Documente Academic
Documente Profesional
Documente Cultură
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Disinfectants and general biocidal products
stance/Mixture
Recommended restrictions : For professional users only.
on use
Hazard symbols :
Corrosive Dangerous
for the envi-
ronment
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
Hazardous components
Chemical Name Index-Number Classification Classification Concentration
CAS-No. (67/548/EEC) (REGULATION [%]
EC-No. (EC) No
Registration 1272/2008)
number
Quaternary ammonium 68424-85-1 Xn; R21/22 Acute Tox. 4; H302 22 %
compounds, benzyl- 270-325-2 C; R34 Acute Tox. 4; H312
C12-16-alkyldimethyl, N; R50 Skin Corr. 1B;
chlorides H314
Aquatic Acute 1;
H400
M-Factor 10
2-Phenoxyethanol 603-098-00-9 Xn; R22 Acute Tox. 4; H302 10 - 20 %
122-99-6 Xi; R36 Eye Irrit. 2; H319
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
204-589-7
1-
2119488943-
21-XXXX
Alkyl polyglycol ether 31726-34-8 Xn; R22 Acute Tox. 4; H302 <5%
Polymer Xi; R38 Skin Irrit. 2; H315
Xi; R41 Eye Dam. 2; H319
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
If inhaled : Move the victim to fresh air and keep him calm.
If unconscious place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
In case of skin contact : Wash off immediately with plenty of water for at least 15
minutes.
If symptoms persist, call a physician.
In case of eye contact : In case of eye contact, remove contact lens and rinse imme-
diately with plenty of water, also under the eyelids, for at least
15 minutes.
Z11816 ZSDB_P_SG EN Page 3/14 0082054628
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Treat symptomatically.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : For specialist advice physicians should contact the Poisons
Information Service.
Specific risk from the sub- : Fire may cause evolution of:, Carbon dioxide (CO2), carbon
stance or the product itself, monoxide (CO), oxides of nitrogen (NOx)
its combustion products or
evolved gases
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
220 mg/m3
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
Engineering measures
Ensure that eyewash stations and safety showers are close to the workstation location.
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
no data available
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
The product is chemically stable.
10.3 Possibility of hazardous reactions
None reasonably foreseeable.
10.4 Conditions to avoid
Extremes of temperature and direct sunlight.
10.5 Incompatible materials
Strong acids
10.6 Hazardous decomposition products
None reasonably foreseeable.
Acute toxicity
Product
Acute oral toxicity : LD50: 1250 mg/kg, rat, Calculation method
Acute inhalation toxicity : LC50: 2,5 mg/l, 4 h, rat, Calculation method
Acute dermal toxicity : LD50: 1440 mg/kg, Calculation method
Skin corrosion/irritation
Product
Causes skin burns.
Serious eye damage/eye irritation
Product
Causes eye burns.
Respiratory or skin sensitisation
Components:
Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides:
Did not cause sensitisation on laboratory animals. guinea pig
2-Phenoxyethanol:
Did not cause sensitisation on laboratory animals. Maximisation Test (GPMT) guinea pig OECD
Test Guideline 406
Tridecylpolyethylenglycolether:
Did not cause sensitisation on laboratory animals. Maximisation Test (GPMT) guinea pig
Propan-2-ol:
Did not cause sensitisation on laboratory animals. Buehler Test guinea pig
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
Reproductive toxicity
Components:
Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides:
Reproductive toxicity - As- : Animal testing did not show any effects on fertility.
sessment
2-Phenoxyethanol:
Reproductive toxicity - As- : Animal testing did not show any effects on fertility.
sessment
Tridecylpolyethylenglycolether:
Two-generation studyrat, NOAEL: > 250 mg/kg, F1: > 250 mg/kg, F2: > 250 mg/kg
Reproductive toxicity - As- : Based on available data, the classification criteria are not met.
sessment
Propan-2-ol:
Reproductive toxicity - As- : Animal testing did not show any effects on fertility.
sessment
Alkyl polyglycol ether:
Reproductive toxicity - As- : no data available
sessment
Tetrahydroxypropylethylendiamin:
Reproductive toxicity - As- : Animal testing did not show any effects on fertility.
sessment
Amines, n-C10-16-alkyltrimethylenedi-,reaction products with chloroacetic acid:
Reproductive toxicity - As- : no data available
sessment
Teratogenicity
Components:
Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides:
Teratogenicity - Assessment : Did not show teratogenic effects in animal experiments.
2-Phenoxyethanol:
Teratogenicity - Assessment : Did not show teratogenic effects in animal experiments.
Tridecylpolyethylenglycolether:
rat, Oral, NOAEL: > 50 mg/kg, NOAEL: 50 mg/kg
rat, Dermal, NOAEL: > 250 mg/kg, NOAEL: 250 mg/kg
Teratogenicity - Assessment : Based on available data, the classification criteria are not met.
Propan-2-ol:
Teratogenicity - Assessment : Ingestion of excessive amounts by pregnant animals resulted
in maternal and foetal toxicity.
Alkyl polyglycol ether:
Teratogenicity - Assessment : no data available
Tetrahydroxypropylethylendiamin:
Teratogenicity - Assessment : Did not show teratogenic effects in animal experiments.
Amines, n-C10-16-alkyltrimethylenedi-,reaction products with chloroacetic acid:
Teratogenicity - Assessment : no data available
STOT - single exposure
Components:
Tridecylpolyethylenglycolether:
The substance or mixture is not classified as specific target organ toxicant, single exposure.
STOT - repeated exposure
Components:
Tridecylpolyethylenglycolether:
Assessment: The substance or mixture is not classified as specific target organ toxicant, repeat-
ed exposure.
Z11816 ZSDB_P_SG EN Page 10/14 0082054628
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
12.1 Toxicity
Product
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0,18 mg/l, 48 h, Analyti-
aquatic invertebrates cal monitoring: yes, OECD Test Guideline 202, GLP: yes
12.2 Persistence and degradability
Product
Biodegradability : Readily biodegradable., OECD 301D / EEC 84/449 C6
Chemical Oxygen Demand : ca. 13.640 mg/l , 1% solution
(COD)
12.3 Bioaccumulative potential
Product
Partition coefficient: n- : not applicable
octanol/water
12.4 Mobility in soil
Components:
Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides :
Mobility : no data available
2-Phenoxyethanol :
Mobility : Mobile in soils
Tridecylpolyethylenglycolether :
Mobility : The product evaporates slowly., Adsorbs on soil.
Propan-2-ol :
Mobility : Mobile in soils
Tetrahydroxypropylethylendiamin :
Mobility : no data available
Amines, n-C10-16-alkyltrimethylenedi-,reaction products with chloroacetic acid :
Mobility : no data available
12.5 Results of PBT and vPvB assessment
Product
This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
Z11816 ZSDB_P_SG EN Page 11/14 0082054628
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
Waste key for the unused : European waste catalog (EWC) 070601
product
Waste key for the unused : Waste material of HZVA from fats, lubricants, soaps, deter-
product(Group) gents, disinfectants and personal protection products.
14.1 UN number
ADR : 1903
IMDG : 1903
IATA IATA_C : 1903
14.2 Proper shipping name
ADR : DISINFECTANT, LIQUID, CORROSIVE, N.O.S.
(Quaternary ammonium compounds, benzyl-C12-16-
alkyldimethyl, chlorides)
IMDG : DISINFECTANT, LIQUID, CORROSIVE, N.O.S.
(Quaternary ammonium compounds, benzyl-C12-16-
alkyldimethyl, chlorides)
IATAIATA_C : DISINFECTANT, LIQUID, CORROSIVE, N.O.S.
(Quaternary ammonium compounds, benzyl-C12-16-
alkyldimethyl, chlorides)
14.3 Transport hazard class
ADR : 8
IMDG : 8
IATAIATA_C : 8
14.4 Packing group
ADR
Packaging group : III
Classification Code : C9
Hazard Identification Number : 80
Labels : 8 (N)
Tunnel restriction code : E
IMDG
Packaging group : III
Labels : 8 (N)
EmS Number : F-A, S-B
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
IATAIATA_C
Packing instruction (cargo : 820
aircraft)
Packaging group : III
Labels : 8 (N)
14.5 Environmental hazards
ADR
Environmentally hazardous : yes
IMDG
Marine pollutant : yes
IATA
Environmentally hazardous : yes
14.6 Special precautions for user
For personal protection see section 8.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Exempt
15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
Volatile organic compounds : 22 %, Directive 1999/13/EC on the limitation of emissions of
volatile organic compounds
terralin® protect
Version 03.04 Revision Date 07.01.2014 Print Date 15.07.2014
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-
formation and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
is not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with
any other materials or in any process, unless specified in the text.