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XI-17
CHAPTER
UNIT
SI Derived Units with Special names
SI Unit
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Dimensions of commonly used Physical Quantities
Dimensional
S.No. Physical Quantity (Mechanics) SI Units formula
1. Velocity = displacement/time m/s M 0LT –1
5. Energy J ML2T –2
L V no units
11. Strain = or
L V
12. Stress = force/area N/m2 ML –1T –2
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Dimensional
S.No. Physical Quantity (Mechanics) SI Units formula
31. Enthalpy cal ML2T –2
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VB
(d) Relative velocity
(i) V AB V A V B
VA
(ii) | V AB | VA2 VB2 2VA VB cos
(iii) If relative velocity makes an angle with VA then,
VB sin
tan
VA VB cos
P
Fy = F sin
(e) Resolution of vectors F
The component of F in a direction making an angle is F cos
.
O Q
The other component of F at right angles to F cos is F sin Fx = F cos
.
F Fx2 Fy2
|A| a 2x a 2y a 2z
| iˆ || ˆj|| kˆ | 1
(i) Vector
product or Cross product
A B | A | | B | sin nˆ where n̂ = unit vector perpendicular to plane containing A and B .
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CHAPTER
02 KINEMATICS
VELOCITY VECTOR
1 T
v av (t) vdt
T 0 P2
r2
The direction of the average velocity vector is the direction r v av
O r1 P
of the displacement vector r as shown in figure. P1 1
(b) The instantaneous velocity vector v is the limit of the z
x
average velocity as the time interval approaches zero.
The average velocity v av
r dr
i.e., v lim between, P1 and P2 has the
t 0 t dt same direction as the
displacement r
ACCELERATION VECTOR
1 T
(a) a av adt
T 0
The direction of the average acceleration vector is same as the direction of the change in velocity vector
v .
y
v2 P aav
2 v
aav
O v1 v2
P 1 v1
z
x
The instantaneous velocity v at any point is tangent to the path
at that point.
(b) The instantaneous acceleration vector is the limit of the average acceleration as the time interval
approaches zero. That is,
v dv
a lim
t 0 t dt
Note:
(a) A particle has an acceleration when its velocity is changing.
(b) Instantaneous acceleration can also be represented in terms of its components parallel and perpendicular
to the direction of the instantaneous velocity
(c) The parallel or tangential component of acceleration is zero if the speed of the particle is constant.
(d) When a particle moves along a straight line the perpendicular component of acceleration is zero.
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v v v
Normal Normal Normal
at P at P at P
P P P
a
a
a
(a) (b) (c)
The figure shows velocity and acceleration vectors for a particle P
moving along a curved path with (a) constant speed (b) increasing
speed (c) decreasing speed.
EQUATIONS OF KINEMATICS
In a straight line motion with constant acceleration, the position x and velocity v at any instant t are related to
acceleration a by simple equations, called the equations of kinematics.
v v0 at
1
x x 0 v0 t at 2
2
v 2 v20 2a(x x 0 )
v v
x x0 0 t
2
where x0 and v0 are the initial position and velocity of the particle (i.e. both at t = 0).
a
x n v 0 (2n 1)
2
RELATIVE MOTION OF TWO PARTICLES
When two particles A and B move along the same straight line, denoting A
by xB/A, the relative position coordinate of B with respect to A, we have O B
xA xB/A
x B x A x B/ A . xB
Denoting by vB/A and aB/A respectively, the relative velocity and the relative acceleration of B with respect to A,
we have
v B v A v B/ A
a B a A a B/A
DEPENDENT MOTIONS
The position of block B depends upon the position of block A xA
x A 2x B length of rope xB
B
v A 2vB 0 and a A 2a B 0
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(iii) If it is a parabola opening upwards a 0
x a>0 x a<0
t t
and if it is a parabola opening downwards a 0
(iv) To convert a displacement time graph in to a distance time graph
Place a plane mirror at O, parallel to time axis and take its reflection
x o s
displacement distance
t t
(b) v – t graph
(i) Slope gives acceleration
(ii) Area under v t curve gives displacement/distance
Displacement = A1 A 2
v
Distance = | A1 | | A 2 |
+A1
A2 t
(c) a – t graph
(i) Area under a t graph gives change in velocity
v2 u 2
(ii) Area under a x graph gives
2
v
vdv v2 u 2
Area = adx .dx
u dx 2 a
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PROJECTILE MOTION (OBLIQUE)
Oblique Projection on a Horizontal Surface y
(a) Change in position vector r
2
gt gt sin 0 P(x, y)
| r | v 0 t 1 v0 r
2v0 v0
0 v
2v sin 0 gt o t=o
tan 1 0 . x
v cos = v0 cos0
2v 0 cos 0
(b) Average Velocity
2
gt gt sin 0
v av v 0 1
2v 0 v0
2v sin 0 gt
tan 1 0
2v0 cos 0
(c) Instantaneous Velocity
2
gt 2gt
v v0 1 sin 0
v0 v0
vy v sin 0 gt
tan 1 tan 1 0
vx v0 cos 0
tan 1{tan 0 (gt / v0 )sec 0 }
vy v2 sin 2 2gt v2 sin 2 2gy
tan 1 tan 1 0 0
= tan 1 0 0
vx v 0 cos 0 v0 cos 0
(d) Equation of Trajectory
gx 2
y (x tan 0 ) 2 sec 2 0
2v 0
(e) Time of Flight
2v sin 0
T 0
g
(f) Maximum height
v2 sin 2 0
H max 0
2g
(g) Range
v 2 sin 20
R 0
g
R is maximum when sin20 is maximum 0 = 45.
(h) Angle of Projection of Given Ratio of Range and Maximum Height Attained
R H
tan 0 4 /
4H
0 tan 1 76 (when H = R or = 1)
R
(i) Projectile Passing Through Two Different Points of same height at Time t1 and t2
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1
y gt1 t1
2
(j) Minimum Velocity of Projection Required to Pass Through a Given Point
v min g(y x 2 y 2 )
v 2 sin 2 2gy
tan 1 0 0
.
v 0 cos 0
y 1 gy
tan 1 tan 1
v 2y / g
2
0 v0
(b) Velocity
v v ˆi-gtjˆ
0
2gy
v v02 2gy and tan 1
v0
(c) Range
2H
R v0
g
(d) Equation of trajectory
gx 2
y 2
2v 0
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v 20
R max . (up the plane)
g(1 sin )
v20
R 'max (down the plane)
g(1 sin )
(c) Condition for retracing the path of a projectile on an inclined plane
v cos
T 0 , where = –
g sin
2 tan cot
cot
tan 1
2
tan 1 (3cot )
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CHAPTER
T m 2g m2a 2 … (ii)
m1g 2m 2 g a1 m
From (i) and (ii) a1 1
a2
m1 4m 2
m2
2m1g 4m 2 g
a2
m1 4m 2
PSEUDO FORCE
In an accelerated frame of reference, Newton’s laws are not applicable unless we introduce pseudo forces.
If we are studying the motion of body of mass m, in a frame of reference with acceleration a, the pseudo force
to be introduced = ma
CONICAL PENDULUM
L cos h
T 2 2 L
g g h
mg
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ELEVATOR OR LIFT
If W0 = mg = actual weight of a body, N = apparent weight of Lift
a body in the lift (which is also reactionary force)
a=0
(a) If the lift is at rest or moves up or down with uniform (constant)
F=0
(constant) velocity, v v N
N Mg W0
The apparent weight is the same as true weight.
mg
mg
mg
FRICTIONAL FORCE R
When a horizontal force F is applied to A and if its magnitude
is gradually increased, a force f comes into play opposing the A
tendency of A to move. F
f1
Mg
TYPES OF FRICTIONAL FORCE
(a) Static frictional force
Self adjusting force having magnitude less than or equal to s N.
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CHAPTER
WORK
(a) Work in terms of rectangular components
F.S Fx Sx FyS y FzSz
WA B F dx F dy F dz
x y z
xA yB zA
POTENTIAL ENERGY :
r
U F.dr W
MECHANICAL ENERGY
Definition : Mechanical energy ‘E’ of an object or a system is defined as the sum of kinetic energy ‘K’ and
potential energy ‘U’, i.e., E K U
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(a) It is a scalar quantity having dimensions [ML2T2] and SI units joule.
(b) It depends on frame of reference.
(c) A body can have mechanical energy without having either kinetic energy or potential energy. How ever,
if both kinetic and potential energies are zero, mechanical energy will be zero. The converse may or may
not be true, i.e., if E 0 either both PE and KE are zero or PE may be negative and KE may be
positive such that KE PE 0 .
(d) As mechanical energy E K U, i.e., E U K. Now as K is always positive, E U 0, for existence
of a particle in the field, E U .
(e) As mechanical energy E K U and K is always positive, so if ‘U’ is positive ‘E’ will be positive.
However, if potential energy U is negative, ‘E’ will be positive if K > |U| and E will be negative if
K | U | i.e., mechanical energy of a body or system can be negative, and negative mechanical energy
means that potential energy is negative and in magnitude it is more than kinetic energy. Such a state is
called bound state, e.g., electron in an atom or a satellite moving around the planet are in bound state.
CONSERVATIVE FORCE
(a) Work done by a conservative force depends only on the initial and final positions of the body.
(b) Relation between Conservative force and potential energy
U U U U
Fs F i i k
S x y z
u 5gR , N 6mg
h>R
u
(c)
Condition of oscillation is 0 u 2gR
u
v 0
N 0 hR
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(b) If we plot graphs between F and r or U F U
and r, F will be zero at equilibrium
while U will be maximum, minimum or
r C r
constant depending on the type of A B C D A B D
equilibrium. This all is shown in figure.
dU
At point A, F 0, = 0, but U is constant. Hence, A is neutral equilibrium position. At points B and D ,
dr
dU
F 0, 0 , but U is maximum. Thus, these are the points of unstable equilibrium. At point C,
dr
dU
F 0, 0, but U is minimum. Hence, point C is in stable equilibrium position.
dr
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CHAPTER
IMPULSE
Impulse is the product of the force and the time during which the force acts. If the force is variable, then
(m1 em 2 ) m 1 e
(a) v1 u1 2 u2
(m1 m 2 ) (m1 m 2 )
and v 2
m1 (1 e) m em1 u
u1 2 2
m1 m 2 m1 m 2
u 2rel 1 e 2 m1m 2
KE , where
2 m1 m 2
(e) K.E. delivered (change in K.E. of the system in perfectly inelastic collision)
1 m12 u12
2 (m1 m2 )
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OBLIQUE IMPACT
Common
tangent
2
1 Line of
impact
1 2
v cos 1 v 2 cos 2
(a) e 1
u1 cos 1 u 2 cos 2
m1m 2
(b) Impulse (1 e)(u1 cos 1 u 2 cos 2 )
m1 m 2
m1m 2
(c) Energy loss (1 e 2 )(u1 cos 1 u 2 cos 2 ) 2
2(m1 m 2 )
t1 t2 t2
ey
x y
u v +v
m
m
Rocket: The velocity of the rocket at any time t is given by, v gt u log e 0
m
where u = velocity of gas relative to rocket
m0 = initial mass of the rocket at time (t = 0)
m = mass of rocket at instant t
dm
The thrust on the rocket F u
dt
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CHAPTER
06 ROTATIONAL MOTION
MOMENT OF INERTIA
n
(a) Moment of inertia of a system of particle about an axis is defined by I m i ri2
i 1
(b) Parallel axis theorem
I Icm md 2
(c) Perpendicular axis theorem Iz I x I y
(d) Moment of inertia of some common bodies.
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Line of action E P F
h
r
O
ANGULAR MOMENTUM
(a) Angular momentum of a particle describing circular motion
L rp
(b) Angular momentum of a rigid body in a fixed axis rotation
L I
(c) Angular momentum of a rigid body describing general plane motion
L L cm R cm Mvcm
(d) Conservation of angular momentum
For a system of particles
dL dL x dL y dL
ex , i.e., ex (x ) ex (y ) z ex (z)
dt dt dt dt
The angular momentum of a system of particles about an axis remains conserved if net torque acting on
the system about that axis is zero. This is called conservation of angular momentum principle.
(e) Angular momentum of a body in combined translational and rotational
LP Icm r mvcm
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ANGULAR IMPULSE (MOMENT OF IMPULSE)
The angular impulse is defined as the change in angular momentum produced by a torque.
2
J dt where J =angular impulse
1
J rI
I(2 1 ) L 2 L1 L
If v and a are the velocity and acceleration of C.M. of a rolling body relative to the surface, then
v R and a R are applicable for pure rolling motion even when the surface is moving.
(b) Combined rotation and translation
r v0
k2
Percentage % of energy of rotation = 100
k 2 r2
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(d) Role of friction in rolling motion F
h
Fh
Icm
f 0 P
If a R , point of contact has a tendency to slip in forward direction and hence f will act in backward
direction to provide pure rolling.
I cm
h
mR
If a R , point of contract has a tendency to slip in backward direction and hence f will act in forward
direction to provide pure rolling.
Icm
h
mR
(e) Rolling on inclined plane
gsin
(i) a
k2
1 2
r
mg sin
(ii) f
r2
1 2
k
1/2
2gh
(iii) Vcm
k2
1
r2
1/ 2
k2
1 r 2
(iv) t
g sin
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CHAPTER
07 GRAVITATION
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2
g h
1
g R
If h R
2h
g g 1
R
(c) Variation with depth
The acceleration due to gravity g, at depth h below the surface of the earth is given by
h
g g 1
R
(d) Effect of rotation
Earth’s rotation affects the value of g
At latitude , g g 2 R cos 2
MOTION OF SATELLITES
A satellite is revolving around the earth in a circular orbit of radius r
4 2 r 3 r3
(a) Time period T 2
GM GM
gR 2 GM
(b) Orbital velocity v 0 =
Rh Rh
1 GMm
(c) Kinetic energy E k .
2 r
GMm
(d) Gravitational potential energy E p
r
ESCAPE VELOCITY
GM
v e 2gR 2
R
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CHAPTER
ELASTICITY
(a) Stress
restoring force F
stress
Area A
(i) Longitudinal or Normal stress
Tensile stress Compressive stress
(b) Strain
change in configuration
Strain,
original configuration
It has no unit
Types of strain
(i) Longitudinal strain F/A x
x
L
Longitudinal strain =
L
(ii) Volumetric strain
V
v volume strain
V
(iii) Shear strain
x
tan or
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i.e. stress strain
stress
Modulus of Elasticity
strain
This constant is called modulus of elasticity
(b) Types of modulus of elasticity
Corresponding to the three types of strain there are three types of modulus of elasticity
Fl
(i) Young’s modulus of elasticity (Y) =
Al
(ii) Bulk modulus:
Pressure
K
Volumetric strain
p pV
K
V V
V
(iii) Compressibility: The reciprocal of bulk modulus of elasticity is called compressibility. Bulk
modulus of solids is about fifty times that of liquids, and for gases it is 108 time of solids.
K solids K liquids K gases
Isothermal modulus of elasticity of gas K P (pressure of gas)
Cp
Adiabatic modulus of elasticity of gas K P where .
Cv
(c) Modulus of rigidity:
F/A F
A
ELONGATION OF ROD
(a) Elongation of rod under it’s self weight
L Tdx L Wxdy WL L
Total elongation s
0 Ay 0 LAY 2AY
Where W is the self weight, A is area of cross-section area and Y is young’s modulus
(b) Elongation due to rotation about an axis passing through one end of the rod.
3
3Y
(c) Elongation in the block L
Tdx Fxdx F
d smooth
0 AY 0 AY 2AY
F
[This result is true for all cases, when F
>mg or when F < mg]
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ANALOGY OF ROD AS A SPRING
stress
(a) Y
strain A, Y
k
F
Y
A
AY
or F
F
AY
constant, depends on type of material and geometry of rod. F k
AY
where k equivalent spring constant.
(b)
A 1, Y 1, 1 A1Y1
A3, Y3, 3 k1
1
A3Y3
k3
AY
k2 2 2 3
A 2, Y 2, 2 2
F F
(c) A mass ‘m’ is attached with rods as shown in figure.
This mass is slightly stretched and released whether the
motion of mass is S.H.M., if yes then find out the time A1, Y1
period. 1 k1
k1 k 2
k eq
k1 k 2
k2
2 A2, Y2
m m(k1 k 2 )
T 2 2
k eq k1 k 2 m m
A1Y1 AY
where k1 and k 2 2 2
1 2
FLUID
(a) Density
M/V
(b) Relative Density or Specific Gravity r / w .
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(c) Density of a Mixture of Substance in the Proportion of Mass
12 (M1 M 2 )
1M 2 2 M1
(d) Density of a Mixture of Substance in the Proportion of Volume
1 v1 2 v2
v1 v 2
y P P+dP
dy
SURFACE TENSION
F
(a) T (surface tension) =
2L
The direction of force due to surface tension is perpendicular to the line and tangential to the liquid
surface.
(b) Surface Energy
Work done in small displacement dx
dW F dx 2TL dx
x
W 2TL dx 2TLx TA
0
(a) (b)
Case I: When > 90 :
The liquid surface curves up towards the solid. This happens when the force of cohesion between
two liquid molecules is less than force of adhesion between the liquid and the solid. If such a
liquid is poured into a solid tube, it will have a concave meniscus. For example, a glass rod
dipped in water, or water inside a glass tube.
Case II: When > 90 :
The liquid surfaces get curved downward in contact with a solid. In this case the force of
cohesion is greater than the force of adhesion.
For example, a glass rod dipped in mercury or mercury within a solid glass tube.
(e) Capillarity
2T cos
h
Rg
VISCOSITY
dv
(a) F A .
dz
(b) Stokes’ Law and Terminal Velocity
(i) F 6 rv
2
(ii) vT r 2 g
9
2
(c) Terminal velocity v T r 2 g
9
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CHAPTER
(a) A body is said to execute simple harmonic motion when it experiences a restoring force which is
proportional to its displacement and is directed to the equilibrium position.
(b) Displacement
y A sin 2ft ; where A is the amplitude and f is the frequency.
(c) Particle velocity
v A 2 y2
(d) Particle acceleration
a 2 y
(e) Restoring force
F m2 y
(f) Differential equation of SHM
d2 y
2 y
dt 2
MOTION OF A BODY SUSPENDED BY A SPRING
m
(a) T 2
k
k
(b) If two masses m1 and m2 are connected by a spring, then the time m1 m2
period is
m1m 2
T 2 where is reduced mass,
k m1 m 2
(c) If a spring of force constant, k is divided into n equal parts and one such part is attached to a mass m,
m
then the time period is T 2
nk
(d) Springs in series
k1
1 1 1 1
k2
k eff k1 k 2 k 3
k3
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(e) Spring in parallel
k1 k2
k eff k1 k 2 k 3 k3
TORSIONAL PENDULUM
Restoring torque, = – C , where C is torsional rigidity of wire
I
T 2
C
SHM OF A PARTICLE IN A TUNNEL ALONG A DIAMETER OF EARTH
R
T 2
g
SIMPLE PENDULUM
(a) Pendulum of small length
L
T 2
g
(b) Pendulum of infinite length
R
T 2
g
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CHAPTER
10 WAVES
Y
(b) Longitudinal wave in solid, v [Y = Young’s Modulus, = density]
K
(c) Longitudinal wave in a fluid : v [ K Bulk Modulus]
(d) Newton’s formula:
Newton assumed propagation of sound through a gaseous medium to be an isothermal process.
PV constant
dP P
and hence B P and thus he obtained for velocity of sound in a gas
dV V
P RT
v where M = molar mass
M
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(e) Laplace’s correction:
Later laplace established that propagation of sound in a gas is not an isothermal but an adiabatic process
and hence PV constant.
P RT
v
M
Factors affecting speed of sound in atmosphere
(i) Effect of temperature : as temperature (T) increase velocity (v) increases. For small change in
temperature above room temperature v increases linearly by 0.6 m/s for every 1C rise in
temperature,
(ii) Effect of humidity : With increase in humidity density decreases. This is because the molar mass
of water vapour is less than the molar mass of air.
P RT
(iii) Effect of pressure : The speed of sound in a gas is given by v
M
P
So at constant temperature, if P changes then also changes in such a way that remains
constant. Hence pressure does not have any effect on velocity of sound as long as temperature is
constant.
Power
(d) Intensity 22 f 2 A 2 V
unit area
P02
(e) Intensity of sound waves I
2v
1 1 a
(i) If the source is point source then I 2
and s0 and s sin t kr
r r r
1 1 a
(ii) If a sound source is a line source then I and s0 and s sin t kr
r r r
(iii) For a 1000 Hz tone, the smallest sound intensity that a human ear can detect is 1012 watt./m2. On
the other hand, continuous exposure to intensities above 1W/m2 can result in permanent hearing
loss.
I
(iv) Decibel scale 10 log (dB) ; I 1012 watt/m2.
I0
INTERFERENCE OF SOUND WAVES
p p0 sin(t kx )
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(i) For constructive interference
= 2n p0 p m1 p m2
I I1 I 2 2 I1I 2 cos
If I1 I 2 I 0
I 2I 0 (1 cos )
I 4I0 cos 2
2
Hence in this case, for constructive interference : = 0, 2, 4 …. and Imax 4I0 and for destructive
interference : = , 3 …. and I min 0
STANDING WAVES
(a) Standing wave
A standing waves is produced by the superposition of two identical waves traveling in opposite
directions viz., y1 a sin[kx t] and y 2 a sin(t kx), gives the standing wave,
y 2a sin t cos kx
The points having the maximum amplitude are those where 2a cos kx has a maximum value of 2a ,
these are at the position,
kx 0, , 2....
3 5
i.e., x 0, , , ,...
2 2 2
these points are called antinodes
The amplitudes reaches a minimum value of zero at the positions
3 5 3 5
where kx , , ,.... or, x , , ....
2 2 2 4 4 4
These points are called nodes.
Energy is not transported along the string to the right or to the left, because energy cannot flow through
the nodal points in the string which are permanently at rest.
(b) Longitudinal standing waves:
p 2p o cos(kx )
2
Points were pressure remains permanently at its average value; i.e. pressure amplitude is zero is called a
pressure node, and the condition for a pressure node would be given by
p0
i.e. cos(kx ) 0
2
i.e. kx 2n , n 0, 1, 2,....
2 2
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Similarly points where pressure amplitude is maximum is called a pressure antinode and condition for a
pressure antinode would be given by
p 2p o
i.e. cos(kx ) 1
2
or (kx ) n , n 0, 1, 2,....
2
Note that a pressure node in a standing wave would correspond to a displacement antinode; and a
pressure anti-node would correspond to a displacement node.
(when we label eqn) as SHM, what we mean is that excess pressure at any point varies simple-
harmonically. If the sound waves were represented in terms of displacement waves, then the equation of
standing wave corresponding to would be
s s o cos(t ) ; where s o 2s o sin(kx )
2 2
BEATS
If two or more waves of slightly different frequencies are superimposed, the intensity of the resulting waves has
alternate maxima and minima. The number of maximas in one second is called beat frequency.
1 2 2
p 2p o cos{(f1 f 2 )t }sin{(f1 f 2 )t 1 }
2 2
2
po (t) 2p o cos (f1 f 2 )t 1
2
f B f1 f 2
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(c) End correction:
e 0.6 r
Radius of the organ pipe
v v
fc and fo
4( 0.6r) 2( 1.2r)
DOPPLER’S EFFECT
(a) Sound source is moving and observer is stationary:
v
f' t
v vs
v vs
apparent wavelength '
v
(b) Sound source is stationary and observer is moving with velocity vo along the line joining them:
v vo
f'f
v
(c) The source and observer both are moving with velocities vs and vo along the line joining them:
v vo
f'f
v vs
v vs
'
v
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CHAPTER
11 THERMAL PHYSICS
(e) At absolute zero, the motion of all molecules of the gas stops.
(f) At higher temperature and low pressure or at higher temperature and low density, a real gas behaves as
an ideal gas.
8kT
(g) Average (or Mean) Speed: V 1.59 kT / m .
m
3kT kT
(h) RMS Speeds: Vrms v 2 1.73 .
m m
dN(v)
(i) Most Probable Speed: 0
dv
2kT
vp 1.41 kT / m Vrms v v p .
m
(j) Degree of freedom
Mono atomic: (all inert gases, He, Ar etc.) f=3 (translational)
Diatomic: (gases like H2, N2, O2 etc.) f=5 (3 translational + 2 rotational)
If temp < 70 K for diatomic molecules, then f=3
If temp in between 250 K to 5000 K, then f=5
(k) Maxwell’s Law of equpartition of energy
1
Energy associated with each degree of freedom kT. If degree of freedom of a molecule is f, then
2
1
total kinetic energy of that molecule fkT .
2
(l) Internal Energy
f
the gas. i.e. U f (T) . For an ideal gas internal energy U nRT .
2
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DIFFERENT TYPES OF PROCESSES:
(a) Isothermal Process
T = constant, PV = constant
P T T
V P V
Slope of P – V curve in isothermal process:
dP P
PV = constant = C
dV V
Work done in isothermal process:
Vf P P
W nRT n
Vi
Expansion Compression
V
W 2.303nRT log10 f
Vi
vi vf V vi vf V
P V V
T T P
f
Change in internal energy in isochoric process: U n R T
2
f
Heat given in isochoric process: Q U n R T
2
(c) Isobaric Process
Pressure remain constant in isobaric process
V
P = constant = constant
T
Indicator diagram of isobaric process:
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P P P
T V T (in Kelvin)
P P P P
V V V V
Q T
1 2 for Heat Engine, 1 2 for Carnot cycle
Q1 T1
(f) Adiabatic process
Equation of adiabatic process is given by
PV = constant Insulating
1- wall
TP = constant
Gas
TV-1 = constant
P
Slope of P – V – curve in adiabatic process: dP P
dV V
Since PV is a constant
dP P
V
dV V
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Work done in adiabatic Process
Pi Vi Pf Vf nR(Ti Tf )
W U nC v (Ti Tf )
( 1) 1
(g) Free Expansion
If a system, say a gas expands in such a way that no heat enters or leaves the system and also no work is
done by or on the system, then the expansion is called the “free expansion”.
Q 0, U 0 and W 0 . Temperature in the free expansion remains constant.
Comparison of slopes of Iso-thermal and Adiabatic Curve
P Adiabatic P Adiabatic
Isothermal Isothermal
dP dP
Isothe- poly
rmal dV adia dV isothermal di adiabatic
Adiabatic mono
V
V1 V2
W mono < W di < W poly < W isothermal < W adiabatic
MIXTURE OF NON-REACTING GASES:
n M n2M2
(a) Molecular weight 1 1 , M1 and M2 are molar masses.
n1 n 2
n1C v1 n 2 C v1 n C n 2CP 2
(b) Specific heat C v ,C p 1 P1
n1 n 2 n1 n 2
C P mix n1Cp1 n 2 CP2 .....
(c) For mixture,
D V mix n1CV1 n 2 CV 2 .....
HEAT TRANSFER
(a) Thermal conduction
Q KA(T1 T2 )
where K is the co-efficient of thermal conductivity of the material of the slab.
t x
x
Also R = thermal resistance =
KA
1 1 1 1
In parallel connection, ...
R eq R1 R 2 Rn
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Net Loss of Thermal energy, E = A (T 4 T04 )
(i) Absorptive power of a body is defined as the fraction of the incident radiation that is absorbed by
the body.
Energy absorbed
Absorptive power (A)
Energy incident
(ii) The emissive power (E) denotes the energy radiated per unit time per unit area of the surface.
(iii) Emissivity () of a surface is the ratio of the emissive power of the surface to the emissive power
of black body at the same temperature.
(iv) Emissivity = (Emissive power of the surface) (Emissive power of black body at the same
temperature).
(v) A perfectly blackbody is one which absorbs completely all the radiations, of whatever
wavelength, incident on it.
(d) Kirchhoff’s Law
It states that the ratio of the emissive power to the absorptive power for radiation of a given wavelength
is the same for all bodies at the same temperature, and is equal to the emissive power of a perfectly
blackbody at that temperature.
e
E (constant)
a
(e) Spectral distribution of energy is Black body radiations
Weins displacement law is m T constant, where, m = wavelength corresponding to maximum
spectral intensity
T = absolute temperature of surface of the body.
(f) Newton’s Law of cooling
For a small temperature difference between a body and its surrounding, the rate of cooling of the body
is directly proportional to the temperature difference.
dT
k(T T0 ) (rate of fall of temperature)
dt
T temperature of the body.
T0 temperature of the surroundings.
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