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141.5 141.5
°API = 𝑆𝐺 − 131.5 OR: SG@15.6̊C = °𝐴𝑃𝐼+131.5
@15.6℃
140.5 140.5
°Baume = 𝑆𝐺 − 130.5 SG@15.6 = °𝐵𝑎𝑢𝑚𝑒+130.5
@15.6℃
140
Other reference: °Baume = 𝑆𝐺 − 130
@15.6℃
Higher Heating Value or Gross Calorific Value – is the heating value obtained when the water in
the products of combustion is in liquid state.
Lower Heating Value or Net Calorific value – is the heating value obtained when the water in the
products of combustion is in vapour state.
4. Viscosity of Lubricants
- Resistance to flow or the property which resists shearing of the lubricant.
Units of Viscosity:
For absolute viscosity: For Kinematic viscosity:
𝑙𝑏−𝑠𝑒𝑐 𝑐𝑚2
1 reyn = 1 stroke = 1
𝑖𝑛2 𝑠𝑒𝑐
𝑑𝑦𝑛𝑒−𝑠𝑒𝑐
where: 1 poise = = 0.1 Pa-sec
𝑐𝑚2
Viscosimeter – an instrument, consisting of standard orifice, used for measuring viscosity (in SSU
and SSF).
SSU ( Saybolt Second Universal) – number of seconds required for 60ml of oil (@ 37.5 °C) to
pass through a standard orifice.
SSF (Saybolt Second Furol) – unit used for very viscous liquids using a relatively large orifice).
1 centistoke = 0.308 (SSU-26)
62 SF = 660SSU
COMBUSTION
– is the process of chemical reaction between fuel and oxygen (reactants). The process releases
heat and produces products of combustion.
- The main elements which burn are: carbon, hydrogen and sulfur. The heat released by 1kg or
m3 of fuel is called CALORIFIC VALUE. “The oxygen used in combustion processes normally
comes from the atmosphere and this brings nitrogen in with it which normally does nothing in
the process but makes up the bulk of the gases remaining after combustion”.
- It is a special exothermic chemical reaction in which oxygen is a major reactant.
Exothermic – means it gives out heat therefore Δh is negative.
Endothermic – means reaction absorbs heat and Δh is positive.
1. Theoretical air-fuel ratio - the exact theoretical amount, as determined from the
combustion reaction, or air needed to burn a unit amount of fuel, kg air per kg of fuel.
𝐴 𝑚
(𝐹)t = air-fuel ratio = 𝑚𝑎
𝑓
Combustion of solid fuel with known ultimate analysis:
𝑂 𝑘𝑔
Theoretical A/F = 11.5C+34.5(H - 8 ) +4.3S ;𝑘𝑔 𝑎𝑖𝑟
𝑓𝑢𝑒𝑙
Where: C,H,O and S are proportions by weight of Carbon, Hydrogen, Oxygen and Sulfur per kg
of fuel from the ultimate analysis.
𝐴
2. Actual air-fuel ratio ;(𝐹)a = theoretical air-fuel ratio plus excess air.
𝑘𝑔𝑎𝑖𝑟
A/F = (Theoretical A/F)(1+e) ; where: e = excess air
𝑘𝑔𝑓𝑢𝑒𝑙
Typical combustion reaction of liquid fuels:
1. Molecular weights:
C = 12 H=1 O = 16 N =14 S = 32
Molecular weight of air = 28.92 kg/kg-mol
2. Composition of Air
Air by volume consists of: Air by weight:
21% of oxygen Oxygen = 23.20%
79% nitrogen Nitrogen = 76.80%
thus there are 3.76 mols of N2 per mol of O2.
𝐴
3. Theoretical air-fuel ratio:(𝐹)t
Fuel + air = Products of combustion
CnHm + xO2 + x (3.76)N2 = yCO2 + zH2O + x(3.76)N2
𝑚
Theoretical air-fuel ratio = 𝑚𝑎
𝑓
Molal basis:
𝑚𝑜𝑙
Theoretical air-fuel ratio = x + 3.76x ; 𝑚𝑜𝑙 𝑎𝑖𝑟
𝑓𝑢𝑒𝑙
Mass basis:
32𝑥+28(3.76)𝑥 𝑘𝑔
Theoretical air - fuel ratio = ; 𝑘𝑔 𝑎𝑖𝑟
12𝑛+𝑚 𝑓𝑢𝑒𝑙
𝐴
1. Actual air-fuel ratio: :(𝐹)a
Considering the excess air, e
Fuel + air = Products of combustion
CnHm + (1+e) x O2 +(1+e) x (3.76)N2 = yCO2 + zH2O + (1+e) x (3.76)N2 + e (x)O2
𝑚
2𝑛+ 𝑚 𝑚
2
For perfect combustion: x= =𝑛+ y=n z=
2 4 2
Gas Constant, R:
8.314 𝐾𝐽
R= 𝑀 ; 𝑘𝑔−°𝐾
1545 𝑓𝑡−𝑙𝑏
R= 𝑀
; 𝑙𝑏−𝑅
where: M= molecular weight of gas