Envirodyne Laboratories, Inc

11011 Brooklet Dr., # 230

Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

29 March 2019

KHOU 11 News
Scott Noll
1945 Allen Parkway
Houston, Texas 77019

Ship Channel Water Testing

Enclosed are the results of analyses for samples received by the laboratory on 22-Mar-19 15:20. The
analytical data provided relates only to the samples as received in this laboratory report.

ELI certifies that all results are NELAP compliant and performed in accordance with the referenced method
except as noted in the Case Narrative or as noted with a qualifier. Any reproductions of this laboratory report
should be in full and only with the written authorization from the client.

The total number of pages in this report is 33

Thank you for selecting ELI for your analytical needs. If you have any questions regarding this report, please
contact us.

Sincerely,

Monica Smith
Certificate No: T104704265-18-14
Client Services Representative

Page 1 of 33
Page 1 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

ANALYTICAL REPORT FOR SAMPLES

Sample ID Laboratory ID Matrix Date Sampled Date Received

Site #4 Deza Valla 19C2732-01 Water 22-Mar-19 11:09 22-Mar-19 15:20

Site #5 Lynchburg Ferry 19C2732-02 Water 22-Mar-19 11:47 22-Mar-19 15:20

Site #6 River Terrace Park 19C2732-03 Water 22-Mar-19 12:07 22-Mar-19 15:20

Site #7 Vince Bayou 19C2732-04 Water 22-Mar-19 13:32 22-Mar-19 15:20

Site #8 Buffalo Bayou 19C2732-05 Water 22-Mar-19 14:35 22-Mar-19 15:20

Volatiles-
Vinyl Chloride, Styrene, MTBE, and 2-Chloroethyl Vinyl Ether are highly reactive compounds when samples are preserved
with acids (pH <2). 2-Chloroethyl Vinyl Ether recoveries deteriorate with acid preservative .

Acrolein or Acrylonitrile should be received with acidic preservation at pH > 4-5 and analyzed as soon as possible if it's a
compound of interest.

Tetrachloroethene was bias high in the Blank Spike Dup (LCSD). Compound was not detected in the sample.
L-Sample analyzed by NELAP accredited lab T104704231-18-21

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 2 of 33

Page 2 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #4 Deza Valla

19C2732-01 (Water) Sampled: 22-Mar-19 11:09

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Petroleum Hydrocarbons by GC FID

Total Petroleum Hydrocarbon <0.50 0.50 mg/L 1 [CALC] 27-Mar-19 28-Mar-19 03:53 TX1005 SUB
(TPH)
TPH >C12 - C28 <0.50 0.50 mg/L 1 B9C3530 27-Mar-19 28-Mar-19 03:53 TX 1005 SUB L
TPH >C28 - C35 <0.50 0.50 mg/L 1 B9C3530 27-Mar-19 28-Mar-19 03:53 TX 1005 SUB L
TPH >C6 - C12 <0.50 0.50 mg/L 1 B9C3530 27-Mar-19 28-Mar-19 03:53 TX 1005 SUB L

Volatile Organic Compounds by EPA 8260C

Dichlorodifluoromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Chloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Vinyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Bromomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Chloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Trichlorofluoromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Diethyl ether <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Acetone <45 45 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Acrolein <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,1-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Iodomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Carbon Disulfide <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Acetonitrile <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Allyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Methylene Chloride <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Acrylonitrile <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
MTBE (Methyl tert-butyl ether) <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
trans-1,2-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,1-Dichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Vinyl Acetate <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
2,2-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
cis-1,2-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Bromochloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 3 of 33

Page 3 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #4 Deza Valla

19C2732-01 (Water) Sampled: 22-Mar-19 11:09

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

Chloroform <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
2-Butanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,2-Dichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,1,1-Trichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Carbon Tetrachloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,1-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Trichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,2-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Methyl methacrylate <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Dibromomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Bromodichloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
2-Chloroethyl vinyl ether <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
cis-1,3-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
trans-1,3-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,1,2-Trichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Dibromochloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,2-Dibromoethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
4-Methyl-2-Pentanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Toluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Tetrachloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC Q
1,3-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
2-Hexanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Chlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,1,1,2-Tetrachloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Ethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
m,p-Xylene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
o-Xylene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Styrene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Bromoform <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 4 of 33

Page 4 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #4 Deza Valla

19C2732-01 (Water) Sampled: 22-Mar-19 11:09

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

Isopropylbenzene (Cumene) <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,1,2,2-Tetrachloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
trans-1,4-Dichloro-2-butene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,2,3-Trichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Bromobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Propylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
2-Chlorotoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,3,5-Trimethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
4-Chlorotoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
tert-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,2,4-Trimethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
sec-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
p-Isopropyltoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,3-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,4-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Benzyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
n-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,2-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,2-Dibromo-3-chloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,2,4-Trichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Hexachlorobutadiene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Naphthalene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
1,2,3-Trichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Total Trihalomethanes <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Total Xylenes <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Surrogate: Dibromofluoromethane 109 % 70-120 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Surrogate: 1,2-Dichloroethane-d4 98.7 % 70-120 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Surrogate: Toluene-d8 95.2 % 70-120 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC
Surrogate: 4-Bromofluorobenzene 92.2 % 70-120 B9C2921 24-Mar-19 24-Mar-19 18:23 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 5 of 33

Page 5 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #4 Deza Valla

19C2732-01 (Water) Sampled: 22-Mar-19 11:09

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 6 of 33

Page 6 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #5 Lynchburg Ferry

19C2732-02 (Water) Sampled: 22-Mar-19 11:47

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Petroleum Hydrocarbons by GC FID

Total Petroleum Hydrocarbon 195 0.99 mg/L 1 [CALC] 27-Mar-19 29-Mar-19 14:46 TX1005 SUB
(TPH)
TPH >C12 - C28 85.0 0.99 mg/L 1 B9C3530 27-Mar-19 29-Mar-19 14:46 TX 1005 SUB L
TPH >C28 - C35 110 0.99 mg/L 1 B9C3530 27-Mar-19 29-Mar-19 14:46 TX 1005 SUB L
TPH >C6 - C12 <0.99 0.99 mg/L 1 B9C3530 27-Mar-19 29-Mar-19 14:46 TX 1005 SUB L

Volatile Organic Compounds by EPA 8260C

Dichlorodifluoromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Chloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Vinyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Bromomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Chloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Trichlorofluoromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Diethyl ether <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Acetone <45 45 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Acrolein <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,1-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Iodomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Carbon Disulfide <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Acetonitrile <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Allyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Methylene Chloride <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Acrylonitrile <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
MTBE (Methyl tert-butyl ether) <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
trans-1,2-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,1-Dichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Vinyl Acetate <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
2,2-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
cis-1,2-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Bromochloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 7 of 33

Page 7 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #5 Lynchburg Ferry

19C2732-02 (Water) Sampled: 22-Mar-19 11:47

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

Chloroform <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
2-Butanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,2-Dichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,1,1-Trichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Carbon Tetrachloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,1-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Trichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,2-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Methyl methacrylate <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Dibromomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Bromodichloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
2-Chloroethyl vinyl ether <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
cis-1,3-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
trans-1,3-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,1,2-Trichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Dibromochloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,2-Dibromoethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
4-Methyl-2-Pentanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Toluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Tetrachloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC Q
1,3-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
2-Hexanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Chlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,1,1,2-Tetrachloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Ethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
m,p-Xylene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
o-Xylene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Styrene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Bromoform <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 8 of 33

Page 8 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #5 Lynchburg Ferry

19C2732-02 (Water) Sampled: 22-Mar-19 11:47

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

Isopropylbenzene (Cumene) <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,1,2,2-Tetrachloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
trans-1,4-Dichloro-2-butene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,2,3-Trichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Bromobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Propylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
2-Chlorotoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,3,5-Trimethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
4-Chlorotoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
tert-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,2,4-Trimethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
sec-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
p-Isopropyltoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,3-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,4-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Benzyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
n-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,2-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,2-Dibromo-3-chloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,2,4-Trichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Hexachlorobutadiene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Naphthalene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
1,2,3-Trichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Total Trihalomethanes <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Total Xylenes <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Surrogate: Dibromofluoromethane 110 % 70-120 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Surrogate: 1,2-Dichloroethane-d4 101 % 70-120 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Surrogate: Toluene-d8 96.3 % 70-120 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC
Surrogate: 4-Bromofluorobenzene 92.0 % 70-120 B9C2921 24-Mar-19 24-Mar-19 18:47 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 9 of 33

Page 9 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #5 Lynchburg Ferry

19C2732-02 (Water) Sampled: 22-Mar-19 11:47

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 10 of 33

Page 10 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #6 River Terrace Park

19C2732-03 (Water) Sampled: 22-Mar-19 12:07

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Petroleum Hydrocarbons by GC FID

Total Petroleum Hydrocarbon <0.49 0.49 mg/L 1 [CALC] 27-Mar-19 28-Mar-19 04:51 TX1005 SUB
(TPH)
TPH >C12 - C28 <0.49 0.49 mg/L 1 B9C3530 27-Mar-19 28-Mar-19 04:51 TX 1005 SUB L
TPH >C28 - C35 <0.49 0.49 mg/L 1 B9C3530 27-Mar-19 28-Mar-19 04:51 TX 1005 SUB L
TPH >C6 - C12 <0.49 0.49 mg/L 1 B9C3530 27-Mar-19 28-Mar-19 04:51 TX 1005 SUB L

Volatile Organic Compounds by EPA 8260C

Dichlorodifluoromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Chloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Vinyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Bromomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Chloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Trichlorofluoromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Diethyl ether <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Acetone <45 45 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Acrolein <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,1-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Iodomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Carbon Disulfide <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Acetonitrile <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Allyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Methylene Chloride <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Acrylonitrile <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
MTBE (Methyl tert-butyl ether) <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
trans-1,2-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,1-Dichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Vinyl Acetate <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
2,2-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
cis-1,2-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Bromochloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 11 of 33

Page 11 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #6 River Terrace Park

19C2732-03 (Water) Sampled: 22-Mar-19 12:07

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

Chloroform 6.4 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
2-Butanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,2-Dichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,1,1-Trichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Carbon Tetrachloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,1-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Trichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,2-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Methyl methacrylate <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Dibromomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Bromodichloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
2-Chloroethyl vinyl ether <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
cis-1,3-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
trans-1,3-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,1,2-Trichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Dibromochloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,2-Dibromoethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
4-Methyl-2-Pentanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Toluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Tetrachloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC Q
1,3-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
2-Hexanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Chlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,1,1,2-Tetrachloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Ethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
m,p-Xylene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
o-Xylene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Styrene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Bromoform <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 12 of 33

Page 12 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #6 River Terrace Park

19C2732-03 (Water) Sampled: 22-Mar-19 12:07

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

Isopropylbenzene (Cumene) <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,1,2,2-Tetrachloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
trans-1,4-Dichloro-2-butene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,2,3-Trichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Bromobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Propylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
2-Chlorotoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,3,5-Trimethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
4-Chlorotoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
tert-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,2,4-Trimethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
sec-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
p-Isopropyltoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,3-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,4-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Benzyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
n-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,2-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,2-Dibromo-3-chloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,2,4-Trichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Hexachlorobutadiene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Naphthalene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
1,2,3-Trichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Total Trihalomethanes <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Total Xylenes <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Surrogate: Dibromofluoromethane 109 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Surrogate: 1,2-Dichloroethane-d4 101 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Surrogate: Toluene-d8 95.6 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC
Surrogate: 4-Bromofluorobenzene 92.1 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:11 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 13 of 33

Page 13 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #6 River Terrace Park

19C2732-03 (Water) Sampled: 22-Mar-19 12:07

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 14 of 33

Page 14 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #7 Vince Bayou

19C2732-04 (Water) Sampled: 22-Mar-19 13:32

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Petroleum Hydrocarbons by GC FID

Total Petroleum Hydrocarbon <0.50 0.50 mg/L 1 [CALC] 27-Mar-19 28-Mar-19 05:20 TX1005 SUB
(TPH)
TPH >C12 - C28 <0.50 0.50 mg/L 1 B9C3530 27-Mar-19 28-Mar-19 05:20 TX 1005 SUB L
TPH >C28 - C35 <0.50 0.50 mg/L 1 B9C3530 27-Mar-19 28-Mar-19 05:20 TX 1005 SUB L
TPH >C6 - C12 <0.50 0.50 mg/L 1 B9C3530 27-Mar-19 28-Mar-19 05:20 TX 1005 SUB L

Volatile Organic Compounds by EPA 8260C

Dichlorodifluoromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Chloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Vinyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Bromomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Chloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Trichlorofluoromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Diethyl ether <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Acetone <45 45 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Acrolein <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,1-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Iodomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Carbon Disulfide <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Acetonitrile <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Allyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Methylene Chloride <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Acrylonitrile <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
MTBE (Methyl tert-butyl ether) <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
trans-1,2-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,1-Dichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Vinyl Acetate <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
2,2-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
cis-1,2-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Bromochloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 15 of 33

Page 15 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #7 Vince Bayou

19C2732-04 (Water) Sampled: 22-Mar-19 13:32

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

Chloroform <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
2-Butanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,2-Dichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,1,1-Trichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Carbon Tetrachloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,1-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Trichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,2-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Methyl methacrylate <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Dibromomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Bromodichloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
2-Chloroethyl vinyl ether <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
cis-1,3-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
trans-1,3-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,1,2-Trichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Dibromochloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,2-Dibromoethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
4-Methyl-2-Pentanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Toluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Tetrachloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC Q
1,3-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
2-Hexanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Chlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,1,1,2-Tetrachloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Ethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
m,p-Xylene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
o-Xylene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Styrene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Bromoform <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 16 of 33

Page 16 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #7 Vince Bayou

19C2732-04 (Water) Sampled: 22-Mar-19 13:32

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

Isopropylbenzene (Cumene) <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,1,2,2-Tetrachloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
trans-1,4-Dichloro-2-butene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,2,3-Trichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Bromobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Propylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
2-Chlorotoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,3,5-Trimethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
4-Chlorotoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
tert-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,2,4-Trimethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
sec-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
p-Isopropyltoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,3-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,4-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Benzyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
n-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,2-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,2-Dibromo-3-chloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,2,4-Trichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Hexachlorobutadiene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Naphthalene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
1,2,3-Trichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Total Trihalomethanes <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Total Xylenes <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Surrogate: Dibromofluoromethane 109 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Surrogate: 1,2-Dichloroethane-d4 98.6 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Surrogate: Toluene-d8 96.9 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC
Surrogate: 4-Bromofluorobenzene 90.1 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:34 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 17 of 33

Page 17 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #7 Vince Bayou

19C2732-04 (Water) Sampled: 22-Mar-19 13:32

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 18 of 33

Page 18 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #8 Buffalo Bayou

19C2732-05 (Water) Sampled: 22-Mar-19 14:35

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

Dichlorodifluoromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Chloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Vinyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Bromomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Chloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Trichlorofluoromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Diethyl ether <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Acetone <45 45 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Acrolein <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,1-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Iodomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Carbon Disulfide <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Acetonitrile <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Allyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Methylene Chloride <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Acrylonitrile <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
MTBE (Methyl tert-butyl ether) <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
trans-1,2-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,1-Dichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Vinyl Acetate <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
2,2-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
cis-1,2-Dichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Bromochloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Chloroform <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
2-Butanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,2-Dichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,1,1-Trichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Carbon Tetrachloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,1-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 19 of 33

Page 19 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #8 Buffalo Bayou

19C2732-05 (Water) Sampled: 22-Mar-19 14:35

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

Trichloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,2-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Methyl methacrylate <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Dibromomethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Bromodichloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
2-Chloroethyl vinyl ether <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
cis-1,3-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
trans-1,3-Dichloropropene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,1,2-Trichloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Dibromochloromethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,2-Dibromoethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
4-Methyl-2-Pentanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Toluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Tetrachloroethene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC Q
1,3-Dichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
2-Hexanone <10 10 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Chlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,1,1,2-Tetrachloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Ethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
m,p-Xylene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
o-Xylene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Styrene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Bromoform <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Isopropylbenzene (Cumene) <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,1,2,2-Tetrachloroethane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
trans-1,4-Dichloro-2-butene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,2,3-Trichloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Bromobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Propylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
2-Chlorotoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 20 of 33

Page 20 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Site #8 Buffalo Bayou

19C2732-05 (Water) Sampled: 22-Mar-19 14:35

Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Analyst Notes

Envirodyne Laboratories, Inc.

Volatile Organic Compounds by EPA 8260C

1,3,5-Trimethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
4-Chlorotoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
tert-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,2,4-Trimethylbenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
sec-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
p-Isopropyltoluene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,3-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,4-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Benzyl Chloride <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
n-butyl Benzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,2-Dichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,2-Dibromo-3-chloropropane <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,2,4-Trichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Hexachlorobutadiene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Naphthalene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
1,2,3-Trichlorobenzene <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Total Trihalomethanes <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Total Xylenes <5.0 5.0 ug/L 1 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Surrogate: Dibromofluoromethane 111 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Surrogate: 1,2-Dichloroethane-d4 102 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Surrogate: Toluene-d8 96.5 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC
Surrogate: 4-Bromofluorobenzene 90.1 % 70-120 B9C2921 24-Mar-19 24-Mar-19 19:58 EPA 8260C BPC

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 21 of 33

Page 21 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

Blank (B9C2921-BLK1) Prepared & Analyzed: 24-Mar-19
Dichlorodifluoromethane <5.0 5.0 ug/L
Chloromethane <5.0 5.0 "
Vinyl Chloride <5.0 5.0 "
Bromomethane <5.0 5.0 "
Chloroethane <5.0 5.0 "
Trichlorofluoromethane <5.0 5.0 "
Diethyl ether <5.0 5.0 "
Acetone <45 45 "
Acrolein <5.0 5.0 "
1,1-Dichloroethene <5.0 5.0 "
Iodomethane <5.0 5.0 "
Carbon Disulfide <5.0 5.0 "
Acetonitrile <5.0 5.0 "
Allyl Chloride <5.0 5.0 "
Methylene Chloride <10 10 "
Acrylonitrile <5.0 5.0 "
MTBE (Methyl tert-butyl ether) <5.0 5.0 "
trans-1,2-Dichloroethene <5.0 5.0 "
1,1-Dichloroethane <5.0 5.0 "
Vinyl Acetate <5.0 5.0 "
2,2-Dichloropropane <5.0 5.0 "
cis-1,2-Dichloroethene <5.0 5.0 "
Bromochloromethane <5.0 5.0 "
Chloroform <5.0 5.0 "
2-Butanone <10 10 "
1,2-Dichloroethane <5.0 5.0 "
1,1,1-Trichloroethane <5.0 5.0 "
Carbon Tetrachloride <5.0 5.0 "
1,1-Dichloropropene <5.0 5.0 "
Benzene <5.0 5.0 "
Trichloroethene <5.0 5.0 "
1,2-Dichloropropane <5.0 5.0 "

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 22 of 33

Page 22 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

Blank (B9C2921-BLK1) Prepared & Analyzed: 24-Mar-19
Methyl methacrylate <5.0 5.0 ug/L
Dibromomethane <5.0 5.0 "
Bromodichloromethane <5.0 5.0 "
2-Chloroethyl vinyl ether <5.0 5.0 "
cis-1,3-Dichloropropene <5.0 5.0 "
trans-1,3-Dichloropropene <5.0 5.0 "
1,1,2-Trichloroethane <5.0 5.0 "
Dibromochloromethane <5.0 5.0 "
1,2-Dibromoethane <5.0 5.0 "
4-Methyl-2-Pentanone <10 10 "
Toluene <5.0 5.0 "
Tetrachloroethene <5.0 5.0 "
1,3-Dichloropropane <5.0 5.0 "
2-Hexanone <10 10 "
Chlorobenzene <5.0 5.0 "
1,1,1,2-Tetrachloroethane <5.0 5.0 "
Ethylbenzene <5.0 5.0 "
m,p-Xylene <5.0 5.0 "
o-Xylene <5.0 5.0 "
Styrene <5.0 5.0 "
Bromoform <5.0 5.0 "
Isopropylbenzene (Cumene) <5.0 5.0 "
1,1,2,2-Tetrachloroethane <5.0 5.0 "
trans-1,4-Dichloro-2-butene <5.0 5.0 "
1,2,3-Trichloropropane <5.0 5.0 "
Bromobenzene <5.0 5.0 "
Propylbenzene <5.0 5.0 "
2-Chlorotoluene <5.0 5.0 "
1,3,5-Trimethylbenzene <5.0 5.0 "
4-Chlorotoluene <5.0 5.0 "
tert-butyl Benzene <5.0 5.0 "
1,2,4-Trimethylbenzene <5.0 5.0 "

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 23 of 33

Page 23 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

Blank (B9C2921-BLK1) Prepared & Analyzed: 24-Mar-19
sec-butyl Benzene <5.0 5.0 ug/L
p-Isopropyltoluene <5.0 5.0 "
1,3-Dichlorobenzene <5.0 5.0 "
1,4-Dichlorobenzene <5.0 5.0 "
Benzyl Chloride <5.0 5.0 "
n-butyl Benzene <5.0 5.0 "
1,2-Dichlorobenzene <5.0 5.0 "
1,2-Dibromo-3-chloropropane <5.0 5.0 "
1,2,4-Trichlorobenzene <5.0 5.0 "
Hexachlorobutadiene <5.0 5.0 "
Naphthalene <5.0 5.0 "
1,2,3-Trichlorobenzene <5.0 5.0 "
Total Trihalomethanes <5.0 5.0 "
Total Xylenes <5.0 5.0 "

Surrogate: Dibromofluoromethane 54 " 50.0 108 70-120

Surrogate: 1,2-Dichloroethane-d4 50 " 50.0 100 70-120
Surrogate: Toluene-d8 48 " 50.0 95.0 70-120
Surrogate: 4-Bromofluorobenzene 47 " 50.0 93.2 70-120

LCS (B9C2921-BS1) Prepared & Analyzed: 24-Mar-19

Dichlorodifluoromethane 50 5.0 ug/L 50.0 100 57.8-127
Chloromethane 46 5.0 " 50.0 92.0 60-130
Vinyl Chloride 47 5.0 " 50.0 93.8 69.1-123
Bromomethane 52 5.0 " 50.0 104 31.7-166
Chloroethane 53 5.0 " 50.0 106 61.2-129
Trichlorofluoromethane 48 5.0 " 50.0 96.0 65.9-133
Diethyl ether 48 5.0 " 50.0 95.2 78.7-126
Acetone 250 45 " 250 101 24.2-172
Acrolein 48 5.0 " 50.0 96.6 27.9-168
1,1-Dichloroethene 47 5.0 " 50.0 93.5 77.6-155
Iodomethane 50 5.0 " 50.0 100 34.2-169
Carbon Disulfide 48 5.0 " 50.0 96.3 74.8-125

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 24 of 33

Page 24 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

LCS (B9C2921-BS1) Prepared & Analyzed: 24-Mar-19
Acetonitrile 49 5.0 ug/L 50.0 98.8 73.1-139
Allyl Chloride 49 5.0 " 50.0 97.7 70.5-142
Methylene Chloride 48 10 " 50.0 96.6 75.6-120
Acrylonitrile 50 5.0 " 50.0 99.9 67.1-131
MTBE (Methyl tert-butyl ether) 50 5.0 " 50.0 99.1 72.5-135
trans-1,2-Dichloroethene 48 5.0 " 50.0 97.0 78.9-122
1,1-Dichloroethane 49 5.0 " 50.0 97.8 77.6-120
Vinyl Acetate 52 5.0 " 50.0 104 58.7-158
2,2-Dichloropropane 46 5.0 " 50.0 92.3 75.8-129
cis-1,2-Dichloroethene 48 5.0 " 50.0 96.1 81-123
Bromochloromethane 48 5.0 " 50.0 96.7 68.4-122
Chloroform 48 5.0 " 50.0 96.2 62.3-128
2-Butanone 240 10 " 250 94.4 63-136
1,2-Dichloroethane 47 5.0 " 50.0 93.7 81.7-115
1,1,1-Trichloroethane 48 5.0 " 50.0 95.1 83-116
Carbon Tetrachloride 48 5.0 " 50.0 95.7 79.7-122
1,1-Dichloropropene 47 5.0 " 50.0 94.9 87.6-115
Benzene 48 5.0 " 50.0 95.7 85.2-113
Trichloroethene 47 5.0 " 50.0 93.1 85.9-115
1,2-Dichloropropane 47 5.0 " 50.0 94.2 85.4-116
Methyl methacrylate 50 5.0 " 50.0 100 78.3-147
Dibromomethane 46 5.0 " 50.0 91.0 81.4-117
Bromodichloromethane 48 5.0 " 50.0 95.5 81.3-120
2-Chloroethyl vinyl ether 50 5.0 " 50.0 99.0 29.2-167
cis-1,3-Dichloropropene 48 5.0 " 50.0 96.8 90.3-123
trans-1,3-Dichloropropene 47 5.0 " 50.0 94.8 87.8-127
1,1,2-Trichloroethane 47 5.0 " 50.0 93.2 82-117
Dibromochloromethane 47 5.0 " 50.0 93.3 82.2-125
1,2-Dibromoethane 48 5.0 " 50.0 95.1 85.4-119
4-Methyl-2-Pentanone 240 10 " 250 95.9 67.8-145
Toluene 45 5.0 " 50.0 90.6 83.3-123
Tetrachloroethene 44 5.0 " 50.0 88.2 61.4-138

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 25 of 33

Page 25 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

LCS (B9C2921-BS1) Prepared & Analyzed: 24-Mar-19
1,3-Dichloropropane 48 5.0 ug/L 50.0 95.7 81.9-119
2-Hexanone 240 10 " 250 95.3 69.7-143
Chlorobenzene 45 5.0 " 50.0 89.0 80.6-111
1,1,1,2-Tetrachloroethane 47 5.0 " 50.0 93.1 80.6-121
Ethylbenzene 46 5.0 " 50.0 92.0 79.9-129
m,p-Xylene 93 5.0 " 100 92.7 78.7-129
o-Xylene 48 5.0 " 50.0 95.1 76.6-135
Styrene 49 5.0 " 50.0 97.7 85.5-124
Bromoform 46 5.0 " 50.0 92.3 75.3-131
Isopropylbenzene (Cumene) 48 5.0 " 50.0 96.2 82.7-126
1,1,2,2-Tetrachloroethane 46 5.0 " 50.0 92.4 73.8-121
trans-1,4-Dichloro-2-butene 48 5.0 " 50.0 96.5 66.9-139
1,2,3-Trichloropropane 47 5.0 " 50.0 93.1 75-127
Bromobenzene 45 5.0 " 50.0 90.6 81.3-120
Propylbenzene 47 5.0 " 50.0 93.8 83.7-132
2-Chlorotoluene 47 5.0 " 50.0 93.7 82.9-122
1,3,5-Trimethylbenzene 48 5.0 " 50.0 95.3 84.8-126
4-Chlorotoluene 46 5.0 " 50.0 91.6 82.5-121
tert-butyl Benzene 47 5.0 " 50.0 94.0 85-128
1,2,4-Trimethylbenzene 48 5.0 " 50.0 95.6 86.7-124
sec-butyl Benzene 48 5.0 " 50.0 97.0 87.2-124
p-Isopropyltoluene 48 5.0 " 50.0 96.6 86-125
1,3-Dichlorobenzene 46 5.0 " 50.0 92.3 83.9-118
1,4-Dichlorobenzene 47 5.0 " 50.0 93.3 81.4-115
Benzyl Chloride 44 5.0 " 50.0 88.8 70-120
n-butyl Benzene 48 5.0 " 50.0 96.7 85.6-127
1,2-Dichlorobenzene 46 5.0 " 50.0 91.8 82.8-118
1,2-Dibromo-3-chloropropane 48 5.0 " 50.0 96.8 68.2-130
1,2,4-Trichlorobenzene 46 5.0 " 50.0 92.9 79.9-133
Hexachlorobutadiene 47 5.0 " 50.0 94.0 75.8-129
Naphthalene 48 5.0 " 50.0 96.8 65.2-145
1,2,3-Trichlorobenzene 46 5.0 " 50.0 91.8 73.7-140

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 26 of 33

Page 26 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

LCS (B9C2921-BS1) Prepared & Analyzed: 24-Mar-19
Total Trihalomethanes 190 5.0 ug/L 200 94.3 79.9-122
Total Xylenes 140 5.0 " 150 93.5 81.2-127

Surrogate: Dibromofluoromethane 52 " 50.0 105 70-120

Surrogate: 1,2-Dichloroethane-d4 52 " 50.0 104 70-120
Surrogate: Toluene-d8 50 " 50.0 99.9 70-120
Surrogate: 4-Bromofluorobenzene 50 " 50.0 101 70-120

LCS Dup (B9C2921-BSD1) Prepared & Analyzed: 24-Mar-19

Dichlorodifluoromethane 48 5.0 ug/L 50.0 96.3 57.8-127 4.21 25
Chloromethane 47 5.0 " 50.0 93.3 60-130 1.32 25
Vinyl Chloride 46 5.0 " 50.0 92.0 69.1-123 1.87 25
Bromomethane 54 5.0 " 50.0 108 31.7-166 3.86 25
Chloroethane 53 5.0 " 50.0 106 61.2-129 0.132 25
Trichlorofluoromethane 47 5.0 " 50.0 94.8 65.9-133 1.22 25
Diethyl ether 46 5.0 " 50.0 92.1 78.7-126 3.33 25
Acetone 260 45 " 250 103 24.2-172 1.79 25
Acrolein 44 5.0 " 50.0 87.9 27.9-168 9.47 25
1,1-Dichloroethene 48 5.0 " 50.0 95.9 77.6-155 2.51 25
Iodomethane 46 5.0 " 50.0 92.9 34.2-169 7.36 25
Carbon Disulfide 48 5.0 " 50.0 95.2 74.8-125 1.09 25
Acetonitrile 52 5.0 " 50.0 103 73.1-139 4.55 25
Allyl Chloride 50 5.0 " 50.0 99.5 70.5-142 1.87 25
Methylene Chloride 48 10 " 50.0 95.6 75.6-120 1.06 25
Acrylonitrile 49 5.0 " 50.0 98.3 67.1-131 1.59 25
MTBE (Methyl tert-butyl ether) 48 5.0 " 50.0 96.3 72.5-135 2.84 25
trans-1,2-Dichloroethene 47 5.0 " 50.0 94.6 78.9-122 2.44 25
1,1-Dichloroethane 47 5.0 " 50.0 94.2 77.6-120 3.77 25
Vinyl Acetate 36 5.0 " 50.0 72.7 58.7-158 35.6 25 RPD
2,2-Dichloropropane 46 5.0 " 50.0 91.1 75.8-129 1.26 25
cis-1,2-Dichloroethene 48 5.0 " 50.0 95.2 81-123 0.878 25
Bromochloromethane 45 5.0 " 50.0 90.6 68.4-122 6.53 25
Chloroform 47 5.0 " 50.0 95.0 62.3-128 1.23 25

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 27 of 33

Page 27 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

LCS Dup (B9C2921-BSD1) Prepared & Analyzed: 24-Mar-19
2-Butanone 230 10 ug/L 250 90.3 63-136 4.44 25
1,2-Dichloroethane 45 5.0 " 50.0 89.4 81.7-115 4.70 25
1,1,1-Trichloroethane 46 5.0 " 50.0 91.2 83-116 4.23 25
Carbon Tetrachloride 45 5.0 " 50.0 90.5 79.7-122 5.63 25
1,1-Dichloropropene 46 5.0 " 50.0 92.1 87.6-115 3.04 25
Benzene 46 5.0 " 50.0 92.6 85.2-113 3.23 25
Trichloroethene 48 5.0 " 50.0 95.1 85.9-115 2.15 25
1,2-Dichloropropane 45 5.0 " 50.0 90.9 85.4-116 3.57 25
Methyl methacrylate 48 5.0 " 50.0 95.7 78.3-147 4.75 25
Dibromomethane 45 5.0 " 50.0 89.2 81.4-117 1.95 25
Bromodichloromethane 45 5.0 " 50.0 90.9 81.3-120 4.96 25
2-Chloroethyl vinyl ether 47 5.0 " 50.0 94.4 29.2-167 4.80 25
cis-1,3-Dichloropropene 47 5.0 " 50.0 93.7 90.3-123 3.21 25
trans-1,3-Dichloropropene 46 5.0 " 50.0 92.2 87.8-127 2.78 25
1,1,2-Trichloroethane 45 5.0 " 50.0 90.9 82-117 2.43 25
Dibromochloromethane 45 5.0 " 50.0 90.7 82.2-125 2.87 25
1,2-Dibromoethane 45 5.0 " 50.0 89.5 85.4-119 6.15 25
4-Methyl-2-Pentanone 230 10 " 250 92.1 67.8-145 4.08 25
Toluene 45 5.0 " 50.0 89.9 83.3-123 0.775 25
Tetrachloroethene 76 5.0 " 50.0 153 61.4-138 53.6 25 Q, RPD
1,3-Dichloropropane 46 5.0 " 50.0 91.4 81.9-119 4.62 25
2-Hexanone 230 10 " 250 91.3 69.7-143 4.27 25
Chlorobenzene 44 5.0 " 50.0 88.0 80.6-111 1.20 25
1,1,1,2-Tetrachloroethane 45 5.0 " 50.0 89.8 80.6-121 3.54 25
Ethylbenzene 46 5.0 " 50.0 91.1 79.9-129 0.939 25
m,p-Xylene 91 5.0 " 100 90.6 78.7-129 2.26 25
o-Xylene 46 5.0 " 50.0 91.6 76.6-135 3.69 25
Styrene 46 5.0 " 50.0 92.4 85.5-124 5.60 25
Bromoform 44 5.0 " 50.0 88.1 75.3-131 4.68 25
Isopropylbenzene (Cumene) 47 5.0 " 50.0 93.3 82.7-126 3.15 25
1,1,2,2-Tetrachloroethane 42 5.0 " 50.0 84.3 73.8-121 9.17 25
trans-1,4-Dichloro-2-butene 45 5.0 " 50.0 90.8 66.9-139 6.08 25

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 28 of 33

Page 28 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

LCS Dup (B9C2921-BSD1) Prepared & Analyzed: 24-Mar-19
1,2,3-Trichloropropane 45 5.0 ug/L 50.0 89.9 75-127 3.45 25
Bromobenzene 44 5.0 " 50.0 88.2 81.3-120 2.75 25
Propylbenzene 46 5.0 " 50.0 91.7 83.7-132 2.35 25
2-Chlorotoluene 45 5.0 " 50.0 90.4 82.9-122 3.67 25
1,3,5-Trimethylbenzene 45 5.0 " 50.0 91.0 84.8-126 4.66 25
4-Chlorotoluene 45 5.0 " 50.0 89.3 82.5-121 2.54 25
tert-butyl Benzene 46 5.0 " 50.0 92.3 85-128 1.82 25
1,2,4-Trimethylbenzene 46 5.0 " 50.0 91.1 86.7-124 4.82 25
sec-butyl Benzene 46 5.0 " 50.0 92.7 87.2-124 4.49 25
p-Isopropyltoluene 47 5.0 " 50.0 94.1 86-125 2.68 25
1,3-Dichlorobenzene 44 5.0 " 50.0 87.9 83.9-118 4.86 25
1,4-Dichlorobenzene 45 5.0 " 50.0 90.1 81.4-115 3.56 25
Benzyl Chloride 41 5.0 " 50.0 82.2 70-120 7.74 25
n-butyl Benzene 46 5.0 " 50.0 93.0 85.6-127 3.90 25
1,2-Dichlorobenzene 44 5.0 " 50.0 87.6 82.8-118 4.62 25
1,2-Dibromo-3-chloropropane 44 5.0 " 50.0 87.4 68.2-130 10.2 25
1,2,4-Trichlorobenzene 44 5.0 " 50.0 87.2 79.9-133 6.37 25
Hexachlorobutadiene 46 5.0 " 50.0 91.8 75.8-129 2.37 25
Naphthalene 45 5.0 " 50.0 90.8 65.2-145 6.44 25
1,2,3-Trichlorobenzene 44 5.0 " 50.0 87.7 73.7-140 4.59 25
Total Trihalomethanes 180 5.0 " 200 91.2 79.9-122 3.41 25
Total Xylenes 140 5.0 " 150 91.0 81.2-127 2.74 25

Surrogate: Dibromofluoromethane 52 " 50.0 104 70-120

Surrogate: 1,2-Dichloroethane-d4 51 " 50.0 101 70-120
Surrogate: Toluene-d8 49 " 50.0 98.4 70-120
Surrogate: 4-Bromofluorobenzene 52 " 50.0 103 70-120

Matrix Spike (B9C2921-MS1) Source: 19C2646-03 Prepared & Analyzed: 24-Mar-19

Dichlorodifluoromethane 52 5.0 ug/L 50.0 ND 104 53-136
Chloromethane 48 5.0 " 50.0 ND 96.5 48.4-151
Vinyl Chloride 52 5.0 " 50.0 ND 104 61-133
Bromomethane 59 5.0 " 50.0 ND 117 1.07-179

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 29 of 33

Page 29 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

Matrix Spike (B9C2921-MS1) Source: 19C2646-03 Prepared & Analyzed: 24-Mar-19
Chloroethane 60 5.0 ug/L 50.0 ND 119 38.7-150
Trichlorofluoromethane 53 5.0 " 50.0 ND 105 56.3-133
Diethyl ether 52 5.0 " 50.0 ND 105 55.3-152
Acetone <45 45 " 50.0 <45 88.6 10.8-177 J
Acrolein 51 5.0 " 50.0 ND 102 7.61-173
1,1-Dichloroethene 56 5.0 " 50.0 ND 111 51.6-155
Iodomethane 54 5.0 " 50.0 ND 107 2.11-190
Carbon Disulfide 50 5.0 " 50.0 ND 99.3 39.6-154
Acetonitrile 51 5.0 " 50.0 ND 103 52.8-164
Allyl Chloride 53 5.0 " 50.0 ND 105 49.9-169
Methylene Chloride 54 10 " 50.0 ND 108 60.9-140
Acrylonitrile 53 5.0 " 50.0 ND 107 39.3-158
MTBE (Methyl tert-butyl ether) 53 5.0 " 50.0 ND 107 60.9-140
trans-1,2-Dichloroethene 52 5.0 " 50.0 ND 105 59.7-149
1,1-Dichloroethane 51 5.0 " 50.0 ND 102 65.2-138
Vinyl Acetate 48 5.0 " 50.0 ND 95.5 35.4-174
2,2-Dichloropropane 49 5.0 " 50.0 ND 97.8 65.6-145
cis-1,2-Dichloroethene 53 5.0 " 50.0 ND 107 63.3-142
Bromochloromethane 50 5.0 " 50.0 ND 101 61.6-131
Chloroform 55 5.0 " 50.0 ND 111 48.7-151
2-Butanone 43 10 " 50.0 ND 85.7 35.8-153
1,2-Dichloroethane 50 5.0 " 50.0 ND 99.8 67.5-133
1,1,1-Trichloroethane 50 5.0 " 50.0 ND 99.8 78.9-126
Carbon Tetrachloride 50 5.0 " 50.0 ND 101 66.9-138
1,1-Dichloropropene 50 5.0 " 50.0 ND 100 79.3-129
Benzene 51 5.0 " 50.0 ND 102 74.6-128
Trichloroethene 51 5.0 " 50.0 ND 102 75.3-128
1,2-Dichloropropane 51 5.0 " 50.0 ND 103 76.8-130
Methyl methacrylate 54 5.0 " 50.0 ND 108 66.3-147
Dibromomethane 52 5.0 " 50.0 ND 104 68.1-134
Bromodichloromethane 53 5.0 " 50.0 ND 106 73.4-134
2-Chloroethyl vinyl ether <5.0 5.0 " 50.0 <5.0 1.28-195 0 Q

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 30 of 33

Page 30 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

Matrix Spike (B9C2921-MS1) Source: 19C2646-03 Prepared & Analyzed: 24-Mar-19
cis-1,3-Dichloropropene 52 5.0 ug/L 50.0 ND 104 77.5-135
trans-1,3-Dichloropropene 51 5.0 " 50.0 ND 102 77.5-143
1,1,2-Trichloroethane 53 5.0 " 50.0 ND 105 76.3-129
Dibromochloromethane 51 5.0 " 50.0 ND 101 74.3-134
1,2-Dibromoethane 52 5.0 " 50.0 ND 105 67.5-133
4-Methyl-2-Pentanone 44 10 " 50.0 ND 88.2 56.6-182
Toluene 48 5.0 " 50.0 ND 96.5 76.5-123
Tetrachloroethene 48 5.0 " 50.0 ND 95.5 57.9-135
1,3-Dichloropropane 51 5.0 " 50.0 ND 102 75.9-129
2-Hexanone 45 10 " 50.0 ND 90.9 47.9-159
Chlorobenzene 47 5.0 " 50.0 ND 94.5 76.2-115
1,1,1,2-Tetrachloroethane 51 5.0 " 50.0 ND 101 66-135
Ethylbenzene 51 5.0 " 50.0 ND 101 80.2-129
m,p-Xylene 100 5.0 " 100 ND 103 78-132
o-Xylene 51 5.0 " 50.0 ND 103 78.5-134
Styrene 52 5.0 " 50.0 ND 104 51.8-151
Bromoform 50 5.0 " 50.0 ND 100 71.6-134
Isopropylbenzene (Cumene) 53 5.0 " 50.0 ND 107 73.6-137
1,1,2,2-Tetrachloroethane 47 5.0 " 50.0 ND 94.3 61.6-134
trans-1,4-Dichloro-2-butene 45 5.0 " 50.0 ND 89.4 42.7-153
1,2,3-Trichloropropane 46 5.0 " 50.0 ND 91.9 66.7-132
Bromobenzene 48 5.0 " 50.0 ND 95.1 75.6-123
Propylbenzene 49 5.0 " 50.0 ND 98.5 77.7-132
2-Chlorotoluene 49 5.0 " 50.0 ND 97.7 77.7-127
1,3,5-Trimethylbenzene 50 5.0 " 50.0 ND 99.8 74.7-134
4-Chlorotoluene 48 5.0 " 50.0 ND 96.0 76.1-128
tert-butyl Benzene 49 5.0 " 50.0 ND 97.9 72.6-141
1,2,4-Trimethylbenzene 49 5.0 " 50.0 ND 98.1 72.7-135
sec-butyl Benzene 46 5.0 " 50.0 ND 91.4 77.2-130
p-Isopropyltoluene 49 5.0 " 50.0 ND 98.7 76.6-133
1,3-Dichlorobenzene 48 5.0 " 50.0 ND 96.7 78.3-122
1,4-Dichlorobenzene 48 5.0 " 50.0 ND 96.7 75.7-120

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 31 of 33

Page 31 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Volatile Organic Compounds by EPA 8260C - Quality Control

Envirodyne Laboratories, Inc.
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch B9C2921 - Organics

Matrix Spike (B9C2921-MS1) Source: 19C2646-03 Prepared & Analyzed: 24-Mar-19
Benzyl Chloride 46 5.0 ug/L 50.0 ND 91.9 70-120
n-butyl Benzene 50 5.0 " 50.0 ND 99.4 75.2-136
1,2-Dichlorobenzene 47 5.0 " 50.0 ND 93.6 76.5-123
1,2-Dibromo-3-chloropropane 48 5.0 " 50.0 ND 96.5 62.1-138
1,2,4-Trichlorobenzene 46 5.0 " 50.0 ND 91.2 62.1-144
Hexachlorobutadiene 44 5.0 " 50.0 ND 87.4 58-135
Naphthalene 46 5.0 " 50.0 ND 91.9 48.1-153
1,2,3-Trichlorobenzene 44 5.0 " 50.0 ND 88.7 47.2-153
Total Trihalomethanes 210 5.0 " 200 ND 104 64.5-146
Total Xylenes 160 5.0 " 150 ND 105 78.5-132

Surrogate: Dibromofluoromethane 54 " 50.0 109 70-120

Surrogate: 1,2-Dichloroethane-d4 52 " 50.0 104 70-120
Surrogate: Toluene-d8 50 " 50.0 99.0 70-120
Surrogate: 4-Bromofluorobenzene 51 " 50.0 101 70-120

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 32 of 33

Page 32 of 35
 Envirodyne Laboratories, Inc
11011 Brooklet Dr., # 230
Houston, TX 77099
281.568.7880 Phone
www.envirodyne.com

Client: KHOU 11 News

Project: Ship Channel Water Testing Reported:
Work Order: 19C2732 29-Mar-19 17:24

Notes and Definitions

RPD Relative Percent Difference

Q QC did not meet ELI acceptance criteria

L Analyzed by third party laboratory

J Analyte detected below quantitation limits

DET Analyte DETECTED

ND Analyte NOT DETECTED at or above the reporting limit

NR Not Reported

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

CLT Client Representative

Envirodyne Laboratories, Inc. The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.

Monica Smith, Client Services Representative Page 33 of 33

Page 33 of 35
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