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Radioactive Pollution: An Overview The Holistic Approach to Environment

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G. Hazra Radioactive Pollution: An Overview

ISSN 1848-0071
614.7+553.76=111
Recieved: 2017-09-04
Accepted: 2017-11-30
Review

RADIOACTIVE POLLUTION: AN OVERVIEW

GOUTAM HAZRA

Department of Chemistry, Kalna College, Kalna, West Bengal, India


e-mail: goutamhazra1@gmail.com

The civilian radioactive waste encompasses a wide range of materials, most of the current debate focuses on highly radioactive
spent fuel from nuclear power plants. Other types of civilian radioactive waste have also generated by nuclear power plants,
medical institutions, industrial operations, and research activities. Disposal of radioactive waste will be a key issue in the
continuing nuclear power debate. Without a national disposal system, spent fuel from nuclear power plants must be stored on-site
indefinitely. the strategy for the management and disposal of used nuclear fuel and high-level radioactive waste has highlighted
agreement with many of the principles of the IAEA recommendations and has outlined actions that, with legislative authorizati on
by Congress, can lead to a safe and responsible solution to managing the nation‘s nuclear waste. Indeed, action by Congress in
the form of new authorizing legislation and appropriations is necessary.
Key words: radioactive spent, nuclear power plants, radioactive waste.

Radioaktivno onečišćenje: Pregled. Civilni radioaktivni otpad obuhvaća široki raspon materijala; većina aktualne rasprave
usmjerena je na visoko radioaktivno istrošeno gorivo iz nuklearnih elektrana. Druge vrste civilnog radioaktivnog otpada također
generiraju nuklearne elektrane, medicinske ustanove, industrijski procesi i istraživačke aktivnosti. Zbrinjavanje radioaktivnog
otpada bit će ključno pitanje u kontinuiranoj raspravi o nuklearnoj energiji. Bez nacionalnog sustava zbrinjavanja, istrošeno
gorivo iz nuklearnih elektrana mora se pohraniti na neodređeno vrijeme. Strategija upravljanja i zbrinjavanja korištenog
nuklearnog goriva i visokoradioaktivnog otpada istaknula je suglasnost s mnogim načelima preporuka IAEA (Međunarodna
agencija za atomsku energiju) i opisala aktivnosti koje uz zakonodavno odobrenje Kongresa mogu dovesti do sigurnog i
odgovornog rješenja za upravljanje nacionalnim nuklearnim otpadom. Doista, Kongres treba poduzeti aktivnosti u obliku nove
legislative i izdvajanja proračunskih sredstava.
Ključne riječi: radioaktivno onečišćenje, nuklearne elektrane, radioaktivni otpad.

INTRODUCTION

Certain elements that compose matter radiation with shorter wavelengths than any
emit particles and radiations spontaneously. X-rays. These ‗rays‘ can penetrate living
This phenomenon is referred to as tissues for short distances and affect the
‗radioactivity‘; it cannot be altered by tissue cells. But because they can disrupt
application of heat, electricity or any other chemical bonds in the molecules of
force and remains unchangeable. Three important chemicals within the cells, they
different kinds of rays, known as alpha, beta help in treating cancers and other diseases.
and gamma rays are associated with Every element can be made to emit such rays
radioactivity. The alpha rays consist of artificially. If such radioactive elements are
particles (nuclei of helium atoms) carrying a placed in the body through food or by other
positive charge, beta rays particles have methods, the rays can be traced through the
negative charge (streams of electrons) and body. This use of tracer elements is
gamma rays are charge less electromagnetic extremely helpful in monitoring life

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G. Hazra Radioactive Pollution: An Overview

processes. Geologists use radioactivity to nuclear weapons and installation of nuclear


determine the age of rocks. As atoms lose reactors for generating electricity. We shall
particles as heavy as nuclei of helium, they discuss the possible threat to human health
become atoms of some other element. That and environment due to nuclear radiations
is, the elements change or ‗transmute‘ into both from natural and anthropogenic (man-
other elements until the series ends with a made) sources. Radioactive waste, arising
stable element. Radioactive elements decay from civilian nuclear activities as well as
at different rates. Rates are measured as half- from defence-related nu- clear-weapon
lives – that is, the time it takes for one half activities, poses a formidable problem for
of any given quantity of a radioactive handling and protecting the environment to
element to disintegrate. The longest half-life be safe to the present and future generations.
is that of the ‗isotope‘ 238U of uranium is 4.5 This article deals with this global problem in
billion years [1]. Some isotopes have half- its varied aspects and discusses the cause for
lives of years, months, days, minutes, concern, the magnitude of the waste
seconds, or even less than millionths of a involved and various solutions proposed and
second. Every inhabitant on this planet is being practised. As nuclear power and
constantly exposed to naturally occurring arsenal grow, continuous monitoring and
ionizing radiation called back- ground immobilization of the waste over several
radiation. Sources of background radiation decades and centuries and deposition in safe
include cosmic rays from the Sun and stars, repositories, assumes great relevance and
naturally occurring radioactive materials in importance [3]. Methods for the safe
rocks and soil, radionuclide normally disposal of nuclear waste materials will also
incorporated into our body‘s tissues, and be discussed. This method is the state-of-the-
radon and its products, which we inhale. We art in nuclear waste disposal technology. It is
are also exposed to ionizing radiation from the single viable means of disposing
man-made sources, mostly through medical radioactive waste that ensures non return of
procedures like X-ray diagnostics. Radiation the relegated material to the biosphere. At
therapy is usually targeted only to the the same time, it affords inaccessibility to
affected tissues [2]. eliminated weapons material. The principle
In this lesson we will discuss about involved is the removal of the material from
the radiations which are the cause of the biosphere faster than it can return. It is
radioactive pollution. These radiations are considered that ‗the safest, the most sensible,
emitted by radioactive decay of unstable the most eco- nominal, the most stable long-
heavy atoms nuclei. Exposure of these term, the most environmentally benign, the
radiations can cause damage to living cells most utterly obvious places to get rid of
and environment. Concern for radioactive nuclear waste, high-level waste or low- level
pollution increased after the discovery of waste is in the deep oceans that cover 70%
artificial radioactivity, development of of the planet‘[4].

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G. Hazra Radioactive Pollution: An Overview

Figure 1. The world's largest nuclear power plant, Kashiwazaki-Kariwa in Japan


Slika 1. Najveća nuklearna elektrana na svijetu, Kashiwazaki-Kariwa u Japanu

WHAT IS RADIOACTIVE POLLUTION?

Production of electricity per capita is pollution and the man is guilty for all of
considered as one of the major development them. The nuclear experiments have led in
index of a country .Among the power some areas on Earth to radioactive waste
generation technologies, nuclear fission is storage and to emanations from the nuclear
one of them .The nuclear power generation centres where there had been accidents (for
has been developed since 1960 and now example the accident from Chernobyl –
around 450 nos. of atomic fission power Ukraine and Fukushima Daiichi nuclear
reactors are there over the world. In nuclear power station –Japan). The radioactive
power production, the power generated from pollution represents a big danger for the
1 gm of U is equivalent to the power humans' and animals' lives. The most
generated from 2083 kg of coal. A large dangerous long-lived radio- nuclides are
amount of energy released in exchange of those emitted by nuclear reactors: they can
small amount of nuclear fuel but the major last even for a century! These radioactive
problem in producing nuclear power is its killers are conserved in soil, from where they
radioactive waste. The future development go to the plants and animals. For example, in
of nuclear power largely depends on the the Northern areas of Europe and America,
success of programmed and management of where nuclear experiments were made, the
radioactive waste generated at various stages lichens store caesium radioactive and the
of the nuclear fuel cycle. reindeer eat the lichens, which store isotopes
Apart from the biological pollution, the in return. By eating reindeer meat, the
industrial and the chemical pollution of the Lapland was loaded with radioactive
soil, nowadays there is also the radioactive isotopes 10 times more than other [5].

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G. Hazra Radioactive Pollution: An Overview

Figure 2. Picture of radioactive waste materials


Slika 2. Slika radioaktivnog otpada

RADIATION NATURE & TYPE

Radiation is energy travelling Ionizing radiations are the


through space. Energy can be transported electromagnetic radiations having high
either in form of electromagnetic waves energy, such as short wavelength ultra violet
(radiations) or a stream of energetic radiations, x-rays and gamma rays. The
particles, which can be electrically charged energetic rays like produced in radioactive
or neutral. decay can cause ionization of atoms and
These radiations are of two types: molecules of the medium through which
 Non-ionizing radiations they pass and convert them into charged
 Ionizing radiations ions. For example in water molecule, it can
 induce reaction that can break bonds in
Non-ionizing radiations are the proteins, DNA and or other important
electromagnetic waves of longer wavelength molecules. Alpha, beta and gamma
from near ultraviolet rays to radio waves. radiations are produced by the process called
These waves have energies enough to excite radioactive decay. The unstable nuclei decay
the atoms and molecules of the medium spontaneously and emit these radiations.
through which they are moving, causing These rays (radiations) can affect some other
them to vibrate faster. These do not have non-radioactive atoms to become radioactive
enough energy to ionize them. (unstable) and give out radioactive radiations
[6].

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G. Hazra Radioactive Pollution: An Overview

RADIOACTIVE POLLUTION &


THEIR SOURCES

Living organisms are continuously 1. Natural sources


exposed to a variety of radiations called  Cosmic rays
background radiations. If the level of the  Terrestrial radiation
radioactive radiations increases above a 2. Man-Made sources
certain limit it causes harmful effects to  Medical sources
living beings. This harmful level of  Industrial sources
radiations emitted by radioactive elements is  Nuclear Explorations
called radioactive pollution. There are two  Nuclear Power
types of sources [7].  Nuclear & Radiation accidents

Natural sources

Throughout the history of life on earth, measurements were made at various


organisms continuously have been exposed altitudes from sea level to 9,000 m. It was
to cosmic rays, radionuclide produced by found that the ionizing radiation rate
cosmic ray interactions in the atmosphere, decreased for some 700 m and from that
and radiation from naturally occurring point increased quite rapidly with elevation.
substances which are ubiquitously The initial decrease could be explained by a
distributed in all living and nonliving decreased intensity of terrestrial gamma
components of the environment. It is clear rays, while the increasing component was
that contemporary life have adjusted or are due to cosmic rays. The likely origin of
doing so to all features and limitations of the cosmic rays is the almost infinite number of
environment, including the natural radiation stars in the Universe. Evidence for this is the
background. Although high levels of increased cosmic ray intensity observed on
radiation are definitely harmful to earth following solar flares. However, it is
organisms, some environmental radiation is clear that the sun is not normally a major
of importance to life, as we know it. For contributor to the total cosmic flux since
example, background radiation has diurnal variations are very small. Cosmic
contributed, though we do not know how rays may be termed "primary" or
much, to the fundamental processes of "secondary". Those, which have not yet
chemical and biological evolution. Of clearer interacted with matter in the earth's
importance is the fact that the earth's heat atmosphere, lithosphere, or hydrosphere, are
content is principally provided and termed primary. These consist principally of
maintained by the heat of decay of protons (≈85%) and alpha particles (≈14%),
primordial, naturally occurring radionuclide. with much smaller fluxes (<1%) of heavier
Cosmic rays nuclei. Secondary cosmic rays, which are
Radiation of extraterrestrial origin, which produced by interactions of the primary rays
rain continuously upon the earth, is termed and atmosphere, consist largely of subatomic
"cosmic rays". The fact that this highly particles such as pions, muons, and
penetrating radiation was impinging upon electrons. At sea level, nearly all the
the earth from space, rather than emanating observed cosmic radiation consists of
from the earth, was deduced from balloon secondary cosmic rays, with some 68% of
experiments in which ionization the flux accounted for by moons‘ and 30%

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G. Hazra Radioactive Pollution: An Overview

by electrons. Less than 1% of the flux at sea still be present in measurable quantities. Of
level consists of protons. the primordial radionuclide that are still
Terrestrial Radiation detectable, three are of overwhelming
Radionuclide‘s, which appeared on the Earth significance. These are K-40, U-238 and Th-
at the time of formation of the Earth, are 232. Uranium and thorium each initiate a
termed "primordial". Of the many chain of radioactive progeny, which are
radionuclides that must have been formed nearly always found in the presence of the
with the Earth, only a few have half-lives parent nuclides (Table 2). Although many of
sufficiently long to explain their current the daughter radionuclide are short-lived,
existence. If the Earth was formed about they are distributed in the environment
6⋅109 years ago, a primordial radionuclide because they are continually being forming
would need a half-life of at least 108 years to from long-lived precursors.

Man-maide sources

Medical source Nuclear power


Radiations are employed for diagnostic and Nuclear explosion tests especially when
therapeutic applications. X-rays are used in carried out in the atmosphere are a major
general radiology and CT scan. Gamma rays cause of radiation pollution. It is responsible
are used in treatment of cancer. In all these for increasing the background level of
procedures we are exposed to varying doses radiation throughout the world. During
of radiations. atmospheric nuclear explosion tests, a
Industrial source number of long-lived radionuclides are
Radioisotopes are much more widely used in released into the atmosphere. This
industry than is generally recognized and radioactive dust (also known as radioactive
represent a significant component in the fallout) gets suspended in air at a height of 6
man-made radiation environment. The to 7 km above the earth‘s surface and is
principal applications include industrial dispersed over long distances by winds from
radiography, radiation gauging, smoke the test site. This radionuclide‘s often settle
detectors and self-luminous materials. down by rain and get mixed with soil and
Because most of these applications entail the water. From there they can easily enter the
utilization of encapsulated sources, radiation food chain and finally get deposited in the
exposures would be expected to occur human body where they cause serious health
mainly externally during shipment, transfer, hazards. Some of the radioactive isotopes
maintenance, and disposal. In the past given off during nuclear test affect the
decade, radiation exposures in research and human body.
industrial applications were roughly half Nuclear & Radiation Accidents
those due to medical occupational exposure; Radiations may leak from nuclear reactors
hence, their contribution to the direct and other nuclear facilities even when they
population dose is substantial. are operating normally. It is often feared that
Nuclear explorations even with the best design, proper handling
Nuclear explosions are a serious source of and techniques; some radioactivity is
radiations hazard. The effects of atomic routinely released into the air and water.
explosions in Nagasaki and Hiroshima are However, dangers of radiation leakage are
still not forgotten. from possibility of accidents that could result

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G. Hazra Radioactive Pollution: An Overview

in the release of radioactive material which cases radiation was released in the
raises the level of radioactive (ionizing) atmosphere. The leakage from the ‗Three
radiations. Such accidents took place at the Mile Island‘ nuclear reactor has been
‗Chernobyl nuclear power plant‘ in USSR in claimed to be very low with no immediate
1986 and at the ‗Three Mile Island Power injuries to workers or people. But the
Plant‘ in USA in 1979. The accidents of leakage at Chernobyl was very heavy
‗Three Mile Island‘ plant in Middletown causing death to many workers and radiation
(U.S.A.) in 1979 and at Chernobyl nuclear was spread over large areas spread all over
power plant (U.S.S.R.) in 1986 were the Europe. The earthquake and tsunami in
worst disasters in the history of nuclear Japan on 11 March 2011 led to releases of
power industry. In both incidents, a series of radioactive material into the environment
mishaps and errors resulted in the from the Tokyo Electric Power Company‘s
overheating of the nuclear core. In both Fukushima Daiichinuclear power station.

Table 1. FDA and FSIS derived intervention levels for imported food after the chernobyl
accident, bq/kg (pci/kg)
Tablica 1. FDA i FSIS izvedene intervencijske razine za uvezenu hranu nakon černobilske
nesreće, bq/kg (pci/kg)
FDA LOC FSIS Screening Value
Radionuclide Infant Food Other Food Meat & Poultry
I-131 55 300 55
(1500) (8000) (1500)
Cs-134 + Cs-l37 370 370 370
(10,000) (10,000) 10,000

RADIATION & MATTER

When radiation passes through matter, it and being charged, they again deposit energy
deposits energy in the material concerned. through electrical interactions. So in all
Alpha & beta particles, being electrically cases, the radiation ultimately produces
charged, deposit energy through electrical electrical interaction in the material. In some
interaction with electrons in the material. cases an electron in the material may receive
Gamma rays and X ray lose energy in a enough energy to escape from an atom
variety of ways, but each involves liberating leaving the atom or molecule thus formed
atomic (orbiting) electrons, which then positively charged. The figured illustrate this
deposit energy in interaction with other process for molecule o water. The molecule
electron. Neutron also loses energy in has ten electrons altogether, but only nine
various ways, the most important being atomic electrons remain after a charged
through collision with nuclei that contain particle passes by, the molecule as whole is
protons. The protons are then set in motion left with one excess positive charged [8].

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G. Hazra Radioactive Pollution: An Overview

RADIOACTIVE CONTAMINATION

Radioactive contamination and radiation Radioactive waste is any material that


exposure could occur if radioactive materials contains or contaminated with radioactive
are released into the environment as the nuclide at concentration greater than a safe
result of an accident, an event in nature, or level. In other word radioactive waste
an act of terrorism. Such a release could containing radioactive element that do not
expose people and contaminate their have practical purpose.
surroundings and personal property.

What radioactive contamination is?

Radioactive contamination occurs buildings, people, or animals to become


when radioactive material is deposited on or contaminated. A contaminated person has
in an object or a person. Radioactive radioactive materials on or inside their body
materials released into the environment can [9].
cause air, water, surfaces, soil, plants,

What External contamination is?

External contamination occurs when body. People who are externally


radioactive material, in the form of dust, contaminated can become internally
powder, or liquid, comes into contact with a contaminated if radioactive material gets
person's skin, hair, or clothing. In other into their bodies [9,10].
words, the contact is external to a person's

What Internal contamination is?

Internal contamination occurs when radioactive materials stay in the body and
people swallow or breathe in radioactive are deposited in different body organs. Other
materials, or when radioactive materials types are eliminated from the body in blood,
enter the body through an open wound or are sweat, urine, and faces [9-11].
absorbed through the skin. Some types of

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G. Hazra Radioactive Pollution: An Overview

Figure 3. Pictorial diagram of radioactive contamination


Slika 3. Slikovni dijagram radioaktivnog onečišćenja

How dangerous is radiation?

Although radiation appears very average. Choice overbuilding materials can


dangerous, we should remember that have a substantial effect on radiation ex-
individuals are struck by about a million posture. Living in a brick or stone house
particles of radiation every minute from typically results in 20 per-cent higher
natural sources. One third of this radiation exposure than living in a wood house, and
comes from outer space, another third comes some particular building materials, like the
from radio-active materials like uranium, granite used in New York‘s Grand Central
thorium, and potassium, which are found in Station and in the congressional office
the ground and in materials we derive from buildings, can more than double a resident‘s
the ground; the remainder comes from exposure. Finally, in some houses radon
radioactive materials in our bodies, levels are 10 or even 100 times higher than
especially potassium, a substantial quantity outdoor levels, because air leakage has been
of which is vital to life. In addition to these reduced. Besides natural radiation, to which
sources of radiation, which affect all our mankind has always been exposed, there is
organs, radon gas (a derivative of uranium) an important new source of radiation
exposes our bronchial regions to radiation introduced this century: medical X-rays. A
from the very air we breathe. Natural typical X-ray exposes us to 100billion
radiation is not insignificant. It is hundreds particles of radiation, or about one fourth as
of times larger than the well-publicized much radiation exposure as the average
radiation exposure from the nuclear industry. American receives annually from natural
In Colorado, where the high altitude reduces sources. This is hundreds of times more
the thickness of air that shields us from radiation than we can ever expect to receive
radiation coming from outer space and from the nuclear industry. There are many
where the amount of uranium and tonal techniques for reducing radiation exposure
average; in Florida, it is 20 percent below in X-rays without com-promising their

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G. Hazra Radioactive Pollution: An Overview

medical usefulness. Moreover, many X-rays billion). Hence, the million particles that
are not thorium in the ground is abnormally strike us each minute have only one chance
large, the average exposure from natural in 30 billion of causing a cancer. A human
sources is more than 50 percent larger than lifespan is about 30 million minutes; thus, all
the nawever, and natural radiation exposure of the natural radiation to which we are
varies considerably. Made for medical exposed has one chance in 1000
purposes, but to protect hospitals and (30million/30 billion) of causing a cancer.
physicians against libel suits, thus, a change Statistics show that our overall chance of
in the legal structure could helps avoid dying from cancer is one in five, so only one
unnecessary medical X-rays. If we are all in200 of all cancers may be due to natural
being struck by a million particles of radiation. The average exposure from a
radiation every minute, why don‘t we all nuclear power plant to those who live closest
develop cancer at an early age? The reason to it is about one percent of their exposure to
we don‘t is not because this level of natural radiation; hence, if they live there for
radiation is ‗safe.‘‘ Even single particle of a lifetime, there is one chance in 100,000
radiation can cause cancer, but the that they will die of cancer as a result of
probability for it to do so is very small, about exposure to radiation from the nuclear plant
one chance in 30 quadrillion (i.e., 30 million [12].

RADIATION EFFECTS

Radiation is the emission of particle or radiations usually work together with tissue
energy in wave form. This is stated as through the generation of heat. The hazard
electromagnetic radiation. Examples consist depends on the ability to go through the
of: visible light, radio waves, microwaves, human body and the absorption charac-
infrared and ultraviolet lights, X-rays, and teristics of different tissues [15]. If each and
gamma-rays [13]. Radiation can be every one of these types of radiation added
described as two basic types, ionizing and by human activities can cause radiation
non-ionizing radiation. The discussion will pollution. The meaning of radiation pollution
include a review of radiation of is that while there are omnipresent sources
radioactivity. There are three main kinds of of radiation, generally the high-energy
ionizing radiation which are included alpha radiations cause radiation pollution with a
particles, beta particles and gamma rays. serious health risk (such as cancer or death)
Beside these there forms of ionizing also we [16]. As has been mentioned air pollution
have neutrons, protons, heavy charged can caused by radioactivity which are in the
particles, X-ray and others. Radioactive air as gas or aerosols that emit such ionizing
substance can penetrate into the body by radiation as alpha and beta particles, gamma
inhalation, in-gestation or dermal absorption. rays, neutrons and other high energy quanta.
In addition, gamma radiation external to the From the beginning of the life story the man
body can enter the skin and produce a dose has been exposed to ionizing radiations from
various tissues [14]. Non ionizing radiation radioactive isotopes and other sources by
refers to radioactive energy which as development of atomic reactor. This kind of
opposed to produce charged ions when pollution has been raised considerably
passing through matters has enough energy [17,18]. Exposure radiation can cause tissue
only for excitation. However it is known to and organ injury unless suitable precautions
cause biological effects. Non ionizing are taken. The more important health effects

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G. Hazra Radioactive Pollution: An Overview

described as being caused by radioactive internal radiation. Controlling Radiation


isotopes are blood abnormalities, skin Pollution can be done at various levels, such
changes, bon changes and so forth. Physical as usage and treatment of radiation waste,
half-life of radioactive isotopes causes the the control and mitigation of nuclear
amount of injury in human body. The most accidents, as well as the control and
in danger part of body is where have many minimization of personal expo-sure to
actively dividing cells such as the skins, radiation at an individual level .Apart from
intestine, gonads and tissues that grow blood being an inevitable series of negative effects
cells [19]. The Radiation has most damaging of radiations, it is the duty of humans with
effect on single celled organisms because a regard to Radiation Standards Organizations
single cell damaged by radiation can in a to help in reducing the harmful effects of this
roundabout way affect other cells in the kind of pollution. Radiation effects are also
individual. Cells which exposed with low classified in two other ways, namely somatic
energy radioactivity can have biochemical and genetic effects. Somatic effects appear
repair system which can repeal some in the exposed person. The delayed somatic
damage. Actually it is good to mention that effects have a potential for the development
all humans during their life are exposed to of cancer and cataracts. Acute somatic
radiation in really small doses. Radioactive effects of radiation include skin burns,
pollution is a vital ecological crisis. It could vomiting, hair loss, temporary sterility or sub
be much worse if extreme caution is not fertility in men, and blood changes. Chronic
utilized in the handling and use of somatic effects include the development of
radioactive material, and in the design and eye cataracts and cancers. The second class
operation of nuclear power plants .There are of effects, namely genetic or heritable effects
three basic tools that can provide protection appears in the future generations of the
against a radiation source. These are time, exposed person as a result of radiation
distance and shielding. The goal of the damage to the reproductive cells, but risks
protection is to prevent over exposure from from genetic effects in humans are seen to be
external radiation and to minimize the en-try considerably smaller than the risks for
of radionuclides into the body or minimize somatic effects [20].

(a) Blistering of the right hand injury (b) Nuclear Test victim
Figure 4. Picture of radioactive hazarders‘ effects.
Slika 4. Slika radioaktivnih efekata

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G. Hazra Radioactive Pollution: An Overview

RADIOACTIVE WASTE

Radioactive waste, arising from the magnitude of the waste involved and
civilian nuclear activities as well as from various solutions proposed and being
defence-related nu-clear-weapon activities, practised. As nuclear power and arsenal
poses a formidable problem for handling and grow, continuous monitoring and
protecting the environment to be safe to t-he immobilization of the waste over several
present and future generations. This article decades and centuries and deposition in safe
deals with this global problem in its varied repositories, assumes great relevance and
aspects and discusses the cause for concern, importance [21].

Classification of Radioactive Waste

Nuclear waste can be generally ‗intermediate level‘ radioactive waste and


classified as ‗low-level‘ radioactive waste, ‗high-level‘ radioactive waste [22].

Low Level Radioactive Waste

Basically all radioactive waste that is level of radioactivity and half-lives of


not high-level radioactive waste or radioactive isotopes in low-level waste are
intermediate-level waste or transuranic waste relatively small. Storing the waste for a
is classified as low-level radioactive waste. period of 10 to 50 years will allow most of
Volume-wise it may be larger than that of the radioactive isotopes in low-level waste to
high-level radioactive waste or intermediate- decay, at which point the waste can be
level radioactive waste or transuranic waste, disposed of as normal refuse methods of
but the radioactivity contained in the low- landfills are adapted for radioactive waste
level radioactive waste is significantly less also. However, during incineration of
and made up of isotopes having much ordinary waste, fly ash, noxious gases and
shorter half-lives than most of the isotopes in chemical contaminants are released into the
high-level radioactive waste or intermediate- air. If radioactive waste is treated in this
level waste or transuranic waste. Large manner, the emissions would contain
amounts of waste contaminated with small radioactive particulate matter. Hence when
amounts of radionuclide‘s, such as adapted, one uses fine particulate filters and
contaminated equipment (glove boxes, air the gaseous effluents are diluted and
filters, shielding materials and laboratory released. Recycling to some extent is
equipment) protective clothing, cleaning feasible. We have already dealt with the
rags, etc. constitute low-level radioactive reprocessing approach, whereby useful
waste. Even components of decommissioned radioactive elements are recovered for cyclic
reactors may come un-der this category use. But it still leaves some waste that is a
(after part decontamination procedures. The part of the high-level radioactive waste [23].

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G. Hazra Radioactive Pollution: An Overview

High Level Radioactive Waste

High-level radioactive waste is levels of radioactivity, and this would take


conceptualized as the waste consisting of the about 1000 years. On the other hand,
spent fuel, the liquid effluents arising from transuranics take nearly 500,000 years to
the reprocessing of spent fuel and the solids reach such levels.
into which the liquid waste is converted. It Heat output lasts over 200 years.
consists, generally, material from the core of Most of the radioactive isotopes in high-
a nuclear reactor or a nuclear weapon. This level waste emit large amounts of radiation
waste includes uranium, plutonium and other and have extremely long half-lives (some
highly radioactive elements created during longer than 100,000 years), creating long
fission, made up of fission fragments and time-periods before the waste will settle to
transuranics. (Note that this definition does safe levels of radioactivity. As a thumb-rule
not specify the radioactivity that must be one may note that ‗volumes of low-level
present to categorize a high-level radioactive radioactive waste and intermediate-level
waste. These two components have different waste greatly exceed those of spent fuel or
times to decay. The radioactive fission high-level radioactive waste‘. In spite of this
fragments decay to different stable elements ground reality, the public concerns regarding
via different nuclear reaction chains disposal of high-level radioactive waste is
involving α, β and γ emissions to innocuous worldwide and quite controversial [24].

Radioactive Waste Management System

Radioactive waste should be radioactive waste should be managed within


managed in such a way as to secure an an appropriate national legal framework
acceptable level of protection for human including clear allocation of responsibilities
health, provide an acceptable level of and provision for independent regulatory
protection for the environment, assure that functions, the generation of radioactive
possible effects on human health and the waste shall be kept to the minimum
environment beyond national borders will be practicable, interdependencies among all
taken into account, ensure that the predicted steps in radioactive waste generation and
impacts on the health of future generations management should be taken into account
will not be greater than relevant levels of and the safety of facilities for radioactive
impact that are acceptable today, and that the waste management shall be appropriately
management practice will not impose undue assured during their lifetime [25].
burdens on future generations. Also,

Radioactive waste Management System


in India

Just as per capita consumption of is generated by a country and hence the


electricity is related to the standard of living related magnitude of radioactive waste
in a country, the electricity generation by management. On the scale of nuclear share
nuclear means can be regarded as a of electricity generation, India ranks fourth
minimum measure of radioactive waste that from the bot-tom in about 30 countries. As

The Holistic Approach to Environment 8(2018)2, 48-65 Page 60


G. Hazra Radioactive Pollution: An Overview

of the year 2000, India‘s share of nuclear stockpile in the nuclear weapons countries.
electricity generation in the total electricity As more power reactors come on-stream and
generation in the country was 2.65% as weaponization takes deeper routes the
compared to 75%, 47%, 42.24%, 34.65%, needs of radioactive waste management
31.21%, 28.87%, 19.80%, 14.41% and increase and in this context the experience of
12.44% of France, Sweden, the Republic of other countries would provide useful lessons.
Korea, Japan, Germany, UK, USA, Russia Radioactive waste management has been an
and Canada, respectively. The reactors in integral part of the entire nuclear fuel cycle
operation produce in net Gig watts (one in India. Low-level radioactive waste and
billion (109 Watts) (E) in the latter countries intermediate-level waste arise from
nearly 63, 9, 13, 44, 21, 13, 97, 20 and 10, operations of reactors and fuel reprocessing
respectively; India‘s reactors in operation facilities. The low-level radioactive waste
yield 1.9 on this scale (both data are as per liquid is retained as sludge after chemical
IAEA Report of 2000). Hence the magnitude treatment, resulting in decontamination
of radioactive waste management in India factors ranging from 10 to 1000. Solid
could be miniscule compared to that in other radioactive waste is compacted, bailed or
countries, especially when one takes into incinerated depending upon the nature of the
account the nuclear arsenal already in waste [26].

Safety of Radioactive Waste Management

IAEA recommended that assessment nuclear waste, were melted in the


studies have to be developed and well temperature range 750-950 degree. IAEA
adapted to situations of concern to ensure the published procedure for conducting
protection of human health and the probabilistic safety assessment for non-
environment. To apply this recommendation, reactor nuclear facilities. This procedure is
an initial assessment of the planned waste consist of six interlinked steps, which
14management practice needs to be include
performed that identifies the radiological  Management and organization,
sources, foresees potential exposures,  Identification of source of radioactive
estimates relevant doses and probabilities, releases, exposure and accident
and identifies the required radiological initiator
protection measures. Various methodologies  Scenario modelling,
with varying complexity have been and are  Sequence quantification,
being developed to assist in the evaluation of  Documentation of the analysis and
radiological impact of nuclear and interpretation of the results
radioactive facilities. Glasses in lead-iron  Quality assurance
phosphate system loaded with simulated

The Holistic Approach to Environment 8(2018)2, 48-65 Page 61


G. Hazra Radioactive Pollution: An Overview

Figure 5. Protection against radioactive radiation.


Slika 5. Zaštita od radioaktivnog zračenja

RADIOACTIVE DISPOSAL

Nuclear waste has sometimes been from the environment is therefore a highly
called the Achilles‘ heel of the nuclear demanding task—for comparison, human
power industry. Much of the controversy civilization has existed for only some 10,000
over nuclear power centres on the lack of a years. Several potential ways of handling
disposal system for the highly radioactive spent fuel in the long term have been
spent fuel that must be regularly removed proposed—none of which are ideal. These
from operating reactors. Low-level include burying the waste below the seabed,
radioactive waste generated by nuclear launching it into outer space, and storing it
power plants, industry, hospitals, and other on remote islands. However, the
activities is also a long-standing issue international scientific consensus is that
because the spent fuel removed from a spent fuel and other high-level waste should
nuclear reactor is highly radioactive, it must be stored underground in a ―geologic‖
be disposed of in a way that protects the repository, where the geological properties
environment from contamination and living of the surrounding area would provide the
organisms from exposure. Radioactive long-term stability needed to isolate the
isotopes can be spread by air or water, and waste from the environment. The waste
can also become part of the food chain. would sit inside tunnels drilled deep into the
While the radioactivity of spent fuel drops earth. UCS concurs with this consensus, and
with time, according to a 1995 National believes that such a repository—if properly
Academy of Sciences study, the ―peak risks sited and constructed—can protect the public
[from a repository] might occur tens to and the environment for tens of thousands of
hundreds of thou-sands of years or even years [28]. The Nuclear Waste Policy Act of
farther into thefuture.‖96 Isolating spent fuel 1982 (NWPA, P.L. 97-425), as amended in

The Holistic Approach to Environment 8(2018)2, 48-65 Page 62


G. Hazra Radioactive Pollution: An Overview

1987, required the Department of Energy the repository and called for a complete halt
(DOE) to focus on Yucca Mountain, in funding and elimination of the Office of
Nevada, as the site of a deep underground Civilian Radioactive Waste Management
repository for spent nuclear fuel and other (OCRWM), which had run the program. In
highly radioactive waste. The state of line with the request, the FY2011
Nevada has strongly opposed DOE‘s efforts Continuing Appropriations Act (P.L. 112-
on the grounds that the site is unsafe, 10) provided no DOE funding for the
pointing to potential volcanic activity, program. DOE shut down the Yucca
earthquakes, water infiltration, underground Mountain project at the end of FY2010 and
flooding, nuclear chain reactions, and fossil transferred OCRWM‘s remaining functions
fuel and mineral deposits that might to the Office of Nuclear Energy. DOE filed a
encourage future human intrusion. Under the motion to withdraw the Yucca Mountain
George W. Bush Administration, DOE license application on March 3, 2010, ―with
determined that Yucca Mountain was prejudice,‖ meaning the application could
suitable for a repository and that licensing of not be resubmitted to NRC in the future [30].
the site by the Nuclear Regulatory DOE‘s motion to withdraw the license
Commission (NRC) should proceed, as application, filed with NRC‘s Atomic Safety
specified by NWPA [29]. DOE submitted a and Licensing Board (ASLB), received
license application for the repository to NRC strong support from the state of Nevada but
on June 3, 2008, and projected that the drew opposition from states with defence-
repository could begin receiving waste in related and civilian radioactive waste that
2020, about 22 years later than the 1998 goal had been expected to go to Yucca Mountain.
established by NWPA. However, the Obama State utility regulators also filed a motion to
Administration had made a policy decision intervene on March 15, 2010, contending
that the Yucca Mountain repository should that ―dismissal of the Yucca Mountain
not be opened, largely because of Nevada‘s application will significantly undermine the
continuing opposition, although it requested government‘s ability to fulfil its outstanding
FY2010 funding to continue the NRC obligation to take possession and dispose of
licensing process. But the Administration‘s the nation‘s spent nuclear fuel and high level
FY2011 budget request reversed the nuclear waste [31, 32].
previous year‘s plan to continue licensing

Figure 6. Methods of Radioactive Disposal system


Slika 6. Načini zbrinjavanja radioaktvnog otpada

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G. Hazra Radioactive Pollution: An Overview

CONCLUSION

The rapidly expanding applications that the only significant exposures result
of radioactive materials and of nuclear from the occupancy and use of the
energy must inevitably lead to a vast contaminated floodplains, particularly if hot
increase in radioactive pollution of the particles are present. Doses of several
atmosphere unless effective preventive millisieverts a year could result from some
measures are taken without delay. Such of the most contaminated sites. The levels
measures, which are essential for of floodplain contamination are very
safeguarding the health of both radiation variable; samples taken at the same
workers and the population at large, must approximate location can be very
be conceived as part of programme for the substantially different. There is also no
control of air pollution in general. The simple correlation with contamination
results of the radiological assessments show levels and distance from the discharge.

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