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I. MO Diagram. Draw the MO diagram, compute for its BO and if it exists. If yes, identify whether it is
paramagnetic or diamagnetic.
1. Li2
2. CF
3. CH4
1. Orange
2. Green
3. Yellow
4. Blue
5. gray
6. Orange
7. Green
8. Yellow
9. Blue
10. gray
III. Functional Groups and Isomers
A.
1. 2.
(from mcmurry)
3. 4. 5.
6. 7. 8.
(from mcmurry)
B. Propose structures that meet the following descriptions:
(from mcmurry)
(a) Biacetyl, C4H6O2, a substance with the aroma of butter; it contains no rings or carbon–carbon
multiple bonds.
(b) Ethylenimine, C2H5N, a substance used in the synthesis of melamine polymers; it contains no
multiple bonds.
(c) Glycerol, C3H8O3, a substance isolated from fat and used in cosmetics; it has an -OH group on each
carbon. (from mcmurry)
IV. Essay
2. Why is it that the bonding molecular orbital has lower energy level compared to antibonding
molecular formula? (5pts)
4. Why is it that there is a switching of positions of σ orbital and π orbital between N and O? (5pts)