
v v v
(!) (!) (!)
o o o
~-12.eL---~-~~---~ ~-12.eL---~-~~---~ ~-12.eL---~-~~---~
-1 2 . 13 -4.13 4 .13 1 2 .13 -12.13 -4.13 4.13 12.13 -12.13 -4.13 4.13 12.13
LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2)) LOGCACZN++)/CACH+)**2))
Phase relations in the system HCI- H20 - PbS - (H 2S) - ZnS.
 144

~ 40 0 ~ 20 .0 ~ 20 0

**
r.
**
r.
HG **
r.
r. HG r. r. HG
+ 25. 0 + 12.0 CP + 12 .0
I I I
v v v
-<
v
-<
v
-<
v
~ 10.0 ~4 0 ~4 0
+ + +
+ + +
w w PYRITE w
u.. u.. u..
v-5.0 v-4 .0 v-4 .0
-<
v
-<
v
-<
v
(!) (!) (!)
o o o
.J- 20 . 0'--"'''--~~....L.-~~ -L'20L-~~~~~~~~ .J-120L---~-L~~~~~
-24.0 -18.0 -12.0 -6.0 -20.0 -14.0 -8.0 -2.0 - 18 . 0 - 12 . 0 -6. 0 0 .0
LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+))
~ 40 . 0 .--~~-~-r-"~-' ~ 20. 0r--~---Tr~--' ~ 20 . 0 r----~--~---r.,..--,
* ** HG **
",....+* 25.0 A
A
+ 12.0
r.
'; 12.0
HG
I I I
v v v
-<
v
-<
v
-<
v
~ 10.0 ~4 0 ~4 0
+ +
PYRITE
+
+ + +
w w w
u.. u.. u..
v-5.0 v-4 .0 v-4 .0 PYRITE
-<
v
-<
v
-<
v
(!) (!) (!)
o o o
.J- 20 . 0L........<:~~~--'--~.>..J .J_ 12 . 0 '---_-.L..~~............-'--' .J-120L-~~~----~~~
-24.0 -18.0 -12.0 -6.0 -20.0 - 1 4 . 0 -8 0 -2.0 - 1 8 . 0 - 12 . 0 -6. 0 0 .0
LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+))
~ 40. 0.---~---.--,--~...., ~ 20 .0 ~ 20 0

**
r.
r.
HG **
r.
r.
HG
**
r.
r. HG

~,
+ 25.0 + 12.0 + 12. 0
I I BN I
v v v
-< -< -<
v v -b- - v
~ 10.0 ~4 0 ~4 0
+ -b + +
+ +
w PYRITE +
w w PYRITE
u.. u.. u..
v-5.0 v-4. 0 v-4. 0
-<
v
-<
v
-<
v
(!) (!) (!)
o o o
.J- 2 0. 0'---'''--~~~---'LJ .J-12.0L-~~~---J~~ .J_120L-__~-L~__~~U
-24.0 -18.0 -12.0 -6.0 -20.0 - 1 4 . 0 -8.0 -2.0 - 18 . 0 - 1 2 . 0 -6. 0 0 .0
LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+))
~ 40. 0r-~~-~...,...,r-~-, ~ 20 . 0r--~---rr-~...., ~ 20. 0r--~--~,.,~....,

** /1 **
r.
-:; 25.0
I
v
HG
/_ I BN
~ 12.0
I
v
HG
:
~

~
+ 12.0
HG

CP
I I

BN
-<
v CP -<
v
-<
v
~ 10.0 ~ 4 0 ~ 40 1--------- ~ -b
+
w
+ - - - - --b
PYRITE
+
+
w w
+
+
PYRITE
,
u.. u.. u..
v-5.0 v-4.0 v-4.0
-<
v
-<
v -<
v
(!) (!) (!)
o o o
.J- 20 . 0 L-..<:"'--~~...l..------''--' .J_ 12 . 0 L-~__'----__.......L_ _l.-....J .J_ 1 2 0 '---~~--'-____.L.....L..J
-24.0 -18.0 -12.0 -6.0 -20.0 -14.0 -8.0 -2.0 - 18 . 0 - 12 . 0 -6. 0 0. 0
LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+))

Phase relations in the system HCI-HP-Cu20-FeO-H2S-(H2S04), at log(aH+a Hs -) = -10.0.

Saturation limits: chalcocite (a), pyrrhotite (b).
 145

~ 20 0 ~ 20 0 ~ 20 .0

,..,** * ,..,**
1
1'1G aI ,..,
,..,* 1'1G
1'1G
'.;' 12. 0
J:
BN + 12 .0
J:
';' 12. 0
J:
v v v
-<
v
-<
v
-<
v
~4 0 ~4 0 ;::; 4. 0
+ + +
+ + +
w w W
LL LL LL
v-4 .0 v-4. 0 PYRITE v-4 .0
-< -< «
v v v
(!) (!) (!)
o o o
...J_ 12 . 0 '--~L..-~-'-'-""""""'-' ...J- 12 0'--~~~~"""""'~ ...J_ 12 . 0 '--~.--.L~~""""'-"
-15.0 -9.0 -3.0 3.0 -15.0 -9.0 -3.0 3.0 -15.0 -9.0 -3.0 3.0
LOGCACCU+)/ACH+» LOGCACCU+)/ACH+» LOGCACCU+)/ACH+»
~ 20. 0.---~-~.....,.......--, ~ 20 0 ~ 20 0
** *
,... ,..,•*
,.., 1'1G ,...*
';' 12.0
J:
+ 12. 0
J:
1'1G "+ 12 0 1'1G
J:
v v v
-<
v
-<
v
-<
v
H1'1
~ 4.0 ~4 0 ~ 4. 0
+ + +
+
W
+
w W
+
LL LL LL
v-4.0 v-4 0 v-'I .0
-< -< -< PYRITE
v v v
(!) (!) (!)
o o o
...J_ 12 . 0'--~L-~....L-"""""-' ...J_ 12 . 0 '--~.-L-~""""""-----'-' ...J- 12 . 0'--~~--.l...o-.l..J
-15.0 -9.0 -3.0 3 0 -15.0 -9.0 -3 0 3.0 -15.0 -9.0 -3.0 3.'
LOGCACCU+)/ACH+» LOGCACCU+)/ACH+» LOG(A(CU+)/A(H+»)
~ 20. 0.---~-~,......,~--, ~ 20 . 0r---~----.-r~--' ~ 20 0
*
,.., ,..,•* ,..,**
,..,* ,.., 1'1G ,..,
+ 12.0 1'1G + 12 0 + 12 0 1'1G
J: J: J:
v v v
-< -< BN -<

I--_~'~
v v v
~ 4.0 ;::; 4.0 ~'I 0
+ + 1 + BN
W
+ W
+ - - - ~--b W
+
1
LL LL LL
v-4.e
-<
v-4.0
-<
v-4. 0
-< 1- -b
v v v PYRITE I
(!) (!)
o ~ o COY
...J_ 12 . 0 '--~.L-~-'---'---' ...J- 12 . 0'--~~--'--l.....--' ...J_ 12 . 0'--~~--"----L.l.----'
-15.0 -9.0 -3.0 3,0 -15.0 -9 0 -3.0 3 0 -15.0 -9.0 -3.0 3 0
LOGCACCU+)/ACH+» LOGCACCU+)/ACH+» LOGCACCU+)/ACH+»

~ 20 0 ~ 20. 0r---~---.......~--' ~ '10 0

,..,**
~5. HG~BN
*
,..,
1'1G ,..,* 1'1G
?J: 12 0 + 20 0
J:

~10 _~l-b
v v
-<
v
CP -<
v
~4 0 0 ~ 00
+
+ - - -- t
w
PYRITE +
+
w W
LL PYRITE LL LL
v-4. 0 v-25.0 v-20 0
-<
v
-<
v
:3 . PYRITE-
(!) (!) (!)
o o o COV
...J-12.0L-~~--L-~~~ ...J-40.0~~~--~~~--' ...J-40.0~~~~~~~~
-1 8 . 0 -1 2 . 0 -6. 0 0 .0 -20.0 -14.0 -8.0 -2.0 -24.0 - 18 . 0 - I 2 0 -6 0
LOGCACCU+)/ACH+» LOGCACCU+)/ACH+» LOGCACCU+)/ACH+»

Phase relations in the system HCl-H20-Cu20-FeO-H2S-(H2S04), at log(aH+a Hs -) = -10.0.

Saturation limits: chalcocite (a), pyrrhotite (b).
 146

c::J 40 0 c::J 20 0 c::J 20 0

** *
,... ,...,...**
,...*
MG
MG MG
~ 25. 0 + 12 .0 + 12. 0
I I I
v v v
<t
v
« «
v v
,... 10 .0
"- ;:::;4 0 ;:::;4 0 HI'!
+ + PYRITE +
+ + +
w w W
lJ.. lJ.. lJ..
~5 .0 ~4. 0 v-4 .0
<t <t «
v v v
(!) (!) (!)
o o o
..J- 20 . 0L-L.-~-~-'-~---" ..J_12.0L-~~~~~-L--~ ..J_ I 2 . 0'--........~~----'"-W--J
-24.0 -18.0 -12.0 -6.0 -20.0 -14.0 -8 0 -2.0 -15.0 -9.0 -3.0 3.0
LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+))
c::J 40 . 0 r----~-.,r--l~-, c::J 20 0 c::J 20 .0

** MG
*
,...* MG ,...,...**
~ 25.0 + 12. 0 + 12 .0 MG
I I I
v v v
<t <t «
v v v
;:::; 10.0 ;:::; 4. 0 ;:::; 4. 0
+ + +
+ + +
W w PYRITE w
lJ.. lJ.. lJ..
v-5.0 v-4 .0 v-4 .0
<t <t «
v v v
(!) (!) (!)
o o o
..J-20.0L-~~--~~--~~ ..J_ 12 . 0 '--~---..L._~--'-'----U ..J- 12 . 0'--........~~----""-~
-24.0 -18.0 -12.0 -6.0 -20.0 -1 4 0 -8 0 -2.0 -15.0 -9.0 -3.0 3.0
LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+))
c::J 40. 0 .------~-....---.~..., c::J 20 0 c::J 20 0
,...** MG ,...**
,...
MG *
,...
,...* MG
~ 25.0 + 12. 0 + 12 .0
I I I
v v
v
<t
v
«
v
;:::; 10.0 ;:::; 4. 0 ;:::;4 .0
+ + PYRITE +
+ + +
W W W
lJ.. lJ.. lJ..
v-5.0 v-4 .0 v-4 .0
« «v «v
8 co,,: (!)
o
(!)
o
..J- 20 . 01L..-..Co..-~~~~--" ..J_ 12 . 0 '--~--.L~~-'--"---,-, ..J_ 12 . 0 '--~~-L.._~-1.--JI
-24. 0 -1 8 . 0 -12 . 0 -6. 0 -20.0 -14.0 -8.0 -2.0 - 18 . 0 -1 2 . 0 -6. 0 0 .0
LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+))
c::J 40 . 0r----~~,-~-, c::J 20. 0r----~~~~, c::J 20. 0 , - - - - - - , r r ,
,...** *
,... *
MG ,...* MG ,...* MG

~BN
~ 25.0 + 12.0 ~! BN + 12.0
I I

v
CP ~ ~------~ -b
v
«
v
;:::; 10.0 ;:::; 4.0 CP ;:::; 4 0
+ -b-- + +
+ + +
W PYRITE W
lJ..
PYRITE W
lJ..
v-5.0 v-4.0
lJ..
v-4.0 PYRITE
« «v <t
v
v
g
J
(!)
COY I o
(!)
o
..J- 20 . 0 ..J_ 1 2 . 0 '--~---..L._~-'---'-->-J ..J_ 12 . 0 '--~~-L.._~-L.----lJ
-24.0 -18.0 -12.0 -6.0 -20.0 -14.0 -8.0 -2.0 - 18 . 0 - 1 2 . 0 -6. 0 0 0
LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+))

Phase relations in the system HCI-H20-Cu20-FeO-H2S-(H2S04), at log(aH+a Hs -) = -11.0.

Saturation limits: chalcocite (a), pyrrhotite (b).
 147

~ 20 0 ~ 20 . 0'--~~--~"""'"T""""1 ~ 20. 0 ,--~~--.-.....--,

**
r. **
r.
**
r.
r. r.
+ 12. 0 MG + 12.0 MG '; 12.0 MG
I I I
v v v
4: 4: «
v
~ 40
v
~ 4.0
...., --b- v
~ 40
- -b-
+ HM + HM + HM
+ +. +
w w W
lJ... lJ... lJ...
v-4.0 v-40 v-4.0
4: 4: 4:
v v v
(!) {!) (!)
a a a
..J_ I 2 . 0'--~.L.-~"""""'~l...J -L I 2 . 0 '---~.....L.-~~..I.....--lJ -L12.0~~~-~~--~
-IS.0 -9.0 -3.0 3.0 -I S . 0 -9.0 -3.0 3.0 - I 2 . 0 -6. 0 0 .0 6 .0
LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+))
~ 20 0,--~~--......,~--, ~ 20 0 ~ 20. 0'--~~--~---r--"

,...** **
r. **
r.
r.
':.:' 12.0
I
MG
I
+ 12 .0 MG 712.0
I
MG
v v v
4:
v
4:
v
«
v
~ 4 0 ~4 0 - -b-- ~ 40 - - -b--
+ HM + HM +
+ +. + HH
w w W
lJ... lJ... lJ...
v-4.0 v- 4 . 0 v-4.0
4: « <C(
v v v
(!)
a
{!)
a 8 COY
..J_ I 2 . 0 '--~.L.-~-'-'------''-' -L 12. 0'--~..o.L..~~""""""""" -L I 2 0'--~""""""~~""""'-"
-IS.0 -9.0 -3.0 3.0 -IS.0 -9.0 -3.0 3.0 -15.0 -9.0 -3.0 3.0
LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+))
~ 20 . 0...-~~--.....,......,......---. ~ 20 0 ~ 20 . 0r-~~---rr~--'
**
r.
**
r.
**
r.
r. MG MG
+ 12.0 '; 12. 0 BN '; 12.0
I
v
I
v
I
v
BN
4: 4: <C(
v v v
~ 4.0 ~4 0 CP~ ~4 0
+ + jL -b +
+ + +
W w W
lJ...
v-4.0
lJ...
v-4. 0
lJ...
v-4. 0 -b- -
4: <C( <C(
v v
(!) {!) ~ PYRITE
a OV a
..J_ I 2 . 0'---~...-..L~--'-""""'-J -L I 2 . 0 '---~~.<..-............~-'
-IS.0 -9.0 -3.0 3.0 -IS.0 -9.0 -3.0 3.0
LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+))
~ 20. 0'--~~--~---rr.,., ~ 20 . 0,--~~--........,..--, ~ 30. 0r-~~--~-r"'I"'--'

,...** *
* MG /
** MG
MG .,...
r. r.
'; 12.0
I I
+ S.0 /cp : BN
...---....
r.
I
+ IS.0
v v v
« « I <C(
v v v
~ 4.0 ;::-10.0 I
+ + ~+ '" 0
+ + +-
W W W
lJ... lJ... lJ...
~4.0 PYRITE v-2S.0 v-IS .0
« <C(
v v v
{!) {!) {!)
o a o
..J_12.0L---~-4---~~ ..J-40.0~--~-~~~~ ..J-30.0~--~---~~~
- I 8 . 0 - I 2 . 0 -6 . 0 0 .0 -20.0 -14.0 -8.0 -2.0 -24.0 -18.0 -12.0 -6 0
LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+)) LOG(A(CU+)/A(H+))

Phase relations in the system HCl-H20-Cu20-FeO-H2S-(H2S04), at log(aH+a Hs -) = -11.0.

Saturation limits: chalcocite (a), pyrrhotite (b).
148
~ 413 13r-~~--......,,-.....--, ~ 213 . 13 ...---~---.-,,-.----, ~ 213.13
* * *
"~* 25 13
"~* 12.13
MG BN "';* 12.0 MG
:r: :r: :r:
v
«
v
« b- v
« - -b-
v v v

co~
~ 113.13 ~4 .13 ~ 'Ie
+ + + HM
+ + +
W w W
I.L I.L PYRITE I.L
v-5 13 v-4 .13 v-4.e
« « «
v
(!) g v
(!)
o
....1_1 2 . eL-.-L~~--..L...--"';'--I
....I-12.eL-~~----~~~
-1 8 . 13 - 12 . 13 -6. 13 13 . 13 -15".13 -9.13 -3.13 3 13
LOG(A(CU+)/A(H+» LOG(A(CU+)/A(H+»
~ 413. e.--~~--........,-r--' ~ 213 13 ~ 213 13
* * *
"~* 25.13 "* MG BN "*
"+ MG
~ 12. 13 12. 13
:r: :r: :r:
v
«
v
« - - - - - b- v
«
v
~ 113.13
v
~ 'Ie
+
cl, v
~ 'Ie
+ HM
+
+ + +
W W W
I.L I.L I.L
v-5.e v-4.e v-4.e
« «
v
«
v
(!) (!) ~ COy I
o o
....I-12.eL-~~---~~~ ....1- 12 . 13
- 18 . 13 - 12 . 13 -6. 13 13 . 13 -15.13 -9.13 -3.13 3.13
LOG(A(CU+)/A(H+» LOG(A(CU+)/A(H+»
~ 413. 13r-~~-~"""'T-r--' ~ 213 13 ~ 213 13
* * *
*
*
"725 0 MG
"*
~ 12. 13
MG "~12 13 HG
:r: :r: :r:
v v v
«
v
«
v
«
v
~ 113.13 ~ 'Ie ~ ".13
+ + + HM
+ + +
w W w
I.L I.L
«t;..5 . 13 v-4.e
« «v-" .13
v I v
~ COY I (!) ~ COy I
o o
....1- 213 13 ....I_I 2. 13 "--_.....L.-_ _I.............lJ ....I_I 2 . eL-.-L_~-L-.l..--l
-24.13 -18.13 -12.13 -6.13 -213.13 -14.13 -8.13 -2.13 -15".13 ~9.e -3.13 3.13
LOG(A(CU+)/A(H+» LOG(A(CU+)/A(H+» LOG(A(CU+)/A(H+»
~ 413 . 13.---~~--.....--r--' ~ 213 . 13.--~,-.--~~...,....---. ~ 213. e.----~--~~~
* * *
"~* 25 13
MG "~* 12.13
MG ""*+ 12.13 HG
:r: :r: :r:
v v v
«v « «
v v
~ 113.13 ~ 4 13 ~ 'I.e
+ + +
+ + +
W W
I.L ~ PYRITE I.L
v-5 13 v-4.13 ~4.e PYRITE
« «
v v v
(!)
~ COY I o
(!)
o
....1- 213 .13 ....I_ 12.0'---....L...._.........J.............l..J ....I-12.eL-~~-L~~~~
-24.13 -18.13 -12.13 -6.13 -213 . 13 -1 4 . 13 -8. 13 -2 . 13 - 18 . 13 - I 2 . 13 -6 . 13 13 . 13
LOG(A(CU+)/A(H+» LOG(A(CU+)/A(H+» LOG(A(CU+)/A(H+»
Phase relations in the system HCl-HzO-Cu20-FeO-H2S-(H2S04), at log(aH+a Hs -) = -12.0.
Saturation limits: chalcocite (a), pyrrhotite (b).
 149
;;:; 2121.12Ir-~~--~.,......,......., ;;:; 2121.121 ;;:; 2121
*
,... ,...** *
,...* ,...
,...*
+ 12.121 MG ':;:' 12.121 MG + 12. 121 MG
I I I
v v v
« « «
v v v - -0-
~ 4.121 ~ 4.121 ~ 4121
+ HM + +
W
+
w
+ HM +
W
lL. lL. lL.
v-4 121 v-4.121 v-4.121
« «v «
v v
(!) (!) (!)
a a
-1_1 2 . 12I'--~.L.-~~'--'-....u -1_ 12 . 121 L--....J..~_~.!.......--ol---'
-1 O. 121 -9. 121 -3. 121 3 . 121 - 12 . 121 -6. 121 121 . 121 6 . 121
LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+))
;;:; 2121 . 12Ir-~~--~r"'""--' ;;:; 2121 121 ;;:; 2121. 121
,...** *
,...
,...* ,...**
':;:' 12.121 MG + 12 .121 MG ':;:'12 121 MG
I I I
v v v
« « «
v v v
~ 4.121 ~ 4.121 ~4 121
t HM +
+ HM
+
+
w w W
lL. lL. lL.
v-4.121 v-"l.12I v-4. 121
« « «
v v v
(!) (!) (!)
a a a
-1_ 12 . 121 L..--~..L-~-----.J,--,--....u -1_ 12 12I'--~""""-~--'-'---' -1_ 1 2 . e '----...~_ __'_----o.'--'
-1 5 . 121 -9. 121 -3. 121 3 . 121 -15.121 -9.121 -3.121 3.121 - 12 121 -6 . 121 121 . 121 6 . 121
LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+)) IOGCACCU+)/ACH+))
;;:; 2121 121 ;;:; 2121 121 ;;:; 2121 121
* ,...** •
,...,...* ,...•
,...
+ 12. 121 MG ':;:' 12 121
MG + 12. 121
I
v
I
v
I
v
MG
« « «
v v v
~ 4 121 ~ "I.e ~4 121
+ ~-~HM~-~ + +
+ + +
w W W
lL.
v-4.121
lL.
v-"l. 121
lL.
v-4. 121 -b
« « « PYRITE
v
8
v
8-1_1 2 . 121 L..--~~_......J...--'---'
COY cov '
(!)
a
-1-12. I2IL.-~"""""'----~""""'''----' -1_ 1 2 . 121 '--~~-'----"-.L...----'
-15.121 -9.121 -3.121 3.121 -10.121 -9.121 -3.121 3.121 -10.121 -9.121 -3.121 3.121
LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+)) LOGCA(CU+)/ACH+))
;;:; 2121 . 121.--~~-~...,-....----, ;;:; 3121 121

:..* pI *
,...
,...*
':;:' 12 121 MG + 15 .121 MG
I I
v v
« «v
v
~ 4 121 ~ 121.121 CP
+
+
W
+
w
+ b
I
lL.
v-4.121 ~15.121 PYRITE
« «
v v v
(!)
a
(!)
a COy 8 COY
-1-12 .12IL--..L-~~~-' -I-2121.12IL--~~-~~~---' -I-3121.12I~~~-~~~~
-15.121 -9.121 -3.121 3.121 -213 . 121 -14.121 -8.121 -2.121 -24.121 - 18 . 121 - 12 121 -6 121
LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+)) LOGCACCU+)/ACH+))
Phase relations in the system HCl-HP-Cu20-FeO-H2S-(H2S04), at log(aH+a Hs -) = -12.0.
Saturation limits: chalcocite (a), pyrrhotite (b).
150
~
**
20.0 \
,, 1 GROSS
~

**
16.0
\
\ 1
~

**
12.0 \

'c\
I
1 r-. \ r-. I GROSS
r-. \ 1 GROSS r-.
+ 18.0 ':;' 14.0 + 10.0
I
v
«
'c
\ 1 PREHN
I
v
«
'c\ bI
I
v
« -0
\ 1
-\ I-pREHN-
v v v
'- 0-""\ ·1
r-. 16.0 ~ 12.0 PREHN ~ 8.0
+
+
\ 1
LAUM +
+
-0- - \...... r-. - - -
1
+
+
1\ LAUM J
« « \.1 LAUM « I\
.1
u u u
v t4 .0 v 10.0 1 :;;: 6.0 PYROPH I \
« ~\PYROPH «
v I\,\YROPH \
(!)

512.0
4.0 8.0
9\ 12.0 16.0
(!)

58.0
0.0 4.0
I
8.0 12.0
(!)

54.0
-2.0 2.0
.~
6.0
\
10.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 20.0
, 1 GROSS
~ 16.'21
\ 1
~ 12.0 \
, 1
**
r-.
r-.
**
r-.
r-.
\ 1 GROSS
*
""+*
C
\
1 GROSS
+ 18.0
\
b PREHN + 14.0 \
10.0 I?
I
v
C
\
J
I
v
C
\ b
T v
I \
«
v --\
0
«
v \
«
v
r-- -0 - -\ ~ PREHN-
'- 1 --0- \...... I_P~E~
r-. 16.0 \ ~ 12.0 ~ 8.0
+
+ \1
LAUM +
+ LAUM
+
+
1\ LAUM~
« ~ « \

~
1
« 1 \
u u u
v 14.0 v 10.0 v 6.0 PYROPH I \
« 1\ « 1\ «
v. PYROPH v
PYROPH v \
1 \ 1 \ 1
(!) (!) (!) \
1 \ 1 \ J
512.0 58.0 54.0
4.0 8.0 12.0 16.0 0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
r-.
,
~ 20.0 16.0 ~ 12.0
1 GROSS
N \
\ \
1 , I
** *
**
r-.
C\ 1 r-.
r-.
\
C 1 GROSS "r-.+*
C
\ I GROSS
"+ PREHN + 14.0 10.0
b
18.0 \
I
v \ I
v \
b
T
I
v
\ I
« « « - -0- \....1- PREHN-
v --" -0 v \ v
\ 1 '- 1 PREHN
~ 16.0 r-. 12.0 -0- - \ - - - - ~ 8.0 1\ WAIR
+ \1 LAUM + +
+ + \ +
« 1 « LAUM « 1\
u
v
«
14.0 1\
u
v
«
10.0 ~ u
v
«
6'.0 PYROPH 1 \
\
v
PYROPH 1 \ PYROPH 1 \
v
I? \
\
(!) (!) (!)
1 .1 .\ I
512.0 58.0 54.0
4.0 8.0 12.0 16.0 0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 20.0 N 16.0 r-. 12.0
1 GROSS
\ N \
\ 1
* ** **
\ 1
\
"* \ 1 C\ 1 GROSS r-. GROSS
~
\
r-. r-.
'; 18.0 C, ~ PREHN + 14.0 + 10.0 C
~
I I \ I \
v \ 1
v v
I
« « \ « \

,
v v v
1 0 ~ 12.0
\ 1 PREHN - - 0 - \-t -PI<EHN -
~ 16.0 ~ 8.0
+ \ 1 + - -0-\-1- - - +
+ \ LAUM + + l, WAIR
« « ,1 «
u
v
«
14.0
1\
u
v 10.0
«
LAUM
r u
:;;: 6.0
v PYROPH:
\
\
\
(!) PYROPH ~. (!) PYROPH: \ (!) \
o ~
58.0 54.0
1
...J I 2. 40 . 0 8 .0 I2 . 0 I 6 .0 0.0 4.0 8.0 12.0 -2.0 2.0 6.0 10.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
Phase relations in the system HCl- H 20 - (Al 20 3) - CaO - FeO - Si0 2 in equilibrium with amor-
phous silica. Saturation limits: wollastonite (a), ferrosilite (b), hedenbergite (c).
 151
c::J 20.0
**
f'o
f'o
GROSS .1
A
(\J

A
A
**
15.0

GRoss.1
! 12. 0r--~G-R~O-S~S-/~~"/"1
+ 18.0 + 13.0 + 10.0
I I I
v
PREHN /
v
!R~H~ L -a __ v
T - a- -
j-
<{
v
<{
v '"'- ~ '- PREHN
;::; 16.0 ;::; 11.0 ;::; 8.0
+
LAUM -0- -
+
LAUM / +
+ + +
<{
u
<{
u K-SPAR <{
u K-SPAR
PYROPH
~ 14.0 K-SPAR ~ 9.0 ~ 6.0
v PYROPH v PYROPH v
(!) (!) (!)
o o o
...J 12 0 ...J 7.0 ...J 4.0
-'3. 0 1• 0 5 .0 9. 0 -3.0 1.0 5.0 9.0 -3.0 1.0 5.0 9.0

I
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

!
c::J 20.0 c::J 15. 0r-~~-~~-~..., c::J 12. 0r-~---~~-~...,

~
GROSS
** GROSS /

7,,1 GROSS
f'o

/
A
+ 18.0 + 13.0 ';.' 10.0
I PREHN I
v
<{
v -0-
~
v
r- ~R-=H~ -a __ v
<{
v
;::; 16.0
LAUM
~ 11.0 LAUM / ;::; 8.0
+ +
+
<{
+
<{
+
<{
u u K-SPAR u
v 14.0 ~ 9.0 ~ 6.0 K-SPAR
<{
PYROPH PYROPH
v v
~ PYROPH (!) (!)
o o o
...J 7.0 ...J 4.121
...J 12_'30 . 0 1.0 5.0 9 .0 -3.0 1.0 5.0 9.0 -3.121 1.121 5.121 9.121

I
LOG CA-CK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
c::J 20 • 0 r--~~-~~-T"T''''' ~ 15.0 A
12.0
* GROSS
(\J

A* ** GROSSi A
**
GROSS
I-a __
A A
~ 18.0 PREHN + 13.0 + 10.0
!~H~
I I I
v v v
<{
v
<{
v
r- <{
v r- PREHN".f -a - -

/
;::; 16.0 ;::; 11.0 ;::; 8.0 \.lAIR
+ + LAUM + /
+ + +
<{
u
<{
u
<{ K-SPAR
K-SPAR u
v 14.0 ~ 9.0 ~ 6.0
<{ PYROPH
v v PYROPH v
8 PYROPH (!)
o
(!)
o
...J 12. 0'--~~--'~~-~~ ...J 7.0 ...J 4 0
-3.0 1.0 5.0 9.0 -3.0 1.0 5.0 9.0 '-3.0 1.0 5.0 9.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
c::J20.0r--~---~·~-/~"" f'o
(\J
15.0 c::J 12.0
: GROSS
** GROSsi **
~
A A
A A
GROSsi
/a--
+ 13.0 + ; 0.0

I
16.' PREHN / I I
v
<{
v _ !~H~ v
<{
v
f
16'0~L=A~U~M=~ ;::; 11.121 ;::; 8.0 ,- PREHN -a--
/
-0- -
+
+
<{
u
LAUM +
+.
<{
u
\.lAIR /K-SPAR
~ 14.0 K-SPAR ~ 9.0 K-SPAR v 6.0
<{ <{
v v
PYROPH
v PYROPH
8 PYROPH I
(!) (!)
o o
...J 12. 0L...~~--'~~-~...J ...J 7 0 ...J 4.0
-3.0 1.0 5.0 9.0 '-3.0 1.0 5.0 9.0 -3.0 1 .0 5.0 9.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

Phase relations in the system HCI-H20-(AI203)-CaO-K20-Si02 in equilibrium with amor-

phous silica. Saturation limit: wollastonite (a).
152
;:;J 20.0 I N" 15.0 \

** *
""*
\
~
I
GROSSi GROSS /
~ \
? "+ b
7
-:;:- 18.0 + 13.0 10.0
:r: 1 :r: ~ \ :r: 1
v
« PREHN v
« " \ IPREHN j v
«
v I v
= " -0- v
~ 16.0 ~ -0- ;; 11.0 ~AUM 1 ~ 8.0
~~
14 - A
+
«
u
+
LAUM
14-A
CL
+
+
«
u
CL
+
+
« "
1\
v 14.0 1\ ' v 9.0
1\ " " u
v 6.0 1 \
«
v
c" «
v
PYROPHI \d
, « PYROPH 1 \
1 \ PYRQfH
1 "c,
d 1
"
(!) (!)
1 \ (!)

:312.0 :3 7.0 :3 4.0

9.0 11.0 13.0 15.0 4.0 6.0 8.0 10.0 2.0 4.0 6.0 8.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)
~ 20.0 ~ 15.0
6 \

/
GROSS
** I *
"*
d GROS~/

r-
1
" b
-:;:- 13.0 I'
\ "+ ""
1 I
-:;:- 18.0 10.0 b
:r: \ PREHN :r: :r:
v 1 v ,,\ I PREHN} v
« \ « « -~-­ -0
v v
t=.--".\~-- 0 PREHN ~ 1
v
~ 16.0
+
"'~:- LAUM 14-A
;; 11.0
+ LAUM '~ 1
14 - A
;; 8.0
+
J~ 14-A

«+ ~"C, CL +
« CL
+
«
LAUM 1\ " " CL
u
v
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14.0
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u
v
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9.0
1 \
1\
" "c , u
~ 6.0
PYROPH 1
1 \ "c,
v PYROPH 1 \
pkOPH
"-
"
(!) 1 \ (!)
\
(!) 1
:312.0 :3 7.0 :3 4.0
9.0 11.0 13.0 15.0 4.0 6.0 8.0 10.0 2.0 4.0 6.0 8.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/(ACH+))**2) LOG CACMG++)/CACH+))**2)
~ 20.0 ;:;J 15.0 ~ 12.0
\
* ** 'cJ , *
"* \ : GROSS./
"* 'cJ
"+ 13.0 "+ 10.0 I
-:;:- 18.0
:r:
v
«
'd
\ b
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v
«
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:r:
v
«
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v -\ v t- - ~ r l - - 0- v -0
~ 16.0 \1- LAUM ;; 11.0
+ \~\ " /, ;; 8.0
\lAIR 14-A
\"
LAUM I 4-A + CL
~ +
«
u ! CL
+
«
u
~ 1 \-c----.;O
1 4 . 01--_-r v
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9.0 b\
"c, v 6.0
« 'c"
v \ I \ PYROPH
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PYROPH 1
(!) PYRO~H \ (!) \ (!)
:3 12. 0 '--~~_~-..l_~--J :3 7.0 :34.0
9.0 11.0 13.0 15.0 4.0 6.0 8.0 10.0 2.0 4.0 6.0 8.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2)

7
~ 20.0 I ~ 15.0 \ ;:;J 12.0 \
GROSS ./
* ** *
"-:;:-*
I
'd
b 1 GROSS./
b ~+ 'd
1-
18.0 'cJ I \

f
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v \
v ,,\ I PREH v \
«
v
~ 16.0
,,\ «
v
;; 11 .0
- - ~\-I - - -0-
«
v
;; 8.0
"-'-"
PREH- -
+
+
" " LAUM
'\ "
0
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+
+ LAUM
\~
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/4-A
CL
+
\lAIR ~" j
« , CL « + 14-A CL
u i\ «
u u
1\ c"
"C, "-
v 14.0 ~ 9.0 v 6.0
« 1\ « 1 "
v I v PYROPH \ v PYROPHI \ c,
(!)

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9.0
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I "" (!)

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1
\ (!)

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1 ""
4.0 6.0 8.0 10.0 2.0 4.0 6.0 8.0
LOG CACMG++)/CACH+))**2) LOG CACMG++)/CACH+))**2) LOG CA(MG++~/CA(H+))**2;

Phase relations in the system HCl- H 20 - (A1 20 3) - CaO - MgO - Si0 2 in equilibrium with amor.
phous silica. Saturation limits: wollastonite (a), talc (b), diopside (c), tremolite (d).
 153
(:;J 20.0 I (:;J 15.0 \ (:;J 12 . 0r--~\-P"-"T~~~--'
* ** \ 1
J..* \
"~*
GROSS
~ "~ GROSS

7
I

18.0
/
13.0 d-\ b
I ~ 10.0
J:
1 J: I J:
v
ct I
PREHN v
ct _ ,-,,- 1 P~E~ JO v
ct

1 ,
v v v
~ 16.0
+
~
LAUM TO ~ 11.0
+
+
~ 1 LAUM ~ 8.0
+ 1\ ,
+
ct ct \' 7-A +
ct
U
~ 14.0 ~ 'PYROPH 7-A,c, CL
U
v 9.0
1 ,
\ c CL U
~ 6.0 PYROPH 1 \
, \
,
ct PYROPHI \ ' ,
1\
,
v v v
b \
(!)
o 1 ~ (!) 1 \ (!) I
...I 12 ·sr.
0 1 1 . 0 13 . 0 15 . 0
g 7.04.0 6.0 8.0 10.0
g 4.02.0 4.0 6.0 8.0
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r
(:;J 20.0 I (:;J 15.0 \ (:;J 12.0 I
GROSS \
* 1 * 'ct ~ GROSS *
"*
~ 18.0 \ b "~* 13.0
i' \
, "~* 10.0
r"'
"
\
'd b
IGROS~~
J:
v
ct \
1 PREHN ./ J:
v
ct
,\ I PREHN
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v
ct ~ -.~ -1- -7- 0-
v v v PREHN ~
~ 16.0 - , r-
I
-" ~ 11.0 ~ 8.0
~I, LAUM LAUM]~
,
+ LAUM \ " 7-A
+ +
+ ~ + + 1 , CL
ct ct
1\ ' c, [7C-~ ct
1\
,
U U U
'"c 'c
~ 14.0
v
1\
1 d, , ,, 17-~
CL
~ 9.0
v PYROPH 1\
1 \
~ 6.0
v PYROPH 1 \ ' "
(!)

g 12.0
PI"RqPH (!)

g 7.04.0 \ " (!)

g 4.02.0
1 \
9.0 11.0 13.0 15.0 6.0 8.0 10.0 4.0 6.0 8.0
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(:;J 20.0 I (:;J 15.0 (:;J 12.0 I

GROSS \
* : \ ~ GROSS
**
"~* GRO~1
\
\
~ 13.0r"' '" 'd "~ I
J:
18.0
'd b PREHN ./
,
J:
10.0 ' '
,d\ ~I
v 1 C ' ,\ 1 PREHN / v
r"' -"\
-1- 0 -

T
ct
v \. ,-u- j 1-0--..-1---1- ct
v -PREH~~"" -
~ 16.0 ~ 11.0 \-l 7 ~ 8.0 \t-.. 1 7-A
!
\1. LAUM \lAIR
+
+
ct
U
\' ,c , LAUM \ 'c 17 - A +
+
ct
U
1"

1\ ,
CL

~ 14.0 1\ ~ 9.0 1 \ " CL ~ 6.0 PYROPH c,

1 \
,
v I \ ,"{-A v PYROPH 1 \ ' v
(!)

g 12.0
PYROpH \ CL
(!)

g 7.04.0
1 \ " (!)

g 4.0
1 \ "
9.0 11.0 13.0 15.0 6.0 8.0 10.0 2.0 4.0 6.0 8.0
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(:;J 20.0 (:;J 15.0 \ (:;J 12.0 \

**
"':;:' \ b
GROSS
~ 'ct b GROSS J..* \
18.0 ':;:' 13.0r"' " I ~ 10.0
J:
v
ct
C ,\ I PREHN /
J:
v
ct
v j 1-0- ~\.-I - - -/. v
~ 16.0 ~ 8.0
+ ~11.0 \~! +
+ ~ LAUM ~ 'c + \lAIR ~'
ct ct
u ,\ 7-A ct

,
U CL U
1 CL
~ 14.0 ~ 9.0 ~ 6.0
1\
'c
,
v r--yc-----'''-:: v PYROPH 1 \ v PYROPH! \
(!) PYROI>H \ , (!)

g 7.04.0 \ " (!)

g 4.02.0
1 \

g 12 0 ·sr.
1 1 .0 13 . 0 15 . 0 6.0 8.0 10.0 4.0 6.0 8.0
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Phase relations in the system HCl- H20 - (AI 20 3) - CaO - MgO - Si0 2 in equilibrium with amor-
phous silica. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A
clinochlore. Saturation limits: wollastonite (a), talc (b), diopside (c), tremolite (d).
 154
~ 20. 0r-~~-~~-~-' ~ 16. 0r---~--~-~-' ~ 12.0

** GROSS A** A
** GROSS
GROSS
/
A A A
+ 18. 0 t - - - - - - , + 14.0 + 10.0
:r: :r:
~ PREHN~ v
«
v
« 0-
:::: - - -0-
V V

;::; 8.0
PREHN 7
+
A ~ 12.0 ~R~~~_ -0-
+
+ .;)( LAUt-V +
« « ALB
U ALB ~ 10 0 ALB u PYROPH
V
« . ~ 6.0
«
H v
YRO H V

(.!) (.!) (.!)

~ 12. 0L-......!~-~~-~--'
4.0 6.0 8.0 10.0
:l 8.03.0 5.0 7.0 9.0
:l 4.0
1.0 3.0 5.0 7.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 20.0 ~ 16. 0r----~--~-~....,
* GROSS /'
~ r-------/~. **
A
GROSS
~ 18.0 PREHY ';' 14.0
:r:
V
«
~ 16.0 LAUr - -0- ::::
A

+
12 • 0 PREHN
__
- -0--

~ LAUM/
~ 14.0- ALB V 10.0 ALB
« «
V YRO H V
YRO H V

(.!) (.!) (.!)

o :l 8.03.0 :l 4.0
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4... '"
6.... '"
8.... 1"'.'"
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LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~ 20. 0r-~~-~~--~-' ~ 16. 0r---~-~~-----' A
12.0
** GROSS /'
**
N

A
~-----------/'/
GROSS A** GROSS
/
A A
+ 18.0 ';' 14.0 + 10.0
:r: PREHN/ :r: :r:
V V V
«
V
« «
V - PREHN-7- 0 -
;::; 16.0 LAUY- -0-- ~ 12.0 _P~E~_o_ ;::; 8.0 \.lAIR I
+ +
+ +
«
u ALB ~ LAUMI ALB «
u
~14.0_. « 10.0 I ~ 6.0
PYROPH
ALB

~
V V

F YR01H (.!)
H (.!)

-I 12 ·40.'-0~-'6~.0-~8~.-0~-1-'0 . 0 :l8.03.0 5.0 7.0 9.0

:l 4.01.0 3.0 5.0 7.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
~20.0r---~--~--~, ~ 16. 0r---~--~-~-, ~ 12.0
* GROSS
'"':;'* "** GROSS A
A
**
GROSS
18.0 PREHN ';' 14.0 + 10.0
:r:
V
«
V -0- -
:r:
V
«
:::: PREHN
:r:
V
«
V
- ~~f'oL
,/
7-
;::; 16.0
~~7- A 12.0 ;::; a.0 0-

/
+ + -0- +
+ + + \.lAIR
« «
u
14.0 / ALB ~ 10.0
LAUj' ALB
u ALB
V ~ 6.0
«
V
«
V V V PYROPH
YRO H (.!) RO H
:la. 0
(.!) (.!)
~ 12. 0L---....!~-~~--~-' ~....oJ-~_~~_ _...J
~ 4.0
4.0 6.0 8.0 10.0 3.0 5.0 7.0 9.0 1.0 3.0 5.0 7.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))
Phase relations in the system HCl- H 20 - (Al 20 3) - CaO - Na20 - Si0 2 in equilibrium with amor-
phous silica. Saturation limit: wollastonite (a).
 155
~ 12.13.-----------, ~ 8.13 ~ 6.13
N N N
* ANNITE * *
~11.e~ '"+* 7.13 ~NNITE
I
'"I*+ 5.13 ~NITE
v v
;3 '- 0 - - ....p-=--=-=-=J «
v
-0- -'----~ « -0- -
v
~ 113.13 ~ 6.13 ~ 4.13
+ PYROPH + PYROPH
t
w PYROPH +
w W
+
lJ... lJ... lJ...
v 9.13 3.13 K-SPAR
« K-SPAR ~ 5.13 K-SPAR v
«
v v v
(!) (!) (!)
o o o
--l 8.13 --l4.e --l 2.13
13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))
~ 12.13.-----------, ~ 8.13 ~ 6.13
N N N

** ANNITE * ** ~NNITE
':;.'11.e~ '"*+ 7.13 ':;.' 5.13
C :- -~- -0- -- I
v
«
I
v
«
;3 1-----~
v v -0- -~----l
~ 113.13 ~ 6.13 ~ 4.13
+ PYROPH + PYROPH + PYROPH
+ + +
W W W
lJ...
K-SPAR
lJ... lJ...
3.13 K-SPAR
~ 9.13 ~ 5.13 K-SPAR v
«
v v v
(!) (!) (!)
o o o
--l8.e --l 4.13 --l 2.13
13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))
~ 12. er-~~-----.., ~ 8.13 ~ 6.13
N N N
* * **
'"+* 7.13
~ ANNITE ANNITE ANNITE
± l1.e~_ ':;.' 5.13
~
~ 113.13
! ~ -0- --,

1-----~
I
v
«v ~-o- ')--------j
I
v
«
v
~ 6.13 ~ 4.13
+ PYROPH + +
W
+ + PYROPH + PYROPH
W W
lJ... lJ... lJ...
~ 9.13 K-SPAR v 5.13 v 3.13
« i{-SPAR « K-SPAR
v v v
(!) (!) (!)
o o o
--l 8.13 --l 4.13 --l2.e
13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))
~ 1.2.13..----------, ~ 8.13 ~ 6.13
N N N
* * **
'"+* *+ 7.13
ANNITE ANNITE
'"

A-a-
11.13 ':;.' 5.13
I I
v
I
v
ANNITE

~ Ie. 13 ~1--0-------l~
« «v
v
~ 6.13 ~---~ ~ 4.13
+ + +
~ fpYROPH + PYROPH +
W W
lJ... lJ... lJ...
v 9.13 v 5.13 v 3.13 PYROPH
« K-SPAR « K-SPAR «
v
(!)
v
(!)
v
(!)
K-SPAR
o o o
--l8.e --l4.e --l 2.13
13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13 13.13 2.13 4.13 6.13
LOGCACK+)/ACH+)) LOGCACK+)/ACH+)) LOGCACK+)/ACH+))
Phase relations in the system HCl- HlO - (Al 10 3) - FeO - KlO - SiOl in equilibrium with amor-
phous silica. Saturation limit: ferrosilite (a).
 156
N 17. 0r-~~--~--., N 12. 0r--~-----, N 9.0
* ** *
"';'* 15.0 14-A CL "';' 10.0 14-A CL "';'* 7.0 14-A CLI
J: J: J: I
~ 0I v
'"~ 8.0
v
v

'"~ 5.0
v
I
v I
~ 13. 0~------...!.--i
+ + I + -a- - r
+ + +
-a- - - - L
(!) (!) (!)
1: 1: 1: PYROPH I
vl1.0 PYROPH
'"
v
~ 6.0
v
PYROPH I ~ 3.0
v b
(!)
-a- - - - ...l (!)
I
(!)
I
.1 I I
::l9.0 ::l4.0 ::l1. 0
0.0 4.0 8.0 12.0 -3 .0 I. 0 5 .0 9 .0 -3.0 1.0 5.0 9.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(ACH+))**2)

N 17.0 N 12.0 N 9.0

* * * I

"';'* 15.0
14-A CL "*
';' 10.0
14-A CL ""*+ 7.0 14-A CL I
J: J: J: I
v v v
I
I
'"~ 13.0
v '"
v '"~ 5.0
v
_1- __
+ bI
~ 8.0
+ b
I +
- -a-
I
+
(!)
I
+
(!)
1:
-- -a- - r- +
(!)
1: PYROPH I
1: PYROPH
~ 11.0 ~ 6.0 ~ 3.0
v - -a-- .J v
PYROPH I
v b
I I I
(!) (!) (!)
I ::l4.0
I 0 1
::l9.00 . 0 ...J 1._03 . 0
4.0 8.0 12.0 -3.0 1.0 5.0 9.0 1.0 5.0 9.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
N 17. 0r-~~--~---' N 12. 0r-~~---.'--., N 9.0
* * *
"*
';' 15.0 14-A CL ""+* 10.0 14-A CL ""*+ 7.0 14-A CLI
J: J: J: I
v v v

'"
v
~ 13.0
'"~ 8.0
v
'"~ 5.0
v
-a-
+
+
PYROPH b +
+ +
+
(!)
1: I (!)
1:
(!)
1: PYROPH I
vl1.0_ - -a- - - -+ v 6.0 v 3.0
'"
v
(!)
I '"
v
(!)
'"
(!)
~
I 1
::l9.0 ::l4.0 ::l,.0
0.0 4.0 8.0 12.0 -3 . 0 1 .0 5 .0 9 .0 -3.0 1.0 5.0 9.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)
N 17. 0r--~~--~---' N 12. 0r-~~--~--., N 9.0
* I * **
* "';'* I I
~ 15.0 14-A CL I 10.0 1 4-A CL I "J:+ 7.0 14-A CL I
J: I J:
~ b v

'"~ 8.0 I)
v

'"~ 5.0
~
v T
13. 0~-------'---t
v v
~
+ + I + - -a- .!..
+
(!)
PYROPH I
+
(!) r -a- - - -1-- (!)
+
I
1: 1:
~ 11.0_ -a- - - + v 6.0 PYROPH I v 3.0 PYROPH I
'"
v
(!)
I '"
v
(!)
I '"
(!)
I
I I .1
~ 9_0 ::l4.0 ::l 1.0
0.0 4.0 8.0 12.0 -3 . 0 1.0 5 .0 9 .0 -3.0 1.0 5.0 9.0
LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2) LOG (A(FE++)/(A(H+))**2)

HCI- H20 - (Ah03) - PeO - MgO - Si0 2 in equilibrium with amorphous silica. Saturation limits:
talc (a), ferrosilite (b).
 157
~ 17. 0r--~~-~~-~-' ~ 12. 0.---~-~~-~.., ~ 9.0
*:I<
**
:I<

"" 7-A CL ""* 7-A CL "" 7-A CL

""+ 15.0 ""+
I
10.0 1
~ 7.0
I
I
v v v
..: ..: I ..: I

-,
v v v
:::; 13.0
+
b :::; 8.0
+
:::; 5.0
+ - -0-
1
1
+ + +
(!) (!) (!) PYROPH
1: PYROPH l: l:
vll.0 6.0 3.0
b1
~ v
..: ..:
v v
- -0-- ...l 1
(!)

39.0 .1
(.')

34.0
1 g 1

0.0 4.0 8.0 12.0 -3.0 1.0 5.0 9.0 ...J 1 ·~3. 0 1. 0 5 .0 9 .0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~
:I<
17.0 ""
N
:I<
12.0 ~
:I<
9.0

""""* ""~*
7-A CL
:I<
7-A CL 7-A CL
""
+ 15.0 ""+
I
10.0
I
7.0
I
v v v
..: ..: ..:
v v v
:::; 13.0 b :::; 8.0
+
b :::; 5.0
+
--0-
+ 1 1
+ + +
(!)
1:
PYROPH (.')
l:
- - -0- - r- (!)
l:
PYROPH
v 11.0 v 6.0 PYROPH v 3.0
..: -0- - - -..l ..: 1 ..:
1 1
(!) (.') (.')
1 I j
39.0 34.0 31.0
0.0 4.0 8.0 12.0 -3.0 1 .0 5.0 9.0 -3.0 1.0 5.0 9.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 17.0 ~ 12. 0r--------~..., ~ 9.0
* :I< :I<

""""+*
:I< :I<
7-A CL 7-A CL 7-A CL
15.0 1
""+ 10.0 1 ~ 7.0
I I I
v 1 v
1
v
..: ..: ..:
v v v
"- 13.0
""+
:::; 8.0 6 :::; 5.0 - -0-
+ 1 +
+ PYROPH + -.0- - -1- ~ +
(!)
l:
1
(.')
l:
(.')
l:
PYROPH 1
v 11.0
..: - - -0-- -+ v
..:
6.0 PYROPH 1 ~ 3.0
b
1 1 1
(!) (.') (.')
I I 1
39.0 34.0 31.0
0.0 4.0 8.0 12.0 -3.0 1 .0 5.0 9.0 -3.0 1 .0 5.0 9.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
~ 17.0 ~ 12.0 ~ 9.0
:I< :I< :I< 1
""*
:I< :I<
"""" 7-A CL
'"+ 10.0
7-A CL
~ 7.0
7-A CL 1
+ 15.0
I
v
I
v I
v b
..: 1 ..: 1 ..: 1
v v v
"- 13.0
""+
+ PYROPH
6, :::; 8.0
+
+
~
I
:::; 5.0
+
+ -0- -
I
..t.. - --
:... - -0- - -1- -
PYROPH 1
(!) (!) (.')
l: 1: l:
v 11.0 - - - 0 - - PYROPH 1 v 3.0
..: + ~ 6.0
..: 1
1
(!)
1 1
(!) (.')
I
34.0 I .1
39.0 31.0
0.0 4.0 8.0 12.0 -3.0 1.0 5.0 9.0 -3.0 1 .0 5.0 9.0
LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2) LOG CACFE++)/CACH+))**2)
Phase relations in the system HCl-H20-(Ah03)-FeO-MgO-Si02 in equilibrium with amor-
phous silica. Metastable 7-A clinochlore was considered instead of its stable counterpart, 14-A
clinochlore. Saturation limits: talc (a), ferrosilite (b).
 158
"N 16.0 r\
12.0 ~ 1~L0

11~
N
* ** **
""* PHLOG r\ r\

+ 14.0 + 10.0 14-A

r\
PHLOG "I+ a.0
v
I I
v
CL v
. \ PHLOG
<: ~. <: <:
v ~ v v
14-A C1.:
"- 12.0 ;::: a.0 ;::: 6.0
"+ + + '-
+ K-SPAR + +
l!l
L
l!l
L -0-
l!l
L
- -0-- - --
v 10.0 r -0-- v 6.0 v 4.0
<: <: <: K-SPAR
PYROPH v PYROPH K-SPAR PYROPH
l!l l!l l!l
:la.0 :l 4.0 :l 2.0
-2.0 1.0 4.0 7.0 -2. 0 1. 0 4. 0 7.0 -2.0 1 .0 4.0 7.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

"
N
16.0 "N 12.0 ~ 10.0

* ** :I<

14'\
"* 14-1 PHLOG *
"I"+ a.0
r\

"+ 14.0 CL "I+ 10.0 PHLOG

-"
I
v v v . \ PHLOG
<: <: <: 14-A C1.:
v v v
"- 12.0 ;::: a. 0 '- ;::: 6.0 ......
"+ K-SPAR + +
+
l!l -0- -
+
l!l --- - - -0- - +
l!l
- -0-- - --
L L L
v 10.0 v 6.0 v 4.0
<: PYROPH <: <: PYROPH
v PYROPH K-SPAR K-SPAR
l!l l!l l!l
:la.0 :l4.0 :l2.0
-2.0 1.0 4.0 7.0 -2.0 1.0 4.0 7.0 -2.0 1 .0 4.0 7.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
~ 16.0 "N 12.0 ~ 10.0

14"~
** * **
"*
PHLOG
"+ r\ PHLOG

14"\.
14.0 1CL
4\ + 10.0 -:;:- a.0 PHLOG
I I I
v v v
<: '- <: <:
v v , v
;::: 12.0 ;::: a.0 ;::: 6.0
+ + +
+
l!l -- - f-O- - - +
l!l
~ -0- - - --- +
l!l - -0- - - - -
L L L
~ 10.0 K-SPAR ~ 6.0 K-SPAR ~ 4.0 K-SPAR
v PYROPH PYROPH PYROPH
l!l l!l l!l
o·a 0 :l4.0 :l 2.0
-.J '-2.0 1.0 4.0 7.0 -2.0 1 .0 4.0 7.0 -2.0 1 .0 4.0 7.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

"N:I< 16.0 " 12.0 ~ 10.0

14"~
N
* *
""* "-:;:-* a.0
:I<
" 1 4 \ PHLOG PHLOG
"I+ 14.0 CL
I
+ 10.0
I
v
......
v v PHLOG
<: <: <:
v v v
"- 12.0 ;::: a.0 ...... ;::: 6.0
"+ + + 14-A CL
+
l!l -- - -0- - - +
l!l f- -0 - - ---- +
l!l
,
L
v 10.0 K-SPAR
L
v 6.0
L
v 4.0 - -0-- - - -
<: PYROPH <: PYROPH K-SPAR <:
v
PYROPH K-SPAR
l!l l!l l!l
:la.0 o :l 2.0
-2.0 1.0 4.0 7.0 -.J 4._02 . 0 1 .0 4 .0 7 .0 -2.0 I .0 4.0 7.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

Phase relations in the system HCl- HP - (Al 20 3) - K20 - MgO - Si0 2 in equilibrium with amor-
phous silica. Saturation limit: talc (a).
 159
;;:; 16. 0.--~~~~~~....., ;;:; 12. 0n-"~~~~~~"""" ;;:; 10. 0.--......~~~~~..,........,
* * *
"';'* 14.0 PHLOG "*
';' 10.0
"';'* 8.0 PHLOG
J: J:
PHLOG J:
v v
7-A CL:
~'"
<
v
<
v
',...------1
::::; 12.0 ::::; 8.0 ::::; 6.0
+ + +
~ K-SPAR + +
(!) (!) - - - - - -0-
E E -0- E
v 10.01- - r- - - -0- - ~ 6.0 ~ 4.0 PYROPH
PYROPH -SPAR
~ f YROP~ v
K-SPAR v
(!) (!) (!)

g 8.00.0 3.0 6.0 9.0

g 4.0
-2.0 1 .0 4 .0 7. 0
g 2.0
-3.0 0.0 3.0 6.0
LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+)) LOG CACK+)/A(H+))
;;:; 16. 0,.......,~~~~~~....., ;;:; 10. 0 ........~~~~~~~
* ;;:; 12.0 7~ *
"';'* ""+* 8.0
: PHLOG
PHLOG

5
14.0
~' - - - - - - - - 1
~ 10.0 7-fI. CL
v
J:
PHLOG
< ~ ~~ <
v
v
::::; 12.0 ::::; 8.0 .-----....j ::::; 6.0
+ + +
+ K-SPAR +
(!) I- - - - I- -0- - +
(!) - - - -0- - -
~ 1-- ~ - - - -0- E E
v 10.0 ~ 6.0 PYROPH ~ 4.0 PYROPH
~ F YROP v K-SPAR v
-SPAR
(!) (!) (!)
0
-.J
80
• 0.0 3.0 6.0 9.0
g 4.0
-2.0 1.0 4.0 7.0
g 2.0
-3.0 0.0 3.0 6.0
LOG (A(K+)/ACH+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))
;;:; 16. 0r--"~~~~~~""""" ;;:; 12 .0 ...~~~~~~........, ;;:; 10. 0 ........~~~~~~........,
* ** *
"* PHLOG PHLOG "';'* 8.0
§14.0~ J: PHLOG
v v
<
v
~----------f <
v
<
v
7-A CL
::::; 12.0 ::::; 8.0 ::::; 6.0
+ K-SPAR + +
~ - - - - - - -0--' +
(!)
-0- +
(!) - - - -0- - -
E
v 10.0
E
~ 6.0 PYROPH
E
v 4.0 PYROPH
~ PYROP < -SPAR
v v
K-SPAR
(!) (!) (!)
0
-.J
80
• 0.0 3.0 6.0 9.0
g 4.0
-2.0 1.0 4. 0 7 .0
g 2.0
-3. 0 0. 0 3. 0 6.0
LOG CA(K+)/ACH+)) LOG (A(K+)/A(H+)) LOG (A(K+)/A(H+))
;;:; 16. 0r--"~~~~~~""""" ;;:; 10.0,................~-~~~.........

~
**
+ 14.0
~~
v
PHLOG

'~------f
1:::: ,\
v
<
7-A CL
1----.
PHLOG
v
<
J:
*
""+* 8.0
PHLOG
v
::::; 12.0 ~ 8. 0 ~'------l ::::; 6.0
+ + +
~ I- - I- - - - -0- +
(!) I- - - - - -0- - +
(!)
E E E - - - -0- - -
v 10.0 K-SPAR ~ 6.0 K-SPAR ~ 4.0
~ I YROP~ v PYROPH v PYROPH -SPAR
(!) (!) (!)

g 8.00.0 g 4·~2.'"'" g 2.0

3.0 6.0 9.0 1.0 4.0 7.0 -3.0 0.0 3. 0 6.0
LOG CACK+)/ACH+)) LOG (A(K+)/ACH+)) LOG (A(K+)/A(H+))
Phase relations in the system HCI- H 20 - (AI 20 3) - K20 - MgO - Si02 in equilibrium with amor·
phous silica. Metastable 7·A clinochlore was considered instead of its stable counterpart, 14-A
c1inochlore. Saturation limit: talc (a).
160
14.0 12.0 10.0
A A A

±7.0
A

± 11.0
A A
+ ALB ALB
I9.0
v
v v
« ALB « «
"-
A
"-
A
"-
A

~ 8.0 ~ 6.0 ~ 4.0 K-SPAR

z zv zv
v K-SPAR
« « «
v v
t!) 5.0 K-SPAR 3.0 1.0 PYROP
t!)
0 PYRO H
t!)
0 PYRO H 0
--l --l --l

-2 0
2.00 . 0 3.0 6.0 9.0 o. 00 . 0 3.0 6 .0 9 .0 . 0.0 3.0 6.0 9.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

A A A
A A A

± 11.0
v
± 9.0
v
ALB
± 7.0
v
ALB
« ALB « «
"-
A
"-
A
"-
A

~ 8.0 ~ 6.0 ~ 4.0 K-SPAR

zv z
v
z
v
« « K-SPAR «
v v
t!) 5.0 K-SPAR t!) 3.0 1.0 PYROP
0 PYRO H 0 PYRO H
--l --l

-2.0
2 . 00 . 0 3 .0 6.0 9.0 o . 00 . 0 3 .0 6.0 9.0 0.0 3.0 6.0 9.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
14.0 12.0
A A
A A
"
I+ 11.0
v
±9.0
v
ALB
±
v
7.0 ALB
« ALB « «
"- "- "-
A

~ 8.0
A

~ 6.0
"~ 4.0 K-SPAR
zv zv z
K-SPAR v
« « «
v v v
t!) 5.0 K-SPAR t!) 3.0 t!) 1.0 PYRO H
0 0 PYRO H o
--l PYRO H --l --l

2 . 00 . 0 3 .0 6.0 9.0 o . 00 . 0 3.0 6.0 9.0 -2. 00. 0 3. 0 6.0 9. 0

LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))

A A A
A A A
+
I
v
11.0 ± 9.0
v
ALB ± 7.0
v
ALB
« ALB « «
"- "- "-
"~4.0
A A

~ 8.0 ~ 6.0 K-SPAR

zv z z
v K-SPAR v
«
v
«
v
«
t!) 5.0 K-SPAR t!) 3.0 ~ 1.0 PYRO H
0 0 PYRO H o
--l PYRO H --l --l

2.00 . 0 3.0 6.0 9.0 0.00 .0 3.0 6.0 9.0 -2.0

0.0 3.0 6.0 9.0
LOG CACK+)/ACH+)) LOG CACK+)/ACH+)) LOG CACK+)/ACH+))
Phase relations in the system HCl- H20- (AI 20) - K20- Na20-Si02 in equilibrium with amor-
phous silica.
 161
~ 18. 0 r - - - - - - - - - - - , ~ 14. 0r--------......., ~ 12.0.----------.
**
**
**

'/
'"'+ 15.0 '"+ '"
'"+ 9.0 14-A CL
11.0
I I I
v v
« «v
v
;::; 12.0
v
;::; 8.0 [----, ;::; 6.0 ALB
ALB
+
+ ALB +
+ '-- -0- - - - - - t -0
(!)
I-- -0- --- (!) (!)
L
L
:;;: 9.0 PYROPH
L
:;;: 5.0
PYROPH :;;: 3.0 YROP
v v v
(!) (,!) (,!)
o o o
--l 6.0 --l2.0 --l0.0
0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA ... )/ACH ... )) LOG CACNA ... )/ACH"')) LOG CACNA ... )/ACH ... ))

~ 18. 0 r - - - - - - - - - - - , ~ 14. 0r-----------, ~ 12. 0r--------~........,

*
'"'*
** **
'"'+
I

v
;::; 12.0
+
15.0 '"+
I
v
«
v
;::; 8.0
+
11.0

'/
1----,/
ALB
'"'+
I

v
;::; 6.0
+
9.0 14-A CL

ALB
+ >-- -0-
ALB
- -- + :-- -0- - - - - -c + -0
(!) (!) (!)
L PYROPH L PYROPH L
:;;: 9.0 v 5.0 v 3.0 YROP
«
v
«
v
v
(!) (,!) (,!)
o o o
--l6.0 --l 2.0 --l0.0
0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA ... )/ACH ... )) LOG CACNA"')/ACH"')) LOG CACNA ... )/ACH ... ))

~ 18.0 r-----------, ~ 14. 0r--------........, ~ 12. 0 r - - - - - - - - - - - ,

* ** *
'"'* '"'*
'"'+ '"'+
'/ '"'+
14-/ 14-A CL
15.0 11 .0 9.0
I I I
v v v
«
v
1-----,." «
v
«
v
~ 12.0 ALB ;::; 8.0 1-----,/ ALB ;::; 6.0 ALB
+ - -0- --- + - -0- - - - - - + -0- - -
(!)
+ (!)
+ (!)
+
L PYROPH L PYROPI- L
v 9.0 v 5.0 v 3.0
«
v
«
v
«
v
YROP
(!) (,!) (,!)
o o o
--l 6.0 --l 2.0 --l0.0
0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA"')/ACH ... )) LOG CACNA ... )/ACH ... )) LOG CACNA"')/ACH ... ))

~ 18. 0r-----------, ~ 14. 0r--------........, ~ 12. 0 r - - - - - - - - - - - ,

** ** **
'"'+ 15.0 14-/ '"'+ 11.0
14-A CL '"'+ 9.0 14-A CL
I I I
v v v
« 1-----, «
v
«
v
v
;::; 12.0 ALB ;::; 8.0 ALB ;::; 6.0
ALB
! ,-- -0- --- +
+
(,!)
-0- - -
(!)
+
+ -0- - -
(!)
L PYROPH L L
v 9.0 v 5.0 YROP :;;: 3.0 YROP
« «
v v
v
(!) (!) (!)
0 0 0
--l 6.0 --l 2.0 --l0.0
0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA ... )/ACH"')) LOG CACNA ... )/ACH"')) LOG CACNA ... )/ACH ... ))

Phase relations in the system HCl- H 20 - (Al 20 3) - MgO - Na20 - Si02 in equilibrium with
amorphous silica. Saturation limit: talc (a).
 162
~ 18. 0r-~~-~~-~..., ~ 14. 0r-~~-~~-~..., ~ 12. 0r-~~-----­

** **
7/
*
r;* 16.0 7-A CL / A
12.13 A
10.0
+ +
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«
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«
v v v
e---./
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+ ALB + ALB + ALB
+ + - - - -0- - - - + r- - - -0- - - -
~10.0r-- 0---- ~ 6.0 ~ 4.0
v
PYROPH v
v PYROPH
;:; 8.0 ;:; 4.0 :5 2.13 PYROP
(!) (!) (!)
o o o
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• 0.0 4.0 8.0 12.0 13.0 4.0 8.0 12.0 0.0 4.0 8.0 12.0
LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) lOG CACNA+)/ACH+))
~ 18. 0r-~~-~~-~..., ~ 14. 0r-~~-~~-~-' ~ 12. 0r-~~----~...,
*
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+
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L
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"N 18.0r-~~~-~~-' ~ 14. 0r-~~-~~--..., ~ 12.0

*
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~ 18. 0r-~~-~~--..., A
14.0 ~ 12.0
N
** ** 12.0
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A
A
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(; 14.01---_ _ _( ' / (; 113.13 ~ 8.13
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v
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ALB
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LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+)) LOG CACNA+)/ACH+))

Phase relations in the system HCl- H20- (Al203) - MgO- Na20-Si02 in equilibrium with
amorphous silica. Metastable 7-A clinochlore was considered instead of its stable counterpart,
14-A clinochlore. Saturation limit: talc (a).
 163
~ 19. 0r-~~-~~-/..,.--' ~ 15. 0r-~~-~~~"'--' ~ 12. 0r--~\-~,......--"""'"T-'

**
: GROSS
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g 13 . 0~J....1-,--
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LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+))**2)
17 • 0 .....~~--::o-::-:r.::--r......."......., 13. 0,...,,~~~~.....-~..-,

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LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+»)**2) LOG (A(MG++)/CACH+»**2)
~ 21 . 0 .....~~~~~.,...-........, ~ 17.0 .....~~~~.........,......,,........., ~ 13. 0.....,...~~~-.-,~~.........,
* 1 PARG~
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1

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LOG (A(MG++)/(A(H+))**2) LOG (A(MG++)/(A(H+)**2) LOG (A(MG++)/(A(H+»)**2)
~ 2'1 • 0,.........,~~~~~.,.-...-., ~ 17 .0 .....~~~r~~~y--, ~ 13. 0r--~~~-r-~~.........,

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1 '"~* 11.0
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g 9.0 t:::::;:E:u......_~..........J g 5.0
5.0 8.0 11.0 14.0 2.0 5.0 8.0 11.0
LOG (A(MG++)/(A(H+»)**2) LOG CA(MG++)/(A(H+»**2)

Phase relations in the system HCI-H20-(Ah03)-CaO-MgO-Na20-Si02 in equilibrium

with albite and amorphous silica. Saturation limits: talc (a), diopside (b), tremolite (c), wollas-
tonite (d).
164
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LOG. CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2) LOG CACMG++)/CACH+»**2)

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LOG CACMG++)/(ACH+»**2) LOG (A(MG++)/CACH+»MM2) LOG (ACMG++)/CACH+»*M2)

Phase relations in the system HCl-H20-(Ah03)-CaO-MgO-Na20-Si02 in equilibrium

with albite and amorphous silica. Metastable 7-A clinochlore was considered instead of its stable
counterpart, 14-A clinochlore. Saturation limits: wollastonite (a), talc (b), diopside (c), tremol-
ite (d).
 165
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$ $ $ YROPH
85.a 84.0 84.0
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LOG (A (S102 (AQ»! (0" (S102 (AQ»» LOG (A(SI02(AQ»!(0"(SI02(AQ)))) LOG (A(SI02(AQ»!(0"(SI02(AQ»»

;::; 9.0 ;::;8.0

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§ 5·~3.a -1.0 1.0

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;::; 9.a
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83.0 82.0 PYROPH 8-7. 0 L---~_--L..L...-'----I
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LOG (A(SI02(AQ))!(0"(SI02(AQ)))) LOG (A (S102(AQ»! (0" (SI02(AQ)))) LOG (A(SI02(AQJJ!(0"(SI02(AQ))))

Phase relations in the system HCI- H 20- (A1 20 3) -'"CaO-C02 - Si02 at Xc0 2 = 0.01. Satura-
tion limits: quartz (a), calcite (b), wollastonite (c).
 166

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;::; 8.13 ;::; 8.13

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;::;-1
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LOG (A(SIU2(AQ))/(O"(SI02(AQ)))) LOG (A(SI02(AQ»/(0"(SI02(AQ»» LOG (A(SI02(AQ!!I(O"(SI02(AQ))))

Phase relations in the system HCI-H 20-(AI 20 3)-CaO-C02 - SiOl at XC02 = 0.05. Satura-
tion limits: quartz (a), calcite (b), wollastonite (c).
 167
;:; 9.0 ;:; 8.0 ;; 8.0
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;:; 9.0 ;; 8.0 ;; 8.0

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Phase relations in the system HCl- H20- (AI 20 3) -CaO-C02 - Si02 at XC02 = 0.10. Satura-
tion limits: quartz (a), calcite (b), wollastonite (c).
 168
;::; 9.0 ;::; 8.0 ;::; 8.0
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Phase relations in the system HCl- H 20 - (AI 20 3) - CaO - CO 2 - Si0 2 at Xco2 = 0.30. Satura-
tion limits: quartz (a), calcite (b), wollastonite (c).
 169

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Phase relations in the system HCl- H 20- (AI 20 3) -CaO-C0 2 - Si0 2 at XC02 = 0.50. Satura-
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Phase relations in the system HCl-H 20-(AI 20 3)-CaO-C02 - Si0 2 at XC02 = 0.70. Satura-
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172
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• 'MARG I " MARG
~ 'd, ?
~
- ~ t- -c-
't- 3 . 0
....+ \~~"I' WAIR
~ ,-. jf1'
~ CLNZ'\ NOR- ,
~-4.0
+ CALC ~
....+
<
~ WOLL: \
'"""'-
X-S.0 ~-1 8.:~.L..0--_-3..l..~0--'-_-..iJl.0
~ -4.0 -2.0 0.0 -1.0
LOG (Msl02 (AQ))/ (u (S102 (AQ)))) LOG (A(SI02(AQ»/(u(SI02(AQ»»

Phase relations in the system HCl-H 20-AI 20 3 -{CaO)-C02 - Si0 2 at XC02 = 0.01. Satura-
tion limits: quartz (a), diaspore (b), corundum (c), andalusite (d), kyanite (e), sillimanite (f),
pyrophyllite (g).
 175
f 2.0 ;: 2.0
"
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+
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~ :$ "-
I
a :$
t+ 1.0 } 1.0
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"-
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~ CALC -9
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~ 0.0 ~ 0.0
+
+
+
+ "-
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~ ~ CALC
~ :$
3 1 ._03 .0 -1 .0 1 .0 8-
...J
1 •0
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LOG (A (S102 (AQ»/ (0' (SI02 (AQ»» LOG (A(SI02(AQ»/(O'(SI02(AQ»»

f 2.0
+ \
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1 MARG
2;
~
aI
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8'1.0
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LOG (A(si02(AQ»/(O'(SI02(AQ)))) LOG (A(SI02(AQ»/(O'(SI02(AQ))))

;: 0.0 ;:-7.0
"
+ MARG I "- MARG I "
+ "" MARG a
a
2;
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+
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1 .0 ...J -4.0
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LOG (A(SI02(AQ»/(0'(SI02(AQ»»
0.0 3 10_'40 .0 -2.0
LOG (A(SI02(AQ»/(O'(SI02(AQ»»
0.0

;:-15.0~--~--~--~-. ;:,24 . 13 r---:-~--~--~-----."

" ~ "" MARG I
MARGI '+
2;
" d, I 2; L" 9
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"- 1
~ "- 1

-\;~N~::fI"
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NOR 1 'd
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0-5.0
3 -3.0 -1.0 1.0 30-18.0
-5.0 -3.0 -1.0 §-27_·~.0 -3.0 -1.0
LOG (A(SI02(AQ))/(O'(SI02(AQ)))) LOG (A(SI02(AQ))!(O'(SI02(AQ)))) LOG (A(SI02(AQ»/(O'(SI02(AQ»)))

Phase relations in the system HCl-H20-AI203-(CaO)-C02-Si02 at Xco = 0.05. Satura-

2
tion limits: quartz (a), diaspore (b), corundum (c), andalusite (d), kyanite (e), sillimanite (0,
pyrophyllite (g).
176
+ 1.0
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+ , MARGI
+
+ 1.0
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t 1.0 'e
"
1
1
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+ 0.0 1 \ ANO~\ t- I . 0
,
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+
9 g\
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3-0- 1 . 0 1 \ $ :;:
o -3.0 -1 .0 1.0 8- I ._03 .0 - I .0 I .0
;-2.0
o -3.0 -1.0 1.0
~ LOG (A(SI02(AQ»/({J" (SI02(AQ)))
;;:;
LOG (A(SI02(AQ»/(u(SI02(AQ»)
,..,
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t 2.0 + 1.0 t 0.0

+
+
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\
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$ $ , MARG,
a
+
+ 1.0 ' , \ 1
1
+
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+ - - ~y- - -b- 2; +
..J
$ ", WAIR $ <
S , ~ .!:
:; 0.0 'e +-1.0 ~-2.0
+ CALC ' + CALC +
+ 2; +
$ $
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<
<
5- 1 . 0 $-2.0
8 -3.0 -1 .0 1 .0 8 -3.0 -1 .0 1.0 8-3._03.0 -1.0 1.0
~ LOG (A(SI02(AQ»/(u(SI02(AQ») ..J LOG (A(SI02(AQ»/(u(SI02IAQ))) ..J LOG (AISI02IAQ»/luISI02IAQ»)
;;:;
r
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0.0 t-3.0 [-70
+ +' +
is , -.HARd i s ' MARG
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$ ,1 $ <

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+ CALC + I' +
+
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3-- 0
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$-1 0 0'--~~-"""""'--'"-----I
8 -5.0 -3.0 -1.0 1.0
,J:! LOG (A(SI02(AQ))/(u(SI02(AQ))) :::! LOG (A(SI02(AQ»/(u(SI02(AQ») ~ LOG (A(SI02(AQ»/(u(SI02IAQ»)

r-2 . 0 [-15 0 [-24 . 0~....--~-~~~---,

sa?
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+ ,+ +
+ + 1 +
+ 2; 9LlC 2;
$ $ $
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o -I .0 I .0 8 -4.0 -2.0 0.0 0 ... -4 -2 '" 0
§
('l ('l
LOG (A(SI02(AQ»/(u(SI02(AQ))) ..J LOG (A(SI02(AQ»/(u(SI02(AQ))) g LOG (A(SI02IAQ»/luISI02IAQ)))

Phase relations in the system HCI-H 20-AI 20 3 -(CaO)-C0 2 - Si02 at XC02 = 0.10. Satura-
tion limits: quartz (a), diaspore (b), corundum (c), andalusite (d), kyanite (e), sillimanite CO,
pyrophyllite (g).
 177
;> 2.0 :' 1.0
•
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5 ~
5
$ $
1
~
~
1.0 l0.0
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$ -C- -~
$
CALC ..s ANOR~,\.IAIR
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? I e, :j:
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CALC I
$
$
8-1.0
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8-
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2 .0
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LOG (A(SI02(AQ»/(u(SI02(AQ)))) LOG (A(SI02(AQ»/(u(SI02(AQ»))) LOG (A(SI02(AQ»/(u(SI02(AQ»»

;> 2.0
•
i 0.0
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5
$
,
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$
11.0
I \.lAIR
t-+ 1 . 0
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+ +
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$ $
8-
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g-3.0
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LOG (A(SI02(AQ»/(u(SI02(AQ»))) LOG (A(SI02(AQ»/(u(SI02(AQ»)))

;> 0.0 ;>·3.0

• .!- ',MARG I
'+ $ ,I
5
$
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ANOR~{I' \.lAIR $ ANOR_._, I 'd
$ "d
t
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:;:-2.0
CALC I ' 5 •• :;:-9.0
!
CALC )\' CALC

~< I
$
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$
$
8-10.0 ..........~~...u.........I.....o.........J
~8-3.0
-3.0 -1.0 1.0 8- 6 ._04.0 -2.0 0.0 ..J .-5.0 -3.0 -1.0 1.0
:: LOG (A(SI02(AQ»/(u(SI02(AQ»» ..J LOG (A(SI02(AQ»/(u(SI02(AQ»» LOG (A(SI02(AQ»/(u(SI02(AQ»)))

;>-2.0 '" 5
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•
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5
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$ $:j: ANOR I "d,
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< CALC
$
8
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-3.0 -I . 0 1 .0 8 -.fl. 0 -2.0 0 .0
LOG (A(SI02(AQ»/(u(SI02(AQ»))) ..J LOG (A(SI02(AQ»/(u(SI02(AQ))))

Phase relations in the system HCl-H 20-AI 20 J -(CaO)-C0 2 - Si02 at XC02 = 0.30. Satura-
tion limits: quartz (a), diaspore (b), corundum (c), andalusite (d), kyanite (e), sillimanite (f),
pyrophyllite (g).
 178
i 2.0 f 1.0 MARG..A'~I
'+ ~ ---c\~-b-
e I
~
aI ~ ANO~ "
'i 0.0 1\ e_,
i
11.0
-b- - 1

CALC
, 3
S
ANOR
1
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'd,
CALC~: \AIR
::;: 0.0
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a
I ~ 1
3 ~OLLI\
8-' .-3.0 1
0 '--~-~~'-'----'
~
\2-1.0
1
~
8- 2 . 0 1
'--~_~~....L-l...J
Lf\
...l -1 .0 1 .0 ~ -3.0 -1 .0 1 .0 ...l -3.0 -1 .0 1 .0

1.
LOG (A(SI02(AQ»/ (u (SI02(AQ»» LOG (A(SI02(AQ»/(u(SI02(AQ)))) LOG (A(SI02(AQ»/(u(SI02(AQ))))

f 2.0 1
f 0 r--~~-"-~-r-"'"
f 0. 0 "'M-A-R-G7:~=!::I=]::-"'"-"'"
'+
e MARG 1
~ :-.. MARG 1
:-.. a ~ ANOR~1-. -b-

1
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11.0
~
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i
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0 0
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ANOR~~~AIR CALC: \ WAIR'
s s ,
t o. 0 CALC ::;:-1.0
1 'c, ~-2.0 \

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+

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~ 3 1
3 ~ 1
8- 1 .0
...l -3.0 "'"I .0 1. 0 ~2·~3.0 -1.0 1.0 ...l
3 .0
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LOG (A (S102 (AQ»/ (u (S102 (AQ»» LOG (A(SI02 (AQ»/ (u (S102 (AQ)))) LOG (A(SI02(AQ»/(u(SI02(AQ»»
~ 0.0 ;>-3.0 r--~--~_~~~ ;>-7.0
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3
s
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+
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0
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8- 10-4.0
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LOG (A (S102 (AQ»/ (u (S102 (AQ)))) LOG (A(SI02(AQ»/(u (SI02(AQ»» LOG (A(SI02(AQ»/ (u (SI02(AQ))))
;>-1 5 . 0.--......':"":"7=-r----.
• f-24 . 0
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5 3 ~
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0
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LOG (A(SI02(AQ»/(u(SI02(AQ»» LOG (A(SI02(AQ»/(u(SI02(AQ»» LOG (A(SI02(AQ»/CuCSI02CAQ))))

Phase relations in the system HCl-H20-AI203-(CaO)-C02-Si02 at Xco = 0.50. Satura-

2
tion limits: quartz (a), corundum (b), andalusite (c), kyanite (d), sillimanite (e), pyrophyllite
(f), diaspore (g).
 179
f 2.0 ;; 2.0
*
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+' +' +' I'
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1\ "
ANOR, , ,
$ $ 1
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1+ 1.0
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i+
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I CALC
~ CALC 1 ~ I C,
~ CALC I
~ 0.0 ~ 0.0 aI a
t + !-0.5
I
+
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« $ ~ 1
$ $ $
8-
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1•0
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8- 1 .-3.
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0
0 - 1. 0 1. 0 Sr l .-3.0
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0
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LOO (A(SI02(AQ»/(,r(SI02(AQ)))) LOO (A(SI02(AQ»/(0'(SI02(AQ»» LOO (A(SI02(AQ»/(O'(SI02(AQ»»

f 2.0 ;; 0 . 0 - b~=r=r=-1="~'
+'
:J:
MARG +'*
S
$ $
i+ 1.0 i+ 0 . 0 '+1- 1 . 0
$
...l ...l
$ $
CALC
~ CALC ~ ~
~ 0.0 6 ~-1 .0 ~-2.0
! I
+
+
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$ $ $
8- 1 •-3.0
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0
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:3 -3.0 -I .0 1 .0
LOO (A(SI02 (AQ»I (0' (S102 (AQ)))) LOO (A(SI02(AQ))/(0'(SI02(AQ)))) LOO (A(SI02(AQ»/(0'(SI02(AQ»»

f 0.0 :-3.0 ;;-6.0

•
+' +'
:t ..... - b-- +'
S 1 ""-" MARG S
$
$
t-1.0 1- 4 .0
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i-+ 7 . 0
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$
~ CALC 1 ~

9\
~
~-2.0 ~-5.0 ~-8.0
+ I + + CALC
+ aI + +
$ : WOLL
f\
...l ...l
$ $
$ $ $
8-
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3 .0
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8- 6 .-3.0
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0
-1.0 1.0 8- 9 .-5.0
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0
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LOO (A(SI02(AQ»/(0'(SI02(AQ)))) LOO (A(SI02(AQ»/(0'(SI02(AQ»» LOO (A(SI02(AQ»/(0'(SI02(AQ»»
;;-2.0 ;;-15 . 0r--.b-_....-_~_-_-,-~--, ;;-24.0r-~~.---~~--'
+'* ~ "I, +'*
S S
$ $ ~NOR' $
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CALC 1
e, i-+ 25 . 0
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CALC
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+
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0-5.0
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8-1 8-4.0
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LOG IAISI02IAQ))/Ia-(SI02(AQ)))) LOO (A(SI02(AQ»/(0'(SI02(AQ»» LOG IAISI02IAQJJ/(0'ISI02IAQIJIJ

Phase relations in the system HCl-H20-AI203-(CaO)-C02-Si02 at XC02 = 0.70. Satura-

tion limits: quartz (a), corundum (b), kyanite (c), sillimanite (d), andalusite (e).
180
M M

~ 3.0
:r
+
:r
5.0

$ 1 MARG <
:::: 4.0 MARG
+ a
. -'. .~'-~ot-
+ 3.0 6 MARG +
t 2 0 1
+
t 3.0 6
+ I
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~
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1 «

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~
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++
2.0 CALC ~, t 1.0 ALC 1
1
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1.0
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0
g -3.0 -1 .0
LOG (A(SI02(AQ))/(0'(SI02(AQ)))
1 .0
;;; LOG (A(SI02(AQ))/(O'(SI02(AQ)))
..,J

M
0.0
LOG (A(SI02(AQ»/(O'(SI02(AQ»)
2.0

~ 3.0 ~
+ 3 .0 ~ 3.0
S
5
+ :r
~ 2.0
b MARG :r
~ 2.0
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+
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+ 1 + + CALC: '",\IR
+ + +
~ t 2 .0 :;!-2.0 \.lOLL
"< « «
; 0.0
o
--!
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LOG (A(SI02(AQ)/(O'(SI02(AQ»)
1 .0 8- 3 ._02 .0
..,J
0.0
LOG (A(SI02(AQ))/(u(SI02(AQ)))
2.0
;-3.0
o -2.0
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0.0
LOG (A(SI02(AQ»/(O'(SI02(AQ»)
2.0

&1.0
M M M

~ 0.0 ;-3.0
S t1 ARG :r :r 1
\.lAIR ~-I .0 I MARG ~-4. 0
5 1 ~ARG
+
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+ 0.0 +-2.0 +-5.0
+ +
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+ -1.0 : ::-4.0 ALC +-7.0
+
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1 :;!-5.0 ~-8. 0 'e
1 '
<: "< «
~-2.0 ;-6.0 ;-9.0
8 -3.0 -1 .0 1 .0 o -3.0 -1 .0 1 .0 o -4.0 -2.0 0.0 2.0
--! LOG (A(SI02(AQ»/(0'(SI02(AQ») ..,J LOG (A(SI02(AQ»/(0'(SI02(AQ))) ..,J LOG (A(SI02(AQ»/(0'(SI02(AQ»)
M M M
~ 0.0 ~-11.0 ~-20.0r-~~-~~---"
+ + +
S I S 1 MARG :r
5 , MARG ~-1 2 . 0 0 $-21 . 0 1 MARG
;::-1.0
t
0, \.lAIR
+-13.0
+ 1
t-22.0 o
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~N-f,-b - 1 tAl \.lAIR
1

~-2.0
+ - ~ ~-14.0
+ _' "'>.....~-b- ~-23.0
+ toINOR
-3 -3 ,_ -3 '4-
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++-3.0 ,+ CALC 1 'e t
~
1
5~-16.0 "
~-
25 0 CALC
.
<: '< \.lOLL
5_ .0 ~-1 7 . 0 ~-26 . 0 '--~~-~~~---'
8 4 -3.0 -1.0 1.0 8 -4.0 -2.0 0.0 8 -4.0 -2.0 0.0 2.0
...l LOG' (A(SI02(AQ))/(0'(SI02(AQ))) ...l LOG (A(SI02(AQ»/(0'(SI02(AQ»)) ...l LOG (A(SI02(AQ»/(0'(SI02(AQ)))

Phase relations in the system HCl-H20-AI203-(CaO)-C02-Si02 at XC02 = 0.90. Satura-

tion limits: quartz (a), corundum (b), kyanite (c), sillimanite (d), andalusite (e).
 181
'" '"
I ~ 3.0 ~ 5.0
a is ~
MARG
I $ ~ 4.0 I

+
I MARG
+ + a )
+ 3.0 + 2.0 + 3.0
+ + +
..J
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~ $ -<:
~ 2.0
-3 -3
+
'- '-
2.0 CALC
'+ 1.0 + 1.0
+
+ +
+ + +
~
..J
~ 0.0
$
3 -<: -<:

8 1 ._03 . 0 - I .0 I .0
;; 0.0
o -2.0 0.0 2.0
X- I . 0
~ -2.0 0.0 2.0
...l LOG (A(SI02(AQ»/(O"(SI02(AQ») LOG IAISI02IAQ»/I<TISI02IAQ») LOG IAISI02IAQ»/I"ISI02IAQ))
..J
....,
i'" 3.0 I
'"
~ 4.0
+
~ 4.0
e ,

r·
~
I MARG MARG
$ 33.0 I
a
MARG
3 3.0 a
I

+ -b-'.:,. I _
t 2.0
I +
+ 2.0

~~AIR
+ +
..J ..J
:5 I .0 ~ 1.0
- CALC ,
:; 1 .0 I C, '+ 0.0 :;: 0.0
t
~
6I t
~-1.0
+
+
~-I .0
00( I -<: -<:
-20 ~-2. 0
8
~0.0
-3.0 -1.0 1.0 8-'-2.0 0.0 2.0 ~ -2.0 0.0 2.0
~ LOG (A(SI02(AQ»/(O"(SI02(AQ») ~ LOG IAISI02IAQ))/1,,15102IAQ))) -=
~
LOG IAISI02IAQ))lI<rlSI02IAQ)))

~2.0 t 1.0 t-3.0

+
+ +
~ IMARG ~ MARG
< I 3 0.0 d 3-4.0

~ 1.0 -b~~'
~~~.!'A-'R ~_..: ;5.
~ 0. 0 ~-2 . 0 - "'--+,- b fAIR i- 6 .0
~ ALC I 'e, :;-3.0 1 ANOR ~- 7.0
+-1 .0 6 + CALC I e- t
+ I ::;-4.0
-<:
:;:-8.0
~
<
...l
$ I OL-<:
$-2.0 ;;-5._03 . r> ;;-9.0
(!) -3.0 -1 .0 I .0 0 <J -I .0 I .0 0 -4.0 -2.0 0.0 2.0
SLOG (A(SI02(AQ»/(0"(SI02(AQ») ...l LOG (A(SI02(AQ»/(O"(SI02IAQ») ::' LOG IAISI02IAQ»/I<TISI02IAQ»)
~ ~
: 0.0 [-11.0 t-20.0r----~-~....."
+ ~ ~
3- 12 . 0 6 MARG 3- 21 .0 6IMARG

t::
~

~:~.:"
-3 CALC I
NOR "AIR
'e . . -3
b- -e~l~,,~,i" 0

..s
,jN~Rj ~A::
I',
:; I :;-15.0 CALC I ~-24 . 0
+-3.0 a + I "-- + CALC", I 'e
+ 1 ::;-1 6 . 0 ::;-25 . 0 '-....J .... ,
~ $ I WOLL:5 WOLL
$-4.0 $-17.0 $-26. 0L-~......L-~""">"~----'
8 -3.0 -1.0 1 .0 8 -4.0 -2.0 0.0 8 -4.0 -2.0 0.0 :2.0
...l LOG (A(SI02(AQ))/(0"(SI02(AQ))) ...l LOG (A(SI02(AQ»/(0"(SI02(AQ») ...l LOG IAI5102IAQ»/I,r.{SI02IAQ)))

Phase relations in the system HCl-H20-AI203-(CaO)-C02-Si02 at XCO = 0.95. Satura-

2
tion limits: quartz (a), corundum (b), kyanite (c), sillimanite (d), andalusite (e).
182
.,.,
:;: 4.0
,.,
:;: 6.0
:; ~ARG~- :r:
$ < 1
MARG " -" -b :::: 5.0 I MARG
+ :;: 3. 0
-
ANOR +
t 4.0
+
+ " t 4.0 "
'NO~
...J

~ ~1"----=-=1
....l
AlC
~ ..: ..: I - -b
-
2
13.0 Ald
ANO -b-
"- \.lAIR -
~ 2.0

+
+ a
~

!
3.0

2.0 CALC
I" " " \.lAIR
1 "d
+ 1 "- + 1.0 +
~ a I
"- ...J
$
1
~ I. 0
1
a " "-

3 $ ..: I

3~ 2.0
-2.0 0.0 2.0
8 0 .-2.0
...J
0
0.0 2.0 30._03 . 0 - 1 .0 1.0 3.0
;::' LOG (A(SI02(AQ))/(<T(SI02(AQ))) ,., LOG (AISI02IAQ))/I,r(SI02IAQ))) ,., LOG IAISI02IAQ))fI"ISI02IAQ)))
::'
~ 4.0 ~ 5.0 ~ 5 0
:; MARG :r: :r: :MARG
: MARG
$ ~ 4.0 ~ 4.0
:;: -b- + +
+ 3.0 + 3. 0 + 3 .0
+ ANOR +
...J " -b +
...J "
..:

-
..: 2. 0
~ "- \.lAIR
~2 0
2 1
- CAlf
:;: 2.0 + 1.0 + 1.0
+ + +
+ 1 + + CALC
....l aI ~ 0.0 :;: 0.0
<
< ~ ..: Oll
-;; 1.0
o -2.0 0.0 2.0 8- 1_03 . 0 - 1.0 1.0 3 .0
~-1 .0
~ -3.0 -1.0 1.0 3.0
LOG (A(SI02(AQ))/(<T(SI02(AQ))) lOG (A(SI02LA.Q))/(CT(SI02(AQ))) LOG (A(SI02(AQ))/((T(SI02(AQ))))
....l
.., ,.,
....J ....J
,.,
E.., 4.0 ~ 1.0 :"-3
+ .0
+ :r: f1ARG 1 MARG
:r:

"~:ANOR~/
3 3 .0 MARG 30.0 3-4.0
:;: + + " : ANOR
+-1 .0 +-5.0 ""1-- -b-
; 2.0 - -:..~~
r:~~tIR +
...J
- "T., -: -
e"
b +
...J
'e"
-
$ 1.0 ~2.0 AI ~-6 .0
2 AlC
1
..... 'e .s .s CALC
CALC 1 "
~ 0.0 1 +-3.0 + -7.0
+ (] \ + I~
a + a
+ + 1
~-I .0 1 ~-4. 0 ~-8. 0 \.lOll
~ 1 \.I l~ ..: ..:
0
8
~-2. ;;-5.0 ;;-9.0
~
..,
-3.0 -1.0
LOG (A(SI02(AQ))/(<T(SI02(AQ))))
1.0
g
o -4.0 -2.0 0.0
LOG IA(SI02(AQ))/I<TISI02IAQ))))
2.0 o -4.0
~
-2.0
LOG IAISI02IAQ))/I<T(SI02IAQ))))
0.0 2.0

• 3 0 E..,-10.0,---~-'---~~ [-19.0r---~----~~
.
~ +
:r: ~ i 1 MARG

-t
:r:
3 2 .0 MARG 3- 11 .0
MARG
~-20. 0 6
;:::

~ 1.0
~ 0.0 ,. . ~.....-b-
t-
~-13·.0
12 0
. \(ANORj
~I-b- -
t-
~-22.0
21
.
0
"
1

1
'-,...C
ANOR
-b-
2 AIR 2 'e .3 I"
: I .0 ItNQR ~-I 4 . 0 I" \.lAIR ~-23 , 0 'e" \.lAIR
AlC 1 ..... 'e + I" +
+
'~-2 .0 a1 +
...J-I 5 . 0
CALC "
I"
"
~-24 . 0 CALC 1
\.I l ~ \.lOll $ 1 \.lOll
<
..: I
3.0 ~-16.0 $-25.0L----'l..-~~-L.------'
8 -3.0 -I .0 I .0 8 -4.0 -2.0 0.0 2.0 8 -4 .0 -2.0 0.0 2. 0
...J LOG (A(SI02(AQ))/(<T(SI02(AQ)))) ...J LOG (A(SI02(AQ))/(<T(SI02(AQ))) ...J LOG IAISI02(AQ))fI"ISI02IAQ)))

Phase relations in the system HCl-H20-Al203-(CaO)-C02-Si02 at XC02 = 0.99. Satura-

tion limits: quartz (a), corundum (b), kyanite (c), sillimanite (d), andalusite (e).
 183
~ 12. 0 EHL
o ·~:r:+
~ I 2 .0 1 bI GEHL
~
•
10.0

f$
!..+
:r:
~ 10.0 \lOLL
GROSS 1/
I ~ 10.0
OL
' ~:r:+ 9.0
~
t i GROSS 1/ i 8.0 - -c-
~ 8.0 ............ LN . ~ 8. 0 ~t ~ 7.0 "-, MARG
~ _ -c- _ - A~G ~ - ~~- -c- ~6 0
A~Rf-_ _-I
+ \I + I MARG +.
:!: 6. 0 arz :!: 6. 0 arz :!: arz \
S:! S:! S:! 5.0 I SILL
$ $ I KYA $
I
84.0 84.0 84.0
...l -2 .0 0.0 2.0 ...l -2. 0 0. 0 2.0 ...l -2 . 0 0.0 2.0
LOG (A(AL+++)/(u(AL+++»)(A(H+)**3» LOG (A(AL+++)/(u (AL+++» (A(H+)**3» LOG (A(AL+++)/(u (AL+++» (A(H+)**3»

~. 12.0

+
~ I 0. 0 GROSS
IGEHL
I
y
I /
;;
•• 12.0

~
~ 10. 0 \lOLL
\

:::1 0,
I

GEHL
;; 10.0
t
S
$
9.0
~8.0
\lOL

c-
ROS I
I
~ GEHL

i
:::: \lOL - -+i'-----1
+ ~~
5 .......... ~t MARG ~ 8.0
GROSSli-
/1 5
+ ~~NZ

~
8. 0 7.0 /
\i--
I MARG
~ --c~ ~ F--;:~M~~~ ~6.0 OR I

:!: 6.0 :!: 6.0 .. ".1, :!: 1'----1

I
aTZ
S:!
$ I KYA
S:!
$
aTZ
I AND
S:! 5.0
$
aTZ ~ SILL

84.0 84.0 84.0

...l -2. 0 0.0 2.0 ...l -3.0 -I . 0 I .0 ...l -3.0 -I .0 I .0
LOG (A (AL+++)/(u (AL+++»)(A(H+)**3» LOG (A(AL+++)/(u(AL+++»)(A(H+)**3» LOG (A(AL+++)/(u(AL+++»)(A(H+)**3»

;; I I . 0.---,....,..~""""'----, ;; 7.0 I
: GEHL
~
~ 9.0 \lOLL
GROSS./
I' ~ 6. 0 ~::~~ ~E~~
-C::A~~-
:::: 5.0 GROSS .......

1 - PREHNJA~\~ARG + I
~ 7.0 ~ 4.0 :\NOR: MARG
~ \~ ~ 3.0
:!: 5.0
S:!
$
arz I
I AND AND 52.0
$
aTZ I'
I AND
83.0
...l -4.0 -2.0 0.0 -5.0 -4.0 -3.0 3 1_'100 .L-0~_-9~.-0........J_L-8~.0---7-1. 0
LOG (A(AL+++)/(u(AL+++»)(A(H+)**3» LOG (A(AL+++)/(u (AL+++» (A(H+)**j» LOG (A(AL+++)/(u(AL+++» (A(H+)**3»

;; I I .0.---........" " ' " - - - , ;; 0.0

! \lOLL ~EHL
GEHL I
~_I .0 ~GEHLti
:r:
~ 9.0 GROSS
\lOLL~~ 6 '< - - I-- -c
GROSS-Z ; 2.0

t
I

~y'
ROS
t c-~f ~-3. 0 \lOLL I.........
"'~A.!iG
~I
~ 7.0 MAR
-C- _.... b ANOR I AR
ANOR:
PREHNj~~1 ~ 4.0 '\-" I
arz ,9 aTZ
I AND ~-5. 0 aTZ \}lAND
lAND ~ I
3 3 ._06 .0 -4.0 -2.0 3- 3_'108.0 -17.0 -16.0 -15.0 3-6_.~ .L-0--~2-6~.-0---2.J..5~.0--2-4""".0
LOG (A(AL+++)/(u(AL+++»)(A(H+)**3» LOG (A(AL+++)/(u(AL+++»)(A(H+)**3)) LOG (A(AL+++)/(u(AL+++»)(A(H+)**3»

Phase relations in the system HCI-H20-AI203-CaO-C02-(Si02) at Xco2 = 0.01. Satura-

tion limits: diaspore (a), corundum (b), calcite (c).
 184

.f
+
:r:
~
12. a r--"""-~-'::-"'-E-H""'L

113.13
GROSS hi : j
;:; 12.13

~
5'13.13
OL
I
I GEHL
;:;
:
~ 9 .a
-<
,13.13r--.,.......,-....,..,-~--,

WOL
GROS
9GEHL
-,/1
+ ~ ::j3 GROSS ~ 8.13

_c_~~A~'
"OLL
+
~ 8.13 ;::
~ 8.0
~II / MAR' ;::
8 7. 0
,?-!if-c- -
~ MAR'
~
+ ~ -c ~ _L~ ,- - - ~ 6 . 13 ~
;:: 6.13 ;:: 6.13 +
aTZ S:! aTZ ~ 5.13 aTZ
S:! SILL
:5 :5 KYA:5
84.13 84.13 84.13
-l -2.13 13.13 2.13 -l -2.13 13.13 2.13 -l -2.13 13.13 2.13
LOG (A(AL+++)/(rr(AL+++» (A(H+)"3» LOG (A(AL+++)/(rr(AL+++»)(A(H+)··3» LOG (A(AL+++)/(rr(AL+++»)(A(H+)"3»

..
i
;:; 12 . e.-----r~-..--..----. ;:; 12.13.--........- - - - . . - - - - . ;:; 10.0 I
: WOL IGEHL GEHLI
WOLL~,
'+
:r:
~ 113.13 GROSS ?/ ~ WOLL
5 113 . 13 ~ 1: 8
9 .0

0 GROS
GEHL

),1-
1 '+ GROSSI, ~.

"d, +
~ 8.13 ~ 7.0 ~ ?""Jf:C=-N:'
~""";
~ 8.13
~7;MARG ,£ ~ "'~RI
--;:: 6.0
MARG
-c- - -\' - - '+
-c- ~6.0 I
+ I ----i
aTZ
I KYA
S:!
:5
aTZ
I AND
~ 5.0 aTZ.l
1
SILL
84.13 84.0 84.0
-l -2.13 0.13 2.0 -l -3.0 -1 . 0 1 .0 -l -3.0 -1 .0 1 .0
LOG (A(AL+++)/(rr(AL+++»)(A(H+)··3» LOG (A (AL+++)/(rr (AL+++»(A(H+)··3» LOG (A(AL+++)/(rr(AL+++»)(A(H+)"3»

;:;11.0 ;:;10.0 ;:;7.0

: WOLL Gj::HL : :

~:L~ ~o~ ....:.~G_EH_L-. . I

~ GROSS I ~ ~ 6. 0
5 9.0 v' 5 8 . 13 <
~ _<~::j3 ~5.e
:j: ,,~N/N + +
~7.e ",-_MARG ~6.0 ,.....--:c-::1-- ~4.0
,£ -C- - -A~~ - ~ ~ORII MARG b ~OR ~ AR'
~ \b '+ ~3.0
;:: 5.0
S:!
:5
aTZ I
I AND
;:: 4.0
S:!
:5
aTZ '1
I AND
;::
S:! 2 . 13
:5
aTZ \i I
AND

83.13 82.0 81.0

-l -4.0 -2.0 0.13 -l -6.13 -5.0 -4.0 -3.0 -l -10.0 -9.0 -8.0 -7.0
LOG (A(AL+++)/(rr (AL+++» (A(H+)··m LOG (A(AL+++)/(rr (AL+++» (A(H+)··3» LOG (A(AL+++)/(rr (AL+++» (A(H+)"3»

;:;11.0 ;:;5.0
.
;:; 0.0
:
~
WOLL GBHL
I
:
~ WOLL~
GEHL ~
i- 1. 0 IGEHL
5 9 .0 GROSS 5 3 •0
~-2.0 W~LL I~ -c-
'++
~ 7.0
~'1'ARG
PREHN'
'++
~ 1 .0
-c-
, ~~:- ARG
+
~-3. 0
GF~I"
I ~ARG
~
;::5.0
-C-ANOR~lb -
II
~
;::-1.0 aTZ
NORI
I
l'
f-4 .0 ,\OR ~ I
S:!
:5
aTZ lAND S:!
:5
I AND ~-5.0 aTZ \ I AND
:5 I
33 ·..e6 . 0 -4.0
LOG (A(AL+++)/(rr(AL+++»)(A(H+)"3»
-2.0 §-3':108.0-17.0-16.0-15.0
LOG (A (AL+++)/(rr (AL+++»)(A(H+)"3»
§-6.:17 . 0 -26.0 -25.0 -24. 0
LOG (A(AL+++)/(rr(AL+++»){A(fl+)"))

Phase relations in the system HCl-H20-A1203-CaO-C02-(Si02) at XC02 = 0.05. Satura-

tion limits: diaspore (a), corundum (b), calcite (c).
 185
;::; 12. 0r-~~-.........,r-~----' fi 10.0 I
Hl
~:I: ~Oll ~I * 9GEHl
9/
WOll WOl
GEHl
~ 9.0
GROSS < 10.0
I

+ GROSSI ;---- ~ 8.0 G~f MARG

~~RG 58.0 _
3
+
~
~MARG
-..... IN
-c- -A t - -
~7.0
3
::;: 6.0
_ .::::-.,~N#_C __
-c- - - - \ 1_ ~ 6.0 +
<
aTZ PY 8
,::;
aTZ II KYA
85.0
,::;
aTZ
SIll

84.0 84.0
~ -2.0 0.0 2.0 ~ -2.0 0.0 2.0
LOG (A(AL+++)/(cr(AL+++»)(A(H+)**3» LOG (A(AL+++)/(cr(AL+++»)(A(H+)**3» LOG (A(AL+++)/(cr(AL+++» (A(H+)"3»

;::; 12. 0r--"-~-....-.., ;::; 12. 0 ...---.,.--~..,-~-..., ;::; 10 . 0 r----..,--........,bl,.--~--,

: IGEHl ** t WOll
~ + ~ 9.0 : GEHl
~ 10.0
GROSSI
1/ :I:
~ 10.0 ,::;
;::: 8.0
GROS
v.

........... ~
+ + ::: ~J..SlNZ
+ +
~ 8.0
~
IN I
9MARG
~ 8.0
~ ~7.0 ~~jll-~;G-
+ -C- - - '\1- - + ::;:6.0 ~
~ 6.0 aTZ ~ 6.0 +
<
8 PYR 8 8 5 .0 aTZ SIll
,::; ,::; AND ,::; I
84.0 84.0 84.0
~ -2.0 0.0 2 .0 ~ -3.0 -1 . 0 1 .0 ~ -3.0 -1 .0 1 .0
LOG (A(AL+++)/(cr(AL+++»)(A(H+)**3» LOG (A(AL+++)/(cr (AL+++» (A(H+)**3» LOG (A(AL+++)/(cr(AL+++»)(A(H+)**3»

;::; 11 • 0r--....,-~-~----, ;::; Ie. e.--.,..-~-~~~---, ;::; 7.13

r-
: ~EHl
iI t;):; Ol1:siGEHlbll
**

~
GEHl
~ GROSS ~ ~ 6.13
WOll I
~ 9.13 WOll ~ ~ 8.13 <
;:: 5.13
t -. . . t GROS:. LIZ
~ +
+ - C- ~ROS '"t......
~ 7. 13 ~blQJ1.ARG ~ 6.0 _ _ '~~11A8..G ~ 4.0 / 9 ARG
~
+
- C- - \J h -
,r
~
+
NOR I
I
b
~3.0 \ANO~
~ 5.13
8
,::;
aTZ I
lAND
~ 4.0
8
,::;
aTZ I
I AND
+
<
82.13
,::;
arz \Y AND
I
83.13
~ -4.13 -2.0 0. 0
82.13
~ -6.0 -5.0 -4.13 -3.0
8~ I.e
-10.0 -9.0 -8.0 -7.0
LOG (A(AL+++)/(cr (AL+++» (A(H+)**3» LOG (A(AL+++)/(cr (AL+++» (A(H+)" 3» LOG (A(AL+++)/(cr(AL+++»(A(H+)**3»
;::; 11 • e ...-~.,...,..~-~-..., ;::; 5.13 ;::; 0.0
: G~Hl ** GEHl I **
b
h
~ WOll I +
:I: WOll ~-1.0 ~IGEHl
~ 9.0 GROSS ~ 3.13 ::;: WOll I

+
+
V +
+
GROSS;
lNZ ..........~
;::-2.13
:::
GRO
-C-I-7T...........
~ 7.13
3
+
~
~~N_~A~G ~ I.e
3
+
~
--.~ AR

~:
~-3.0
b
~-4. 13
/
~'
ANOR I M RG
b
~ 5.13
8
,::;
aTZ "
lAND
~-1 .13
8
,::;
arz
I AND a-5.e
<
arz ' /
)I AND
~ I
§ 3 '~6 . 0 -4 . 13 -2 . 0
8-3.13
~ -18.0-17.13-16.13-15.13 §-6__ 17. 13 -26.0 -25.0 -24.0
LOG (A(AL+++)/(cr(AL+++»(A(H+)**3» LOG (A(AL+++)/(cr (AL+++»)(A(H+)**3» LOG (A(AL+++)/(,,.(AL+++J)(AOHJ**3JJ

Phase relations in the system HCl- H20 - Al 20 3 - CaO - CO 2 - (SiO z) at X eoz = 0.10. Satura-
tion limits: diaspore (a), corundum (b), calcite (c).
186
~ 12 • 0 .---r-~___.-,--~---, ;; 12 • 0r--.---~.-~--" ~ 10 . 0 r - -...'"""'....--,I,--~-..,
~ II GEHl ~ ~GEHl ~
i 9.0 WOll 9GEHl
3 10 . 0 GROSS 11/
3::I: 10 . 0 all I
<

i.. :~ MAR' I··· -c-~~:~R~

:I:
GROSS
/1
5
~8.0
,~r/MARG
.3
t
7.0

6. 0
- - =-\_I
ANOR,....\~
rc -
~6.0 - - - C -I ~6.0 aTZ \ 00(
8 8 b 85.0 aTZ I SIll
~ PYR PHKYA ~ 1 KYA ~
I
84.0 84.0 84.0
-' -1.0 1.0 3.0 -' -2.0 0.0 2.0 -' -2.0 0.0 2.0
LOO (A(AL+++)!(", (AL+++ll (A(H+)**3)) LOO (A(AL+++)!(", (AL+++» (A(H+)**3» LOO (A(AL+++)!(", (AL+++»)(A(H+)"3»

;; 12.0 ;; 1 2 . 0r--....--~-,-~--,
:
~
IGEHl:
~
!~0~0 WOll
~IGEHl
((j:
WOl GROSS b11) / WOll ::I:'
3 10 . 0 / 3 10 . 0 <
~8.0 ROS --.
~:j:
~ 8.0 -........ IN IIMARG
~+
~ 8.0
l ,..../ t'ClNZ
~ 7.0 -c _-~Q.; M~R~
.3 .3
~ LI ~ +6.0 b.
~ 6.0 - aTZ - ~ - C- ~ 6.0 ~ arz Y
8 8 aTZ 85.0
00(
I SIll
~ ~ - I
84.0
-' -2.0 0.0 2.0
84.0
-' -3.0 -1.0 1.0 § 4 '~3 . 0 -1 .0 1.0
LOO (A (AL+++)! ('" (AL+++» (A(H+ ) .. 3)) LOO (A (AL+++)!('" (AL+++» (A(H+)**3» LOO (A(AL+++)!(",(AL+++»)(A(H+)**3»

·•
;; 11 .0 ;; 7.0
I
~GEHl ••
+ WPl
~,
GEHl
::I: GROSsi ~6.0
3' 9.0 < WOll

-.. . cr:J:
ROS
......
t MARG
~5.0
+
+
-c- ' - -
~ 7.0 ~ 4.0 - - ,t...

.3 - _A~F-t -C- - ~ .3 ANOR M RG

'
~
~5.0
\1 +
~4.0
i
+
3 .0
arz
b
8
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LOO (A(AL+++)!(",(AL+++»)(A(H+)"3)) LOO (A(AL+++)!(",(AL+++»)(A(H+)**3» LOO (A(AL+++)!(",(AL+++»)(A(H+)**3»
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Phase relations in the system HCI- HzO- Al z0 3 -CaO-COz- (SiO z) at X eoz = 0.30. Satura-
tion limits: diaspore (a), corundum (b), calcite (c).
 187

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LOG (A(AL+++)/(u(AL+++»(A(H+)**m LOG (A(AL+++)/(u(AL+++»(A(H+)"m LOG (A(AL+++)/(u(AL+++»(A(H+)"3»

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Phase relations in the system HCl-H20-AI203-CaO-C02-(Si02) at XC02 = 0.50. Satura-

tion limits: corundum (a), calcite (b), diaspore (c).
188
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Phase relations in the system HCI-H20-AI203-CaO-C02-(Si02) at XC02 = 0.70. Satura-

tion limits: corundum (a), calcite (b).
 189

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Phase relations in the system HCl- H 20- AI 20 3 -CaO-C0 2 - (Si0 2) at Xco 2 = 0.90. Satura-
tion limits: corundum (a), calcite (b).
190
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Phase relations in the system HCI-H20-AI203-CaO-C02-(Si02) at XC02 = 0.95. Satura·

tion limits: corundum (a), calcite (b).
 191
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Phase relations in the system HCl-H20-AI203-CaO-C02-(Si02) at XC02 = 0.99. Satura-

tion limits: corundum (a), calcite (b).
192
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Phase relations in the system HCI-H20-(AI203)-C02-MgO-Si02 at XC02 = 0.01. Satura-

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Phase relations in the system HCl-H20-(AI20J)-C02-MgO-Si02 at XC02 = 0.05. Satura-

tion limits: quartz (a), talc (b), magnesite (c), forsterite (d), antigorite (e), brucite (f), periclase
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Phase relations in the system HCI- H 20 - (AI 20 3) -C0 2 - MgO-Si02 at XC02 = 0.10. Satura-

tion limits: quartz (a), magnesite (b), talc (c), forsterite (d), antigorite (e), brucite (f), periclase
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Phase relations in the system HCl- H 20- (AI 20 3) -C0 2 - MgO-Si0 2 at X C02 = 0.30. Satura-
tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
196
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Phase relations in the system HCl-H20-(Al203)-C02-MgO-Si02 at XC02 = 0.50. Satura-

tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
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Phase relations in the system HCl- H 20 - (AI 20) - CO 2 - MgO - Si0 2 at X C02 = 0.70. Satura-
tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
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Phase relations in the system HCl-H20-(Al203)-C02-MgO-Si02 at XC02 = 0.90. Satura-

tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
 199
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2 .a

Phase relations in the system HCl-H 20-(AlP3)-C0 2 -MgO-Si0 2 at XC02 = 0.95. Satura-
tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
200
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Phase relations in the system HCI- H 20 - (Ah03) -C0 2 - MgO-Si0 2 at Xeo2 = 0.99. Satura·

tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
 201
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Phase relations in the system HCI-H20-(AI203)-C02-MgO-Si02 at XC02 = 0.01. Meta-

stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), talc (b), magnesite (c), forsterite (d), antigorite (e), brucite (f), periclase
(g).
202
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Phase relations in the system HCl- H 20- (AIP3) -C0 2 - MgO-Si0 2 at XC02 = 0.05. Meta-
stable 7-A c1inochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), talc (b), magnesite (c), forsterite (d), antigorite (e), brucite (0, periclase
(g).
 203
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Phase relations in the system HCI- H 20 - (AI 20 3) - CO 2 - MgO - Si0 2 at XC02 = 0.10. Meta-
stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), talc (b), magnesite (c), forsterite (d), antigorite (e), brucite (0, periclase
(g).
204
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Phase relations in the system HCI-H20-(AI203)-C02-MgO-Si02 at Xeo 2 = 030_ Met1

stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satun
tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
 205
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Phase relations in the system HCl-H20-(AI203)-C02-MgO-Si02 at XC02 = 0.50. Met1

stable 7-A c1inochlore was considered instead of its stable counterpart, 14-A clinochlore. Satun
tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
206
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Phase relations in the system HCl-H20'(AI203)-C02-MgO-Si02 at XC02 = 0.70. Meta-

stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
 207
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Phase relations in the system HCl-H20-(AI203)-C02-MgO-Si02 at XC02 = 0.90. Meta-

stable 7-A c1inochlore was considered instead of its stable counterpart, 14-A c1inochlore. Satura-
tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
208
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Phase relations in the system HCl- H 20 - (AI 20 3) -C0 2 - MgO-Si02 at XC02 = 0.95. Meta-

stable 7-A c1inochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
 209
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Phase relations in the system HCl-H20-(Al203)-C02-MgO-Si02 at XC02 = 0.99. Meta-
stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), magnesite (b), talc (c), forsterite (d).
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Phase relations in the system HCI-H20-AI203-C02-(MgO)-Si02 at XC02 = 0.01. Satura-

tion limits: quartz (a), kyanite (b), corundum (c), andalusite (d), sillimanite (e), diaspore (0,
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Phase relations in the system HCI-H20-AI203-C02-(MgO)-Si02 at XC02 = 0.05. Satura-

tion limits: quartz (a), kyanite (b), corundum (c), andalusite (d), sillimanite (e), diaspore (f),
pyrophyllite (g).
 212
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Phase relations in the system HCl-H20-AI203-C02-(MgO)-Si02 at XC02 = 0.10. Satura-

tion limits: quartz (a), kyanite (b), corundum (c), andalusite (d), sillimanite (e), diaspore (0,
pyrophyllite (g).
 213
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Phase relations in the system HCl-H20-AI203-C02-(MgO)-Si02 at XC02 = 0.30. Satura-

tion limits: quartz (a), kyanite (b), corundum (c), andalusite (d), sillimanite (e), diaspore (f),
pyrophyllite (g).
214
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Phase relations in the system HCI-H20-AI203-C02-(MgO)-Si02 at XC02 = 0.50. Satura-

tion limits: quartz (a), kyanite (b), corundum (c), andalusite (d), sillimanite (e), diaspore (f),
pyrophyllite (g).
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Phase relations in the system HCI-HP-AI 20 3 -C0 2 -(MgO)-Si0 2 at X C02 = 0.70. Satura-
tion limits: quartz (a), kyanite (b), corundum (c), andalusite (d), sillimanite (e).
 216
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Phase relations in the system HCI- HP- AI 20 3 -C0 2 - (MgO) -Si0 2 at XC02 = 0.90. Satura-
tion limits: quartz (a), kyanite (b), corundum (c), andalusite (d), sillimanite (e).
 217
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Phase relations in the system HCl-H20-AI203-C02-(MgO)-Si02 at XC02 = 0.95. Satura-

tion limits: quartz (a), kyanite (b), corundum (c), andalusite (d), sillimanite (e).
218
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Phase relations in the system HCI-H20-AI203-C02-(MgO)-Si02 at XC02 = 0.99. Satura-

tion limits: quartz (a), kyanite (b), corundum (c), andalusite (d), sillimanite (e).
 .~
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Phase relations in the system HCl- H20- AI 20 3 -C0 2 - (MgO) -Si0 2 at XC02 = 0.01. Meta-
stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), diaspore (b), corundum (c), andalusite (d), kyanite (e), sillimanite ([),
pyrophyllite (g).
220
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Phase relations in the system HCl-H20-Al203-C02-(MgO)-Si02 at XC02 = 0.05. Meta-

stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), diaspore (b), corundum (c), andalusite (d), kyanite (e), sillimanite (f),
pyrophyllite (g).
 221
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Phase relations in the system HCl-H20-A1203-C02-(MgO)-Si02 at XC02 = 0.10. Meta-

stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), diaspore (b), corundum (c), andalusite (d), kyanite (e), sillimanite (f),
pyrophyllite (g).
222
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Phase relations in the system HCI- H 20- AI 20 3 -C0 2 - (MgO) -Si0 2 at XC02 = 0.30. Meta·
stable 7-A c1inochlore was considered instead of its stable counterpart, 14-A c1inochlore. Satura·
tion limits: quartz (a), diaspore (b), corundum (c), andalusite (d), kyanite (e), sillimanite (n.
pyrophyllite (g).
 II
~ ~ 223
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Phase relations in the system HCl-H20-AI203-C02-(MgO)-Si02 at XC02 = 0.50. Met

stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satur
tion limits: quartz (a), diaspore (b), corundum (c), andalusite (d), kyanite (e), sillimanite (J
pyrophyllite (g).
224
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Phase relations in the system HCl-H20-AI203-C02-(MgO)-Si02 at XC02 = 0.70. Meta-
stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), corundum (b), andalusite (c), kyanite (d), sillimanite (e).
M M 225
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~ 7.0 I ~ 5.0 I
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+ I
:; a ~ :I: I'SPINEL
5 SPINE I 34.0
I
aI 0( , I CORD
~ 5.0 I + SPINEL e, I
t a
+
+
I CORD
I
+ 3.0
+
I CORD
I +
1.0
"" I
o-l ..J ..J
,\"-b- -
-+
~ 3.0 ~ 2.0
0(
I C, I 2
~
t 1.0
_d.::.",,-~ _ -b-
I
+ 1.0 ---~~
t +
+
0.0
MAG
Fe
~tf\
N5 "
<! MAG TALC ~ 0.0 MAG I ~ ..J
I
<
0(
0(
I TALC 0( I
TALC
~-I .0 ;-1.0 --1.0
8 -3.0 -I .0 I .0 0 -3.0 -I .0 I .0 8 -3.0 -1.0 1.0
~ LOG (A(SI02(AQ»/(u(SI02(AQ»» ~ LOG (A(SI02(AQ»/(u(SI02(AQ»» := LOG (A(SI02(AQ»/(u(SI02(AQ»»

J.., 3.0 ;"'-1.0 I

+
~
~ 2.0
+
:;
5
SPINEL I
a "
SPINEL "~ :CORD
" 'c , :=t:/ \:
I
+
+ 1.0
+
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ICORD
t-7.0 I ,
11\
+ +
"" I FORST
+
~0.0 ~ I_ b _ ~

i\
~ ~ 2 EN~
~-1.0 ~-3.0 ~-8.0 MAG I
+ + Fa + a
~~2.0 ~ MAG E ~ tN H
ljH tALC
< -5-9.0
5 0 ( 0 (
0(
~-3.0 --4.0
TALC I
8 -4.0 -2.0 0.0 8 -4.0 ~2.0 0.0 8 -4.0 -2.0 0.0
~ LOG (A(SI02(AQ»/(u(SI02(AQ)))) ~ LOG (A(SI02(AQ»/(u(SI02(AQ»» ;::' LOG (A(SI02(AQ))f(u(SI02(AQ))))

r 0.0 [-13.0 r-23.0r-~~~-,---..,

+
~ +
~ aI -~ "
SPINEL" L
CORD
~~1 .0 ~ INEL I CORD 3 - -b- - ,-l.-

1-2 . 0 1- 14 . 0 'C'" : 1-24 . 0 ~I'CC"

+ + + -- ~--b- :'\
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~ ~"2 MG I
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+ + MA +
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5 5 TALC 0(

5-6·~4.0 -2.0 0.0 5- 16__..f'.0 -2.0 0.0 ~-26__~.0 -3.0 I -1.0

§ LOG (A(SI02(AQ»/(u(SI02(AQ»» § LOG (A(SI02(AQ»/(u(SI02(AQ»» g LOG (A(SI02(AQ»/(u(SI02(AQ))))

Phase relations in the system HCl- H 20 - Al 20 3 - CO 2 - (MgO) - Si02 at XC02 = 0.90. Meta-
stable 7-A c1inochlore was considered instead of its stable counterpart, 14-A c1inochlore. Satura-
tion limits: quartz (a), corundum (b), andalusite (c), kyanite (d), sillimanite (e).
226
f 5.0 i 7.e
'+ SPINELi ~ '+ C
~ 4.0 .l I CORD
5
~ 5.e SPINEL
I
SPINEL
1 !~ ----~ -b-
3.0 '+
:I:
I CORD
I
I
....
e, I

~I ~ " a
o-l o-l
c5 2.0 c5 3.0 d I 1---,--"'--' I
-S MAG
1+ I.e --~~fI~
~
:;:: 1.0 TALC
+
+ MAG
~ 0.0 ~ I TALC
$ $ I
8-1.0-3.0
o-l -1.0 1.0
8- 1 •-3.0
o-l
0
-1 .0 1.e
LOG (A(SI02(AQ))!«J"(SI02(AQ)))) LOG (A(SI02(AQ))!«J"(SI02(AQ))))

;> 5.0 ;> 5. e

*
'+ a
I
'+* b
e 4.0 PINEL I 54.e I
SPINEL
c5 CORD c5 SPINEL I CORD
1
I :CORD
3.0 0:::--

- 'j~- -b-
I 1
o-l
3 .0 I
I
'e ,
a
I
~ 2.0 c5 2.e C..... I
-S :r~ -s - - -~ - -b- - -S
" I

'~L-b-
:;:: 1.0 :;:: 1. e
~
:;:: 1.0
MAG I + F S ~
:I: TALC :I:
MAG
+
JI.IS " ,
~ 0.e ~ 0.e
o-l
« MAG
$ c5 TALC $ IAN
8- 1 •-3.e
o-l
e -I.e I.e
e e
3'-'-I .-3. -1 . e 1.e
8 e.e
o-l -3. e -1 . e 1. e
LOG (A(SI02(AQll!«J"(SI02(AQ)))) LOG (A(SI02(AQ))/«J"(SI02(AQ)))) LOG (A(SI02(AQ))/«J"(SI02(AQ))))

i 3.e I
:-I.e
'+ SPINEL I
'+ .... C,
52.e :t
'C, :CORD
c5 ,CORD $ a
C....
l1.e t- -b - -:",~I -
a
- -,
1-
+
2.0 PINEL "" PINEL" "
- -b--
I

-t--
~
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c5 e.e
-S
c5
-S
I
"'
:;::-I.e MAG :;::-3. e FORS
I
+ TALC :I: ~ST
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c5 MAG
MAG
I AN H
$ c5 T C
8- 3 •-4.e
o-l
e -2.e e.e 8- 4 .-4.0
o-l
0
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8-
~
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LOG (A(SI02(AQll!«J"(SI02(AQ)))) LOG (A(SI02IAQ))!I(J"ISI02IAQ)))) LOG (A(SI02(AQ))!«J"ISI02IAQ))))

;> 0.0 ;>-13. e , a

f- 22 . er-7,-------r,----,
*
'+
'SP~NEL
'+* + . . C. . I
5-1.0
.....
5 "
~pnlf;L
I CORD e FORD
- -/1\-
c5 c5 I
~:::
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PINEL" aI
f23.e- ~"T,,-
:I: I :I: r-- "

II~ !~ ~
~-3.e a o-l
c5
-S MAG I
-S
I TALC F ORST~ " FORST
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:I: :I: MAG ANTH
I '->--' M ;NSTft,
~-5.0 ~ ~ T~I
$ I c5 I TALC ~ LC~
§;6·~4.e -2.e e.e 8o-l -16-4.e
.e
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'-'-25 .,
3 -"5.e -3.e -1.0
LOG IA(SI02(AQ))/«J"(SI02(AQ)))) LOG (A(SI02(AQ))!«J"(SI02(AQ)))) LOG IAISI02IAQ))f«J"ISI02IAQ))))

Phase relations in the system HCI-H20-AI203-C02-(MgO)-Si02 at XC02 = 0.95. Meta-

stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: quartz (a), corundum (b), andalusite (c), kyanite (d), sillimanite (e).
 227
:' 6.0 :' 6.0 I
'+ SPINEL '+
:r: SPINEL I
~ 5.0
CORD
3 5 .0 I
CORD

t 4.0
-b- t+ 4.0 d I
+
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- - '-~~-b--
I

1
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1""'-

2 .0 t 2.0
MAG aII~
TALC +
..... TALC
~ 1.0 :s I .0 Et> T
~ :s I
8 0 .-3.0
...l
0
-1.0 1.0
800
...l -3.0 -1.0 1.0
LOG (A(SI02(AQ»/(u(SI02(AO)))) LOG (AISI02IAQ»)/lu(SI02(AQ)))) LOG (AISI02IAQ))/luISI02IAQ))))
;;;
: 6.0 :' 6 0 I
'+
:r:
'+
:r: I
3 5 .0 CORD 3 5 .0 SPINEL I
CORD
t+ 4.0 t+ 4.0 I
a
.....
:s 3.0
...l I
:5 3.0 ~
I
.3 .3 - - -~- -b-
t
~

~ 2 0 MAG
aI 2 0
l~
+ . I
+ I + ~ 1

:s
...l
1. 0 TALC
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:5 I .0 Ej~S a A H

:s :s MAG
I TALC
I
I
TALC
80.0 800 800
..... -3.0 -1.0 1.0 ...l -3.0 -1.0 1.0 ..... -2.0 0.0 2.0
LOG (A (SI02(AQ»/(u(SI02(AQ»» LOG (A(SI02IAQ))/luISI02IAQ)))) LOG IAISI02IAQ»)/luISI02IAQ))))
~ ~

~ 5.0 ~ 0.0 ~-4.0

~ ~ ~ \
~ 4.0 3 SPINEL, CORD

r ,·
<:
~ :::: \ a
~ +
?
PINEL I + 5 0 \ I
13.0 , CORD 0 ;-. -/!';t--b-
~ 2.0 ~_ ~ ~ ~\
1 'c\ \
_ -b _
~ 1.0 I~" ~-20 ~-6.0 OR
+ I .... c, + ! ~s
~ 0 0 MAG ,:; MA
~ . TALC:S \:;! I A \
~ I <: <: T~
8
...l
1 0
'-4.0 -2.0 0.0 2.0
;-3.0
0 -4.0 -2.0 0.0 2.0
--7.0
8 -4.0 -2.0 0.0 2.0
~ LOG (A(SI02(AQ»/(u(SI02(AQ»))) ...l LOG (A(SI02(AQ))/(u(SI02(AQ)))) .:::! LOG (A(SI02(AQ»/(u(SI02(AQ»»
;;;
~ 3.0 [-12.0 [-21.0
+ + + \
:r: :r: ::s C, I CORD
32.0 3 :5
a
I

SPINEL\
I
! 1.0 !-13.0 !-22.0 r- -b - - I}- - -
:; +. :;

~\
~0.0 ~ :5 r----
.3 .3 b
~-I . 0 ~-I 4 . 0 ~-23 . 0 FORS
+ + + I S LC
:;-2 0 + + MAG
:;! :;!
<:
<
.
< -:5-24.0 IAND.tfl~
- 3 0 --15.0
8 '-6.0 -4.0 -2 0 0.0 8 -6.0 -4.0 -2.0 0.0 8 -6.0 -4.0 -2.0 0.0
...l LOG (A(SI02(AQ»/(u(SI02(AQ)))) ...l LOG (A(SI02(AQ»/(u(SI02(AQ»» ..... LOG (A(SIU2IAQ))/luISI02IAQ))))

Phase relations in the system HCl-H20-Al203-C02-(MgO)-Si02 at XC02 = 0.99. Meta-

stable 7-A c1inochlore was considered instead of its stable counterpart, 14-A c1inochlore. Satura-
tion limits: quartz (a), corundum (b), andalusite (c), kyanite (d), sillimanite (e).
 228
~ 8.13
a,
"
+
;;
FORST
FORST
d b,
\
d\
~ 7.13 FL - -C- -e- - -
+
14-A FORST ~4=-A
+ \ ICL
\:)
\1
~ 6.13
~
+
~
TALC
TALC ~8
ib 5.13
~ aTZ aTZ
.:$ aTZ
84.13 83.13 83.13
..J -2.13 0.0 2.0 ..J -3.13 -1.13 1.0 ..J -3.0 -1.0 1.0
LOG (A (AL+++)!«T (AL+++» (A(H+)**m LOG (A(AL+++)!«T (AL+++» (A(H+)**3» LOG (A(AL+++)!«T (AL+++» (A(H+)**3»

~ 7.0
a, "
'+ FORST
I
b
:I:
_ - - ..l -.l -C-
14-~ CL ~ 6.0
I ~_IA CL

A~T~ ~
'+ \1 CL
+
\:)

~~\
-C- __ ~ 5.0
~
TALC~:
TALC AND
'+
ib 4.0 I d
1 KYA ~ aTZ \
aTZ .:$ aTZ
84.0 83.0 83.0
..J -2.0 0.0 2.0 ..J -3.0 -1.0 1.0 ..J -3.0 -1.0 1.0
LOG (A(AL+++)!«T(AL+++»)(A(H+)**3» LOG (A(AL+++)!«T(AL+++»(A(H+)**3» LOG (A(AL+++)!«T(AL+++»)(A(H+)**3»

j;' 7.0
"
'+
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~ 6.0
l:i d
14-k
I
CL
j;' 5.0
~
~
*

4.0
-e - - _\
FORST b
\ I
L_ \ b
e- \- -,
'cJ1
14-A C

- ~ 14-A CL
t ANTrG\C - - ~

:Y
::: \1
\:)
~ 5.0
~'\ ~ 3.0
\:)
TALC ~~
t
~
~
t\:)4.0
TALC
1-------'1 d
I \ ~ 2.0 aTZ I \
~ aTZ AND
.:$ I $ lAND \
J
83.0 8,.0 8-1.0
..J -4.0 -2.0 0.0 ..J -7.13 -5.0 -3.0 ..J -10.0 -8.0 -6.0
LOG (A(AL+++)!«T(AL+++»)(A(H+)**3» LOG (A(AL+++)!«T(AL+++»)(A(H+)**3)) LOG (A(AL+++)!«T(AL+++»)(A(H+)**3»

j;'-I .0 j;'-6.0
FORST \ 9 "
'+
e:;
"
'+
:I:
\ b
f- i _,_ 11:--"-
C - -\...J.. - ~-2.0 CL }7.0 d I CL
14-A \~L
ANTI
t
\:)
'+
+
\:)
\ I
FORST\ I

TALC ~I\ ~-3.0

~
~-8.0
~
\1
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d ~ TALC
~

I------~'I '+
ib-4.0 AND ib-9.0 VI \
\
::. ::.
aTZ I AND
I $
aTZ
d $
aTZ I \ AND
I \
82.0 8-5.0 8-1 0 . 0 '--~-----'-"~'--'------'
..J -6.0 -4.0 -2.0 ..J -18.0 -16.0 -14.0 ..J -27.0 -25.0 -23.13
LOG (A(AL+++)!«T (AL+++» (A(H+)**3» LOG (A(AL+++)!«T(AL+++» (A(H+)**3» LOG (A(AL+++)!«T(AL+++)) (MH+!**3))

Phase relations in the system HCl-H20-AlP3-C02-MgO-(Si02) at XC02 = 0.01. Satura-

tion limits: diaspore (a), corundum (b), magnesite (c), spinel (d), brucite (e), periclase (f).
 229
~8.0 :;<7.0 :;<7.0
,
* *
* * *

:1-~ 7•0 CL I <

;:::6.0 NTI
J
14 A CL
I
<
;:::6.0
FORsr 114_A CL
-C- _'J - - -
ot t
0
t l
-, -C - 1- -
t0
\9
~ 6. 0 ~ 5.0 TALC b, ~ 5. 0
~ 2
i 4. 0
2
¥ TALC ""~
it+ 5. 0 0 KY A 0 4. 0
r - - - - - ; I ,SILL
"
3 5 5
~ aTZ ~ aTZ I 'd,
84.0 83.0 83.0
~ -2.0 0.0 2.0 ~ -2.0 0.0 2.0 ~ -2.0 0.0 2.0
LOG (A (AL+++)/(O' (AL+++»(A(H+)**3» LOG (A (AL+++)/(O' (AL+++»(A(H+)**m LOG (A (AL+++)/(O' (AL+++»(A(H+)**3»
:;< 8.0 :;< 7.0
* •
'+
e ~ e'+
57.0 \4}A CL 56.0
14-A:CL
:;:
to
~ 6.0
ANT~ ~ -C- -'ti--
\ o+
~5.0
~
I
~I\AND --t2
TArc~J
TALC
t0 b
,
5 •0 4 .0 1------;'1
,
I 0
~ I aTZ I \ ~
5 aTZ 5 aTZ
I
8
~ 4.0
-2.0 0.0 2.0 ~_ 3·~3.0 -I .0 I .0 ~_ 3·~3.0 -1.0 1 .0
LOG (A (AL+++)/(O' (AL+++»(A(H+)**3» LOG (A(AL+++)/(0'(AL+++»(A(H+)**3» LOG (A(AL+++)/(0'(AL+++»)(A(H+)**3»
:;<7.0 :;<5.0 :;<3.0
~+ b' '+ •
'+ • b'
e l e e - -\- -1- - -e-
56.0 14-A I CL 54.0 FORST 52.0, I 14-A C
'+ ANTIG\ I:;: '+
+ C + + FORST\ I
~ 5.0 TALC " \---II - 3.0 1.0 ~ ~
2 ~ ~ ~
~ ~++ '+ TALC /1,..CORD
it 4.0
~ aTZ ~
2 0
• aTZ
+ " ,
~ 0.0 I a AND
5 5 3 aTZ I "

§ 3 ·~4. 0 -2.0 0.0 § I '-'7. 0 -5.0 -3.0 § 1-'100. 0 -8.0 -6.0

LOG (A(AL+++)/(0'(AL+++»(A(H+)**3)) LOG (A(AL+++)/(0'(AL+++»)(A(H+)**3)) LOG (A (AL+++)t(O' (AL+++»)(A(H+)**3»
:;<-1.0 ~-6.0
FORST ,9 e-i ' - -e - ~:I: \
-f.>. - - 9
14-~ICL 5-2.0 CL 3~7.0 ,I
t t
I
~UG~ -C - -f - FORSl. I
'I
~ I'
r 0 0
TALC ~-3.0 ~-8.0 ANtTH 'I

1-- - - - - - - 1 1 : : :++
d' ~+ TALC , iCORD
• \.J
0-4.0 0-9.0" u
aTZ I' "aTZ " a T Z I ' AND
lAND 3 3 I '
~ 2._06 .'-0-------'"---..J ~-5_·108. 0 8-10. 0'--~-.J.......----'----'
- -4.0 -2.0 _ -16.0 -14.0 ~ -27.0 -25.0 -23.0
LOG (A(AL+++)/(O' (AL+++» (A(H+)**3» LOG (A(AL+++)/(O' (AL+++» (A(H+)**3» LOG (A(AL+++)/(O' (AL+++» (A(H+) **3»

Phase relations in the system HCl-H20-Ah03-C02-MgO-(Si02) at XC02 = 0.05. Satura-

tion limits: diaspore (a), corundum (b), magnesite (c), spinel (d), brucite (e), peric1ase (f).
230
;<
*
:;:
8.0 ;<
*
:;:
7.0 ;< 7.0
*
:;:
e;
,
e; e; FORST , I
,::; 7.0 14-A CLI ,::; 6.0 ~ 6.0 FORST, ,1 4-A C

ANTI~
NTI b
to ;
~
o+
y---, b to -c- Li - -

~~~~~
~ 6.0 ~ 5.0 ~ 5.0 'I
3 3 1'
i
65.0
TALC ~:
~
t0 4.0
f-----' KYA t
~ 4.0
TALC '\
, SILL

~
,::;
-c- - - -
aTZ
PYR
~
,::;
aTZ
~ aTZ d,
84.0 83.0 83.0
....l -2.0 0.0 2.0 ....l -2.0 0.0 2.0 ....l -2.0 0.0 2.0
LOG (A (AL+++)/(<T (AL+++» (A(H+)**m LOG (A(AL+++)/(<T (AL+++» (A(H+)**3» LOG (A(AL+++)/(<T (AL+++» (A(H+)**3»

;<8.0 ;<7.0
* * , I \
:;: :;: b
e;
~ 7.0
t iI t0
CL
I e;
,::; 6.0
FORST \4~A CL FORST'
-c- -
,
o - - - -'I -c-
~6.0
3
::::::++
~'I
_T~c:..
a ~5.0
3
i
TALC ~ ~"AND
TALC
0 5 .0 c- 64.0 I ~
~ I ~
aTZ
,::; aTZ ~ I aTZ
PYR PH 0
8 83.0
....l 4._02 • 0 0.0 2.0 S 3._03 • 0 -1.0 1.0 ....l -3.0 -1.0 1.0
LOG (A (AL+++)/(<T (AL+++»)(A(H+)*·3)) LOG (A(AL+++)/(<T (AL+++» (A(H+)**3» LOG (A(AL+++)/(<T(AL+++»)(A(H+)**3»

;< 7.0 ;< 5.0

*
'+ FORST *
:;: 114- A CL
:I: I :I: FORST
~ 6.0 14-A C~ ~ 4.0 - - - -I -c-
, I
~ ANTIG\ b ~ , I
+ I + 'I
0 0 FORST,
~ 5.0
~
-T~L~~~- ~ 3.0
~
TALC\~ d 1----,)
'+ :;: I \ TALC ~CORD
64.0
~
,::; aTZ
~
62.0
~ aTZ b
I
' AND

aTZ
I'd ,, AND
8 3. 0 8 1 •0 8- 1 • 0
....l -4.0 -2.0 0.0 ....l -6.0 -4.0 -2.0 ....l -10.0 -8.0 -6.0
LOG (A(AL+++)/(<T(AL+++»)(A(H+)*.3» LOG (A(AL+++)/(<T(AL+++»)(A(H+)**3» LOG (A(AL+++)/(<T(AL+++»)(A(H+)**m

;< 6.0 ;<-1.0 ;<i6 • 0

*
:;: *
'+ *
:;:
:I: FORST 14-A CL e; :I:
~ 5.0 b ~2.0 ~-7 .0
:;: :;: :;:
+
0
~~G~ -c- ~_ +
0
+
0

-
~ 4.0 I ~-3 .0 ~-8.0
3 TALC 3 3 ANTH
'+ ~ AND ~ TALC
63.0
~ lAND
6-4.0
~ ~ 6-9.0
~
aTZ aTZ aTZ
,::; I ~ ~
8 2 •0 8-5 • 0 8- 10 • 0 '---~---'------'------'
-6.0
....l -4.0 -2.0 -18.0
....l -16.0 -14.0 -27.0
....l -25.0 -23.0
LOG (A(AL+++J/(<T (AL+++J) (A(H+)**3» LOG (A(AL+++)/(<T (AL+++» (A(H+)**3» LOG (A (AL+++)/(<T (AL+++ J) (A(H+)**3»

Phase relations in the system HCl- H 20- AIP3 -C0 2 - MgO- (Si0 2) at XC02 = 0.10. Satura-
tion limits: diaspore (a), corundum (b), magnesite (c), spinel (d), brucite (e), periciase (f).
 231

r· r r:
:;;8.0 :;;7.0 :;;7.0
*
+ *
+ *
+ \
e
FORST
e 6 e \

1:::
FORST \
A
ANTI. y T_Al_C "'_ 14:A CL
]6.0 "" S -~ s
t
~ 5.0
TALC "" : t
,,4.0
'I t
,,4.0
TALC

,:;: I 6 aTZ 6 aTZ

$ -c- m[ - YA $ $
\
§ 4.-2.0
0
0.0
PY PH
2.0
8 3. 0
....l -2.0 0.0 2.0
8 3. 0
....l -2.0 0.0 2.0
LOG (A (AL+++)/(u (AL+++»)(A(H+)**m LOG (A(AL+++)/(u (AL+++)) (A(H+)**m LOG (A(AL+++)/(u(AL+++»)(A(H+)**m
:;; 8.0 :;; 7.0 :;; 7.0
* * FORST *
+
e I +
e 14-A Cl +
::c
$ 7.0 I $ 6.0 $ 6.0
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Phase relations in the system HCI-H20-AI203-C02-MgO-(Si02) at XC02 = 0.30. Satura-

tion limits: diaspore (a), corundum (b), magnesite (c), spinel (d).
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Phase relations in the system HCl-H20-AI203-C02-MgO-(Si02) at Xco2 = 0.50. Satura-

tion limits: diaspore (a), corundum (b), magnesite (c), spinel (d).
 233
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Phase relations in the system HCl-H20-AI203-C02-MgO-(Si02) at XC02 = 0.70. Satura"

tion limits: corundum (a), magnesite (b), spinel (c).
 234

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Phase relations in the system HCl-H20-AI203-C02-MgO-(Si02) at XC02 = 0.90. Satura-

tion limits: corundum (a), magnesite (b), spinel (c).
 235
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Phase relations in the system HCl-H20-AI203-C02-MgO-(Si02) at XC02 = 0.95. Satura-

tion limits: corundum (a), magnesite (b), spinel (c).
 236
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II L
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Phase relations in the system HCl-H20-AI203-C02-MgO-(Si02) at XC02 = 0.99. Satura-

tion limits: corundum (a), magnesite (b), spinel (c).
 237
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Phase relations in the system HCl-H20-AI203-C02-MgO-(Si02) at XC02 = 0.01. Meta-

stable 7-A c1inochlore was considered instead of its stable counterpart, 14-A c1inochlore. Satura-
tion limits: diaspore (a), corundum (b), magnesite (c), spinel (d), brucite (e), peric1ase (f).
238
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Phase relations in the system HCI-H20-Ah03-C02-MgO-(SiO~) at XC02 = 0.05. Meta-

stable 7-A c1inochlore was considered instead of its stable counterpart, 14-A c1inochlore. Satura-
tion limits: diaspore (a), corundum (b), magnesite (c), spinel (d), brucite (e), peric1ase (0.
 239

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Phase relations in the system HCl-H20-AI203-C02-MgO-(Si02) at Xco2 = 0.10. Meta-

stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: diaspore (a), corundum (b), magnesite (c), spinel (d), brucite (e), periclase (0.
240
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Phase relations in the system HCl-H20-Al203-C02-MgO-(Si02) at XC02 = 0.30. Meta-

stable 7-A clinochlore was considered instea<i of its stable counterpart, 14-A clinochlore. Satura-
tion limits: diaspore (a), corundum (b), rrlagnesite (c), spinel (d).
 241
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Phase relations in the system HCI-H20-AI20J-C02-MgO-(Si02) Xc02 = 0.50. Metastable

7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Saturation
limits: diaspore (a), corundum (b), magnesite (c), spinel (d).
242
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Phase relations in the system HCI-H20-AI203-C02-MgO-(Si02) at XC02 = 0.70. Meta-

stable 7-A clinochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: corundum (a), magnesite (b), spinel (c).
 243
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Phase relations in the system HCI- H 20 - Al 203 - CO 2 - MgO - (Si0 2) at XC02 = 0.90. Meta-
stable 7-A c1inochlore was considered instead of its stable counterpart, L4-A c1inochlore. Satura-
tion limits: corundum (a), magnesite (b), spinel (c).
 244

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Phase relations in the system HCl-H20-AI203-C02-MgO-(Si02) at XC02 = 0.95. Meta-

stable 7-A c1inochlore was considered instead of its stable counterpart, 14-A clinochlore. Satura-
tion limits: corundum (a), magnesite (b), spinel (c).
 245
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Phase relations in the system HCI-H20-AI203-C02-MgO-(Si02) at XC02 = 0.99. Meta-

stable 7-A clinochlore was considered instead of its stable counterpart, 14-A c1inochlore. Satura-
tion limits: corundum (a), magnesite (b), spinel (c).
246
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Phase relations in the system HCI-H 20-CaO-C0 2 -MgO-(Si0 2) at XC02 = 0.01. Saturation
limits: calcite (a), magnesite (b), dolomite (c), brucite (d).
 247
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Phase relations in the system HCl- H 20-CaO-C0 2 - MgO- (Si0 2) at XC02 = 0.05. Saturation
limits: calcite (a), magnesite (b), dolomite (c).
 248
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Phase relations in the system HCl-Hp-CaO-C0 2 -MgO-(Si0 2) at XC02 = 0.10. Saturation

limits: calcite (a), magnesite (b), dolomite (c).
 249
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Phase relations in the system HCl-H 20-CaO-C02 -MgO-(Si0 2) at Xc0 2 = 0.30. Saturation
limits: calcite (a), magnesite (b), dolomite (c).
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Phase relations in the system HCI-HzO-CaO-COz-MgO-(SiO z) at X coz = 0.50. Saturation

limits: calcite (a), magnesite (b), dolomite (c).
 251

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Phase relations in the system HCl- H 20-CaO-C0 2 - MgO- (Si0 2) at XC02 = 0.70. Saturation
limits: calcite (a), magnesite (b), dolomite (c).
 252
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limits: calcite (a), magnesite (b), dolomite (c).
 253

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Phase relations in the system HCI-H 20-CaO-C02 -MgO-(Si02) at XC02 = 0.95. Saturation
limits: calcite (a), magnesite (b), dolomite (c).
 254
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+ -0 - - - ::;:5.121 ~~ ,~O,
« < IFORS +
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~ 7.121 aTz'l E $6.121
S
1 'c Sd 4.0
::: aTZ FOrST
§ 6.1215.121 6.121 7.121 8.121 ":3 5.1213 • 121 4.121 5.121 6.121 8~ 3.1211.121 2.121 4.121
LOG (A-(MG++)!(u(MG++»)(A(H+)**2)) LOG (A(MG++)!(u(MG++»)(A(H+)**2» LOG (A(MG++)!(u(MG++»)(A(H+)**2»
~ 1 2 . 12Ir-~~-..:-..-.::::="""'~---' ;; 6. 0 r-~"---~~'--'::r--1 ;; 2.0
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** MERW

f
~ 1 1 • 121 Wall 1 I MONTI ~5.121 Wall I MQlNTI ~ 1.0
$ :::
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+
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E T
:3 6. 1214 . 121 5.121 6.121 7 • 121 ~ -3.0 -2.0 -1.0 0.0 ~ -8 • 121 -7. 0 -6 • 0 -5 . 0
LOG (A(MG++)!(u(MG++»)(A(H+)**2» LOG (A(MG++)!(u(MG++»)(A(H+)**2» LOG (A(MG++)!(u(MG++) (A(H+)**2))

Phase relations in the system HCl- H20-CaO-C0 2 - MgO- (Si0 2) at XC02 = 0.99. Saturation
limits: calcite (a), magnesite (b), dolomite (c).
 255
,::; 10.0
**
~
«
9.0
,
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::;: 6.0
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CL KYA
~ ~ ~
\
84.0 8~ 4 . 02.0 83.0

IG7
~ 2.0 4.0 6.0 4.0 6.0 ~ 2.0 4.0 6.0
LOG (A(MG++)/(0'(MG++»)(A(H+)**2» LOG {A(MG++)/(O' (MG++» (A(H+)**2» LOG (A(MG++)/(0'(MG++»)(A(H+)**2»

·
p::::il,1 ,
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•• I GROSS

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9.0 '< « 'd I
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- ~ 7.0 CLNZ 14-A ~ 6.0 ANOR 't 14-A CL
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::;: 6.0 f - - - - - - ; \
CL ..9
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+
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I \
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~ ~ ~
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84.0 ~ 4. O2 .L..0-~-....oL.-~---J 83.0
~ 2.0 4.0 6.0 _ 4.0 6.0 ~ 2.0 4.0 6.0
LOG (A(MG++)/(O'(MG++»)(A(H+)**m LOG (A(MG++)/(0'(MG++»)(A(H+)**2» LOG (A(MG++)/(0'(MG++»)(A(H+)**2»

, '::;6.0

·•
~ 9.0 ~8.0 \
•• ••
t3ROS I GROSS I GROSS
~ 8.0 ~7.0 \ cI
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\
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\ \ I
83.0
~ 2.0 4.0 6.0
82.0
~ 1.0 3.0 5.0 § 0·~2.0 0.0 2.0
LOG (A(MG++)/(O'(MG++»)(A(H+)**m LOG (A(MG++)/(0'(MG++»)(A(H+)U2» LOG (A(MG++)/(0'(MG++»)(A(H+)**2»

~ 9.0 ~ 3.0 ;;:;-2.0 \ GROSS

GROSS : : 'd e, I
e,
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LOG (A(MG++J/(O' (MG++»(A(H+)**2» LOG (A(MG++)/(0'(MG++»)(A(H+).*2» LOG (A(MG++)/(0'(MG++J)(A(H+J U 2JJ

Phase relations in the system HCI- H 20 - (AI 20 3) - CaO - CO 2 - MgO - Si02, in equilibrium with
quartz, at XC02 = 0.01. Saturation limits: calcite (a), dolomite (b), talc (c), diopside (d),
tremolite (e), wollastonite (f).
256

*
;::; 10.0 ~ 10. 0r--""T'"--'-~--' ~ 10. 0r'""'.----.--r---~--,
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84.0 6.0 8 4. 0 L--~_--'-'-~_""" 84.0

..J 2.0 4.0 ..J 2.0 4.0 6.0 ..J 2.0 4.0 6.0
LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**2»

*
10.0..------.,...---, 10. 0.---T"""--'-~---' 9. 0

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: GROSS : \ GROSS •* \
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3
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$ $ AND I \ $
§ 4.02 . 0 4.0 6.0
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1·7
LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m

·5
9.0 8.0 ~ 6.0 r---.-\--..----,

*
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8.0 ~ 7.0 e\ cI ~ S.0 \
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::: 7.0 1='''=''''---:-'--; ::: 6.0 ~
+ +

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AND I \
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\ $ $ AND \
I \
..J 2.0 4.0 6.0 § 2.01 • 0 3.0 5.0 § 0 '~2 ....0 - - -........--2-'. 0
LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**2))

~ 9. 0 ~ 3. 0 ~ 1. 0 r-""T'"--'T""---'
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5
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83.0
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LOG (A!MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++J)(A!H+J"2j)

Phase relations in the system HCI-H20-(AI203)-CaO-C02-MgO-Si02, in equilibrium with

quartz, at XC02 = 0.05. Saturation limits: calcite (a), dolomite (b)" talc (c), diopside (d),
tremolite (e), wollastonite (f).
 257

..
;; 10. 0r-------r-~--,
..
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\
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GROSsi
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GROSS: ~ 8.0
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::::: 8.0 ::::: 8.0 f I :::: 7.0
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~ ~ ~ I \
84.0 84.0 83.0
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LOG (A(MG++)f(u(MG++»(A(H+)"m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+J**2»

..
~ 10.0
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85.0 PYROPH \ 85.0 AND 84.0 I' e
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84.0 84.0 83.0
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LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**2» LOG (A(MG++l!(u(MG++»(A(H+)**m

..
~ 9.0
..
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84.0 I f
\ 83.0 AND I f, 81.0 ,-II \ "
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83.0 82.0 00.0
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LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)f(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**2»

*
~ 9.0 ~ 3.0 ~-1.0
: \ I GROSS : \ :
\ I GROSS
f,,~ ~ ~-2.0
<
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\
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::: ~
6.0 ~L!iZ_ J L{ -0 - I
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~ """"""""'----'1 \ ~ + e,
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g- ':11.0
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g . 1.0 3.0 5.0 ...l -6.0 -4.0 -2.0 -9.0 -7.0
LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++J/(u(MU++J)(AUf+J"2)j
Phase relations in the system HCI- H 20 - (AI 20 3) - CaO - CO 2 - MgO - Si02, in equilibrium with
quartz, at XC02 = 0.10. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (f), wollastonite (g).
 258
;:; 10.0 ;; 10. 0r-~~--"'~-...., ;; 10. 0r-......-~.-~-,
** I •• •• \ I GROSS
~ 9.0 GROSS ~ 9.0 ~ 9.0
~ ./ dI
GROSS I
"< 3'::::: 8.0 d -<
;:: 8.0
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gt 7.0
+ I
+
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+
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14-A
CL
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~ 6.0 ~ - 0 - ~-
,I
- ~ 6.0
MARG=I---1"
~6.0
+ + +
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Ed 5.0 Ed 5.0 ~ 5.0
~ I 'c, ~ KYA I ' SILL

84.0 60 84.0
~ 2.0 4.0 . §4.02 . 0 4.0 6.0 ~ 2.0 4.0 6.0
LOG (A(MG++)/(u(MG++»)(A(H+)"m LOG (A(MG++)/(u(MG++»)(A(H+) •• 2» LOG (A(MG++)/(u(MG++»(A(H+)"2»

·~
;; 10.0 ;; I 0 . 0 r-"T"~--'-~-"'" ;; 9. 0 r--;\~--r-----r1

•• •
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+
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~\
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84.0 83.0
§ 4.02 . 0 4.0 6.0 ~ 2.0 4.0 6.0 ~ 2.0 4.0 6.0
LOG (A(MG++)/(u(MG++»)(A(H+)"2) LOG (A(MG++)/(u(MG++»(A(H+)"m LOG (A(MG++)/(u(MG++»(A(H+)"m

;; 9.0
•• ,GROSS
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;; 8.0
••
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\

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;::7.0 ~ 6.0 ¥4.0
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g 6.0 ~N~_ ~ ~';O-
+ , I

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MARG c, ANOR ~
I \ 'e
~ ~ CL
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+
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AND
I CL
I
+
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I \
I \
e,
,, -<
~ I .0 AND
CORD I
\.l!. \
' ,

~ ~
I I \ II \
83.0 82.0 80.0
~ 2.0 4.0 6.0 ~ 1.0 3.0 5.0 ~ -2.0 0.0 2.0
LOG (A(MG++)/(u(MG++»)(A(H+)"m LOG (A(MG++)/(u(MG++»(A(H+)"2» LOG (A(MG++)/(u(MG++»(A(H+)"m

·•
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\
f, ' : / ~-2.0
"<
i
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~ "I
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t-< 0.1.00 " \. TZ- O
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3.0

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t ,
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ANOR Ii 14-A
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~ MARG j I \\ ~ CORD e, +
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Ed 4.0 Ed-2.0 '---...:. \ Ed-6.0 AND
~ AND I \ ~
8-3.0
AND 1 \ ~
8-7.0
83.0
~ 1.0 3.0 5 .0 ~ -6.0 -4.0 -2.0 ~ - I I .0 -9. 0 - 7 .0
LOG (A(MG++)/(u(MG++»)(A(H+)"2» LOG (A(MG++)/(u(MG++»(A(H+)"2» LOG (A(MG++)/(u(MG++»)(A(H+)"2»

Phase relations in the system HCl-H20-(AI203)-CaO-C02-MgO-Si02, in equilibrium with

quartz, at XC02 = 0.30. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (0, wollastonite (g).
 259
~ 10.0 ~ 10. 0r----~--r--.... ~ 10.0r--~-~-r--...,
•• ** •* GROSS
GROSS J \

/ ~ 9.0
~ 9.0 I GROSS ~ 9.0
';( < <
I
:=: 8.0
:i4-
::: 8.0 , l8 . 0 ~'--,,-:-_ _~..,,
+
+
c, CLNZ :::
...
~ 7.0
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~ 7.0
-S
~ 7.0
-S
:;: 6.0 ~ - - ~,I- -0 !6.0 :;:6.0
+ +
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I 1', KYA SILL
~ ~ ~ \
84.0
~ 2.0 4.0 6.0
8~ 4 . 02.0 4.0 6.0
8~ 4 .02.0 4.0 6.0
LOG (A(MG++)/(<T(MG++»(A(H+)**m LOG (A(MG++)/(<T(MG++»(A(H+)**2» LOG (A(MG++)/(<T(MG++»(A(H+)"m

~ 10.0 ~ 10. 0r-----.-~-r--..., ~ 9.0

•• ** •*
GROSS ~
~9.0
, 1/ ~ 9.0 ~ 8.0 'e
1
I

< $ d $ ,

:/
l8.0 'c :::: 8.0 7 . 0 I-----'::>-.......l"'-'r-

~ 7.0
CLNZ' , ~ 7.0
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:;:6.0 14-~ :;:6.0 14-A :;: 5.0
+ j: CL + \
t~L
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I
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<
~ 4.0 SILL \
~ ~ \ \
§ 4.0
2.0 4.0 6.0 § 4.02 . 0 4.0 6.0 83.0
~ 2.0 4.0 6.0
LOG (A(MG++)/(<T(MG++»(A(H+)**m LOG (A(MG++)/(<T(MG++»(A(H+)Um LOG (A(MG++)/(<T(MG++»(A(H+)**m

·$~
~ 6. 0 r---""""\-~""I-GR-O-S-S""
9.0
, GROSS ~,./
~
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S.0 "
e, f \ /
:=: 7.0 '. 'lI4-A ~ 4.0 - -o-,...l
::: _A!:!.O~ ..t. _ + '\ I

t
:: 0C:-
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AND
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\...L!II \\
I
83.0
~ 2.0 4.0 6.0 § 0 '-"2 .L.0- - -0-.-0 .1...--L-":' --'.0
2
LOG (A(MG++)/(<T(MG++»(A(H+)**m LOG (A(MG++)/(<T(MG++»(A(H+)**m

~9.0 ~ 3.0 ~-1.0

•• I GROSS •* I GROSS
•*
~ 8.0 't
\
d
I
~ 2.0 ' d
I
l2.0
<' $ <'
:=: 7.0 :::: 1.0 :=:-3.0
+
+
F=::"':'=:::Y:=j'1 4-A
CL
::: :::
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-S
:;:5.0
+ MARGJ \
-S
-:;: 1.0
j:
t S .0
'e
<
~
~
4.0
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\ ~-2.0
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\
<
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\
§ 3.01 . 0 3.0 S.0 §-3 '-"6 . 0 -4 . 0 -2 . 0 §-7.: 100 .L.0-............. 8~.0.1...---_-6-'. 0
_ ....
LOG (A(MG++)/(<T(MG++»(A(H+)**2» LOG (A(MG++)/(<T(MG++»(A(H+)**2» LOG (A(MG++)/(<T(MG++»)(A(H+)U2»

Phase relations in the system HCI-H20-(AI203)-CaO-C02-MgO-Si02, in equilibrium with

quartz, at XC02 = 0.50. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (f), wollastonite (g), anthophyllite (h).
260

rlf
,
/I
;; 113.13 ;::; 113.13 ;::; 113.13 \
•
**
~ 9.13
GROSS I
b
**
~ 9.13
I' ,\ GROSS: /
*
~ 9.13 GROSS,
«
::: 8.13
C
\ ~
:::: 8.0 C
d, <
;::: 8.13
\
\ f
+
+ "CLNZ I ::: CLNZ' 1/14-A
+
+
~ 7.13 i 14-A ~ 7.13 ~ 7.0 ANOR 'I
b MARG, CL 3 ANOR 'I CL 3 0- - -" --
'¥ 6.13 r- -0 - - , - -- ~s.e
0--
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«+
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~
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, ~ 5.13 SILL
caE!! , CL

I , I
~
~l
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84.13 84.0 84.0
I.e 3.13 5.13 7.13 I.e 3.0 5.13 7.13 I.e 3.0 5.13 7.13

d/
. ...< ~ ~

I
LoG (A (MG++)/(u (MG++»)(A(H+)U2)) LOG (A(MG++)/(u(MG++»)(A(H+)**m LOG (A(MG++)/(u(MG++»)(A(H+)'*2»

;::; 10.0 ;::; 10.13 ;::; 10. er---.----r-~-."

•• p..
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~9.0 c GROSS I ~g.e I ~9.0 e,
$
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b $
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1
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::::8.0 :::: 8.0 ;:::8.0
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o---\( f -
1!14_A \ j14-A +
\
67.0 CL ~ 7.0 ANOR \ I CL ~ 7.0 , 1 CL
~ I1ARG \ 3 ' - - - - ....1 0- - b
1. 0 - -
~6.0
~ KYA
'I
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+
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,
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\ ~ SILL ~ \
\
84.0 84.0 84.0
~ 1.0 3.0 5.0 7.0 ~ 1.0 3.0 5.13 7.0 ~ I.e 3.13 5.0 7.0
LOG (A(MG++)/(u (MG++)) (A(H+)·'m LOG (A(MG++)/(u(MG++»)(A(H+)*'2» LOG (A(MG++)/(u(MG++»)(A(H+)**2»

;::;

*
le.er---~~.-~~, ;::; 8.13 ;::; 7.0
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~7.e ~ e,
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, GROSS I S.0 GRlI!SS I
9.13 , d $
~
:::: 8.0
+
+
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' ~6.e
+ - - ~ -0-
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~ 7.13 \ I / 14-A ~5.e ANOR ) 14-A C ~ 4.13
3 o _A~O~'-.{ /_ :'L 3 3
~ 6.13 ~4.e ~3.e
«+ «+ +
S 5.13 AND
I 'c S 3.13 ~ 2.0 CORD I' ,
~ I ' \ ~ AND ~ AND ----":-1' ,
84.13
..J I.e 3.13 5.13 7.13
82.13
~ 13.13 2.13
.
4.13 6.13
8..J I.e
-3.0 -1.0 I.e 3.0
LOG (A(MG++)/(u(MG++»)(A(H+)"m LOG (A(MG++)/(u(MG++»)(A(H+)**2» LOG (A(MG++)/(u(MG++»)(A(H+)**2»

\ / ~3.e ~ 1.0
GROSS "\ 9 ~* 2.0 GROSS' e' \ *
~-2.0
«
~ 7.0
+
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\ I : : :
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-
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~5.0 ~------;-I~ CL :;:-1 .13 CORD I \ '¥-5 • 0
+ CORD :!: '--'>- :!:
« I I' ~ I ~
S 4.0 '---<>'-1 f, S-2 . 0 AND S-S. 0 AND
« AND
~ I f ~
83 0 \ 8-3 0 8-7.0
~ . 0.0 2.0 4.0 6.0 ..J'-7.0 -5.0 -3.0 -1.0 ..J -12.0 -10.0 -8.13 -S. 0
LOG (A(MG++)/(u(MG++»)(A(H+)**2» LOG (A(MG++)/(u(MG++»)(A(H+)**2» LOG (A(MG++)/(u(MG++)) (A(H+J*'2JJ

Phase relations in the system HCI- H 20- (AI 20 3) -CaO-C02 - MgO-Si0 2, in equilibrium with
quartz, at Xeo = 0.70. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
2
side (e), tremolite (0, wollastonite (g), anthophyllite (h), enstatite (i).
 261
~ 10.0.----------, ~ 10.0.-----------, ~ 10.0 ,
: " GROSS / : GROSS , • I GROSS
~ 9.0 / ~ 9.0 b ~9.0 r--
< , 'fgI /
~ CLNZ1.
< CLNZ / :::: 8.0 Y
I
::: 8.0 ,,~'
~ 8.0 r- MARG1~ +7.0 +7.0 " /-
g 7. 0 ~-.====!.+==i g g ~N£R-O:"~K -
i:::-=-=-=-F--a. - a
~
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a-'. . . . -'-
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--
14-A
~
~ 6.0
14-A
S
~6.0 CORD I
14-A
",CL
CL
~ ,'c CL ~ ~ V ' c,
~ 5.0 KYA ' 5.0 KYA
$ b
~
~ ~ 5.0 SILL } ~
12 4.0 84.0 84.0
~ 3.0 5.0 7.0 ~ 3.0 5.0 7.0 ~ 3.0 5.0 7.0

,,
LOG (A(MO++)/(u(MO++»(A(H+)"2» LOG (A(MO++)/(u(MG++»)(A(H+).*2» LOG (A(MG++)/(u(MG++»(A(H+)**2»

10.0 10.0 10.0

*
~ ~ ~
•• GROSS bI •• GROSS •• GROSS

,
I
f\
~9.0
d
: 7/
~ 9.0
~ t-, CLNZ <
9.0
I < , 9
::::8.0
t 7
::: 8.0
+
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+ ,
X
+ +
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'ANOR 1
g 7.0 g 7.0 a- - ~ L -
~ 0- - ~ -1 - -- S ANOR 14-A

'",, " 'c,

14-A
i e .0
~
14-A ~6.0 CL ~ 6.0 CL
KYA CL +
'c ,
+ CORD I, \ ,
-<
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<
~ 5.0
AND
g 5.0 W
1
\ e,
$ ~ $ SILL
I
§ 4.03 • 0 S.0 7.0 § 4.03 . 0 5.0 7.0 § 4.03 . 0 5.0 7.0
LOG (A(MO++)/(u(MO++»(A(H+)**m LOG (A(MG++)/(u(MG++»)(A(H+)**2» LOG (A(MG++l/(u(MG++»(A(H+)**2»

~ 9.0
, ~ 7.0
~ 10.0..--~-----,

! GROSS I
•• \ "" , 1
d ~ 8.0 ~ 6.0 f,
1 GROSS

L
~ 9.0
~ I < 'f, d
I
< 9
I

::: 7.0 ::: 5.0

+
:::: 8 . 0 , ,
14-A
g+6.0
+
+ ',\ -r - -/-0 -
X, '
6 7. 0 NO~ , , CL g 4.0
~ -0- .... t-/ - ~ ANOR ~ NOR 'I-A C
i 6 .0 ~5.0
+
C
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+ ,
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~ S.0 AND " ~
~
4.0 AND , ~
$
2.0 1
AND CORD'
\
" e,
,
§ 4.03 . 0 5.0 7.0 § 3.02 • 0 4.0 6.0 § 1.00 . 0 2.0 4.0
LOO (A(Mo++)/(ufMO++»(A(H+)**2» LOO (A(MG++)/(u(MG++»(A(H+).*2» LOG (A(MG++)/(u(MG++»(A(H+)**m

d
*
:
~9.0 ~3.0 , ~-1.0 r--~'-1~-;1-~
: GROSS f : 1 GROSS
~ 8.0
~
I
~
2.0 ' ~-2. 0
~ ~- ra-
1
, I
7 •0 ANOR"C,~ ll.0 t NO~'~ /
3 .0
~e.0 - -0-
.><'14-A g0.0 g-4.0 ,,{', 14-A
~ CL ~ ~ - ,CL
is.0 CORD' -:; 1.0 -:;S.0 1 ,
-< I I ' ~ ~ AND' e,
~ 4.0 ~ 8-2.0 ~-6.0 CORD
~ AND ~ ~ "
§ 3.°2 . 0 4.0 6. ° §-3 ·~4 . 0 -2.0 0. ° §-7 ·_°9 . 0 -7.0 -S . 0
LOO (A(MO++)/(u(MO++»(A(H+)"2» LOG (A(MO++)/(u(MO++»(A(H+)**2» LOG (A(MO++)/(u(MG++»)(ACH+)**m

Phase relations in the system HCI- H 20 - (Ah03) - CaO - CO 2 - MgO - Si02, in equilibrium with
quartz, at XC02 = 0.90. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (f), enstatite (g).
 262

· · IGROY · ? GR07
;; 10.0 ;::; 10.0 ;; 10.0
~ GROS~/ •
~ 9.0
-<
~ 9.0
< b ~ 9.0
<
CLNZ: / :::: 8.0 :::: 8.0

1-
:::: 8.0
~NOR
+
+
~ 7.0 1 14-A C
+
+
§ 7.0
I ;, 4-A C +
+
~ 7.0
~OB~~~/_o_
~, +0- - - - 1 0- 14-A
-S -S 'I -S
:j:6.0 ~ , :j:6.0 I' -<>---, :j:6.0
I , CL
+ + , CORD +
I
,
-< KYA 1 C,
, -< 1 , -< c,
Ed 5.0
:5 1
Ed 5.0
:5
KYA
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I aRC
I ,
84.0
~ 4.0
I
6.0
" 8.0
84.0
~ 4.0
I
6.0
--'"
8.0
84.0
~ 4.0 6.0 8.0
LOG (A(MG++)/(u(MG++»)(A(H+)**2» LOG (A(MG++)/(u(MG++»)(A(H+).*m LOG (A(MG++)/(u(MG++»)(A(H+) •• m

·• GROI
;; 10.0 ;::; 10.0 ;::; 10.0
•• GROSS 1 GROSS 1 • I
*
~ ~ 9.0 9
9.0 I
< b ~ 9.0
I
¥-< 8.0 :::: 8.0
/
-<
:::: 8.0
+
§ 7.0
+
+ "
A~R,,"" L
1 +
+ "" I /
-0-
~ 7.0 ~ 7.0 ;:N~"--'X 4-A Cl
-S b -S
:j: 6.0
+
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CL ~6.0
+
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:5 c, :5 :5 CORD ,
§ 4.04 . 0 6.0 8.0
84.0
~ 4.0 6.0 8.0
84.0
..J 4.0 6.0 8.0
LOG (A(MG++)/(u(MG++»)(A(H+)**2» LOG (A(MG++)/(u(MG++» (A(H+).*m LOG (A(MG++)/(u(MG++»)(A(H+)**2»

GROS;
;::; 10. er---~-~-"--'----' ;::; 9.13 ;::; 7.13
•• • ••
~ 9.13
GROSSI
I ~ 8.13 \ GRqSS ~ 6.13
~
¥<+ 8.13 d
<
:::: 7 . 0
"f,
r-......... --->--'
9
---/ -<
:::: 5.0
t ,,' I +
~N~R"-; -~ ~~A
I
+
§ 7.13 -0- § 6.13 0 - -"~- § 4.13
-S t--~t'
CL
-S ANOR ~RDIICL
:j: 6.13 :j: 5.13 f - - - - ,
+ AND +
r--- I "
-< -< AND Ie,
Ed 5.0 r7" Ed 4.13 AND
:5 CORD :5 I '
8 4. 13 '---~--'--"-'-~~--' 8 3. 13 '--_---"-L--.--'------' § 1. 1313 ....e-~'--.l...........
--4.---'
~ 4.13 6.13 8.13 ~ 2.13 4.13 6.0 2.13 4.13
LOG (A(MG++)/(u(MG++»)(A(H+)**m LOG (A(MG++)/(u(MG++»)(A(H+)*·m LOG (A(MG++)/(u(MG++»)(A(H+) •• 2»
4. 0 ;::; I.e
/
~ ,....".--~......,..~-~--,
GROSS I • •*
I ~ 3.0 '+ 1 GROSS
:I: 9
~ 1.13
" I / :5 "
~ 2.0 p-:-,,-\--+---/

~tr~A-C
+ -~ J.. - -0
'++
~- 1.0 ANOR " 14-A § 3.0 "
AN OR "
I
b
~
I, '
~5.e -S " CL
'c , :j: 0.0 , " '+ 1
+
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iJ "
r
Ed 4.13 COR~ , 1 '" AND Ie, Ed AND C6RD
:5 ~ .... CPRD' :5 I

'"
5 . ... 7. 0 8~ 2.0
-4.0 -2. ...
'" \ 0. 0 ~
- 7._09 . ...
'" -7. ...
'" -5. 0
LOG (A(MG++)/(u(MG++»)(A(H+)**m LOG (A(MG++)/(u(MG++»)(A(H+)**m LOG (A(MG++)/(u(MG++»)(A(H+J •• 2Jj

Phase relations in the system HCl-H20-(AI203)-CaO-C02-MgO-Si02, in equilibrium with

quartz, at XC02 = 0.95. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (0, enstatite (g).
 263
;::; 11 . 0.---~---~--" 11.0.----,--------,

*
;::;11.0 N

• I •• I
•• 1
• b bI

r----:-A-I
10.0 GROSS '+
:;
10.0
GROSS/ ~ 10.0 ~ GROSS /
« « 1
::: 9.0 ::: 9.0

a
:::: 9.0
+
t
+
§ 8.0 14-A
§ 8.0 ANOR:
-" ,
7[14-A
CL 8.0 ~~~ -0 -

! --
1 CL 0- 'I 4-A
3 3 3~ 7.0 ~l'-~ORD CL
"""" - -0-
~ 7.0 ,I 7.0 i- CORD ,
+
« I'C C I ' "- +
«
6.0 SILL
,
~ ~ 6.0 KYAI C, ~ 6.0
~
KYAI " , ~
~
8 5. 0 L--..L...-~.....J.........--..J 8~ 5 . 05.0 J 8 5.0 '--~~-~........
~ 5.0 7.0 9.0 7.0 9.0 ~ 5.0 7.0 9.0
LOG (A(MG++)/(<T(MG++»(A(H+)"2)) LOG (A(MG++)/(<T(MG++»)(A(H+)"2» LOG (A(MG++)/(t,.(MG++»)(A(H+)".2»

;::; 11.0 ~ II . 0 . - - - - - - - - - - , ~ II .0.---..,.--------,

••
I
bI : ~II GROSSi
•• GROSS
~ 10.0 GROSSi ~ 10.0 ~ 10.0 I

$ <' $ 9
::::9.0
t
§ 8.0
iAN OR 1
/l14-A
CL I
iti.s.
9 0
.
0 AtlJ~R 1
I~ 14-A
CL
:::: 9.0
+
+
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, I
-0
3 1 - " , + - -0 - - -
3
- ~ I.
~,CORD
-0 --
3 NOR i. CORD I 4-A
KYA'I, !,--OR
,
~7.0 ~7.0 , ~ 7.0 CL
~ 1 + +
«
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1 'c § 6.0 AND ~ 6.0 ILL I
~ ~ ~
85.0
I " 8 5. 0 ~""""""'~-.....J,"-,---' ~ 5. 0 .L-0-"--~--"..........,.......I
~ S.0 7.0 9.0 ~ 5.0 7.0 9.0 _ 5 7.0 9.0
LOG (A(MG++)/(<T(MG++»)(A(H+)"2» LOG (A(MG++)/(<T(MG++»)(A(H+) .... m LOG (A(MG++)/(<T(MG++»)(A(H+)"2»

~ I I . 0r---~-----" ~9.0 ~ 7.0

•• GROSS •• ••
~ 10.0
$ b ~8.0 ~ 6.0
<'
1
$
17 . 0
I
9 .0 ::: 5.0
+
+
u 8.0 ~NOR 1 2S 6.0 r------'I
§ 4.0
~ ",+'-0--- ~ 3
~7.0 'CORD, ~5.0 9 ~3.0
~ AND «+ «+ AND
~
~
6.0 ~ 4.0
~
AND ~ 2.0
~
I "
8 5. 0 '---~~--1....-'>--..J 83.0 81.0 i
~ 5.0 7.0 9.0 ~ 3.0 5.0 7.0 ~ 1.0 3.0 5.0
LOG (A(MG++)/(<T(MG++»)(A(H+) •• m LOG (A(MG++)/(<T(MG++»)(A(H+)".m LOG (A(MG++)/(<T(MG++»)(A(H+)".2»
~ 10.0.---------" ~ 4.0 ~ 0.0 , . - - - - - - - - - - ,
•• GROSS •• GROSS •• GROSS
~9.0 ~ 3.0 ~-1.0
$ $
1
:::: 8.0
$
14-A 2 .0 ::::-2.0
t 7.0 C..h t
~
3
~
3
1.0
I
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3 1
,
, CORD
~6.0 ~0.0
9
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+
« AND «+ +
« AND 9
~5.0 ~-1.0 AND ~-5.0
~ ~ ~
84.0 8-2.0 8-6.0
~ 4.0 6.0 8.0 ~ -3.0 -1 .0 I .0 ~ -8.0 -6.0 -4.0
LOG (A(MG++)/(<T(MG++»)(A(H+)"2)) LOG (A(MG++)/(<T(MG++»)(A(H+) .... 2» LOG (A(MG++)/(<T(MG++»)(A(H+) .... 2»

Phase relations in the system HCI - H 20- (AI 20 3) -CaO-C0 2 - MgO-Si0 2, in equilibrium with
quartz, at XC02 = 0.99. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite CO, enstatite (g).
264
;::; 10. 0r-~---'-"-~-"'71 ~ 10.13 ~ Ie. er---'<~---"----'
i
* •*
~ 9.13
e, I
C
•*
~ 9.13
GROSS

,
9.0 GROSS: I
I
-< , 3:::: 8.13 '
GROOS
<
,10:
C C
~ 8. 0 f--~_--,-I_-, 1 ::: 8.13 I
'd, , +
+ CLNZ' I :I: 1
~
~ 7.0 ' ~ 7.13
CLNZ \1 2 7 . 13
/7-A
2 2 't- 2
~ 6.0
+
'b , ~6.e I'1AK~ i' ,,CL ~6.e
+
~
,
-< -<
25.0 PYROPH I 25.13 KYA
1 , 25.13
:$ I :$ 1 :$
84.0
~ 3.0 5.0 7.0
84.13
~ 2.13 4.13 6.13
34. 132 .Le-~-4"".e.....Ll...:........-6---'. 13

'- 9IGR;
LOG (A(MG++)/(u (MG++»)(A(H+) •• 2» LOG (A(MG++)/(u(MG++»)(A(H+)··2» LOG (A(MG++)/(u(MG++»)(A(H+)"2»

~ 10.13
••
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**
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I
e
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83.13
~ 2.13 4.13 6.0

G7
LOG (A(MG++)/(u(MG++»)(A(H+)··2» LOG (A(MG++)/(u(MG++»)(A(H+) •• 2» LOG (A(MG++)/(u(MG++»)(A(H+)"2»

~ 9.0 ~8.e ~7 .13

• ••
GR~.1
1
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'+
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+
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23.13
I,
AND I COR~' 2
~ I.e

:$ AND I I , \
:$ 1 ~
:$
83.0 82.13 8-1.13
~ 2.0 4.0 6.0 ~ I.e 3.13 5.13 ~ -2.13 13.13 2.13
LOG (A(MG++)/(u(MGH-»)(A(H+)··2» LOG (A(MG++)/(u(MG++»)(A(H+) •• 2» LOG (A(MG++)/(u(MG++»)(A(H+)**2»

·
~ 9.13
• \
\ 1 GROSS
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*
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+ + ANOR ~y7-A
~ 5.13
ANOR ~ CL
a-I.e ~.(" CL ~-5.e CL
~\;j :y""
2 I \ " ~ 1\"
cORd I 'e i~-3.e I [\ +
~-7.e
I \

AND ~
\
\
2
:$
AND ~PRC \ 2
:$
AND SORD
\

"
\ .1 \
8-5.13 8-9.13
3. 13 5. 13 ~ -6 . 13 -4 . 13 -2 . 13 ~ - I I 13 -9. 13 -7 . 13
LOG (A(MG++)/(u(MG++»)(A(H+)··2» LOG (A(MG++)/(u(MG++»)(A(H+)··2» LOG (A(MG++)/(u(MG++»)(A(H+1"2))

Phase relations in the system HCl- H20 - (AI 20 3) - CaO - CO 2 - MgO - Si0 2, in equilibrium with
quartz, at XC02 = 0.01. Metastable 7-A c1inochlore was considered instead of its stable counter-
part, 14-A c1inochlore. Saturation limits: calcite (a), dolomite (b), talc (c), diopside (d), tremol-
ite (e), wollastonite (f).
 265
...
;::; I 0. 0 r--~--'-~-~--"
..
:;:; 10. 0r--....-~-~-r1
GROSS
..
:;:; 10. 0..--.,.....--~-~....,...,

~ 9.0 GROSS ~ 9.0 , ~ 9.0 I GROSS

I 1
-< C $ C $ \
e 1
+ \
;:: 8.0 ;:: 8.0 J
;:: 8.0
+
+
~ 7.0
+
~ 7.0
J---o.",-'--./7-A CL
~7.0 - -
1
- --; ~A-~~
-0 - -
S S
::;: 6.0
+
f=1=-~""""'~
'1 , 7-A
-0-
CL
::;: 6.0
+
!6.0 NO~,j
-<
~ 5.0
$
PYROPH 1 'b
1 ,
-<
~ 5.0
$
KYA
, ~ 5.0
$
1
ILL 1
CORD
'd
I
84.0 ' 84.0 84.0 '
~ 3.0 5.0 7.0 ~ 3.0 5.0 7.0 ~ 3.0 5.0 7.0
LOG (A(MG++)/(u(MG++»)(A(H+)"2)) LOG (A (MG++)/(u (MG++»)(A(H+)**2» LOG (A(MG++)/(u(MG++»)(A(H+)*.2»

... ..
;::; 10. 0r--~-r~-~"""""71 :;:; 1121. 0r--"'--~-~--r-1 :;:;9.0
: GROSS I GROSS
~9.0 ~9.0 ~ GROSS ~8.0 C
I

-< $ \ $ J
;::8.0 e I
+
+ CL~,
+
;:: 8.0
\ ~ 7.0
+
~7.0 ~_..,......-:'::-! ~ 7. 0 t-nmr-,_--~ - 0 __ ~6.0
S
::;:6.0 ::;:6.0
S NOR \-
1-..1 j 7-A CL
S
::;:5.0
+
+ + /1 'd -<
-< iS 50 1,-0,:-..
YROPH 1 ~ 4.0
'<'
',-
~5.0
$ 1 ANDI CORl), $

5.0 7.0
~
84.0
3.121 5.0 7.0
§ 3. 03 .L-r>-~-'-~-~.>......J
~ '" 5.0 7.0
LOG (A(MG++)/(u(MG++»)(A(H+)"m LOG (A(MG++)/(u(MG++»)(A(H+)**2» LOG (A(MG++)/(u(MG++»)(A(H+)*.2»

...
:;:; 9.0
GR~./
..
:;:; 8.0
\ 1 GROSS \, GROSS
, , e\
, 1
PREH~~L,
,
~ 8.0 ~ 7.0 e\ cI I
CI

I
'< I
$
:=: CLNZ \ I ~~ -f-
----'[1 0 - -
7.0 ;:: 6.0
+
+ + ,'I
1«
ANOR ,

n-
~ 6.0 ~ 5.0 "'\
IJ'. 7-A CL ANOR '\ 7-A
1
S A CL
S NOR CL
f------:-;Y I'd
\1 '
::;: 5.0 MARB ::;: 4.0
+
-<
~ 4.0 AND
cO~DI~\
'e
+
-<
~ 3.0 AND
1
1
,C"I'
CORD- ,
1-----. 1
AND
\

ORD
d,
$
83.0
1 il , $
82.0 80.0
~ 2.0 4.0 6.0 ~ 1.0 3.0 5.0 ~ -2.0 0.0 2.0
LOG (A(MG++)/(u(MG++»)(A(H+)**2» LOG (A(MG++)/(u (MG++»)(A(H+)**2» LOG (A(MG++)/(u(MG++»)(A(H+)*.2»

~9.0 ~3.0 \ ~-1.0 \

.. \ IGROSS ~ \ ~"GROS~iS .. \ 1
~ 8.0 ~ 2 .0 GROS~!S
;-f
e\ Cl , e, l2 . 0 e, I
'< ,C
1 t ,·0 1
~ $ '-, -<,
7 .0 3 .0 \-~ tf
X 7C-t
PREH:.:..,..yl, ,\ 1 ' ........

r:
~6.0 ~1' ~0.0 ~-4.0 '~I /7
v
\." 7-A
A~O; 7~A

i:: AND CD~ \d" i:::

S - -) s ANOR: CL S ANOR

AND :\;:0 AND I~o~ "

§ 3.0, .0 3.0 5.0 §-3·~6.0 -4.0 -2.0 §-7_. ,0, . 0 -9.0 -7.0
LOG (A(MG++)/(u(MG++»)(A(H+)"2)) LOG (A(MG++)/(u(MG++»)(A(H+)"m LOG (A(MG++)/«,.(MG++»(A(H+)"2»

Phase relations in the system HCl- H 20 - (AI 20 3) - CaO - CO 2 - MgO - Si0 2, in equilibrium with
quartz, at XC02 = 0.05. Metastable 7-A c1inochlore was considered instead of its stable counter-
part, 14-A c1inochlore. Saturation limits: calcite (a), dolomite (b), talc (c), diopside (d), tremol-
ite (e), wollastonite (0.
266
.. .. .
/
;; 10.0 ;:;; 1121. 12Ir-~~-'--~T1 ;:;; 1121. 12Ir-....-,r-o-~.---~~"

~ 9.0 f' , GROSS I b ~ 9.121

,'!..
:I: 9.121 If I
J
-< C 3
GROSS\ 3 'e I GROSS
=: I
f\ '\!J
+
+
8.0
CLNt- \
I
~8.121 I t· 8121
CLNZ. \ ~
~ 7.0 I !7-A
CL
!::? 7.121 CLNZ \ I ~7.121 _L' ~o-
b MARG I S - - -.,.... -0- S \J
~6.0 r- - -0 ANOR h
,
~6.121 ~ 6. 121 -A CL
+ \1 +
-< -< CL ~
!::? 5.0 PYROPH 1\ !::? 5.121 KYA !::? 5.121 CORd,
$ I "-
\
$ $ SILL W \
84.0 84.121 84.121
... t.0 3.0 5.0 7.121 ... 1.121 3.121 5.121 7.121 ... 1.121 3.121 5.121 7.121
LOG (A(MG++)/(u(MG++»(A(H+)**2» LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m

;:;; 1121. 121~~~----.-~"""

d ...
;:;; 1121. 12Ir-~~-r--~T1
..
;:;;9.121

, ,If
: \ GROSS ,
~9.121, I ~ 9.121 \ ~ 8.121
\

=:-< 8. 121 C, 3;:::: 8.121 \

, \d "<
!
~-___--'-~ ::: 7.121 ~~~--!-9-
:j: :j: +
~I't-
,\ I
CLNZ , 7-A +
~ 7.121 1--_ _--''--'1---< CL ~ 7.121 I ~ 6.121 ANOR 7-A CL
S S - - -~-/O-
MARG O - ~'l- ~ 6.121 ANOR A\I7-A CL
S
~6.121 ~5.121
+ 1',,\
+
~
!::? 5.121 PYROPH : \ ~ 5.121 CORDI ~ 4.121
$ \ $ AND Ll..!. $
84.121 84.121 83.121
... 1.121 3.121 5.121 7.121 ... 1.121 3.121 5.121 7.121 ... 1.121 3.121 5.121 7.121
LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m

..
;:;; 9.121 ~ 8.121
. ,
..
;:;; 6.121 \
, I GROSS
\' I GR~,1 GROSS
d
/
~ 8.0 I ~ 7.121 'f ~ 5.121 f,
~LL
"< ~ "< "" I

t
\

\ - [9
::: 7.121 f':LNZ \ \
I=~~~=:-'~I=-'-t:C - 0 -
I ./ ::: 4.121
:j:
ANOR- - \- -0 f 6 • 121
~ 5.121 \1' 7-A CL
+
+ "
't-I
k<l
~ 6.121 ~ 3.121 ANOR 7-A
MARG 'v' 7-A S ANOR \ ,
t 5.121
S
I CL ~4.121
+
IYI'
-1\1 'e
S
~2.121
+ I \
CL
e,
CORDI \ -<
~ 4.121 AND ~ f, ~ 3 • 121 AND I 7"l "" !::? 1.121 AND I '
$ I -I , $ I ,CORD $ RORO
83.121 8 2.121 8121.121
... 2.121 4.121 6.121 ..J t .121 3.121 5.121 ... -2.121 121.121 2.121
LOG (A (MG++ )/(00 (MG++) )(A(H+) **2» LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m

~9.121 ~3.121

1-
, V1.121
.. \ I GROSS .. \ GROSS ..
'+

t.·
f f
'd ~
d ~

i i
:I: 8.121 :I: 2.121" , :1:-2 • 121
7.0 PREH.y , I .0 '~,: ( 0

~ 6.121 _Ltg:d-.S 1- 0 1' _ ~ 121.121 ANOR \.~ 7-A ~-4.121

~5.121 ~-1.121 )7" ~5.121
1\ ",
ANOR " 7-A CL

~ 4.121 AND : ~k~~D ~-2.121 AND ~-6.121 AND

8 '"' 8 CORD-<- j\ 8- \
... 3.1211 .121 3.121 5.121 ... -3._1216 • 121 -4.121 -2.121 ... 7_. 11211 • 121 -9.121 -7.121
LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++)J(A(H+)"2)j
Phase relations in the system HCl- H 20 - (Al 20 3) - CaO - CO 2 - MgO - Si0 2, in equilibrium with
quartz, at Xeo = 0.10. Metastable 7-A clinochlore was considered instead of its stable counter-
2
part, 14-A clinochlore. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (0, wollastonite (g).
 267
~ 10.0 ~10.0r---~--~----~ ~10.0r-~--~~---~
•• • ••

7/
• I
~9.0 GROSS:
~ 9.0 GROSS (I' *9.0
GROSS
$ b $ ~
;::8.0 l8.0
l8 .0 ,,=-:-:-=-,.....-__....1_ _
:t: LNZ
I
g7.0 I ~7.0 ~ 7 . 0 F==d;;±==f=:d
.g M4RG I I .g .g
~6.0
~
-~--
,I
-a-
1< 6.0 1< 6 .0

~5.0 PVROPH l'c I7-A CL

~5.0 ~5.0
~ I ' ~ ~ ILL
I'
84.0
~ 3.0 5.0 7.0
84.0
~ 2.0 4.0 6.0
§ 4. O2 .1-0-~-""""'--'--J,"-----I
4.0 6.0
LOG (A(MG++)/(u (MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**2»

~10.0r---~~--~--~ ~10.0r--\~--~~--~ ~ 9.0 ...----",...---.-------.

•• • ••
~9.0
" , 'f,
~9.0 GROSS : ' I GROSS *8.0
a
$;:: 8.0
:t:
is 7 . 0
1-----'----;"

1--........_-'-
~
l8.0

~7.0
\,

i
al'
.I ' /
~
;::7.0
:t:
g6.0 ANOR
- -at-
--....~
\: 7-A
:i .g ~__-I'./<
16 . 0 ~6.0 - mOR -'~ ~A 1
CL
f---~---i-._A CL
a/ 5.0
~ 1 CL
CORDII', 'e,
g5.0 ~5.0 COR~ , ~4.0 ~
~ 'C , ~ AND 4>j ~
ILL
I ,
§ 4.03 . 0 5.0 7.0 84.0
~ 2.0 4.0 6.0
83.0
~ 2.0 4.0 6.0
LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m

8 .0 6.0
,GROSS
~9.0 ~ r.,--~-:-----~-,-, ~
••
/
I
•
'f ••
*8.0 PRliHN1 d ~ 7 '" .!, GROSS
~ 5.0 'e , 'f\ IGROSS

"I
';'''' \ U
';( I
~ <
+_
LNZ , I
~ 6.0 _*-1_ ::: 4. 0 b:-=".--\,.---,--.'

i:::
l7.0
~~R_a~i.. :t:
~6.0
.g
~5.0
,+
MARG

I
/
'c
I 7-~' +
NOR '1' J~A
I, e
CL
is 3.0
:i
~2.0
+
< AND CL < ' <
~ 4.0 ~ 3.0 1.0 AND
~ CORD~ ~
AND I
I
CORD'
~
~
~
I
83.0
~ 2.0 4.0
I
6.0
82.0
~ 1.0 3.0
\
5.0
§ 0 '!'2 .L0-~-..L.:....~L----I
0.0 2.0
LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**2» LOG (A(MG++)/(u(MG++»)(A(H+)**2»

·•
~8.0

~ 7. 0
.•
~3.0

~ 2. 0
.• ,
;::; 1.0

~-2. 0
't, d
I GROSS

$ $ $ I
I
l6.0 ll.0 [3.0
~ 5. 0 ~ 0. 0 ~-4. 0
.g .g .g
14 . 0 tl.0 ~5.0
< < ~
~ 3.0 ~2.0 ~-6.0 AND 'e,
§ 2.01 . 0 3.0 5.0 §-3·!'6.0 -4.0 -2.0 §-7_·100 . 0 -8.0 -~.0
LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++J/(u(MG++J)(A(H+J**2»
Phase relations in the system HCI-H20-(AI203)-CaO-C02-MgO-Si02, in equilibrium with
quartz, at XC02 = 0.30. Metastable 7-A c1inochlore was considered instead of its stable counter-
part, 14-A clinochlore. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (f), wollastonite (g).
268

/
;;; 10.0 ;;; 10. 0r-~--'--~--"" ;;; 10. 0r--~.....,.----..,
•• •• ••
~ 9.0 GROSS: ~ 9.0 GROSSI ~9.0
:;;: b 3 3:::: 8.0
d
/
:::: 8.0 ~ 8.0
+ t
7
+ CLNZ I
~ 7.0 I 8 7 •0 Cl"NZ ~ 7.0
.s -t:1ARG I I .s .s
~6.0 - ~::':-I- -0- ~6.0 t-==-~-"-ol.'- 0 - - ~6.0
+ I, 7-A CL +
I7-A CL ~ I <:
~ 5.0 YROPH I'C
, 85.0 85.0
~ I .:s KYA IC R~ C ~ SILL
84.0 84.0 84.0
~ 3.0 5.0 7.0 ~ 3.0 5.0 7.0 ~ 3.0 5.0 7.0
Loo (A(MG++)/(u(MG++»)(A(H+)**m Loo (A(MG++)/(u(MG++»)(A(H+)**2» LOG (A(MG++)/(u(MG++»)(A(H+)*.m
;;; 10.0r-~~~--~--, ;;;10.0r-~~-------~ ;;; 9. 0 r-~"'7I-----T-T---'
•• t::E 9 . 0\, : I GROSS
~ 9.0 GROSS I I GROSS ~ 'f\ d
\,. aI
1 ~8.0
d

F: :;{;t/~:::
:;;: ~ f .:s
.:s 8 0 I
:::: 8.0
1 . CL"Zt~
1__a-
t
~ 7.0
.s ~ 7. 0 ~N~ \ I _
1 6 .0 ~6.0 i /17-A CL ~5.0
+ I \
\,
e
~5.0 KYA I
'C,
§5.0 AND I \ CORD
<:
84.0
SILL
I
'
CORD'
~ I ~ I ..;.,.....J .:s I ~ ,
84.0 §4.03 . 0 5.0 7.0 § 3. 03 .'-0----.....0'---5.....0-----7....... 0
~ 3.0 5.0 7.0
Loo (A(MG++)/(u(MG++»)(A(H+)Um LOG (A(MG++)/(u(MG++»)(A(H+)UZ» Loo (A(MG++)/(u(MG++»)(A(H+)Um

;;; 10.0 ~ 8.0 \ ;;; 6.0

•• I •
'+ 'f I GROSS
••
~ 9.0 :t 7.0 ~ 5.0
:;;: ,GROSS d 3 ,\ (j :;;:
:::: 8.0
t
, I
/ ~6.0 '\ :::: 4.0
+
~ 7.0
.s
CLNZ'
/7-"
_A~O~O::- -t. _ ~L
, I
+

.s~ 5.0
- -
ANOR
~t-
l' >tJ
'..r' -A
- -0-

CL
+
~ 3.0
.s
~6.0 ~ 4.0 \ ' ~2.0
+ MAk>C
-' I'C ~ I \ 'e, +
<: ,, <:
85.0
~ AND
CO~DI
~
83.0
~ AND
I
I ~
CORD 81.0
.:s
84.0
~ 2.0 4.0 6.0
82.0
~ 1.0 3.0 5.0
8~ 0.0
-1.0 1.0 3.0
Loo (A(MG++)/(u(MG++»)(A(H+)··m LOG (A(MG++)/(u(MG++»)(A(H+)"m LOG (A(MG++)/(u(MG++»)(A(H+)U2»
;;; 9.0 ;;;3.0 ~I . 0 rr-~~~------,
•• \
•• •• GROSS
~ 8.0
\ I GROSS
~2.0 't I GROSS
~-2.0
't d
.1
\
-< 3 :;;:
:::: 7.0 I CLNZ] \ I
~ 1.0 ¥-3.0

t -/:- -
~-,
::':-~11-- g-
+ - - -; -0-
'1,r ,
+ + +
~ 6.0
.s _A~O~O - Q0.0
.s
ANOR ~-4.0
.s NOR tl -A C
~ 5.0
\/ 7-A
CL }1.0 , -A CL
:; 5.0
+
MARG~ I(~ + I '
-< D <:
O~ ~ IC~RD 'e
84.0 8·2.0 8-6.0 AND
~ AND I \ .:s AND .:s I \ '
83.0
1.0 3.0 5.0 §.3 ._\ .L..0-.o.-J_'-3~.0--'--~-_--JI. 0 8-7.0
~ ~ -I 0 . 0 -8 . 0 -6 . 0
Loo (A(MG++)/(u(MG++»)(A(H+)··m LOG (A(MG++)/(u(MG++»)(A(H+).*m LOG (A(MG++)/(u(MG++»)(A(H+)··m

Phase relations in the system HCl- H 20 - (AI 20 3) - CaO - CO 2 - MgO - Si02, in equilibrium with
quartz, at XC02 = 0.50. Metastable 7-A c1inochlore was considered instead of its stable counter-
part, 14-A c1inochlore. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (n, wollastonite (g), anthophyllite (h).
 269
;:; 1121.121
** 1
GROS1
~ 1121.12Ir-~-~----,
•• 1
~ 9.121
,
~ 1121.l2Irr~--~-----,

** GROSS
~9.121 I * 9.121 GROSS I I
b ,:$ dI '<
,d
7
-(
I
~8.121 ;::: 8.121 ~8.121
+
+
+
~ 7.121
CLNZ 1
L t
!,i 7.121
+
~ 7.121
..l? M)\RG I ..l? ..l?
~6.121 -~---
,I -0- ~6.121 ~6.121
+ +
l'c , -A CL ~ -(

,
-(
!,i 5.121 KYA !,i 5.121 !,i 5.121
.:s 1 .:s KYA .:s
84.121 84.121 84.121
~ 3.121 5.121 7.121 ~ 3.121 5.121 7.121 ~ 3.121 5.121 7.121
LOG (A(MG++)/(<T(MG++»(A(H+)**2» LOG (A(MG++)/(<T(MO++»(A(H+)**2)) LOG (A(MO++)/(<T(MO++»)(A(H+)**2»

;:; 1121.121 ~1121.12Ir-~-~-~-, ~ 9.121

•• GR~/
/
** **
* 9.121
GROSS 1
*9.121 GROSS I ~ 8.121
,
f\ 1
I
dI
~

j{\r
'<
d - ~\-I- ~
-( -(
;:: 8.121 ;:: 8.121 ~ 7.121
:1:
~ 7.121
,
~ CLNZ 1 /7-A
CL
+
+
~ 7.121
+
+
~ 6.121 ~NOR
-0-

' -A CL
..L ..l?
,
..l? MARG::.. -0- ..l?
~6.121
'-I.. !6.121 -A CL ~5.121
+
, 'e ,
~ I'
'2bRD -(
!,i 5.121 KYA ~5.121 'c, !,i 4.121 , CORD'
, .:s SILL
c,
.:s
84.121
I .:s
84.121
AND
83.121
T
~ 3.121 5.121 7.121 ~ 3.121 5.121 7.121 ~ 3.121 5.121 7.121
LOG (A(MO++)/(<T(MO++»(A(H+)**2)) LOG (A(MO++)!(<T(MG++»(A(H+)**Z» LOG (A(MO++)!(<T(MO++»)(A(H+)**2»

~ 1121.12Ir-~........,,.......-~-... ~8.121 ~6.121

•• ** **
, 1 GROSS
~ 9.121 *7.121 ~ 5.121 \ h
$ -( '< +- r -0
;::: 8.121 ;::6.121 ~ 4.121 - ->,.

:1: :1: +
+ ANOR " '>J
~ 7.121
..l?
~5.121
..l?
~3.121
b , 7-A
CL
~6.121 ~4.121 ~2.121 1,
,
+ + + e,
:CO~D
,
-( -(
!,i 5.121 ~3.121 AND !,i 1.121 AND
.:s 'c , .:s .:s I
84.121 82.121 8121.121
~ 3.121 5.121 7.121 ~ 1.121 3.121 5.121 ~ -1.121 1.121 3.121
LOG (A(MO++)!(<T(MO++»(A(H+)**2)) LOG (A(MO++)/(<T(MG++»(A(H+)**2» LOG (A(MG++)/(<T(MG++»)(A(H+)**2Jj

,\. 9 GR0j'
;:; 9.121 ~3.121 ~-1 .121
** ** ** GROSS
~ 8.121 *2.0 e+-2 . 121 f \
i
I

-( -( -(
;: 7.121
+
;:: 1.121
- -'""\ Ti:j- - ::: 3.121
+
- " -g -/-
+
~ 6.121
:1:
~121.121 ANOR '1' 7-A
+
~-4.121 NOR ' \ : /7-A
b
~5.121
..l?
~-1 .121 I'
, CL
'e
..l?
T5.121
A'e
I' ,
CL
+ + +
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Phase relations in the system HCl-HzO-(Alz03)-CaO-COz-MgO-SiOz, in equilibrium with

quartz, at XC02 = 0.70. Metastable 7-A c1inochlore was considered instead of its stable counter-
part, 14-A c1inochlore. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (n, wollastonite (g), anthophyllite (h), enstatite (i).
 270
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Phase relations in the system HCI-H20-(AI203)-CaO-C02-MgO-Si02, in equilibrium with

quartz, at XC02 = 0.90. Metastable 7-A clinochlore was considered instead of its stable counter-
part, 14-A clinochlore. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (f), enstatite (g).
 271
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Phase relations in the system HCl- H 20- (A1 20 3) -CaO-C0 2 - MgO-Si0 2, in equilibrium with
quartz, at XC02 = 0.95. Metastable 7-A clinochlore was considered instead of its stable counter-
part, 14-A clinochlore. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (f), enstatite (g).
 272

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Phase relations in the system HCI-H20-(Ah03)-CaO-C02-MgO-Si02, in equilibrium with

quartz, at XC02 = 0,99. Metastable 7-A clinochlore was considered instead of its stable counter-
part, 14-A clinochlore. Saturation limits: calcite (a), magnesite (b), dolomite (c), talc (d), diop-
side (e), tremolite (f), enstatite (g).
 I
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Phase relations in the system HCl- H20- (AI 20 3) -CaO-C02 - K20- MgO-Si0 2, in equilibri-
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phlogopite (c), diopside (d), tremolite (e), wollastonite CO.
 274

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Phase relations in the system HCI-H20-(AI203)-CaO-C02-K20-MgO-Si02, in equilibri-

um with quartz and K-feldspar, at XC02 = 0.05. Saturation limits: calcite (a), dolomite (b),
phlogopite (c), diopside (d), tremolite (e), wollastonite (f).
 275

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Phase relations in the system HCl- H20- (Ah03) -CaO-C02 - K20- MgO-Si0 2, in equilibri-
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 276
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Phase relations in the system HCl- H20 - (Al 20 3) - CaO - CO 2 - K20 - MgO - Si02, in equilibri-
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dolomite (c), phlogopite (d), diopside (e), tremolite (f), wollastonite (g).
 L , d/
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Phase relations in the system HCl- H 20- (A1 20 3) -CaO-C0 2 - K20- MgO-Si0 2, in equilibri-
um with quartz and K-feldspar, at Xco2 = 0.50. Saturation limits: calcite (a), magnesite (b),
dolomite (c), phlogopite (d), diopside (e), tremolite (0, wollastonite (g).
278

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Phase relations in the system HCl-H20-(Ab03)-CaO-C02-K20-MgO-Si02, in equilibri-

um with quartz and K-feldspar, at X C02 = 0.70. Saturation limits: calcite (a), magnesite (b),
dolomite (c), phlogopite (d), diopside (e), tremolite (0, wollastonite (g), enstatite (h).
 279

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LOG (A(MG++)!(u(MG++»(A(H+)**2» LOG (A(MG++)!(u(MG++»)(A(H+)·*2» LOG (A(MG++)!(u(MG++»)(A(H+) •• 2»

Phase relations in the system HCl- H 20- (AI 20 3) -CaO-C0 2 - K20- MgO-Si0 2 , in equilibri-
um with quartz and K-feldspar, at XC02 = 0.90. Saturation limits: calcite (a), magnesite (b),
dolomite (c), phlogopite (d), diopside (e), tremolite (f), enstatite (g).
280

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Phase relations in the system HCl-H20-(Ah03)-CaO-COz-K20-MgO-SiOz, in equilibri-

um with quartz and K-feldspar, at XC02 = 0.95. Saturation limits: calcite (a), magnesite (b),
dolomite (c), phlogopite (d), diopside (e), tremolite (0, enstatite (g).
 281
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LOG (AIMG++J/lu(MG++»(A(H+)**m LOO (A(MG++)/(u(MG++»)(A(H+)**2)j LOG (A(MG++)/(u(MG++J)(A(H+J**m

Phase relations in the system HCI-H20-(AI203)-CaO-C02-K20-MgO-Si02, in equilibri-

um with quartz and K-feldspar, at XC02 = 0.99. Saturation limits: calcite (a), magnesite (b),
dolomite (c), phlogopite (d), diopside (e), tremolite (f), enstatite (g).
 282

I
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Phase relations in the system HCl- H 20 - (AI 20 3) - CaO - CO 2 - K20 - MgO - Si0 2 , in equilibri-
um with quartz and K-feldspar, at XC02 = 0.01. Metastable 7-A clinochlore was considered in-
stead of its stable counterpart, 14-A clinochlore. Saturation limits: calcite (a), dolomite (b),
phlogopite (c), diopside (d), tremolite (e), wollastonite (0.
 283

/
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Phase relations in the system HCl-H20-(Ah03)-CaO-C02-K20-MgO-Si02, in equilibri-
um with quartz and K-feldspar, at XC02 = 0.05. Metastable 7-A clinochlore was considered in-
stead of its stable counterpart, 14-A clinochlore. Saturation limits: calcite (a), dolomite (b),
phlogopite (c), diopside (d), tremolite (e), wollastonite (f).
284

,/
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dolomite (c), phlogopite (d), diopside (e), tremolite wollastonite (g). en,
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dolomite (c), phlogopite (d), diopside (e), tremolite ([), wollastonite (g).
 286

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 287
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dolomite (c), phlogopite (d), diopside (e), tremolite (0, wollastonite (g), enstatite (h).
 288
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--\V
~ 9.0 ~ 8.0 ~ 6.0
e,
<
3'
;:::: 8.0 , 7-A C
<
;::: 7.0
+ , \ I
:::: 5.0
+ -0
~
S17.0
+
g 6.0 -0- ~C --
+
g 4.0 7-A
ANOR'1
.s .s ANOR
,
7-A
CL
b CL
~
~6.0 ~ 5.0
CORD 11\ \
3.0
II \ ,
,,
CORD

1:
+
~ ~ '-1>'-, 't < '-+-1
S15.0
$
S1 4.0
$ AND I \ \ , S1 2.0
$
8
AND \

'1
\.
84.0 83.0 1.0
3.0 5.0 7.0 9.0 1.0 3.0 5.0 7.0 -1.01.03.05.0

Iv
..J ..J ..J
LOG (A(MG++)!(u(MG++i)(A(H+)"m LOG (A(MG++l!«T(MG++»)(A(H+)**2» LOG (A(MG++)/(u(MG++»)(A(H+)"m

~9.0
: IGROSS ~4.0
: " \ I GROSS ;:;0.0
*
~, ~ I' I I !!.. I
:t 8 .0 I :t 3 .0 , f 9 :t- 1.0 , 9
3' 3' ' \ 0 3' , I
;:::: 7.0 ;:::: 2.0 \. ;::::-2.0 -'<-1'-
~ 0 - -, \-t - - -
u 6.0 g:1: 1.0 \ 7-A
:1:
g-3.0 , I
7-A
~
~ 5.0
, .s
~ 0.0
ANOR
1 'e
CL .s
Y4 .0
ANOR " ORD CL

+ + CORD 1\ , +
g 4.0 AND g-I.0 II \ g-5.0
$ $ AND II \ ' $ AND I
8 3.0 8 - 2 . 0 · \. 8-6. 0 L-~..!....L~..........J...----.J
..J 2.0 4.0 6.0 8.0 ..J -5.0 -3.0 -1.0 1.0 ..J -10.0 -8.0 -6.0 -4.0
LOG (A(MG++)!(u(MG++»)(A(H+)"2)j LOG (A(MG++)!(u(MG++»)(A(H+)**m LOG (A(MG++)!(u(MG++»)(A(H+)**2»
Phase relations in the system HCl-H20-(AI203)-CaO-C02-K20-MgO-Si02, in equilibri-
um with quartz and K-feldspar, at XC02 = 0.95. Metastable 7-A clinochlore was considered in-
stead of its stable counterpart, 14-A clinochlore. Saturation limits: calcite (a), magnesite (b),
dolomite (c), phlogopite (d), diopside (e), tremolite (n, enstatite (g).
290
e ;:; 11.13

:GROSs(
Nil • er-~~~~~!~,..., ,,

••
~ GROSsi
: I GROSS
N •
•*
~ 113.0 b ~ 113.0 ~ 113.0
«
¥+ 9.0
T
rC~L"",N:-:::Z...Ll_--,,/ 7-A
3:
;::: 9.13 --- 7-A
<
;:: 9.13
I'
, g
'
. / 7-A
:): +
~ 8.13
,ANn!;
, I
CL
~ 8.0
A~OR: / CL +
~ 8.0 ~N~" I~ _ ~L_
i_ .s -- .s
~
b
7.13
_ ~
,I CPR[
-0
:;: 7.0
+
\;
t CORD
-0
:;:7.0
+
I ,,
I CORD

j( 1\ < I \ I
~ 6.13 KYA I 'c ~ 6.13 KYA I 'c,
<
~ 6.13
SILL C,,
CS CS CS
85.13 I. ' 85.0 1 85.0
...J 4.13 6.0 8.0 10.0 ...J 4.0 6.0 8.0 10.0 ...J 4.0 6.0 8.13 10.0
LOG (A(MG++)/(u(MG++»)(A(H+)*.m LOG (A(MG++)/(u(MG++»(A(H+)·*m LOG (A(MG++)/(u(MG++» (A(H+).*2»

;:; 11.13 ;:; 11 •.er-~~-~~~-'-' ~ 1 1. er-~---"'-~~~-r"1

•• *
~ 113.13 bGROSsi :
$ 10 • 0
I
bGROSS *
~ 113.0
I
I
< CS < g

/
I
;:: 9.13 7-A
~ 7-A ;::9.13 , ~ 7-A
, a'8.e
+ 'ANORI ;:::9.0
:): 'I
AN~~:
+ CL CL CL
I
~ 8.13
.s - - '--1- -0- - -
_ -0 ~ 8. 13 ANOR\....-{ -C~RaD -
:;: 7.13 'I ORD
.s:;: 7.0 CORD
:;: 7.0 ,
+ I' + , +

,
< < C, <
~
CS
6.13 KYA
I , ~
CS
6.0 AND u 6.0
3: SILL
1 C"
85.0 85.0 85.0
...J 4.13 6.0 8.0 10.13 ...J 4.0 6.0 8.0 113.0 ...J 4.13 6.13 8.0 10.0
LOG (A(MG++)/(u(MG++»)(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**m LOG (A(MG++)/(u(MG++»(A(H+)**2»

:;; 11.0 :;; 9.0 ;:; 8.0

~ GRDs1
•• •* *
~ 10.0 ~ 8.0 $* 7.0 , 1
g
< 3: <
;:: 9.13
+
+ , I(
• 7-A
CL
t 7.0 ;:: 6.13
+
+
AN{JR I
~ 8.0 ~ 6.0 ~ 5.0
.s - -'--I - -0 .s .s
:;: 7.13
+
,,
CORD :;: 5.0
+
<
:;: 4.13
«+
,
<
~
CS
6.13 AND C, ~
CS
4.0 AND ~
CS
3.0 AND
\
85.0 83.0 82.0
...J 4.0 6.0 8.0 10.0 ...J 2.0 4.0 6.0 8.0 ...J 0.0 2.0 4.0 6.0
LOG (A(MG++)/(u(MG++»)(A(H+)*·m LOG (A(MG++)/(u(MG++»)(A(H+)**2» LOG (A(MG++l/(u(MG++))(A(H+l.*2))

·•
:;; 10.0 :;; 5.0 :;; 1.0

"g
*
~ I
*
~ GROSS
~ 9.0 IGROS.i
d ,; 4.0 g :± 0.0 g
I

« CS <
~8.0 ANOR\
';L' ::;::3.0 ~-1.0 ' ~I
~ 7. Ii)
--""", -0
CORD
--
~ 2 .e ~-2 . 13 A:~-' I - 0 C~
~ 6. 13
j(
I' , :;: 1 .13
j( 'e
:;:-3.13
j(
\ CORD

~ 5.13
I C , ~ 0.0 AND' ~-4.e
I,
e,
AND
~ I CS, cs
1 1'"
8 4 13 8-1 . 0 8-5 • 13 '
...J • 3.13 5.13 7.13 9.0 ...J -4.13 -2.13 0.13 2.13 ...J -9.13 -7.13 -5.13 -3.0
LOG (A(MG++)/(u(MG++»)(A(H+)"m LOG (A(MG++)/(u(MG++»)(A(H+)**m LOG (A(MG++l/(,r(MG++))(A(H+)··W

Phase relations in the system HCl- H 20- (Al 20 3) -CaO-C02 - K20- MgO-Si0 2, in equilibri-
um with quartz and K-feldspar, at XC02 = 0.99. Metastable 7-A c1inochlore was considered in-
stead of its stable counterpart, 14-A c1inochlore. Saturation limits: calcite (a), magnesite (b),
dolomite (c), phlogopite (d), diopside (e), tremolite (f), enstatite (g).
FUGACITY DIAGRAMS
 292
20.0 20.0

WITH
,... 10.0 WITH ,... 10.0 ,.... 10.0
N N N
o 0 0
U u u
~ 0.0 ~ 0.0 ~ 0.0
(!) (!) (!)
o 0
BARITE
0
...I
...1- 10 . 0 BARITE ...1- 10 . 0 -10.0 BARITE

-20 0 -20 0 -20 0L-~-~~~----'

-::f0.0 -20.0 -10.0 0.0 -::f0.0 -20.0 -10.0 0.0 -g0.0 -20.0 -10.0 0.0
LOG (A(S04--)*(CACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2))
20.0 20.0 20.0r-~~--~~-.

,.... 10.0 ,.... 10.0 WITH ,.... 113.0

N N N
0 0 o
u u U
~ 0.0 ~ 13.13 ~ 13.0
(!) (!) (!)
0 0 o
...I ...I ...I
-10.0 BARITE -113.13 BARITE -10.0

-20 0 -213.0 -213 . a'---~~~~~~...J

-::fe.a -213.13 -113.13 13.0 -313.13 -213.13 -113.13 0.13 -313.13 -213.13 -113.13 13.0
LOG CACS04--)*CCACH+))**2)) LOG (ACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2))
213.13 213.13

WITH WITH WITH

,... 10.13 ,.... 113.0 ,.... 113.0
N N N
0 0 o
u u U
~ 13.0 ~ 0.13 ~ 13.0
(!) (!) (!)
0 0 o
...I BARITE ...I ...I
-113.13 -113.13 BARITE -113.13 BARITE

-213.13 -20.13 -20.a'---~--~--~~~

-313.0 -213.13 -113.13 13.13 -313.13 -213.0 -10.13 13.0 -30.13 -20.13 -10.0 0.0
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2):
213.13 20.13 213.0

WITH WITH WITH

113.0 ,... 113.0 ,....
'"
N
0
N
0
N
0
u u u
~ 0.0 ~ 13.0 ~ 0.13
(!) (!)
0 0
BARITE ...I
...1- 113 • 0 -10.0 BARITE

-20 a -213 . a -213. a '---~--~--~~~

-ga.a -213.13 -10.0 0.13 -30.13 -213.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2):

Phase relations in the system HCI-H 20-(BaO)-C02 -H2S04•

 293

WITH WITH WITH

,... 10.0 ,... 10.0 ,... 10.0
N N N
o o o
U U U
~ 0.0 ~ 0.0 ~ 0.0
(!) (!)
o o BARITE
-1 BARITE -1
-10.0 -10.0

-20.0 -20.0 -20.0~~~--~~~~

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2))
20.0 20.0 20.0

10.0 WITH WITH 10.0 WITH

,... ,... 10.0 ,...
N N N
0 0 0
u u u
~ 0.0 ~ 0.0 ~ 0.0
(!) (!) (!)
0 0 0 BARITE
-1 BARITE -1 BARITE -1
-10.0 -10.0 -10.0

-20.0 -20.0 -20.0L-~~~--~~~

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2))
20.0 20.0 30.0

WITH
10.0 WITH
,... ,... 10.0 ,... 20.0 WITH
N N N
0 0 0
u u u
~ 0.0 ~"0.0 ~ 10.0
(!) (!) (!)
0 0 BARITE 0 BARITE
-1 -1 -1
-10.0 BARITE -10.0 0.0

-20.0 -20.0 -10.0L-~~~--~--~

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2))
20.0 30.0 30.0.-~~~--r-~~

WITH WITH
WITH
,... 10.0 ,... 20.0 ,... 20.0
N N N
0 0 o
u u U
~ 0.0 ~ 10.0 ~ 10.0
(!) (!)
BARITE
(!)
0 BARITE 0 o
-1
-10.0
-1
0.0 BARITE -1
0.0

-20.0 -10 0 -10.0~~~~--~~~

-30.0 -20.0 -10.0 0.0 -40.0 -30.0 -20.0 -10.0 -40.0 -30.0 -20.0 -10.0
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2))
Phase relations in the system HCl-H 20-(BaO)-C0 2 -H 2S04•
 294
20.0 20.0 20.0

10.0 ARAG 10.0 ARAG 10.0 CALC

,.., ,.., ,..,
N N N
0 0 0
u u u
~ 0.0 ~ 0.0 ~ 0.0
(.') (.') (.')
0 0 0
...J ...J
ANHYD ...J ANHYD
-10.0 ANHYD -10.0 -10.0

-2_0300.0 -20.0 -10.0 0.0 -2_03'.,"'.0 -20.0 -10.0 0. 0 -2!'3.,"'.'-0--~2-0~.0--~1-0~.~0~-0--'. 0

LOG CACS04--)*CCACH+))**2) LOG CACS04--)*CCACH+))**2) LOG CACS04--)*CCACH+))**2)
20.0~~----~~--~

CALC
,... 10.0 CALC ,... 10.0 ,... 10.0
N N N
o o o
U U U
~ 0.0 ~ 0.0 ~ 0.0
(.') (.') (.')
o o o
...J ...J ...J ANHYD
-10.0 ANHYD -10.0 ANHYD -10.0

-20.0L-~~~--~~~ -20.0 -20.0L-~~~--~~~

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+))**2) LOG CACS04--)*CCACH+))**2) LOG CACS04--)*CCACH+))**2:

10.0 CALC CALC

,... 10.0 CALC ,... 10.0
N
o
"
N N
U
o o
U U
~ 0.0 ~ 0.0 ~ 0.0
(.') (.') (.')
o o o
...J ...J ...J ANHYD
-10.0 -10.0 ANHYD -10.0
ANHYD

-20.0'--~~--~~~~ -20.0'--~~--~~--~ -20.0~~~--~----~

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+))**2) LOG CACS04--)*CCACH+))**2) LOG CACS04--)*CCACH+))**2
20.0 20.0 20.0

10.0 10.0 CALC CALC

CALC ,... ,... 10.0
"N0 N
0
N
0
u u u
~ 0.0 ~ 0.0 ~ 0.0
(.') (.') l'l
0 0 0
...J ...J ...J ANHYD
-10.0 ANHYD -10.0 ANHYD -10.0

-20.0L-----~--~~~ -20.0 -20.0~~~--~~~~

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+))**2) LOG CACS04--)*CCACH+))**2) LOG CACS04--)*CCACH+))**2
Phase relations in the system HCI- H 20- (CaO) -C0 2 - H 2S0 4.
 295
20.0 20.0 20.0

CALC CALC
10.0 CALC 10.0 10.0
"
N
0
"N0 "N0
U U U
;:;:: 0.0 ;:;:: 0.0 ;:;:: 0.0
(!) (!) (!)
0 0 0
...J
ANHYD ...J ANHYD ...J ANHYD
-10.0 -10.0 -10.0

-20 0L-~~--~~~--J -20.0L-~~~~~~~ -20.0L---~~--~~~

-::f0.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG (A(S04--)*«A(H+»**2) LOG (A(S04--)*«A(H+»**2) LOG (A(S04--)*«A(H+»**2)
20.0 20.0 20.0

CALC CALC CALC

10.0 10.0 10.0
"
N
0
'"
N
0
"N
0
u u u
;:;:: 0.0 ;:;:: 0.0 ;:;:: 0.0
(!) (!)
0 0
...J ANHYD ...J ANHYD
-10.0 -10.0

-20.0L-~~--~~~--J -20 0 -20.0L-~~~----~~

-30.0 -20.0 -10.0 0.0 -::f0.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG (A(S04--)*«A(H+»**2) LOG (A(S04--).«A(H+» •• 2) LOG (A(S04--).«A(H+».*2)
20.0 30.0

CALC
10.0 10.0 20.0 CALC
"No '"
N
0
"
N
0
U u u
;:;:: 0.0 ;:;:: 0.0 ;:;:: 10.0
(!) (!) (!)
o 0 ANHYD 0
...J ANHYD ...J ...J
-10.0 -10.0 0.0 ANHYD

-20.0L-~~~~~~~ -20.0L-~~--~~~~ -10.0L-~~~~--~...J

-30.0 -20.0 -1 0 . ~ 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG (A(S04--)*«A(H+»**2) LOG (A(S04--).«A(H+» •• 2) LOG (A(S04--)*«A(H+»**2)
20.0 30.0 30.0
CALC
CALC
10.0 20.0 20.0
"N0 '"
N
0
'"
N
0
u u u
;:;:: 0.0 ;:;:: 10.0 ;:;:: 10.0
ANHYD
(!) (!) (!)
0
...J
ANHYD 0 0
-10.0 ...J 0.0 ANHYD ...J 0.0

-20.0 . -10.0 -10 0'---~~~~-~

-30.0 -20.0 -10.0 0.0 -40.0 -30.0 -20.0 -10.0 -4'0.0 -30.0 -20.0 -10.0
LOG (A(S04--)*«A(H+».*2) LOG (A(S04--)*«A(H+».*2) LOG (A(S04--).«A(H+».*2)
Phase relations in the system HCI- H 20 - (CaO) - CO 2 - H2S04,
 296
2121.121 2121.121 2121.'"

1121.121 CER CER

CER ,... 1121.121 ,... 1121 .• 121
'"
N
0
N
0
N
0
u u u
~ 121.121 ~ 121.121 ~ 121.121
(!) (!) (!)
0 0 0
..J ..J ANG ..J ANG
-1121.121 ANG -1121.121 -1121.121

-2121.121 -2121.121 -2121.12I~--~~--~~~

-3121.121-2121.121-1121.121 121.121 -3121.121-2121.121-1121.121 121.121 -3121.121-2121.121-1121.121 121.121
LOG (A(S04--)*«A(H+))**2)) LOG (A(S04--)*«A(H+))**2)) LOG (A(S04--)*«A(H+))**2)
2121.121 2121.121 2121.121

CER 1121.121 CER CER

,... 1121.121 ,... ,... 1121.121
N N N
0 0 0
u u u
~ 121.121 ~ 121.121 ~ 121.121
(!) (!)
0 0
..J ANG ..J ANG
-1121.121 -1121.121

-2121.121 -2121.121 -2121.12IL---~~--~~~

-3121.121-2121.121 -1121.121 121.121 -3121.121-2121.121 -1121.121 121.121 -3121.121 -2121.121-1121.121 121.121
LOG (A(S04--)*«A(H+))**2)) LOG (A(S04--)*«A(H+))**2)) LOG (A(S04--)*«A(H+))**2)
2121.121 2121.121 2121.121

1121.121 CER 1121.121 CER 1121.121 CER

,... ,... ,...
N N N
0 0 0
u u u
~ 121.121 ~ 0.121 ~ 121.121
(!) (!) (!)
0 0 0
..J ..J ANG ..J ANG
-1121.121 ANG -1121.121 -1121.121

-2121.121 -2121.121 -2121 12IL---~~--~~~

-3121.121-2121.121 -1121.121 121.121 -3121.121-2121.121-1121.121 121.121 -3'121.121 -2121.121-1121.121 121.121
LOG (A(S04--)*«A(H+))**2)) LOG (A(S04--)*«A(H+))**2)) LOG (A(S04--)*«A(H+))**2:
2121.121 2121.121 2121.121

CER CER
,... 1121.121 ,... 1121.121 ,... 1121.121
N N N
0 0 0
u u u
~ 121.121 ~ 121.121 ;;:: 0.121
(!) (!)
0 0
..J ANG ..J ANG
-1121.121 -1121.121

-2121.121 -2121.121 -2121.12IL-------------..J

-3121.121-2121.121-1121.121 121.121 -3121.121-2121.121-1121.121 121.121 -3121.121-2121.121-1121.121 121.121
LOG (A(S04--)*«A(H+))**2)) LOG (A(S04--)*«A(H+))**2)) LOG (A(S04--)*«A(H+))*~2:
Phase relations in the system HCl-H 20-C0 2 -H2S04 -(PbO).
 297
20.0 20.0 20.0

CER
10.0 CER 10.0 r.
'"
N
0
'"
N
0
N
0
u u u
~ 0.0 ~ 0.0 ~ 0.0
(!) (!)
0 0
-oJ- 10 .0 ANG ..J ANG
-10.0

-20 0 -20 .0 -20 .0

-g~.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG <A<S04--)*«A<H+))**2)) LOG <ACS04--)*C(ACH+))**2)) LOG CACS04--)*C(ACH+))**2)J
20.0 20.0 213.0

CER CER CER

10.0 10.13 10.0
r. r. r.
N N N
0 0 0
u u u
~ 13.0 ~ 0.0 ~ 0.0
(!) (!)
0
ANG (!)
0
0 ANG
..J ANG ..J ..J
-113.0 -113.13 -113.0

-213.0 -213.13 -20.0L-~~~~~~..J

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.13
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCA(H+))**2)) LOG CACS04--)*«A<H+))**2))
20.0 20.13 213.0

CER CER
113.0 10.0 10.0
r\ r\ r.
N N N
0 0 0
u u u
~ 13.0 ~ 13.13 ~ 13.0
(!)
0
(!)
0 ANG (!)
0
ANG
..J ANG ..J ..J
-10.0 -10.13 -113.0

-20 0 -213.13 . -2a.0'--~~~~~~...J

-3"13.0 -213 . a -10.0 0.0 -30.0 -20.0 -10.0 0. a -30. a -20. a -10.0 0.0
LOG CACS04--)*C(ACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2))
20.0 313.0
CER
CER
10.0 20.0
r\ r. r.
N N N
0 0 0
u u u
~ 13.0 ~ 13.13 ~ 10.13
ANG
(!)
ANG
(!)
0
(!)
0
ANG
0
..J ..J ..J
-10.0 -10.0 0.0

-20.13 -20.0 -la.aL-~~~--~~~

-30.0 -20.0 -10.0 0.0 -40.0 -30.0 -20.0 -10.0 -40.0 -30.0 -20.0 -10.0
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2))
 298
3.0 3.0 3.0

1.0 1.0 1.0

STRONT STRONT
"
N "
N "
N
8'1.0 8- 1 . 0 8- 1 . 0
v v v
lL. lL. lL.
w 3 .0 w3.0 w 3 .0
0 0 0
..J ..J ..J
CELEST
-5.0 -5.0 -5.0

-7.0 -7.0 -7.0

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+»**2» LOG CACS04--)*CCACH+»**2» LOG CACS04--)*CCACH+»**2»
3.0 3.0 3.0

1 .0 1.0 1.0
STRONT STRONT
"N "N "
N
8- 1.0 8- 1 . 0 8- 1 . 0
v v v
lL. lL. lL.
w3.0 w3.0 w 3 .0
0 0 0
..J ..J CELEST ..J
CELEST
-5.0 -5.0 -5.0

-7.0 -7.0 -7.0

-30.0 -20.0 -10.0 0.0 -30.0-20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+»**2» LOG CACS04--)*CCACH+»**2» LOG CACS04--)*CCACH+»**2,:
3.0 3.0 3.0

1.0 1.0 1.0

STRONT STRONT
"
N "N "
N
8- 1 . 0 8- 1. 0 8- 1 . 0
v v v
lL. lL. lL.
w 3 .0 w3.0 w3.0
0 0 0
..J ..J ..J CELEST
CELEST
-5.0 -5.0 -5.0

-7.0 ' -7.0. -7.0

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+»**2» LOG CACS04--)*CCACH+»**2» LOG CACS04--)*CCACH+»**2):
0.0 0.0 0.0

-2.0 STRONT -2.0 -2.0

"N "N "N
8- 4.0 8- 4 .0 8- 4 . 0
v v v
lL. lL. lL.
w 6 .0 w6.0 w 6 .0
o CELEST o o
..J ..J ..J
CELEST CELEST
-8.0 -8.0 -8.0

-10 0 -10.0 -10.0

-3'13.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -313.0 -20.0 -10.0 0.0
LOG CACS04--)*CCACH+»**2» LOG CACS04--)*CCACH+»**2» LOG CACS04--)*CCACH+» ••2)
Phase relations in the system HCI-H 20-C0 2-H2SOc(SrO).
 299
3.0 3.0 3.0

1.0 1.0 TRONT 1.0

STRONT
"N N" "N
8- 1 . 0
v
8-
v
1.0 8-
v
1. 0
lL lL lL
(!T"3 . 0 (!T"3.0 (!T"3 . 0
0 0 0
..J CELEST ..J CELEST ..J CELEST
-5.0 -5.0 -5.0

-7.0 -7.0 -7.0

-30.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -30.0 -20.13 -113.0 13.0
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)
3.0 3.0 3.0

1 .0 1 .0 1 .0
r-. r-.
"
N N N
8-
v
1.0 8-
v
1.0 8- 1.0
v
lL lL lL
(!T"3 . 0 (!T"3.0 (!T"3 . 0
0 0 0
..J ..J ..J CELEST
CELEST CELEST
-5.0 -5.0 -5.0

-7.0 -7.0 -7.0

-30.0-20.0-10.0 0.0 -30.0-20.0-10.0 0.0 -30.0-20.0-10.13 0.0
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2):
3.0 3.0 3.0

1.0 1.0 1.0 /

~
STRONT
"N "N "
N
8-
v
1.0 8-
v
1.0 8-
v
1.0
lL lL lL
(!T"3 . 0 (!T"3 .0 (!T"3 . 0
0 0 0 CELEST
..J CELEST ..J CELEST ..J
-5.0 -5.0 -5.0

-7':300.0 -20.0 -10.0 0.0 -7_·~0.0 -20.0 -10.0 0.0 -7_'300.0 -20.0 -10.0 0.13
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)
2.0 2.0 2.0

0.0 0.0 0.0

r-. r-.
N "N N
8- 2 . 0
v
8- 2 . 0
v
8- 2 . 0
lL lL lL
(!T"4.0 (!T"4.0 CELEST (!T"4 . 0
0 0 0 CELEST
..J CELEST ..J ..J
-6.0 -6.0 -6.0

-8 . 0 -8 . 0 -8 . 0
-30.0 -20.0 -10.0 0.0 -50.0 -40.0 -30.0 -20.0 -60.0 -50.0 -40.0 -30.0
LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)) LOG CACS04--)*CCACH+))**2)

Phase relations in the system HCI- H20 - CO 2 - H 2S0 4 - (SrO).

 300
20. 0r--~---~----'

10.0
" o" "No
N N
o
U U U
;;:: 0.0 ;;:: 0.0 ;;:: 0.0

8
...J.. 10 . 0

-20 0 L - . . . . - - - - - - I
-2_0~00.0 -20.0 -10.0 0.0 -2_03':.0 -20.0 -10.0 0.0 -3"3.0 -20.0 -10.0 0.0
LOG (A(HS-).A(H+» LOG (A(HS-).ACH+» LOG (A(HS-).A(H+»
20.0~----~~~~~ 20.0r------~~~~~ 20.0~~---~--~

10.0 SMITH 10.0 SMITH

"No "o
N "No
U U U
;;:: 0.0 ;;:: 0.0 ;;:: 0.0
(!) (!)
o SL o
...J.. 10 . 0 ...J.. 10 . 0 SL

-20 0L....---~~~---' -20.0 -20 .0L-....------I

-3"0.0 -20.0 -10.0 0.0 -30.0 -20.0 -10.0 0.0 -3"3.0 -20.0 -10.0 0.0
LOG (A(HS-).A(H+» LOG (ACHS-).A(H+» LOG CACHS-)*A(H+»
20. 0r--~---~------' 20.0r------~~~--~

10.0 SMITH 10.0 SMITH

"No "No "o
N
U U U
;;:: 0.0 ;;:: 0.0 ;;:: 0.0
(!)
o
...J SL
(!)
o SL 8 SL
-10.0 ...J.. 10 . 0 ...J- 10 .0

-20.0 -20 0'----~~----' -20.0L-....------I

-3"3.0 -20.0 -10.0 0.0 -3"0.0 -20.0 -10.0 0.0 -33.0 -20.0 -10.0 0.0
LOG (A(HS-).ACH+» LOG (ACHS-)*A(H+» LOG CA(HS-).A(H+»
20.0~~----~--~ 20.0r------~~~--~

10.0
SMITH .10.0 SMITH
"N0 "N "
N
U
0
U 8
;;:: 0.0 ;;:: 0.0 ;;:: 0.0
(!) (!)
0 o
...J
-10.0
SL ...J.. 10 . 0 SL

-20.0 -20 eL.---~~~---' -20.e~--~~~---~

-30.0 -20.0 -10.0 0.0 -3"0 . 0 -20. 0 -1 0 . 0 0 .0 -30.0 -20.0 -10.0 0.0
LOG CA(HS-).A(H+» LOG CA(HS-)*ACH+» LOG (A(HS-).A(H+»
Phase relations in the system HCl-H 20-C0 2-H 2S-(ZnO).
 301

to.0 SMITH SMITH 10.0 SMITH

r\
10.0 r\
r\
N N N
o o o
U U U
~0.0 ~0.0 ~ 0.0
(!) (!) (!)
o o o SL
SL ...J SL .0
~10.0 -10.0 ...J_ 10

-20.0~~~~------~
-30.0-20.0-10.0 0.0 -2_03"1.0 -20.0 -10.0 0.0 -2_°3'00.0 -20.0 -10.0 0.0
LOG (A(HS-)*A(H+» LOG CA(HS-)*ACH+» LOG (ACHS-)*ACH+»
20.0r---~~------~ 20.0r---~~-------' 20.0r-~~~~--~~

SMITH
10.0 1O.O SMITH 10.0 SMITH
r\ r\ r\
N N N
0 0 o
u u U
~ 0.O ~ O.O ~ 0.0
(!)
0
...J
SL 8...J SL
(!)
o
...J
SL
-10.0 -1O.O -10.0

-2_03"00.0 -20. ° -1 ° .0 ° .° -2_°3"00. 0 -20. 0 - 10 . 0 0. 0 -2-03 /.0-20.0-10.0 0.0

LOG (A(HS-)*A(H+») LOG CACHS-)*A(H+)) LOG (A(HS-)*A(H+»
20.0r---~--~--~~ 20.0,--------------, 20.0r---~------~~

10.0 SMITH 10.O SMITH 10.0 SMITH

r\ r-. r-.
N N N
o o o
U U U
~ 0.0 ~ 0.0 ~ 0.0
(!) (!) (!)
o SL o SL o
...J ...J ...J SL
-10.0 -10.0 -10.0

-20 0~~~----~~~ -20.0L-----------~-...J

-2_03" 00.0 -20.0 - 1° . 0 0. 0 -3"0.O -20.0 -10.O 0.O -30.0 -20.0 -10.0 0.0
LOG CACHS-)*ACH+» LOG CACHS-)*ACH+» LOG CACHS-)*ACH+)
20.0r---~~------~ 20.0r-~~----~-r-. 20.0r-------~~--~

SMITH SMITH
10.O SMITH 10.0 10.0
r\ r-. r\
N N N
o 0 0
U u u
~ O.O ;;:: 0.0 ~ 0.0
SL
(!) (!) (!)
o SL 0 SL 0
...J ...J ...J
-10.0 -10.0 -10.0

-20.0~~~--~~~~
-2~3"0~~0~-2-0~.0----1-0-.-0~-0~.0 -20.0~--~------~~
-30.0-20.0-10.0 0.0 -30.0-20.0-10.0 0.0
LOG CACHS-)*ACH+») LOG CACHS-)*ACH+» LOG CACHS-)*A(H+»
Phase relations in the system HCl-H 20-C02 -H 2S-(ZnO).
302
0.0 10.0

TO TO ..--/
-20.0 A- 10 . 0 TO / -10.0
A
N
o ~ ,/""
"
N
o
CUP/
V V

U-40.0
CUP
~30.0~Y COy
u-30.0 COy
(') (') (')
o COy o o CC
-' CC -' CC -' COPPER
-60.0 -50'~pPPE~ -50.0
OPPE

-70.0
-8-"kJl.0 -30.0 -5.0 -15.0 10.0 -40.0 -15.0 10.0
LOG FCS2) LOG FCS2) LOG FCS2)
0.0 10.0

TO TO TO ./
-20.0 -10.0 -10.0 /1
A A A
N N N CUP /
oV 0
V
o
V
U-40.0 U-30.0 CUP U-30.0
CUP COy COy
(') (') (')
o COy 0 o CC
-' CC -' CC -' COPPER
-50.0 -50.0
C PPE

-8_"kJl.0 -70.0 -70.0

-30.0 -5.0 -40.0 -15.0 10.1'1 -40.0 -15.0 10.0
LOG FCS2) LOG FCS2) LOG FCS2)
0.0 10.1'1 10.0

TO TO TO ../
-20.0 -10.0 -10.0 ,/'
1'\ A A
N N N CUP /
0 0 o
V V V

u-4a.a U-30.0 CUP U-30.0

CUP COy COy
(') (') (')
0 COy 0 o CC
-' CC -' CC -' COPPER
-60.0 -50.0 -50.1'1
C PP R C PP R

-81'1 Jl -70.0L-~~~~~~~ -70.0

-5 .0 -30.0 -5.0 -40.0 -15.1'1 11'1.0 -41'1.0 -15.1'1 10.1'1
LOG FCS2) LOG FCS2) LOG FCS2)
0.0 10.0

TO ,/
~-20.0 TO / A-10 • 0 TO,/ -10.1'1 .....-
N "N CUP /
o f----,-------- oV
~
8 40 . 0 cuy ~
COy (')
o
-'
~30.0 CuV
-
CC
COy (')
o
u-30.0

-'
CC
COy

-' - CC COPPER
-60.0 -50.0~, ,. -50.0
C)PPER CJPP.R

-81'1 0 -70.0L--L~~~~~~
-55.0 -30.0 -5.1'1 -40.0 -15.0 10.0 -15.0 11'1.0
LOG FCS2) LOG FCS2) LOG FCS2)

Phase relations in the system HCI- H 20- (CuO) -02-S2'

 303
10.0 10.0 10.0
TO TO
TO
// //
,...-10.0 CUP /
----/ ,...-10.0 CUP / ,...-10.0 CUP /'
N N N
ov o
v
o
v
Lt......30.0 COIJ Lt......30.0 COIJ Lt......30.0 CO\
(!)
o CC (!)
o CC (!)
o CC
...J COPPER ...J COPPER ...J COPPER
-50.0 -50.0 -50.0

-70.0
-7~41.0 -15.0 10.0 -40.0 -15.0 10.0
LOG F(S2) LOG F(S2)
10.0 10.0 10.0
TO TO

,...-10.0
TO
,........,
/
,...-10.0 CUP /
/./
,...-10.0 ~UP
7~
CUP /
N N N
o o ov
v v
Lt......30.0 COY Lt......30.0 COY Lt......30.0 0\
(!)
o CC (!)
o
CC (!)
o CC
...J COPPER ...J COPPER ...J
COPPER
-50.0 -50.0 -50.0

-7~41.0 -15.0 10.0 -7~41.0 -15.0 10.0 -7~41.0 -15.0 10.0

LOG F(S2) LOG F(S2) LOG F<S2)
10.0 10.0 10.0
TO
TO
//
TO
,........,/ l;U ....
----/
,...-10.0 CUP / ,...-10.0 CUP / ,...-10.0 /'
N N N
ov o
v
ov
Lt......30.0 CO~
Lt......30.0 COY Lt......30.0 iCO\
(!)
o CC (!)
o CC (!)
o CC
...J COPPER ...J COPPER ...J
COPPER
-50.0 -50.0 -50.0

-7_0"00.0 0 0 -7~41.0 -15.0 10.0 -70.0

.. -15.0 1. -40.0 -15.0 10.0
LOG F(S2) LOG F(S2) LOG F(S2)
10.0 10.0 10.0
TO
//
TO
;"/ TO
./
,...-10.0 CUP / ,...-10.0 CUP / ,...-10.0 ~ /'
N N N
ov ov ov
Lt......30.0 COY Lt......30.0 COY Lt......30.0 cm
(!)
o CC (!)
o CC (!)
o COPPER
cc
...J COPPER ...J COPPER ...J
-50.0 -50.0 -50.0

-70 0 -70 a -70.0

-4"~.0 -15.0 10.0 -4"0.0 -15.0 10.0 -4~.0 -15.0 10.0
LOG F(S2) LOG F(S2) LOG F(S2)
Phase relations in the system HCl- H 20- (CuO) -02-S2.
304
-60.0r-----~--~~1 -30. 0.------~-~
HM / HM
-70.01--_ _ _ _: -40.0 -20.0 HM
~ / "N "N
8-80.0 / MG 8- 50 . 0
~
MG 8- 30 . 0
~
r_-------
MG
~ ~ iPYRITE
g-90.0~· PO 8-60.01------1 8-40.0
...J ...J

-100. /FE- -70,0 -50.0

V'YXIDE
-80. 0 ~"---~--'-~--' -60.0~--~------~~
-1_1'0.0 -50.0 -30.0 -10.0 -60.0 -40.0 -20.0 0.0 -60.0 -40.0 -20.0 0.0
LOG F(S2) LOG F(S2) LOG F(S2)
-10.0r--------------,
HM
-70.01-_ _ _ _/ -40.0 -20.0 HM
,...,
"N "N
8-80 . 0
~
MG
N
8- 50 . 0
~
MG 8- 30 . 0
~
r_-------
MG /7
g-60. 01--F-E-_--J 8-40.01------~
PO ...J
OXID
-100. FE- -70.0 -50.0 PY IT
PO
~XIDE
-80.0L-~~-~~~~
-1_1'0.0 -50.0 -30.0 -10.0 -60.0 -40.0 -20.0 0.0 -6_06 """.0 -40.0 -20.0 0.0
LOG F(S2) LOG F(S2) LOG f(S2)

-60.0r---~----~~_, -10.0r--------------,

HM ./ HM
-70.01-_ _ __ -40.0 -20.0 HM
~ / ,...,
N
8- 50 . 0 I
,...,
N
8- 30 . 0 1---------.
~80. 0 MG / PYRITE MG
~YRITE ~ MG
~

(!)
8-40.01------~·
g-90. 0 r--~/ PO g-60.0 FE- ...J
FE- OXIDE
-100. ~XIDE -70.0 -50.0
PO
V -80.0~~------L---~ -60.0~--~~--~~~
-1_1'0.0 -50.0 -30.0 -10.0 -60.0 -40.0 -20.0 0.0 -60.0 -40.0 -20.0 0.0
LOG F(S2) LOG F(S2) LOG F(S2)
-10.0r---~----~---,

HM
HM
-70.01--_ _ ___ -40.0 -20.0 HM
N"
8- 80 . 0
/ "N
8- 50 . 0
"N
MG / PYRITE MG ~30.0r---M-G---~--
~ ~

8-90.0
...J
8-60.01----/
...J
8-40.0~----7;11
...J
PO
-100. FE- -50.0 RIT
~IDE
-80.0L-"-------L---~ -60.0~--~~--~~~
-1_1'0.0 -50.0 -30.0 -10.0 -60.0 -40.0 -20.0 0.0 -60.0 -40.0 -20.0 0.0
LOG F(S2) LOG F(S2) LOG F(S2)
Phase relations in the system HCl- H20- (FeO) -02- S2'
 305
0.0 0.0 121.0
HM
-10.0 -10.0 HM -1121.121
HM
"N "N "
N MG
8- 20 . 0 8- 20 . 0 MG I 8- 2121 . 0
~
MG
~
/ ~
FE-OXIDE
8-30.0 8-30.0 8-3121.121
...J P RITE ...J FE-OXIDE ...J
PRIT
-4121.121 -4121.0 PO
PO PO
-S0.0L-~~~---L~~ -SI2I.0L-~~~----~~
-50.0 -30.0 - 10 . 0 10.121 -S~5'I2II21. 121 -3121.121 -1121.121 1121 . 0 -50.121 -3121.0 - 10 . 0 10.121
LOG FCS2) LOG FCS2) LOG FCS2)
121.121 121.121 121.0
HM
-1121.121 -1121.121 HM -1121.121
HM
"N "N ~ MG /
8- 2121 . 121 8- 2121 . 121 MG 7 8-2121 . 0l--_____~/
~

MG
~ 1--------/ ~
FE-OXIDE
8-3121.121 8-3121.121 8-3121.121
...J
P RITE ...J FE-OXIDE ...J
P RIT
FE-OXIDE PRIT
-4121.121 -4121.121 -4121.121 PO
PO PO
-SI2I.I2IL-~~-~--~~
-5_1215'121121.121 -3121.121 -1121.121 1121 .121 -5_1215'121121.121 -3121.121 -1121.121 10.121 -5121.121 -3121.0 -1121.121 10.0
LOG FCS2) LOG FCS2) LOG FCS2)

121.121 121.121 0.0

HM HM
-1121.121 HM -1121.121 -10.0
"N "N "N MG I
8- 2121 . 121 8-2121 .121
MG I 8- 20 . 0 /
~ l----------- ~
/ ~
FE-OXIDE
MG /1 8-3121 .121 8-30.0
l---------. ...J FE-OXIDE ...J
P RITE PRIT
-4121.121 PRIT -40.0
PO PO
PO

-5.5'5'121121.121 -3121.121 -1121.121 1121 . 121 -5_1215'121121.121 -3121.121 -1121.121 10.0 -5_05'00.0 -30.0 -10.0 10.0
LOG FCS2) LOG FCS2) LOG FCS2)
121.121 121.0 0.0

HM HM
-1121.121 HM -1121.121 -10.0
"
N "N "N MG
8-2121 .121 8- 20 . 0 7 8-20 . 01-_________ 1
MG
~ l----------- ~
/ ~
FE-OXIDE
MG /1 8-3121.0 8-30.0
\----------. ...J FE-OXIDE ...J
P RITE PRIT
PRIT
-4121.121 -4121.0
PO PO PO
-5121 12IL-~~----~~--J
-5_05'121121.121 -3121 . 121 - 1121 . 0 10.121 -5_1215'121121.121 -30.121 -1121.0 10.0 -!:)0. 0 -30.0 - 10 . 0 10.0
LOG FCS2) LOG FCS2) LOG FCS2)
Phase relations in the system HCl-H20-(FeO)-02-S2'
 APPENDIX

The hydrolysis constants shown in the following pages correspond to those for the reac-
tions shown in table 3. The reactions are designated below by the abbreviations given in
table 2 for the minerals being hydrolyzed. The values of the equilibrium constants were gen-
erated using equations and data summarized by Helgeson and Kirkham (1974a), Walther and
Helgeson (1977), Helgeson and others (1978), and Helgeson, Kirkham, and Flowers (1981),
taking account of corrections given by Helgeson (1982b, 1984). PSAT in the tables refers to
pressures along the vapor-liquid equilibrium curve for H20.
308
Log K , P = P SAT for T ~ 350·C ; P = 500 b for T > 350·C

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

AND 1001 20.17 16.57 13.53 10.97 8.78 6.89 5.23 3.76
KYA 1002 19.83 16.30 13.32 10.80 8.65 6.80 5.18 3.74
SILL 1003 20.58 16.93 13.85 11.24 9.02 7.11 5.43 3.94
KAOL 1004 9.73 7.43 5.46 3.80 2.41 1.22 0.19 -0.72
CHRYS 1007 35.12 31.55 28.44 25.81 23.56 21.64 19.98 18.52
MUSC 1012 18.26 14.56 11.39 8.70 6.42 4.47 2.78 1.28
PARAG 1013 22.69 18.47 14.87 11.83 9.25 7.05 5.14 3.46
PHLOG 1014 43.20 38.22 33.90 30.22 27.08 24.39 22.06 20.00
ANNITE 1015 33.86 29.74 26.12 23.03 20.39 18.12 16.14 14.39
DEHYD-ANAL 1021 13.80 11.99 10.39 9.02 7.84 6.83 5.96 5.19
ANAL 1022 8.62 7.28 6.10 5.09 4.23 3.51 2.89 2.35
SEPIO 1023 33.74 31.00 28.45 26.24 24.38 22.81 21.49 20.36
LO-ALB 1025 3.92 3.10 2.29 1.57 0.95 0.41 -0.05 -0.45
MAX-MICRO 1027 0.45 0.08 -0.35 -0.76 -1.12 -1.44 -1.71 -1.95
K-SPAR 1028 0.45 0.08 -0.35 -0.75 -1.11 -1.42 -1.69 -1.93
HI-SAN 1029 1.83 1.28 0.70 0.16 -0.31 -0.73 -1.09 -1.41
ANOR 1030 31.75 27.06 23.05 19.63 16.70 14.18 11.97 10.00
NEPH 1031 16.23 14.13 12.35 10.84 9.55 8.46 7.51 6.67
WOLL 1035 14.85 13.62 12.53 11.57 10.75 10.04 9.41 8.86
DIOP 1039 23.15 20.97 19.02 17.33 15.87 14.61 13.51 12.54
CA-AL PYX 1040 42.06 36.46 31.73 27.72 24.30 21.34 18.76 16.46
AKER 1044 49.82 45.19 41.15 37.69 34.71 32.13 29.87 27.87
MERW 1045 75.13 68.25 62.31 57.23 52.87 49.08 45.78 42.85
MONTI 1046 32.91 29.75 27.02 24.69 22.69 20.96 19.45 18.11
GEHL 1047 64.29 56.65 50.19 44.72 40.04 36.01 32.48 29.35
FORST 1048 31.47 28.15 25.28 22.83 20.73 18.91 17.32 15.92
FAY 1049 21.50 19.05 16.92 15.10 13.53 12.17 10.98 9.93
HUNT 1050 13.36 10.75 8.32 6.11 4.10 2.24 0.49 -1.20
ART 1053 22.02 19.94 18.15 16.65 15.37 14.26 13.29 12.42
HED 1054 21.45 19.44 17.62 16.04 14.67 13.48 12.44 11.52
MALACH 1059 2.97 2.98 2.96 2.92 2.89 2.85 2.80 2.74
AZUR 1060 4.82 4.73 4.56 4.38 4.18 3.98 3.76 3.51
HYDRO-MAG 1062 36.11 31.56 27.53 24.02 20.94 18.20 15.70 13.37
SMITH 1064 1.01 0.56 0.12 -0.29 -0.67 -1.03 -1.37 -1.70
ANH-CORD 1065 63.61 53.83 45.41 38.23 32.06 26.74 22.07 17.92
HYD-CORD 1066 60.86 51.35 43.17 36.20 30.23 25.08 20.57 16.57
JADEITE 1067 10.04 8.72 7.55 6.54 5.68 4.94 4.31 3.76
CER 1068 -3.44 -3.19 -3.01 -2.87 -2.76 -2.67 -2.61 -2.57
STRONT 1069 -1.08 -1.08 -1.15 -1.24 -1.35 -1.47 -1.60 -1.75
DIS-DOL 1070 5.13 4.06 3.04 2.11 1.24 0.44 -0.33 -1.08
 log K , P = P SAT for T (; 350°C; P = 500 b for T > 350°C 309

TEMPERATURE,OC
INDEX
200 225 250 300 350 400 450 500 550 600

1001 2.42 1.16 -0.09 -2.89 -8.07 -7.89 -18.22 -34.04 -45.90 (-52.58)
1002 2.43 1.19 -0.04 -2.81 -7.96 -7.77 -18.07 -33.87 -45.72 (-52.38)
1003 2.58 1.30 0.04 -2.79 -7.99 -7.83 -18.17 -34.00 -45.87 (-52.56)
1004 -1.55 -2.35 -3.l6 -5.22 -9.79 -9.02 -18.99 -34.61 -46.21 ( -52.56)
1007 17.22 16.02 14.86 12.38 8.01 8.10 -0.42 -13.41 -23.08 (-28.45)
1012 -0.10 -1.41 -2.74 -6.03 -13.17 -12.05 -27.45 -51.51 -69.41 (-79.26)
1013 1.93 0.48 -0.98 -4.49 -11.86 -10.81 -26.51 -50.98 -69.l9 (-79.20
1014 18.15 16.42 14.75 11.01 4.08 4.51 -9.44 -30.89 -46.86 (-55.73)
1015 12.81 11.33 9.88 6.55 5.96 0.71 -12.67 -33.34 -48.72 (-59.22)
1021 4.49 3.84 3.21 1.77 -1.06 -0.67 -6.57 -15.69 -22.48 (-26.23)
1022 1.87 1.42 0.97 -0.15 -2.70 -2.10 -7.75 -16.63 -23.19 (-26.73)
1023 19.37 18.47 17.58 15.43 10.48 11.71 0.66 -16.77 -29.52 (-36.21)
1025 -0.82 -1.17 -1.53 -2.52 -5.01 -4.21 -9.98 -19.15 -25.91 (-29.54)
1027 -2.18 -2.41 -2.67 -3.46 -5.75 -4.89 -10.37 -19.l4 -25.61 ( -29.08)
1028 -2.16 -2.39 -2.65 -3.46 -5.76 -4.92 -10.43 -19.21 -25.71 (-29.20)
1029 -1.70 -1.99 -2.30 -3.20 -5.56 -4.77 -10.32 -19.13 -25.65 (-29.l6)
1030 8.22 6.55 4.93 1.32 -5.l5 -4.94 -17.73 -37.26 -51.89 ( -60.13)
1031 5.92 5.22 4.54 3.02 0.18 0.40 -5.35 -14.20 -20.79 (-24.45)
1035 8.36 7.91 7.48 6.60 5.23 5.17 2.66 -1.09 -3.90 (-5.49)
1039 11.66 10.85 10.08 8.43 5.63 5.66 0.27 -7.92 -14.03 (-17.45)
1040 14.38 12.45 10.58 6.56 -0.22 -0.44 -13.30 -32.75 -47.35 (-55.66)
1044 26.08 24.44 22.90 19.80 15.20 14.69 6.62 -5.33 -14.30 (-19.44)
1045 40.23 37.84 35.60 31.15 24.84 23.83 13.15 -2.50 -14.28 (-21.10)
1046 16.91 15.81 14.77 12.68 9.55 9.19 3.70 -4.42 -10.53 (-14.04)
1047 26.53 23.91 21.42 16.19 7.81 7.22 -8.17 -31.25 -48.60 (-58.53)
1048 14.65 13.49 12.40 1O.l6 6.76 6.39 0.36 -8.59 -15.32 (-19.19)
1049 8.98 8.10 7.26 5.48 2.54 2.45 -3.06 -11.40 -17.64 (-21.17)
1050 -2.88 -4.61 -6.47 -11.18 -20.78 -20.50 -40.64 -70.83 -94.00 (-107.50)
1053 11.61 10.83 10.04 8.l7 4.47 4.58 -2.99 -14.65 -23.35 (-28.23)
1054 10.69 9.92 9.l8 7.60 4.90 4.96 -0.28 -8.25 -14.20 (-17.53)
1059 2.65 2.54 2.38 1.80 0.10 0.51 -3.51 -9.87 -14.65 (-17.35)
1060 3.22 2.89 2.47 1.17 -2.10 -1.59 -8.98 -20.51 -29.25 ( -34.29)
1062 11.14 8.92 6.61 0.97 -10.23 -10.01 -32.92 -68.06 -94.60 (-109.86)
1064 -2.04 -2.40 -2.80 -3.86 -6.17 -6.07 -10.95 -18.49 -24.21 (-27.53)
1065 14.15 10.63 7.19 -0.41 -14.03 -13.57 -40.48 -81.55 -112.32 (-129.66)
1066 12.93 9.54 6.22 -1.17 -14.60 -14.02 -40.74 -81.63 -112.23 (-129.40)
1067 3.25 2.78 2.31 1.13 -1.48 -0.95 -6.65 -15.61 -22.25 (-25.85)
1068 -2.55 -2.58 -2.66 -3.l0 -4.65 -4.12 -8.00 -14.20 -18.86 (-21.47)
1069 -1.92 -2.13 -2.38 -3.15 -5.04 -4.78 -9.00 -15.59 -20.59 (-23.46)
1070 -1.83 -2.62 -3.47 -5.67 -10.27 -10.07 -19.69 -34.47 -45.70 (-52.24)
310
log K, P = P SAT for T :( 350°C; P = 500 b for T > 350°C

TEMPERATURE, °C
NAME INDEX
0 25 50 75 100 125 150 175

ORD-DOL 1071 3.39 2.52 l.66 0.87 0.13 -0.57 -1.24 -l. 91
ARAG 1072 2.24 l.88 1.51 1.17 0.85 0.54 0.24 -0.06
CALC 1073 2.07 1.71 1.35 l.01 0.69 0.38 0.08 -0.23
MAG 1074 3.12 2.44 l.80 1.23 0.71 0.23 -0.22 -0.65
DOL 1075 3.39 2.52 l.66 0.87 0.13 -0.57 -1.24 -l.90
SIDER 1076 0.25 -0.22 -0.68 -1.11 -1.51 -l.88 -2.25 -2.60
ANHYD 1078 -4.07 -4.27 -4.58 -4.95 -5.34 -5.77 -6.22 -6.70
FLUORITE 1079 -10.32 -10.04 -9.92 -9.90 -9.95 -10.06 -10.23 -10.45
BARITE 1080 -10.49 -9.96 -9.68 -9.54 -9.51 -9.56 -9.69 -9.89
ANG 1081 -8.09 -7.81 -7.71 -7.70 -7.75 -7.85 -8.00 -8.19
CELEST 1082 -6.51 -6.43 -6.53 -6.71 -6.95 -7.23 -7.56 -7.93
ALUN 1083 3.91 0.66 -2.26 -4.86 -7.20 -9.35 -11.38 -13.35
WITH 1084 -3.30 -3.00 -2.82 -2.70 -2.63 -2.60 -2.61 -2.65
RHODO 1085 0.11 -0.19 -0.50 -0.79 -l.06 -1.32 -1.57 -l.82
COV 1086 -26.58 -24.32 -22.48 -20.95 -19.66 -18.57 -17.64 -16.85
GALENA 1087 -16.20 -14.85 -13.76 -12.85 -12.08 -1l.42 -10.85 -10.37
SL 1088 -1l.95 -11.36 -10.93 -10.61 -10.36 -10.18 -10.05 -9.97
WURT 1089 -9.44 -9.06 -8.81 -8.64 -8.53 -8.46 -8.43 -8.45
M-CINN 1090 -4l.89 -38.61 -35.89 -33.60 -31.64 -29.94 -28.47 -27.19
CINN 1091 -42.33 -38.98 -36.21 -33.87 -3l.87 -30.13 -28.63 -27.32
ALA 1092 -0.07 -0.41 -0.77 -1.12 -1.45 -l.77 -2.08 -2.39
PYRITE 1093 -26.53 -24.70 -23.32 -22.26 -21.43 -20.80 -20.34 -20.02
GOLD 1100 -27.10 -24.38 -22.07 -20.08 -18.34 -16.81 -15.44 -14.22
SILVER 1101 -10.48 -9.30 -8.28 -7.39 -6.60 -5.89 -5.24 -4.66
COPPER 1102 -5.19 -4.55 -3.99 -3.48 -3.02 -2.59 -2.19 -l.81
GRAPHITE 1103 -5.68 -5.00 -4.44 -3.98 -3.60 -3.29 -3.02 -2.81
HALITE 1106 1.52 1.61 l.64 l.63 1.59 1.54 1.46 1.36
SYLVITE 1107 0.58 0.90 1.11 1.24 1.32 1.36 l.36 1.32
COR 1108 25.56 2l.38 17.91 15.00 12.53 10.40 8.53 6.87
PER 1109 23.89 21.48 19.44 17.71 16.23 14.95 13.83 12.84
LIME 1110 35.70 32.60 29.98 27.74 25.82 24.15 22.69 21.40
TO 1111 6.61 6.18 5.82 5.52 5.28 5.08 4.91 4.76
CUP 1112 -2.35 -l.90 -1.50 -1.11 -0.73 -0.36 -0.01 0.33
FE-OXIDE 1113 15.19 13.50 12.07 10.85 9.81 8.91 8.12 7.41
GIBBS 1114 9.52 7.96 6.69 5.65 4.78 4.06 3.43 2.89
DIAS 1115 10.54 8.75 7.27 6.04 4.99 4.10 3.33 2.65
BOEH 1116 11.53 9.60 8.00 6.66 5.53 4.56 3.72 2.98
BRUC 1117 18.23 16.44 14.93 13.67 12.60 1l.68 10.89 10.19
MANGAN 1119 19.85 17.92 16.28 14.90 13.73 12.72 1l.84 11.07
SPINEL 1120 44.58 38.39 33.22 28.86 25.16 21.96 19.17 16.69
 log K , P = P SA T for T ~ 350·C ; P = 500 b for T > 350·C 311

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1071 -2.58 -3.30 -4.09 -6.19 -10.70 -10.42 -19.97 -34.69 -45.88 (-52.37)
1072 -0.37 -0.70 -1.06 -2.03 -4.15 -4.01 -8.51 -15.45 -20.72 (-23.78)
1073 -0.53 -0.86 -1.23 -2.21 -4.33 -4.19 -8.70 -15.65 -20.93 (-24.00)
1074 -1.08 -1.53 -2.00 -3.21 -5.67 -5.60 -10.70 -18.52 -24.46 (-27.92)
1075 -2.58 -3.30 -4.09 -6.19 -10.70 -10.43 -19.98 -34.71 -45.90 (-52.39)
1076 -2.96 -3.34 -3.76 -4.86 -7.19 -7.07 -11.99 -19.56 -25.32 (-28.68)
1078 -7.21 -7.79 -8.44 -10.22 -14.02 -13.91 -21.92 -34.20 -43.58 (-49.11)
1079 -10.73 -11.09 -11.56 -13.05 -16.78 -16.30 -24.67 -37.69 -47.59 (-53.32)
1080 -10.16 -10.51 -10.96 -12.35 -15.72 -15.43 -22.84 -34.30 -43.04 (-48.16)
1081 -8.44 -8.76 -9.16 -10.46 -13.75 -13.29 -20.70 -32.25 -41.02 (-46.10)
1082 -8.35 -8.84 -9.41 -11.03 -14.65 -14.46 -22.22 -34.16 -43.28 (-48.63)
1083 -15.32 -17.36 -19.59 -25.4G -38.06 -37.33 -63.99 -105.15 -136.25 (-154.11)
1084 -2.72 -2.84 -3.02 -3.63 -5.33 "5.02 -8.94 -15.09 -19.75 (-22.43)
1085 -2.09 -2.37 -2.70 -3.63 -5.77 -5.53 -10.22 -17.53 -23.06 (-26.23)
1086 -16.18 -15.63 -15.19 -14.72 -15.35 -14.38 -17.17 -21.96 -25.55 (-27.49)
1087 -9.98 -9.66 -9.43 -9.35 -10.53 -9.61 -13.33 -19.52 -24.13 (-26.63)
1088 -9.95 -9.98 -10.09 -10.67 -12.61 -12.08 -16.83 -24.38 -30.08 (-33.31)
1089 -8.50 -8.61 -8.79 -9.48 -11.52 -11.08 -15.90 -23.51 -29.26 (-32.53)
1090 -26.08 -25.13 -24.33 -23.28 -23.69 -22.06 -25.32 -31.19 -35.51 (-37.71)
1091 -26.19 -25.22 '-24.40 -23.31 -23.70 -22.05 -25.28 -31.14 -35.44 (-37.62)
1092 -2.71 -3.05 -3.44 -4.48 -6.79 -6.62 -11.56 -19.21 -25.01 (-28.35)
1093 -19.84 -19.79 -19.91 -20.81 -24.06 -23.29 -31.25 -43.87 -53.47 (-59.00)
1100 -13.12 -12.13 -11.21 -9.61 -8.21 -7.08 -5.96 -4.90 -3.98 (-317)
1101 -4.12 -3.63 -3.17 -2.34 -1.61 -0.98 -0.38 0.18 0.69 (1.15)
1102 -1.46 -1.13 -0.83 -0.26 0.19 0.71 0.98 1.12 1.30 (1.56)
1103 -2.63 -2.48 -2.37 -2.26 -2.41 -2.23 -2.85 -3.92 -4.75 (-5.24)
1106 1.24 1.09 0.90 0.32 -1.09 -0.96 -4.07 -8.91 -12.59 (-14.72)
1107 1.25 1.15 1.00 0.49 -0.81 -0.69 -3.59 -8.09 -11.53 (-13.54)
1108 5.37 3.96 2.58 -0.45 -5.77 -5.85 -16.14 -31.78 -43.52 (-50.20)
1109 11.95 11.13 10.38 8.90 6.93 6.44 3.30 -1.22 -4.64 (-6.67)
1110 20.24 19.19 18.22 16.42 14.32 13.50 10.61 6.66 3.64 (1.77)
1111 4.64 4.53 4.42 4.19 3.75 3.82 2.89 1.45 0.38 (-0.20)
1112 0.65 0.96 1.25 1.72 1.86 2.56 1.99 0.77 -0.04 (-0.29)
1113 6.79 6.21 5.66 4.55 2.93 2.68 -0.13 -4.25 -7.37 (9.18)
1114 2.39 1.92 1.46 0.34 -1.97 -1.77 -6.62 -14.16 -19.77 (-22.88)
1115 2.02 1.44 0.87 -0.45 -2.92 -2.82 -7.81 -15.48 -21.21 (-24.41)
1116 2.30 1.67 1.05 -0.34 -2.87 -2.82 -7.86 -15.57 -21.33 (-24.57)
1117 9.57 9.00 8.47 7.38 5.75 5.53 2.66 -1.59 -4.76 (-6.57)
1119 10.38 9.76 9.17 8.02 6.40 6.11 3.40 -0.58 -3.57 (-5.30)
1120 14.45 12.36 10.35 6.06 -1.05 -1.46 -14.76 -34.80 -49.87 (-58.49)
312
log K, P = P SAT for T (: 350°C; P = 500 b for T > 350°C

TEMPERATURE, °C
NAME INDEX
0 25 50 75 100 125 150 175

K-OXIDE 1123 90.98 84.14 78.35 73.41 69.14 65.42 62.15 59.25
NA-OXIDE 1124 73.13 67.47 62.72 58.69 55.22 52.23 49.61 47.30
AMORPH SIL 1125 -2.99 -2.71 -2.51 -2.34 -2.20 -2.08 -1.98 -1.89
A-CRIST 1126 -3.89 -3.45 -3.13 -2.88 -2.68 -2.51 -2.36 -2.24
B-CRIST 1127 -3.37 -3.01 -2.74 -2.54 -2.38 -2.24 -2.12 -2.01
CHALCED 1128 -4.21 -3.73 -3.38 -3.10 -2.88 -2.69 -2.53 -2.38
WAIR 1130 22.26 18.56 15.29 12.47 10.05 7.96 6.15 4.54
LAUM 1132 17.01 14.15 11.61 9.43 7.58 6.00 4.65 3.46
ACAN 1501 -39.70 -36.05 -33.01 -30.45 -28.25 -26.35 -24.70 -23.26
CP 1502 -36.79 -34.10 -31.97 -30.23 -28.80 -27.62 -26.65 -25.86
BN 1503 -113.19 -104.00 -96.48 -90.15 -84.78 -80.17 -76.20 -72.80
CC 1504 -38.08 -34.75 -31.98 -29.63 -27.60 -25.88 -24.38 -23.07
QTZ 1505 -4.50 -4.00 -3.63 -3.33 -3.10 -2.89 -2.72 -2.56
MG 1506 31.78 27.99 24.75 22.01 19.65 17.61 15.81 14.21
KALS 1507 12.93 11.26 9.83 8.61 7.58 6.69 5.92 5.24
FERROSIL 1508 8.36 7.42 6.56 5.82 5.17 4.61 4.12 3.67
PYROPH 1509 2.61 1.06 -0.39 -1.67 -2.78 -3.73 -4.57 -5.31
TALC 1510 24.06 21.56 19.24 17.21 15.46 13.94 12.63 11.47
7-A CL 1512 81.89 71.94 63.46 56.31 50.24 45.04 40.53 36.55
14-A CL 1513 78.30 68.57 60.27 53.26 47.32 42.22 37.80 33.90
CLNZ 1515 51.00 43.91 37.86 32.72 28.33 24.55 2l.26 18.33
LAWS 1516 26.47 22.70 19.48 16.77 14.47 12.50 10.80 9.29
TREM 1517 68.37 61.67 55.58 50.29 45.72 41.77 38.33 35.29
ANTH 1518 75.77 67.79 60.62 54.40 49.04 44.39 40.34 36.76
ZOIS 1519 51.05 43.96 37.90 32.75 28.36 24.58 2l.28 18.35
GROSS 1529 58.87 52.13 46.33 41.38 37.14 33.49 30.30 27.47
ANDRA 1530 55.64 50.47 45.91 41.98 38.59 35.65 33.07 30.78
ALB 1531 3.92 3.10 2.29 1.57 0.95 0.41 -0.05 -0.45
PREHN 1532 38.12 33.28 29.09 25.52 22.47 19.85 17.56 15.54
ENST 1537 12.82 11.47 10.27 9.23 8.34 7.57 6.89 6.29
PARG 1538 117.20 103.24 91.23 81.01 72.26 64.73 58.17 52.36
ANTIG 1542 539.15 483.97 435.83 394.88 360.04 330.21 304.38 281.71
HM 1544 20.06 17.65 15.60 13.85 12.34 11.03 9.88 8.85
ORD-EP 1545 48.25 42.05 36.70 32.l3 28.23 24.86 21.92 19.31
MARG 1551 50.19 42.17 35.42 29.73 24.89 20.74 17.12 13.90
MERCURY 1552 -22.14 -20.43 -18.96 -17.66 -16.49 -15.43 -14.47 -13.58
PO 1555 -3.67 -3.76 -3.92 -4.10 -4.30 -4.51 -4.75 -5.01
NESQ 1558 6.56 5.l3 4.98 4.90 4.83 4.76 4.69 4.60
EPID 1559 48.25 42.05 36.70 32.l3 28.23 24.86 21.91 19.29
HI-ALB 1560 5.41 4.42 3.46 2.61 1.88 1.24 0.70 0.22
 log K , P = P SAT for T :::;; 350·C ; P = 500 b for T > 350·C 313

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1123 56.66 54.34 52.24 48.57 45.32 42.84 40.08 37.25 34.91 (33.11)
1124 45.26 43.44 41.79 38.90 36.21 34.45 31.83 28.83 26.46 (24.82)
1125 -1.81 -1.74 -1.68 -1.60 -1.60 -1.46 -1.64 -1.96 -2.21 (-2.37)
1126 -2.12 -2.02 -1.93 -1.78 -1.70 -1.49 -1.58 -1.80 -1.95 (-1.99)
1127 -1.92 -1.83 -1.75 -1.63 -1.57 -1.37 -1.48 -1.71 -1.87 (-1.92)
1128 -2.26 -2.14 -2.04 -1.87 -1.78 -1.56 -1.64 -1.86 -1.99 (-2.03)
1130 3.08 1.72 0.37 -2.73 -8.87 -8.12 -20.89 -40.65 -55.35 (-63.46)
1132 2.38 1.37 0.35 -2.16 -7.78 -6.65 -18.97 -38.28 -52.55 (-60.26)
1501 -22.02 -20.96 -20.05 -18.74 -18.60 -17.12 -19.18 -23.17 -26.08 (-27.48)
1502 -25.25 -24.81 -24.56 -24.79 -27.50 -26.12 -33.78 -46.21 -55.60 (-60.89)
1503 -69.90 -67.48 -65.56 -63.47 -66.33 -61.86 -74.43 -96.10 -112.22 (-120.79)
1504 -21.92 -20.93 -20.08 -18.88 -18.92 -17.34 -19.77 -24.35 -27.69 (-29.31)
1505 -2.43 -2.30 -2.19 -2.01 -1.91 -1.68 -1.75 -1.96 -2.09 (-2.12)
1506 12.76 11.40 10.08 7.24 2.54 2.26 -6.58 -19.90 -29.94 (-35.71)
1507 4.62 4.04 3.47 2.13 -0.50 -0.23 -5.69 -14.14 -20.45 (-23.94)
1508 3.28 2.90 2.55 1.76 0.35 0.43 -2.36 -6.62 -9.80 (-11.58)
1509 -6.00 -6.67 -7.37 -9.26 -13.80 -12.70 -22.96 -39.13 -51.13 (-57.67)
1510 10.43 9.46 8.52 6.37 2.19 2.72 -5.97 -19.43 -29.42 (-34.90)
1515 15.68 13.19 10.76 5.31 -4.73 -4.30 -24.37 -55.14 -78.14 (-91.03)
1516 7.93 6.65 5.38 2.42 -3.50 -2.93 -15.23 -34.28 -48.46 (-56.28)
1517 32.56 30.03 27.59 22.24 12.52 13.20 -6.22 -36.01 -58.20 (-70.49)
1518 33.54 30.56 27.70 21.55 10.87 11.18 -9.62 -41.32 -64.97 (-78.18)
1519 15.70 13.21 10.78 5.32 -4.72 -4.29 -24.36 -55.13 -78.14 (-91.03)
1529 24.92 22.54 20.23 15.18 6.27 6.41 -11.00 -37.55 -57.42 (-68.59)
1530 28.71 26.78 24.92 20.90 13.99 14.00 0.67 -19.55 -34.70 (-43.24)
1531 -0.82 -1.17 -1.53 -2.52 -5.02 -4.24 -10.03 -19.21 -26.00 (-29.66)
1532 13.71 11.99 10.31 6.48 -0.81 -0.25 -15.11 -37.98 -55.05 (-64.54)
1537 5.75 5.25 4.78 3.79 2.17 2.12 -0.90 -5.46 -8.87 (-10.80)
1538 47.13 42.29 37.64 27.64 10.59 10.49 -22.23 -71.92 -109.09 (-130.02)
1542 261.41 242.72 224.76 185.78 116.53 118.62 -17.53 -225.72 -380.58 (-466.39)
1544 7.91 7.02 6.16 4.27 1.06 0.92 -5.20 -14.45 -21.43 (-25.43)
1545 16.94 14.72 12.54 7.67 -1.31 -0.90 -18.87 -46.43 -67.03 (-78.56)
1551 10.98 8.24 5.55 -0.53 -11.84 -11.35 -34.03 -68.83 -94.86 (-109.46)
1552 -12.77 -12.03 -11.35 -10.19 -9.49 -8.62 -9.12 -10.32 -11.09 (-11.28)
1555 -5.29 -5.61 -5.98 -7.03 -9.39 -9.23 -14.29 -22.12 -28.07 (-31.51)
1558 4.49 4.34 4.14 3.43 1.39 1.74 -3.00 -10.45 -16.05 (-19.20)
1559 16.62 14.69 12.51 7.63 -1.37 -0.97 -18.96 -46.53 -67.14 (-78.69)
1560 -0.21 -0.62 -1.04 -2.12 -4.70 -3.97 -9.80 -19.02 -25.84 (-29.52)
314 Log K, P = 1 kb

TEMPERATURE,OC
NAME INDEX
0 25 50 75 100 125 150 175

AND 1001 21.29 17.67 14.60 12.01 9.81 7.93 6.31 4.91
KYA 1002 20.81 17.26 14.26 11.73 9.58 7.75 6.17 4.80
SILL 1003 21.67 18.00 14.89 12.26 10.03 8.13 6.49 5.06
KAOL 1004 10.69 8.49 6.53 4.87 3.47 2.29 1.29 0.45
CHRYS 1007 35.62 32.30 29.25 26.63 24.40 22.50 20.86 19.45
MUSC 1012 19.85 16.28 13.11 10.41 8.13 6.20 4.55 3.15
PARAG 1013 24.33 20.22 16.62 13.55 10.97 8.78 6.93 5.34
PHLOG 1014 44.34 39.64 35.36 31.69 28.56 25.90 23.61 21.64
ANNITE 1015 35.50 31.47 27.87 24.76 22.10 19.83 17.88 16.20
DEHYD-ANAL 1021 14.81 13.09 11.49 10.09 8.90 7.88 7.00 6.24
ANAL 1022 9.44 8.21 7.03 6.01 5.14 4.41 3.79 3.28
SEPIO· 1023 34.27 32.26 29.90 27.76 25.92 24.37 23.07 21.98
LO-ALB 1025 4.72 4.13 3.37 2.65 2.02 1.49 1.03 0.65
MAX-MICRO 1027 1.22 1.09 0.72 0.32 -0.05 -0.37 -0.63 -0.86
K-SPAR 1028 1.23 1.09 0.72 0.32 -0.04 -0.35 -0.61 -0.83
HI-SAN 1029 2.61 2.30 l.77 1.24 0.76 0.35 -0.01 -0.30
ANOR 1030 33.37 28.72 24.68 21.23 18.28 15.76 13.58 11.68
NEPH 1031 16.98 14.88 13.07 11.54 10.25 9.15 8.21 7.41
WOLL 1035 15.17 14.02 12.94 11.99 11.17 10.45 9.83 9.28
DIOP 1039 23.52 21.56 19.67 18.01 16.56 15.31 14.23 13.28
CA-AL PYX 1040 43.38 37.73 32.95 28.91 25.48 22.55 20.01 17.79
AKER 1044 50.67 46.21 42.20 38.74 35.76 33.18 30.93 28.97
MERW 1045 76.16 69.43 63.51 58.43 54.06 50.29 47.01 44.13
MONTI 1046 33.42 30.35 27.63 25.30 23.30 21.57 20.07 18.76
GEHL 1047 66.07 58.34 51.81 46.29 4l.59 37.56 34.08 3l.03
FORST 1048 3l.85 28.65 25.80 23.37 21.27 19.47 17.91 16.54
FAY 1049 22.20 19.76 17.63 15.80 14.22 12.86 1l.68 10.65
HUNT 1050 15.23 12.40 9.85 7.60 5.60 3.80 2.15 0.63
ART 1053 22.38 20.28 18.47 16.96 15.68 14.60 13.66 12.84
HED 1054 22.01 20.15 18.38 16.81 15.44 14.26 13.23 12.33
MALACH 1059 3.50 3.50 3.44 3.38 3.33 3.29 3.26 3.22
AZUR 1060 5.90 5.76 5.51 5.28 5.07 4.86 4.66 4.46
HYDRO-MAG 1062 37.92 33.20 29.06 25.51 22.43 19.74 17.36 15.21
SMITH 1064 1.13 0.61 0.17 -0.23 -0.59 -0.91 -1.20 -1.48
ANH-CORD 1065 67.05 57.52 49.07 41.83 35.62 30.30 25.69 2l.67
HYD-CORD 1066 64.12 54.87 46.67 39.65 33.65 28.50 24.05 20.18
JADEITE 1067 10.50 9.32 8.18 7.18 6.33 5.61 5.00 4.48
CER 1068 -2.84 -2.67 -2.54 -2.42 -2.32 -2.23 -2.14 -2.07
STRONT 1069 -0.45 -0.57 -0.68 -0.79 -0.90 -1.02 -1.13 -1.26
DIS-DOL 1070 6.12 4.92 3.84 2.88 2.01 1.23 0.51 -0.16
 log K ,P = 1 kb 315

TEMPERATURE,OC
INDEX
200 225 250 300 350 400 450 500 550 600

1001 3.67 2.57 1.59 -0.18 -1.87 -3.81 -6.35 -9.88 -14.33 (-17.95)
1002 3.60 2.53 1.56 -0.16 -1.81 -3.71 -6.23 -9.74 -14.17 (-17.77)
1003 3.81 2.70 1.70 -0.09 -1.81 -3.75 -6.31 -9.85 -14.31 (-17.94)
1004 -0.28 -0.92 -1.48 -2.49 -3.54 -4.90 -6.96 -10.08 -14.17 (-17.46)
1007 18.23 17.l6 16.20 14.55 l3.04 11.39 9.28 6.40 2.79 (-0.11)
1012 1.94 0.88 -0.07 -1.76 -3.47 -5.67 -8.91 -l3.76 -20.11 (-25.21)
1Ol3 3.98 2.78 1.72 -0.16 -2.02 -4.34 -7.70 -12.67 -19.14 (-24.34)
1014 19.92 18.42 17.08 14.74 12.55 10.06 6.77 2.14 -3.73 (-8.44)
1015 14.74 l3.46 12.32 10.32 8.41 6.18 3.l3 -1.23 -6.82 (-11.31)
1021 5.59 5.02 4.52 3.64 2.82 1.86 0.54 -1.36 -3.80 (-5.75)
1022 2.84 2.47 2.15 1.60 1.06 0.35 -0.74 -2.42 -4.67 (-6.44)
1023 21.08 20.33 19.69 18.64 '17.66 16.37 14.36 11.17 6.89 (3.58)
1025 0.34 0.07 -0.16 -0.55 -0.97 -1.58 -2.60 -4.26 -6.52 (-8.28)
1027 -1.04 -1.19 -1.32 -1.55 -1.84 -2.34 -3.27 -4.82 -6.96 (-8.64)
1028 -1.02 -1.17 -1.30 -1.55 -1.85 -2.37 -3.32 -4.90 -7.05 (-8.76)
1029 -0.55 -0.77 -0.95 -1.28 -1.65 -2.22 -3.21 -4.82 -6.99 (-8.71)
1030 lO.oI 8.54 7.21 4.86 2.64 0.l7 -3.04 -7.43 -12.94 (-17.41)
1031 6.71 6.10 5.56 4.61 3.73 2.73 1.40 -0.49 -2.89 (-4.82)
1035 8.80 8.38 8.00 7.34 6.76 6.16 5.45 4.55 3.45 (2.57)
1039 12.46 , 11.73 11.08 9.94 8.91 7.81 6.42 4.57 2.26 (0.40)
1040 15.84 14.11 12.55 9.79 7.23 4.47 1.02 -3.55 -9.20 (-l3.81)
1044 27.24 25.71 24.34 21.95 19.83 17.71 15.28 12.24 8.62 (5.68)
1045 41.60 39.34 37.33 33.82 30.72 27.67 24.27 20.11 15.23 (I 1.24)
1046 17.61 16.59 15.67 14.07 12.65 11.22 9.57 7.50 5.04 (3.03)
1047 28.35 25.97 23.83 20.05 16.61 l3.00 8.66 3.03 -3.82 (-9.41)
1048 15.33 14.26 l3.30 11.63 10.l2 8.59 6.81 4.56 1.86 (-0.35)
1049 9.75 8.95 8.23 6.97 5.81 4.60 3.l0 1.13 -1.29 (-3.25)
1050 -0.81 -2.l8 -3.50 -6.15 -9.07 -12.75 -17.83 -24.94 -33.94 (-41.49)
1053 12.l2 11.47 10.88 9.80 8.70 7.38 5.57 3.01 -0.27 (-2.94)
1054 11.54 10.84 10.22 9.l3 8.l4 7.07 5.73 3.92 1.68 (-1.23)
1059 3.18 3.14 3.08 2.93 2.68 2.20 1.39 0.10 -1.62 (-3.05)
1060 4.25 4.04 3.81 3.27 2.55 1.47 -0.21 -2.73 -6.01 (-8.76)
1062 l3.25 11.43 9.72 6.44 2.97 -1.27 -7.05 -15.l5 -25.38 (-33.87)
1064 -1.75 -2.00 -2.26 -2.78 -3.39 -4.21 -5.40 -7.10 -9.29 (-11.12)
1065 18.14 15.01 12.19 7.20 2.50 -2.74 -9.51 -18.77 -30.38 (-39.80)
1066 16.79 l3.79 11.09 6.31 1.80 -3.26 -9.87 -18.98 -30.44 (-39.73)
1067 4.04 3.67 3.34 2.77 2.21 1.47 0.35 -1.37 -3.65 (-5.46)
1068 -2.01 -1.97 -1.94 -1.94 -2.07 -2.42 -3.11 -4.29 -5.90 (-7.23)
1069 -1.38 -1.51 -1.65 -1.98 -2.41 -3.04 -4.00 -5.44 -7.31 (-8.90)
1070 -0.79 -1.40 -2.00 -3.20 -4.56 -6.29 -8.71 -12.l3 -16.47 (-20.l2)
316 log K , P = 1 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

ORD-DOL 1071 4.37 3.37 2.46 1.64 0.90 0.23 -0.40 -0.98
ARAG 1072 2.76 2.32 1.92 1.56 1.24 0.94 0.66 0.40
CALC 1073 2.64 2.20 1.81 1.45 1.12 0.82 0.53 0.27
MAG 1074 3.54 2.81 2.15 1.57 1.06 0.60 0.18 -0.21
DOL 1075 4.37 3.37 2.46 1.64 0.90 0.23 -0.40 -0.98
SIDER 1076 0.84 0.26 -0.24 -0.69 -1.09 -1.45 -1.79 -2.11
ANHYD 1078 -3.20 -3.50 -3.85 -4.23 -4.63 -5.03 -5.44 -5.86
FLUORITE 1079 -9.53 -9.33 -9.24 -9.23 -9.27 -9.35 -9.47 -9.61
BARITE 1080 -9.59 -9.21 -8.98 -8.87 -8.84 -8.88 -8.97 -9.11
ANG 1081 -7.22 -7.05 -6.99 -6.99 -7.04 -7.13 -7.24 -7.37
CELEST 1082 -5.61 -5.67 -5.81 -6.00 -6.24 -6.51 -6.80 -7.11
ALUN 1083 6.26 2.67 -0.38 -3.03 -5.37 -7.45 -9.35 -11.10
WITH 1084 -2.66 -2.49 -2.35 -2.26 -2.20 -2.17 -2.17 -2.18
RHODO 1085 0.56 0.19 -0.15 -0.44 -0.71 -0.96 -1.18 -1.39
COV 1086 -26.25 -24.02 -22.20 -20.67 -19.38 -18.28 -17.32 -16.50
GALENA 1087 -15.70 -14.43 -13.37 -12.47 -11.70 -11.03 -10.44 -9.92
SL 1088 -11.46 -10.97 -10.57 -10.25 -9.99 -9.80 -9.64 -9.51
WURT 1089 -8.95 -8.67 -8.45 -8.28 -8.16 -8.08 -8.02 -7.99
M-CINN 1090 -41.33 -38.15 -35.47 -33.19 -31.22 -29.52 -28.02 -26.71
CINN 1091 -41.80 -38.55 -35.81 -33.48 -31.48 -29.73 -28.21 -26.86
ALA 1092 0.27 -0.13 -0.51 -0.85 -1.17' -1.47 -1.74 -2.01
PYRITE 1093 -25.99 -24.29 -22.93 -21.98 -21.01 -20.33 -19.81 -19.40
GOLD 1100 -27.34 -24.63 -22.31 -20.31 -18.56 -17.02 -15.65 -14.42
SILVER 1101 -10.47 -9.31 -8.29 -7.40 -6.61 -5.90 -5.26 -4.68
COPPER 1102 -5.11 -4.45 -3.90 -3.40 -2.94 -2.51 -2.12 -1.75
GRAPHITE 1103 -5.70 -5.05 -4.50 -4.04 -3.65 -3.33 -3.05 -2.82
HALITE 1106 1.72 1.75 1.76 1.75 1.72 1.67 1.62 1.55
SYLVITE 1107 0.79 1.05 1.25 1.38 1.47 1.52 1.54 1.53
COR 1108 26.60 22.29 18.75 15.81 13.32 11.21 9.39 7.80
PER 1109 24.08 21.67 19.63 17.90 16.42 15.14 14.03 13.06
LIME 1110 35.98 32.85 30.21 27.97 26.04 24.38 22.92 21.64
TO 1111 6.80 6.38 6.01 5.71 5.45 5.25 5.08 4.93
CUP 1112 -2.01 -1.52 -1.14 -0.78 -0.42 -0.06 0.28 0.61
FE-OXIDE 1113 15.53 13.79 12.33 11.11 10.06 9.16 8.37 7.92
GIBBS 1114 9.90 8.28 6.99 5.93 5.07 4.35 3.74 3.23
DIAS 1115 10.99 9.14 7.63 6.38 5.33 4.45 3.70 3.05
BOEH 1116 12.01 10.01 8.38 7.03 5.90 4.94 4.11 3.41
BRUC 1117 18.34 16.56 15.05 13.78 12.72 11.81 11.02 10.35
MANGAN 1119 20.05 18.11 16.46 15.08 13.90 12.90 12.03 11.28
SPINEL 1120 45.86 39.55 34.29 29.90 26.18 23.01 20.27 17.88
 log K ,P = 1 kb 317

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1071 -1.54 -2.09 -2.62 -3.72 -4.98 -6.64 -9.00 -12.36 -16.65 (-20.25)
1072 0.14 -0.10 -0.35 -0.85 -1.44 -2.21 -3.32 -4.90 -6.92 (-8.60
1073 0.01 -0.24 -0.49 -1.01 -1.60 -2.39 -3.50 -5.09 -7.12 (-8.82)
1074 -0.58 -0.93 -1.27 -1.94 -2.68 -3.62 -4.92 -6.74 -9.05 (-10.98)
1075 -1.54 -2.08 -2.62 -3.72 -4.98 -6.65 -9.00 -12.37 -16.67 (-20.27)
1076 -2.41 -2.70 -2.98 -3.58 -4.25 -5.12 -6.35 -8.10 -10.32 (-12.18)
1078 -6.28 -6.72 -7.16 -8.13 -9.27 -10.77 -12.86 -15.80 -19.51 (-22.65)
1079 -9.79 -10.00 -10.24 -10.83 -11.66 -12.92 -14.85 -17.73 -21.46 (-24.60)
1080 -9.29 -9.51 -9.76 -10.39 -11.25 -12.48 -14.30 -16.95 -20.34 (-23.22)
1081 -7.53 -7.71 -7.92 -8.44 -9.16 -10.26 -11.96 -14.50 -17.80 (-20.58)
1082 -7.44 -7.79 -8.16 -8.99 -10.01 -11.39 -13.37 -16.18 -19.75 (-22.77)
1083 -12.74 -14.31 -15.84 -18.92 -22.41 -26.96 -33.44 -42.71 -54.58 (-64.44)
1084 -2.21 -2.26 -2.33 -2.54 -2.86 -3.39 -4.25 -5.57 -7.30 (-8.75)
1085 -1.59 -1.79 -1.99 -2.41 -2.92 -3.64 -4.72 -6.31 -8.38 (-10.10)
1086 -15.79 -15.17 -14.64 -13.79 -13.23 -12.98 -13.13 -13.75 -14.80 (-15.66)
1087 -9.47 -9.08 -8.73 -8.19 -7.88 -7.85 -8.25 -9.18 -10.61 (-11.76)
1088 -9.42 -9.36 -9.33 -9.37 -9.59 -10.08 -10.99 -12.49 -14.51 (-16.19)
1089 -7.98 -7.99 -8.03 -8.18 -8.50 -9.07 -10.06 -11.61 -13.69 (-15.42)
1090 -25.16 -24.11 -23.16 -21.53 -20.22 -19.18 -18.41 -17.88 -17.48 (-16.92)
1091 -25.67 -24.62 -23.68 -22.12 -20.96 -20.24 -20.05 -20.50 -21.52 (-22.32)
1092 -2.26 -2.51 -2.75 -3.26 -3.87 -4.68 -5.86 -7.57 -9.76 (-11.60)
1093 -19.10 -18.89 -18.76 -18.75 -19.11 -19.99 -21.62 -24.22 -27.74 (-30.70)
1100 -13.31 -12.30 -11.39 -9.78 -8.40 -7.20 -6.14 -5.18 -4.32 (-3.55)
1101 -4.15 -3.65 -3.20 -2.38 -1.65 -1.01 -0.43 0.10 0.58 (1.03)
1102 -1.40 -1.07 -0.76 -0.19 0.32 0.78 1.19 1.55 1.87 (2.17)
1103 -2.62 -2.45 -2.31 -2.10 -1.97 -1.93 -1.98 -2.14 -2.41 (-2.64)
1106 1.47 1.39 1.29 1.06 0.74 0.26 -0.46 -1.53 -2.92 (-4.08)
1107 1.50 1.45 1.38 1.19 0.90 0.44 -0.25 -1.27 -2.59 (-3.71)
1108 6.41 5.16 4.04 2.05 0.16 -1.93 -4.60 -8.22 -12.72 (-16.39)
1109 12.20 11.44 10.75 9.55 8.49 7.47 6.36 5.06 3.57 (2.34)
1110 20.50 19.48 18.57 16.98 15.61 14.35 13.08 11.71 10.24 (9.00)
1111 4.82 4.72 4.63 4.49 4.36 4.22 4.02 3.74 3.37 (3.07)
1112 0.94 1.25 1.55 2.12 2.63 3.05 3.36 3.51 3.52 (3.59)
1113 7.08 6.54 6.06 5.20 4.44 3.67 2.80 1.70 0.42 (-0.62)
1114 2.79 2.41 2.07 1.46 0.85 0.10 -0.97 -2.54 -4.58 (-6.23)
1115 2.49 1.99 1.54 0.75 -0.01 -0.90 -2.08 -3.75 -5.88 (-7.60)
1116 2.79 2.24 1.75 0.88 0.05 -0.89 -2.13 -3.84 -6.00 (-7.75)
1117 9.75 9.23 8.76 7.95 7.23 6.50 5.66 4.59 3.31 (2.27)
1119 10.62 10.03 9.51 8.61 7.82 7.05 6.19 5.14 3.90 (2.90)
1120 15.77 13.90 12.22 9.23 6.47 3.50 -0.14 -4.94 -10.84 (-15.66)
318
log K ,P = 1 kb

TEMPERATURE, °C
NAME INDEX
0 25 50 75 100 125 150 175

K-OXIDE 1123 91.07 84.17 78.37 73.41 69.14 65.42 62.15 59.25
NA-OXIDE 1124 73.31 67.58 62.79 58.74 55.26 52.26 49.64 47.34
AMORPH SIL 1125 -2.85 -2.47 -2.23 -2.06 -1.92 -1.81 -1.71 -1.63
A-CRIST 1126 -3.81 -3.26 -2.91 -2.65 -2.45 -2.28 -2.14 -2.02
B-CRIST 1127 -3.26 -2.79 -2.50 -2.28 -2.12 -1.99 -1.87 -1.77
CHALCED 1128 -4.18 -3.59 -3.21 -2.92 -2.69 -2.50 -2.34 -2.20
WAIR 1130 24.02 20.57 17.34 14.50 12.06 9.96 8.16 6.60
LAUM 1132 18.50 15.91 13.42 1l.23 9.37 7.78 6.44 5.31
ACAN 1501 -39.42 -35.86 -32.85 -30.28 -28.08 -26.16 -24.49 -23.02
CP 1502 -35.95 -33.38 -31.29 -29.57 -28.13 -26.92 -25.90 -25.04
BN 1503 -111.52 -102.46 -95.04 -88.75 -83.37 -78.73 -74.68 -71.15
CC 1504 -37.68 -34.35 -31.61 -29.27 -27.24 -25.51 -24.00 -22.66
QTZ 1505 -4.48 -3.87 -3.46 -3.15 -2.91 -2.70 -2.53 -2.38
MG 1506 32.98 29.02 25.72 22.93 20.55 18.51 16.74 15.18
KALS 1507 13.59 11.94 10.49 9.27 8.22 7.34 6.58 5.93
FERROSIL 1508 8.69 7.81 6.98 6.24 5.59 5.03 4.54 4.11
PYROPH 1509 3.60 2.37 1.01 -0.24 -1.34 -2.28 -3.08 -3.76
TALC 1510 24.61 22.59 20.40 18.41 16.68 15.19 13.90 12.79
7-A CL 1512 83.77 74.07 65.61 58.44 52.38 47.22 42.79 38.96
14-A CL 1513 80.10 70.62 62.34 55.33 49.39 44.34 40.01 36.26
CLNZ 1515 52.94 45.96 39.91 34.75 30.36 26.61 23.38 20.59
LAWS 1516 27.42 23.74 20.54 17.83 15.54 13.60 11.95 10.53
TREM 1517 69.75 63.96 58.12 52.91 48.38 44.47 41.09 38.16
ANTH 1518 71.01 70.00 63.09 56.97 51.66 47.07 43.09 39.63
ZOIS 1519 52.99 46.00 39.94 34.78 30.39 26.63 23.41 20.61
GROSS 1529 60.47 53.88 48.09 43.14 38.92 35.29 32.16 29.45
ANDRA 1530 57.04 52.04 47.53 43.60 40.21 37.28 34.74 32.52
ALB 1531 4.72 4.13 3.37 2.65 2.02 1.49 1.03 0.65
PREHN 1532 39.70 35.01 30.84 27.26 24.21 21.60 19.36 17.42
ENST 1537 12.98 1l.75 10.59 9.57 8.68 7.91 7.25 6.67
PARG 1538 120.11 106.59 94.63 84.40 75.66 68.18 61.72 56.11
ANTIG 1542 546.89 496.05 448.89 408.27 373.63 344.06 318.71 296.84
HM 1544 20.87 18.36 16.26 14.48 12.96 11.65 10.51 9.52
ORD-EP 1545 50.10 44.01 38.66 34.08 30.18 26.83 23.94 21.44
MARG 1551 52.56 44.48 37.65 31.91 27.06 22.93 19.39 16.32
MERCURY 1552 -21.87 -20.20 -18.75 -17.46 -16.30 -15.25 -14.29 -13.41
PO 1555 -3.23 -3.41 -3.60 -3.78 -3.97 -4.16 -4.37 -4.58
NESQ 1558 6.86 5.40 5.22 5.13 5.06 5.01 4.95 4.90
EPID 1559 50.10 44.01 38.66 34.08 30.17 26.82 23.94 21.43
HI-ALB 1560 6.22 5.45 4.55 3.70 2.96 2.33 l.79 1.33
 log K ,P = 1 kb 319

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1123 56.67 54.36 52.27 48.66 45.64 43.05 40.78 38.74 36.86 (35.24)
1124 45.31 43.50 41.89 39.11 36.82 34.85 33.10 31.46 29.91 (28.60)
1125 -1.56 -1.50 -1.44 -1.36 -1.31 -1.29 -1.30 -1.35 -1.45 (-1.53)
1126 -1.91 -1.81 -1.72 -1.57 -1.44 -1.33 -1.25 -1.20 -1.19 (-1.16)
1127 -1.69 -1.61 -1.53 -1.40 -1.29 -1.20 -1.14 -1.11 -1.10 (-1.09)
1128 -2.08 -1.97 -1.86 -1.69 -1.54 -1.41 -1.32 -1.27 -1.24 (-1.20
1130 5.24 4.05 2.99 1.12 -0.67 -2.77 -5.66 -9.81 -15.14 (-19.40
1132 4.33 3.49 2.76 1.48 0.20 -1.44 -3.91 -7.67 -12.64 (-16.57)
1501 -21.74 -20.61 -19.61 -17.95 -16.69 -15.85 -15.45 -15.54 -16.09 (-16.50
1502 -24.32 -23.72 -23.23 -22.56 -22.34 -22.70 -23.88 -26.10 -29.27 (-31.95)
1503 -68.05 -65.35 -63.01 -59.25 -56.69 -55.49 -56.02 -58.68 -63.26 (-66.98)
1504 -21.47 -20.41 -19.47 -17.88 -16.68 -15.86 -15.51 -15.70 -16.37 (-16.88)
1505 -2.25 -2.13 -2.02 -1.82 -1.66 -1.53 -1.43 -1.37 -1.34 (-1.30)
1506 13.81 12.57 11.46 9.47 7.60 5.60 3.12 -0.12 -4.10 (-7.38)
1507 5.37 4.87 4.43 3.65 2.89 2.00 0.76 -1.02 -3.30 (-5.15)
1508 3.74 3.41 3.11 2.59 2.10 1.57 0.88 -0.06 -1.25 (-2.20
1509 -4.35 -4.86 -5.31 -6.13 -7.01 -8.25 -10.24 -13.34 -17.48 (-20.78)
1510 11.83 10.99 10.25 8.96 7.75 6.35 4.43 1.65 -1.93 (-4.78)
1512 35.62 32.68 30.05 25.44 21.16 16.43 10.35 2.04 -8.38 (-16.80)
1513 33.00 30.12 27.55 23.04 18.84 14.19 8.18 -0.08 -10.45 (-18.82)
1515 18.14 15.97 14.03 10.60 7.34 3.64 -1.23 -8.02 -16.59 (-23.52)
1516 9.30 8.22 7.26 5.57 3.93 1.97 ,-0.78 -4.75 -9.87 (-13.98)
1517 35.60 33.35 31.36 27.89 24.68 21.13 16.50 10.05 1.90 (-4.63)
1518 36.60 33.93 31.55 27.41 23.61 19.51 14.30 7.21 -1.64 (-8.76)
1519 18.16 15.99 14.05 10.61 7.35 3.65 -1.23 -8.02 -16.59 (-23.52)
1529 27.07 24.96 23.07 19.75 16.65 13.23 8.85 2.86 -4.62 (-10.68)
1530 30.56 28.83 27.27 24.53 21.99 19.23 15.76 11.10 5.32 (0.63)
1531 0.34 0.07 -0.16 -0.56 -0.98 -1.60 -2.65 -4.33 -6.60 (-8.40)
1532 15.73 14.24 12.91 10.56 8.32 5.74 2.26 -2.66 -8.93 (-13.99)
1537 6.16 5.71 5.30 4.60 3.96 3.29 2.47 1.40 0.09 (-0.98)
1538 51.20 46.86 42.98 36.19 29.94 23.20 14.74 3.37 -10.76 (-22.19)
1542 277.84 261.20 246.44 220.82 197.33 171.55 138.30 92.53 34.94 (-11.24)
1544 8.63 7.84 7.11 5.82 4.59 3.25 1.57 -0.66 -3.40 (-5.65)
1545 19.25 17.31 15.57 12.49 9.56 6.25 1.88 -4.19 -11.86 (-18.06)
1551 13.63 11.26 9.13 5.34 1.72 -2.42 -7.91 -15.58 -25.28 (-33.14)
1552 -12.59 -11.83 -11.13 -9.85 -8.75 -8.14 -7.72 -7.46 -7.36 (-7.20)
1555 -4.80 -5.02 -5.26 -5.76 -6.38 -7.23 -8.46 -10.23 -12.50 (-14.40
1558 4.85 4.79 4.71 4.51 4.16 3.57 2.58 1.03 -1.03 (-2.75)
1559 19.23 17.28 15.53 12.44 9.51 6.18 1.80 -4.29 -11.97 (-18.19)
1560 0.95 0.62 0.33 -0.15 -0.65 -1.33 -2.42 -4.14 -6.44 (-8.26)
320 Log K , P = 1.5 kb

TEMPERATURE, 'C
NAME INDEX
0 25 50 75 100 125 150 175

AND 1001 21.77 18.14 15.05 12.46 10.26 8.38 6.76 5.36
KYA 1002 2l.21 17.66 14.66 12.l2 9.98 8.15 6.58 5.21
SILL 1003 22.13 18.45 15.33 12.70 10.47 8.57 6.93 5.51
KAOL 1004 11.07 8.92 6.98 5.32 3.93 2.75 1.75 0.91
CHRYS 1007 35.66 32.52 29.50 26.90 24.68 22.79 21.16 19.76
MUSC 1012 20.47 16.97 13.83 11.13 8.85 6.92 5.29 3.89
PARAG 1013 24.96 20.92 17.34 14.28 11.70 9.52 7.67 6.09
PHLOG 1014 44.61 40.11 35.88 32.23 29.11 26.45 24.17 22.21
ANNITE 1015 36.05 32.14 28.56 25.46 22.80 20.53 18.58 16.90
DEHYD-ANAL 1021 15.20 13.55 11.96 10.56 9.36 8.33 7.45 6.69
ANAL 1022 9.75 8.59 7.43 6.41 5.54 4.80 4.18 3.66
SEPIO 1023 34.20 32.63 30.39 28.30 26.48 24.94 23.64 22.55
LO-ALB 1025 4.99 4.53 3.82 3.11 2.49 1.95 1.49 1.11
MAX-MICRO 1027 1.48 1.49 1.16 0.77 0.41 0.09 -0.18 -0.40
K-SPAR 1028 1.49 1.49 1.16 0.78 0.42 0.11 -0.16 -0.38
HI-SAN 1029 2.87 2.70 2.21 1.70 l.22 0.81 0.45 0.15
ANOR 1030 34.01 29.41 25.37 21.91 18.96 16.43 14.25 12.35
NEPH 1031 17.27 15.19 13.38 11.84 10.55 9.45 8.51 7.70
WOLL 1035 15.25 14.16 13.10 12.16 11.33 10.62 9.99 9.44
DIOP 1039 23.56 21.74 19.89 18.24 16.81 15.56 14.48 13.54
CA-AL PYX 1040 43.89 38.24 33.45 29.41 25.98 23.04 20.50 18.30
AKER 1044 50.89 46.56 42.58 39.13 36.15 33.57 31.33 29.37
MERW 1045 76.42 69.82 63.93 58.86 54.50 50.73 47.45 44.58
MONTI 1046 33.54 30.55 27.85 25.52 23.52 21.80 20.30 18.99
GEHL 1047 66.78 59.03 52.48 46.94 42.24 38.21 34.72 31.68
FORST 1048 31.89 28.79 25.97 23.54 21.45 19.66 18.10 16.74
FAY 1049 22.42 20.03 17.91 16.07 14.50 13.14 11.96 10.93
HUNT 1050 15.87 13.03 10.44 8.19 6.20 4.41 2.78 l.28
ART 1053 22.45 20.37 18.55 17.04 15.77 14.69 13.76 12.95
HED 1054 19.91 18.21 16.51 14.99 13.65 12.48 11.45 10.56
MALACH 1059 3.46 3.69 3.61 3.55 3.50 3.46 3.43 3.39
AZUR 1060 5.97 6.16 5.89 5.65 5.43 5.22 5.02 4.82
HYDRO-MAG 1062 38.50 33.80 29.61 26.06 22.99 20.32 17.95 15.83
SMITH 1064 1.11 0.60 0.l6 -0.23 -0.57 -0.88 -1.17 -1.43
ANH-CORD 1065 68.42 59.05 50.62 43.37 37.16 31.81 27.19 23.18
HYD-CORD 1066 65.40 56.32 48.15 41.12 35.11 29.95 25.49 21.63
JADEITE 1067 10.62 9.53 8.42 7.44 6.60 5.88 5.27 4.76
CER 1068 -2.61 -2.45 -2.33 -2.22 -2.12 -2.03 -1.95 -1.87
STRONT 1069 -0.20 -0.36 -0.49 -0.60 -0.72 -0.83 -0.95 -1.07
DIS-DOL 1070 6.47 5.25 4.15 3.18 2.32 1.55 0.84 0.18
 321
log K ,P = 1.5 kb

TEMPERATURE,OC
INDEX
200 225 250 300 350 400 450 500 550 600

1001 4.14 3.07 2.12 0.50 -0.92 -2.32 -3.90 -5.76 -7.73 (-9.06)
1002 4.03 2.98 2.06 0.49 -0.89 -2.26 -3.81 -5.64 -7.60 (-8.90
1003 4.27 3.19 2.22 0.58 -0.85 -2.28 -3.87 -5.73 -7.72 (-9.05)
1004 0.19 -0.42 -0.94 -1.82 -2.59 -3.43 -4.52 -5.94 -7.53 (-8.49)
1007 18.54 17.49 16.57 15.03 13.74 12.52 11.20 9.68 8.09 (7.07)
1012 2.70 1.67 0.79 -0.68 -1.97 -3.36 -5.10 -7.34 -9.83 (-11.35)
1013 4.74 3.59 2.59 0.94 -0.49 -1.99 -3.82 -6.14 -8.70 (-10.27)
1014 20.52 19.05 17.77 15.62 13.80 12.03 10.05 7.71 5.22 (3.63)
1015 15.45 14.20 13.11 11.28 9.72 8.17 6.39 4.24 1.92 (0.46)
1021 6.04 5.48 4.99 4.19 3.52 2.85 2.09 1.17 0.l8 (-0.42)
1022 3.22 2.86 2.56 2.08 1.69 1.28 0.75 0.03 -0.77 (-1.20
1023 21.66 20.92 20.32 19.41 18.71 18.00 17.07 15.78 14.33 (13.63)
1025 0.80 0.54 0.33 0.02 -0.24 -0.54 -0.99 -1.63 -2.38 (-2.75)
1027 -0.58 -0.72 -0.83 -0.99 -1.13 -1.34 -1.71 -2.29 -2.98 (-3.31)
1028 -0.56 -0.71 -0.82 -0.99 -1.14 -1.37 -1.76 -2.36 -3.07 (-3.43)
1029 -0.10 -0.30 -0.47 -0.72 -0.94 -1.22 -1.65 -2.28 -3.01 (-3.39)
1030 10.70 9.25 7.97 5.79 3.90 2.06 0.05 -2.29 -4.76 (-6.41)
1031 7.01 6.41 5.89 5.03 4.30 3.59 2.80 1.86 0.85 (0.22)
1035 8.97 8.55 8.17 7.54 7.02 6.54 6.05 5.53 5.01 (4.65)
1039 12.72 12.01 11.38 10.32 9.42 8.59 7.70 6.70 5.67 (4.99)
1040 16.37 14.67 13.16 10.57 8.35 6.22 3.95 1.40 -1.26 (-3.09)
1044 27.65 26.13 24.78 22.49 20.57 18.82 17.09 15.25 13.42 (12.13)
1045 42.05 39.82 37.84 34.46 31.62 29.06 26.54 23.94 21.37 (19.51)
1046 17.84 16.83 15.93 14.41 13.12 11.94 10.77 9.52 8.27 (7.39)
1047 29.01 26.67 24.58 21.01 17.96 15.09 12.11 8.86 5.52 (3.17)
1048 15.54 14.49 13.55 11.96 10.61 9.36 8.11 6.77 5.41 (4.46)
1049 10.03 9.24 8.54 7.35 6.34 5.38 4.38 3.28 2.13 (1.35)
1050 -0.10 -1.40 -2.63 -4.97 -7.33 -9.98 -13.18 -17.08 -21.34 (-24.49)
1053 12.25 11.62 11.06 10.09 9.20 8.26 7.16 5.83 4.37 (3.39)
1054 9.78 9.09 8.48 7.45 6.57 5.74 4.85 3.86 2.83 (2.14)
1059 3.36 3.33 3.30 3.20 3.05 2.80 2.39 1.80 1.10 (0.62)
1060 4.63 4.43 4.23 3.81 3.30 2.60 1.64 0.36 1.10 (2.16)
1062 13.92 12.17 10.57 7.63 4.80 1.73 -1.90 -6.30 -11.07 (-14.50)
1064 -1.68 -1.91 -2.14 -2.57 -3.04 -3.60 -4.30 -5.20 -6.20 (-6.93)
1065 19.67 16.59 13.87 9.23 5.22 1.32 -2.96 -7.90 -13.11 (-16.61)
1066 18.26 15.31 12.71 8.28 4.47 0.73 -3.39 -8.18 -13.26 (-16.63)
1067 4.33 3.97 3.67 3.18 2.78 2.35 1.80 1.06 0.23 (-0.22)
1068 -1.81 -1.75 -1.70 -1.64 -1.66 -1.78 -2.08 -2.56 -3.l5 (-3.54)
1069 -1.18 -1.30 -1.42 -1.68 -1.99 -2.40 -2.95 -3.68 -4.51 (-5.11)
1070 -0.43 -1.01 -1.56 -2.62 -3.70 -4.93 -6.44 -8.30 -10.34 (-11.84)
322 log K ,P = 1.5 kb

TEMPERATURE, °C
NAME INDEX
0 25 50 75 100 125 150 175

ORD-DOL 1071 4.73 3.71 2.77 1.95 1.21 0.54 -0.07 -0.65
ARAG 1072 2.96 2.50 2.09 1.73 1.40 l.l0 0.83 0.57
CALC 1073 2.87 2.40 1.99 1.63 1.30 1.00 0.72 0.45
MAG 1074 3.67 2.95 2.28 1.70 1.19 0.73 0.32 -0.06
DOL 1075 4.73 3.71 2.77 1.95 1.21 0.54 -0.07 -0.64
SIDER 1076 l.06 0.46 -0.05 -0.50 -0.90 -1.27 -1.60 -1.91
ANHYD 1078 -2.89 -3.20 -3.56 -3.95 -4.34 -4.74 -5.15 -5.55
FLUORITE 1079 -9.27 -9.05 -8.97 -8.96 -8.99 -9.07 -9.18 -9.31
BARITE 1080 -9.30 -8.94 -8.72 -8.61 -8.58 -8.61 -8.70 -8.83
ANG 1081 -6.93 -6.75 -6.70 -6.71 -6.76 -6.84 -6.94 -7.07
CELEST 1082 -5.29 -5.38 -5.53 -5.73 -5.97 -6.23 -6.51 -6.82
ALUN 1083 7.16 3.46 0.37 -2.29 -4.61 -6.68 -8.56 -10.28
WITH 1084 -2.42 -2.29 -2.17 -2.09 -2.03 -2.00 -1.99 -2.00
RHODO 1085 0.71 0.34 0.00 -0.30 -0.57 -0.81 -1.03 -1.23
COV 1086 -26.27 -23.92 -22.10 -20.57 -19.27 -18.16 -17.21 -16.38
GALENA 1087 -15.54 -14.26 -13.21 -12.31 -11.54 -10.86 -10.27 -9.75
SL 1088 -11.31 -10.81 -10.42 -10.10 -9.85 -9.64 -9.47 -9.34
WURT 1089 -8.80 -8.51 -8.30 -8.13 -8.01 -7.92 -7.86 -7.82
M-CINN 1090 -41.15 -37.96 -35.29 -33.01 -31.05 -29.34 -27.84 -26.52
CINN 1091 -41.64 -38.37 -35.64 -33.32 -31.31 -29.57 -28.04 -26.69
ALA 1092 0.35 -0.03 -0.41 -0.75 -1.06 -1.35 -1.62 -1.87
PYRITE 1093 -25.83 -24.15 -22.79 -21.70 -20.84 -20.15 -19.61 -19.18
GOLD 1100 -27.49 -24.77 -22.44 -20.43 -18.68 -17.13 -15.75 -14.52
SILVER 1101 -10.51 -9.34 -8.32 -7.43 -6.64 -5.93 -5.29 -4.70
COPPER 1102 -5.21 -4.42 -3.87 -3.37 -2.91 -2.49 -2.10 -1.73
GRAPHITE 1103 -5.69 -5.06 -4.51 -4.05 -3.66 -3.33 -3.05 -2.81
HALITE 1106 1.77 1.80 1.80 1.79 1.77 1.73 1.68 1.62
SYLVITE 1107 0.84 1.10 1.30 1.44 1.53 1.58 1.60 1.60
COR 1108 27.05 22.68 19.11 16.16 13.67 11.56 9.74 8.16
PER 1109 24.11 21.73 19.68 17.95 16.47 15.20 14.09 13.13
LIME 1110 36.07 32.94 30.30 28.05 26.12 24.45 23.00 21.72
TO 1111 6.74 6.45 6.08 5.77 5.52 5.31 5.14 4.99
CUP 1112 -2.12 -1.39 -1.02 -0.66 -0.30 0.05 0.38 0.71
FE-OXIDE 1113 15.65 13.90 12.44 11.21 10.16 9.26 8.47 7.79
GIBBS 1114 10.07 8.42 7.11 6.05 5.19 4.47 3.86 3.36
DIAS 1115 1l.l8 9.30 7.78 6.52 5.48 4.60 3.85 3.21
BOEH 1116 12.22 10.19 8.55 7.19 6.05 5.09 4.27 3.57
BRUC 1117 18.34 16.58 15.07 13.80 12.74 11.83 11.05 10.38
MANGAN 1119 20.09 18.16 16.52 15.14 13.96 12.96 12.09 11.34
SPINEL 1120 46.38 40.01 34.73 30.32 26.61 23.43 20.69 18.32
 323
log K , P = 1.5 kb

TEMPERATURE, °C
INDEX
200 225 250 300 350 400 450 500 550 600

1071 -1.18 -1.69 -2.18 -3.13 -4.12 -5.28 -6.72 -8.52 -10.52 (-11.97)
1072 0.32 0.09 -0.13 -0.57 -1.02 -1.56 -2.24 -3.08 -4.02 (-4.70)
1073 0.20 -0.03 -0.26 -0.71 -1.18 -1.72 -2.41 -3.26 -4.21 (-4.90)
1074 -0.41 -0.74 -1.06 -1.65 -2.25 -2.92 -3.74 -4.73 -5.82 (-6.62)
1075 -1.18 -1.69 -2.18 -3.13 -4.12 -5.28 -6.73 -8.54 -10.53 (-12.00)
1076 -2.21 -2.48 -2.75 -3.26 -3.79 -4.41 -5.17 -6.12 -7.16 (-7.93)
1078 -5.96 -6.37 -6.78 -7.62 -8.54 -9.63 -10.97 -12.62 -14.44 (-15.82)
1079 -9.47 -9.65 -9.84 -10.30 -10.89 -11.70 -12.82 -14.30 -15.97 (-17.20)
1080 -9.00 -9.19 -9.41 -9.92 -10.57 -11.41 -12.53 -13.96 -15.57 (-16.78)
1081 -7.21 -7.37 -7.54 -7.94 -8.45 -9.15 -10.13 -11.43 -12.91 (-13.99)
1082 -7.13 -7.45 -7.79 -8.49 -9.30 -10.28 -11.53 -13.08 -14.80 (-16.10)
1083 -11.87 -13.35 -14.75 -17.43 -20.17 -23.34 -27.28 -32.20 -37.63 (-41.52)
1084 -2.03 -2.07 -2.12 -2.26 -2.47 -2.79 -3.27 -3.92 -4.67 (-5.21)
1085 -1.42 -1.60 -1.78 -2.12 -2.49 -2.96 -3.58 -4.39 -5.30 (-5.94)
1086 -15.66 -15.03 -14.4 7 -13.57 -12.90 -12.47 -12.28 -12.32 -12.52 (-12.60)
1087 -9.29 -8.88 -8.51 -7.91 -7.46 -7.21 -7.18 -7.40 -7.76 (-7.92)
1088 -9.24 -9.16 -9.11 -9.06 -9.13 -9.36 -9.79 -10.45 -11.24 (-11.78)
1089 -7.80 -7.79 -7.80 -7.88 -8.04 -8.35 -8.85 -9.57 -10.42 (-11.01)
1090 -25.35 -24.30 -23.36 -21.77 -20.51 -19.58 -18.98 -18.70 -18.65 (-18.44)
1091 -25.49 -24.42 -23.46 -21.83 -20.54 -19.58 -18.96 -18.66 -18.59 (-18.37)
1092 -2.11 -2.34 -2.56 -2.99 -3.45 -3.99 -4.70 -5.59 -6.58 (-7.29)
1093 -18.85 -18.60 -18.43 -18.28 -18.40 -18.82 -19.64 -20.86 -22.34 (-23.41)
1100 -13.41 -12.40 -11.48 -9.87 -8.48 -7.29 -6.23 -5.29 -4.45 (-3.70)
1101 -4.17 -3.67 -3.22 -2.40 -1.68 -1.04 -0.46 0.06 0.54 (0.98)
1102 -1.38 -1.06 -0.75 -0.18 0.34 0.81 1.23 1.62 1.97 (2.32)
1103 -2.61 -2.44 -2.29 -2.06 -1.91 -1.81 -1.80 -1.82 -1.90 (-1.95)
1106 1.55 1.48 1.40 1.22 0.99 0.69 0.27 -0.28 -0.90 ( -1.36)
1107 1.58 1.54 1.49 1.35 1.14 0.84 0.43 -0.11 -0.73 (-1.19)
1108 6.78 5.57 4.49 2.64 1.03 -0.55 -2.27 -4.24 -6.32 (-7.76)
1109 12.27 11.52 10.84 9.68 8.70 7.81 6.96 6.10 5.25 (4.62)
1110 20.58 19.57 18.66 17.10 15.79 14.64 13.58 12.56 11.60 (10.84)
1111 4.87 4.77 4.69 4.56 4.46 4.36 4.26 4.13 3.99 (3.91)
1112 1.04 1.35 1.65 2.23 2.76 3.24 3.64 3.98 4.26 (4.59)
1113 7.19 6.65 6.18 5.36 4.66 4.03 3.39 2.72 2.04 (1.55)
1114 2.92 2.55 2.23 1.70 1.22 0.72 0.12 -0.65 -1.49 (-2.04)
1115 2.65 2.17 1.74 1.02 0.39 -0.23 -0.95 -1.80 -2.72 (-3.32)
1116 2.96 2.42 1.95 1.15 0.46 -0.22 -0.99 -1.88 -2.84 (-3.47)
1117 9.79 9.27 8.82 8.04 7.39 6.80 6.20 5.57 4.92 (4.48)
1119 10.69 10.11 9.60 8.73 8.01 7.37 6.74 6.08 5.44 (4.98)
1120 16.23 14.40 12.77 9.97 7.55 5.24 2.80 0.07 -2.75 (-4.73)
324 log K ,P = 1.5 kb

TEMPERATURE,OC
NAME INDEX
0 25 50 75 100 125 150 175

K-OXIDE 1123 91.05 84.15 78.34 73.39 69.12 65.40 62.13 59.23
NA-OXIDE 1124 73.33 67.59 62.79 58.74 55.26 52.26 49.64 47.35
AMORPH SIL 1125 -2.80 -2.36 -2.11 -1.94 -1.80 -1.69 -1.60 -1.52
A-CRIST 1126 -3.79 -3.18 -2.81 -2.55 -2.34 -2.18 -2.04 -1.92
B-CRIST 1127 -3.22 -2.70 -2.39 -2.17 -2.01 -1.87 -1.76 -1.67
CHALCED 1128 -4.19 -3.54 -3.14 -2.84 -2.61 -2.42 -2.26 -2.12
WAIR 1130 24.71 21.41 18.21 15.38 12.93 10.83 9.01 7.45
LAUM 1132 19.06 16.63 14.18 12.01 10.14 8.55 7.20 6.05
ACAN 1501 -39.42 -35.84 -32.81 -30.25 -28.03 -26.11 -24.43 -22.95
CP 1502 -35.77 -33.10 -31.02 -29.30 -27.86 -26.64 -25.61 -24.74
BN 1503 -111.57 -101.92 -94.51 -88.22 -82.83 -78.17 -74.11 -70.55
CC 1504 -37.79 -34.22 -31.48 -29.14 -27.11 -25.38 -23.86 -22.51
QTZ 1505 -4.49 -3.82 -3.39 -3.07 -2.82 -2.62 -2.45 -2.30
MG 1506 33.42 29.43 26.11 23.30 20.92 18.87 17.10 15.54
KALS 1507 13.84 12.21 10.77 9.54 8.50 7.61 6.86 6.21
FERROSIL 1508 8.78 7.96 7.14 6.41 5.76 5.20 4.71 4.29
PYROPH 1509 3.95 2.90 1.59 0.36 -0.72 -1.66 -2.46 -3.14
TALC 1510 24.62 22.90 20.79 18.84 17.13 15.64 14.36 13.26
7-A CL 1512 84.31 74.81 66.37 59.22 53.17 48.02 43.60 39.79
14-A CL 1513 80.59 71.33 63.07 56.08 50.16 45.12 40.80 37.07
CLNZ 1515 53.66 46.76 40.72 35.57 31.19 27.45 24.23 21.44
LAWS 1516 27.75 24.14 20.96 18.26 . 15.97 14.04 12.39 10.98
TREM 1517 69.87 64.66 58.98 53.84 49.35 . 45.46 42.09 39.17
ANTH 1518 77.05 70.66 63.91 57.87 52.60 48.03 44.06 40.62
ZOIS 1519 53.70 46.80 40.75 35.60 31.22 27.47 24.25 21.46
GROSS 1529 60.98 54.52 48.76 43.83 39.61 36.00 32.88 30.17
ANDRA 1530 57.42 52.59 48.11 44.20 40.82 37.90 35.36 33.15
ALB 1531 4.99 4.53 3.82 3.11 2.49 1.95 1.49 1.11
PREHN 1532 40.27 35.69 31.54 27.97 24.92 22.31 20.07 18.14
ENST 1537 12.98 11.83 10.69 9.68 8.80 8.04 7.37 6.80
PARG 1538 120.97 107.78 95.89 85.69 76.98 69.51 63.06 57.47
ANTIG 1542 547.33 499.46 452.93 412.64 378.20 348.75 323.48 301.73
HM 1544 21.17 18.64 16.52 14.73 13.21 11.90 10.76 9.76
ORD-EP 1545 50.74 44.76 39.44 34.87 30.97 27.62 24.74 22.25
MARG 1551 53.53 45.43 38.58 32.83 27.98 23.85 20.31 17.26
MERCURY 1552 -21.79 -20.11 -18.66 -17.38 -16.22 -15.18 -14.22 -13.34
PO 1555 -3.08 -3.28 -3.47 -3.65 -3.84 -4.02 -4.22 -4.43
NESQ 1558 6.96 5.49 5.30 5.21 5.15 5.09 5.04 5.00
EPID 1559 50.74 44.76 39.43 34.87 30.96 27.62 24.73 22.23
HI-ALB 1560 6.50 5.86 4.99 4.16 3.43 2.79 2.25 1.79
 log K ,P = 1.5 kb 325

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1123 56.65 54.34 52.26 48.66 45.66 43.10 40.89 38.95 37.23 (35.75)
1124 45.31 43.51 41.90 39.14 36.88 34.97 33.32 31.87 30.59 (29.53)
1125 -1.45 -1.39 -1.34 -1.26 -1.20 -1.17 -1.17 -1.19 -1.23 (-1.27)
1126 -1.81 -1.72 -1.63 -1.48 -1.34 -1.23 -1.13 -1.05 -0.98 (-0.90
1127 -1.58 -1.50 -1.43 -1.31 -1.19 -1.10 -1.02 -0.95 -0.90 (-0.83)
1128 -2.00 -1.89 -1.79 -1.61 -1.46 -1.33 -1.22 -1.13 -1.05 (-0.97)
1130 6.09 4.92 3.90 2.19 0.72 -0.74 -2.42 -4.46 -6.67 (-8.05)
1132 5.09 4.27 3.57 2.45 1.49 0.49 -0.79 -2.46 -4.33 (-5.39)
1501 -21.67 -20.52 -19.51 -17.79 -16.44 -15.42 -14.70 -14.26 -14.02 (-13.70)
1502 -24.00 -23.37 -22.83 -22.03 -21.56 -21.47 -21.82 -22.63 -23.73 (-24.47)
1503 -67.42 -64.66 -62.24 -58.23 -55.21 -53.18 -52.18 -52.22 -52.95 (-53.08)
1504 -21.32 -20.25 -19.29 -17.65 -16.34 -15.33 -14.62 -14.21 -13.99 (-13.67)
1505 -2.17 -2.05 -1.94 -1.75 -1.58 -1.44 -1.32 -1.23 -1.14 (-1.06)
1506 14.18 12.97 11.88 10.01 8.37 6.79 5.10 3.23 1.27 (-0.13)
1507 5.65 5.16 4.74 4.04 3.43 2.82 2.10 1.23 0.28 (-0.32)
1508 3.91 3.59 3.30 2.81 2.40 2.00 1.57 1.08 0.55 (0.20
1509 -3.71 -4.20 -4.61 -5.28 -5.88 -6.58 -7.54 -8.87 -10.39 (-11.26)
1510 12.31 11.49 10.78 9.61 8.64 7.68 6.59 5.26 3.82 (2.96)
1512 36.49 33.61 31.08 26.80 23.16 19.65 15.82 11.41 6.76 (3.68)
1513 33.84 31.02 28.55 24.38 20.83 17.39 13.62 9.27 4.68 (1.65)
1515 19.02 16.91 15.05 11.90 9.17 6.49 3.50 -0.02 -3.77 (-6.23)
1516 9.77 8.73 7.82 6.30 5.00 3.67 2.11 0.18 -1.91 (-3.22)
1517 36.64 34.43 32.51 29.30 26.61 24.04 21.22 17.94 14.47 (12.28)
1518 37.62 35.01 32.71 28.85 25.60 22.53 19.24 15.50 11.59 (9.05)
1519 19.04 16.92 15.06 11.91 9.18 6.50 3.50 -0.02 -3.77 (-6.23)
1529 27.82 25.76 23.94 20.86 18.22 15.67 12.90 9.72 6.37 (4.14)
1530 31.21 29.50 28.00 25.43 23.23 21.13 18.88 16.33 13.68 (11.89)
1531 0.80 0.54 0.33 0.01 -0.25 -0.57 -1.03 -1.70 -2.47 (-2.87)
1532 16.47 15.01 13.74 11.59 9.75 7.92 5.84 3.35 0.69 (-1.03)
1537 6.29 5.85 5.46 4.79 4.23 3.71 3.17 2.57 1.95 (1.54)
1538 52.61 48.35 44.60 38.25 32.86 27.75 22.29 16.12 9.70 (5.40)
1542 282.93 266.62 252.39 228.64 208.71 189.73 169.11 145.31 120.25 (104.14)
1544 8.89 8.11 7.41 6.19 5.12 4.08 2.95 1.68 0.35 (-0.59)
1545 20.80 18.18 16.51 13.68 11.24 8.83 6.15 2.99 -0.36 (-2.56)
1551 14.60 12.28 10.24 6.78 3.76 0.77 -2.59 -6.56 -10.81 (-13.62)
1552 -12.52 -11.76 -11.05 -9.77 -8.64 -7.97 -7.43 -6.98 -6.60 (-6.17)
1555 -4.63 -4.84 -5.04 -5.47 -5.94 -6.52 -7.26 -8.20 -9.24 (-10.00
1558 4.95 4.90 4.85 4.72 4.51 4.17 3.64 2.89 2.01 (1.38)
1559 20.06 18.16 16.48 13.64 11.18 8.76 6.06 2.90 -0.47 (-2.69)
1560 1.41 1.09 0.83 0.41 0.08 -0.29 -0.80 -1.51 -2.31 (-2.73)
326 Log K, P = 2 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

AND 1001 22.15 18.57 15.49 12.89 10.69 8.81 7.19 5.80
KYA 1002 21.52 18.03 15.04 12.50 10.36 8.53 6.96 5.61
SILL 1003 22.50 18.87 15.75 13.12 10.89 8.98 7.35 5.94
KAOL 1004 11.35 9.32 7.40 5.75 4.36 3.18 2.19 1.35
CHRYS 1007 35.52 32.64 29.68 27.10 24.89 23.00 21.38 19.99
MUSC 1012 20.90 17.59 14.49 1l.81 9.53 7.60 5.97 4.59
PARAG 1013 25.41 21.55 18.01 14.96 12.39 10.21 8.36 6.80
PHLOG 1014 44.63 40.45 36.29 32.66 29.57 26.92 24.65 22.70
ANNITE 1015 36.38 32.70 29.18 26.09 23.44 21.16 19.21 17.54
DEHYD-ANAL 1021 15.51 13.96 12.40 1l.00 9.80 8.76 7.88 7.12
ANAL 1022 9.97 8.92 7.79 6.78 5.90 5.16 4.54 4.02
SEPIO 1023 33.87 32.85 30.75 28.72 26.92 25.39 24.10 23.03
LO-ALB 1025 5.16 4.88 4.22 3.54 2.91 2.38 l.92 1.54
MAX-MICRO 1027 l.64 l.83 1.56 1.19 0.83 0.51 0.24 0.02
K-SPAR 1028 l.65 l.83 1.56 1.20 0.84 0.53 0.26 0.04
HI-SAN 1029 3.03 3.04 2.61 2.12 l.65 1.23 0.88 0.58
ANOR 1030 34.52 30.03 26.01 22.55 19.59 17.06 14.87 12.98
NEPH 1031 17.48 15.45 13.65 12.12 10.82 9.72 8.78 7.98
WOLL 1035 15.28 14.27 13.23 12.29 11.47 10.75 10.13 9.58
DIOP 1039 23.47 21.84 20.05 18.42 17.00 15.76 14.69 13.75
CA-AL PYX 1040 44.28 38.70 33.92 29.87 26.44 23.50 20.97 18.77
AKER 1044 50.95 46.82 42.89 39.45 36.47 33.90 3l.66 29.70
MERW 1045 76.48 70.10 64.26 59.21 54.85 5l.08 47.81 44.95
MONTI 1046 33.56 30.69 28.01 25.69 23.69 21.97 20.48 19.18
GEHL 1047 67.31 59.64 53.09 47.54 42.83 38.79 35.30 32.27
FORST 1048 3l.82 28.88 26.08 23.66 21.58 19.79 18.24 16.89
FAY 1049 22.55 20.26 18.15 16.32 14.75 13.39 12.21 11.19
HUNT 1050 16.28 13.57 10.97 8.71 6.72 4.95 3.35 l.88
ART 1053 22.42 20.42 18.61 17.10 15.83 14.76 13.84 13.04
HED 1054 22.17 20.58 18.89 17.35 16.00 14.82 13.79 12.90
MALACH 1059 3.20 3.84 3.77 3.70 3.65 3.61 3.58 3.55
AZUR 1060 5.70 6.50 6.23 5.98 5.76 5.54 5.35 5.15
HYDRO-MAG 1062 38.79 34.29 30.10 26.53 23.47 20.81 18.47 16.38
SMITH 1064 l.03 0.57 0.14 -0.23 -0.57 -0.86 -1.14 -1.39
ANH-CORD 1065 69.46 60.44 52.06 44.80 38.58 33.22 28.60 24.59
HYD-CORD 1066 66.36 57.62 49.51 42.48 36.46 31.29 26.83 22.98
JADEITE 1067 10.64 9.68 8.62 7.66 6.83 6.12 5.52 5.02
CER 1068 -2.46 -2.25 -2.14 -2.03 -l.94 -l.84 -1.76 -1.68
STRONT 1069 -0.00 -0.17 -0.31 -0.43 -0.55 -0.66 -0.78 -0.89
DIS-DOL 1070 6.71 5.54 4.43 3.46 2.60 l.83 1.13 0.49
 log K ,P = 2 kb 327

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1001 4.59 3.53 2.61 1.05 -0.25 -1.44 -2.65 -3.94 -5.14 (-5.68)
1002 4.43 3.41 2.51 1.00 -0.25 -1.41 -2.59 -3.85 -5.03 (-5.55)
1003 4.71 3.64 2.70 1.12 -0.19 -1.40 -2.63 -3.92 -5.13 (-5.68)
1004 0.64 0.05 -0.46 -1.27 -1.93 -2.56 -3.28 -4.13 -4.94 (-5.12)
1007 18.79 17.75 16.85 15.37 14.18 13.13 12.10 11.05 10.09 (9.71)
1012 3.41 2.41 1.56 0.18 -0.93 -1.98 -3.15 -4.51 -5.80 (-6.10)
1013 5.47 4.33 3.37 1.81 0.57 -0.59 -1.85 -3.27 -4.61 (-4.93)
1014 21.03 19.59 18.33 16.28 14.63 13.15 11.67 10.10 8.66 (8.15)
1015 16.11 14.87 13.80 12.05 10.64 9.37 8.06 6.65 5.35 (4.93)
1021 6.46 5.91 5.43 4.65 4.03 3.49 2.94 2.35 1.80 (1.65)
1022 3.59 3.23 2.93 2.48 2.15 1.86 1.53 1.14 0.78 (0.79)
1023 22.14 21.41 20.83 19.97 19.39 18.90 18.36 17.71 17.13 (l7 .30)
1025 1.23 0.98 0.77 0.49 0.30 0.12 -0.11 -0.41 -0.70 (-0.60)
1027 -0.16 -0.29 -0.40 -0.53 -0.61 -0.70 -0.86 -1.11 -1.35 (-1.24)
1028 -0.14 -0.28 -0.38 -0.53 -0.62 -0.73 -0.91 -1.18 -1.45 (-1.36)
1029 0.33 0.13 -0.03 -0.26 -0.42 -0.58 -0.80 -1.10 -1.39 (-1.31)
1030 11.34 9.91 8.65 6.54 4.79 3.21 1.64 -0.00 -1.52 (-2.21)
1031 7.30 6.70 6.19 5.36 4.70 4.11 3.53 2.90 2.34 (2.15)
1035 9.11 8.69 8.32 7.70 7.20 6.77 6.37 5.97 5.62 (5.45)
1039 12.94 12.24 11.62 10.59 9.76 9.03 8.34 7.63 6.99 (6.72)
1040 16.86 15.18 13.69 11.19 9.11 7.24 5.42 3.55 1.83 (0.95)
1044 27.99 26.48 25.15 22.91 21.07 19.47 17.99 16.57 15.29 (14.57)
1045 42.44 40.22 38.26 34.94 32.21 29.84 27.67 25.60 23.74 (22.62)
1046 18.04 17.03 16.15 14.65 13.42 12.35 11.36 10.39 9.53 (9.03)
1047 29.63 27.30 25.24 21.76 18.87 16.31 13.85 11.40 9.16 (7.93)
1048 15.71 14.67 13.75 12.19 10.91 9.79 8.73 7.70 6.77 (6.24)
1049 10.29 9.51 8.82 7.66 6.70 5.85 5.04 4.22 3.48 (3.10)
1050 0.54 -0.71 -1.89 -4.07 -6.17 -8.37 -10.85 -13.63 -16.39 (-18.01)
1053 12.35 11.74 11.20 10.28 9.48 8.71 7.88 6.96 6.07 (5.66)
1054 12.12 11.44 10.84 9.85 9.05 8.34 7.66 6.97 6.34 (6.07)
1059 3.52 3.50 3.47 3.41 3.31 3.15 2.89 2.54 2.16 (2.01)
1060 4.96 4.79 4.61 4.24 3.81 3.28 2.60 1.74 0.86 (0.38)
1062 14.51 12.82 11.28 8.51 5.97 3.40 0.59 -2.54 -5.59 (-7.28)
1064 -1.62 -1.83 -2.04 -2.43 -2.82 -3.26 -3.79 -4.40 -5.02 (-5.37)
1065 21.10 18.05 15.37 10.88 7.16 3.80 0.46 -3.02 -6.24 (-7.71)
1066 19.63 16.71 14.15 9.87 6.35 3.16 -0.03 -3.37 -6.46 (-7.80)
1067 4.60 4.25 3.96 3.51 3.18 2.88 2.54 2.14 1.76 (1.77)
1068 -1.61 -1.55 -1.49 -1.40 -1.36 -1.40 -1.54 -1.78 -2.05 (-2.11)
1069 -1.00 -1.11 -1.22 -1.45 -1.70 -2.01 -2.41 -2.90 -3.40 (-3.66)
1070 -0.10 -0.66 -1.18 -2.16 -3.12 -4.14 -5.29 -6.61 -7.92 (-8.68)
328 log K ,P = 2 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

ORD-DOL 1071 4.96 4.00 3.05 2.22 1.49 0.83 0.22 -0.34
ARAG 1072 3.10 2.65 2.24 1.88 1.55 1.25 0.98 0.73
CALC 1073 3.04 2.59 2.17 1.80 1.47 1.17 0.89 0.63
MAG 1074 3.74 3.06 2.39 1.82 1.31 0.86 0.45 0.08
DOL 1075 4.97 4.00 3.05 2.23 1.49 0.83 0.22 -0.33
SIDER 1076 1.24 0.65 0.13 -0.32 -0.73 -1.09 -1.42 -1.73
ANHYD 1078 -2.69 -2.94 -3.31 -3.70 -4.09 -4.49 -4.88 -5.28
FLUORITE 1079 -9.12 -8.79 -8.72 -8.71 -8.74 -8.81 -8.91 -9.03
BARITE 1080 -9.12 -8.72 -8.50 -8.39 -8.36 -8.39 -8.47 -8.59
ANG 1081 -6.76 -6.49 -6.44 -6.45 -6.50 -6.57 -6.67 -6.79
CELEST 1082 -5.09 -5.13 -5.28 -5.49 -5.72 -5.98 -6.26 -6.55
ALUN 1083 7.80 4.18 1.08 -1.58 -3.91 -5.97 -7.82 -9.50
WITH 1084 -2.25 -2.12 -2.01 -1.93 -1.87 -1.84 -1.83 -1.84
RHODO 1085 0.79 0.48 0.14 -0.17 -0.43 -0.66 -0.88 -1.08
COV 1086 -26.41 -23.84 -22.01 -20.48 -19.18 -18.06 -17.10 -16.27
GALENA 1087 -15.45 -14.11 -13.05 -12.16 -11.39 -10.71 -10.12 -9.59
SL 1088 -11.23 -10.68 -10.28 -9.96 -9.70 -9.49 -9.32 -9.18
WURT 1089 -8.72 -8.38 -8.16 -7.99 -7.87 -7.77 -7.71 -7.66
M-CINN 1090 -41.05 -37.79 -35.11 -32.84 -30.88 -29.17 -27.67 -26.34
CINN 1091 -41.55 -38.22 -35.49 -33.16 -31.16 -29.41 -27.88 -26.52
ALA 1092 0.36 0.05 -0.32 -0.66 -0.97 -1.25 -1.51 -1.75
PYRITE 1093 -25.77 -24.02 -22.65 -21.56 -20.69 -19.98 -19.42 -18.98
GOLD 1100 -27.67 -24.93 -22.59 -20.57 -18.80 -17.25 -15.87 -14.63
SILVER 1101 -10.59 -9.38 -8.36 -7.46 -6.67 -5.96 -5.32 -4.73
COPPER 1102 -5.40 -4.42 -3.86 -3.36 -2.90 -2.48 -2.09 -1.71
GRAPHITE 1103 -5.68 -5.06 -4.51 -4.05 -3.65 -3.32 -3.04 -2.80
HALITE 1106 1.78 1.83 1.84 1.84 1.82 1.78 1.74 1.69
SYLVITE 1107 0.87 1.15 1.35 1.49 1.58 1.64 1.67 1.68
COR 1108 27.43 23.04 19.47 16.50 14.00 11.89 10.07 8.50
PER 1109 24.09 21.76 19.71 17.98 16.51 15.24 14.13 13.17
LIME 1110 36.12 33.01 30.36 28.11 26.19 24.52 23.06 21.78
TO 1111 6.58 6.50 6.13 5.82 5.56 5.35 5.18 5.04
CUP 1112 -2.44 -1.31 -0.92 -0.56 -0.21 0.13 0.47 0.79
FE-OXIDE 1113 15.73 14.00 12.54 11.30 10.25 9.35 8.56 7.88
GIBBS 1114 10.20 8.55 7.23 6.17 5.30 4.58 3.98 3.48
DIAS 1115 11.34 9.45 7.92 6.67 5.62 4.74 3.99 3.35
BOEH 1116 12.39 10.36 8.71 7.34 6.21 5.25 4.43 3.73
BRUC 1117 18.29 16.58 15.07 13.81 12.74 11.84 11.06 10.39
MANGAN 1119 20.08 18.21 16.57 15.18 14.01 13.01 12.15 11.40
SPINEL 1120 46.77 40.43 35.14 30.72 26.99 23.82 21.09 18.72
 log K ,P = 2 kb 329

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1071 -0.86 -1.34 -1.80 -2.68 -3.54 -4.49 -5.58 -6.84 -8.10 (-8.81)
1072 0.49 0.27 0.06 -0.34 -0.74 -1.17 -1.68 -2.27 -2.87 (-3.20)
1073 0.39 0.16 -0.06 -0.47 -0.88 -1.33 -1.85 -2.45 -3.05 (-3.39)
1074 -0.26 -0.58 -0.88 -1.43 -1.96 -2.52 -3.15 -3.85 -4.56 (-4.96)
1075 -0.85 -1.34 -1.80 -2.68 -3.55 -4.49 -5.59 -6.85 -8.11 (-8.83)
1076 -2.01 -2.28 -2.53 -3.00 -3.47 -3.98 -4.56 -5.23 -5.90 (6.29)
1078 -5.67 -6.06 -6.45 -7.23 -8.05 -8.96 -10.02 -11.22 -12.44 (-13.21)
1079 -9.18 -9.33 -9.50 -9.90 -10.38 -10.99 -11.79 -12.79 -13.81 (-14.37)
1080 -8.74 -8.91 -9.11 -9.57 -10.11 -10.79 -11.63 -12.65 -13.69 (-14.32)
1081 -6.92 -7.06 -7.21 -7.55 -7.97 -8.50 -9.20 -10.07 -10.97 (-11.46)
1082 -6.85 -7.16 -7.47 -8.12 -8.82 -9.63 -10.59 -11.71 -12.84 (-13.55)
1083 -11.04 -12.47 -13.80 -16.28 -18.69 -21.27 -24.25 -27.66 -31.07 (-32.90)
1084 -1.86 -1.89 -1.93 -2.04 -2.20 -2.43 -2.76 -3.18 -3.62 (-3.85)
1085 -1.26 -1.43 -1.59 -1.89 -2.21 -2.57 -3.01 -3.54 -4.08 (-4.35)
1086 -15.54 -14.90 -14.33 -13.40 -12.69 -12.17 -11.85 -11.69 -11.62 (-11.42)
1087 -9.12 -8.70 -8.32 -7.68 -7.18 -6.83 -6.64 -6.60 -6.63 (-6.45)
1088 -9.07 -8.98 -8.91 -8.83 -8.83 -8.94 -9.18 -9.55 -9.96 (-10.10)
1089 -7.62 -7.61 -7.60 -7.64 -7.74 -7.93 -8.24 -8.68 -9.14 (-9.33)
1090 -25.16 -24.11 -23.16 -21.53 -20.22 -19.18 -18.41 -17.88 -17.48 (-16.92)
1091 -25.31 -24.23 -23.26 -21.60 -20.25 -19.19 -18.40 -17.85 -17.43 (-16.85)
1092 -1.98 -2.19 -2.39 -2.78 -3.17 -3.61 -4.12 -4.73 -5.34 (-5.66)
1093 -18.63 -18.35 -18.15 -17.92 -17.92 -18.15 -18.65 -19.39 -20.21 (-20.62)
1100 -13.52 -12.50 -11.58 -9.96 -8.57 -7.37 -6.32 -5.38 -4.55 (-3.80)
1101 -4.20 -3.70 -3.25 -2.43 -1.71 -1.07 -0.49 0.03 0.50 (0.94)
1102 -1.37 -1.05 -0.74 -0.17 0.35 0.82 1.25 1.64 2.01 (2.36)
1103 -2.59 -2.42 -2.26 -2.02 -1.85 -1.74 -1.68 -1.67 -1.68 (-1.67)
1106 1.63 1.56 1.49 1.34 1.16 0.93 0.63 0.26 -0.12 (-0.32)
1107 1.66 1.63 1.59 1.47 1.30 1.07 0.77 0.39 0.00 (-0.23)
1108 7.14 5.94 4.89 3.11 1.61 0.25 -1.11 -2.52 -3.84 (-4.50)
1109 12.32 11.57 10.90 9.76 8.82 7.99 7.24 6.53 5.89 (5.46)
1110 20.65 19.64 18.74 17.19 15.90 14.80 13.81 12.91 12.11 (11.52)
1111 4.92 4.82 4.74 4.61 4.52 4.45 4.37 4.30 4.23 (4.23)
1112 1.11 1.42 1.73 2.31 2.85 3.35 3.79 4.18 4.55 (4.96)
1113 7.28 6.75 6.28 5.48 4.81 4.23 3.68 3.15 2.66 (2.37)
1114 3.05 2.69 2.38 1.87 1.46 1.06 0.63 0.14 -0.33 (-0.50)
1115 2.80 2.33 1.92 1.23 0.66 0.14 -0.40 -0.97 -1.51 (-1.73)
1116 3.12 2.60 2.14 1.37 0.74 0.16 -0.43 -1.05 -1.62 (-1.88)
1117 9.81 9.30 8.85 8.10 7.48 6.94 6.44 5.95 5.50 (5.26)
1119 10.75 10.17 9.67 8.82 8.13 7.54 6.99 6.48 6.02 (5.74)
1120 16.66 14.85 13.24 10.53 8.27 6.23 4.25 2.23 0.37 (-0.63)
330 log K ,P = 2 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

K-OXIDE 1123 90.99 84.10 78.30 73.36 69.09 65.37 62.10 59.21
NA-OXIDE 1124 73.31 67.57 62.78 58.72 55.25 52.25 49.64 47.34
AMORPH SIL 1125 -2.77 -2.27 -2.00 -1.82 -1.68 -1.57 -1.48 -1.41
A-CRIST 1126 -3.79 -3.12 -2.73 -2.46 -2.25 -2.09 -1.95 -1.83
B-CRIST 1127 -3.20 -2.62 -2.29 -2.07 -1.90 -1.77 -1.66 -1.57
CHALCED 1128 -4.22 -3.51 -3.08 -2.77 -2.54 -2.35 -2.19 -2.05
WAIR 1130 25.23 22.17 19.02 16.20 13.75 11.63 9.81 8.24
LAUM 1132 19.46 17.27 14.88 12.72 10.85 9.26 7.90 6.76
ACAN 1501 -39.53 -35.85 -32.81 -30.23 -28.01 -26.09 -24.40 -22.91
CP 1502 -35.79 -32.87 -30.78 -29.05 -27.60 -26.38 -25.34 -24.45
BN 1503 -112.24 -101.51 -94.05 -87.76 -82.36 -77.68 -73.60 -70.02
CC 1504 -38.12 -34.13 -31.37 -29.03 -27.00 -25.26 -23.74 -22.40
QTZ 1505 -4.52 -3.78 -3.33 -3.00 -2.75 -2.55 -2.38 -2.23
MG 1506 33.72 29.79 26.45 23.64 21.25 19.20 17.42 15.87
KALS 1507 14.01 12.44 11.02 9.79 8.75 7.87 7.11 6.46
FERROSIL 1508 8.82 8.08 7.28 6.55 5.91 5.35 4.86 4.44
PYROPH 1509 4.16 3.36 2.13 0.93 -0.15 -1.08 -1.88 -2.55
TALC 1510 24.43 23.09 21.08 19.17 17.48 16.01 14.74 13.64
7-A CL 1512 84.48 75.38 67.00 59.87 53.83 48.69 44.29 40.51
14-A CL 1513 80.72 71.86 63.66 56.69 50.79 45.76 41.46 37.76
CLNZ 1515 54.13 47.45 41.46 36.32 31.95 28.21 25.00 22.23
LAWS 1516 27.93 24.47 21.32 18.64 16.36 14.44 12.80 11.40
TREM 1517 69.55 65.11 59.62 54.56 50.12 46.25 42.90 40.01
ANTH 1518 76.62 71.05 64.50 58.55 53.32 48.78 44.85 41.44
ZOIS 1519 54.17 47.49 41.49 36.35 31.97 28.23 25.02 22.25
GROSS 1529 61.26 55.03 49.34 44.43 40.22 36.61 33.51 30.82
ANDRA 1530 57.54 52.99 48.59 44.70 41.33 38.41 35.88 33.68
ALB 1531 5.16 4.88 4.22 3.54 2.91 2.38 1.92 1.54
PREHN 1532 40.64 36.27 32.17 28.62 25.57 22.96 20.72 18.80
ENST 1537 12.92 11.88 10.76 9.76 8.89 8.13 7.47 6.90
PARG 1538 121.33 108.72 96.95 86.80 78.10 70.65 64.23 58.68
ANTIG 1542 544.98 501.37 455.69 415.79 381.55 352.26 327.15 305.58
HM 1544 21.37 18.88 16.75 14.96 13.43 12.12 10.98 9.99
ORD-EP 1545 51.13 45.39 40.12 35.57 31.67 28.33 25.46 22.98
MARG 1551 54.28 46.30 39.46 33.70 28.84 24.71 21.18 18.14
MERCURY 1552 -21.76 -20.03 -18.59 -17.31 -16.15 -15.11 -14.15 -13.27
PO 1555 -3.00 -3.17 -3.35 -3.53 -3.71 -3.89 -4.08 -4.28
NESQ 1558 7.00 5.57 5.38 5.29 5.22 5.17 5.12 5.08
EPID 1559 51.13 45.39 40.12 35.57 31.67 28.32 25.45 22.97
HI-ALB 1560 6.67 6.21 5.40 4.59 3.86 3.22 2.68 2.22
 log K ,P = 2 kb 331

TEMPERATURE,OC
INDEX
200 225 250 300 350 400 450 500 550 600

1123 56.63 54.32 52.24 48.65 45.65 43.11 40.92 39.01 37.34 (35.91)
1124 45.32 43.51 41.90 39.16 36.91 35.02 33.42 32.03 30.83 (29.85)
1125 -1.34 -1.28 -1.24 -1.16 -1.11 -1.08 -1.07 -1.09 -1.11 (-1.14)
1126 -1.73 -1.63 -1.55 -1.40 -1.27 -1.15 -1.05 -0.96 -0.87 (-0.79)
1127 -1.48 -1.41 -1.34 -1.22 -1.11 -1.01 -0.93 -0.85 -0.78 (-0.70)
1128 -1.93 -1.82 -1.72 -1.54 -1.39 -1.26 -1.14 -1.04 -0.95 (-0.86)
1130 6.89 5.73 4.72 3.07 1.73 0.53 -0.71 -2.05 -3.29 (-3.69)
1132 5.79 4.98 4.30 3.23 2.41 1.65 0.81 -0.16 -1.07 (-1.16)
1501 -21.61 -20.46 -19.43 -17.68 -16.28 -15.19 -14.34 -13.71 -13.22 (-12.64)
1502 -23.69 -23.04 -22.48 -21.61 -21.02 -20.74 -20.77 -21.09 -21.52 (-21.60)
1503 -66.85 -64.05 -61.59 -57.45 -54.22 -51.83 -50.24 -49.37 -48.87 (-47.76)
1504 -21.19 -20.11 -19.14 -17.47 -16.11 -15.02 -14.17 -13.55 -13.05 (-12.45)
1505 -2.09 -1.98 -1.87 -1.68 -1.51 -1.37 -1.25 -1.14 -1.04 (-0.94)
1506 14.52 13.32 12.25 10.43 8.88 7.48 6.09 4.68 3.36 (2.60)
1507 5.91 5.44 5.02 4.35 3.81 3.31 2.79 2.22 1.69 (1.52)
1508 4.07 3.74 3.46 2.99 2.61 2.27 1.93 1.59 1.27 (1.14)
1509 -3.12 -3.59 -3.98 -4.60 -5.08 -5.55 -6.14 -6.87 -7.57 (-7.61)
1510 12.71 11.90 11.21 10.10 9.22 8.45 7.67 6.83 6.06 (5.87)
1512 37.24 34.40 31.92 27.80 24.44 21.43 18.45 15.36 12.52 (11.27)
1513 34.57 31.79 29.38 25.36 22.09 19.15 16.24 13.21 10.42 (9.22)
1515 19.84 17.76 15.94 12.91 10.42 8.16 5.88 3.47 1.23 (0.30)
1516 10.21 9.18 8.30 6.87 5.71 4.64 3.52 2.29 1.14 (0.79)
1517 37.50 35.34 33.45 30.37 27.89 25.72 23.59 21.38 19.37 (18.67)
1518 38.47 35.89 33.64 29.91 26.90 24.26 21.70 19.10 16.73 (15.76)
1519 19.85 17.77 15.95 12.92 10.43 8.17 5.88 3.47 1.23 (0.30)
1529 28.49 26.46 24.68 21.71 19.27 17.09 14.93 12.70 10.64 (9.73)
1530 31.76 30.08 28.60 26.11 24.06 22.23 20.44 18.61 16.93 (16.13)
1531 1.23 0.98 0.77 0.49 0.28 0.09 -0.15 -0.48 -0.79 (-0.71)
.1532 17.14 15.71 14.46 12.41 10.73 9.21 7.65 5.99 4.45 (3.88)
1537 6.40 5.96 5.58 4.93 4.41 3.95 3.51 3.07 2.68 (2.49)
1538 53.86 49.65 45.97 39.83 34.81 30.37 26.05 21.65 17.63 (15.78)
1542 287.00 270.94 257.Q1 234.12 215.75 199.57 183.73 167.36 152.43 (146.60)
1544 9.12 8.35 7.66 6.48 5.48 4.56 3.64 2.70 1.81 (1.31)
1545 20.83 18.97 17.33 14.61 12.37 10.34 8.29 6.13 4.13 (3.30)
1551 15.51 13.23 11.24 7.91 5.16 2.65 0.09 -2.63 -5.17 (-6.24)
1552 -12.46 -11.70 -10.99 -9.70 -8.56 -7.87 -7.29 -6.78 -6.30 (-5.79)
1555 -4.47 -4.66 -4.85 -5.24 -5.64 -6.11 -6.66 -7.31 -7.96 (-8.33)
1558 5.05 5.01 4.97 4.86 4.72 4.48 4.12 3.65 3.13 (2.89)
1559 20.81 18.94 17.30 14.57 12.31 10.27 8.21 6.03 4.01 (3.17)
1560 1.84 1.53 1.27 0.89 0.62 0.37 0.08 -0.29 -0.62 (-0.57)
332 log K, P = 2.5 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

AND 1001 22.47 18.95 15.89 13.29 11.08 9.20 7.59 6.20
KYA 1002 21.77 18.35 15.37 12.84 10.70 8.87 7.31 5.97
SILL 1003 22.80 19.24 16.14 13.51 11.27 9.37 7.74 6.33
KAOL 1004 11.56 9.66 7.78 6.14 4.75 3.58 2.59 1.75
CHRYS 1007 35.23 32.66 29.76 27.21 25.01 23.14 21.53 20.l5
MUSC 1012 21.20 18.10 15.07 12.41 10.83 8.22 6.59 5.22
PARAG 1013 25.71 22.07 18.59 15.57 13.00 10.83 8.99 7.44
PHLOG 1014 44.43 40.65 36.57 32.98 29.90 27.27 25.02 23.09
ANNITE 1015 36.52 33.15 29.70 26.63 23.99 21.72 19.77 18.11
DEHYD-ANAL 1021 15.73 14.31 12.79 11.41 10.20 9.16 8.27 7.51
ANAL 1022 10.11 9.20 8.11 7.11 6.24 5.50 4.88 4.36
SEPIO 1023 33.30 32.90 30.95 28.99 27.23 25.72 24.44 23.38
LO-ALB 1025 5.23 5.15 4.56 3.91 3.30 2.76 2.31 1.93
MAX-MICRO 1027 1.71 2.11 1.90 1.56 l.21 0.89 0.63 0.40
K-SPAR 1028 1.72 2.11 1.90 1.56 l.22 0.91 0.65 0.43
HI-SAN 1029 3.l0 3.32 2.96 2.49 2.03 1.61 l.26 0.96
ANOR 1030 34.91 30.57 26.58 23.13 20.17 17.63 15.44 13.56
NEPH 1031 17.63 15.67 13.90 12.37 11.08 9.97 9.04 8.24
WOLL 1035 15.26 14.34 13.33 12.40 11.58 10.87 10.24 9.70
DIOP 1039 23.28 21.88 20.13 18.54 17.13 15.90 14.84 13.91
CA-AL PYX 1040 44.57 39.08 34.32 30.28 26.84 23.91 21.38 19.19
AKER 1044 50.87 46.98 43.10 39.68 36.72 34.l5 31.91 29.97
MERW 1045 76.36 70.26 64.48 59.45 55.10 51.34 48.08 45.23
MONTI 1046 34.48 30.76 28.11 25.81 23.82 22.10 20.61 19.32
GEHL 1047 67.70 60.16 53.62 48.07 43.35 39.31 35.82 32.80
FORST 1048 31.65 28.89 26.l3 23.73 21.66 19.88 18.34 17.00
FAY 1049 22.60 20.43 18.36 16.54 14.96 13.60 12.43 11.41
HUNT 1050 16.49 14.00 11.41 9.15 7.17 5.41 3.83 2.40
ART 1053 22.31 20.43 18.62 17.12 15.86 14.79 13.88 13.09
HED 1054 22.09 20.70 19.06 17.55 16.20 15.03 14.01 13.12
MALACH 1059 2.72 3.94 3.88 3.82 3.77 3.73 3.70 3.68
AZUR 1060 5.11 6.76 6.52 6.27 6.04 5.83 5.63 5.45
HYDRO-MAG 1062 38.85 34.65 30.46 26.91 23.85 2l.21 18.89 16.84
SMITH 1064 0.89 0.52 0.11 -0.25 -0.57 -0.86 -1.12 -1.36
ANH-CORD 1065 70.25 61.63 53.33 46.09 39.86 34.49 29.87 25.87
HYD-CORD 1066 67.06 58.75 50.71 43.70 37.68 32.50 28.04 24.20
JADEITE 1067 10.59 9.79 8.78 7.85 7.03 6.33 5.74 5.25
CER 1068 -2.36 -2.07 -1.95 -1.85 -1.76 -1.67 -1.59 -1.51
STRONT 1069 1.47 0.01 -0.l5 -0.28 -0.40 -0.51 -0.62 -0.73
DIS-DOL 1070 6.85 5.78 4.67 3.70 2.85 2.08 1.39 0.76
 log K ,P = 2.5 kb 333

TEMPERATURE, 'c
INDEX
200 225 250 300 350 400 450 500 550 600

1001 5.00 3.96 3.05 1.53 0.30 -0.78 -1.82 -2.83 -3.66 (-3.83)
1002 4.80 3.80 2.91 1.45 0.27 -0.78 -1.78 -2.76 -3.57 (-3.72)
1003 5.11 4.06 3.13 1.60 0.35 -0.75 -1.79 -2.81 -3.65 (-3.29)
1004 1.06 0.47 -0.03 -0.80 -1.39 -1.92 -2.46 -3.04 -3.t8 (-3.29)
1007 18.97 17.94 17.06 15.62 14.48 13.52 12.65 11.82 11.16 (11.08)
1012 4.06 3.08 2.25 0.94 -0.07 -0.96 -1.85 -2.79 -3.50 (-3.23)
1013 6.12 5.01 4.07 2.58 1.41 0.45 -0.53 -1.52 -2.28 (-2.02)
1014 21.44 20.02 18.80 16.81 15.25 13.92 12.69 11.50 10.57 (10.55)
1015 16.69 15.46 14.41 12.71 11.38 10.25 9.17 8.12 7.30 (7.35)
1021 6.86 6.30 5.82 5.06 4.48 3.99 3.53 3.10 2.77 (2.83)
1022 3.92 3.57 3.28 2.84 2.54 2.30 2.07 1.83 1.68 (1.90)
1023 22.50 22.02 21.22 20.41 19.51 19.51 19.16 18.80 18.63 (19.21)
1025 1.62 1.37 1.18 0.91 0.75 0.63 0.51 0.36 0.30 (0.62)
1027 0.23 0.09 -0.00 -0.12 -0.17 -0.20 -0.26 -0.36 -0.39 (-0.06)
1028 0.25 0.11 0.01 -0.12 -0.18 -0.23 -0.31 -0.43 -0.49 (-0.18)
1029 0.72 0.52 0.37 0.16 0.03 -0.08 -0.20 -0.35 -0.43 (0.14)
1030 11.92 10.50 9.26 7.19 5.52 4.08 2.72 1.41 0.35 (0.11)
1031 7.56 6.97 6.47 5.66 5.03 4.51 4.02 3.55 3.19 (3.21)
1035 9.22 8.81 8.44 7.83 7.35 6.94 6.57 6.24 5.98 (5.88)
1039 13.11 12.42 11.81 10.81 10.01 9.34 8.74 8.17 7.73 (7.64)
1040 17.29 15.63 14.17 11.72 9.72 7.99 6.38 4.85 3.58 (3.15)
1044 28.26 26.77 25.45 23.23 21.44 19.93 18.58 17.35 16.34 (15.88)
1045 42.73 40.53 38.59 35.31 32.64 30.38 28.38 26.56 25.05 (24.27)
1046 18.19 17.19 16.31 14.84 13.65 12.63 11.73 10.90 10.21 (9.90)
1047 30.17 27.86 25.82 22.40 19.61 17.20 15.00 12.94 11.22 (10.5-l)
1048 15.82 14.79 13.89 12.36 11.12 10.06 9.11 8.24 7.51 (7.18)
1049 10.52 9.47 9.05 7.91 6.99 6.20 5.48 4.80 4.25 (4.06)
1050 1.09 -0.12 -1.24 -3.31 -5.25 -7.22 -9.32 -11.55 -13.58 (-14.47)
1053 12.41 11.82 11.30 10.41 9.67 8.98 8.28 7.57 6.96 (6.82)
1054 12.35 11.67 11.09 10.11 9.34 8.69 8.09 7.54 7.10 (7.01)
1059 3.66 3.64 3.62 3.58 3.51 3.40 3.22 2.98 2.76 (2.76)
1060 5.27 5.10 4.94 4.60 4.23 3.79 3.24 2.59 1.98 (1.78)
1062 15.01 13.36 11.87 9.22 6.85 4.55 2.15 -0.35 -2.57 (-3.43)
1064 -1.57 -1.77 -1.96 -2.32 -2.67 -3.04 -3.47 -3.94 -4.37 (-4.54)
1065 22.40 19.37 16.73 12.33 8.77 5.68 2.79 0.09 -2.26 (-2.79)
1066 20.87 17.97 15.45 11.26 7.90 4.98 2.24 -0.40 -2.54 (-2.95)
1067 4.83 4.49 4.21 3.80 3.50 3.27 3.03 2.79 2.64 (2.86)
1068 -1.43 -1.36 -1.29 -1.18 -1.11 -1.10 -1.17 -1.30 -1.41 (-1.31)
1069 -0.84 -0.94 -1.04 -1.25 -1.47 -1.73 -2.04 -2.41 -2.75 (-2.85)
1070 0.18 -0.35 -0.85 -1.78 -2.66 -3.56 -4.54 -5.59 -6.54 (-6.95)
334 log K , P = 2.5 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

ORD-DOL 1071 5.11 4.23 3.29 2.46 1.73 1.07 0.48 -0.07
ARAG 1072 3.20 2.79 2.37 2.01 1.68 1.39 1.12 0.87
CALC 1073 3.16 2.74 2.32 1.95 1.62 1.32 1.04 0.79
MAG 1074 3.77 3.15 2.48 1.91 1.40 0.95 0.55 0.19
DOL 1075 5.11 4.23 3.29 2.47 1.73 1.07 0.48 -0.06
SIDER 1076 1.37 0.81 0.30 -0.16 -0.56 -0.9.2 -1.25 -1.55
ANHYD 1078 -2.59 -2.74 -3.10 -3.49 -3.88 -4.27 -4.66 -5.04
FLUORITE 1079 -9.07 -8.57 -8.50 -8.49 -8.53 -8.59 -8.69 -8.80
BARITE 1080 -9.06 -8.57 -8.33 -8.22 -8.18 -8.20 -8.28 -8.38
ANG 1081 -6.69 -6.27 -6.21 -6.22 -6.27 -6.34 -6.44 -6.54
CELEST 1082 -4.97 -4.94 -5.09 -5.29 -5.52 -5.78 -6.05 -6.33
ALUN 1083 8.24 4.78 1.70 -0.96 -3.28 -5.33 -7.16 -8.81
WITH 1084 -2.14 -1.99 -1.87 -1.79 -1.74 -1.71 -1.69 -1.70
RHODO 1085 0.83 0.59 0.25 -0.04 -0.30 -0.54 -0.75 -0.94
COV 1086 -26.67 -23.78 -21.94 -20.40 -19.10 -17.98 -17.01 -16.17
GALENA 1087 -15.43 -13.98 -12.92 -12.02 -11.25 -10.57 -9.97 -9.44
SL 1088 -11.21 -10.57 -10.16 -9.83 -9.58 -9.36 -9.18 -9.04
WURT 1089 -8.70 -8.27 -8.04 -7.87 -7.74 -7.64 -7.57 -7.51
M-CINN 1090 -41.01 -37.64 -34.96 -32.69 -30.72 -29.01 -27.51 -26.18
CINN 1091 -41.53 -38.04 -35.35 -33.02 -31.01 -29.27 -27.72 -26.37
ALA 1092 0.31 0.10 -0.25 -0.59 -0.89 -1.16 -1.41 -1.65
PYRITE 1093 -25.78 -23.94 -22.54 -21.44 -20.55 -19.84 -19.26 -18.79
GOLD 1100 -27.86 -25.10 -22.74 -20.71 -18.93 -17.37 -15.98 -14.74
SILVER 1101 -10.71 -9.44 -8.41 -7.50 -6.71 -6.00 -5.35 -4.77
COPPER 1102 -5.69 -4.43 -3.86 -3.36 -2.90 -2.48 -2.08 -1.72
GRAPHITE 1103 -5.65 -5.05 -4.50 -4.03 -3.64 -3.30 -3.02 -2.77
HALITE 1106 1.76 1.84 1.87 1.87 1.86 1.83 1.79 1.75
SYLVITE 1107 0.85 1.17 1.38 1.53 1.63 1.70 1.73 1.75
COR 1108 27.75 23.38 19.79 16.81 14.31 12.19 10.38 8.82
PER 1109 24.04 21.76 19.72 17.99 16.52 15.25 14.15 13.20
LIME 1110 36.14 33.05 30.41 28.16 26.23 24.56 23.11 21.83
TO 1111 6.31 6.52 6.15 5.85 5.59 5.38 5.21 5.07
CUP 1112 -2.95 -1.26 -0.86 -0.50 -0.15 0.19 0.52 0.85
FE-OXIDE 1113 15.77 14.07 12.61 11.38 10.33 9.42 8.64 7.96
GIBBS 1114 10.31 8.66 7.34 6.28 5.41 4.69 4.09 3.59
DIAS 1115 11.47 9.59 8.06 6.80 5.75 4.87 4.12 3.49
BOEH 1116 12.54 10.51 8.85 7.49 6.35 5.39 4.57 3.87
BRUC 1117 18.21 16.55 15.05 13.79 12.73 11.83 11.05 10.39
MANGAN 1119 20.02 18.23 16.59 15.21 14.04 13.04 12.18 11.44
SPINEL 1120 47.06 40.79 35.49 31.06 27.33 24.16 21.44 19.08
 335
log K , P = 2.5 kb

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1071 -0.57 -1.04 -1.47 -2.29 -3.08 -3.91 -4.82 -5.82 -6.72 (-7.08)
1072 0.64 0.42 0.23 -0.15 -0.51 -0.90 -1.32 -1.79 -2.21 (-2.38)
1073 0.55 0.33 0.13 -0.26 -0.64 -1.04 -1.47 -1.95 -2.38 (-2.56)
1074 -0.14 -0.45 -0.73 -1.25 -1.74 -2.23 -2.76 -3.33 -3.84 (-4.07)
1075 -0.57 -1.03 -1.47 -2.29 -3.08 -3.91 -4.83 -5.83 -6.74 (-7.10)
1076 -1.83 -2.09 -2.33 -2.78 -3.21 -3.66 -4.16 -4.69 -5.18 (-5.39)
1078 -5.42 -5.80 -6.17 -6.90 -7.66 -8.48 -8.39 -10.37 -11.30 (-11.78)
1079 -8.92 -9.06 -9.21 -9.55 -9.97 -10.48 -11.12 -11.88 -12.58 (-12.83)
1080 -8.52 -8.68 -8.86 -9.27 -9.76 -10.34 -11.05 -11.85 -12.62 (-12.98)
1081 -6.66 -6.79 -6.92 -7.22 -7.58 -8.02 -8.58 -9.24 -9.86 (-10.07)
1082 -6.61 -6.90 -7.20 -7.80 -8.45 -9.16 -9.98 -10.88 -11.73 (-12.16)
1083 -10.31 -11.69 -12.96 -15.30 -17.51 -19.79 -22.28 -24.96 -27.38 (-28.25)
1084 -1.71 -1.73 -1.76 -1.85 -1.98 -2.17 -2.42 -2.73 -3.02 (-3.10)
1085 -1.11 -1.27 -1.42 -1.70 -1.97 -2.27 -2.63 -3.03 -3.39 (-3.48)
1086 -15.43 -14.78 -14.21 -13.25 -12.51 -11.95 -11.56 -11.30 -11.10 (-10.77)
1087 -8.96 -8.54 -8.15 -7.48 -6.95 -6.55 -6.28 -6.12 -5.97 (-5.63)
1088 -8.91 -8.81 -8.73 -8.62 -8.58 -8.63 -8.77 -9.00 -9.22 (-9.18)
1089 -7.47 -7.44 -7.43 -7.43 -7.49 -7.62 -7.83 -8.13 -8.40 (-8.41)
1090 -24.99 -23.92 -22.97 -21.32 -19.97 -18.88 -18.03 -17.38 -16.81 (-16.08)
1091 -25.15 -24.06 -23.08 -21.39 -20.19 -18.90 -18.24 -17.34 -16.76 (-16.02)
1092 -1.86 -2.06 -2.25 -2.61 -2.96 -3.33 -3.75 -4.21 -4.64 (-4.77)
1093 -18.42 -18.13 -17.90 -17.62 -17.54 -17.66 -18.00 -18.50 -19.00 (-19.10)
1100 -13.62 -12.60 -11.68 -10.05 -8.66 -7.45 -6.40 -5.46 -4.63 (-3.88)
1101 -4.23 -3.74 -3.28 -2.46 -1.74 -1.10 -0.53 -0.01 0.47 (0.90)
1102 -1.37 -1.05 -0.74 -0.17 0.35 0.82 1.25 1.65 2.02 (2.38)
1103 -2.56 -2.38 -2.23 -1.98 -1.80 -1.68 -1.60 -1.56 -1.55 (-1.50)
1106 1.70 1.64 1.58 1.45 1.29 1.10 0.86 0.59 0.33 (0.24)
1107 1.73 1.71 1.68 1.58 1.43 1.24 0.99 0.70 0.42 (0.29)
1108 7.47 6.29 5.25 3.51 2.09 0.84 -0.34 -1.49 -2.44 (-2.74)
1109 12.35 11.61 10.95 9.82 8.90 8.10 7.40 6.76 6.22 (5.89)
1110 20.70 19.69 18.80 17.26 15.98 14.90 13.96 13.11 12.39 (11.88)
1111 4.95 4.85 4.77 4.65 4.57 4.50 4.44 4.39 4.36 (4.49)
1112 1.17 1.48 1.78 2.37 2.91 3.42 3.88 4.30 4.71 (5.16)
1113 7.36 6.83 6.37 5.58 4.93 4.37 3.87 3.40 3.01 (2.81)
1114 3.17 2.81 2.51 2.03 1.64 1.30 0.95 0.59 0.30 (0.31)
1115 2.95 2.48 2.07 1.41 0.88 0.41 -0.04 -0.48 -0.84 (-0.88)
1116 3.27 2.75 2.30 1.56 0.96 0.43 -0.06 -0.55 -0.94 (-1.02)
1117 9.81 9.31 8.86 8.12 7.53 7..02 6.56 6.14 5.80 (5.64)
1119 10.79 10.22 9.72 8.89 8.22 7.65 7.15 6.70 6.33 (6.15)
1120 17.03 15.24 13.66 11.01 8.84 6.94 5.19 3.51 2.12 (1.57)
336 log K ,P = 2.5 kb

TEMPERATURE, DC
NAME INDEX
0 25 50 75 100 125 150 175

K-OXIDE 1123 90.89 84.03 78.25 73.31 69.04 65.33 62.06 59.17
NA-OXIDE 1124 73.23 67.52 62.74 58.70 55.23 52.24 49.63 47.34
AMORPH SIL 1125 -2.74 -2.19 -1.90 -1.71 -1.57 -1.47 -1.38 -1.30
A-CRIST 1126 -3.80 -3.07 -2.65 -2.37 -2.16 -2.00 -1.86 -1.75
B-CRIST 1127 -3.20 -2.55 -2.20 -1.97 -1.81 -1.67 -1.57 -1.47
CHALCED 1128 -4.26 -3.48 -3.03 -2.71 -2.47 -2.28 -2.12 -1.98
WAIR 1130 25.61 22.82 19.75 16.94 14.49 12.36 10.54 8.97
LAUM 1132 19.73 17.82 15.50 13.36 11.50 9.90 8.54 7.39
ACAN 1501 -39.73 -35.91 -32.84 -30.25 -28.02 -26.08 -24.38 -22.88
CP 1502 -35.98 -32.69 -30.58 -28.84 -27.39 -26.15 -25.10 -24.20
BN 1503 -113.50 -101.23 -93.70 -87.39 -81.97 -77.28 -73.18 -69.56
CC 1504 -38.67 -34.09 -31.31 -28.95 -26.92 -25.18 -23.65 -22.29
QTZ 1505 -4.56 -3.75 -3.28 -2.94 -2.69 -2.48 -2.31 -2.16
MG 1506 33.91 30.08 26.75 23.93 21.53 19.47 17.70 16.16
KALS 1507 14.13 12.63 11.23 10.02 8.98 8.09 7.34 6.70
FERROSIL 1508 8.81 8.16 7.39 6.68 6.04 5.48 5.00 4.57
PYROPH 1509 4.28 3.74 2.60 1.43 0.37 -0.56 -1.35 -2.02
TALC 1510 24.05 23.15 21.25 19.39 17.73 16.27 15.02 13.94
7-A CL 1512 84.36 75.75 67.45 60.36 54.33 49.21 44.83 41.08
14-A CL 1513 80.56 72.19 64.08 57.14 51.26 46.25 41.97 38.30
CLNZ 1515 54.42 48.00 42.08 36.97 32.60 28.87 25.67 22.93
LAWS 1516 28.01 24.72 21.63 18.96 16.70 14.78 13.15 11.76
TREM 1517 68.84 65.28 60.00 55.05 50.66 46.83 43.51 40.64
ANTH 1518 75.79 71.16 64.83 58.98 53.82 49.32 45.42 42.04
ZOIS 1519 54.45 48.04 42.11 36.99 32.62 28.89 25.69 22.94
GROSS 1529 61.33 55.41 49.79 44.91 40.72 37.13 34.04 31.37
ANDRA 1530 57.43 53.25 48.93 45.08 41.72 38.82 36.30 34.11
ALB 1531 5.23 5.15 4.56 3.91 3.30 2.76 2.31 1.93
PREHN 1532 40.84 36.73 32.70 29.17 26.12 23.52 21.29 19.38
ENST 1537 12.79 11.88 10.79 9.80 8.94 8.19 7.54 6.97
PARG 1538 121.26 109.36 97.75 87.66 79.00 71.58 65.19 59.67
ANTIG 1542 540.17 501.61 456.93 417.50 383.54 354.46 329.56 308.20
HM 1544 21.49 19.07 16.95 15.15 13.62 12.31 11.17 10.18
ORD-EP 1545 51.32 45.88 40.69 36.16 32.27 28.94 26.08 23.62
MARG 1551 54.86 47.05 40.24 34.49 29.62 25.49 21.97 18.94
MERCURY 1552 -21.77 -19.97 -18.52 -17.24 -16.09 -15.05 -14.10 -13.22
PO 1555 -2.97 -3.08 -3.25 -3.42 -3.60 -3.78 -3.96 -4.15
NESQ 1558 6.99 5.63 5.43 5.34 5.28 5.23 5.19 5.16
EPID 1559 51.32 45.88 40.68 36.15 32.26 28.93 26.07 23.60
HI-ALB 1560 6.75 6.49 5.75 4.96 4.24 3.61 3.07 2.61
 log K ,P = 2.5 kb 337

TEMPERATURE, °C
INDEX
200 225 250 300 350 400 450 500 550 600

1123 56.60 54.30 52.22 48.63 45.64 43.10 40.92 39.03 37.39 (35.97)
1124 45.31 43.51 4l.91 39.17 36.92 35.05 33.47 32.11 30.95 (30.01)
1125 -1.24 -1.19 -1.14 -l.07 -l.02 -l.00 -0.99 -l.00 -l.02 (-l.04)
1126 -l.64 -1.55 -l.47 -l.32 -1.19 -l.08 -0.97 -0.88 -0.79 (-0.70)
1127 -l.39 -l.32 -1.25 -1.13 -l.03 -0.93 -0.85 -0.77 -0.70 (-0.61)
1128 -l.86 -1.75 -l.66 -1.48 -l.33 -1.20 -l.08 -0.98 -0.88 (-0.78)
1130 7.67 6.46 5.46 3.84 2.58 1.49 0.46 -0.54 -l.32 (-l.27)
1132 6.43 5.63 4.96 3.92 3.16 2.52 l.89 1.25 0.79 (1.14)
1501 -21.58 -20.41 -19.37 -17.60 -16.17 -15.03 -14.12 -13.40 -12.78 (-12.08)
1502 -23.43 -22.76 -22.18 -21.25 -20.59 -20.20 -20.07 -20.15 -20.27 (-20.03)
1503 -66.37 -63.54 -6l.03 -56.80 -53.44 -50.85 -48.96 -47.65 -46.55 (-44.84)
1504 -2l.08 -20.00 -19.02 -17.33 -15.94 -14.80 -13.88 -13.16 -12.52 (-11.78)
1505 -2.03 -l.91 -l.81 -l.62 -1.45 -l.31 -1.19 -l.07 -0.97 (-0.86)
1506 14.81 13.62 12.56 10.78 9.29 7.97 6.74 5.55 4.53 (4.08)
1507 6.15 5.68 5.28 4.62 4.11 3.67 3.25 2.83 2.50 (2.52)
1508 4.21 3.89 3.61 3.15 2.78 2.47 2.18 l.90 l.69 (1.65)
1509 -2.57 -3.04 -3.42 -3.99 -4.41 -4.77 -5.18 -5.62 -5.94 (-5.59)
1510 13.01 12.23 11.55 10.48 9.66 8.99 8.36 7.75 7.30 (7.43)
1512 37.84 35.04 32.61 28.60 25.40 22.65 20.09 17.64 15.66 (15.27)
1513 35.14 32.41 30.04 26.14 23.02 20.36 17.86 15.48 13.55 (13.21)
1515 10.59 9.58 8.72 7.34 6.26 5.33 4.43 3.53 2.48 (2.93)
1516 10.59 9.58 8.72 7.34 6.26 5.33 4.43 3.53 2.84 (2.93)
1517 38.17 36.04 34.19 31.20 28.86 26.90 25.10 23.41 22.11 (22.09)
1518 39.11 36.57 34.36 30.74 27.87 25.46 23.26 21.20 19.58 (19.34)
1519 20.57 18.51 16.73 13.78 11.42 9.38 7.44 5.57 4.05 (3.83)
1529 29.06 27.07 25.31 22.42 20.10 18.10 16.24 14.47 13.04 (12.74)
1530 32.21 30.55 29.09 26.66 24.70 23.00 2l.44 19.96 18.75 (18.41)
1531 l.62 l.37 1.18 0.91 0.74 0.61 0.46 0.30 0.21 (0.51)
1532 17.74 16.32 15.10 13.10 11.52 10.15 8.85 7.59 6.58 (6.54)
1537 6.48 6.05 5.67 5.04 4.54 4.11 3.72 3.36 3.08 (2.99)
1538 54.89 50.74 47.12 41.12 36.32 32.32 28.47 24.93 22.07 (2l.36)
1542 289.84 274.03 260.38 238.15 220.72 206.01 192.52 179.75 169.69 (168.66)
1544 9.32 8.55 7.87 6.72 5.76 4.90 4.09 3.30 2.63 (2.34)
1545 2l.49 19.64 18.04 15.40 13.27 1l.44 9.70 8.02 6.66 (6.47)
1551 16.34 14.09 12.13 8.90 6.29 4.02 l.86 -0.26 -l.89 (-2.25)
1552 -12.40 -1l.64 -10.93 -9.64 -8.49 -7.80 -7.20 -6.66 -6.14 (-5.58)
1555 -4.33 -4.51 -4.69 -5.04 -5.41 -5.81 -6.26 -6.77 -7.24 (-7.42)
1558 5.12 5.09 5.06 4.98 4.87 4.69 4.42 4.07 3.74 (3.66)
1559 2l.47 19.62 18.01 15.35 13.22 1l.36 9.61 7.91 6.55 (6.34)
1560 2.24 l.93 l.68 l.31 l.07 0.88 0.69 0.49 0.38 (0.65)
338 Log K, P = 3 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

AND 1001 22.72 19.29 16.25 13.65 11.45 9.56 7.95 6.57
KYA 1002 21.95 18.63 15.67 13.15 11.01 9.19 7.63 6.29
SILL 1003 23.04 19.56 16.49 13.86 11.62 9.72 8.09 6.69
KAOL 1004 11.69 9.94 8.12 6.50 5.11 3.93 2.95 2.12
CHRYS 1007 34.80 32.58 29.74 27.22 25.05 23.19 21.60 20.24
MUSC 1012 21.36 18.52 15.57 12.94 10.68 8.77 7.15 5.78
PARAG 1013 25.88 22.49 19.10 16.11 13.56 11.39 9.56 8.01
PH LOG 1014 44.02 40.69 36.72 33.18 30.13 27.52 25.29 23.38
ANNITE 1015 36.47 33.47 30.12 27.09 24.45 22.19 20.25 18.60
DEHYD-ANAL 1021 15.88 14.61 13.14 1l.77 10.57 9.53 8.63 7.87
ANAL 1022 10.18 9.42 8.39 7.41 6.54 5.80 5.18 4.66
SEPIO 1023 32.49 32.78 31.01 29.12 27.41 25.92 24.66 23.61
LO-ALB 1025 5.21 5.36 4.86 4.23 3.64 3.11 2.66 2.28
MAX-MICRO 1027 1.69 2.31 2.19 1.88 1.54 1.23 0.97 0.75
K-SPAR 1028 l.70 2.31 2.19 1.88 1.55 1.25 0.99 0.77
HI-SAN 1029 3.08 3.53 3.25 2.81 2.36 1.95 1.60 1.30
AN OR 1030 35.18 31.03 27.08 23.64 20.68 18.14 15.95 14.07
NEPH 1031 17.71 15.85 14.11 12.59 11.30 10.20 9.27 8.47
WOLL 1035 15.19 14.38 13.39 12.48 11.66 10.95 10.33 9.79
DIOP 1039 22.98 21.83 20.16 18.59 17.20 15.98 14.93 14.02
CA-AL PYX 1040 44.76 39.40 34.67 30.63 27.20 24.26 2l.74 19.56
AKER 1044 50.64 47.05 43.23 39.83 36.88 34.32 32.10 30.16
MERW 1045 76.06 70.30 64.58 59.58 55.25 51.51 48.26 45.42
MONTI 1046 33.31 30.78 28.16 25.87 23.89 22.18 20.70 19.41
GEHL 1047 67.96 60.58 54.06 48.52 43.80 39.75 36.27 33.26
FORST 1048 31.39 28.84 26.11 23.73 21.68 19.91 18.38 17.05
FAY 1049 22.57 20.56 18.52 16.71 15.14 13.78 12.61 11.59
HUNT 1050 16.51 14.32 1l.76 9.51 7.54 5.80 4.23 2.83
ART 1053 22.11 20.38 18.59 17.10 15.84 14.78 13.88 13.11
RED 1054 21.92 20.75 19.18 17.69 16.36 15.19 14.18 13.30
MALACH 1059 2.04 3.99 3.96 3.91 3.86 3.83 3.80 3.78
AZUR 1060 4.20 6.96 6.75 6.51 6.28 6.07 5.87 5.70
HYDRO-MAG 1062 38.68 34.87 30.72 27.18 24.14 21.51 19.21 17.19
SMITH 1064 0.71 0.45 0.06 -0.28 -0.59 -0.87 -1.12 -1.34
ANH-CORD 1065 70.77 62.65 54.45 47.24 41.00 35.63 31.01 27.01
HYD-CORD 1066 67.51 59.69 5l.76 44.78 38.76 33.58 29.12 25.28
JADEITE 1067 10.46 9.83 8.90 8.00 7.20 6.51 5.93 5.44
CER 1068 -2.31 -1.91 -l.79 -1.69 -1.60 -1.51 -1.42 -1.34
STRONT 1069 0.25 0.12 -0.01 -0.14 -0.27 -0.38 -0.49 -0.59
DIS-DOL 1070 6.90 5.96 4.87 3.90 3.05 2.29 1.61 0.99
 log K ,P = 3 kb 339

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1001 5.38 4.34 3.44 1.96 0.77 -0.25 -1.18 -2.04 -2.66 (-2.64)
1002 5.14 4.14 3.27 1.84 0.70 -0.27 -1.17 -2.00 -2.60 (-2.55)
1003 5.48 4.43 3.52 2.01 0.81 -0.22 -1.16 -2.03 -2.67 (-2.65)
1004 1.43 0.85 0.36 -0.38 -0.94 -1.40 -1.85 -2.27 -2.51 (-2.12)
1007 19.06 18.06 17.19 15.78 14.69 13.79 13.00 12.30 11.81 (11.88)
1012 4.64 3.67 2.86 1.60 0.66 -0.13 -0.87 -1.57 -1.97 (-1.40)
1013 6.71 5.62 4.69 3.25 2.17 1.29 0.47 -0.28 -0.72 (-0.16)
1014 21.74 20.35 19.15 17.21 15.72 14.50 13.40 12.43 11.78 (12.03)
1015 17.18 15.97 14.93 13.27 12.00 10.94 9.99 9.14 8.59 (8.89)
1021 7.22 6.66 6.19 5.43 4.87 4.41 4.01 3.65 3.44 (3.61)
1022 4.23 3.87 3.58 3.16 2.88 2.67 2.49 2.33 2.30 (2.63)
1023 22.75 22.05 21.50 20.72 20.24 19.93 19.69 19.49 19.54 (20.33)
1025 1.97 1.73 1.54 1.28 1.14 1.06 0.99 0.93 0.99 (1.43)
1027 0.57 0.44 0.35 0.24 0.22 0.21 0.20 0.19 0.27 (0.71)
1028 0.59 0.46 0.36 0.25 0.20 0.18 0.15 0.12 0.18 (0.59)
1029 1.06 0.87 0.72 0.52 0.41 0.34 0.27 0.20 0.24 (0.64)
1030 12.44 11.02 9.79 7.76 6.15 4.78 3.54 2.42 1.60 (1.60)
1031 7.79 7.21 6.72 5.92 5.32 4.83 4.39 4.01 3.76 (3.89)
1035 9.32 8.90 8.54 7.94 7.46 7.07 6.72 6.43 6.21 (6.16)
1039 13.23 12.54 11.94 10.96 10.20 9.57 9.01 8.53 8.19 (8.21)
1040 17.67 16.02 14.58 12.17 10.23 8.58 7.10 5.75 4.73 (4.53)
1044 28.46 26.98 25.67 23.48 21.72 20.26 18.98 17.87 17.01 (16.69)
1045 42.94 40.75 38.82 35.58 32.96 30.77 28.86 27.19 25.88 (25.28)
1046 18.29 17.30 16.43 14.98 13.81 12.83 11.98 11.23 10.65 (10.43)
1047 30.63 28.34 26.32 22.95 20.22 17.90 15.85 14.00 12.57 (12.14)
1048 15.89 14.87 13.97 12.48 11.27 10.25 9.36 8.57 7.96 (7.75)
1049 10.70 9.93 9.25 8.13 7.23 6.47 5.80 5.20 4.75 (4.66)
1050 1.55 0.38 -0.70 -2.68 -4.51 -6.32 -8.20 -10.12 -11.73 (-12.23)
1053 12.44 11.86 11.35 10.50 9.80 9.16 8.54 7.94 7.48 (7.49)
1054 12.53 11.86 11.28 10.32 9.57 8.95 8.41 7.93 7.59 (7.59)
1059 3.76 3.75 3.74 3.71 3.67 3.59 3.45 3.28 3.14 (3.23)
1060 5.52 5.37 5.21 4.91 4.58 4.19 3.72 3.19 2.73 (2.68)
1062 15.39 13.78 12.33 9.79 7.54 5.41 3.26 1.12 -0.64 (-1.06)
1064 -1.54 -1.73 -1.91 -2.23 -2.55 -2.88 -3.24 -3.63 -3.96 (-4.02)
1065 23.55 20.54 17.92 13.59 10.13 7.20 4.56 2.17 0.42 (0.40)
1066 21.96 19.09 16.58 12.47 9.21 6.45 3.96 1.71 0.09 (0.18)
1067 5.04 4.70 4.43 4.04 3.77 3.58 3.40 3.25 3.22 (3.55)
1068 -1.26 -1.19 -1.12 -0.99 -0.90 -0.86 -0.88 -0.94 -0.98 (-0.79)
1069 -0.70 -0.79 -0.89 -1.07 -1.27 -1.50 -1.77 -2.07 -2.32 (-2.34)
1070 0.43 -0.09 -0.57 -1.45 -2.28 -3.11 -3.98 -4.88 -5.63 (-5.85)
340 log K ,P = 3 kb

TEMPERATURE, °C
NAME INDEX
0 25 50 75 100 125 150 175

ORD-DOL 1071 5.16 4.42 3.49 2.66 1.93 1.28 0.70 0.16
ARAG 1072 3.26 2.89 2.49 2.12 1.80 1.50 1.24 1.00
CALC 1073 3.25 2.87 2.46 2.09 1.75 1.45 1.18 0.93
MAG 1074 3.74 3.20 2.55 1.98 1.48 1.03 0.64 0.28
DOL 1075 5.16 4.42 3.49 2.67 1.94 1.28 0.70 0.17
SIDER 1076 1.46 0.96 0.45 -0.01 -0.41 -0.77 -1.10 -1.39
ANHYD 1078 -2.57 -2.59 -2.93 -3.31 -3.70 -4.09 -4.47 -4.85
FLUORITE 1079 -9.11 -8.39 -8.32 -8.31 -8.35 -8.41 -8.49 -8.59
BARITE 1080 -9.09 -8.47 -8.21 -8.09 -8.04 -8.06 -8.12 -8.22
ANG 1081 -6.73 -6.10 -6.02 -6.03 -6.08 -6.15 -6.24 -6.33
CELEST 1082 -4.95 -4.80 -4.93 -5.13 -5.36 -5.62 -5.88 -6.15
ALUN 1083 8.49 5.28 2.23 -0.42 -2.73 -4.77 -6.58 -8.20
WITH 1084 -2.08 -1.89 -1.76 -1.68 -1.62 -1.59 -1.57 -1.57
RHODO 1085 0.81 0.69 0.36 0.06 -0.20 -0.43 -0.63 -0.82
COV 1086 -27.04 -23.76 -21.89 -20.34 -19.03 -17.91 -16.94 -16.09
GALENA 1087 -15.47 -13.88 -12.80 -11.90 -11.12 -10.45 -9.84 -9.31
SL 1088 -11.25 -10.48 -10.06 -9.73 -9.47 -9.25 -9.06 -8.91
WURT 1089 -8.74 -8.18 -7.94 -7.76 -7.63 -7.53 -7.45 -7.39
M-CINN 1090 -41.04 -37.52 -34.82 -32.55 -30.58 -28.87 -27.37 -26.03
CINN 1091 -41.57 -37.98 -35.22 -32.89 -30.89 -29.14 -27.60 -26.23
ALA 1092 0.20 0.13 -0.20 -0.53 -0.82 -1.09 -1.33 -1.56
PYRITE 1093 -25.87 -23.88 -22.45 -21.33 -20.43 -19.70 -19.11 -18.64
GOLD 1100 -28.08 -25.29 -22.91 -20.86 -19.07 -17.50 -16.10 -14.85
SILVER 1101 -10.86 -9.52 -8.47 -7.57 -6.76 -6.05 -5.40 -4.81
COPPER 1102 -6.06 -4.45 -3.88 -3.37 -2.91 -2.49 -2.09 -1.73
GRAPHITE 1103 -5.61 -5.03 -4.47 -4.01 -3.61 -3.27 -2.98 -2.74
HALITE 1106 1.70 1.84 1.89 1.90 1.90 1.88 1.84 1.81
SYLVITE 1107 0.81 1.18 1.41 1.57 1.68 1.75 1.78 1.80
COR 1108 28.03 23.67 20.08 17.10 14.60 12.48 10.67 9.11
PER 1109 23.93 21.73 19.70 17.97 16.50 15.24 14.15 13.20
LIME 1110 36.11 33.07 30.43 28.18 26.25 24.59 23.13 21.86
TO 1111 5.95 6.52 6.16 5.86 5.61 5.40 5.23 5.09
CUP 1112 -3.65 -1.25 -0.84 -0.47 -0.12 0.22 0.56 0.88
FE-OXIDE 1113 15.78 14.13 12.68 11.44 10.39 9.48 8.70 8.02
GIBBS 1114 10.40 8.76 7.44 6.38 5.51 4.79 4.19 3.69
DIAS 1115 11.58 9.71 8.18 6.92 5.87 4.99 4.24 3.61
BOEH 1116 12.66 10.64 8.99 7.62 6.48 5.52 4.70 4.00
BRUC 1117 18.08 16.50 15.00 13.74 12.69 11.79 11.02 10.36
MANGAN 1119 19.92 18.23 16.60 15.23 14.06 13.06 12.20 11.46
SPINEL 1120 47.27 41.09 35.79 31.36 27.63 24.45 21.73 19.39
 341
log K ,P = 3 kb

TEMPERATURE, °C
INDEX
200 225 250 300 350 400 450 500 550 600

1071 -0.32 -0.78 -1.20 -1.97 -2.71 -3.46 -4.27 -5.10 -5.81 (-5.98)
1072 0.77 0.57 0.37 0.02 -0.32 -0.67 -1.05 -1.44 -1.77 (-1.85)
1073 0.70 0.49 0.29 -0.09 -0.44 -0.80 -1.19 -1.59 -1.93 (-2.02)
1074 -0.04 -0.33 -0.61 -1.10 -1.56 -2.01 -2.49 -2.97 -3.38 (-3.50)
1075 -0.32 -0.77 -1.19 -1.97 -2.71 -3.46 -4.27 -5.12 -5.83 (-6.00)
1076 -1.67 -1.92 -2.15 -2.58 -2.99 -3.40 -3.84 -4.30 -4.69 (-4.80)
1078 -5.22 -5.58 -5.93 -6.64 -7.35 -8.10 -8.93 -9.79 -10.55 ( -10.87)
1079 -8.71 -8.83 -8.97 -9.27 -9.63 -10.08 -10.63 -11.24 -11.77 (-11.85)
1080 -8.35 -8.49 -8.65 -9.03 -9.48 -10.00 -10.63 -11.31 -11.92 (-12.13)
1081 -6.44 -6.56 -6.68 -6.95 -7.26 -7.65 -8.13 -8.66 -9.13 (-9.19)
1082 -6.42 -6.70 -6.98 -7.55 -8.15 -8.81 -9.54 -10.32 -11.00 (-11.27)
1083 -9.67 -11.01 -12.24 -14.47 -16.55 -18.63 -20.83 -23.10 -24.98 (-25.32)
1084 -1.58 -1.60 -1.62 -1.69 -1.80 -1.96 -2.16 -2.41 -2.62 (-2.61)
1085 -0.98 -1.13 -1.27 -1.53 -1.78 -2.04 -2.34 -2.67 -2.93 (-2.92)
1086 -15.35 -14.69 -14.11 -13.13 -12.37 -11.78 -11.35 -1l.04 -10.76 (-10.36)
1087 -8.83 -8.39 -8.00 -7.31 -6.76 -6.32 -6.00 -5.77 -5.54 (-5.11)
1088 -8.78 -8.67 -8.58 -8.44 -8.38 -8.38 -8.47 -8.62 -8.73 (-8.59)
1089 -7.34 -7.30 -7.28 -7.26 -7.29 -7.38 -7.54 -7.75 -7.91 (-7.82)
1090 -24.84 -23.77 -22.80 -21.14 -19.76 -18.64 -17.74 -17.01 -16.35 (-15.54)
1091 -25.01 -23.91 -22.92 -21.22 -19.81 -18.66 -17.74· -16.99 -16.30 (-15.48)
1092 -1.76 -1.96 -2.13 -2.46 -2.78 -3.11 -3.48 -3.86 -4.18 (-4.21)
1093 -18.25 -17.94 -17.69 -17.36 -17.23 -17.28 -17.51 -17.88 -18.20 (-18.12)
1100 -13.73 -12.71 -11.78 -10.14 -8.75 -7.54 -6.48 -5.54 -4.71 (-3.96)
1101 -4.27 -3.78 -3.32 -2.50 -1.78 -1.14 -0.56 -0.04 0.43 (0.86)
1102 -1.38 -1.05 -0.75 -0.18 0.34 0.81 1.25 1.65 2.02 (2.39)
1103 -2.53 -2.34 -2.19 -1.94 -1.75 -1.62 -1.53 -1.48 -1.44 (-1.38)
1106 1.76 1.71 1.66 1.54 1.41 1.24 1.04 0.82 0.62 (0.60)
1107 1.80 1.79 1.76 1.67 1.54 1.37 1.16 0.91 0.69 (0.62)
1108 7.76 6.59 5.57 3.87 2.49 1.31 0.23 -0.76 -1.52 (-1.62)
1109 12.36 11.62 10.97 9.85 8.95 8.17 7.50 6.91 6.42 (6.15)
1110 20.73 19.73 18.83 17.30 16.04 14.98 14.05 13.24 12.56 (12.09)
1111 4.97 4.87 4.79 4.68 4.60 4.54 4.49 4.45 4.44 (4.49)
1112 1.20 1.51 1.82 2.40 2.95 3.46 3.94 4.37 4.80 (5.27)
1113 7.43 6.90 6.44 5.66 5.02 4.48 4.00 3.58 3.24 (3.08)
1114 3.27 2.92 2.63 2.16 1.80 1.49 1.19 0.90 0.70 (0.80)
1115 3.07 2.61 2.21 1.56 1.05 0.62 0.22 -0.14 -0.40 (-0.35)
1116 3.41 2.89 2.45 1.72 1.14 0.65 0.21 -0.20 -0.50 (-0.48)
1117 9.79 9.29 8.85 8.13 7.55 7.06 6.63 6.25 5.96 (5.85)
1119 10.82 10.26 9.76 8.94 8.28 7.73 7.26 6.85 6.52 (6.39)
1120 17.35 15.58 14.02 11.41 9.30 7.50 5.87 4.39 3.25 (2.95)
342 log K ,P = 3 kb

TEMPERATURE, °C
NAME INDEX
0 25 50 75 100 125 150 175

K-OXIDE 1123 90.74 83.93 78.17 73.24 68.99 65.28 62.02 59.l3
NA-OXIDE 1124 73.10 67.44 62.69 58.66 55.20 52.21 49.61 47.32
AMORPH SIL 1125 -2.74 -2.12 -1.81 -1.61 -1.48 -1.37 -l.28 -l.21
A-CRIST 1126 -3.82 -3.03 -2.59 -2.30 -2.09 -1.92 -1.79 -1.67
B-CRIST 1127 -3.21 -2.50 -2.13 -1.89 -1.72 -1.59 -1.48 -1.39
CHALCED 1128 -4.31 -3.47 -2.99 -2.66 -2.42 -2.22 -2.06 -1.93
WAIR 1130 25.85 23.37 20.38 17.60 15.15 13.03 11.19 9.62
LAUM ll32 19.86 18.26 16.04 l3.93 12.07 10.47 9.11 7.96
ACAN 1501 -40.02 -36.01 -32.90 -30.29 -28.05 -26.10 -24.39 -22.88
CP 1502 -36.33 -32.55 -30.40 -28.66 -27.19 -25.96 -24.90 -23.98
BN 1503 -115.36 -101.09 -93.46 -87.10 -81.67 -76.96 -72.84 -69.20
CC 1504 -39.42 -34.08 -3l.27 -28.91 -26.87 -25.12 -23.58 -22.22
QTZ 1505 -4.61 -3.74 -3.24 -2.89 -2.63 -2.42 -2.25 -2.10
MG 1506 33.99 30.31 26.99 24.16 21.76 19.71 17.93 16.39
KALS 1507 14.l8 12.78 ll.41 10.21 9.18 8.29 7.54 6.90
FERROSIL 1508 8.75 8.22 7.48 6.78 6.l4 5.59 5.ll 4.69
PYROPH 1509 4.28 4.03 3.00 1.87 0.82 -0.09 -0.88 -1.54
TALC 1510 23.49 23.09 21.30 19.51 17.87 16.44 15.20 14.14
7-A CL 1512 83.94 75.92 67.72 60.67 54.68 49.57 45.22 41.49
14-A CL 1513 80.09 72.32 64.31 57.43 51.57 46.58 42.33 38.69
CLNZ 1515 54.51 48.42 42.59 37.51 33.16 29.44 26.25 23.52
LAWS 1516 27.98 24.89 21.86 19.22 16.97 15.06 l3.44 12.07
TREM 1517 67.73 65.16 60.14 55.30 50.97 47.19 43.91 41.08
ANTH 1518 74.54 70.98 64.90 59.17 54.08 49.63 45.77 42.43
ZQIS 1519 54.55 48.45 42.61 37.53 33.18 29.45 26.27 23.53
GROSS 1529 6l.20 55.64 50.12 45.28 41.11 37.54 34.46 31.81
ANDRA 1530 57.08 53.35 49.l3 45.33 42.00 39.11 36.61 34.44
ALB 1531 5.21 5.36 4.86 4.23 3.64 3.11 2.66 2.28
PREHN 1532 40.88 37.08 33.l3 29.62 26.60 24,00 21.78 19.87
ENST 1537 12.62 11.85 10.79 9.82 8.97 8.22 7.58 7.02
PARG 1538 120.77 109.70 98.29 88.29 79.68 72.29 65.93 60.45
ANTIG 1542 532.89 500.18 456.65 417.78 384.17 355.36 330.68 309.55
HM 1544 21.54 19.22 17.ll 15.31 13.78 12.46 11.33 10.34
ORD-EP 1545 51.31 46.23 41.13 36.64 32.77 29.45 26.60 24.15
MARG 1551 55.28 47.69 40.93 35.19 30.32 26.19 22.67 19.66
MERCURY 1552 -21.82 -19.92 -18.47 -17.19 -16.04 -15.00 -14.05 -l3.17
PO 1555 -2.99 -3.01 -3.16 -3.33 -3.50 -3.67 -3.85 -4.03
NESQ 1558 6.94 5.66 5.47 5.38 5.32 5.27 5.24 5.21
EPID 1559 51.31 46.23 41.13 36.63 32.76 29.44 26.59 24.13
HI-ALB 1560 6.73 6.70 6.04 5.29 4.58 3.96 3.42 2.97
 log K ,P = 3 kb 343

TEMPERATURE, 'c
INDEX
200 225 250 300 350 400 450 500 550 600

1123 56.56 54.26 52.18 48.60 45.61 43.08 40.91 39.03 37.40 (36.00)
1124 45.30 43.51 41.90 39.17 36.93 35.07 33.50 32.16 31.02 (30.11)
1125 -1.15 -1.10 -1.06 -0.99 -0.94 -0.92 -0.91 -0.92 -0.94 (-0.96)
1126 -1.57 -1.48 -1.40 -1.25 -1.13 -1.01 -0.91 -0.82 -0.73 (-0.63)
1127 -1.31 -1.24 -1.17 -1.06 -0.96 -0.86 -0.78 -0.70 -0.62 (-0.54)
1128 -1.81 -1.70 -1.60 -1.43 -1.28 -1.15 -1.03 -0.92 -0.82 (-0.72)
1130 8.27 7.12 6.12 4.53 3.30 2.29 1.37 0.55 0.01 (0.30)
1132 7.00 6.20 5.54 4.52 3.80 3.23 2.71 2.25 2.03 (2.62)
1501 -21.57 -20.39 -19.34 -17.55 -16.10 -14.93 -13.98 -13.20 -12.51 (-11.74)
1502 -23.19 -22.51 -21.91 -20.94 -20.24 -19.78 -19.55 -19.49 -19.42 (-19.00
1503 -65.97 -63.11 -60.57 -56.26 -52.81 -50.09 -48.02 -46.45 -45.02 (-42.99)
1504 -21.00 -19.91 -18.92 -17.21 -15.80 -14.63 -13.68 -12.89 -12.18 (-11.36)
1505 -1.97 -1.85 -1.75 -1.56 -1.40 -1.26 -1.13 -1.02 -0.91 (-0.80)
1506 15.05 13.87 12.83 11.07 9.62 8.36 7.20 6.14 5.29 . (5.00)
1507 6.36 5.89 5.50 4.86 4.37 3.97 3.60 3.26 3.04 (3.17)
1508 4.32 4.00 3.73 3.27 2.92 2.62 2.36 2.13 1.96 (1.98)
1509 -2.09 -2.54 -2.91 -3.46 -3.83 -4.14 -4.44 -4.73 -4.83 (-4.28)
1510 13.23 12.46 11.80 10.76 9.99 9.37 8.83 8.36 8.09 (8.39)
1512 38.28 35.52 33.12 29.21 26.12 23.54 21.22 19.13 17.63 (17.69)
1513 35.56 32.86 30.53 26.73 23.73 21.22 18.98 16.96 15.51 (15.62)
1515 21.17 19.14 17.38 14.51 12.24 10.33 8.60 7.02 5.91 (6.07)
1516 10.90 9.91 9.07 7.74 6.72 5.87 5.09 4.38 3.93 (4.26)
1517 38.64 36.54 34.73 31.81 29.57 27.74 26.15 24.75 23.83 (24.19)
1518 39.54 37.04 34.87 31.33 28.57 26.31 24.32 22.58 21.37 (21.53)
1519 21.18 19.15 17.39 14.51 12.24 10.33 8.60 7.02 5.90 (6.06)
1529 29.52 27.54 25.82 22.99 20.75 18.88 17.20 15.68 14.59 (14.63)
1530 32.55 30.91 29.47 27.09 25.19 23.58 22.15 20.86 19.91 (19.83)
1531 1.97 1.73 1.54 1.28 1.13 1.03 0.95 0.87 0.90 (1.30
1532 18.24 16.84 15.63 13.68 12.16 10.89 9.74 8.70 7.98 (8.22)
1537 6.53 6.10 5.73 5.12 4.63 4.22 3.87 3.55 3.33 (3.29)
1538 55.71 51.61 48.03 42.16 37.51 33.63 30.20 27.14 24.92 (24.83)
1542 291.43 275.86 262.47 240.81 224.06 210.31 198.22 187.50 180.14 (181.68)
1544 9.48 8.72 8.05 6.92 5.98 5.16 4.41 3.71 3.16 (2.98)
1545 22.04 20.21 18.63 16.05 14.01 12.29 10.73 9.32 8.31 (8.46)
1551 17.07 14.84 12.91 9.75 7.24 5.12 3.18 1.40 0.13 (0.29)
1552 -12.35 -11.60 -10.89 -9.59 -8.44 -7.74 -7.13 -6.57 -6.03 (-5.45)
1555 -4.21 -4.38 -4.55 -4.87 -5.21 -5.57 -5.97 -6.40 -6.75 (-6.83)
1558 5.18 5.16 5.13 5.08 4.98 4.83 4.62 4.34 4.11 (4.13)
1559 22.02 20.19 18.60 16.01 13.95 12.22 10.65 9.22 8.20 (8.34)
1560 2.59 2.29 2.04 1.69 1.47 1.31 1.18 1.06 1.07 (1.45)
344 Log K , P = 3.5 kb

TEMPERATURE, °C
NAME INDEX
0 25 50 75 100 125 150 175

AND 1001 22.91 19.59 16.58 13.99 11.78 9.90 8.29 6.90
KYA 1002 22.07 18.86 15.94 13.43 11.29 9.47 7.92 6.58
SILL 1003 23.22 19.85 16.80 14.18 1l.95 10.04 8.41 7.01
KAOL 1004 11.75 10.18 8.41 6.81 5.43 4.26 3.27 2.45
CHRYS 1007 34.20 32.40 29.64 27.16 25.01 23.17 21.59 20.24
MUSC 1012 21.39 18.84 15.99 13.41 11.17 9.26 7.65 6.29
PARAG 1013 25.91 22.82 19.53 16.59 14.05 1l.89 10.07 8.53
PHLOG 1014 43.40 40.60 36.74 33.26 30.25 27.66 25.45 23.56
ANNITE 1015 36.23 33.67 30.44 27.46 24.84 22.59 20.66 19.01
DEHYD-ANAL 1021 15.94 14.85 13.44 12.10 10.90 9.86 8.97 8.20
ANAL 1022 10.l7 9.59 8.62 7.67 6.81 6.08 5.46 4.93
SEPIO 1023 3l.44 32.50 30.91 29.12 27.45 25.99 24.76 23.72
LO-ALB 1025 5.l0 5.51 5.09 4.51 3.93 3.41 2.97 2.59
MAX-MICRO 1027 1.58 2.46 2.42 2.15 l.83 1.53 1.27 l.05
K-SPAR 1028 1.59 2.46 2.42 2.16 l.85 1.55 1.29 l.07
HI-SAN 1029 2.98 3.67 3.49 3.09 2.65 2.25 l.90 l.61
ANOR 1030 35.34 3l.41 27.52 24.09 21.13 18.59 16.40 14.52
NEPH 1031 17.73 15.98 14.28 12.79 11.50 10.41 9.47 8.68
WOLL 1035 15.07 14.38 13.43 12.53 11.72 1l.01 10.39 9.86
DIOP 1039 22.58 21.72 20.11 18.58 17.21 16.01 14.97 14.07
CA-AL PYX 1040 44.84 39.65 34.95 30.93 27.51 24.57 22.05 19.88
AKER 1044 50.27 47.01 43.26 39.90 36.97 34.42 32.21 30.28
MERW 1045 75.58 70.22 64.58 59.62 55.31 51.58 48.34 45.52
MONTI 1046 33.05 30.73 28.15 25.88 23.91 22.21 20.74 19.46
GEHL 1047 68.08 60.91 54.44 48.90 44.18 40.14 36.66 33.65
FORST 1048 3l.02 28.73 26.04 23.68 2l.65 19.89 18.37 17.05
FAY 1049 22.45 20.64 18.64 16.85 15.28 13.93 12.76 1l.47
HUNT 1050 16.34 14.54 12.02 9.80 7.84 6.11 4.57 3.18
ART 1053 2l.82 20.30 18.52 17.04 15.80 14.74 13.85 13.08
HED 1054 2l.65 20.74 19.24 17.78 16.47 15.31 14.30 13.43
MALACH 1059 1.14 4.00 4.01 3.96 3.92 3.89 3.87 3.85
AZUR 1060 2.98 7.10 6.93 6.70 6.47 6.27 6.08 5.91
HYDRO-MAG 1062 38.27 34.98 30.88 27.35 24.33 2l.72 19.44 17.44
SMITH 1064 0.47 0.36 0.00 -0.33 -0.63 -0.89 -1.13 -1.34
ANH-CORD 1065 7l.04 63.49 55.42 48.25 42.02 36.65 32.02 28.02
HYD-CORD 1066 67.70 60.45 52.66 45.73 39.71 34.53 30.08 26.24
JADEITE 1067 10.26 9.83 8.97 8.11 7.33 6.65 6.08 5.60
CER 1068 -2.32 -1.76 -l.63 -1.53 -1.44 -1.36 -1.27 -1.19
STRONT 1069 0.32 0.24 0.10 -0.03 -0.15 -0.26 -0.37 -0.48
DIS-DOL 1070 6.86 6.10 5.03 4.07 3.22 2.47 1.79 1.18
 log K ,P = 3.5 kb 345

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1001 5.71 4.69 3.79 2.33 1.17 0.20 -0.67 -1.44 -1.94 (-1.81)
1002 5.43 4.44 3.59 2.18 1.07 0.14 -0.69 -1.43 -1.90 (-1.74)
1003 5.81 4.77 3.86 2.38 1.20 0.22 -0.66 -1.44 -1.95 (-1.82)
1004 1.76 1.18 0.71 -0.02 -0.55 -0.98 -1.36 -1.70 -1.82 (-1.32)
1007 19.08 18.09 17.24 15.86 14.80 13.95 13.22 12.60 12.21 (12.38)
1012 5.15 4.19 3.40 2.16 1.27 0.54 -0.10 -0.66 -0.87 (-0.12)
1013 7.24 6.15 5.24 3.83 2.80 1.98 1.26 0.65 0.41 (1.14)
1014 21.95 20.57 19.39 17.50 16.06 14.90 13.91 13.06 12.59 (12.99)
1015 17.60 16.40 15.37 13.74 12.50 11.50 10.63 9.89 9.50 (9.55)
1021 7.55 6.99 6.52 5.77 5.21 4.77 4.40 4.09 3.94 (4.17)
1022 4.50 4.15 3.86 3.44 3.17 2.98 2.83 2.72 2.75 (3.14)
1023 22.88 22.20 21.65 20.90 20.46 20.20 20.02 19.93 20.11 (21.02)
1025 2.29 2.05 1.86 1.61 1.49 1.42 1.39 1.38 1.51 (2.01)
1027 0.88 0.75 0.66 0.56 0.54 0.56 0.58 0.62 0.77 (1.27)
1028 0.90 0.77 0.67 0.56 0.53 0.53 0.53 0.55 0.67 (1.15)
1029 1.37 1.18 1.03 0.84 0.74 0.69 0.65 0.63 0.74 (1.19)
1030 12.90 11.49 10.26 8.26 6.67 5.35 4.19 3.18 2.51 (2.64)
1031 8.00 7.43 6.94 6.15 5.56 5.09 4.70 4.36 4.18 (4.37)
1035 9.38 8.97 8.61 8.02 7.55 7.16 6.83. 6.56 6.37 (6.34)
1039 13.29 12.61 12.02 11.06 10.32 9.71 9.20 8.77 8.50 (8.57)
1040 18.00 16.36 14.92 12.55 10.65 9.05 7.65 6.42 5.55 (5.49)
1044 28.59 27.12 25.82 23.65 21.92 20.49 19.27 18.23 17.45 (17.22)
1045 43.05 40.88 38.97 35.76 33.18 31.03 29.19 27.61 26.41 (25.93)
1046 18.34 17.36 16.50 15.07 13.92 12.97 12.15 11.45 10.93 (10.77)
1047 31.03 28.74 26.74 23.40 20.71 18.46 16.50 14.78 13.53 (13.26)
1048 15.90 14.89 14.01 12.54 11.35 10.37 9.52 8.79 8.25 (8.10)
1049 10.86 10.09 9.42 8.30 7.42 6.68 6.04 5.49 5.10 (5.07)
1050 1.93 0.78 -0.27 -2.17 -3.91 -5.61 -7.35 -9.07 -10A3 (-10.69)
1053 12.42 11.86 11.36 10.54 9.86 9.27 8.70 8.17 7.81 (7.89)
1054 12.67 12.00 11.43 10.49 9.75 9.15 8.64 8.21 7.93 (7.99)
1059 3.84 3.83 3.83 3.82 3.79 3.73 3.62 3.49 3.41 (3.54)
1060 5.75 5.59 5.45 5.16 4.86 4.51 4.09 3.63 3.27 (3.31)
1062 15.67 14.10 12.68 10.22 8.06 6.05 4.06 2.14 0.67 (0.52)
1064 -1.53 -1.71 -1.87 -2.17 -2.46 -2.76 -3.08 -3.42 -3.68 (-3.68)
1065 24.57 21.57 18.96 14.68 11.28 8.46 5.97 3.82 2.38 (2.64)
1066 22.92 20.06 17.57 13.51 10.31 7.65 5.32 3.30 1.99 (2.36)
1067 5.21 4.88 4.62 4.24 4.00 3.83 3.69 3.59 3.63 (4.03)
1068 -1.11 -1.03 -0.96 -0.82 -0.72 -0.66 -0.65 -0.67 -0.65 (-0.42)
1069 -0.57 -0.66 -0.75 -0.93 -1.11 -1.32 -1.56 -1.82 -2.01 (-1.98)
1070 0.63 0.13 -0.34 -1.19 -1.97 -2.75 -3.55 -4.35 -4.99 (-5.08)
346 log K ,P = 3.5 kb

TEMPERATURE, DC
NAME INDEX
0 25 50 75 100 125 150 175

ORD-DOL 1071 5.11 4.55 3.65 2.83 2.10 1.46 0.88 0.36
ARAG 1072 3.27 2.98 2.58 2.22 1.90 1.60 1.34 1.10
CALC 1073 3.29 2.98 2.58 2.21 1.87 1.57 1.30 1.05
MAG 1074 3.66 3.23 2.59 2.03 1.53 1.09 0.70 0.36
DOL 1075 5.12 4.55 3.65 2.83 2.11 1.46 0.88 0.36
SIDER 1076 1.51 1.09 0.59 0.14 -0.27 -0.63 -0.95 -1.25
ANHYD 1078 -2.64 -2.48 -2.80 -3.18 -3.57 -3.95 -4.33 -4.69
FLUORITE 1079 -9.24 -8.24 -8.17 -8.16 -8.20 -8.26 -8.33 -8.43
BARITE 1080 -9.23 -8.44 -8.14 -8.00 -7.95 -7.96 -8.01 -8.10
ANG 1081 -6.86 -5.98 -5.87 -5.87 -5.92 -5.99 -6.07 -6.16
CELEST 1082 -5.01 -4.71 -4.82 -5.01 -5.24 -5.49 -5.74 -6.01
ALUN 1083 8.53 5.66 2.68 0.05 -2.25 -4.28 -6.07 -7.68
WITH 1084 -2.09 -1.83 -1.68 -1.58 -1.52 -1.49 -1.47 -1.47
RHODO 1085 0.74 0.76 0.45 0.16 -0.10 -0.33 -0.53 -0.71
COV 1086 -27.53 -23.75 -21.86 -20.30 -18.98 -17.86 -16.88 -16.02
GALENA 1087 -15.57 -13.80 -12.70 -11.79 -11.01 -10.33 -9.73 -9.19
SL 1088 -11.35 -10.42 -9.97 -9.64 -9.37 -9.14 -8.96 -8.80
WURT 1089 -8.84 -8.12 -7.85 -7.67 -7.53 -7.42 -7.34 -7.27
M-CINN 1090 -41.13 -37.42 -34.70 -32.42 -30.46 -28.74 -27.24 -25.90
CINN 1091 -41.68 -37.90 -35.12 -32.78 -30.77 -29.02 -27.48 -26.11
ALA 1092 0.04 0.14 -0.17 -0.48 -0.77 -1.03 -1.27 -1.49
PYRITE 1093 -26.03 -23.85 -22.38 -21.24 -20.33 -19.59 -18.99 -18.50
GOLD 1100 -28.33 -25.48 -23.08 -21.01 -19.21 -17.63 -16.23 -14.97
SILVER 1101 -11.05 -9.62 -8.55 -7.64 -6.83 -6.11 -5.46 -4.87
COPPER 1102 -6.53 -4.50 -3.91 -3.39 -2.93 -2.51 -2.11 -1.74
GRAPHITE 1103 -5.56 -4.99 -4.43 -3.96 -3.57 -3.23 -2.94 -2.69
HALITE 1106 1.61 1.82 1.90 1.93 1.93 1.92 1.89 1.86
SYLVITE 1107 0.74 1.18 1.44 1.61 1.72 1.79 1.84 1.86
COR 1108 28.25 23.94 20:36 17.37 14.86 12.74 10.93 9.38
PER 1109 23.79 21.68 19.65 17.93 16.47 15.21 14.12 13.18
LIME 1110 36.05 33.07 30.43 28.19 26.26 24.59 23.14 21.87
TO 1111 5.48 6.49 6.15 5.86 5.61 5.40 5.23 5.09
CUP 1112 -4.55 -1.28 -0.84 -0.47 -0.11 0.23 0.56 0.89
FE-OXIDE 1113 15.76 14.17 12.72 11.49 10.44 9.53 8.75 8.07
GIBBS 1114 10.46 8.85 7.54 6.47 5.60 4.88 4.28 3.78
DIAS 1115 11.66 9.81 8.29 7.03 5.97 5.09 4.35 3.72
BOEH 1116 12.76 10.76 9.11 7.74 6.60 5.63 4.82 4.12
BRUC 1117 17.91 16.42 14.93 13.68 12.63 11.74 10.97 10.32
MANGAN 1119 19.78 18.21 16.60 15.22 14.06 13.06 12.21 11.47
SPINEL 1120 47.37 41.32 36.04 31.61 27.88 24.71 21.99 19.65
 347
log K ,P = 3.5 kb

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1071 -0.12 -0.56 -0.96 -1.71 -2.40 -3.10 -3.84 -4.58 -5.16 (-5.22)
1072 0.88 0.68 0.50 0.16 -0.17 -0.49 -0.84 -1.18 -1.46 (-1.48)
1073 0.83 0.62 0.42 0.07 -0.27 -0.61 -0.97 -1.33 -1.61 (-1.64)
1074 0.04 -0.24 -0.51 -0.98 -1.42 -1.85 -2.28 -2.71 -3.05 (-3.1 1)
1075 -0.12 -0.55 -0.96 -1.70 -2.40 -3.11 -3.85 -4.59 -5.18 (-5.24)
1076 -1.52 -1.76 -1.99 -2.41 -2.80 -3.19 -3.59 -4.00 -4.33 (-4.39)
1078 -5.05 -5.40 -5.75 -6.42 -7.10 -7.81 -8.58 -9.36 -10.02 (-10.25)
1079 -8.53 -8.65 -8.77 -9.04 -9.37 -9.77 -10.25 -10.78 -11.20 (-11.17)
1080 -8.21 -8.35 -8.50 -8.85 -9.26 -9.74 -10.31 -10.92 -11.43 (-11.56)
1081 -6.26 -6.37 -6.48 -6.72 -7.00 -7.35 -7.77 -8.24 -8.60 (-8.57)
1082 -6.27 -6.54 -6.80 -7.35 -7.91 -8.53 -9.20 -9.90 -10.49 (-10.67)
1083 -9.12 -10.43 -11.63 -13.78 -15.75 -17.70 -19.73 -21.74 -23.28 (-23.32)
1084 -1.47 -1.48 -1.50 -1.56 -1.65 -1.78 -1.96 -2.17 -2.33 (-2.28)
1085 -0.87 -1.01 -1.15 -1.39 -1.61 -1.85 -2.12 -2.39 -2.59 (-2.53)
1086 -15.27 -14.61 -14.02 -13.04 -12.26 -11.65 -11.19 -10.84 -10.51 (-10.07)
1087 -8.70 -8.26 -7.86 -7.17 -6.59 -6.14 -5.78 -5.51 -5.22 (-4.74)
1088 -8.66 -8.55 -8.45 -8.29 -8.21 -8.18 -8.24 -8.34 -8.38 (-8.18)
1089 -7.22 -7.18 -7.14 -7.11 -7.11 -7.18 -7.30 -7.46 -7.56 (-7.40)
1090 -24.71 -23.63 -22.66 -20.98 -19.59 -18.44 -17.51 -16.74 -16.02 (-15.15)
1091 -24.88 -23.78 -22.79 -21.06 -19.64 -18.47 -17.51 -16.72 -15.98 (-15.10)
1092 -1.68 -1.87 -2.04 -2.35 -2.64 -2.95 -3.27· -3.60 -3.85 (-3.83)
1093 -18.96 -17.62 -17.34 -16.95 -16.75 -16.72 -16.84 -17.06 -17.20 (-16.95)
1100 -13.84 -12.82 -11.88 -10.24 -8.84 -7.62 -6.56 -5.62 -4.79 (-4.04)
1101 -4.32 -3.83 -3.37 -2.54 -1.82 -1.18 -0.60 -0.08 0.39 (0.83)
1102 -1.40 -1.07 -0.76 -0.19 0.33 0.80 1.24 1.64 2.02 (2.38)
1103 -2.48 -2.30 -2.14 -1.88 -1.69 -1.56 -1.46 -1.40 -1.53 (-1.28)
1106 1.82 1.78 1.73 1.63 1.51 1.36 1.18 0.99 0.84 (0.85)
1107 1.86 1.85 1.83 1.75 1.64 1.48 1.29 1.08 0.89 (0.86)
1108 8.03 6.87 5.86 4.18 2.83 1.69 0.68 -0.22 -0.85 (-0.85)
1109 12.35 11.61 10.96 9.86 8.97 8.21 7.56 6.99 6.54 (6.30)
1110 20.74 19.75 18.85 17.33 16.08 15.02 14.11 13.33 12.67 (12.22)
1111 4.97 4.88 4.80 4.69 4.61 4.56 4.52 4.49 4.49 (4.55)
1112 1.21 1.53 1.83 2.42 2.97 3.49 3.97 4.41 4.86 (5.34)
1113 7.48 6.96 6.50 5.72 5.09 4.56 4.10 3.7<1 3.39 (3.26)
1114 3.37 3.02 2.73 2.27 1.92 1.63 1.36 1.12 0.98 (1.13)
1115 3.18 2.73 2.33 1.70 1.20 0.79 0.43 0.11 -0.09 (0.02)
1116 3.53 3.02 2.58 1.86 1.30 0.83 0.42 0.05 -0.19 (-0.1 1)
1117 9.75 9.26 8.83 8.11 7.54 7.07 6.66 6.31 6.05 (5.97)
1119 10.83 10.27 9.78 8.97 8.32 7.78 7.33 6.94 6.65 (6.54)
1120 17.62 15.86 14.32 11.74 9.68 7.93 6.39 5.03 4.04 (3.89)
348 log K ,P = 3.5 kb

TEMPERATURE, °C
NAME INDEX
0 25 50 75 100 125 150 175

K-OXIDE 1123 90.55 83.80 78.07 73.16 68.92 65.21 61.96 59.08
NA-OXIDE 1124 72.93 67.33 62.61 58.60 55.16 52.18 49.58 47.30
AMORPH SIL 1125 -2.74 -2.06 -1.73 -1.53 -1.38 -1.28 -1.19 -1.12
A-CRIST 1126 -3.86 -3.00 -2.54 -2.24 -2.02 -1.85 -1.72 -1.60
B-CRIST 1127 -3.23 -2.45 -2.06 -1.81 -1.64 -1.51 -1.40 -1.31
CHALCED 1128 -4.38 -3.46 -2.96 -2.62 -2.37 -2.17 -2.01 -1.87
WAIR 1130 25.96 23.83 20.94 18.19 15.75 13.62 11.78 10.21
LAUM 1132 19.85 18.61 16.50 14.42 12.57 10.98 9.61 8.47
ACAN 1501 -40.41 -36.15 -33.00 -30.36 -28.10 -26.14 -24.42 -22.91
CP 1502 -36.85 -32.4 7 -30.27 -28.50 -27.03 -25.78 -24.71 -23.79
BN 1503 -117.80 -101.08 -93.31 -86.91 -81.44 -76.71 -72.57 -68.91
CC 1504 -40.38 -34.13 -31.27 -28.89 -26.84 -25.08 -23.54 -22.17
QTZ 1505 -4.68 -3.74 -3.21 -2.85 -2.59 -2.38 -2.20 -2.05
MG 1506 33.95 30.47 27.18 24.36 21.96 19.90 18.12 16.59
KALS 1507 14.17 12.89 11.56 10.38 9.35 8.47 7.72 7.09
FERROSIL 1508 8.64 8.24 7.54 6.85 6.23 5.68 5.19 4.78
PYROPH 1509 4.18 4.26 3.33 2.25 1.23 0.32 -0.46 -1.11
TALC 1510 22.75 22.90 21.25 19.51 17.92 16.51 15.29 14.25
7-A CL 1512 83.22 75.89 67.82 60.83 54.87 49.79 45.46 41.75
14-A CL 1513 79.33 72.25 64.37 57.55 51.73 46.77 42.54 38.93
CLNZ 1515 54.42 48.72 42.99 37.95 33.62 29.91 26.74 24.02
LAWS 1516 27.83 24.99 22.04 19.43 17.20 15.30 13.69 12.32
TREM 1517 66.22 64.78 60.03 55.33 51.08 47.35 44.11 41.31
ANTH 1518 72.89 70.52 64.72 59.13 54.12 49.73 45.92 42.62
ZOIS 1519 54.45 48.74 43.01 37.97 33.64 29.93 26.75 24.03
GROSS 1529 60.87 55.73 50.34 45.55 41.41 37.85 34.79 32.16
ANDRA 1530 56.51 53.31 49.22 45.47 42.17 39.30 36.81 34.66
ALB 1531 5.10 5.51 5.09 4.51 3.93 3.41 2.97 2.59
PREHN 1532 40.76 37.32 33.47 30.00 26.99 24.40 22.18 20.29
ENST 1537 12.38 11.77 10.75 9.80 8.96 8.22 7.59 7.03
PARG 1538 119.85 109.77 98.59 88.70 80.15 72.80 66.47 61.03
ANTIG 1542 523.14 497.11 454.88 416.67 383.49 354.98 330.57 309.67
HM 1544 21.50 19.33 17.23 15.44 13.90 12.59 11.45 10.47
ORD-EP 1545 51.09 46.45 41.46 37.01 33.17 29.86 27.02 24.58
MARG 1551 55.54 48.21 41.53 35.81 30.95 26.82 23.30 20.29
MERCURY 1552 -21.91 -19.88 -18.42 -17.14 -16.00 -14.96 -14.01 -13.13
PO 1555 -3.05 -2.96 -3.09 -3.25 -3.42 -3.58 -3.75 -3.93
NESQ 1558 6.85 5.67 5.49 5.41 5.35 5.30 5.27 5.24
EPID 1559 51.09 46.45 41.46 37.01 33.16 29.85 27.01 24.57
HI-ALB 1560 6.62 6.85 6.28 5.57 4.88 4.27 3.73 3.28
 log K ,P = 3.5 kb 349

TEMPERATURE, DC
INDEX
200 225 250 300 350 400 450 500 550 600

1123 56.51 54.21 52.14 48.56 45.58 43.06 40.89 39.02 37.39 (36.00)
1124 45.28 43.49 41.89 39.17 36.94 35.08 33.52 32.19 31.06 (30.16)
1125 -1.06 -1.02 -0.97 -0.91 -0.87 -0.85 -0.84 -0.86 -0.88 (-0.89)
1126 -1.50 -1.41 -1.33 -1.19 -1.07 -0.96 -0.85 -0.76 -0.67 (-0.57)
1127 -1.23 -1.16 -1.10 -0.99 -0.89 -0.80 -0.72 -0.64 -0.56 (-0.47)
1128 -1.75 -1.65 -1.55 -1.38 -1.23 -1.10 -0.98 -0.88 -0.77 (-0.67)
1130 8.86 7.70 6.71 5.13 3.92 2.95 2.10 1.38 0.99 0.41)
1132 7.50 6.70 6.04 5.04 4.34 3.81 3.36 3.00 2.92 (3.64)
1501 -21.58 -20.39 -19.33 -17.52 -16.05 -14.86 -13.88 -13.07 -12.33 (-11.53)
1502 -22.99 -22.29 -21.68 -20.68 -19.94 -19.44 -19.14 -19.00 -18.83 (-18.30)
1503 -65.66 -62.77 -60.20 -55.83 -52.31 -49.50 -48.31 -46.58 -43.93 (-41.71)
1504 -20.95 -19.85 -18.85 -17.13 -15.70 -14.50 -13.53 -12.70 -11.94 (-11.08)
1505 -1.92 -1.80 -1.70 -1.51 -1.35 -1.21 -1.08 -0.97 -0.86 (-0.75)
1506 15.25 14.07 13.04 11.30 9.87 8.56 7.55 6.57 5.82 (5.62)
1507 6.54 6.08 5.69 5.07 4.59 4.21 3.87 3.59 3.43 (3.62)
1508 4.41 4.10 3.83 3.38 3.03 2.75 2.50 2.29 2.16 (2.21)
1509 -1.66 -2.11 -2.47 -3.00 -3.35 -3.61 -3.85 -4.04 -4.02 (-3.36)
1510 13.35 12.59 11.95 10.94 10.21 9.63 9.16 8.77 8.61 (9.01)
1512 38.58 35.84 33.48 29.64 26.64 24.16 22.01 20.15 18.94 09.27)
1513 35.83 33.16 30.87 27.13 24.23 21.84 19.75 17.95 16.80 (17.18)
1515 21.68 19.67 17.93 15.11 12.91 11.08 9.48 8.09 7.21 (7.60)
1516 11.17 10.19 9.36 8.06 7.08 6.28 5.59 4.99 4.69 (5.16)
1517 38.91 36.84 35.06 32.21 30.05 28.32 26.86 25.65 24.97 (25.55)
1518 39.77 37.30 35.17 31.71 29.04 26.88 25.04 23.50 22.54 (22.94)
1519 21.69 19.68 17.94 15.11 12.91 11.08 9.48 8.08 7.21 (7.59)
1529 29.89 27.92 26.22 23.44 21.27 19.47 17.90 16.55 15.67 05.89)
1530 32.79 31.16 29.74 27.40 25.54 24.00 22.65 21.49 20.70 (20.76)
1531 2.29 2.05 1.86 1.61 1.47 1.40 1.34 1.32 1.42 (1.89)
1532 18.67 17.28 16.08 14.16 12.69 11.48 10.42 9.51 8.97 (9.38)
1537 6.55 6.13 5.76 5.16 4.69 4.30 3.96 3.68 3.49 (3.49)
1538 56.33 52.26 48.73 42.95 38.42 34.69 31.47 28.71 26.88 (27.14)
1542 291.79 276.47 263.31 242.15 225.96 212.89 201.74 192.32 186.64 089.70)
1544 9.61 8.86 8.20 7.08 6.16 5.37 4.65 4.01 3.52 (3.42)
1545 22.49 20.68 19.12 16.58 14.60 12.95 11.51 10.26 9.48 (9.82)
1551 17.72 15.50 13.59 10.48 8.04 6.01 4.21 2.63 1.63 (2.04)
1552 -12.32 -11.58 -10.85 -9.55 -8.40 -7.69 -7.08 -6.51 -5.96 (-5.37)
1555 -4.10 -4.26 -4.42 -4.73 -5.05 -5.38 -5.74 -6.12 -6.41 (-6.42)
1558 5.22 5.21 5.19 5.14 5.07 4.94 4.76 4.53 4.35 (4.42)
1559 22.47 20.66 19.09 16.54 14.54 12.88 11.43 10.16 9.36 (9.69)
1560 2.91 2.61 2.36 2.02 1.81 1.68 1.57 1.51 1.59 (2.04)
350 Log K, P = 4 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

AND 1001 23.04 19.84 16.87 14.30 12.09 10.21 8.60 7.21
KYA 1002 22.13 19.04 16.17 13.68 11.55 9.73 8.18 6.85
SILL 1003 23.33 20.09 17.08 14.48 12.25 10.34 8.71 7.31
KAOL 1004 11.73 10.36 8.66 7.09 5.72 4.55 3.57 2.74
CHRYS 1007 33.46 32.11 29.44 27.01 24.89 23.07 21.51 20.18
MUSC 1012 21.28 19.07 16.35 13.81 11.60 9.70 8.09 6.74
PARAG 1013 25.79 23.05 19.90 17.01 14.49 12.35 10.53 9.00
PHLOG 1014 42.56 40.36 36.64 33.24 30.26 27.71 25.52 23.65
ANNITE 1015 35.79 33.75 30.66 27.74 25.16 22.92 20.99 19.35
DEHYD-ANAL 1021 15.94 15.04 13.70 12.39 11.20 10.17 9.27 8.51
ANAL 1022 10.08 9.71 8.82 7.90 7.06 6.33 5.70 5.18
SEPIO 1023 30.14 32.05 30.67 28.97 27.37 25.95 24.74 23.73
LO-ALB 1025 4.90 5.59 5.28 4.75 4.19 3.68 3.24 2.87
MAX-MICRO 1027 1.39 2.54 2.61 2.38 2.08 1.79 1.53 1.32
K-SPAR 1028 1.39 2.54 2.61 2.39 2.10 1.81 1.55 1.34
HI-SAN 1029 2.79 3.76 3.67 3.32 2.91 2.52 2.17 1.88
ANOR 1030 35.38 31.71 27.89 24.49 21.54 19.00 16.81 14.93
NEPH 1031 17.68 16.08 14.43 12.96 11.68 10.59 9.66 8.87
WOLL 1035 14.90 14.35 13.43 12.55 11.75 11.05 10.43 9.90
DIOP 1039 22.07 21.53 20.00 18.51 17.17 15.99 14.96 14.07
CA-AL PYX 1040 44.83 39.83 35.19 31.19 27.77 24.84 22.33 20.16
AKER 1044 49.76 46.88 43.22 39.90 36.99 34.45 32.25 30.33
MERW 1045 74.93 70.02 64.47 59.56 55.28 51.57 48.35 45.54
MONTI 1046 32.70 30.62 28.09 25.84 23.89 22.20 20.73 19.46
GEHL 1047 68.07 61.16 54.74 49.22 44.50 40.46 36.98 33.98
FORST 1048 30.55 28.55 25.91 23.58 21.56 19.82 18.31 17.01
FAY 1049 22.25 20.66 18.72 16.95 15.39 14.04 12.88 11.86
HUNT 1050 15.98 14.66 12.21 10.01 8.07 6.36 4.83 3.47
ART 1053 21.45 20.16 18.42 16.95 15.71 14.67 13.78 13.03
HED 1054 21.27 20.66 19.24 16.53 17.82 16.53 15.38 14.38
MALACH 1059 0.04 3.97 4.02 3.99 3.96 3.93 3.92 3.90
AZUR 1060 1.43 7.16 7.07 6.86 6.64 6.44 6.26 6.08
HYDRO-MAG 1062 37.64 34.96 30.93 27.44 24.44 21.85 19.58 17.61
SMITH 1064 0.17 0.25 -0.07 -0.38 -0.66 -0.92 -1.14 -1.35
ANH-CORD 1065 71.06 64.15 56.25 49.13 42.92 37.55 32.92 28.92
HYD-CORD 1066 67.64 61.05 53.42 46.54 40.55 35.38 30.92 27.08
JADEITE 1067 9.98 9.77 9.00 8.18 7.43 6.77 6.21 5.74
CER 1068 -2.38 -1.64 -1.49 -1.39 -1.30 -1.21 -1.13 -1.05
STRONT 1069 0.33 0.32 0.20 0.07 -0.05 -0.16 -0.27 -0.37
DIS-DOL 1070 6.73 6.19 5.15 4.20 3.36 2.61 1.95 1.35
 log K ,P = 4 kb 351

TEMPERATURE, DC
INDEX
200 225 250 300 350 400 450 500 550 600

1001 6.02 5.00 4.11 2.66 1.52 0.57 -0.26 -0.97 -1.40 (-1.19)
1002 5.70 4.72 3.87 2.48 1.39 0.49 -0.31 -0.98 -1.38 (-1.15)
1003 6.11 5.07 4.17 2.70 1.54 0.58 -0.26 -0.97 -1.41 (-1.21)
1004 2.05 1.48 1.01 0.29 -0.22 -0.62 -0.97 -1.25 -1.30 (-0.73)
1007 19.04 18.06 17.22 15.87 14.84 14.02 13.33 12.76 12.45 (12.68)
1012 5.60 4.66 3.87 2.66 1.79 1.10 0.52 0.05 -0.04 (0.81)
1013 7.71 6.63 5.73 4.34 3.34 2.56 1.90 1.38 1.25 (2.10)
1014 22.05 20.69 19.53 17.68 16.29 15.18 14.25 13.49 13.13 (13.64)
1015 17.95 16.75 15.73 14.12 12.90 11.94 11.12 10.46 10.17 (10.71)
1021 7.85 7.29 6.82 6.07 5.52 5.08 4.73 4.45 4.35 (4.61)
1022 4.75 4.40 4.11 3.69 3.43 3.25 3.11 3.04 3.10 (3.53)
1023 22.90 22.23 21.70 20.98 20.57 20.33 20.20 20.18 20.45 (21.43)
1025 2.57 2.33 2.14 1.90 1.78 1.73 1.71 1.74 1.91 (2.45)
1027 1.15 1.02 0.93 0.84 0.83 0.85 0.90 0.96 1.16 (1.69)
1028 1.17 1.04 0.94 0.84 0.81 0.82 0.84 0.89 1.06 (1.57)
1029 1.64 1.45 1.30 1.11 1.02 0.98 0.96 0.98 1.12 (1.62)
1030 13.30 11.90 10.68 8.68 7.12 5.83 4.71 3.77 3.19 (3.41)
1031 8.19 7.62 7.13 6.36 5.78 5.32 4.94 4.64 4.50 (4.73)
1035 9.43 9.02 8.66 8.07 7.61 7.23 6.91 6.65 6.48 (6.47)
1039 13.30 12.63 12.05 11.11 10.39 9.80 9.32 8.92 8.69 (8.81)
1040 18.28 16.65 15.22 12.87 10.99 9.43 8.08 6.92 6.15 (6.17)
1044 28.66 27.19 25.90 23.76 22.05 20.65 19.46 18.46 17.75 (17.57)
1045 43.08 40.93 39.03 35.85 33.30 31.19 29.40 27.88 26.76 (26.34)
1046 18.35 17.38 16.53 15.11 13.98 13.05 12.25 11.59 11.11 (10.99)
1047 31.36 29.09 27.09 23.77 21.12 18.90 17.00 15.37 14.23 (14.06)
1048 15.87 14.87 14.00 12.55 11.39 10.43 9.61 8.92 8.43 (8.32)
1049 10.98 10.22 9.55 8.46 7.57 6.84 6.23 5.71 5.36 (5.36)
1050 2.23 1.11 0.09 -1.76 -3.44 -5.06 -6.70 -8.28 -9.47 (-9.58)
1053 12.38 11.82 11.33 10.53 9.88 9.32 8.79 8.31 8.00 (8.14)
1054 12.76 12.10 11.53 10.60 9.88 9.30 8.81 8.41 8.17 (8.27)
1059 3.90 3.89 3.89 3.89 3.88 3.83 3.75 3.64 3.59 (3.76)
1060 5.93 5.78 5.64 5.37 5.09 4.76 4.38 3.96 3.67 (3.76)
1062 15.87 14.32 12.92 10.53 8.44 6.51 4.64 2.87 1.58 (1.60)
1064 -1.53 -1.70 -1.85 -2.13 -2.40 -2.67 -2.97 -3.27 -3.49 (-3.44)
1065 25.47 22.47 19.87 15.61 12.26 9.50 7.11 5.10 3.86 (4.29)
1066 23.77 20.91 18.44 14.40 11.24 8.65 6.41 4.54 3.42 (3.97)
1067 5.35 5.03 4.78 4.41 4.18 4.03 3.92 3.86 3.94 (4.38)
1068 -0.96 -0.89 -0.81 -0.67 -0.56 -0.48 -0.46 -0.45 -0.40 (-0.14)
1069 -0.46 -0.55 -0.64 -0.80 -0.98 -1.17 -1.39 -1.62 -1.78 (-1.71)
1070 0.80 0.31 -0.15 -0.97 -1.73 -2.47 -3.22 -3.96 -4.51 (-4.53)
352 log K ,P = 4 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

ORD-DOL 1071 4.98 4.64 3.76 2.97 2.24 1.61 1.03 0.52
ARAG 1072 3.24 3.04 2.66 2.30 1.98 1.69 1.43 1.20
CALC 1073 3.29 3.07 2.68 2.31 1.98 1.68 1.41 1.16
MAG 1074 3.54 3.24 2.62 2.06 1.57 1.14 0.75 0.41
DOL 1075 4.98 4.64 3.77 2.96 2.25 1.61 1.04 0.52
SIDER 1076 1.51 1.20 0.72 0.27 -0.13 -0.49 -0.82 -1.11
ANHYD 1078 -2.79 -2.42 -2.71 -3.08 -3.46 -3.84 -4.21 -4.57
FLUORITE 1079 -9.46 -8.13 -8.04 -8.04 -8.07 -8.13 -8.20 -8.29
BARITE 1080 -9.47 -8.46 -8.12 -7.95 -7.89 -7.89 -7.93 -8.01
ANG 1081 -7.09 -5.90 -5.76 -5.75 -5.78 -5.85 -5.93 -6.01
CELEST 1082 -5.16 -4.66 -4.75 -4.93 -5.15 -5.39 -5.64 -5.90
ALUN 1083 8.39 5.95 3.06 0.46 -1.82 -3.84 -5.62 -7.21
WITH 1084 -2.15 -1.80 -1.62 -1.52 -1.45 -1.41 -1.38 -1.37
RHODO 1085 0.62 0.81 0.53 0.24 -0.01 -0.24 -0.43 -0.61
COV 1086 -28.14 -23.77 -21.84 -20.27 -18.95 -17.81 -16.83 -15.97
GALENA 1087 -15.74 -13.74 -12.61 -11.69 -10.91 -10.23 -9.62 -9.08
SL 1088 -11.51 -10.38 -9.90 -9.55 -9.28 -9.05 -8.86 -8.70
WURT 1089 -8.99 -8.08 -7.78 -7.58 -7.44 -7.33 -7.24 -7.17
M-CINN 1090 -41.29 -37.34 -34.60 -32.30 -30.34 -28.62 -27.12 -25.78
CINN 1091 -41.86 -37.83 -35.02 -32.68 -30.66 -28.91 -27.37 -25.99
ALA 1092 -0.19 0.12 -0.15 -0.45 -0.73 -0.98 -1.21 -1.43
PYRITE 1093 -26.26 -23.85 -22.32 -21.16 -20.23 -19.48 -18.87 -18.37
GOLD 1100 -28.59 -25.70 -23.26 -21.18 -19.37 -17.77 -16.36 "15.10
SILVER 1101 -11.27 -9.73 -8.64 -7.72 -6.90 -6.17 -5.52 -4.93
COPPER 1102 -7.10 -4.56 -3.95 -3.43 -2.96 -2.54 -2.14 -1.77
GRAPHITE 1103 -5.50 -4.95 -4.38 -3.91 -3.51 -3.17 -2.88 -2.64
HALITE 1106 1.49 1.79 1.90 1.95 1.96 1.96 1.94 1.91
SYLVITE 1107 0.64 1.17 1.45 1.64 1.76 1.84 1.88 1.91
COR 1108 28.43 24.17 20.60 17.62 15.11 12.99 11.18 9.62
PER 1109 23.61 21.60 19.58 17.87 16.41 15.16 14.08 13.14
LIME 1110 35.96 33.04 30.41 28.17 26.25 24.58 23.14 21.86
TO 1111 4.91 6.44 6.13 5.83 5.59 5.38 5.22 5.08
CUP 1112 -5.64 -1.36 -0.88 -0.50 -0.14 0.21 0.55 0.88
FE-OXIDE 1113 15.70 14.19 12.76 11.53 10.47 9.57 8.79 8.11
GIBBS 1114 10.50 8.92 7.62 6.55 5.68 4.96 4.36 3.86
DIAS 1115 11.72 9.90 8.39 7.13 6.08 5.19 4.45 3.82
BOEH 1116 12.84 10.87 9.23 7.86 6.71 5.75 4.93 4.24
BRUC 1117 17.70 16.31 14.84 13.59 12.55 11.66 10.91 10.25
MANGAN 1119 19.59 18.17 16.57 15.21 14.05 13.05 12.20 11.47
SPINEL 1120 47.39 41.50 36.24 31.82 28.09 24.92 22.21 19.87
 log K ,P = 4 kb 353

TEMPERATURE, °C
INDEX
200 225 250 300 350 400 450 500 550 600

1071 0.05 -0.38 -0.77 -1.49 -2.15 -2.82 -3.51 -4.18 -4.68 ( -4.66)
1072 0.98 0.79 0.61 0.27 -0.04 -0.35 -0.67 -0.98 -1.22 (-1.21)
1073 0.94 0.73 0.54 0.20 -0.13 -0.45 -0.79 -1.12 -1.37 (-1.37)
1074 0.10 -0.18 -0.43 -0.89 -1.31 -1.72 -2.13 -2.52 -2.82 (-2.84)
1075 0.05 -0.37 -0.77 -1.49 -2.15 -2.82 -3.51 -4.20 -4.70 (-4.69)
1076 -1.38 -1.62 -1.84 -2.25 -2.63 -3.00 -3.39 -3.77 -4.05 (-4.07)
1078 -4.92 -5.26 -5.60 -6.25 -6.91 -7.59 -8.31 -9.04 -9.63 (-9.80)
1079 -8.39 -8.49 -8.60 -8.86 -9.16 -9.52 -9.96 -10.44 -10.78 (-10.69)
1080 -8.11 -8.24 -8.38 -8.70 -9.09 -9.55 -10.07 -10.63 -11.08 (-11.15)
1081 -6.11 -6.21 -6.31 -6.53 -6.80 -7.12 -7.50 -7.91 -8.21 (-8.13)
1082 -6.16 -6.41 -6.67 -7.19 -7.73 -8.32 -8.95 -9.60 -10.12 (-10.24)
1083 -8.64 -9.93 -11.10 -13.20 -15.10 -16.96 -18.86 -20.71 -22.04 (-21.88)
1084 -1.37 -1.38 -1.40 -1.45 -1.53 -1.65 -1.81 -1.98 -2.11 (-2.03)
1085 -0.77 -0.91 -1.03 -1.26 -1.48 -1.70 -1.94 -2.18 -2.34 (-2.25)
1086 -15.22 -14.55 -13.96 -12.95 -12.16 -11.54 -11.06 -10.69 -10.33 (-9.86)
1087 -8.59 -8.15 -7.74 -7.04 -6.45 -5.98 -5.61 -5.31 -4.98 (-4.47)
1088 -8.56 -8.44 -8.33 -8.17 -8.06 -8.02 -8.05 -8.12 -8.12 (-7.87)
1089 -7.11 -7.07 . -7.03 -6.98 -6.97 -7.02 -7.12 -7.24 -7.30 (-7.10)
1090 -24.58 -23.50 -22.52 -20.83 -19.43 -18.28 -17.32 -16.52 -15.77 (-14.87)
1091 -24.77 -23.66 -22.66 -20.93 -19.50 -18.31 -17.33 -16.51 -15.73 (-14.82)
1092 -1.62 -1.79 -1.96 -2.25 -2.53 -2.81 -3.11 -3.41 -3.62 (-3.55)
1093 -17.96 -17.62 -17.34 -16.95 -16.75 -16.72 -16.84 -17.06 -17.20 (-16.95)
1100 -13.96 -12.93 -11.99 -10.34 -8.93 -7.71 -6.64 -5.70 -4.86 (-4.11)
1101 -4.38 -3.88 -3.42 -2.59 -1.86 -1.22 -0.64 -0.12 0.35 (0.79)
1102 -1.42 -1.09 -0.78 -0.21 0.31 0.78 1.22 1.62 2.00 (2.37)
1103 -2.42 -2.24 -2.08 -1.82 -1.62 -1.49 -1.39 -1.32 -1.27 ( -1.20)
1106 1.88 1.84 1.80 1.71 1.60 1.46 1.30 1.13 1.00 (1.04)
1107 1.92 1.91 1.89 1.82 1.72 1.58 1.40 1.20 1.04 (1.03)
1108 8.28 7.12 6.11 4.45 3.12 2.01 1.04 0.20 -0.36 (-0.28)
1109 12.31 11.58 10.94 9.85 8.97 8.22 7.59 7.04 6.61 (6.39)
1110 20.74 19.75 18.86 17.34 16.10 15.05 14.15 13.38 12.74 (12.31)
1111 4.96 4.87 4.80 4.68 4.61 4.56 4.53 4.51 4.51 (4.58)
1112 1.20 1.52 1.82 2.41 2.97 3.49 3.97 4.43 4.88 (5.37)
1113 7.52 7.00 6.54 5.77 5.15 4.63 4.18 3.79 3.50 (3.39)
1114 3.45 3.10 2.81 2.36 2.02 1.75 1.50 1.28 1.18 (1.37)
1115 3.29 2.83 2.44 1.81 1.33 0.93 0.59 0.30 0.13 (0.28)
1116 3.64 3.13 2.70 1.99 1.43 0.98 0.58 0.25 0.05 (0.16)
1117 9.69 9.20 8.78 8.07 7.51 7.05 6.66 6.32 6.08 (6.03)
1119 10.83 10.28 9.79 8.98 8.34 7.82 7.37 7.00 6.73 (6.64)
1120 17.85 16.10 14.56 12.02 9.98 8.27 6.78 5.51 4.62 (4.56)
354 log K , P = 4 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

K-OXIDE 1123 90.32 83.65 77.95 73.06 68.83 65.14 61.89 59.02
NA-OXIDE 1124 72.71 67.19 62.52 58.53 55.11 52.14 49.55 47.27
AMORPH SIL 1125 -2.76 -2.02 -1.66 -1.45 -1.30 -1.19 -1.11 -1.04
A-CRIST 1126 -3.91 -2.98 -2.49 -2.18 -1.96 -1.79 -1.66 -1.54
B-CRIST 1127 -3.26 -2.42 -2.00 -1.75 -1.57 -1.43 -1.33 -1.24
CHALCED 1128 -4.46 -3.47 -2.94 -2.59 -2.33 -2.13 -1.97 -1.83
WAIR 1130 25.92 24.18 21.41 18.71 16.28 14.15 12.31 10.73
LAUM 1132 19.72 18.87 16.88 14.85 13.02 11.42 10.06 8.91
ACAN 1501 -40.90 -36.33 -33.12 -30.45 -28.18 -26.20 -24.47 -22.95
CP 1502 -37.54 -32.42 -30.16 -28.36 -26.88 -25.63 -24.55 -23.62
BN 1503 -120.82 -101.19 -93.26 -86.78 -81.28 -76.53 -72.36 -68.68
CC 1504 -41.56 -34.21 -31.30 -28.89 -26.84 -25.07 -23.52 -22.15
QTZ 1505 -4.76 -3.75 -3.19 -2.82 -2.55 -2.33 -2.16 -2.01
MG 1506 33.79 30.58 27.32 24.51 22.10 20.04 18.28 16.74
KALS 1507 14.10 12.96 11.68 10.52 9.50 8.63 7.88 7.25
FERROSIL 1508 8.48 8.24 7.58 6.91 6.29 5.74 5.27 4.85
PYROPH 1509 3.98 4.40 3.61 2.58 1.59 0.69 -0.08 -0.73
TALC 1510 21.83 22.59 21.08 19.42 17.87 16.49 15.30 14.27
7-A CL 1512 82.20 75.68 67.75 60.83 54.91 49.87 45.57 41.88
14-A CL 1513 78.27 71.99 64.27 57.52 51.74 46.82 42.62 39.03
CLNZ 1515 54.14 48.88 43.29 38.31 34.00 30.31 27.15 24.44
LAWS 1516 27.58 25.02 22.15 19.59 17.37 15.48 13.88 12.53
TREM 1517 64.32 64.13 59.67 55.13 50.97 47.31 44.12 41.36
ANTH 1518 70.83 69.79 64.28 58.85 53.94 49.62 45.86 42.61
ZOIS 1519 54.17 48.91 43.31 38.32 34.02 30.32 27.16 24.45
GROSS 1529 60.35 55.70 50.44 45.71 41.61 38.07 35.03 32.41
ANDRA 1530 55.71 53.11 49.17 45.49 42.23 39.38 36.92 34.78
ALB 1531 4.90 5.59 5.28 4.75 4.19 3.68 3.24 2.87
PREHN 1532 40.48 37.44 33.71 30.29 27.30 24.73 22.52 20.63
ENST 1537 12.09 11.66 10.68 9.75 8.92 8.20 7.57 7.02
PARG 1538 118.51 109.55 98.65 88.89 80.42 73.12 66.83 61.42
ANTIG 1542 510.95 492.42 451.64 414.21 381.53 353.39 329.27 308.65
HM 1544 21.39 19.39 17.32 15.53 14.00 12.69 11.55 10.57
ORD-EP 1545 50.67 46.54 41.68 37.30 33.48 30.19 27.36 24.93
MARG 1551 55.64 4S.64 42.05 36.36 31.51 27.38 23.86 20.86
MERCURY 1552 -22.04 -19.86 -18.39 -17.11 -15.96 -14.92 -13.97 -13.10
PO 1555 -3.17 -2.93 -3.03 -3.18 -3.34 -3.50 -3.67 -3.84
NESQ 1558 6.72 5.66 5.50 5.42 5.3 5.32 5.29 5.27
EPID 1559 50.68 46.54 41.68 37.29 33.47 30.18 27.35 24.91
HI-ALB 1560 6.42 6.93 6.47 5.81 5.14 4.54 4.01 3.56
 log K ,P = 4 kb 355

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1123 56.46 54.l6 52.09 48.52 45.54 43.02 40.86 39.00 37.38 (35.99)
1124 45.26 43.48 41.88 39.16 36.94 35.09 33.53 32.20 31.09 (30.20)
1125 -0.99 -0.94 -0.90 -0.84 -0.80 -0.78 -0.78 -0.79 -0.82 (-0.83)
1126 -1.44 -1.35 -l.28 -1.14 -1.01 -0.90 -0.80 -0.71 -0.62 (-0.52)
1127 -1.16 -1.10 -1.04 -0.93 -0.83 -0.74 -0.66 -0.58 -0.51 (-0.42)
1128 -1.71 -1.60 -1.51 -1.34 -1.19 -1.06 -0.94 -0.84 -0.73 (-0.63)
1130 9.38 8.22 7.23 5.65 4.46 3.50 2.70 2.04 1.74 (2.24)
1132 7.95 7.15 6.48 5.49 4.80 4.29 3.88 3.58 3.59 (4.38)
1501 -21.61 -20.42 -19.35 -17.52 -16.03 -14.82 -l3.83 -12.99 -12.22 (-11.38)
1502 -22.81 -22.11 -21.48 -20.46 -19.70 -19.16 -18.82 -18.62 -18.37 (17.79)
1503 -65.41 -62.50 -59.91 -55.49 -51.92 -49.04 -46.77 -44.92 -43.14 (-40.80)
1504 -20.92 -19.81 -18.81 -17.07 -15.63 -14.42 -13.42 -12.57 -11.77 (-10.88)
1505 -1.88 -1.76 -1.65 -1.47 -l.31 -1.17 -1.04 -0.93 -0.82 (-0.71)
1506 15.41 14.24 l3.21 11.48 10.07 8.88 7.81 6.88 6.20 (6.05)
1507 6.71 6.25 5.86 5.24 4.78 4.41 4.09 3.84 3.72 (3.95)
1508 4.49 4.18 3.90 3.46 3.12 2.84 2.61 2.42 2.30 (2.37)
1509 -l.28 -1.72 -2.08 -2.60 -2.93 -3.17 -3.37 -3.51 -3.40 (-2.67)
1510 l3.39 12.65 12.02 11.04 10.33 9.79 9.36 9.03 8.94 (9.40)
1512 38.73 36.02 33.69 29.91 26.97 24.58 22.54 20.82 19.80 (20.30)
1513 35.96 33.32 31.05 27.38 24.55 22.24 20.26 18.62 17.65 (18.20)
1515 22.11 20.11 18.39 15.61 l3.45 11.68 10.16 8.89 8.16 (8.69)
1516 1l.38 10.41 9.60 8.31 7.36 6.60 5.96 5.43 5.23 (5.78)
1517 38.99 36.96 35.22 32.43 30.33 28.67 27.31 26.23 25.71 (26.43)
1518 39.80 37.37 35.28 31.89 29.29 27.21 25.48 24.07 23.29 (23.84)
1519 22.12 20.12 18.40 15.61 l3.45 11.68 10.16 8.88 8.16 (8.68)
1529 30.16 28.21 26.53 23.79 21.66 19.91 18.42 17.18 16.43 (16.78)
1530 32.93 31.31 29.91 27.60 25.78 24.29 23.00 21.92 2l.23 (2l.38)
1531 2.57 2.33 2.14 1.90 1.77 1.70 1.67 1.68 1.82 (2.34)
1532 19.02 17.64 16.45 14.56 l3.11 11.94 10.94 10.12 9.70 (10.20)
1537 6.54 6.13 5.77 5.18 4.71 4.34 4.02 3.76 3.59 (3.61)
1538 56.76 52.72 49.23 43.53 39.08 35.46 32.38 29.83 28.24 (28.73)
1542 291.01 275.92 262.99 242.29 226.57 214.03 203.55 195.03 190.45 (194.51)
1544 9.72 8.97 8.31 7.20 6.30 5.52 4.83 4.22 3.79 (3.72)
1545 22.85 21.06 19.51 17.00 15.06 13.47 12.10 10.96 10.31 (10.78)
1551 18.29 16.08 14.18 11.10 8.71 6.74 5.03 3.58 2.75 (3.32)
1552 -12.28 -11.53 -10.82 -9.52 -8.37 -7.66 -7.05 -6.47 -5.91 (-5.31)
1555 -4.00 -4.16 -4.31 -4.61 -4.91 -5.22 -5.56 -5.90 -6.15 (-6.13)
1558 5.25 5.24 5.22 5.19 5.13 5.02 4.85 4.65 4.51 (4.62)
1559 22.83 21.03 19.48 16.96 15.00 13.40 12.02 10.86 10.20 (10.66)
1560 3.19 2.89 2.65 2.31 2.11 1.98 1.90 l.87 1.99 (2.48)
356
Log K , P = 4.5 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

AND 1001 23.10 20.05 17.14 14.58 12.38 10.50 8.88 7.50
KYA 1002 22.12 19.19 16.38 13.91 11.79 9.97 8.42 7.09
SILL 1003 23.37 20.28 17.33 14.75 12.52 10.62 8.99 7.59
KAOL 1004 11.64 10.49 8.88 7.34 5.99 4.82 3.84 3.01
CHRYS 1007 32.57 31.73 29.15 26.77 24.69 22.90 21.36 20.04
MUSC 1012 21.03 19.21 16.63 14.16 11.97 10.09 8.49 7.14
PARAG 1013 25.54 23.19 20.19 17.36 14.88 12.75 10.94 9.42
PHLOG 1014 41.51 39.98 36.43 33.10 30.18 27.66 25.50 23.65
ANNITE 1015 35.17 33.72 30.80 27.95 25.40 23.18 21.26 19.63
DEHYD-ANAL 1021 15.85 15.18 13.93 12.65 11.48 10.45 9.55 8.79
ANAL 1022 9.92 9.78 8.98 8.09 7.27 6.55 5.93 5.41
SEPIO 1023 28.61 31.44 30.27 28.70 27.16 25.78 24.60 23.62
LO-ALB 1025 4.61 5.60 5.42 4.94 4.41 3.92 3.49 3.12
MAX-MICRO 1027 1.10 2.56 2.74 2.57 2.30 2.02 1.77 1.55
K-SPAR 1028 1.11 2.56 2.74 2.57 2.31 2.03 1.79 1.58
HI-SAN 1029 2.50 3.78 3.81 3.50 3.12 2.74 2.41 2.12
ANOR 1030 35.31 31.94 28.21 24.84 21.90 19.36 17.17 15.29
NEPH 1031 17.57 16.13 14.54 13.10 11.84 10.76 9.83 9.04
WOLL 1035 14.68 14.28 13.40 12.54 11.75 11.06 10.45 9.92
DIOP 1039 21.45 21.27 19.83 18.38 17.07 15.91 14.90 14.02
CA-AL PYX 1040 44.71 39.95 35.38 31.41 28.00 25.07 22.56 20.40
AKER 1044 49.11 46.66 43.08 39.81 36.93 34.42 32.23 30.32
MERW 1045 74.10 69.69 64.26 59.40 55.16 51.47 48.27 45.48
MONTI 1046 32.25 30.45 27.97 25.75 23.82 22.14 20.69 19.42
GEHL 1047 67:93 61.31 54.96 49.47 44.77 40.73 37.26 34.25
FORST 1048 29.99 28.30 25.72 23.42 21.43 19.70 18.21 16.92
FAY 1049 21.97 20.64 18.76 17.01 15.47 14.13 12.97 11.96
HUNT 1050 15.43 14.68 12.32 10.16 8.25 6.55 5.05 3.70
ART 1053 21.00 19.98 18.27 16.82 15.60 14.57 13.69 12.95
HED 1054 20.81 20.52 19.19 17.81 16.54 15.41 14.43 13.56
MALACH 1059 -1.27 3.90 4.00 4.00 3.97 3.95 3.94 3.93
AZUR 1060 -0.43 7.17 7.15 6.97 6.77 6.58 6.40 6.33
HYDRO-MAG 1062 36.78 34.83 30.89 27.45 24.48 21.90 19.67 17.71
SMITH 1064 -0.17 0.12 -0.15 -0.44 -0.71 -0.95 -1.17 -1.36
ANH-CORD 1065 70.83 64.65 56.93 49.89 43.71 38.35 33.72 29.72
HYD-CORD 1066 67.33 61.48 54.04 47.24 41.28 36.12 31.66 27.83
JADEITE 1067 9.62 9.66 8.99 8.23 7.50 6.86 6.31 5.85
CER 1068 -2.49 -1.53 -1.36 -1.25 -1.16 -1.07 -0.99 -0.91
STRONT 1069 0.31 0.39 0.28 0.16 0.04 -0.07 -0.18 -0.28
DIS-DOL 1070 6.50 6.23 5.23 4.30 3.47 2.74 2.08 1.48
 357
log K ,P = 4.5 kb
TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1001 6.31 5.29 4.40 2.95 1.82 0.89 0.08 -0.59 -0.97 (-0.72)
1002 5.95 4.97 4.12 2.74 1.66 0.78 0.01 -0.62 -0.97 (-0.70)
1003 6.39 5.35 4.45 2.99 1.84 0.90 0.08 -0.60 -0.98 (-0.74)
1004 2.33 1.75 1.28 0.57 0.06 -0.32 -0.65 -0.90 -0.89 (-0.29)
1007 18.92 17.96 17.13 15.81 14.80 14.01 13.35 12.83 12.56 (12.83)
1012 6.01 5.07 4.28 3.08 2.23 1.57 1.02 0.61 0.60 (1.52)
1013 8.13 7.06 6.16 4.78 3.80 3.04 2.42 1.96 1.91 (2.83)
1014 22.08 20.73 19.59 17.78 16.41 15.34 14.46 13.77 13.48 (14.06)
1015 18.23 17.04 16.03 14.43 13.23 12.28 11.50 10.89 10.66 (11.26)
1021 8.13 7.57 7.09 6.34 5.79 5.36 5.02 4.76 4.67 (4.96)
1022 4.98 4.62 4.34 3.92 3.65 3.48 3035 3.29 3.38 (3.83)
1023 22.81 22.16 21.65 20.95 20.56 20.36 20.26 20.29 20.61 (21.65)
1025 2.82 2.58 2.40 2.16 2.04 2.00 1.99 2.04 2.24 (2.80)
1027 1.39 1.26 1.17 1.08 1.07 1.10 1.16 1.24 1.46 (2.02)
1028 1.41 1.28 1.18 1.08 1.06 1.07 1.10 1.17 1.36 (1.90)
1029 1.88 1.69 1.54 1.36 1.27 1.23 1.22 1.26 1.43 (1.95)
1030 13.66 12.26 11.04 9.05 7.50 6.23 5.14 4.25 3.73 (4.00)
1031 8.37 7.80 7.31 6.54 5.96 5.51 5.15 4.87 4.76 (5.01)
1035 9.45 9.05 8.69 8.10 7.64 7.27 6.96 6.71 6.55 (6.55)
1039 13.26 12.60 12.03 11.11 10.40 9.84 9.37 9.00 8.81 (8.95)
1040 18.52 16.89 15.48 13.13 11.27 9.74 8.42 7.31 6.60 (6.68)
1044 28.66 27.20 25.93 23.80 22.11 20.73 19.56 18.60 17.93 (17.79)
1045 43.04 40.90 39.02 35.86 33.34 31.26 29.50 28.03 26.97 (26.60)
1046 18.32 17.36 16.52 15.11 14.00 13.08 12.31 11.66 11.21 (11.12)
1047 31.65 29.37 27.38 24.08 21.44 19.26 17.39 15.82 14.75 (14.64)
1048 15.79 14.80 13.94 12.51 11.37 10.43 9.64 8.98 8.52 (8.44)
1049 11.08 10.32 9.65 8.55 7.68 6.97 6.37 5.87 5.55 (5.58)
1050 2.48 1.38 0.37 -1.43 -3.06 -4.63 -6.19 -7.68 -8.76 (-8.76)
1053 12.31 11.75 11.28 10.50 9.86 9.32 8.81 8.37 8.10 (8.28)
1054 12.81 12.16 11.60 10.68 9.97 9.40 8.92 8.54 8.33 (8.45)
1059 3.93 3.93 3.94 3.95 3.94 3.91 3.84 3.75 3.73 (3.91)
1060 6.08 5.94 5.81 5.55 5.28 4.97 4.61 4.23 3.98 (4.10)
1062 15.99 14.46 13.10 10.74 8.71 6.84 5.04 3.38 2.22 (2.35)
1064 -1.54 -1.69 -1.84 -2.10 -2.35 -2.61 -2.89 -3.16 -3.35 (-3.28)
1065 26.26 23.27 20.67 16.43 13.10 10.37 8.04 6.13 5.01 (5.55)
1066 24.52 21.66 19.19 15.16 12.03 9.47 7.30 5.52 4.53 (5.19)
1067 5.47 5.16 4.91 4.55 4.33 4.19 4.10 4.06 4.18 (4.64)
1068 -0.83 -0.75 -0.67 -0.53 -0.41 -0.33 -0.29 -0.27 -0.20 (0.08)
1069 -0.37 -0.46 -0.54 -0.70 -0.86 -1.05 -1.25 -1.46 -1.60 (-1.51)
1070 0.95 0.46 0.01 -0.79 -1.52 -2.24 -2.96 -3.65 -4.15 (-4.12)
358 log K ,P = 4.5 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

ORD-DOL 1071 4.76 4.68 3.85 3.06 2.36 1.73 1.16 0.65
ARAG 1072 3.17 3.08 2.72 2.38 2.06 1.77 1.51 1.28
CALC 1073 3.24 3.14 2.76 2.40 2.07 1.77 1.51 1.26
MAG 1074 3.36 3.22 2.62 2.07 1.59 1.17 0.79 0.45
DOL 1075 4.76 4.68 3.85 3.07 2.36 1.73 1.16 0.66
SIDER 1076 1.48 1.29 0.84 0.40 0.00 -0.36 -0.69 -0.98
ANHYD 1078 -3.03 -2.41 -2.66 -3.01 -3.38 -3.76 -4.12 -4.48
FLUORITE 1079 -9.77 -8.05 -7.95 -7.94 -7.97 -8.02 -8.10 -8.18
BARITE 1080 -9.81 -8.54 -8.14 -7.95 -7.86 -7.85 -7.89 -7.96
ANG 1081 -7.42 -5.85 -5.67 -5.64 -5.68 -5.74 -5.81 -5.89
CELEST 1082 -5.40 -4.66 -4.71 -4.88 -5.10 -5.33 -5.57 -5.82
ALUN 1083 8.05 6.14 3.37 0.82 -1.45 -3.45 -5.22 -6.80
WITH 1084 -2.26 -1.80 -1.59 -1.46 -1.39 -1.34 -1.31 -1.30
RHODO 1085 0.46 0.85 0.59 0.32 0.07 -0.15 -0.35 -0.52
COV 1086 -28.87 -23.82 -21.84 -20.26 -18.92 -17.78 -16.79 -15.93
GALENA 1087 -15.96 -13.69 -12.53 -11.60 -10.82 -10.13 -9.53 -8.98
SL 1088 -11.72 -10.36 -9.84 -9.48 -9.20 -8.97 -8.77 -8.60
WURT 1089 ~9.21 -8.06 -7.72 -7.51 -7.36 -7.24 -7.16 -7.08
M-CINN 1090 -41.51 -37.28 -34.50 -32.20 -30.23 -28.51 -27.00 -25.66
CINN 1091 -42.10 -37.79 -34.94 -32.59 -30.57 -28.81 -27.26 -25.89
ALA 1092 -0.47 0.09 -0.14 -0.42 -0.69 -0.94 -1.17 -1.38
.PYRITE 1093 -26.57 -23.87 -22.28 -21.09 -20.15 -19.39 -18.77 -18.25
GOLD 1100 -28.88 -25.92 -23.46 -21.35 -19.52 -17.92 -16.50 -15.22
SILVER 1101 -11.52 -9.86 -8.75 -7.81 -6.98 -6.25 -5.59 -4.99
COPPER 1102 -7.75 -4.64 -4.01 -3.48 -3.01 -2.58 -2.18 -1.80
GRAPHITE 1103 -5.42 -4.89 -4.32 -3.84 -3.44 -3.10 -2.81 -2.57
HALITE 1106 1.33 1.74 1.90 1.97 2.00 2.00 1.99 1.97
SYLVITE 1107 0.51 1.14 1.46 1.66 1.79 1.88 1.93 1.96
COR 1108 28.56 24.37 20.83 17.86 15.35 13.22 11.41 9.85
PER 1109 23.38 21.49 19.49 17.79 16.34 15.09 14.01 13.08
LIME 1110 35.83 32.99 30.37 28.14 26.22 24.56 23.11 21.84
TO 1111 4.24 6.37 6.08 5.79 5.55 5.35 5.19 5.05
CUP 1112 -6.93 -1.47 -0.96 -0.55 -0.19 0.17 0.51 0.84
FE-OXIDE 1113 15.61 14.19 12.77 11.55 10.50 9.60 8.82 8.14
GIBBS 1114 10.53 8.98 7.69 6.63 5.76 5.04 4.44 3.94
DIAS 1115 11.76 9.98 8.47 7.22 6.17 5.29 4.55 3.92
BOEH 1116 12.89 10.96 9.33 7.96 6.82 5.85 5.04 4.34
BRUC 1117 17.45 16.18 14.72 13.49 12.45 11.57 10.82 10.17
MANGAN 1119 19.36 18.11 16.53 15.18 14.02 13.03 12.19 11.45
SPINEL 1120 47.32 41.63 36.40 31.99 28.27 25.10 22.39 20.06
 359
log K ,P = 4.5 kb

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1071 0.19 -0.22 -0.61 -1.31 -1.95 -2.59 -3.25 -3.88 -4.32 (-4.26)
1072 1.07 0.88 0.70 0.37 0.07 -0.23 -0.53 -0.83 -1.04 (-1.01)
1073 1.04 0.84 0.65 0.31 -0.01 -0.32 -0.64 -0.95 -1.18 (-1.15)
1074 0.15 -0.13 -0.38 -0.82 -l.23 -1.62 -2.01 -2.38 -2.65 (-2.64)
1075 0.20 -0.22 -0.61 -1.31 -1.95 -2.59 -3.25 -3.89 -4.34 (-4.28)
1076 -l.24 -1.48 -1.71 -2.11 -2.48 -2.84 -3.21 -3.57 -3.83 (-3.83)
1078 -4.82 -5.16 -5.48 -6.12 -6.75 -7.42 -8.11 -8.80 -9.35 (-9.48)
1079 -8.27 -8.37 -8.47 -8.71 -8.99 -9.33 -9.74 -10.17 -10.47 (-10.33)
1080 -8.05 -8.16 -8.30 -8.60 -8.97 -9.40 -9.90 -10.42 -10.82 (-10.85)
1081 -5.98 -6.07 -6.17 -6.38 -6.63 -6.93 -7.29 -7.66 -7.92 (-7.79)
1082 -6.07 -6.32 -6.57 -7.07 -7.60 -8.16 -8.77 -9.38 -9.85 (-9.93)
1083 -8.21 -9.48 -10.64 -12.70 -14.56 -16.36 -18.18 -19.91 -21.10 (-20.82)
1084 -l.29 -1.30 -1.31 -1.35 -1.42 -1.53 -1.68 -1.84 -1.94 (-1.84)
1085 -0.67 -0.81 -0.93 -1.16 -1.36 -1.57 -1.80 -2.02 -2.15 (-2.03)
1086 -15.17 -14.50 -13.90 -12.89 -12.09 -11.46 -10.96 -10.57 -10.19 (-9.70)
1087 -8.49 -8.05 -7.64 -6.93 -6.33 -5.85 -5.46 -5.14 . -4.79 (-4.26)
1088 -8.46 -8.33 -8.23 -8.05 -7.94 -7.89 -7.90 -7.94 -7.91 (-7.64)
1089 -7.02 -6.97 -6.92 -6.87 -6.85 -6.88 -6.96 -7.07 -7.10 (-6.87)
1090 -24.46 -23.38 -22.41 -20.71 -19.30 -18.14 -17.17 -16.35 -15.57 (-14.64)
1091 -24.66 -23.55 -22.55 -20.82 -19.37 -18.18 -17.18 -16.34 -15.53 (-14.60)
1092 -1.56 -1.73 -1.89 -2.17 -2.44 -2.71 -2.99 -3.26 -3.44 (-3.35)
1093 -17.83 -17.49 -17.20 -16.79 -16.57 -16.51 -16.60 -16.78 -16.87 (-16.57)
1100 -14.08 -13.04 -12.10 -10.44 -9.02 -7.80 -6.73 -5.78 -4.94 (-4.19)
1101 -4.45 -3.94 -3.48 -2.65 -1.92 -l.27 -0.69 -0.17 0.31 (0.74)
1102 -1.45 -1.13 -0.81 -0.24 0.28 0.78 l.20 1.60 1.98 (2.35)
1103 -2.35 -2.17 -2.01 -1.75 -1.56 -1.42 -1.32 -l.25 -1.19 (-1.11)
1106 1.94 1.90 1.87 1.78 1.68 1.55 1.40 l.24 1.14 (1.19)
1107 1.97 1.97 1.95 1.89 1.79 1.66 1.49 1.31 1.17 0.17)
1108 8.51 7.36 6.35 4.69 3.38 2.28 1.33 0.53 0.03 (0.15)
1109 12.26 11.53 10.90 9.82 8.94 8.21 7.59 7.05 6.64 (6.44)
1110 20.73 19.73 18.85 17.34 16.10 15.06 14.16 13.40 12.78 02.36)
1111 4.94 4.85 4.78 4.67 4.60 4.56 4.53 4.51 4.52 (4.59)
1112 1.17 1.49 1.80 2.39 2.95 3.47 3.96 4.42 4.88 (5.38)
1113 7.55 7.03 6.58 5.81 5.19 4.67 4.67 3.85 3.58 (3.48)
1114 3.53 3.18 2.89 2.44 2.11 1.84 1.60 1.40 1.32 0.53)
1115 3.38 2.93 2.54 1.92 1.44 1.05 0.72 0.44 0.31 (0.47)
1116 3.75 3.24 2.80 2.10 1.55 1.10 0.72 0.40 0.22 (0.36)
1117 9.62 9.13 8.71 8.02 7.47 7.01 6.63 6.31 6.09 (6.05)
1119 10.82 10.27 9.78 8.98 8.35 7.83 7.40 7.04 6.78 (6.70)
1120 18.05 16.30 14.77 12.24 10.22 8.54 7.09 5.87 5.05 (5.04)
360 log K ,P = 4.5 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

K-OXIDE 1123 90.05 83.47 77.82 72.95 68.74 65.06 61.82 58.95
NA-OXIDE 1124 72.44 67.03 62.40 58.45 55.04 52.09 49.51 47.24
AMORPH SIL 1125 -2.80 -1.98 -1.60 -1.38 -1.23 -1.12 -1.04 -0.97
A-CRIST 1126 -3.97 -2.97 -2.46 -2.14 -1.91 -1.74 -1.60 -1.49
B-CRIST 1127 -3.31 -2.40 -1.96 -1.69 -1.50 -1.37 -1.26 -1.18
CHALCED 1128 -4.55 -3.49 -2.93 -2.57 -2.30 -2.10 -1.93 -1.79
WAIR 1130 25.75 24.44 21.80 19.15 16.75 14.63 12.79 11.20
LAUM 1132 19.44 19.04 17.18 15.21 13.40 11.82 10.45 9.30
ACAN 1501 -41.48 -36.55 -33.27 -30.57 -28.27 -26.28 -24.54 -23.00
CP 1502 -38.38 -32.42 -30.08 -28.26 -26.76 -25.49 -24.41 -23.48
BN 1503 -124.42 -101.44 -93.29 -86.74 -81.19 -76.41 -72.22 -68.52
CC 1504 -42.94 -34.34 -31.36 -28.93 -26.86 -25.08 -23.52 -22.14
QTZ 1505 -4.86 -3.77 -3.19 -2.80 -2.52 -2.30 -2.12 -1.97
MG 1506 33.53 30.62 27.41 24.61 22.22 20.16 18.39 16.86
KALS 1507 13.98 12.99 11.77 10.63 9.63 8.76 8.02 7.39
FERROSIL 1508 8.28 8.20 7.59 6.94 6.33 5.79 5.32 4.91
PYROPH 1509 3.68 4.48 3.82 2.86 1.90 1.02 0.25 -0.40
TALC 1510 20.73 22.15 20.79 19.22 17.72 16.38 15.21 14.21
7-A CL 1512 80.89 75.27 67.51 60.68 54.82 49.82 45.54 41.89
14-A CL 1513 76.92 71.55 64.00 57.34 51.62 46.74 42.57 39.01
CLNZ 1515 53.68 48.92 43.48 38.57 34.30 30.63 27.48 24.78
LAWS 1516 27.21 24.97 22.21 19.69 17.50 15.63 14.04 12.69
TREM 1517 62.03 63.20 59.08 54.71 50.66 47.07 43.94 41.23
ANTH 1518 68.37 68.77 63.60 58.35 53.55 49.31 45.62 42.41
ZOIS 1519 53.70 48.94 43.50 38.59 34.32 30.64 27.49 24.79
GROSS 1529 59.62 55.52 50.42 45.77 41.71 38.20 35.18 32.58
ANDRA 1530 54.69 52.78 49.00 45.39 42.18 39.37 36.93 34.81
ALB 1531 4.61 5.60 5.42 4.94 4.41 3.92 3.49 3.12
PREHN 1532 40.04 37.46 33.86 30.50 27.55 24.99 22.79 20.91
ENST 1537 11.74 11.51 10.57 9.67 8.86 8.14 7.52 6.98
PARG 1538 116.75 109.05 98.47 88.87 80.49 73.25 67.02 61.65
ANTIG 1542 496.30 486.11 446.95 410.41 378.32 350.61 326.84 306.51
HM 1544 21.20 19.41 17.38 15.60 14.07 12.76 11.63 10.65
ORD-EP 1545 50.06 46.49 41.80 37.48 33.70 30.43 27.62 25.21
MARG 1551 55.58 48.95 42.48 36.84 32.01 27.89 24.37 21.37
MERCURY 1552 -22.22 -19.85 -18.37 -17.08 -15.94 -14.90 -13.95 -13.07
PO 1555 -3.33 -2.92 -2.98 -3.11 -3.27 -3.43 -3.59 -3.76
NESQ 1558 6.54 5.63 5.49 5.42 5.37 5.33 5.30 5.28
EPID 1559 50.06 46.49 41.80 37.47 33.69 30.42 27.61 25.19
HI-ALB 1560 6.14 6.95 6.61 6.01 5.37 4.78 4.26 3.81
 361
log K ,P = 4.5 kb

TEMPERATURE, °C
INDEX
200 225 250 300 350 400 450 500 550 600

1123 56.39 54.10 52.04 48.47 45.50 42.98 40.83 38.96 37.35 (35.96)
1124 45.24 43.45 41.86 39.15 36.93 35.08 33.53 32.21 31.11 (30.22)
1125 -0.91 -0.87 -0.83 -0.78 -0.74 -0.73 -0.73 -0.74 -0.76 (-0.78)
1126 -1.39 -1.30 -1.22 -1.09 -0.96 -0.86 -0.76 -0.67 -0.58 (-0.48)
1127 -1.10 -1.03 -0.97 -0.87 -0.77 -0.69 -0.61 -0.53 -0.46 (-0.37)
1128 -1.67 -1.57 -1.47 -1.30 -1.15 -1.02 -0.91 -0.80 -0.70 (-0.59)
1130 9.85 8.68 7.69 6.11 4.92 3.97 3.19 2.57 2.32 (2.87)
1132 8.34 7.53 6.87 5.87 5.19 4.69 4.30 4.04 4.10 (4.94)
1501 -21.66 -20.46 -19.38 -17.54 -16.01 -14.81 -13.80 -12.94 -12.15 (-11.29)
1502 -22.66 -21.94 -21.31 -20.27 -19.48 -18.93 -18.56 -18.32 -18.02 (-17.39)
1503 -65.23 -62.30 -59.69 -55.23 -51.61 -48.69 -46.35 -44.43 -42.56 (-40.13)
1504 -20.90 -19.79 -18.78 -17.04 -15.58 -14.36 -13.34 -12.47 -11.66 (-10.74)
1505 -1.84 -1.72 -1.62 -1.43 -1.27 -1.13 -1.01 -0.89 -0.78 (-0.67)
1506 15.53 14.36 13.34 11.62 10.23 9.05 8.01 7.11 6.47 (6.36)
1507 6.85 6.39 6.01 5.39 4.94 4.58 4.27 4.04 3.95 (4.20)
1508 4.55 4.24 3.97 3.53 3.19 2.92 2.69 2.51 2.41 (2.49)
1509 -0.94 -1.38 -1.74 -2.25 -2.57 -2.80 -2.97 -3.07 -2.92 (-2.15)
1510 13.35 12.62 12.01 11.06 10.38 9.86 9.46 9.18 9.14 (9.65)
1512 38.76 36.08 33.77 30.04 27.16 24.83 22.86 21.25 20.36 (20.97)
1513 35.97 33.36 31.11 27.50 24.71 22.46 20.57 19.03 18.20 (18.86)
1515 22.47 20.48 18.77 16.01 13.88 12.15 10.69 9.49 8.87 (9.48)
1516 11.55 10.59 9.78 8.52 7.58 6.85 6.24· 5.76 5.62 (6.23)
1517 38.90 36.90 35.19 32.47 30.43 28.83 27.54 26.55 26.15 (26.97)
1518 39.65 37.26 35.21 31.89 29.35 27.34 25.69 24.39 23.73 (24.38)
1519 22.47 20.49 18.77 16.01 13.88 12.15 10.68 9.49 8.87 (9.48)
1529 30.35 28.42 26.75 24.04 21.94 20.24 18.80 17.63 16.97 (17.40)
1530 32.97 31.38 29.99 27.71 25.92 24.46 23.22 22.20 21.58 (21.80)
1531 2.82 2.58 2.40 2.15 2.03 1.97 1.95 1.97 2.15 (2.68)
1532 19.30 17.93 16.75 14.87 13.45 12.31 11.35 10.58 10.23 (10.80)
1537 6.51 6.10 5.75 5.17 4.72 4.35 4.04 3.79 3.64 (3.69)
1538 57.01 53.02 49.55 43.91 39.54 35.99 33.02 30.60 29.19 (29.83)
1542 289.14 274.30 261.60 241.33 226.03 213.93 203.97 196.10 192.31 (197.06)
1544 9.79 9.05 8.39 7.29 6.40 5.64 4.96 4.38 3.97 (3.93)
1545 23.13 21.35 19.82 17.33 15.42 13.87 12.55 11.48 10.92 (11.47)
1551 18.80 16.60 14.71 11.64 9.27 7.34 5.69 4.33 3.61 (4.27)
1552 -12.26 -11.50 -10.79 -9.50 -8.35 -7.64 -7.02 -6.44 -5.87 (-5.27)
1555 -3.92 -4.07 -4.22 -4.51 -4.79 -5.09 -5.41 -5.73 -5.95 (-5.90)
1558 5.27 5.26 5.25 5.22 5.16 5.06 4.91 4.74 4.62 (4.75)
1559 23.11 21.32 19.78 17.29 15.36 13.80 12.46 11.38 10.81 (11.35)
1560 3.45 3.14 2.90 2.57 2.37 2.25 2.18 2.17 2.32 (2.83)
362 Log K, P = 5 kb

TEMPERATURE, DC
NAME INDEX
0 25 50 75 100 125 150 175

AND 1001 23.10 20,22 17.37 14.83 12.65 10.77 9.15 7.77
KYA 1002 22.05 19.30 16.55 14.11 12.00 10.19 8.64 7.32
SILL 1003 23.36 20.44 17.55 14.99 12.78 10.88 9.25 7.85
KAOL 1004 11.47 10.58 9.05 7.56 6.22 5.07 4.09 3.26
CHRYS 1007 31.52 31.25 28.78 26.46 24.42 22.66 21.14 19.85
MUSC 1012 20.65 19.26 16.84 14.45 12.30 10.44 8.85 7.50
PARAG 1013 25.15 23.24 20.40 17.66 15.22 13.11 11.32 9.79
PHLOG 1014 40.25 39.46 36.09 32.86 30.00 27.52 25.39 23.57
ANNITE 1015 34.36 33.57 30.84 28.07 25.56 23.37 21.47 19.85
DEHYD-ANAL 1021 15.69 15.27 14.11 12.87 11.72 10.70 9.81 9.04
ANAL 1022 9.69 9.80 9.09 8.26 7.46 6.75 6.13 5.62
SEPIO 1023 26.83 30.66 29.73 28.28 26.82 25.50 24.36 23.40
LO-ALB 1025 4.23 5.56 5.50 5.09 4.60 4.12 3.70 3.34
MAX-MICRO 1027 0.73 2.52 2.82 2.71 2.47 2.21 1.97 1.76
K-SPAR 1028 0.74 2.52 2.82 2.72 2.48 2.22 1.99 1.78
HI-SAN 1029 2.14 3.74 3.89 3.65 3.30 2.94 2.61 2.32
ANOR 1030 35.13 32.09 28.46 25.13 22.21 19.68 17.49 15.61
NEPH 1031 17.40 16.14 14.63 13.22 11.98 10.91 9.98 9.20
WOLL 1035 14.41 14.18 13.35 12.50 11.73 11.05 10.44 9.91
DIOP 1039 20.73 20.93 19.59 18.20 16.92 15.78 14.79 13.93
CA-AL PYX 1040 44.50 40.01 35.51 31.57 28.18 25.27 22.76 20.60
AKER 1044 48.32 46.33 42.87 39.65 36.80 34.31 32.14 30.25
MERW 1045 73.09 69.25 63.94 59.15 54.95 51.29 48.12 45.35
MONTI 1046 31.71 30.22 27.80 25.61 23.70 22.04 20.60 19.35
GEHL 1047 67.64 61.38 55.12 49.67 44.98 40.95 37.48 34.48
FORST 1048 29.33 27.99 25.47 23.21 21.25 19.54 18.06 16.78
FAY 1049 21.60 20.57 18.76 17.04 15.52 14.91 13.03 12.02
HUNT 1050 14.70 14.61 12.35 10.25 8.37 6.70 5.21 3.88
ART 1053 20.46 19.75 18.09 16.66 15.45 14.44 13.57 12.83
HED 1054 20.24 20.32 19.08 17.75 16.51 15.40 14.43 13.57
MALACH 1059 -2.79 3.78 3.95 3.97 3.97 3.96 3.95 3.95
AZUR 1060 -2.61 7.11 7.19 7.05 6.87 6.68 6.51 6.35
HYDRO-MAG 1062 35.69 34.57 30.75 27.37 24.43 21.89 19.68 17.74
SMITH 1064 -0.56 -0.02 -0.25 -0.51 -0.77 -1.00 -1.20 -1.39
ANH-CORD 1065 70.34 64.98 57.48 50.52 44.38 39.04 34.42 30.42
HYD-CORD 1066 66.77 61.73 54.52 47.82 41.90 36.75 32.31 28.47
JADEITE 1067 9.18 9.49 8.94 8.24 7.55 6.93 6.39 5.94
CER 1068 -2.66 -1.44 -1.24 -1.12 -1.03 -0.94 -0.86 -0.78
STRONT 1069 0.24 0.43 0.34 0.23 0.11 0.00 -0.10 -0.20
DIS-DOL 1070 6.19 6.22 5.28 4.38 3.56 2.83 2.18 1.59
 log K ,P = 5 kb 363

TEMPERATURE, °C
INDEX
200 225 250 300 350 400 450 500 550 600

1001 6.58 5.55 4.66 3.22 2.09 1.17 0.37 -0.27 -0.62 (-0.34)
1002 6.17 5.19 4.35 2.97 1.90 1.02 0.28 -0.33 -0.65 (-0.34)
1003 6.64 5.61 4.71 3.25 2.10 1.17 0.37 -0.29 -0.64 (-0.37)
1004 2.57 2.00 1.53 0.81 0.31 -0.07 -0.39 -0.61 -0.58 (0.06)
1007 18.74 17.79 16.98 15.69 14.71 13.93 13.30 12.81 12.58 02.89)
1012 6.38 5.44 4.65 3.46 2.62 1.97 1.45 1.07 1.11 (2.07)
1013 8.52 7.45 6.55 5.18 4.20 3.46 2.86 2.44 2.44 (3.40)
1014 22.01 20.69 19.57 17.78 16.45 15.41 14.57 13.92 13.69 (14.32)
1015 18.46 17.28 16.27 14.67 13.49 12.56 11.80 11.22 11.03 (I 1.67)
1021 8.39 7.82 7.35 6.59 6.03 5.61 5.27 5.02 4.95 (5.25)
1022 5.18 4.83 4.54 4.12 3.85 3.68 3.56 3.51 3.62 (4.08)
1023 22.62 21.99 21.49 20.83 20.46 20.28 20.22 20.27 20.64 (21.72)
1025 3.05 2.81 2.62 2.38 2.27 2.23 2.23 2.29 2.50 (3.08)
1027 1.59 1.47 1.38 1.29 1.28 1.32 1.38 1.47 1.71 (2.28)
1028 1.61 1.48 1.39 1.LOt
~~" 1.27 1.29 1.32 1.40 1.61 (2.16)
1029 2.09 1.90 1.75 1.57 1.48 1.45 1.44 1.49 1.68 (2.20
1030 13.98 12.58 \1.36 9.37 7.83 6.56 5.49 4.63 4.15 (4.46)
1031 8.53 7.96 7.47 6.70 6.13 5.68 5.33 5.06 4.97 (5.23)
1035 9.45 9.05 8.70 8.12 7.66 7.29 6.99 6.75 6.60 (6.60
1039 13.18 12.53 11.97 11.07 10.38 9.83 9.38 9.03 8.86 (9.02)
1040 18.73 17.11 '15.69 13.36 11.51 9.99 8.69 7.62 6.95 (7.07)
1044 28.60 27.16 25.89 23.78 22.11 20.75 19.61 18.67 18.03 (I7.90
1045 42.92 40.80 38.93 35.80 33.30 31.25 29.52 28.09 27.06 (26.73)
1046 18.26 17.30 16.47 15.08 13.98 13.07 12.31 11.69 11.26 (11.19)
1047 31.88 29.61 27.62 24.33 21.70 19.54 17.70 16.16 15.14 (15.08)
1048 15.67 14.70 13.85 12.43 11.31 10.39 9.62 8.98 8.55 (8.50)
1049 11.15 10.39 9.72 8.63 7.77 7.06 6.47 5.99 5.68 (5.73)
1050 2.68 1.59 0.60 -1.16 -2.76 -4.28 -5.80 -7.22 -8.21 (-8.14)
1053 12.20 11.66 11.19 10.43 9.81 9.28 8.80 8.37 8.14 (8.35)
1054 12.83 12.19 11.63 10.72 10.02 9.46 9.00 8.63 8.44 (8.58)
1059 3.95 3.95 3.96 3.98 3.98 3.96 3.90 3.82 3.82 (4.02)
1060 6.20 6.08 5.94 5.69 5.43 5.13 4.79 4.44 4.21 (4.37)
1062 16.04 14.53 13.19 10.87 8.89 7.06 5.32 3.73 2.67 (2.88)
1064 -1.55 -1.70 -1.84 -2.09 -2.32 -2.57 -2.83 -3.08 -3.25 (-3.16)
1065 26.96 23.97 21.38 17.13 13.81 11.10 8.82 6.96 5.92 (6.54)
1066 25.17 22.31 19.84 15.82 12.70 10.16 8.03 6.31 5.40 (6.13)
1067 5.57 5.26 5.02 4.67 4.46 4.33 4.25 4.23 4.36 (4.85)
1068 -0.70 -0.62 -0.54 -0.40 -0.28 -0.19 -0.15 -0.12 -0.03 (0.27)
1069 -0.29 -0.38 -0.46 -0.61 -0.77 -0.94 -1.14 -1.34 -1.45 (-1.35)
1070 1.07 0.59 0.15 -0.64 -1.36 -2.06 -2.75 -3.41 -3.87 (-3.80
364 log K ,P = 5 kb

TEMPERATURE, ·C
NAME INDEX
0 25 50 75 100 125 150 175

ORD-DOL 1071 4.45 4.67 3.89 3.14 2.44 1.82 1.27 0.77
ARAG 1072 3.06 3.10 2.77 2.43 2.12 1.84 1.58 1.35
CALC 1073 3.16 3.18 2.83 2.48 2.16 1.86 1.59 1.35
MAG 1074 3.14 3.17 2.60 2.07 1.60 1.18 0.81 0.48
DOL 1075 4.45 4.68 3.90 3.14 2.45 1.83 1.27 0.77
SIDER 1076 1.41 1.37 0.95 0.52 0.12 -0.23 -0.56 -0.85
ANHYD 1078 -3.36 -2.44 -2.65 -2.98 -3.34 -3.70 -4.06 -4.41
FLUORITE 1079 -10.18 -7.99 -7.88 -7.87 -7.89 -7.94 -8.01 -8.09
BARITE 1080 -10.26 -8.67 -8.20 -7.98 -7.87 -7.85 -7.87 -7.93
ANG 1081 -7.84 -5.85 -5.62 -5.57 -5.60 -5.65 -5.72 -5.80
CELEST 1082 -5.73 -4.71 -4.72 -4.87 -5.07 -5.30 -5.54 -5.78
ALUN 1083 7.52 6.24 3.60 1.11 -1.12 -3.10 -4.86 -6.43
WITH 1084 -2.44 -1.84 -1.57 -1.43 -1.34 -1.28 -1.25 -1.23
RHODO 1085 0.24 0.87 0.64 0.39 0.14 -0.07 -0.26 -0.44
COV 1086 -29.71 -23.89 -21.86 -20.25 -18.91 -17.79 -16.77 -15.90
GALENA 1087 -16.25 -13.67 -12.47 -11.53 -10.73 -10.04 -9.44 -8.89
SL 1088 -12.00 -10.35 -9.79 -9.41 -9.12 -8.89 -8.69 -8.52
WURT 1089 -9.49 -8.05 -7.67 -7.45 -7.29 -7.17 -7.07 -7.00
M-CINN 1090 -41.80 -37.24 -34.42 -32.10 -30.13 -28.41 -26.90 -25.56
CINN 1091 -42.40 -37.76 -34.88 -32.50 -30.48 -28.72 -27.17 -25.79
ALA 1092 -0.82 0.04 -0.15 -0.41 -0.67 -0.91 -1.13 -1.33
PYRITE 1093 -26.95 -23.92 -22.25 -21.03 -20.07 -19.30 -18.67 -18.15
GOLD 1100 -29.19 -26.16 -23.66 -21.53 -19.69 -18.07 -16.64 -15.36
SILVER 1101 -11.82 -10.00 -8.87 -7.91 -7.08 -6.34 -5.67 -5.07
COPPER 1102 -8.50 -4.74 -4.08 -3.54 -3.06 -2.63 -2.22 -1.85
GRAPHITE 1103 -5.34 -4.82 -4.24 -3.76 -3.36 -3.02 -2.73 -2.49
HALITE 1106 1.14 1.68 1.89 1.99 2.03 2.04 2.04 2.02
SYLVITE 1107 0.35 1.10 1.46 1.68 1.83 1.92 1.98 2.01
COR 1108 28.63 24.55 21.04 18.08 15.57 13.44 11.63 10.07
PER 1109 23.11 21.36 19.37 17.68 16.24 15.00 13.93 13.00
LIME 1110 35.67 32.91 30.31 28.09 26.17 24.52 23.08 21.81
TO 1111 3.46 6.28 6.01 5.74 5.50 5.31 5.15 5.02
CUP 1112 -8.42 -1.63 -1.06 -0.64 -0.26 0.10 0.45 0.79
FE-OXIDE 1113 15.48 14.17 12.78 11.56 10.51 9.61 8.84 8.16
GIBBS 1114 10.52 9.03 7.76 6.70 5.83 5.11 4.51 4.01
DIAS 1115 11.77 10.04 8.55 7.31 6.26 5.38 4.64 4.01
BOEH 1116 12.92 11.04 9.42 8.06 6.92 5.95 5.14 4.44
BRUC 1117 17.15 16.03 14.58 13.36 12.33 11.46 10.72 10.08
MANGAN 1119 19.08 18.03 16.48 15.13 13.98 13.00 12.15 11.43
SPINEL 1120 47.15 41.69 36.51 32.13 28.41 25.25 22.55 20.22
 log K ,P = 5 kb 365

TEMPERATURE, ·C
INDEX
200 225 250 300 350 400 450 500 550 600

1071 0.31 -0.10 -0.48 -1.16 -1.79 -2.41 -3.04 -3.67 -4.04 (-3.94)
1072 1.14 0.95 0.78 0.46 0.17 -0.13 -0.42 -0.70 -0.90 (-0.85)
1073 1.13 0.93 0.74 0.41 0.10 -0.21 -0.52 -0.82 -1.02 (-0.99)
1074 0.18 -0.09 -0.33 -0.77 -1.16 -1.54 -1.92 -2.27 -2.52 (-2.49)
1075 0.32 -0.10 -0.47 -1.16 -1.79 -2.41 -3.04 -3.65 -4.06 (-3.97)
1076 -1.12 -1.36 -1.58 -1.98 -2.34 -2.70 -3.06 -3.41 -3.65 (-3.63)
1078 -4.75 -5.08 -5.40 -6.02 -6.64 -7.28 -7.96 -8.62 -9.13 (-9.23)
1079 -8.18 -8.27 -8.37 -8.59 -8.86 -9.18 -9.57 -9.97 -10.23 (-10.07)
1080 -8.01 -8.12 -8.24 -8.53 -8.88 -9.30 -9.77 -10.27 -10.64 (-10.64)
1081 -5.88 -5.97 -6.06 -6.26 -6.49 -6.78 -7.12 -7.47 -7.70 (-7.54)
1082 -6.02 -6.26 -6.50 -6.99 -7.50 -8.04 -8.63 -9.22 -9.66 (-9.70)
1083 -7.83 -9.09 -10.24 -12.27 -14.10 -15.86 -17.62 -19.28 -20.37 (-20.00)
1084 -1.22 -1.23 -1.23 -1.27 -1.33 -1.44 -1.57 -1.72 -1.81 (-1.69)
1085 -0.59 -0.72 -0.84 -1.06 -1.26 -1.46 -1.67 -1.88 -2.00 (-1.86)
1086 -15.14 -14.46 -13.86 -12.84 -12.03 -11.39 -10.88 -10.48 -10.09 (-9.58)
1087 -8.40 -8.95 -7.54 -6.82 -6.23 -5.74 -5.34 -5.01 -4.64 (-4.09)
1088 -8.38 -8.25 -8.14 -7.96 -7.83 -7.77 -7.77 -7.80 -7.75 (-7.46)
1089 -6.93 -6.88 -6.83 -6.77 -6.74 -6.77 -6.84 -6.92 -6.93 (-6.69)
1090 -24.36 -23.27 -22.30 -20.60 -19.18 -18.01 -17.04 -16.20 -15.40 (-14.47)
1091 -24.56 -23.45 -22.45 -20.71 -19.26 -18.06 -17.06 -16.20 -15.38 (-14.43)
1092 -1.52 -1.68 -1.83 -2.08 -2.36 -2.62 -2.89 -3.14 -3.30 (-3.19)
1093 -17.72 -17.36 -17.07 -16.65 -16.41 -16.33 -16.40 -16.54 -16.60 (-16.27)
1100 -14.20 -13.16 -12.21 -10.54 -9.12 -7.89 -6.81 -5.86 -5.02 (-4.26)
1101 -4.52 -4.01 -3.55 -2.71 -1.97 -1.32 -0.74 -0.22 0.26 (0.70)
1102 -1.50 -1.17 -0.85 -0.27 0.25 0.73 1.17 1.57 1.96 (2.32)
1103 -2.27 -2.09 -1.93 -1.68 -1.49 -1.34 -1.24 -1.17 -1.11 (-1.03)
1106 1.99 1.96 1.93 1.85 1.75 1.63 1.49 1.34 1.25 0.31)
1107 2.02 2.02 2.01 1.95 1.86 1.73 1.57 1.40 1.27 (1.28)
1108 8.73 7.57 6.57 4.91 3.60 2.52 1.59 0.81 0.34 (0.49)
1109 12.19 11.47 10.84 9.77 8.90 8.18 7.56 7.04 6.65 (6.45)
1110 20.69 19.70 18.82 17.32 16.08 15.05 14.16 13.41 12.79 02.38)
1111 4.91 4.82 4.75 4.65 4.58 4.54 4.51 4.50 4.52 (4.59)
1112 1.12 1.44 1.75 2.35 2.91 3.44 3.94 4.40 4.86 (5.37)
1113 7.57 7.05 6.60 5.83 5.22 4.70 4.27 3.90 3.63 (3.54)
1114 3.60 3.25 2.97 2.52 2.19 1.92 1.69 LSO 1.44 (1.66)
1115 3.47 3.02 2.63 2.01 1.53 1.15 0.82 0.56 0.44 (0.62)
1116 3.85 3.34 2.90 2.20 1.65 1.21 0.83 0.53 0.37 (0.51)
1117 9.52 9.05 8.63 7.94 7.40 6.96 6.58 6.27 6.06 (6.04)
1119 10.80 10.25 9.77 8.97 8.34 7.83 7.40 7.05 6.81 (6.74)
1120 18.21 16.47 14.94 12.42 10.42 8.76 7.33 6.14 5.37 (5.40)
366 log K ,P = 5 kb

TEMPERATURE, DC
NAME INDEX
0 25 50 75 100 125 150 175

K-OXIDE 1123 89.74 83.27 77.66 72.82 68.63 64.96 61.73 58.87
NA-OXIDE 1124 72.12 66.83 62.27 58.35 54.97 52.03 49.46 47.20
AMORPH SIL 1125 -2.85 -1.96 -1.55 -1.32 -1.16 -1.05 -0.97 -0.90
A-CRIST 1126 -4.05 -2.98 -2.44 -2.10 -1.87 -1.69 -1.55 -1.44
B-CRIST 1127 -3.38 -2.39 -1.92 -1.64 -1.45 -1.31 -1.21 -1.12
CHALCED 1128 -4.66 -3.53 -2.93 -2.55 -2.28 -2.07 -1.91 -1.77
WAIR 1130 25.44 24.61 22.12 19.53 17.15 15.04 13.21 11.62
LAUM 1132 19.03 19.11 17.40 15.50 13.72 12.15 10.80 9.64
ACAN 1501 -42.15 -36.81 -33.45 -30.71 -28.39 -26.39 -24.63 -23.08
CP 1502 -39.40 -32.47 -30.03 -28.17 -26.65 -25.38 -24.28 -23.34
BN 1503 -128.61 -101.81 -93.42 -86.77 -81.17 -76.34 -72.13 -68.41
CC 1504 -44.53 -34.50 -31.46 -28.99 -26.90 -25.11 -23.54 -22.15
QTZ 1505 -4.97 -3.81 -3.19 -2.79 -2.50 -2.28 -2.10 -1.94
MG 1506 33.16 30.60 27.45 24.68 22.29 20.24 18.47 16.94
KALS 1507 13.79 12.98 11.83 10.72 9.74 8.88 8.14 7.51
FERROSIL 1508 8.02 8.14 7.58 6.95 6.36 5.82 5.35 4.94
PYROPH 1509 3.27 4.47 3.97 3.09 2.16 1.30 0.54 -0.10
TALC 1510 19.45 21.58 20.40 18.92 17.48 16.18 15.04 14.06
7-A CL 1512 79.28 74.66 67.11 60.39 54.59 49.63 45.40 41.78
14-A CL 1513 75.27 70.91 63.56 57.01 51.36 46.53 42.40 38.87
CLNZ 1515 53.02 48.84 43.57 38.75 34.52 30.88 27.75 25.06
LAWS 1516 26.74 24.85 22.20 19.74 17.59 15.73 14.15 12.82
TREM 1517 59.34 62.01 58.25 54.07 50.15 46.64 43.58 40.92
ANTH 1518 65.49 67.48 62.67 57.62 52.95 48.81 45.18 42.04
ZOIS 1519 53.05 48.86 43.59 38.76 34.53 30.89 27.75 25.07
GROSS 1529 58.70 55.22 50.30 45.74 41.73 38.26 35.26 32.68
ANDRA 1530 53.44 52.28 48.70 45.19 42.03 39.25 36.84 34.75
ALB 1531 4.23 5.56 5.50 5.09 4.60 4.12 3.70 3.34
PREHN 1532 39.44 37.37 33.92 30.64 27.72 25.18 23.00 21.13
ENST 1537 11.34 11.32 l0A3 9.55 8.76 8.06 7.45 6.92
PARG 1538 114.57 108.27 98.05 88.64 80.37 73.21 67.03 61.70
ANTIG 1542 479.19 478.17 440.80 405.27 373.85 346.66 323.30 303.31
HM 1544 20.93 19.39 17.40 15.63 14.11 12.81 11.68 10.70
ORD-EP 1545 49.24 46.32 41.80 37.57 33.83 30.59 27.80 25.40
MARG 1551 55.35 49.17 42.83 37.25 32.44 28.34 24.83 21.83
MERCURY 1552 -22.43 -19.86 -18.36 -17.07 -15.92 -14.88 -13.93 -13.05
PO 1555 -3.55 -2.93 -2.95 -3.06 -3.21 -3.36 -3.52 -3.68
NESQ 1558 6.31 5.58 5.46 5.40 5.36 5.32 5.30 5.28
EPID 1559 49.24 46.32 41.80 37.57 33.83 30.59 27.79 25.39
HI-ALB 1560 5.76 6.91 6.70 6.16 5.55 4.98 4.47 4.04
 log K ,P = 5 kb 367

TEMPERATURE, °C
INDEX
200 225 250 300 350 400 450 500 550 600

1123 56.32 54.04 51.98 48.42 45.45 42.94 40.79 38.93 37.32 (35.93)
1124 45.21 43.43 41.84 39.14 36.92 35.08 33.53 32.22 31.11 (30.23)
1125 -0.85 -0.80 -0.77 -0.72 -0.68 -0.67 -0.67 -0.69 -0.71 (-0.73)
1126 -1.34 -1.25 -1.18 -1.04 -0.92 -0.82 -0.72 -0.63 -0.54 (-0.44)
1127 -1.04 -0.98 -0.92 -0.82 -0.72 -0.64 -0.56 -0.49 -0.41 (-0.33)
1128 -1.64 -1.54 -1.44 -1.27 -1.12 -1.00 -0.88 -0.77 -0.67 (-0.56)
1130 10.26 9.09 8.10 6.51 5.32 4.37 3.60 3.01 2.79 (3.37)
1132 8.68 7.87 7.20 6.20 5.52 5.02 4.64 4.40 4.50 (5.37)
1501 -21.72 -20.51 -19.43 -17.57 -16.05 -14.82 -13.79 -12.92 -12.11 (-11.24)
1502 -22.52 -21.80 -21.16 -20.11 -19.31 -18.73 -18.35 -18.07 -17.74 (-17.08)
1503 -65.10 -62.15 -59.52 -55.03 -51.38 -48.42 -46.04 -44.06 -42.12 (-39.62)
1504 -20.91 -19.79 -18.78 -17.02 -15.55 -14.32 -13.29 -12.41 -11.57 (-10.65)
1505 -1.81 -1.69 -1.59 -1.40 -1.24 -1.10 -0.98 -0.86 -0.75 (-0.64)
1506 15.61 14.45 13.43 11.72 10.34 9.17 8.15 7.27 6.66 (6.59)
1507 6.98 6.52 6.14 5.53 5.07 4.72 4.42 4.20 4.13 (4.39)
1508 4.59 4.28 4.01 3.58 3.24 2.97 2.75 2.58 2.49 (2.58)
1509 -0.63 -1.07 -1.43 -1.94 -2.26 -2.48 -2.64 -2.72 -2.53 (-1.73)
1510 13.23 12.52 11.92 11.00 10.34 9.86 9.48 9.23 9.23 (9.77)
1512 38.68 36.02 33.73 30.05 27.21 24.93 23.02 21.49 20.69 (21.39)
1513 35.86 33.27 31.06 27.48 24.75 22.55 20.71 19.25 18.51 (19.26)
1515 22.76 20.78 19.08 16.33 14.23 12.52 11.10 9.96 9.41 (10.08)
1516 11.69 10.73 9.93 8.67 7.75 7.04 6.45 6.01 5.91 (6.55)
1517 38.64 36.68 35.01 32.35 30.36 28.82 27.59 26.68 26.36 (27.26)
1518 39.32 36.98 34.96 31.72 29.24 27.30 25.71 24.49 23.92 (24.66)
1519 22.76 20.78 19.08 16.33 14.22 12.52 11.09 9.95 9.40 (10.07)
1529 30.46 28.55 26.89 24.21 22.14 20.46 19.06 17.94 17.35 (17.84)
1530 32.93 31.35 29.98 27.73 25.97 24.54 23.33 22.35 21.79 (22.05)
1531 3.05 2.81 2.62 2.38 2.26 2.20 2.18 2.22 2.41 (2.96)
1532 19.53 18.16 16.99 15.12 13.71 12.59 11.65 10.92 10.63 (11.24)
1537 6.46 6.06 5.71 5.14 4.69 4.34 4.04 3.80 3.67 (3.72)
1538 57.11 53.15 49.72 44.13 39.81 36.33 33.43 31.11 29.83 (30.58)
1542 286.23 271.66 259.20 239.37 224.46 212.76 203.22 195.86 192.68 (197.96)
1544 9.85 9.11 8.45 7.36 6.47 5.72 5.06 4.49 4.11 (4.09)
1545 23.34 21.57 20.05 17.59 15.69 14.16 12.88 11.86 11.37 (11.98)
1551 19.26 17.06 15.17 12.l2 9.76 7.85 6.23 4.93 4.28 (5.01)
1552 -12.24 -11.48 -10.78 -9.48 -8.33 -7.62 -7.00 -6.42 -5.85 (-5.24)
1555 -3.84 -3.99 -4.13 -4.41 -4.69 -4.98 -5.29 -5.59 -5.79 (-5.72)
1558 5.27 5.26 5.26 5.23 5.19 5.09 4.95 4.79 4.69 (4.84)
1559 23.32 21.55 20.02 17.54 15.63 14.09 12.80 11.76 11.26 (1l.85)
1560 3.67 3.37 3.13 2.79 2.60 2.48 2.42 2.42 2.58 (3.l1)
 INDEX

The systems considered in the present study are cross-indexed below in an alphabetical
arrangement of components other than the ubiquitous components, Hel and H20. The latter
components appear only at the top of each index page. The balancing component is shown in
parentheses and the components represented by the descriptive variables appear in italics.
370 INDEX

25°_ 400°-
System HCl-H 2O- Constraints
300°C 600°C
Ag20- (H 2S)- H 2SO4 132 133
(Al 20 3) - CaO-C0 2- K20-MgO-Si0 2 Quartz and K-feldspar saturation.
XC02 = 0.01 273
XC02 = 0.05 274
XC02 = 0.10 275
XC02 = 0.30 276
XC02 = 0.50 277
XC02 = 0.70 278
XC02 = 0.90 279
XC02 = 0.95 280
XC02 = 0.99 281
Quartz and K-feldspar saturation.
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
XC02 = 0.01 282
XC02 = 0.05 283
XC02 = 0.10 284
XC02 = 0.30 285
XC02 = 0.50 286
XC02 = 0.70 287
XC02 = 0.90 288
XC02 = 0.95 289
XC02 = 0.99 290
(Al 20 3)-CaO-C02-MgO-Si0 2 Quartz saturation.
XC02 = 0.01 255
XC02 = 0.05 256
XC02 = 0.10 257
XC02 = 0.30 258
XC02 = 0.50 259
XC02 = 0.70 260
XC02 = 0.90 261
XC02 = 0.95 262
XC02 = 0.99 263
Quartz saturation. Metastable 7-
A clinochlore was considered
instead of its stable counterpart,
14-A clinochlore.
INDEX 371

25°- 400°-
System HCI-H2O- Constraints
300°C 600°C
(AI 20 3)-CaO-C02-MgO-Si0 2 (cont'd) X C02 = 0.01 264
X C02 = 0.05 265
X C02 = 0.10 266
X C02 = 0.30 267
X C02 = 0.50 268
X C02 = 0.70 269
X C02 = 0.90 270
"
X C02 = 0.95 271
X C02 = 0.99 272
(AI 20 3)-CaO-C02-Si0 2 X C02 = 0.01 165
X C02 = 0.05 166
X C02 = 0.10 167
X C02 = 0.30 168
X C02 = 0.50 169
X C02 = 0.70 170
X C02 = 0.90 171
X C02 = 0.95 172
X C02 = 0.99 173
A120 3- (CaO)-C0 2-Si0 2 X C02 = 0.01 174
X C02 = 0.05 175
X C02 = 0.10 176
X C02 = 0.30 177
X C02 = 0.50 178
X C02 = 0.70 179
X C02 = 0.90 180
XC02 = 0.95 181
X C02 = 0.99 182
AI20 3-CaO-C0 2- (Si02) X C02 = 0.01 183
X C02 = 0.05 184
X C02 = 0.10 185
X C02 = 0.30 186
XC02 = 0.50 187
XC02 = 0.70 ·188
X C02 = 0.90 189
X C02 = 0.95 190
X C02 = 0.99 191
372
System HCI-H 2O-
(AI 20 3)-CaO-FeO-Si02
AI 20 3-CaO-FeO- (Si0 2)
(AI 20 3)-CaO- K2O-Si0 2
AI 20 3-CaO-K 20- (Si0 2)
(AI 20 3)-CaO-MgO- Na20-Si02
(AI 20 3)-CaO-MgO-Si0 2
AI 20 3-CaO-MgO- (Si0 2)
INDEX
25°_ 400°-
Constraints
300°C 600°C
Amorphous silica saturation. 150
Quartz saturation. 54 55
Gibbsite, diaspore, or corundum 56 57
saturation, depending on which
mineral is stable at each pressure
and temperature.
Amorphous silica saturation. 151
Quartz saturation. 58 59
Gibbsite, diaspore, or corundum 60 61
saturation, depending on which
mineral is stable at each pressure
and temperature.
Albite and amorphous silica 163
saturation.
Albite and amorphous silica 164
saturation. Metastable 7-A clino-
chlore was considered instead of
its stable counterpart, 14-A clino-
chlore.
Quartz and albite saturation. 122 123
Quartz and albite saturation. 124 125
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
Amorphous silica saturation. 152
Amorphous silica saturation. 153
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
Quartz saturation. 62 63
Quartz saturation. Metastable 7- 64 65
A clinochlore was considered
instead of its stable counterpart,
14-A clinochlore.
Gibbsite, diaspore, or corundum 66 67
saturation, depending on which
mineral is stable at each pressure
and temperature.
INDEX 373

25°- 400°-
System HCl-H 2O- Constraints
300°C 600°C
AI20 j-CaO-MgO-(Si0 2) (cont'd) Gibbsite, diaspore, or corundum 68 69
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore was considered
instead of its stable counterpart
14-A c1inochlore.
Gibbsite, diaspore, or corundum 70 71
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart antigor-
ite.
Gibbsite, diaspore, or corundum 72 73
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore and chrysotile were
considered instead of their stable
counterparts 14-A c1inochlore and
antigorite.
(AI20)-CaO-Na20-Si02 Amorphous silica saturation 154
Quartz saturation. 74 75
AI20j-CaO-Na20-(Si02) Gibbsite, diaspore, or corundum 76 77
saturation, depending on which
mineral is stable at each pressure
and temperature.
(AI20j)-CaO-Si02 2 3
AI20 j- (CaO)-Si0 2 4 5
AI20j-CaO- (Si0 2) 6 7
(AI20j)-COcMgO-Si0 2 X C02 = 0.01 192
XC02 = 0.05 193
XC02 = 0.10 194
X C02 = 0.30 195
XC02 = 0.50 196
XC02 = 0.70 197
XC02 = 0.90 198
XC02 = 0.95 199
XC02 = 0.99 200
374 INDEX

25°- 400°-
System HCl-H 2O- Constraints
300°C 600°C
(Al 20 3)-C02-MgO-Si0 2 (cont'd) Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
XC02 = 0.01 201
XC02 = 0.05 202
XC02 = 0.10 203
XC02 = 0.30 204
XC02 = 0.50 205
XC02 = 0,70 206
XC02 = 0.90 207
XC02 = 0.95 208
XC02 = 0.99 209
AI20 3-C0 2- (MgO)-Si0 2 Xc0 2 = 0.01 210
XC02 = 0.05 211
XC02 = 0.10 212
XC02 = 0.30 213
XC02 = 0.50 214
XC02 = 0.70 215
XC02 = 0.90 216
XC02 = 0.95 217
XC02 = 0.99 218
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
XC02 = 0.01 219
XC02 = 0.05 220
XC02 = 0.10 221
XC02 = 0.30 222
XC02 = 0.50 223
XC02 = 0.70 224
XC02 = 0.90 225
XC02 = 0.95 226
XC02 = 0.99 227
AI20 3-C0 2-MgO- (Si0 2) XC02 = 0.01 228
XC02 = 0.05 229
XC02 = 0.10 230
XC02 = 0.30 231
XC02 = 0.50 232
INDEX 375

25°_ 400°-
System HCI-H 2O- Constraints
300°C 600°C
AI2 0 3-C0 2-MgO-(Si0 2) (cont'd) XC02 = 0.70 233
XC02 = 0.90 234
XC02 = 0.95 235
XC02 = 0.99 236
AI20 3-C0 2- MgO- (Si0 2) Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
XC02 = 0.01 237
XC02 = 0.05 238
XC02 = 0.10 239
XC02 = 0.30 240
XC02 = 0.50 241
XC02 = 0.70 242
XC02 = 0.90 243
XC02 = 0.95 244
XC02 = 0.99 245
(AI 20 3) - FeO- K2 O-Si0 2 Amorphous silica saturation. 155
Quartz saturation. 78 79
A1 20 3- FeO-K 20- (Si0 2) Gibbsite, diaspore, or corundum 80 81
saturation, depending on which
mineral is stable at each pressure
and temperature.
(AI 20 3) - FeO-MgO-Si0 2 Amorphous silica saturation. 156
Amorphous silica saturation. 157
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
Quartz saturation. 82 83
Quartz saturation. Metastable 7- 84 85
A clinochlore was considered
instead of its stable counterpart
14-A clinochlore.
A1 20 3- FeO-MgO- (Si0 2) Gibbsite, diaspore, or corundum 86 87
saturation, depending on which
mineral is stable at each pressure
and temperature.
376
System HCl- H 2O-
A1 20 3- FeO-MgO- (Si0 2) (cont'd)
(AI 20 3) - K 2 0-MgO-Si0 2
AI 20 3-K20-MgO- (Si0 2)
INDEX
25°_ 400°-
Constraints
300°C 600°C
Gibbsite, diaspore, or corundum 88 89
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
Gibbsite, diaspore, or corundum 90 91
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 92 93
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore and chrysotile were
considered instead of their stable
counterparts, 14-A c1inochlore
and antigorite.
Amorphous silica saturation 158
Amorphous silica saturation. 159
Metastable 7-A c1inochlore was
considered instead of its stable
counterpart, 14-A c1inochlore.
Quartz saturation. 94 95
Quartz saturation. Metastable 7- 96 97
A c1inochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
Gibbsite, diaspore, or corundum 98 99
saturation, depending on which
mineral is stable at each pressure
and temperature.
Gibbsite, diaspore, or corundum 100 101
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
INDEX 377

25°_ 400°-
System HCl- H 2O- Constraints
300°C 600°C
AI 20 3-K20-MgO-(Si0 2) (cont'd) Gibbsite, diaspore, or corundum 102 103
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 104 105
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore and chrysotile were
considered instead of their stable
counterparts, 14-A clinochlore
and antigorite.
(AI 20 3) - K 20-Na20-Si02 Amorphous silica saturation. 160
Quartz saturation. 106 107
A1 20 3- K 20-Na20- (Si0 2) Gibbsite, diaspore, or corundum 108 109
saturation, depending on which
mineral is stable at each pressure
and temperature.
(AI 20 3) - K 2O-Si0 2 8 9
A120 3- (K2O)-Si0 2 10 11
AI20 3-K20- (Si0 2) 12 13
(AI 20 3) -MgO-Na20-Si02 Amorphous silica saturation. 161
Amorphous silica saturation. 162
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
Quartz saturation. 110 111
Quartz saturation Metastable 7-A 112 113
clinochlore was considered
instead of its stable counterpart,
14-A clinochlore.
A1 20 3- MgO- Na20- (Si0 2) Gibbsite, diaspore, or corundum 114 115
saturation, depending on which
mineral is stable at each pressure
and temperature.
378
System HCI-H 2O-
AI203-MgO-Na20-(Si02) (cont'd)
(AI 20 3) - MgO-Si0 2
A 120 3- (MgO)-Si0 2
A 120 3- MgO- (Si0 2)
INDEX
25°_ 400°-
Constraints
300°C 600°C
Gibbsite, diaspore, or corundum 116 117
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
Gibbsite, diaspore, or corundum 118 119
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 120 121
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore and chrysotile were
considered instead of their stable
counterparts, 14-A c1inochlore
and antigorite.
14 15
Metastable 7-A clinochlore was 16 17
considered instead of its stable
counterpart, 14-A c1inochlore.
18 19
Metastable 7-A c1inochlore was 20 21
considered instead of its stable
counterpart, 14-A clinochlore.
Metastable chrysotile was con- 22 23
sidered instead of its stable coun-
terpart, antigorite.
Metastable 7-A c1inochlore and 24 25
chrysotile were considered instead
of their stable counterparts, 14-A
clinochlore and antigorite.
26 27
Metastable 7-A c1inochlore was 28 29
considered instead of its stable
counterpart, 14-A clinochlore.
INDEX 379

25°_ 400°-
System HCl-H 2O- Constraints
300°C 600°C
AI20 3-MgO-(Si0 2) (cont'd) Metastable chrysotile was con- 30 31
sidered instead of its stable coun-
terpart, antigorite.
Metastable 7-A clinochlore and 32 33
chrysotile were considered instead
of their stable counterparts, 14-A
clinochlore and antigorite.
(AI 20 3) - Na20-Si02 34 35
A120 3- ( Na20 )-Si02 36 37
A120 3- Na20- (Si0 2) 38 39
(BaO)- CO 2-H2SO4 292 293
CaO- (AI 20 3)-C02- K2O-MgO-Si0 2 Quartz and K-feldspar saturation.
XC02 = 0.01 273
XC02 = 0.05 274
XC02 = 0.10 275
XC02 = 0.30 276
XC02 = 0.50 277
XC02 = 0.70 278
XC02 = 0.90 279
XC02 = 0.95 280
XC02 = 0.99 281
Quartz and K-feldspar saturation.
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
XC02 = 0.01 282
XC02 = 0.05 283
XC02 = 0.10 284
XC02 = 0.30 285
XC02 = 0.50 286
XC02 = 0.70 287
XC02 = 0.90 288
XC02 = 0.95 289
XC02 = 0.99 290
CaO- (AI 20 3)-C02- MgO-Si0 2 Quartz saturation.
XC02 = 0.01 255
XC02 = 0.05 256
XC02 = 0.10 257
380 INDEX

25° 400°
System HCI-H 2O- Constraints
-300°C -600°C
CaO-(AI 20 3)-C0 2-MgO-Si0 2 (cont'd) XC02 = 0.30 258
XC02 = 0.50 259
X C02 = 0.70 260
XC02 = 0.90 261
XC02 = 0.95 262
XC02 = 0.99 263
Quartz saturation. Metastable 7-
A clinochlore was considered
instead of its stable counterpart,
14-A clinochlore.
XC02 = 0.01 264
XC02 = 0.05 265
XC02 = 0.10 266
X C02 = 0.30 267
X C02 = 0.50 268
X C02 = 0.70 269
XC02 = 0.90 270
XC02 = 0.95 271
XC02 = 0.99 272
CaO- (AI203)-C02-Si02 XC02 = o.ot 165
X C02 = 0.05 166
X C02 = 0.10 167
X C02 = 0.30 168
X C02 = 0.50 169
XC02 = 0.70 170
XC02 = 0.90 171
XC02 = 0.95 172
XC02 = 0.99 173
(CaO)-AI20 3-C0 2-Si0 2 XC02 = 0.01 174
XC02 = 0.05 175
XC02 = 0.10 176
XC02 = 0.30 177
XC02 = 0.50 178
XC02 = 0.70 179
XC02 = 0.90 180
X C02 = 0.95 181
X C02 = 0.99 182
INDEX 381

25° 400°
System HCI-H 2O- Constraints
-300°C -600°C
CaO-AI20 3-C02- (Si0 2) XC02 = 0.01 183
XC02 = 0.05 184
XC02 = 0.10 185
XC02 = 0.30 186
XC02 = 0.50 187
XC02 = 0.70 188
XC02 = 0.90 189
XC02 = 0.95 190
XC02 = 0.99 191
CaO- (AI 20 3) - FeO-Si02 Amorphous silica saturation. 150
Quartz saturation. 54 55
CaO- A1 20 3- FeO- (Si02) Gibbsite, diaspore, or corundum 56 57
saturation, depending on which
mineral is stable at each pressure
and temperature.
CaO- (AI 20 3) - K2O-Si02 Amorphous silica saturation. 151
Quartz saturation. 58 59
CaO- A1 20 3- K 20- (Si0 2) Gibbsite, diaspore, or corundum 60 61
saturation, depending on which
mineral is stable at each pressure
and temperature.
CaO- (AI 20 3) - MgO- Na2D-Si02 Albite and amorphous silica 163
saturation.
Albite and amorphous silica 164
saturation. Metastable 7-A c1ino-
chlore was considered instead of
its stable counterpart, 14-A c1ino-
chlore.
Quartz and albite saturation. 122 123
Quartz and albite saturation. 124 125
Metastable 7-A c1inochlore was
considered instead of its stable
counterpart, 14-A c1inochlore.
CaO- (AI 20 3) - MgO-Si0 2 Amorphous silica saturation. 152
Amorphous silica saturation. 153
Metastable 7-A c1inochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
Quartz saturation. 62 63
382 INDEX

25° 400°
System HCl-H 2O- Constraints
-300°C -600°C
CaO-(AI 20 3)-MgO-Si02 (cont'd) Quartz saturation. Metastable 7- 64 65
A c1inochlore was considered
instead of its stable counterpart,
14-A
CaO- A1 20 3- MgO- (Si0 2) Gibbsite, diaspore, or corundum 66 67
saturation, depending on which
mineral is stable at each pressure
and temperature.
Gibbsite, diaspore, or corundum 68 69
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore was considered
instead of its stable counterpart,
14-A clinochlore.
Gibbsite, diaspore, or corundum 70 71
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 72 73
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore and chrysotile were
considered instead of their stable
counterparts, 14-A c1inochlore
and antigorite.
CaO- (AI 20 3) - Na20-Si02 Amorphous silica saturation. 154
Quartz saturation. 74 75
CaO- A1 20 3- Na20- (Si0 2) Gibbsite, diaspore, or corundum 76 77
saturation, depending on which
mineral is stable at each pressure
and temperature.
CaO- (AI 20 3)-Si02 2 3
(CaO)-AI 20 3-Si0 2 4 5
CaO-AI20 3-(Si0 2) 6 7
CaO-(C0 2)-FeO 126 127
(CaO)-C0 2-H2S04 294 295
INDEX 383

25° 400°
System HCI-H 2O- Constraints
-300°C -600°C
CaO-(C0 2)-MgO 128 129
CaO -C02- MgO - (Si0 2) X C02 = 0.01 246
XC02 = 0.05 247
XC02 = 0.10 248
Xc0 2 = 0.30 249
X C02 = 0.50 250
Xc0 2 = 0.70 251
X C02 = 0.90 252
XC02 = 0.95 253
X C02 = 0.99 254
CaO-(MgO)-Si0 2 40 41
Metastable chrysotile was con- 42 43
sidered instead of its stable coun-
teflprt, antigorite.
(CaO)-MgO-Si0 2 44 45
CaO-MgO-(Si0 2) 46 47
Metastable chrysotile was con- 48 49
sidered instead of its stable coun-
terpart, antigorite.
CO 2 and other components--see listing
under other components.
CU20-FeO-H2S-(H2S04) log (aH+aHS -) = -10.0 144 145
log (aH+a HS -) = -11.0 146 147
log (aH+a HS-) = -12.0 148 149
CuO-H2S-(H 2S04) 134 135
CuO-(H2S)-H2S04 136 137
(CUO)-02-S 2 302 303
FeO-(AI 20 3)-CaO-Si02 Amorphous silica saturation. 150
Quartz saturation. 54 55
FeO-AI 20 3-CaO-(Si0 2) Gibbsite, diaspore, or corundum 56 57
saturation, depending on which
mineral is stable at each pressure
and temperature.
FeO-(AI 20 3)-K2O-Si0 2 Amorphous silica saturation. 155
384
System HCl-H 2O-
FeO- (AI 20 3) - K 20-Si0 2 (cont'd)
FeO- A1 20 3- K 20- (Si0 2)
FeO- (AI 20 3) - MgO-Si0 2
FeO-AI 20 3-MgO-(Si0 2)
INDEX
25° 400°
Constraints
-300°C -600°C
Quartz saturation. 78 79
Gibbsite, diaspore, or corundum 80 81
saturation, depending on which
mineral is stable at each pressure
and temperature.
Amorphous silica saturation 156
Amorphous silica saturation. 157
Metastable 7-A c1inochlore was
considered instead of its stable
counterpart, 14-A c1inochlore.
Quartz saturation. 82 83
Quartz saturation. Metastable 7- 84 85
A c1inochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
Gibbsite, diaspore, or corundum 86 87
saturation, depending on which
mineral is stable at each pressure
and temperature.
Gibbsite, diaspore, or corundum 88 89
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
Gibbsite, diaspore, or corundum 90 91
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 92 93
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore and chrysotile were
considered instead of their stable
counterparts, 14-A clinochlore
and antigorite.
INDEX 385

25° 400 0
System BCI-H2O- Constraints
-300°C -600°C
FeO-CGO-(C0 2) 126 127
FeO - (C0 2) - MgO 130 131
FeO -CU20 - H 2S- (H 2SO 4) log (GH+G HS -) =-10.0 144 145
log (GH+G HS -) =-11.0 146 147
log (GH+GHSJ =-12.0 148 149
FeO-H2S-(H 2S0 4) 138 139
FeO-MgO-(Si0 2) 50 51
Metastable chrysotile was con- 52 53
sidered instead of its stable coun-
terpart, antigorite.
(FeO)-02- S 2 304 305
HgS-{H2S)-H2S04 140 141
(H 2S)-Ag2O-H2S04 132 133
H2S-C0 2-(ZnO) 300 301
H 2S-CU 20 - FeO- (H 2SO 4) log (GH+G HS -) =-10.0 144 145
log (GH+G HS -) =-11.0 146 147
log (GH+G HS -) =-12.0 148 149
H2S-CuO-(H 2S0 4) 134 135
(H2 S)-CuO-H2S04 136 137
H2S-FeO-{H2S04) 138 139
(H 2S)-HgS-H2S04 140 141
(H2 S)-PbS-ZnS 142 143
H2S04-Ag2O-(H 2S) 132 133
H 2S04-(BaO)-C0 2 292 293
H 2SOc(CaO)-C0 2 294 295
H2S04-C0 2-(PbO) 296 297
H2S04-C0 2-(SrO) 298 299
(H2S04)-Cu20-FeO-H2S log(GH+G Hs -) = -10.0 144 145
log (GH+G HS -) = -11. 0 146 147
log(GH+G Hs -) = -12.0 148 149
(H 2S0 4)-CuO-H2S 134 135
H2S04-CUO - (H2 S) 136 137
{H2S04)-FeO-H2S 138 139
386 INDEX

25° 400°
System HCI-H 2O- Constraints
-300°C -600°C
H 2S04-HgS-(H 2S) 140 141
K20- (AI 20 3)-CaO-C02- MgO-Si02 Quartz and K-feldspar saturation.
XC02 = 0.01 273
XC02 = 0.05 274
XC02 = 0.10 275
XC02 = 0.30 276
XC02 = 0.50 277
XC02 = 0.70 278
XC02 = 0.90 279
XC02 = 0.95 280
XC02 = 0.99 281
Quartz and K-feldspar saturation.
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
XC02 = 0.01 282
XC02 = 0.05 283
XC02 = 0.10 284
XC02 = 0.30 285
XC02 = 0.50 286
XC02 = 0.70 287
XC02 = 0.90 288
XC02 = 0.95 289
XC02 = 0.99 290
K 20- (AI 20 3)-CaO-Si0 2 Amorphous silica saturation. 151
Quartz saturation. 58 59
K 20- AI 20 3-CaO- (Si0 2) Gibbsite, diaspore, or corundum 60 61
saturation, depending on which
mineral is stable at each pressure
and temperature.
K 20- (AI 20 3) - FeO-Si02 Amorphous silica saturation. 155
Quartz saturation. 78 79
K 20- A1 20 3- FeO- (Si0 2) Gibbsite, diaspore, or corundum 80 81
saturation, depending on which
mineral is stable at each pressure
and temperature.
K 20- (AI 20 3) -MgO-Si0 2 Amorphous silica saturation. 158
INDEX
System HCI-H 2O-
K 20- (AI 20 3) - MgO-Si0 2 (cont'd)
K 20- A1 20 3- MgO- (Si0 2)
K 20- (AI 20 3) - Na20-Si02
K 20- A1 20 3- Na20- (Si0 2)
K 20- (AI 20 3)-Si02
387
25° 400°
Constraints
-300°C -600°C
Amorphous silica saturation. 159
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
Quartz saturation. 94 95
Quartz saturation. Metastable 7- 96 97
A clinochlore was considered
instead of its stable counterpart,
14-A clinochlore.
Gibbsite, diaspore, or corundum 98 99
saturation, depending on which
mineral is stable at each pressure
and temperature.
Gibbsite, diaspore, or corundum 100 101
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore was considered
instead of its stable counterpart,
14-A clinochlore.
Gibbsite, diaspore, or corundum 102 103
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 104 105
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore and chrysotile were
considered instead of their stable
counterparts, 14-A clinochlore
and antigorite.
Amorphous silica saturation. 160
Quartz saturation. 106 107
Gibbsite, diaspore, or corundum 108 109
saturation, depending on which
mineral is stable at each pressure
and temperature.
8 9
388 INDEX

25° 400°
System HCI-H2O- Constraints
-300°C -600°C
(K20)-AI20rSi02 10 11
K 20-A120 3- (Si0 2) 12 13
MgO- (AI 20 3)-CaO-C0 2- K2o-Si0 2 Quartz and K-feldspar saturation.
Xc0 2 = 0.01 273
XC02 = 0.05 274
XC02 = 0.10 275
XC02 = 0.30 276
XC02 = 0.50 277
XC02 = 0.70 278
XC02 = 0.90 279
XC02 = 0.95 280
XC02 = 0.99 2S1
Quartz and K-feldspar saturation.
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
XC02 = 0.01 282
XC02 = 0.05 283
XC02 = 0.10 284
XC02 = 0.30 285
XC02 = 0.50 286
XC02 = 0.70 287
XC02 = 0.90 288
XC02 = 0.95 289
XC02 = 0.99 290
MgO- (AI 20 3)-CaO-C02-Si0 2 Quartz saturation.
XC02 = 0.01 255
XC02 = 0.05 256
XC02 = 0.10 257
XC02 = 0.30 258
XC02 = 0.50 259
XC02 = 0.70 260
XC02 = 0.90 261
XC02 = 0.95 262
XC02 = 0.99 263
INDEX 389

25° 400°
System HCI-H 2O- Constraints
-300°C -600°C
MgO-(AI 20 3)-CaO-C02-Si02 (cont'd) Quartz saturation. Metastable 7-
A c1inochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
XC02 = 0.01 264
XC02 = 0.05 265
XC02 = 0.10 266
XC02 = 0.30 267
XC02 = 0.50 268
XC02 = 0.70 269
XC02 = 0.90 270
XC02 = 0.95 271
XC02 = 0.99 272
MgO- (AI 20 3)-CaO- Na2o-Si02 Albite and amorphous silica 163
saturation.
Albite and amorphous silica 164
saturation. Metastable 7-A c1ino-
chi ore was considered instead of
its stable counterpart, 14-A c1ino-
chlore.
Quartz and albite saturation. 122 123
Quartz and albite saturation. 124 125
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
MgO- (AI 20 3)-CaO-Si02 Amorphous silica saturation. 152
Amorphous silica saturation. 153
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A c1inochlore.
Quartz saturation. 62 63
Quartz saturation. Metastable 7- 64 65
A c1inochlore was considered
instead of its stable counterpart,
14-A clinochlore.
MgO- AI 20 3-CaO- (Si0 2) Gibbsite, diaspore, or corundum 66 67
saturation, depending on which
mineral is stable at each pressure
and temperature.
390 INDEX

25° 400°
System HCI-H 2O- Constraints
-300°C -600°C
MgO-AI 20 3-CaO-(Si0 2) (cont'd) Gibbsite, diaspore, or corundum 68 69
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore was considered
instead of its stable counterpart,
14-A clinochlore.
Gibbsite, diaspore, or corundum 70 71
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 72 73
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore and chrysotile were
considered instead of their stable
counterparts, 14-A clinochlore
and antigorite.
MgO- (AI 20 3)-C0 2-Si0 2 XC02 = 0.01 192
XC02 = 0.05 193
XC02 = 0.10 194
XC02 = 0.30 195
XC02 = 0.50 196
XC02 = 0.70 197
XC02 = 0.90 198
XC02 = 0.95 199
XC02 = 0.99 200
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
XC02 = 0.01 201
XC02 = 0.05 202
XC02 = 0.10 203
XC02 = 0.30 204
XC02 = 0.50 205
XC02 = 0.70 206
XC02 = 0.90 207
INDEX 391

25° 400°
System HCl-H 2O- Constraints
-300°C -600°C
MgO- (Al 20 3)-C02-Si0 2 (cont'd) X C02 - 0.95 208
X C02 = 0.99 209
(MgO)-AI20 3-C0 2-Si0 2 XC02 = 0.01 210
XC02 = 0.05 211
XC02 = 0.10 212
XC02 = 0.30 213
XC02 = 0.50 214
XC02 = 0.70 215
XC02 = 0.90 216
XC02 = 0.95 217
XC02 = 0.99 218
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
XC02 = 0.01 219
X C02 = 0.05 220
XC02 = 0.10 221
X C02 = 0.30 222
X C02 = 0.50 223
X C02 = 0.70 224
X C02 = 0.90 225
XC02 = 0.95 226
XC02 = 0.99 227
MgO- AI20 3-C0 2- (Si0 2) X C02 = 0.01 228
XC02 = 0.05 229
XC02 = 0.10 230
XC02 = 0.30 231
XC02 = 0.50 232
X C02 = 0.70 233
XC02 = 0.90 234
XC02 = 0.95 235
X C02 = 0.99 236
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
X C02 = 0.01 237
X C02 = 0.05 238
392 INDEX

25° 400°
System HCI-H 2O- Constraints
-300°C -600°C
MgO-AI20 3-C0 2-(Si0 2 ) (cont'd) XC02 = 0.10 239
XC02 = 0.30 240
XC02 = 0.50 241
XC02 = 0.70 242
XC02 = 0.90 243
Xc0 2 = 0.95 244
XC02 = 0.99 245
MgO-(AI 20 3)-FeO-Si02 Amorphous silica saturation. 156
Amorphous silica saturation. 157
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
Quartz saturation. 82 8j
Quartz saturation. Metastable 7- 84 85
A c1inochlore was considered
instead of its stable counterpart,
14-A clinochlore.
MgO- A1 20 3- FeO- (Si0 2) Gibbsite, diaspore, or corundum 86 87
saturation, depending on which
mineral is stable at each pressure
and temperature.
Gibbsite, diaspore, or corundum 88 89
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore was considered
instead of its stable counterpart,
14-A clinochlore.
Gibbsite, diaspore, or corundum 90 91
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 92 93
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore and chrysotile were
considered instead of their stable
counterparts, 14-A clinochlore
and antigorite.
INDEX
System HCI-H 2o-
MgO- (AI 20 3) - K 2O-Si0 2
MgO- A1 20 3- K 20- (Si0 2)
MgO- (AI 20 3) - Na20-Si02
393
25° 400°
Constraints
-300°C -600°C
Amorphous silica saturation. 158
Amorphous silica saturation. 159
Metastable 7-A c1inochlore was
considered instead of its stable
counterpart, 14-A c1inochlore.
Quartz saturation. 94 95
Quartz saturation. Metastable 7- 96 97
A c1inochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
Gibbsite, diaspore, or corundum 98 99
saturation, depending on which
mineral is stable at each pressure
and temperature.
Gibbsite, diaspore, or corundum 100 101
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
Gibbsite, diaspore, or corundum 102 103
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 104 105
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore and chrysotile were
considered instead of their stable
counterparts, 14-A c1inochlore
and antigorite.
Amorphous silica saturation. 161
Amorphous silica saturation. 162
Metastable 7-A c1inochlore was
considered instead of its stable
counterpart, 14-A clinochlore.
Quartz saturation. 110 111
394
System HCl- H 2O-
MgO-(AI203)-Na20-Si02 (cont'd)
MgO- A1 20 3- Na20- (Si0 2)
MgO- (AI 20 3)-Si0 2
(MgO)-AI 20 3-Si0 2
INDEX
25° 400°
Constraints
-300°C -600°C
Quartz saturation. Metastable 7- 112 113
A c1inochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
Gibbsite, diaspore, or corundum 114 115
saturation, depending on which
mineral is stable at each pressure
and temperature.
Gibbsite, diaspore, or corundum 116 117
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore was considered
instead of its stable counterpart,
14-A c1inochlore.
Gibbsite, diaspore, or corundum 118 119
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 120 121
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
c1inochlore and chrysotile were
considered instead of their stable
counterparts, 14-A c1inochlore
and antigorite.
14 15
Metastable 7-A c1inochlore was 16 17
considered instead of its stable
counterpart, 14-A c1inochlore.
18 19
Metastable 7-A c1inochlore was 20 21
considered instead of its stable
counterpart, 14-A c1inochlore.
Metastable chrysotile was con- 22 23
sidered instead of its stable coun-
terpart, antigorite.
INDEX 395

25° 400°
System HCl-H 2O- Constraints
-300°C -600°C
(MgO)-AI 20 3-Si0 2 (cont'd) Metastable 7-A clinochlore and 24 25
chrysotile were considered instead
of their stable counterparts, 14-A
clinochlore and antigorite.
MgO-A120 3- (Si0 2) 26 27
Metastable 7-A clinochlore was 28 29
considered instead of its stable
counterpart, 14-A clinochlore.
Metastable chrysotile was con- 30 31
sidered instead of its stable coun-
terpart, antigorite.
Metastable 7-A clinochlore and 32 33
chrysotile were considered instead
of their stable counterparts, 14-A
clinochlore and antigorite.
MgO-CaO-(C0 2) 128 129
MgO-CaO-C0 2- (Si0 2) XC02 = 0.01 246
XC02 = 0.05 247
XC02 = 0.10 248
XC02 = 0.30 249
XC02 = 0.50 250
XC02 = 0.70 251
XC02 = 0.90 252
XC02 = 0.95 253
XC02 = 0.99 254
(MgO)-CaO-Si0 2 40 41
Metastable chrysotile was con- 42 43
sidered instead of its stable coun-
terpart, antigorite.
MgO- (CaO)-Si0 2 44 45
MgO-CaO- (Si0 2) 46 47
Metastable chrysotile was con- 48 49
sidered instead of its stable coun-
terpart, antigorite.
MgO-(C0 2)-FeO 130 131
MgO-FeO- (Si0 2) 50 51
396
System HCI-H 2D-
MgO-FeO-(Si0 2) (cont'd)
Na20- (AI 20 3) - CaO-MgO-Si0 2
Na20- (AI 20 3)-CaO-Si02
Na20-AI203-CaO-(Si02)
Na20- (AI 20 3) -K 2O-Si0 2
Na20- A1 20 3- K 20- (Si0 2)
Na20- (AI 20 3) - MgO-Si02
INDEX
25° 400°
Constraints
-300°C -600°C
Metastable chrysotite was con- 52 53
sidered instead of its stable coun-
terpart, antigorite.
Albite and amorphous silica 163
saturation.
Albite and amorphous silica 164
saturation. Metastable 7-A c1ino-
chlore was considered instead of
its stable counterpart, 14-A c1ino-
chlore.
Quartz and albite saturation. 122 123
Quartz and albite saturation. 124 125
Metastable 7-A clinochlore was
considered of its stable counter-
part, 14-A c1inochlore.
Amorphous silica saturation. 154
Quartz saturation. 74 75
Gibbsite, diaspore, or corundum 76 77
saturation, depending on which
mineral is stable at each pressure
and temperature.
Amorphous silica saturation. 160
Quartz saturation. 106 107
Gibbsite, diaspore, or corundum 108 109
saturation, depending on which
mineral is stable at each pressure
and temperature.
Amorphous silica saturation. 161
Amorphous silica saturation. 162
Metastable 7-A clinochlore was
considered instead of its stable
counterpart, 14-A c1inochlore.
Quartz saturation. 110 111
Quartz saturation. Metastable 7- 112 113
A c1inochlore was considered
instead of its stable counterpart,
14-A clinochlore.
INDEX 397

25° 400°
System HCI-H 2o- Constraints
-300°C -600°C
Na20-AI203-MgO-(Si02) Gibbsite, diaspore, or corundum 114 115
saturation, depending on which
mineral is stable at each pressure
and temperature.
Gibbsite, diaspore, or corundum 116 117
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore was considered
instead of its stable counterpart,
14-A clinochlore.
Gibbsite, diaspore, or corundum 118 119
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable
chrysotile was considered instead
of its stable counterpart, antigor-
ite.
Gibbsite, diaspore, or corundum 120 121
saturation, depending on which
mineral is stable at each pressure
and temperature. Metastable 7-A
clinochlore and chrysotile were
considered instead of their stable
counterparts, 14-A clinochlore
and antigorite.
Na20- (AI 20 3)-Si02 34 35
(Na20)- AI20 3-Si0 2 36 37
Na20-A120 3- (Si0 2) 38 39
02-(CUO)-S2 302 303
02-(FeO)-S2 304 305
(PbO )-C02- H 2SO4 296 297
I
PbS - (H2S)- ZnS 142 143
S2-(CUO)-02 302 303
S2-(FeO)-02 304 305
Si02 and other components--see listing
under other components.
(SrO)-C0 2-H2S04 298 299
(ZnO)-C0 2-H2S 300 301
ZnS - (H2S)- PbS 142 143
Advances Volume 2
•
In Editor: S. K. Saxena
Physical With contributions by numerous experts
Geochemistry
1982. 113 figures. X, 353 pages.
Editor-in-Chief: S. K. Saxena
ISBN 3-540-90644-4

The second volume of the series Advances in

Physical Geochemistry critically reviews
recent data and presents new information on
the crystal chemistry, thermodynamics, and
kinetics of the Earth's crust and mantle.
Among the topics treated are:

- intracrystalline reactions, including

demonstrations of future applications to
thermodynamics of solid solutions and the
cooling history of rocks
- melts, incorporating silicate density struc-
ture relationships and phase equilibrium
data on feldspars coexisting with fluids
- thermodynamic methods of calculating
phase equilibria
- Gibbs free energy of formation of
substances in laterites and bauxites
the crystal chemistry of pyroxenes and
perovskite

Springer-Verlag Summarizing contemporary topics and new

Berlin crystal-chemical and thermodynamic data,
Heidelberg this volume will be extremely useful geo-
New York chemists, geophysicists, and other material
Tokyo scientists.
Advances Volume 3
•
In Kinetics
Physical and Equilibrium
Geochemistry in Mineml Reactions
Editor-in-Chief: S.K.Saxena
Editor: S. K. Saxena
With contributions by numerous experts
1983. 99 figures. X, 273 pages
ISBN 3-540-90865-X

Contents: Compositional Zoning of Crystals: A

Record of Growth and Reaction History. - Exso-
lution and Fe2+-Mg Order-Disorder in Pyroxenes.
- Geospeedometry: An Extension of Geother-
mometry. - Mg-Fe Fractionation in Metamorphic
Environments. - Geobarometry in Granulites. -
The Cordierite-Garnet-Sillimanite-QWLrtz
Equilibrium: Experiments and Applications. -
Experimental Investigation of Exchange Equi-
libria in the System Cordierite-Garnet-Biotite. -
Thermodynamics of Complex Phases. - Index.

Volume 3 of Advances in Physical Geochemistry

continues this annual series of reviews of
contemporary research on thermodynamics and
reaction kinetics in geological systems.
The authors, all experts in their specialized fields,
consider that equilibrium data are important in
measuring pressure and temperature of the
paleonenvironment of rock formation, but they
also emphasize that the kinetics of mineral reac-
Springer-Verlag tions is of utmost significance in revealing the
thermal history of rocks.
Berlin Each chapter in this volume not only reviews the
Heidelberg state-of-the-art and the authors' own original
New York work, but also considers the directions which
Tokyo future research will take.