Biodiesel

 Biodiesel is made from virgin or used vegetable oils (both edible & non-
edible) and animal fats through trans-etherification and is a diesel
substitute and requires very little or no engine modifications up to 20%
blend and minor modification for higher percentage blends.
 The use of biodiesel results in substantial reduction of un-burnt
hydrocarbons, carbon monoxide and particulate matters.
 It has almost no sulphur, no aromatics and has about 10 % built in oxygen,
which helps it to burn fully. Its higher cetane number improves the
combustion.

a. Problems in Using Petroleum Derived HSD:

 Like all fossil fuels the use of HSD also makes net addition of Carbon to the
atmosphere.
 In addition, diesel emits particulate matter (PM), specially below micron 2.5
which passes the protection system of the body to get lodged in lungs
causing reduction in its vital capacity.
 In association with the particulate matter the un-burnt oil is carcinogenic.
In addition Carbon Monoxide, Hydrocarbon, Sulphur and PAH emissions are
on the higher side.
 Attempts to reduce particulate matter emissions have not been entirely
successful.
 A 15% ethanol –diesel blend reduces particulate matter emission, however
the blend provides certain technical problems for which satisfactory
solution has not been found.
 b. Characteristics of Biodiesel Bio-diesel is fatty acid ethyl or methyl ester
and has properties similar to petroleum diesel fuels.
 Similar to the HSD, bio diesel is its substitute.
 The specifications of bio-diesel are such that it can be mixed with any diesel
fuel. Cetane number (CN) of the bio-diesel is in the range of 48-60 and the
sulphur content is typically less than 15 ppm.
  Studies conducted with bio-diesel on engines have shown substantial
reduction in Particulate matter (25 – 50%).
 However, a marginal increase in NOx (1-6%) is also reported; but it can be
taken care of either by optimization of engine parts or by using DeNOx
catalyst .
 HC and CO emissions were also reported to be lower.
 Non-regulated emissions like PAH Polycyclic aromatic hydrocarbon etc
were also found to be lower.
 Thus, bio-diesel can supplement the supply of environment friendly fuels in
our country in future.
 In conventional diesel fuels, the reduction in sulfur content is compensated
by adding additive for lubricity of fuel injection pump (FIP).
 Bio-diesel is reported to have superior lubricity. Flash point of bio-diesel is
high (> 100o C).
 Its blending with diesel fuel can be utilized to increase the flash point of
diesel particularly in India where flash point is 35o C well below the world
average of 55o C. This is important from the safety point of view.
 The viscosity of biodiesel is higher (1.9 to 6.0 cSt) and is reported to result
into gum formation on injector, cylinder liner etc.

Why IDID Deposits are Lethal

Traditionally, coking deposits built up over time, affecting engine performance so

slowly that the effect on fuel economy and performance was not immediate. IDID
deposits have a more abrupt impact. Affecting the internal moving parts, where
tolerances are extremely tight and the parts light, the deposits cause binding or
sticking. In extreme cases, the injector gets stuck in an open or closed
position. More commonly, the parts will move slowly and not accomplish the
required multiple injections with split second timing. IDID has been reported to
develop in less than 100 hours.
  However, blends of up to 20% should not give any problem. While an
engine can be designed for 100% bio-diesel use, the existing engines can
use 20% biodiesel blend without any modification and reduction in torque
output.
 In USA, 20% biodiesel blend is being used, while in European countries 5 -
15% blends have been adopted. Bio-diesel can be blended in any ratio with
petroleum diesel fuel. It can be stored just like the petroleum diesel fuel
and hence does not require separate infrastructure.
 Bio-diesel has been accepted as clean alternative fuel by US . Due to its
favorable properties, biodiesel can be used as fuel for diesel engines ( as
either,B5-a blend of 5% bio-diesel in petro-diesel fuel,) or B20 or B100).
USA uses B20 and B100 bio-diesel, France uses B5 as mandatory in all diesel
fuel. Sunflower, rapeseed is the raw material for Bio-Diesel used in Europe
whereas soybean is used in USA. Thailand uses palm oil, Ireland uses frying
oil and animal fats.
 In India it is proposed to use non-edible oil for producing Biodiesel.
Presently many species are being grown which yield seed containing non-
edible oil. The present production is being used and much surplus is not
available. It is proposed to take up a major plantation programme of
Jatropha curcas, for reasons which are given in the later part of this report,
to provide the oil needed.

c. Rationale: The rationale of taking up a major programme for the production of

bio-diesel in India for blending with diesel lies in the context of : ix ·

 Bio-diesel being a superior fuel than HSD from the environmental

point of view;
 Use of bio-diesel becomes compelling in view of the tightening of
automotive vehicle emission standards and court interventions; ·
 The need to provide energy security, specially for the rural areas; ·
 The need to create employment; · Providing nutrients to soil,
checking soil erosion and land degradation; ·
 Rehabilitating degraded lands through greening; ·
 Addressing global concern relating to containing Carbon emissions
as provided in the Framework Convention on Climate Change; and
 Reduce dependence on crude oil imports