Cu(s)+4HNO3(ac) Cu(NO3)2(ac)+2H2O(l)+2NO2(g) (1)

Cu(NO3)2(ac)+2NaOH(ac) 2NaNO(ac)+ Cu(OH)2(s) (2)

1 𝑚𝑜𝑙 𝐶𝑢 4 𝑚𝑜𝑙 𝐻𝑁𝑂3 63𝑔 𝐻𝑁𝑂3

80g Cu x ( )X( ) x (1 𝑚𝑜𝑙 𝐻𝑁𝑂3) = 317,3g HNO3
63,54𝑔 1 𝑚𝑜𝑙 𝐶𝑢

1 𝑚𝑜𝑙 1𝑜𝑜 𝑚𝑙 𝑚𝑢𝑒𝑠𝑡𝑟𝑎

317,3g x ( 1,54𝑔 ) = 206,04 ml HNO3 x ( 65𝑚𝑙 𝐻𝑁𝑂3 ) = 317 ml HNO3 65%

Cu(OH)2(s) CuO(s)+H2O(ac) (3)

CuO(s)+H2SO4(ac) CuSO4(ac) + H2O (ac) (4)
CuSO4(ac)+ Zn(s) ZnSO4(ac) + Cu(s) (5)

Zn+2HCl ZnCl2+H2 (6)

Cu+4HNO3 Cu(NO3)2+ 2NO2+2H20

1 𝑚𝑜𝑙 4 𝑚𝑜𝑙 63𝑔
6g Cu x (63,54𝑔) X ( 1 𝑚𝑜𝑙 )x (1 𝑚𝑜𝑙 )=(23,8g Puros) 0,2

=23,8g +4,76g=28,56g
100𝑔 𝑑𝑒 𝑙𝑎 𝑠𝑜𝑙𝑢𝑐𝑖𝑜𝑛 1 𝑚𝑙 𝑠𝑜𝑙𝑢𝑐𝑖𝑜𝑛
28,56g Puros x ( )x( )=31,61ml
65𝑔 1,39𝑔

(31,61ml)x7=221,3ml a medir de HNO3

Extraer ácido nítrico concentrado HNO3
12g de cobre
1 𝑚𝑜𝑙 𝐶𝑢 1 𝑚𝑜𝑙 𝐶𝑢(𝑁𝑂3)2 187,55𝑔
6g Cu x ( )x( )x( ) = 17,71g Cu(NO3)2
63,55𝑔 1 𝑚𝑜𝑙 𝐶𝑢 1 𝑚𝑜𝑙

(1,5 M)

Cu(NO3)2+ 2NaOH Cu(OH)2(s) + NaNO3

1 𝑚𝑜𝑙 2 𝑚𝑜𝑙 𝑁𝑎𝑂𝐻
17,71g x (187,55𝑔) x ( ) = 0.19 mol NaOH
1 𝑚𝑜𝑙

1,5 𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 1000 𝑚𝑙 𝑠𝑜𝑙𝑢𝑐𝑖ó𝑛

x 0,19 mol NaOH = 127ml NaOH
100𝑚𝑙 1,5 𝑚𝑜𝑙
 1 𝑚𝑜𝑙 𝐶𝑢 1 𝑚𝑜𝑙 𝐶𝑢 (𝑁𝑂3)2 187.55𝑔
6g Cu x ( 63.55 𝑔 ) x ( ) x ( 1 𝑚𝑜𝑙 )=17.71 g Cu(NO3)2
1 𝑚𝑜𝑙 𝐶𝑢

Cu(NO3)2 + 2NaOH Cu(OH)2(s) +2NaNO3

1 𝑚𝑜𝑙 2 𝑚𝑜𝑙 𝑁𝑎𝑂𝐻
17.71g x (187.55 𝑔) x ( )= 0.19 NaOH
1 𝑚𝑜𝑙

1.5𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 1000𝑚𝑙 𝑠𝑙𝑛

x 0.19 mol NaOH = 127ml NaOH
1000𝑚𝑙 1.5 𝑚𝑜𝑙
127
= 5.08
25

pH=10 Cu(OH)2 CuO + H2O

CuO +H2SO4 CuSO2(s) + H2O= 7.51g
79.55 𝑔 𝐶𝑢𝑂
6g Cu x ( 63.55 𝑔 𝐶𝑢 )= 7.51 g CuO

98 𝑔 𝐻2𝑆𝑂4 100𝑔 𝑠𝑙𝑛

7.51g CuO x (79.55𝑔 𝐶𝑢𝑂 )= 9.2g H2SO4 x (0.7𝑔 𝐻2𝑆𝑂4) = 9.6g

1 𝑚𝑜𝑙 𝑠𝑙𝑛
9.6g sln H2SO4 x ( 1.84𝑔 𝑠𝑙𝑛 )= 5.22ml x 0.2 = 1.04

En el laboratorio existe solución en un balón aforado de 100ml de ácido clorhídrico

que tiene una etiqueta de.