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I n the manufacture of trisodium phosphate, phosphoric tion of double salts in the product or by spray-con-
acid is added to a solution of soda ash to form disodium gealing.
phosphate, with evolution of carbon dioxide. The solu- The value of trisodium phosphate a s a detergent is due
tion is diluted and extraneous matter removed by filtra- to its high pH value in solution, its ability to lower inter-
tion. Sodium hydroxide, added to t h e filtrate, converts it facial tension against oils or solids, and its marked power
to trisodium phosphate. This solution is diluted, filtered of emulsifying oils. Trisodium phosphate is used a s a
hot, and crystallized. The crystals of trisodium phosphate detergent in households, laundries, factories, hotels,
are separated from the filtrate, dried, meshed, and aged. dairies, and garages. I t is used a s a water softener and
A spray-congealed product may also be prepared from the boiler compound because of its ability to precipitate cal-
clear trisodium phosphate solution. cium and magnesium phosphates. It has many other
Caking of the crystals may be avoided either by forma- miscellaneous uses.
.....
HE tertiary sodium salt of phosphoric acid finds use in liberated. As the neutralization proceeds, steam is used for
T industry because of various applications of two proper- heating the batch to boiling. Slightly more phosphoric acid
ties. The salt in water hydrolyzes to give a solution is added than that required to convert all the soda ash to
of reasonably high pH value, well buffered a t that level disodium phosphate. The solution is then boiled until
against neutralization. This pH value is higher than that of all the carbon dioxide has been eliminated. Since the pH
soda ash and modified soda, the principal competitive alkalies. level at which the third hydrogen of phosphoric acid is
The salt forms insoluble phosphates under conditions which neutralized is higher than that a t which the second hydrogen
permit its use for removal of heavy metal ions from solution. of carbonic acid is converted to form sodium carbonate, it is
The manufacture of trisodium phosphate is essentially not to be expected that phosphoric acid can be neutralized
the neutralization of phosphoric acid and subsequent crys- further than to the disodium stage with sodium carbonate.
tallization. For economic reasons it is desirable to neut.ra1- Plant experience confirms this since, if just sufficient phos-
ize in two stages as follows: phoric acid is added theoretically to convert all the soda ash
to disodium phosphate, some remains unconverted in the mix.
The practically complete elimination of carbon dioxide
by boiling is insured by laboratory control. At suitable in-
The phosphoric acid may be of variable purity and concen- tervals the batch is sampled. One portion of the sample is
t r a t i o n . The process de- further boiled in the labora-
scribed in this paper is one used tory; another is not. Both
with electric furnace acid by are then titrated. Agreement
the Swann Chemical Company. shows c o m p l e t e removal of
An outstanding feature of the carbon dioxide in the plant.
process is the absence of con- By addition of mother liquor
centration or e v a p o r a t i o n from a previous crystalliza-
steps. With some modifica- tion of trisodium phosphate
tion it is applicable to acid the specific gravity of the mix
made by the Dorr process. is suitably lowered. This gives
a solution of disodium phos-
MANUFACTURE
?
phate, the excess alkalinity of
Production of Disodium Tri s o d i urn P h o s p h a f e the trisodium phosphate crys-
Phosphate Liquor tallizing liquor having neutral-
Solutlon
ized any deficiency in the
I n a 4000-gallon tank (right, batch below the disodium
Figure 1) equipped with an [ T i t e r
I I phosphate stage. This solu-
agitator, 7000 pounds of 58 per tion of disodium p h o s p h a t e
cent soda ash are suspended carries in suspension any solid
in 900 gallons of hot liquid. 1 i impurities from the phosphoric
This liquid may be water, but acid, as well as iron, aluminum,
is more commonly wash liquor and calcium which were in the
from filtration of previous phosphoric acid and soda ash
batches of disodium phosphate solutions.
or mother liquor from diso- The diluted disodium phos-
dium phosphate manufacture. phate s o l u t i o n is filtered
Phosphoric acid containing ap- through a deeply recessed
proximately 45 per cent PzO6 plate-and-frame filter p r e s s
is added a t the surface of the (left, Figure 1) and the filtrate
tank so that the carbon dioxide pumped directly to storage
evolved can be more readily t a n k s . This f i l t r a t i o n is
1 Received December 9, 1930. Flow Sheet for Trisodium Phosphate carried out at 85-100° C. The
allay, 1931 INDUSTRIAL A N D ENGINEERING CHEMISTRY 471
PiCure 1 -Tanks and Filter Pres8 I'ned In Manufacture of Figure Z--CausfIc Pot8
Disodium Phoaphafe
As with all crystalliiie prodiicts, oiic problem is that of h decline in average value in a pcriud of generally advancing
caking. h i general, coarse crysials arc produced because t h i prices is indicated. The distribution of consumpt,ion in 102
caking tendencies are less. Government specifications requin is shown iii Table 11.
that a t least 50 per cent of the product pass 10 mcsh and Ix
retained on 100 mesh (.5). Table 11-Consumption of Trisodium Phosphate in 1927
Paundr % of T o l d
HE chemical industry probably uses as much steam and provided yorld peace obtains. Upon the return of commerce