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Original article

Textile Research Journal


82(3) 211–219

Statistical modeling of water vapor ! The Author(s) 2012


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transport through woven fabrics DOI: 10.1177/0040517511433145
trj.sagepub.com

Seungsin Lee1 and S Kay Obendorf2

Abstract
Water vapor transport through textile structures is complicated and governed by various factors, including fabric
openness, fabric thickness, pore size, and intrinsic fiber properties. The objective of this study is to understand param-
eters that are critical in the moisture vapor transport through woven textiles and develop a predictive model that
describes water vapor transport of woven fabrics using those parameters. Fifteen woven fabrics with various fabric
thickness, weight, fabric construction, and staple fiber type were selected, and the water vapor transmission rate, fabric
thickness, fabric count, weight, yarn number, yarn twist, yarn diameter, and pore size distribution were measured. Based
on the mechanisms of water vapor transmission through porous textile materials, the fabric cover factor, solid volume
fraction, yarn twist factor, and yarn packing factor were computed and used as possible predictor variables in the
modeling. Moisture regains of fiber were obtained from literature and used as a possible predictor variable. Statistical
analyses were performed to examine the relationship between these parameters and water vapor transmission.
Statistical analyses revealed that fabric thickness, fabric cover factor, mean flow pore diameter of fabric, and moisture
regain of fiber were significant parameters affecting water vapor transmission through woven fabrics. The adjusted R2
value for the final model selected was 0.97. Influence of yarn twist factor and yarn packing factor were shown to be
insignificant at the 5% significance level for these experimental conditions.

Keywords
Water vapor transmission, woven fabric, fabric thickness, cover factor, pore diameter, moisture regain

Water vapor transport plays a significant role in deter- interyarn; thus, the rate of diffusion is governed by
mining the thermal comfort of a fabric since it repre- the yarn/fabric structure, including the size and concen-
sents the ability to transfer perspiration from the body. tration of intra/interyarn pores and the fabric thick-
It becomes extremely important in determining thermal ness. Transport of water vapor through the fiber can
comfort in hot environments in which sweat production be either adsorption or absorption, depending upon the
and evaporation from the human body are the major fiber morphology. Absorption involves the diffusion of
cooling mechanisms for maintaining thermal comfort water vapor through the polymer structure of the fiber
and avoiding heat stress. Free movement of moisture by permeation or solution and its desorption at the outer
vapor to the fabric surface is essential in cold weather surface. Thus, the ability of the fibers to undergo diffu-
as well, since perspiration can cause fabric wetness, sion depends on the hydrophilic or hydrophobic nature
resulting in freezing in winter.1 of the fiber. Adsorption is a surface phenomenon with
Water vapor transport through textile structures is a
complex phenomenon determined by various parame-
ters. The mechanisms of water vapor transmission 1
Department of Clothing and Textiles, Yonsei University, Korea.
2
(WVT) through porous textiles involve diffusion of Department of Fiber Science and Apparel Design, Cornell University,
water vapor through voids (openings) and diffusion USA.
through individual fibers.2 Diffusion of water vapor
Corresponding author:
through the void spaces is controlled by the water Seungsin Lee, Department of Clothing and Textiles, Yonsei University,
vapor pressure gradient across the two sides of the Seoul 120-749, Korea
fabric. Pores in woven fabrics can be interfiber and Email: SL158@yonsei.ac.kr
212 Textile Research Journal 82(3)

the adhesion of molecules of gas, liquid, or solids to a model to describe water vapor diffusion through non-
solid surface that can result in a liquid wicking through a woven fabrics composed of non-hydrophilic fibers. They
fibrous assembly. There has been a great deal of research found that fiber volume fraction and shape coefficient are
on the diverse aspects of moisture vapor transport the most influential structural parameters affecting water
through woven textiles, both experimentally and theo- vapor diffusivity through non-hydrophilic nonwoven
retically.3–12 Fourt and Harris3 studied the diffusion of fabrics.
water vapor through woven fabrics, and reported that Although theoretical models provide meaningful
the resistance of a woven fabric to the transport of mois- insight into the relationship between the various
ture vapor depends on the type of fiber, fabric thickness, parameters and moisture vapor transport of porous
and the tightness of the weave. They also noted that textiles, assumptions underlying their calculations are
water vapor transport occurs primarily through the often violated due to the complexity of a textile struc-
voids in the material due to the readily available, low- ture. As described by previous researchers,6 the yarns of
resistance pathway; thus, the nature of fibers itself only open-weave fabrics are often distorted both in and out
contributes to vapor transmission when the volume of the plane of the fabric to achieve static equilibrium
occupied by the fibers is considerably larger. Rainard4 within the weave structure. In tightly woven fabrics,
showed experimentally and theoretically that the intrin- there is an increased tendency toward flattening of the
sic permeability of a fabric was related to the amount of yarns when they are bent over cross yarns, which vio-
voids present in the fabric and the void geometry. lates the assumption in most theoretical models that
Backer5 reported that air/gas permeability of a fabric textile yarns act as inextensible, circular cylinders.
was dependent on the fabric thickness, pore size, and Furthermore, the pore structure in fibrous materials is
the number of pores in a given area. In a study of the complex in that multiple pores have different shapes
geometry of fabric interstices as related to gas transport, and size distributions. Pore size may vary even along
Backer6 observed that the different behavior of various a single pore path, and the material may contain closed
textile structures possessing equal projected pore areas or blind pores that terminate inside the material, which
may be attributed to the nature of the interlacing of warp do not contribute to fluid flow through. The numerous
and filling yarns. He also suggested that where fabrics interrelated structural features of textiles make it hard
are woven with maximum tightness, it is likely that inter- to generalize the analytical aspects of the mechanism of
fiber spacings within yarns also contribute to transport. flow-through fabrics.
However, if a reasonably circular yarn section is main- From the aspect of providing information for prac-
tained in moderately tight fabrics, the relative flow- tical situations, a statistical model would be useful as a
resistance of the interyarn pores should dominate the supplement to theoretical modeling. Statistical analyses
flow through the fabric. would further clarify the governing factors that impact
Whelan et al.7 developed an analytical and experi- the transmission of water vapor through woven textiles,
mental model to predict WVT of textile fabrics based reveal the relative significance of different variables,
on vapor flow through the uniform holes of a perfo- and improve the understanding of the complex behav-
rated metal plate. The model showed that diffusion of ior of moisture vapor transport through textile struc-
water vapor through a perforated metal plate is a func- tures. Although previous studies elucidated influential
tion of the thickness of the plate, the fractional pore factors in moisture movement through woven fabrics,
area of the plate, and the diameter of the individual much research has focused on parts of the elements con-
holes, which stresses the importance of fabric thickness tributing to moisture vapor transport, rather than cov-
and porosity in WVT through woven fabrics. This plate ering the contribution of all the elements. To have a
model, however, assumes that pore diameters are con- comprehensive understanding, a systematic approach
stant throughout the thickness of the material and that based on the mechanisms of moisture movement through
transmission through the solid areas of the plate, porous textiles is needed.
corresponding to the contribution of fabric yarns and Our objectives in this study are to understand
fibers, is zero. Weiner8 proposed two mathematical parameters that are critical in the moisture vapor trans-
models to predict moisture vapor transmission in port through woven fabrics, to quantify the individual
terms of fabric geometry. One model was based on a contributions of those parameters to water vapor trans-
perforated plate theory in which moisture vapor diffuses port, and to develop a statistical model to predict WVT
partly through the pores and through the non-perfo- through woven fabrics.
rated areas of the fabric. In the other model, he con-
siders the fabric as a relatively uniform mixture of fiber
Materials and methods
and air and calculates the resistance to diffusion as the
sum of the components derived from fiber-space and Fifteen woven fabrics with various fabric thickness,
air-space resistances. Woo et al.9 presented an analytical weight, fabric construction, and staple fiber type were
Lee and Obendorf 213

selected. Fiber types included cotton, lyocell, nylon, Mass per unit area. Mass per unit area (weight) was mea-
polyester, and polypropylene to represent different sured according to ASTM D 3776-96.14 Measurements
levels of hydrophilic nature of fibers. For cotton fab- were taken for four randomly selected samples.
rics, which are hydrophilic, fabrics with a range of
thickness, weight, and fabric count were chosen, so Fabric count. Fabric count, that is, number of yarns per
that cotton fabrics from thin, open structures to unit distance, was measured according to ASTM D
heavy, compact structures were included to assess the 3775-03.15 Measurements were taken at five randomly
influence of structural characteristics on moisture vapor selected areas.
transport when intrinsic fiber properties are controlled.
Fabrics had no finishing treatments. Fabric descrip- Yarn number. Yarn number was measured according
tions are given in Table 1. to ASTM D 1059-01.16 Measurements were taken
from 10 warp samples and 10 filling samples for each
fabric.
Textile parameters
Fabric thickness. was measured according to ASTM D Yarn twist. Yarn twist was measured according
1777-96.13 Measurements were taken with a Frazier to ASTM D 1423-99.17 Measurements were taken
Compressometer using a 0.95 cm diameter presser foot from 25 warp samples and 25 filling samples for each
at 6.9 kPa of pressure at 10 randomly selected areas. fabric.

Table 1. Fabric descriptions

Fabric code Fiber Fabric count, yarns/cm; W  F Fabric weight, g/m2 Fabric thickness, mm Construction

W1 Cotton 34  28 108 (1) 0.206 (0.005) Plain


(0.2) (0.2)
W2 Cotton 13  11 540 (4) 1.000 (0.022) Plain
(0) (0.2)
W3 Nylon 6,6 20  18 125 (0.9) 0.323 (0.011) Plain
(0) (0.2)
W4 Polyester 20  20 126 (2) 0.301 (0.006) Plain
(0.2) (0.2)
W5 Polyester 16  13 179 (2) 0.402 (0.006) Plain
(0.2) (0)
W6 Polypropylene 16  13 189 (3) 0.552 (0.007) Plain
(0.2) (0)
W7 Cotton 31  11 316 (2) 0.615 (0.008) Rib
(0.2) (0.2)
W8 Cotton 35  11 209 (2) 0.474 (0.008) Rib
(0.2) (0)
W9 Cotton 22  16 359 (3) 0.601 (0.010) Plain
(0) (0)
W10 Cotton 45  20 278 (2) 0.480 (0.008) Twill
(0.2) (0.2)
W11 Lyocell 36  27 148 (3) 0.254 (0.014) Plain
(0.2) (0.3)
W12 Lyocell 28  20 205 (1) 0.421 (0.008) Plain
(0.2) (0.2)
W13 Cotton 29  19 358 (2) 0.683 (0.008) Twill
(0) (0.3)
W14 Cotton 34  11 445 (8) 0.813 (0.036) Rib
(0.2) (0.2)
W15 Cotton 18  18 474 (2) 0.972 (0.008) Twill
(0) (0)
Standard deviations in parentheses.
214 Textile Research Journal 82(3)

Yarn diameter. Yarn diameter was measured using a interfiber space should be included in the modeling. In
microscope equipped with a calibrated micrometer order to be used in modeling, the concepts described in
(ContinummTM, Thermo Nicolet Co., Madison, WI). the mechanisms of moisture vapor movement through
Measurements were taken from 50 warp samples and porous textiles should be expressed in appropriate var-
50 filling samples for each fabric. iables that are quantifiable.
In this study, the fabric cover factor was selected as a
Pore size distribution. Pore size distribution was measured possible predictor variable in the modeling to approx-
by a Capillary Flow Porometer (Model CFP-1200- imate the contribution of interyarn spaces. The cover
AEX, Porous Materials, Inc., Ithaca, NY). Gas flow factor is a measure of fabric tightness and describes the
rates through wet and dry samples versus differential compactness of the weaving of a given yarn system,
pressure were measured, and pore diameters of which could represent the relative magnitude of inter-
through-pores at the most constricted part of the pore yarn space of a given fabric. The cover factor was cal-
were determined.18 culated from fabric counts and yarn diameters using the
following equation:
Water vapor transmission
C ¼ ed1 þ pd2  epd1 d2 ð1Þ
WVT rate was measured according to ASTM E 96-0019
using a dish assembly (Vapometer, Thwing-Albert where C represents cover factor of the fabric; e is the
Instrument Company, Philadelphia, PA) for three samples. number of warp yarns over 1 cm of fabric width; p is the
number of filling yarns over 1 cm of fabric width; d1 is
Statistical analyses the diameter of the warp yarn (cm); d2 is the diameter of
the filling yarn (cm). Cover factors for the specimens,
Statistical analyses were performed on textile measure- which ranged from 0.71 to 1.00, are shown in Table 2.
ments and water vapor transport data using the SASÕ The relative magnitude of interfiber space could be
system (SAS Institute Inc., Cary, NC). Multivariate sta- quantified by textile parameters such as yarn twist
tistical methods, including multiple linear and multiple factor or yarn packing factor. The twist factor is a mea-
polynomial regressions, all-subsets regression, and step- sure of ‘twist hardness’ of yarn and describes compact-
wise regression were performed. Before the analyses, ness in yarns of the same size. The twist factor was
data were centered by subtracting the mean for each pre- calculated using the following equation:
dictor variable to reduce the degree of multicollinearity.
tpi
tw ¼ pffiffiffiffiffiffi ð2Þ
Ne
Results and discussion
Selection of textile parameters Table 2. Fabric parameters

Fabric weight and thickness were measured for each spe- Fabric Yarn Yarn Solid
cimen. Fabrics ranged in mass per unit area from 108 to Fabric cover twist packing volume Moisture
540 g/m2, and varied in thickness from 0.206 to1.000 mm. code factor factor factor fraction regain, %21,22
Weight and thickness are presented in Table 1. W1 0.71 3.65 0.62 0.345 7.5
Based on the mechanisms of water vapor transport W2 0.96 5.30 0.41 0.355 7.5
through porous textile fabrics, water vapor may diffuse:
W3 0.78 2.92 0.46 0.340 4.5
(1) through the interyarn spaces; (2) through the inter-
W4 0.87 3.08 0.30 0.303 0.4
fiber spaces; (3) through the fiber substance itself. In
order to have a comprehensive understanding of W5 0.88 3.83 0.26 0.322 0.4
WVT through a textile fabric and to obtain an expres- W6 0.91 2.53 0.37 0.369 0.1
sion for the moisture vapor transport, the contribution W7 1.00 4.12 0.53 0.338 7.5
of each of these parts needs to be taken into account. W8 0.90 3.61 0.55 0.290 7.5
Woven textiles have complex geometric configura- W9 0.88 5.10 0.66 0.394 7.5
tions because of the fabric weave and yarn structure. W10 1.00 3.86 0.64 0.381 7.5
In woven structures, pores can be interfiber and inter- W11 0.78 3.64 0.70 0.386 12
yarn. The structure and dimension of intra- and inter- W12 0.86 3.67 0.50 0.322 12
yarn pores strongly depend on hardness of twist in W13 0.94 4.11 0.56 0.345 7.5
the yarn structure and compactness in the woven struc- W14 1.00 4.37 0.55 0.360 7.5
ture.20 Thus, textile structural parameters that could
W15 0.94 4.38 0.48 0.321 7.5
describe the relative magnitude of interyarn space and
Lee and Obendorf 215

where tw represents the twist factor of the yarn; tpi is The fabric weave and nature of the yarn interlacing
the twist in turns per inch; Ne is the yarn number in the influence the amount and size of voids and the pore
cotton system. Average twist factors of warp and filling geometry, and therefore vapor transport through
yarns for each specimen, which ranged from 2.53 to fabric. To represent the interlacing pattern between
5.30, are presented in Table 2. warp and filling yarns we chose variables that could
The yarn packing factor, which describes the ratio of reflect the effect of fabric weave and that are quantifi-
the total fiber area to actual yarn area in the cross- able to be used in the modeling. The fabric cover factor
section of a multifilament yarn, was calculated as was selected to describe fabric tightness and solid
follows: volume fraction to quantify the amount of voids.
Pore size and shape are also affected by fabric and
4Nt yarn structure, as well as fiber size. Pore size was
’¼ ð3Þ
  d2   S reported as an important parameter affecting WVT
through woven fabrics.5,7 Although woven textiles
where ’ represents the packing factor of the yarn; d is have complex geometric configurations with a range
the diameter of the yarn (cm);  is the density of the of pore diameters, a descriptor that could represent
fiber (g/cm3); Nt is the linear density of the yarn (tex); S the pore dimension of woven fabric needs to be
is the constant, 105. Densities for cellulose, nylon, poly- explored in order to be used as a predictor variable in
propylene, and polyester were obtained from Morton modeling and to examine the contribution of pore size
and Hearle.21 Average packing factors of warp and fill- to moisture vapor movement through the material. In
ing yarns for each specimen, which ranged from 0.26 to this study, capillary flow porometry was used to mea-
0.70, are presented in Table 2. sure pore diameters of only through-pores at the most
The solid volume fraction of fabric, the ratio of solid constricted part of the pore for each fabric. From the
parts to the total volume of the material, which has through-pore size distribution of each specimen, we
shown to be an influential structural parameter affect- computed two different types of pore size that might
ing water vapor diffusivity through non-hydrophilic be used as a possible predictor variable in modeling:
nonwoven fabrics,9 was calculated as follows: mean flow pore diameter and diameter at maximum
pore size distribution. Mean flow pore diameters for
m= the specimens ranged from 4.89 to 49.59 mm, and diam-
S¼ ð4Þ
at eters at maximum pore size distribution ranged from
0.60 to 7.50 mm. Pore size data for each specimen are
where S represents the solid volume fraction of the given in Table 3.
fabric; m is the mass of the specimen at standard con- Based on the mechanisms of WVT through woven
dition (g);  is the density of the fiber (g/cm3); a is the fabrics and previous studies, we selected seven factors
area of the specimen (cm2); t is the thickness of the for statistical analyses: fabric thickness, cover factor,
specimen (cm). Solid volume fractions for the speci- solid volume fraction, yarn twist factor, yarn packing
mens, which ranged from 0.290 to 0.394, are shown factor, pore diameter, and moisture regain of fiber. The
in Table 2. selection process is summarized in Figure 1.
Since water vapor may diffuse not only through the
void spaces but also through the fiber substance, the
nature of fibers may contribute to moisture vapor
Parameters influencing water vapor transport
transport. Moisture regain is a property that reflects WVT rates for each specimen are shown in Table 3.
the hydrophilic or hydrophobic nature of fibers, and Statistical analyses were performed to determine the
such inherent fiber characteristics may affect moisture characteristics for each parameter that influences the
vapor transport through a textile fabric. Absorption of WVT. Table 4 shows the correlation coefficients
moisture can result in fiber swelling, particularly for between WVT and textile parameters. Fabric thickness
hydrophilic fibers with high moisture regain. This mois- has the highest correlation coefficient, followed by the
ture absorption is a dynamic factor until a steady state mean flow pore diameter of fabric, fabric cover factor,
is reached, which is the condition at which WVT was yarn twist factor, diameter at maximum pore size dis-
measured. In this study, moisture regain of fiber was tribution, yarn packing factor, moisture regain of fiber,
selected as a possible predictor variable to represent the and solid volume fraction of fabric. It shows that the
hydrophilic or hydrophobic nature of fibers and possi- fabric thickness, fabric cover factor, yarn twist factor,
ble changes in porosity due to fiber swelling. Moisture yarn packing factor, moisture regain of fiber, and solid
regains for cotton, lyocell, nylon, polyester, and poly- volume fraction of fabric are negatively related to
propylene were obtained from literature21,22 and are WVT, whereas pore diameters of fabric are positively
presented in Table 2. related to moisture vapor movement through the
216 Textile Research Journal 82(3)

material. In other words, WVT decreases with To develop a statistical model predicting WVT
increased fabric thickness, fabric cover factor, yarn through woven fabrics, regression analyses were per-
twist factor, yarn packing factor, moisture regain of formed using those textile parameters. Since some of
fiber, and solid volume fraction, whereas WVT the parameters, such as mean flow pore diameter and
increases with increased pore diameter of fabric. diameter at maximum pore size distribution, are highly
interrelated, all-subsets regression and stepwise regres-
sion were performed first to screen the variables that
Table 3. Pore size measurements and water vapor transmis- have little influence in predicting the response variable
sion rate of woven fabrics when other predictor variables are present in the model.
Pore size We found that diameter at maximum pore size distri-
Water bution does not contribute much to the model when the
Mean flow Diameter at vapor mean flow pore diameter is present in the model.
Fabric pore diameter maximum pore size transmission We also found that solid volume fraction does not con-
code mm distribution, mm rate, g/h/m2 tribute to the model when the fabric cover factor is
W1 28.73 7.18 19.70 present in the model. Thus, the two variables, diameter
W2 14.07 7.21 18.48
W3 32.65 7.50 19.54
Table 4. Correlation coefficients between water vapor trans-
W4 36.31 7.34 20.31
mission and fabric parameters
W5 42.56 7.49 19.67
W6 49.59 6.34 19.24 Correlation
Fabric parameters coefficient
W7 9.71 5.45 18.96
W8 13.04 7.06 19.08 Fabric thickness 0.86
W9 8.21 5.55 18.76 Mean flow pore diameter of fabric 0.75
W10 9.35 6.29 18.87 Fabric cover factor 0.67
W11 34.74 7.26 19.71 Yarn twist factor 0.66
W12 18.58 5.70 19.72 Diameter at maximum pore size distribution 0.52
W13 4.89 0.60 18.36 Yarn packing factor 0.29
W14 6.52 1.36 18.64 Moisture regain of fiber 0.28
W15 7.70 7.04 18.36 Solid volume fraction of fabric 0.28

Figure 1. Influential factors involved in water vapor transmission through woven fabrics.
Lee and Obendorf 217

Table 5. Summary of coefficients and R2 values for regression models for water vapor transmission

Regression coefficientsa

Intercept T C tW f M P T2 C2 t W2 f2 M2 P2 Adjusted R2

Model 1 0 2.2 0.2 0.07 2.5 0.05 0.008 - - - - - - 0.87


(0.5) (1) (0.1) (0.8) (0.03) (0.009)
Model 2 0.6 2 1 0.07 4 0.19 0.03 3 14 0.20 8 0.045 0.0041 0.99
(0.2) (1) (1) (0.2) (1) (0.04) (0.01) (2) (10) (0.09) (9) (0.005) (0.0007)
Model 3 0.08 1.0 - - - 0.06 - - 12 - - 0.026 0.0017 0.97
(0.06) (0.2) (0.01) (4) (0.003) (0.0002)
Model 4 0.05 1.0 0.2 - - 0.06 0.002 - 11 - - 0.025 0.0017 0.97
(0.1) (0.2) (0.7) (0.02) (0.008) (6) (0.005) (0.0002)
a
T (fabric thickness); C (fabric cover factor); tW (yarn twist factor); f (yarn packing factor); M (moisture regain); P (Mean flow pore diameter).
Standard errors of coefficients in parentheses.

at maximum pore size distribution and solid volume fabric thickness, cover factor, moisture regain of fiber,
fraction of fabric, which were not significant in the and mean flow pore diameter of fabric, and quadratic
presence of other predictor variables, were eliminated terms of cover factor, moisture regain of fiber, and
in further modeling efforts. mean flow pore diameter of fabric (Table 5, Model 4).
We started with a multiple linear regression model, Thus, a regression equation to predict WVT through
and the regression equation resulted in an adjusted R2 woven fabrics is as follows:
value of 0.87 (Table 5, Model 1). Table 5 shows the
coefficients for textiles parameters with adjusted R2 WVT ¼  0:05  T  0:2C  0:06M þ 0:002P
values for models developed. Since partial regression þ 11C2 þ 0:025M2  0:0017P2 ð5Þ
leverage plots of the dependent variables versus inde-
pendent variables showed quadratic relationships, a
polynomial multiple regression model with linear and where T is fabric thickness (mm); C is the fabric cover
quadratic terms was refitted to the data. When the qua- factor; M is the moisture regain of fiber (%); P is the
dratic terms, as well as linear terms, were entered in the mean flow pore diameter of fabric (mm). The adjusted
model, the adjusted R2 value increased to 0.99 (Table 5, R2 value is 0.97, which indicates that the four textile
Model 2). For the polynomial model, the linear terms parameters, fabric thickness, cover factor, moisture
of fabric thickness and moisture regain were found to regain of fiber, and mean flow pore diameter of
be significant factors among the six linear terms, and fabric, accounted for significant amounts of the differ-
the quadratic terms of cover factor, mean flow pore ences observed in WVT of woven fabrics among the
diameter, and moisture regain were found to be signif- fabrics examined. Influence of the yarn twist and yarn
icant factors among the six quadratic terms. The vari- packing factor was shown to be insignificant at the 5%
ance inflation factors were much higher than the critical significance level for these experimental conditions for
value, 10, which indicates high multicollinearity among models that also include fabric thickness and cover
the independent variables. Since the four other linear factor. This may indicate that, for woven fabrics, inter-
terms and three other quadratic terms did not appear to yarn spacings may have greater influence on moisture
be influential for prediction of WVT, those terms were vapor transport than interfiber spacings within yarns.
dropped at the 5% significance level. The polynomial Fabric thickness was one of the highly influential fac-
model with linear terms of thickness and moisture tors affecting water vapor transport of woven fabrics as
regain and quadratic terms of cover factor, mean flow a singular parameter with a negative relationship
pore diameter, and moisture regain resulted in an between fabric thickness and WVT. Moisture regain
adjusted R2 value of 0.97, keeping only significant of fiber was shown to be another important factor in
terms at a 5% significance level (Table 5, Model 3). moisture vapor transport. Previous researchers3 noted
Since it is a rule of thumb to keep lower order terms that significant amounts of moisture vapor travel through
of predictor variables even if they are non-significant in the fiber substance for hydrophilic fibers, and this effect of
polynomial models, the linear terms of cover factor and fiber type was observed when the volume occupied by the
mean flow pore diameter were kept in the model. The fibers exceeded 30–40%. The majority of our specimens
final model selected to predict WVT through woven ranged from 0.30 to 0.40 in solid volume fraction; thus,
fabrics was a polynomial model with linear terms of we suppose that the contribution of the intrinsic fiber
218 Textile Research Journal 82(3)

properties was revealed in the model. There was no Acknowledgement


significant difference between Models 2, 3, and 4 in Jared Matteau of Porous Materials, Inc., 20 Dutch Mill
terms of R2 at the 5% significance level. Thus, the final Road, Ithaca, NY, USA measured the pore sizes presented
model selected is the one showing higher R2 with the in Table 3.
fewest number of significant variables.
Funding
Conclusions This work was supported by the Yonsei University Research
Fund of 2010; the National Textile Center, projects M01-
Water vapor transport through porous textile mate- CR02, M02-CD03; and C05-CR01; Cornell Agricultural
rials is governed by various factors. Diversity and Experiment Station, North Central Regional Research
complexity of the involved parameters makes it hard Project NC 170; and the College of Human Ecology.
to describe moisture vapor transport in relation to
these factors. References
We attempted to describe moisture vapor transport
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A statistical model predicting WVT through woven 12. Nefzi N, Jouini M and Nasrallah SB. Water vapor trans-
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diameter of fabric, with an adjusted R2 value of 0.97. 13. ASTM D 1777-96. Standard test method for thickness of
This model would be valid for fabrics with characteris- textile materials.
14. ASTM D 3776-96. Standard test method for mass per unit
tics within the range of the fabrics in our sample pop-
area (weight) of fabric, option C, small swatch of fabric.
ulation, for instance, for fabrics woven of staple fibers
15. ASTM D 3775-03. Standard test method for fabric count
when fabric thickness is in the range from 0.206 to of woven fabric.
1.000 mm, etc. While based on statistics of a sample 16. ASTM D 1059-01. Standard test method for yarn number
population rather than a physical mechanism, these based on short-length specimens.
findings are of practical use for engineering woven 17. ASTM D 1423-99. Standard test method for twist in
textiles with high water vapor permeability. yarns by the direct counting method.
Lee and Obendorf 219

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by porometry. Chem Eng Technol 2010; 33: 1241–1250. tile fibres, 3rd ed. Manchester, UK: The Textile Institute,
19. ASTM E 96-00. Standard test method for water vapor 1993.
transmission of materials, upright cup method. 22. Mizutani C, Tsujii Y and Bertoniere N. Effect of fiber
20. Lee S and Obendorf SK. Statistical model of pesticide structure on heat of wetting of cotton and regenerated
penetration through woven work clothing fabrics. Arch cellulosic fibers. Textile Res J 1999; 69: 559–564.
Environ Contam Toxicol 2005; 49: 266–273.

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