N■ Pr● pyI acetate

BAICHUAN(RUGAo)CHElMlCAL Co。 J LTD。

● ACcord∶ ngto GHs(sixth Revised Edition)

section1 Product and Company Identification

> Product ldentifier

Product Name N-PrOpyl acetate

synonyms
CAs No。 109-60冖 4

EC No。 203o686-1
MoIecuIar ForlmuIa C5H10O2

Relevaht ldentified Uses of the substance or Mixture and Uses Advised Against
ReIevant ldentified
P丨 ease cOnsu丨 t rη anufactureIr∶ 。
Uses
Uses Advised Against P丨 ease cOnsu丨 t rη anufacturen

>DetaⅡ s of the suppⅡ er of the safety Data sheet

AppIicant Nalme BA丨 CHUAN(RUGJ;\O)CHEMlCAL CO。 `LTD。
AppIication Address
6X丨 ANG爿 A D`CHANGJ丨 ANG TOWN`(RUGAO PORT D丨 STR丨 CT)RUGAO
C丨 T丫 AN
J丨 E`CHlNA
AppⅡ cant Post Code 226532
AppⅡ cant TeIephone +86-513-87229532
AppⅡ cant Fax +86-513-87229555
AppⅡ cant E■ lmaⅡ shibin@bcchem。 cOm
Manufacturer Name BA丨 CHUAN(RUGAO)CHEMlCAL Co。 `lJD。
Manufacturer 6X丨 ANGJ丨 ANG ROA⒐ CHANGJIANG TOWN` (RUGAO PORT D丨 STR丨 CT)RUGAO
Address C丨 T丫 ANGSU PROV丨 NCE`CHINA
J丨

Manufacturer Post
226532
Code
Manufacturer +86-513-87229532
TeIephone
Manufacturer Fax +86-513-87229555
Manufacturer E■ lma" shibin@bcchem。 cOm
■■
'
ιι丶

Emergency Phone Number

’一
r`ˉ

N:;Ibg:rcyPhone +:6~513-87229523
J
‘

section2 Hazards ldentification

Hazard cIass and IabeI eIements of the product accOrding to GHs(the sixth revised edition):

>GHs Hazard CIass

Page 1 of8
 FIalmlη abIe Liqu∶ ds CategOry2
Eye Damage/lrritation CategOry2A
c Target0)rgan
specif∶
Toxicity(singIe CategOry3
Exposure)

> GHs LabeI Elelments

Pictogram

signaI Word

Hazard Statements
H225 High丨 yf丨 anγ ηab丨 e liquid and vapOur
H319 Causes serious eye irritatiOn
H336 May cause dro讥
`sIness Or dizzIness
)Precautionary statements
Prevention
Keep away from hea1hot surfaces`sparks`Open flames and Otherignition
P210
sources。 NO smoHng。
P233 Keep cOntainer tight丨 yc丨 osed。
P240 Ground and bond cOntainer and receiψ ing equipment。
P241 ting/Ⅱ ghting]equipment。

P242
P243
P261 Avoid breathing dust/fume/gas/miSt/vapours/spray。
P264 Wash。 ¨thorOughly after handⅡ ng。

P272 Contaminated、 ″ork clothing shou丨 d not be aHowed Out of the workplace。
P280 VVear protective g丨 oves/prOtective c丨 othing/eye protection/face protectiOn。
Response
¨
P312 Ca丨 l a POIsON CENTEIVdoCtOGif you fee丨 unwel丨 。
P304+P340 IFINHALED∶ RemoVe person tO fresh air and keep cOrrlfortab丨 e for breathing。
P337+P313 丨
f eye irritation persists∶ Get rnedica丨 advice/attentiOn。
lF ON SKlN(Or hair)∶ Take offimmediately a丨 丨
cOntaminated dothing。 Rinse skin qJΞ

P303+P361+P353 with water/showen

勿丫

lFlN EYES∶ Rinse cautiOusly、 Ⅳith、″ater fOr severa丨 rninutes。 Remove cOntact
P305+P351+P338 lenses`if present and easy tO dO。 Continue rinsing。
storage
P403+P233 reH-venti丨 ated p丨 ace。 Keep cOntainer tight丨 yc丨 osed。
StOre in a、 冖

P403+P235 stOre in a vve"-venti丨 ated p丨 ace。 Keep cOo丨 。

hΗ

DisposaI
″飞

DispOse of cOntents/cOntainerin accOrdance with丨 oca丨 /regiona丨 /nationa丨 /

J

P501
internatiOnal regu丨 atiOns。

section3 Composition/Inforlmation on lngredients

Component Concentrat∶ on (weight CAs No。 EC No。

percentr %)

Page2Of8
 n-Propy丨 acetate )〓 99.5 109-60-4 203-686-1

section4 First Aid1Ⅵ easures

>Description of First Aid Measures

丨
mmediate medica丨 attentiOn is required。 ShOw this safety data sheet(sDS)to
GeneraI Advice
the doctOrin attendance。
Rinse thorough丨 y vvith p丨 enty Of讷 east151η inutes and cOnsu丨 ta
Eye Contact `ater fOr at丨
physician if fee丨 uncOrnfortab丨 e。
Take Off cOntarninated c丨 othing and shoes irnrη ediate丨 )^Wash Off vvith p丨 enty of
skin Contact
water fOr at丨 east15rη inutes and cOnsu丨 t a physician if fee丨 uncOrnfortab丨 e。
Do nOt induce vorniting。 Never give anything by rnouth to an uncOnsciOus
Ingestion
persOn。 Ca"a physician Or PoisOn ContrO丨 CenteriIη mediate丨 y.
MOve victim into fresh ai∴ 丨 f breathing is difficu丨 t`give oxygen。 Do nOt use
lnhaIation mOuth to rη outh resuscitation if victim ingested Orinha丨 ed the substance。 丨 f nOt
breathing`give artificia丨 respiration and cOnsu丨 t a physician imrη ediate丨 y.
Protecting of Ensure that rnedica丨 persOnnel are aware Of the substance invO丨 ved。 Take
First■ aiders precautions to protect themse丨 ves and prevent spread Of cOntamination。

)Mostlmportant symptoms and Effectsr b。 th Acute and DeIayed

ay° Ccur and may cause some cOncern foHOwing
1 Subs∶
』f(1丌 :‖ :`⒘ Ⅰ::L瓦 甘:∶ i:甘 r∶ ;古11古 I3!η
∶

亠 Indication of Any lΠ Ⅱ edical Attention and special Treatlη ent Needed

"ediate,田
1 Treat syn∩ ptOmaticaHy。

2 SymptOmsrnay be de丨 ayed。

section5 Fire Fighting Measures

)Extinguishing1Ⅵ edia

:岁 皂辱 ng MeⅢ a № not use a s引 d lvater鼓 mam as k may∝ atter Or叩 臼 dH℃ ・

拓

)specific Hazards Ar∶ sing from the Substance or""xture

1 vri丨 丨forrη exp丨 osive mixtures、″ith ain ”
lvestheTbyinCreasingⅡ ℃
fJ::∶ ∶
2⒎ 挹 1尼 9魂 ⒒
::jT亻s靴 :萎 :ntS thrOugh pressure relief旧
3 VapOurs rη ay trave丨 to source ofignitiOn and f丨 ash back。 囗

4 Liquid and vapour are f丨 arnIη ab丨 e。

b:—

5 COntainers rη ay
巧

exp丨 ode vvhen heated。

q

6 Fire expOsed cOntainers may vent contents thrOugh pressure reⅡ ef va丨 ves。

7 May expansion Or decOmpose exp丨 osive丨 y、 Ⅳhen heated orinvo丨 ved in fire。

>Advice for Firefighters 9.

1 ∞ f^C° ntained breathing apparatus(MSHⅣ N丨 OSH appmved Orequ~a丨 entland J。

扌i∫ ∶忍 ζ庄畏 u::∶ J

2 Fight fire frOm a safe distance`Ⅵ oth adequate cOven

3 Prevent fire extinguishing、″ater frOn∩ cOntaminating surface llvater or the ground、 ″ater system。

6
Page 3 Of8
>Personal Precautionsr Protective Equipment and Emergency Procedures
1 JAvOid breathing vapOrs and cOntacting v勹 1th skin and eye。
2 Beware Of vapours accumu丨 ating tO forrη exp丨 Osive cOncentratiOns。
3 VapOurs can accumu丨 ate in丨 Ow areas。
ed折 猁Ⅲng appⅢ 洫。
We吖 町
d咖 e and
4羿 漯::猛胥
:::孔 雾1茁 盱i擢 :⒖ 百
〖石1:t】 Γ
5 Ensure adequate venti丨 atiOn。 Remove a"sources Of ignitiOn。
6 Evacuate persOnne丨 tO safe areas。 Keep peOp丨 e away frorn and upwind OfspH丨 /丨 eak。
7 Use persona丨 protective equipment。 Avoid breathing vapOurs`rη is1gas or dust。

>EnvironmentaI Precautions
1 Prevent further丨 eakage Or spHlage if safe tO do so。
2 Discharge intO the envirOnment rnust be avoided。

>Methods and,Ⅵ ateriaIs for Containment and Cleaning Up

1坫 甜eHalin dγ 叼nd Orinert ab∞ №e吐 。ln ca∞ d hrge amOLl吐 d” 丨
丨ag⒍ cOntain a
i%;∶ :甘 :三 罗
ded m敲 m引 sh。 涮 № prompt9d叩 Osed o讠 m acco曲 nce潲 h appropH敲 eb岖
2‖ 早黑 漾 i烈罗
3 RemOve aH sOurces OfignitiOn,Use spark-prOOftOOls and exp丨 osion-prOOf equipment。

section7 HandⅡ ng and storage

>Precautions for HandⅡ ng

1 AvOid inhalatiOn Of vapors。
2 Use only non-sparking too丨 s。

rge steanη etal parts shou丨 d be

`equipment on aH rη

7 Avoid cOntact vvith skin and eyes。

8 Keep away frOm heat/sparks/Open f丨 a mes/hot surfaces。
9 Take precautiOnary rneasures against static discharges。

)Precautions for storage `力

1 Keep cOntainers tightly closed。

r〓

2 Keep cOntainers in a dryr CoO丨 and llveH-ventilated p丨 ace。

丁 丶

3 Keep a讷 Γay frOrn heat/Sparks/Open f丨 ames/hOt Surfaces。

(C(L~孑

4 Store a讷 `ay frOm incOmpatib丨 e1η ateria丨 s and fOodstuff cOntainers。

一
J

section8 Exposure Controls/PersonaI Protection

)Control Parameters
occupationaI Exposure Lilnit VaIues
Component Country/Region Lirnit、 J%,Iue■ Eight HOurs LiImit VbIue■ short TeⅡ η

Page4of8
|++湍
〓1〓+出 〓〓Ⅲ+础
=l:Ⅲ
+:出 七出揣拙跚 …
Ⅲ:Ⅲ ++半 :昔 ++出 ++器 Ⅱ++击 ++
i ppm ∶ mg/m3 : ppm ∶ mg/m3 ∵

n^PrP?y丨
卩卩y岍 ⑶ ∶
∶ 100
100 ∴ 4⒛
420 | |200 i20o | …¨ 84o
:r :∶Germany(DFG)
jJj二 ∶ ¨¨…¨
¨¨¨……
………
∶ FFr叩
r~_ˉ __ ∶ ⌒^^ λiX 丨 lΓ
109-60-4 ∶ France ∶ 200 . 840 } ¨
…¨
⒈̈ ¨¨
¨¨¨
………艹…
川
∶ Denmark ∶ 150 ∷ 625 1 300 ∶ 1250 -
∶ AustraⅡ a ∶ 200 | 835 ∶ 250 ∶ 1040
BioIogicaI LiⅡ △t VaIues
NO infOrIη atiOn ava"ab丨 e
Monitoring IⅥ ethods
EN14042Workp丨 ace atrnospheres。 Guide forthe appⅡ catiOn and use of prOcedures fOrthe assessment
Of expOsure tO che1nica丨 and biO丨 Ogica丨 agents。
2 GBZ/T160.1~GBz/T160.81-2004DeterIη ination of toxic substances in wOrkp丨 ace air(Series standard)。

>Engineering Controls
1 Ensure adequate venti丨 atiOn`especiaHy in cOnfined areas。
2 Ensure that eye讷 ose tO the、″orkstatiOn丨 ocatiOn。
`ash stations and safety showers are c丨
3 Use exp丨 osion-proof e丨 ectrica丨 /venti丨 ating/Ⅱ ghting/equipment。
4 Set up emergency exit and necessary risk-eⅡ rnination area。

)Personal Protection Equipment

Eye Protection Tightly fitting safety gOgg丨 es(apprOved by EN166(EU)or N丨 OsH(∪ S)。
Wear protective g丨 oves(such as buty丨 rubber)`passing the tests accOrding to
Hand Protection
EN374(EU)`US F739or AS/NZS2161.1standard。
lf exposure丨 imits are exceeded orifirritation or Other symptoms are
Respiratory protection experienced`use a fu"-face respiratOr vvith rη u丨 ti-purpOse cOmbinatiOn(US)or

type AXBEK(EN14387)respirator cartridges。

skin and Body wearfire/f丨
ame resistant/retardant c丨 othing and antistatic bOOts。
Protection

section9 Physic mical Properties

Appearance:COlor丨 ess transparent Ⅱquid odor:No informatiOn available ¨

odor ThreshoId:NO infOrIη atiOn avai丨 ab丨 e pH:No inforrnation avai丨 ab丨 e
MeIting Point/Freez∶ ng Point(° C):-92 InitiaI BoⅢ ing Point and BoⅡ ing Range(° C):101.6

FIash Point(°C)(CIosed Cup):14 Evaporation Rate:No infor1η atiOn avaHab丨 e

Uppe〃 I。 wer expIosive Ⅱmits[%fv/v)l:Upper Ⅱmit
FIalm1η abⅢ ity:NOt appⅡ cab丨 e
8;Lower Ⅱmit∶ 2
Vbpor Pressure(MPa):3.3 W/apor Density(g/mL):3.5
ReIat∶ ve Density(g/clm3):0.89 soIubⅢ ity:Part丨 y miscible vvith讷
`ater
n■ OctanoV勹 ″ater Partition Coefficient:1.24 Auto丬 gnition Temperature(° C):450
DecOmposition Telη perature(° C):No infOrIη atiOn Kinematic ViscOsity(mmγ s):No infOrmation
avai丨 ab丨 e ava"ab丨 e
ParticIe characterist∶ cs:Not appⅡ cab丨 e

section10 stab"ity and Reactivity

Reactivity COntact vvith incompatib丨 e substances can cause decOmpOsitiOn Or Other

Page 5 Of8
 chernica丨 reactions。

ChelmicaI stab"ity stab丨 e under proper operatiOn and storage conditions。

Possib"ity of
Hazardous Reactions
Conditions to Avoid
IncompatibIe MateriaIs
ln cOntact vvith rη etal alkoxides rnay cause a fire。
lnCOmpatib丨 e rnateria丨 s'hea1f丨 ame and spark。
Metal a丨 kyl oxide`meta丨 hydride`inorganic peroxide`nitrate and ha丨 ogens
oxyacid sa丨 ts。

Hazardous
Under nOr1η al conditiOns of storage and use`hazardOus decOmpositiOn
DecOmposition
products should not be produced。
products

sect∶ on11 Tox∶ coIog∶ caI Information

>Acute Toxicity
Component CAS No。 LDso(oraI) LD5o(DeⅡ ηaI) LC5o(lnhaIationJ4h)

n-PrOpy丨 No infOrrnatiOn NO inforrnatiOn

acetate
109-60-4 9370mg/kg(Rat)
avai丨 ab|e avaHab丨 e

)skin Corrosion/lrritation
No inforIη atiOn avai丨 ab丨 e

>Serious Eye Damage/lrritation

Causes serious eye irritation(Category2A)(n- etate)

>skin sensitization
No infOHη ation avaHab丨 e

>Respiratory sensitization
No inforIη ation avai丨 able

)Germ CeⅡ ,Ⅵ utagenicity

NO infoΠ ηation avai丨 ab丨 e

>Carcinogenicity
丶 ∷

ID CAs No。 Component IARC NTP

109-60-4
`彐

n-PrOpy丨 acetate NOt Listed NOt Listed

彐

)Reproductive Toxicity
氵

No infOrrnation e
亠丿

avai丨 ab丨
7

>Reproductive Toxicity(AdditionaI)
NO information avaHab丨 e

>STOT■ single Exposure

May cause drOwsiness Or dizziness(CategOry3)(n-PrOpy丨 acetate)

Page6Of8
)sTOT■ Repeated Exposure
No infor1η ation avaHab丨 e

)Aspiration Hazard
NO infOrIη ation avaHab丨 e

section12 EcoIogicaI lnfOrlmation

>Acute Aquatic1oxicity
Component CAs No。 Fish Crustaceans AIgae
n-PrOpy丨 NO infOrrnatiOn No inforrnatiOn
acetate
109-60-4 LCsO‘ 0mg/L lg6h)(Fish)
avaHab丨 e avaHab丨 e

)Chron∶ c Aquatic toxicity

No inforIη ation avaHab丨 e

>(others
Persistence and
NO inforIη atiOn avaHab|e
Degradab"ity
BioaccumuIative
No inforIη ation avai丨 ab丨 e
PotentiaI
Mob"ity in soⅢ No information avai
Resuks of PBT and n-Propy丨 acetate dO iteria for PBT and vPvB accOrding to
vPvB Assessment Regu丨 ation(EC)No XIl丨 。

section13 DisposaI Considerations

Waste Che1micaIs Before disposa丨 shou丨 d refer tO the relevant national and丨 oca丨 丨
a讥
`s and
regu丨 ation。RecOrn1η end the use ofincineratiOn dispOsa丨 。
Contan1inated Containers rη ay stiH present chemica丨 hazard when empty.Keep a讷
`ay frOΠ
1hOt
Packaging and ignitiOn sOurce of fire。Return tO suppⅡ er fOr^recycⅡ ng if pOssib丨 e。

DisposaI Refer tO sectiOn13.1and13.2。

Recolmlmendations
\η
ˉ
〓 ε
ˉ刊刂

Transporting LabeI
`

Marine poⅡ utant None

UN Number 1276
UN Proper sh∶ pping
n-PROPYL ACETATE
Name
Transport Hazard CIass 3

Page7 Of8
 Transport subsidiary
Hazard CIass
None
Packing Group Ⅱ

section15 ReguIatory Information

>International Chelmical lnventory

Component EINECs TsCA DsL IECsC NzIoC PICCs ΚECI AICs ENCs
n-PrOpy丨 acetate √ √ √ √ √ √ √ √ √

【
EIN ECs1 European Inventory of Existing CornrnerciaI Chernical substances。
【
TSCA】 United States Toxic Substances ControI Act Inventory。
【
DSL】 Canadian IDomestic Substances List。
【
IECSC】 China Inventory of Existing Chenη ical substances。
【
NZloC】 Nel、
`|J`Zealand Inventory of ChernicaIs。
【
PICCs】 Ph"ippines Inventory of ChernicaIs and ChemicaI Substances。
【
KECI】 Existing and EvaIuated ChernicaI substances。
AlCS1
【 AustraⅡ a Inventory of ChernicaI Substances。
【
ENCS】 Existing And New ChemicaI Substances。

Note
〃 ″
√ Indicates that the substance included in the regulations
″×″
That no data orincIuded in the regu丨 ations

section16 AdditionaI InfoⅡ ηation

Creation Date 2016/12/12

Revision Date 2016/12/12
Reason for Revision

>Disdaimer
This Safety Data sheet(sDS)Ⅵ ras prepared accOrding to UN GHS lthe6th revised editiOn)。 The data
inc丨 uded was derived from internationa丨 authOritative database。 C)ther infOrrη atiOn、
state Of Our knOw丨 edge。 We try to ensure the cOrrectness Of aH infOrrη atiOn,HOweve1dueⅡ`as based
`、 On the
tO the present
diversity Of
infor1η atiOn sOurces and the丨 irnitatiOns Of Our knOwledge`this documentis([)氵 nly for user′ s reference。 Users
shou丨 d make their independentjudgment Of suitability of this infOrmation fOr their particu丨 ar purposes。 Ⅵ 佗
do not assume responsibi丨 ity for丨 oss`damage or expense arising Out of orin any、
handⅡ ng`storage`use Or disposa丨 of the product。 `、 `ay cOnnected、 `\`ith the

Page8Of8