TECHNOLOGICAL INSTITUTE OF THE PHILIPPINES

CHEMICAL ENGINEERING DEPARTMENT

MOCK BOARD EXAM
DAY 1 – PHYSICAL AND CHEMICAL PRINCIPLES

INSTRUCTIONS: Select the correct answer for each of the following questions. Mark only one answer for
each item by marking the circle corresponding to the letter of your choice on the sheet provided. STRICTLY
NO ERASURES. Use pencil no.2 only.

1. Air entering the lungs ends up in tiny sacs called alveoli. It is from the alveoli that oxygen diffuses into
the blood. The average radius of alveoli is 0.0050 cm and the air inside contains 14% oxygen.
Assuming the pressure in the alveoli is 1.0 atm and the temperature is 37 °C, calculate the number of
oxygen molecules in one of the alveoli.
A. 1.3 x 1012 molecules B. 1.5 x 1012 molecules
C. 1.7 x 1012 molecules D. 1.9 x 1012 molecules

2. It is the tendency of any biological processes to remain stability while adapting to survival conditions.
A. Adaptation B. Equilibrium
C. Homeostasis D. Internal equilibrium

3. Which of the following compounds undergo sublimation?

A. Acetylene B. Butyne
C. Pentyne D. Propyne

4. Glycolysis produces how many ATP molecules?

A. 2 B. 4
C. 6 D. 8

5. How many amino acids are considered essential?

A. 7 B. 9
C. 11 D. 13

6. A sample of wastewater has an ultimate BOD of 290 ppm and a 5-day BOD of 235 ppm. Calculate the
15-day BOD of the sample.
A. 258 ppm B. 268 ppm
C. 278 ppm D. 288 ppm

7. A 0.50 molal aqueous solution of sodium sulfate has a vapor pressure of 747.7 torr at 100 °C. Estimate
the degree of dissociation of the salt at this temperature.
A. 28% B. 38%
C. 48% D. 58%

8. A solution of gold nitrate is electrolyzed with a 0.5 A current. If 3.57 g gold is deposited on the cathode,
what is the duration of the electrolysis in minutes?
A. 145 B. 155

Page 1 of 12
 C. 165 D. 175

9. A 20 molal solution of sodium sulfate in ethyl alcohol has a density of 1.14 g/mL. What is the molarity
of the solution?
A. 4.9 M B. 5.9 M
C. 6.9 M D. 7.9 M

10. Bone dry air is allowed to flow into a 750 mL water-filled saturator in order to increase its moisture
content. If the saturator is operating at equilibrium conditions of 50 °C and 1 atm, determine the mole
ratio of water to dry air in the exit air stream.
A. 0.14 B. 0.19
C. 0.24 D. 0.29

11. When 3.0 g of methane is burned in a bomb calorimeter containing 3 kg of water, it causes the
temperature of the water to rise by 13.3 °C. What is the molar heat of combustion of methane?
A. 841 kJ B. 891 kJ
C. 941 kJ D. 991 kJ

12. The average wastewater flow of a municipal wastewater plant is 3.2 million gallons per day. If the total
volume of the two primary clarifiers, which are operated in parallel, is 2080 cubic meters, and the total
surface area for both clarifiers if 600 square meters, determine the hydraulic retention time.
A. 4.1 hours B. 4.6 hours
C. 5.1 hours D. 5.6 hours

13. When cells of the skeletal vacuole of a frog were placed in a series of aqueous NaCl solutions of
different concentrations at 25 °C, it was observed using a microscope that they remained unchanged
in 0.70% by weight NaCl solution, shrank in more concentrated solutions, and swelled in more dilute
solutions. The 0.70% salt solution freezes as -0.406 °C. What is the osmotic pressure of the
protoplasm at 25 °C? Each Na+ ions is hydrated by 4 water molecules, while each Cl- ion is hydrated
with 2 water molecules. At 25 °C the density of pure water and 0.70% NaCl solution are 997.07 and
1002.0 kg/m3, respectively.
A. 4.25 bar B. 5.39 bar
C. 6.12 bar D. 7.43 bar

14. This acid is the most acidic of all organic acids, it is present in the stings of nettles, bees, and ants.
A. Acetic acid B. Formic acid
C. Glycogenic acid D. Sulfamic acid

15. One way to gain a physical understanding of b in Van der Waals equation is to calculate the “excluded
volume”. Assume that the distance of closest approach between two similar atoms is the sum of their
radii (2r). Calculate the volume around each atom into which the center of another atom cannot
penetrate.
A. 16πr3/3 B. 4πr3
C. 32πr3/3 D. 8πr3

Page 2 of 12
16. Which of the following is NOT classified as Bronsted-Lowry base?
A. Ammonia B. Ammonium ion
C. Nitrate ion D. Perchlorate ion

17. Liquid benzene has a vapor pressure of 6.17 kPa and 15.8 kPa at 10 and 30 °C, respectively. Similarly,
the solid has a vapor pressure of 0.299 and 3.27 kPa at -30 and 0 °C, respectively. Calculate its triple
point.
A. 4.21 °C, 3.67 kPa B. 4.78 °C, 4.13 kPa
C. 5.78 °C, 5.03 kPa D. 6.87 °C, 5.26 kPa

18. Which of these inhibitors does not affect Km, but do reduce Vmax?
A. Competitive inhibitors B. Pacific inhibitors
C. Non-competitive inhibitors D. Uncompetitive inhibitors

19. Two 1000 g copper blocks, one initially at a temperature of 200.0 °C and the other initially at a
temperature of 0.0 °C, are put into a well-insulated box and allowed to come to thermal equilibrium at
one bar pressure. What is the change in the entropy of the universe as a result of this process? The
molar heat capacity of copper is Cp=24.44 /mol-K.
A. 28.66 J/K B. 29.77 J/K
C. 30.88 J/K D. 31.99 J/K

20. Gold crystallizes in an FCC structure and has a density of 19.3 g/cm3. Calculate the atomic radius of
gold in picometers.
A. 122 B. 133
C. 144 D. 155

21. What food component contributes 9 calories per gram?

A. Carbohydrates B. Fiber
C. Lipids D. Protein

22. Ammonia was formed at 450 °C by passing a mixture of nitrogen and hydrogen gas at a 1:3 mole ratio
over a catalyst. When the total pressure was held constant at 10.13 bar it was found that the product
gas contained 2.04% by volume ammonia. Calculate the value of equilibrium constant K at 450 °C for
the reaction: ½ N2 + 3/2 H2 → NH3
A. 6.46 x 10-3 B. 7.46 x 10-3
C. 8.46 x 10-3 D. 9.46 x 10-3

23. The solubility product of PbBr2 is 8.9 x 10-6. Determine the molar solubility in 0.20 M KBr solution.
A. 1.2 x 10-4 M B. 1.7 x 10-4 M
C. 2.2 x 10-4 M D. 2.7 x 10-4 M

24. At 300 K and 1 atm, carbon dioxide is 40% dissociated to CO and O2 according to the equation: 2 CO2
→ 2 CO + O2. Its percent dissociation when pressure is increased to 2 atm is
A. 0.395 B. 0.375
C. 0.355 D. 0.335

Page 3 of 12
25. The crystalline material in a bottle having no label is known to be either NaCl, CaCl2, or AlCl3. When
a small amount of this substance is dissolved in 150 g of benzene, the freezing point is lowered by
0.60°C. When the same amount is dissolved in 100 g water, the freezing point is lowered by 0.998°C.
What is this substance?
A. CaCl2 B. AlCl3
C. NaCl D. none of the above

26. A certain first order reaction has an activation energy of 104.6 kJ/mol and a pre-exponential factor of
5 x 1013/s. At what temperature will the half-life be 30 days?
A. -2.03°C B. 2.03°C
C. -3.62°C D. 3.62°C

27. Which of the following enzymes is not involved in the DNA replication?
A. DNA Ligase B. DNA Polymerase
C. Phosphatase D. Helicase

28. Which of the following techniques is NOT used in the process of manufacturing citric acid?
A. Crystallization B. Ion-exchange
C. Distillation D. Ultrafitration

29. What less expensive catalyst is used during the hydrogenation of alkynes?
A. Palladium B. Platinum
C. Rhodium D. Nickel

30. Diethyl ether is a volatile, highly flammable organic liquid that is used mainly as a solvent. The vapor
pressure of diethyl ether is 401 mmHg at 18°C. Calculate its vapor pressure at 32°C.
A. 927 mmHg B. 845 mmHg
C. 712 mmHg D. 656 mmHg

31. A sample of iron weighing 15.0 g was heated with KClO3 in an evacuated container. The oxygen
generated from the decomposition of KClO3 converted some of the Fe to Fe2O3. If the combined
mass of Fe and Fe2O3 was 17.9 g, calculate the mass of Fe2O3 formed and the mass of KClO3
decomposed.
A. 9.6 g Fe2O3, 7.4 g KClO3 B. 10.6 g Fe2O3, 8.4 g KClO3
C. 11.6 g Fe2O3, 9.4 g KClO3 D. 12.6 g Fe2O3, 10.4 g KClO3

32. The rms of a certain gaseous oxide is 493 m/s at 20°C. What is the molecular formula of the
compound?
A. NO B. NO2
C. N3O D. N2O5

33. One mole of gaseous A is injected at 25 into a rigid reactor having a total constant volume of 1.00 L,
and initially containing 2.00 moles of liquid B. The reactor is sealed and the following chemical reaction
proceeds to completion, with the evolution of 285.0 kJ of heat: A (g) + 2B(l) → 3C(s) + 2D(g). At the

Page 4 of 12
 completion of the reaction, the temperature of the reactor is 500 K. The molar volume of the liquid B
and 25°C and solid C at 500 K are 24.0 mL and 14.2 mL, respectively. What is ΔH for this process?
A. -253.6 kJ B. -265.8 kJ
C. -278.9 kJ D. -288.7 kJ

34. Which of the following represents the three names of artificial sugars that are much sweeter, but not
absorbed by our body system?
A. Aspartame, sucralose, and saccharin B. Beet sugar, cane sugar, date sugar
C. Mannose, galactose, and dextrose D. Sorbitol, mannitol, and ethyl maltol

35. Which of the following is the most abundant isotope of hydrogen?

A. Deuterium B. Protium
C. Elerium D. Tritium

36. Vitamin A can be found in the form of:

A. Thiamine B. Riboflavin
C. Retinol D. Pyridoxine

37. The boiling point of acetone is:

A. 88°C B. 74°C
C. 60°C D. 56°C

38. How many grams of ozone were degraded if a certain CFC pollutant was able to capture 2.37 moles
of atomic oxygen?
A. 113.76 g B. 56.88 g
C. 45.50 g D. 37.92 g

39. Which of the following is not a major contributor to the greenhouse effect?
A. CO2 B. NO
C. CO D. CH4

40. Which of the following has the highest pH?

A. 0.1 M NH4OH B. 0.1 M NaOH
C. 0.1 M NaCH3COO D. 0.1 M C2H5OH

41. Which of the following alcohols is the least soluble in water?

A. decanol B. hexanol
C. propanol D. methanol

42. Which of the following is not soluble in water?

A. Sodium sulfate B. Barium sulfate
C. Calcium sulfate D. Zinc sulfate

43. This refers to the hydrolysis of triglycerides using a strong base to form salt and carboxylates.
A. Glycerolysis B. Saponification

Page 5 of 12
 C. Solvation D. Hydroxylation

44. A carbon that has a high percentage of C-12 among its other isotope, C-13
A. Light carbon B. Radioactive carbon
C. Biogenic carbon D. Normal carbon

45. The variety of coal in which the deposit contains recognizable traces of plant material is
A. Anthracite B. Bituminous
C. Lignite D. Peat

46. Suppose that the enzyme mixture contains an enzyme with a Km of 5.0 x 10 5 M. If the substrate
concentration in this mixture is 4.5 x 106 M, what is the fractional saturation of this enzyme mixture?
A. 20% B. 30%
C. 40% D. 50%

47. Which of the following is a set of fat-soluble vitamins?

A. Vitamin B1, B6, B12 B. Vitamin A, D, E, K
C. Thiamin, Riboflavin, Niacin D. Vitamin C, Folate, Biotin

48. Which of the following is NOT a necessary component of a Maillard browning reaction?
A. Water B. Protein
C. Sugar D. Sulfur-containing compound

49. This is a common procedure used to separate organic compounds and to monitor a reaction’s
progress. It is also used to determine solvent systems for purification of a column. An organic chemist
armed with a pencil, a chamber containing organic solvent, and a special plate can perform this easily.
A. Gas chromatography B. Flash column chromatography
C. Nuclear magnetic resonance D. Thin layer chromatography

50. A soap that does not lather easily contains:

A. Unsaponified triglyceride B. Insufficient amount of filler
C. Unreacted base D. Poor production

51. A soap that irritates skin easily contains:

A. Unsaponified triglyceride B. Insufficient amount of filler
C. Unreacted base D. Poor production

52. Assuming constant heat capacities, calculate the molar heat of vaporization of liquid water to steam
at 100°C. Heat of formation of liquid water is -285.830 kJ/mol, while heat of formation of steam is -
241.818 kJ/mol.
A. -44 kJ/mol B. -43 kJ/mol
C. -42 kJ/mol D. -41 kJ/mol

Page 6 of 12
For Numbers 53-55:

One mole of water vapor is heated at constant volume from 25 to 200°C. The molar heat capacity at constant
pressure for water vapor varies with temperature according to:

Cp = 30.54 + 0.0103 T
Where Cp is in J/mol-K and T in Kelvin. Assume ideal gas behavior. Calculate the following:

53. Work, W
A. -4.6 kJ B. 0 kJ
C. 4.6 kJ D. None of the given

54. Heat, Q
A. -4.6 kJ B. 0 kJ
C. 4.6 kJ D. None of the given

55. Internal Energy, ΔU

A. -4.6 kJ B. 0 kJ
C. 4.6 kJ D. None of the given

For Numbers 56-58:

100.0 g of liquid water is heated from 4°C to 85°C at a constant pressure of one bar. For this process,
calculate the following. Cp for water is 4.18 J/g-K and densities of water at 4°C and 85°C are 1.00 g/cm3 and
0.96865 g/cm3.

56. Heat, Q
A. 34000 J B. 0.32 J
C. -34000 J D. None of the given

57. Work, W
A. 34000 J B. 0.32 J
C. -34000 J D. None of the given

58. Internal Energy, ΔU

A. 34000 J B. 0.32 J
C. -34000 J D. None of the given

59. What is [HCOO-1] in a solution that is both 0.015 M HCOOH and 0.020 M HCl?
A. 1.99 x 10-5 B. 1.40 x 10-4
C. 1.52 x 10 -3 D. 0.012

Page 7 of 12
60. Consider a solution of monoprotic weak acid of acidity constant Ka. Calculate the minimum
concentration C, for which the percent ionization is less than 10%
A. C=60Ka B. C=80Ka
C. C=70Ka D. C=90Ka

61. What mass of Na2S2O3 5H2O is needed to make up 500 cm3 of 0.200 N solution?
A. 23.1 g B. 24.8 g
C. 25.8 g D. 26.3 g

62. A 4.51 g sample of an unknown compound was dissolved in 98.0 g of solvent. By close observation
of its freezing point, the solution was found to be 0.388m. Calculate the molar mass of the unknown
compound.
A. 98 g/mol B. 103 g/mol
C. 114 g/mol D. 119 g/mol

63. How many cubic centimeters of solution of concentration 100 mg Co2+ per cubic centimeter are needed
to prepare 1.5 L of solution of concentration 20 mg Co2+ per cubic centimeter?
A. 100 cm3 B. 300 cm3
C. 200 cm3 D. 400 cm3

64. Each Rubidium halide crystallizing in the NaCl-type lattice has a unit cell length of 30pm greater than
that for the corresponding potassium salt of the same halogen. What is the ionic radius of Rb +
computed from these data?
A. 118 pm B. 128 pm
C. 138 pm D. 148 pm

65. At a certain altitude in the upper atmosphere, the temperature is estimated to be -100OC and the
density just 10-9 that of the earth’s atmosphere at STP. Assuming uniform atmospheric composition,
what is the pressure in torr, at this altitude?
A. 2.30 x 10-7 torr B. 3.77 x 10-7 torr
C. 4.82 x 10-7 torr D. 5.63 x 10-7 torr

66. The vapor pressure of water at 80OC is 355 torr. A 100-mL vessel contained water-saturated oxygen
at 80OC, the total gas pressure being 760 torr. The contents of the vessel were pumped into a 50-mL
vessel at the same temperature. What were the partial pressure of oxygen, and of water vapor and
what was the total pressure in the final equilibrated state? Neglect the volume of any water which
might condense.
A. 810 torr; 355 torr; 1165 torr B. 820 torr; 521 torr; 1341 torr
C. 761 torr; 662 torr; 1423 torr D. 720 torr; 1029 torr; 1749 torr

67. At 0OC the density of nitrogen at 1atm is 1.25 kg/m3. The nitrogen which occupied 1,500 cm3 at STP
was compressed at 0OC to 575 atm and the gas volume was observed to be 3.92 cm3, in violation of
Boyle’s law. What is the final density?
A. 250 kg/m3 B. 331 kg/m3
C. 478 kg/m 3 D. 601 kg/m3

Page 8 of 12
68. A solution containing 2.00g of Hg(NO3)2 was added to a solution containing 2.00g of Na2S. Calculate
the mass of HgS that was formed.
A. 1.22 g B. 1.34 g
C. 1.43 g D. 1.56 g

69. How much water vapor is contained in a cubic room 4.0 m along an edge if the relative humidity is
50% and the temperature is 27OC.
A. 0.45 g B. 0.68 g
C. 0.82 g D. 0.92 g

70. A batch of wet clothes in a dryer contains 0.983 kg of water. Assuming air leaves the dryer saturated
with water vapor at 48OC and 738 of total pressure. Calculate the volume of dry air at 24OC and 738
torr required to dry the clothes
A. 1.88 x 103 L B. 1.07 x 104 L
C. 1.03 x 105 L D. 1.21 x 106 L

71. A large cylinder of helium filled at 2000 psi has a small thin orifice through which helium escaped into
an evacuated space at the rate of 3.4 millimoles per hour. How long would it take for 10 millimoles of
CO to leak through a similar orifice if the CO were confined in the same pressure?
A. 5.3 h B. 6.1 h
C. 7.8 h D. 8.2 h

72. A mixture of 5.00g of water, 5.00g of methanol and 5.00g of ethanol was put into a large sealed vessel
and heated until all traces of liquid has evaporated. If the total pressure was 2.57atm what was the
partial pressure of ethanol
A. 0.320 atm B. 0.439 atm
C. 0.514 atm D. 0.663 atm

73. What is the ratio of urms and ump

A. 1.22 B. 1.30
C. 1.51 D. 1.63

74. At what temperature would the most probable speed of CO molecules be twice that at 0 OC
A. 432 OC B. 678 OC
C. 819 OC D. 1035 OC

75. What is ratio of the average molecular kinetic energy of UF6 to that of He both at 300K?
A. 1 B. 1.5
C. 2 D. 2.5

76. The combustion of 5.00g of coke raised the temperature of 1.00kg of water from 10 OC to 47OC.
Calculate the heating value of coke.
A. 16 kJ/kg B. 31 kJ/kg
C. 46 kJ/kh D. 61 kJ/kg

Page 9 of 12
77. A 45.0-g sample of an alloy was heated to 90.0OC and then dropped into a beaker containing 82.0g
of water at 23.50OC. The temperature of the water rose to a final 26.25 OC. What is the specific heat
capacity of the alloy?
A. 0.043 cal/g K B. 0.055 cal/g K
C. 0.065 cal/g K D. 0.079 cal/g K

78. What is the heat of sublimation of solid iodine at 25OC?

A. 7.83 kcal/mol B. 10.32 kcal/mol
C. 12.01 kcal/mol D. 14.92 kcal/mol

79. The standard enthalpy of formation of H(g) has been determined to be 218 kJ/mol. Calculate ΔH O in
kJ for the following reaction:
H(g) + Br(g) → HBr(g)
H(g) + Br2 (l) → HBr(g) + Br(g)
A. -190 kJ; -155 kJ B. -255 kJ; 109 kJ
C. -366 kJ; -142.6 kJ D. -402 kJ; 201 kJ

80. Determine ΔHO of decomposition of 1 mol of solid KClO3 into solid KCl and gaseous oxygen.
A. -20.5 kJ B. -33.5 kJ
C. -45.4 kJ D. -50.1 kJ

81. How may grams of 5.0wt% NaCl solution necessary to yield 3.2g of NaCl?
A. 64 g B. 76 g
C. 80 g D. 93 g

82. Calculate the volume of concentrated sulfuric acid (SG 1.84) containing 98% H 2SO4 by weight that
would contain 40.0g pure H2SO4
A. 10.51 cc B. 17.36 cc
C. 22.2 cc D. 25.67 cc

83. To determine the sulfate content of drinking water a 6L sample was first concentrated to small volume.
Treatment of this with barium chloride solution resulted in the precipitation of 0.0965 g of BaSO 4.
A. 3.45 ppm B. 4.33 ppm
C. 5.31 ppm D. 6.62 ppm

84. What is the molar concentration of a solution containing 37.5g Ba(MnO4)2 per liter.
A. 0.100 M B. 0.150 M
C. 0.200 M D. 0.250 M

85. How many g of CaCl2 should be added to 300 mL of water to make up 2.46m solution
A. 67 g B. 78 g
C. 82 g D. 99 g

Page 10 of 12
 86. Calculate the percent ionization of 1.00M solution of hydrocyanic acid.
A. 13% B. 22%
C. 35% D. 40%

87. A 0.100M solution of an acid (SG 1.01) is 4.5% ionized. Compute the freezing point of the solution.
The molar mass of the acid is 300.
A. – 0.113 OC B. – 0.155 OC
C. – 0.198 OC D. – 0.210 OC

88. A solution was made up to be 0.0100 M in chloroacetic acid, HC2H2O2Cl and also in 0.0020 M in
sodium chloroacetate, NaC2H2O2Cl, Ka is 1.40 x 10-3. What is the [H+] in the solution.
A. 2.4 x 10-3 B. 7.0 x 10-3
C. 1.2 x 10 -2 D. 1.6 x 10-2

89. Calculate the pH of a 4.9 x10 -4 N acid assuming complete ionization.

A. 2.01 B. 2.50
C. 3.31 D. 3.78

90. What is the [NH4+] in a solution that is 0.0200 M NH3 and 0.0100 M KOH?
A. 3.50 x 10-5 B. 3.78 x 10-5
C. 4.05 x 10-5 D. 4.33 x 19-5

91. Two 1000 g copper blocks, one initially at a temperature 200.0 OC and the other initially at a
temperature of 0.0 OC, are put into a well – insulated box and allowed to come to thermal equilibrium
at one bar pressure. What is the change in entropy of the universe as a result of this process?
A. 28.66 J/K B. - 28.66 J/K
C. 115.39 J/K D. - 115.39 J/K

92. A 300 mL cup of hot coffee initially at 60.0 OC is placed on the table and allowed to cool to room
temperature (25.0 OC). Estimate the change in entropy of the universe as a result of this process. It
may be assumed that the specific heat capacity and the density of coffee is the same with that of
water. You may neglect the heat capacity of the cup itself.
A. -139.19 J/K B. 139.19 J/K
C. 147.21 J/K D. 8.02 J/K

For Numbers 93-94:

For a one – step isothermal expansion of one mole of an ideal gas at 0 OC from 1.00 atm to 0.500 atm in
which all other irreversibilities may be taken to be negligible.

93. Calculate the entropy change in the system.

A. 5.762 J/K B. 1.135 kJ/K
C. - 5.762 J/K D. - 1.135 kJ/K

94. Calculate the minimum entropy change in the universe.

Page 11 of 12
 A. -5.762 J/K B. 1.135 kJ/K
C. 1.607 J/K D. 4.155 kJ/K

For Numbers 95-96:

Calculate the change in Gibbs free energy when one mole of supercooled water at – 3OC and one atm
pressure freezes to ice at the same temperature and pressure. The heat of fusion of ice at 0 OC and one atm
pressure is 6.01 kJ/mol. The molar heat capacity of liquid water and ice near the normal freezing point are
75.3 and 38.0 J/ mol – K, respectively.

95. Calculate the change in enthalpy of the process.

A. 5972.7 J/mol B. -5898 J/mol
C. 6121.9 J/mol D. 6047.3 J/mol

96. Calculate the change in entropy of the process.

A. 59.33 J/mol - K B. -15.3 J/mol - K
C. 21.59 J/mol - K D. 15.3 J/mol - K

97. Calculate the change in Gibbs free energy of the process.

A. -1839 J/mol B. 119.55 J/mol
C. 10.105 kJ/mol D. -65.29 J/mol

98. Nitrogen gas is compressed isothermally at 100 OC from initial pressure of one bar to a final pressure
of ten bar. An external pressure of 25 bar is used to carry out the compression. Calculate the change
in Gibbs free energy for one mole of nitrogen gas undergoing this process.
A. -7.14 kJ/mol B. 7.14 kJ/mol
C. 2.842 kJ/mol D. - 2.842 kJ/mol

99. Calculate the change in entropy when one mole of steam at 100 OC and one bar pressure is cooled to
produce ice at 0OC and one bar pressure. Heat of fusion and heat of vaporization at 0OC are 333.5 J/g
and 2258.1 J/g, respectively.
A. - 154.6 J/mol - K B. - 110.61 J/mol - K
C. -107.41 J/mol - K D. - 63.43 J/mol - K

100. The normal boiling point of carbon tetrachloride is 76.75 OC. Estimate the enthalpy change when
one mole of CCl4 vaporizes at its normal boiling point.
A. 30.8 kJ/mol B. 11.6 kJ/mol
C. 42.3 kJ/mol D. 27.5 kJ/mol

Page 12 of 12